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Monatomic Ions Variable and Fixed

Monatomic Ions Variable and Fixed. Fixed Variable

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Why is it important to know common oxidation states? What happens when iron rusts? –List some ideas using your monatomic list.

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Page 1: Monatomic Ions Variable and Fixed. Fixed Variable

Monatomic Ions Variable and Fixed

Page 2: Monatomic Ions Variable and Fixed. Fixed Variable

Symbols and Charges for Monatomic Ions Fixed Charge

Symbol Name Symbol Name H1+ hydrogen ion H1- hydride Li1+ lithium ion F1- fluoride Na1+ sodium ion Cl1- chloride K1+ potassium ion Br1- bromide Rb1+ rubidium ion I1- iodide Cs1+ cesium ion O2- oxide Be2+ beryllium ion S2- sulfide Mg2+ magnesium ion Se2- selenide Ca2+ calcium ion Te2- telluride Sr2+ strontium ion N3- nitride Ba2+ barium ion P3- phosphide Ra2+ radium ion As3- arsenide Al3+ aluminum ion Ag1+ silver ion Zn2+ zinc ion

The ending for a negative ion’s name is –ide. For example, fluorine is fluoride. Replace the -ine with -ide

Cd2+ strontium ion

Symbols and Charges for Monatomic Ions Variable Charge

Symbol (Stock system) Systematic name

Common name

Symbol (Stock system) Systematic name

Common name

Cu+ copper(I) cuprous Ni2+ nickel(II) nickelous Cu2+ copper(II) cupric Ni3+ nickel(II) nickelic Au+ gold(I) aurous Au3+ gold(III) auric Sn2+ tin(II) stannous Cr2+ chromium(II) chromous Sn4+ tin(IV) stannic Cr3+ chromium(III) chromic Pb2+ lead(II) plumbous Mn2+ manganese(II) manganous Pb4+ lead(IV) plumbic Mn3+ manganese(III) manganic Fe2+ iron(II) ferrous Hg2

2+ mercury(I) mercurous Fe3+ iron(III) ferric Hg2+ mercury(II) mercuric Co2+ cobalt(II) cobaltous Co3+ cobalt(III) cobaltic

Fixed

Variable

Page 3: Monatomic Ions Variable and Fixed. Fixed Variable

Why is it important to know common oxidation states?

• What happens when iron rusts?– List some ideas using your monatomic list.

Page 4: Monatomic Ions Variable and Fixed. Fixed Variable

Iron Rusting

Fe is oxidation state 0

Fe2+ is oxidation state of 2+

A pit is formed in the Fe. Water enters the pit.

Fe2+ and Fe3+ is exposed to oxygen and forms Fe2O3 with water attached.

Picture from: http://library.kcc.hawaii.edu/external/chemistry/everyday_corrosion.html

Page 5: Monatomic Ions Variable and Fixed. Fixed Variable

Memorizing Monatomic Ions

• Recall the number in a series that you are able to remember in short term memory from the sequencing lab.

• Use this number and chunking when you study the monatomic ions to memorize these ions.

• This presentation will give you large chunks, but you may have to break them down into smaller chunks for your span.

Page 6: Monatomic Ions Variable and Fixed. Fixed Variable

Hopefully, your brain is a little larger than this one.

His sequence recall is less than one.

Picture from:http://www.simpsonstrivia.com.ar/simpsons-photos/wallpapers/homer-simpson-wallpaper-brain-1024.jpg

Page 7: Monatomic Ions Variable and Fixed. Fixed Variable

Fixed Monatomic IonsSymbols and Charges for Monatomic Ions

Fixed Charge Symbol Name Symbol Name H1+ hydrogen ion H1- hydride Li1+ lithium ion F1- fluoride Na1+ sodium ion Cl1- chloride K1+ potassium ion Br1- bromide Rb1+ rubidium ion I1- iodide Cs1+ cesium ion O2- oxide Be2+ beryllium ion S2- sulfide Mg2+ magnesium ion Se2- selenide Ca2+ calcium ion Te2- telluride Sr2+ strontium ion N3- nitride Ba2+ barium ion P3- phosphide Ra2+ radium ion As3- arsenide Al3+ aluminum ion Ag1+ silver ion Zn2+ zinc ion

The ending for a negative ion’s name is –ide. For example, fluorine is fluoride. Replace the -ine with -ide

Cd2+ strontium ion

Page 8: Monatomic Ions Variable and Fixed. Fixed Variable

Some of the columns of the periodic table have a pattern for the

monatomic fixed ions

Page 9: Monatomic Ions Variable and Fixed. Fixed Variable

Column 1FixedColumn 1 loses an electron to obtain the noble gas

configuration of column 18.

1+ 1 The Periodic Table of the Elements 18

1

H 1.008 2

13 14 15 16 17

2

He 4.003

3

Li 6.941

4

Be 9.012

5

B 10.81

6

C 12.01

7

N 14.01

8

O 16.00

9

F 19.00

10

Ne 20.18

11

Na 22.99

12

Mg 24.31 3 4 5 6 7 8 9 10 11 12

13

Al 26.98

14

Si 28.09

15

P 30.97

16

S 32.07

17

Cl 35.45

18

Ar 39.95

19

K 39.10

20

Ca 40.08

21

Sc 44.96

22

Ti 47.87

23

V 50.94

24

Cr 52.00

25

Mn 54.94

26

Fe 55.85

27

Co 58.93

28

Ni 58.69

29

Cu 63.55

30

Zn 65.39

31

Ga 69.72

32

Ge 72.61

33

As 74.92

34

Se 78.96

35

Br 79.90

36

Kr 83.80

37

Rb 85.47

38

Sr 87.62

39

Y 88.91

40

Zr 91.22

41

Nb 92.91

42

Mo 95.94

43

Tc (98)

44

Ru 101.1

45

Rh 102.9

46

Pd 106.4

47

Ag 107.9

48

Cd 112.4

49

In 114.8

50

Sn 118.7

51

Sb 121.8

52

Te 127.6

53

I 126.9

54

Xe 131.3

55

Cs 132.9

56

Ba 137.3

57

La 138.9

72

Hf 178.5

73

Ta 180.9

74

W 183.8

75

Re 186.2

76

Os 190.2

77

Ir 192.2

78

Pt 195.1

79

Au 197.0

80

Hg 200.6

81

Tl 204.4

82

Pb 207.2

83

Bi 209.0

84

Po (209)

85

At (210)

86

Rn (222)

87

Fr (223)

88

Ra (226)

89

Ac (227)

104

Rf (261)

105

Db (262)

106

Sg (266)

107

Bh (264)

108

Hs (269)

109

Mt (268)

110

Uun (271)

111

Uuu (272)

112

Uub (277)

Periodic table adapted from: www.swansontec.com/selement.htm

Page 10: Monatomic Ions Variable and Fixed. Fixed Variable

Column 2Fixed Column 1 loses two electrons to obtain the

noble gas configuration of column 18.

1+ 1 The Periodic Table of the Elements 18

1

H 1.008

2+ 2

13 14 15 16 17

2

He 4.003

3

Li 6.941

4

Be 9.012

5

B 10.81

6

C 12.01

7

N 14.01

8

O 16.00

9

F 19.00

10

Ne 20.18

11

Na 22.99

12

Mg 24.31 3 4 5 6 7 8 9 10 11 12

13

Al 26.98

14

Si 28.09

15

P 30.97

16

S 32.07

17

Cl 35.45

18

Ar 39.95

19

K 39.10

20

Ca 40.08

21

Sc 44.96

22

Ti 47.87

23

V 50.94

24

Cr 52.00

25

Mn 54.94

26

Fe 55.85

27

Co 58.93

28

Ni 58.69

29

Cu 63.55

30

Zn 65.39

31

Ga 69.72

32

Ge 72.61

33

As 74.92

34

Se 78.96

35

Br 79.90

36

Kr 83.80

37

Rb 85.47

38

Sr 87.62

39

Y 88.91

40

Zr 91.22

41

Nb 92.91

42

Mo 95.94

43

Tc (98)

44

Ru 101.1

45

Rh 102.9

46

Pd 106.4

47

Ag 107.9

48

Cd 112.4

49

In 114.8

50

Sn 118.7

51

Sb 121.8

52

Te 127.6

53

I 126.9

54

Xe 131.3

55

Cs 132.9

56

Ba 137.3

57

La 138.9

72

Hf 178.5

73

Ta 180.9

74

W 183.8

75

Re 186.2

76

Os 190.2

77

Ir 192.2

78

Pt 195.1

79

Au 197.0

80

Hg 200.6

81

Tl 204.4

82

Pb 207.2

83

Bi 209.0

84

Po (209)

85

At (210)

86

Rn (222)

87

Fr (223)

88

Ra (226)

89

Ac (227)

104

Rf (261)

105

Db (262)

106

Sg (266)

107

Bh (264)

108

Hs (269)

109

Mt (268)

110

Uun (271)

111

Uuu (272)

112

Uub (277)

Periodic table adapted from: www.swansontec.com/selement.htm

Page 11: Monatomic Ions Variable and Fixed. Fixed Variable

Column 11 Silver Ag FixedColumn 11 loses two electrons to obtain the noble gas configuration of column 18 for the outer shell.

1+ 1 The Periodic Table of the Elements 18

1

H 1.008

2+ 2

13 14 15 16 17

2

He 4.003

3

Li 6.941

4

Be 9.012

5

B 10.81

6

C 12.01

7

N 14.01

8

O 16.00

9

F 19.00

10

Ne 20.18

11

Na 22.99

12

Mg 24.31 3 4 5 6 7 8 9 10 11 12

13

Al 26.98

14

Si 28.09

15

P 30.97

16

S 32.07

17

Cl 35.45

18

Ar 39.95

19

K 39.10

20

Ca 40.08

21

Sc 44.96

22

Ti 47.87

23

V 50.94

24

Cr 52.00

25

Mn 54.94

26

Fe 55.85

27

Co 58.93

28

Ni 58.69

29

Cu 63.55

30

Zn 65.39

31

Ga 69.72

32

Ge 72.61

33

As 74.92

34

Se 78.96

35

Br 79.90

36

Kr 83.80

37

Rb 85.47

38

Sr 87.62

39

Y 88.91

40

Zr 91.22

41

Nb 92.91

42

Mo 95.94

43

Tc (98)

44

Ru 101.1

45

Rh 102.9

46

Pd 106.4

47

Ag 107.9

48

Cd 112.4

49

In 114.8

50

Sn 118.7

51

Sb 121.8

52

Te 127.6

53

I 126.9

54

Xe 131.3

55

Cs 132.9

56

Ba 137.3

57

La 138.9

72

Hf 178.5

73

Ta 180.9

74

W 183.8

75

Re 186.2

76

Os 190.2

77

Ir 192.2

78

Pt 195.1

79

Au 197.0

80

Hg 200.6

81

Tl 204.4

82

Pb 207.2

83

Bi 209.0

84

Po (209)

85

At (210)

86

Rn (222)

87

Fr (223)

88

Ra (226)

89

Ac (227)

104

Rf (261)

105

Db (262)

106

Sg (266)

107

Bh (264)

108

Hs (269)

109

Mt (268)

110

Uun (271)

111

Uuu (272)

112

Uub (277)

Periodic table adapted from: www.swansontec.com/selement.htm

Page 12: Monatomic Ions Variable and Fixed. Fixed Variable

Column 12 FixedColumn 12 loses two electrons to obtain the noble gas configuration of column 18 for the outer shell.

1+ 1 The Periodic Table of the Elements 18

1

H 1.008

2+ 2

13 14 15 16 17

2

He 4.003

3

Li 6.941

4

Be 9.012

5

B 10.81

6

C 12.01

7

N 14.01

8

O 16.00

9

F 19.00

10

Ne 20.18

11

Na 22.99

12

Mg 24.31 3 4 5 6 7 8 9 10 11

2+ 12

13

Al 26.98

14

Si 28.09

15

P 30.97

16

S 32.07

17

Cl 35.45

18

Ar 39.95

19

K 39.10

20

Ca 40.08

21

Sc 44.96

22

Ti 47.87

23

V 50.94

24

Cr 52.00

25

Mn 54.94

26

Fe 55.85

27

Co 58.93

28

Ni 58.69

29

Cu 63.55

30

Zn 65.39

31

Ga 69.72

32

Ge 72.61

33

As 74.92

34

Se 78.96

35

Br 79.90

36

Kr 83.80

37

Rb 85.47

38

Sr 87.62

39

Y 88.91

40

Zr 91.22

41

Nb 92.91

42

Mo 95.94

43

Tc (98)

44

Ru 101.1

45

Rh 102.9

46

Pd 106.4

47

Ag 107.9

48

Cd 112.4

49

In 114.8

50

Sn 118.7

51

Sb 121.8

52

Te 127.6

53

I 126.9

54

Xe 131.3

55

Cs 132.9

56

Ba 137.3

57

La 138.9

72

Hf 178.5

73

Ta 180.9

74

W 183.8

75

Re 186.2

76

Os 190.2

77

Ir 192.2

78

Pt 195.1

79

Au 197.0

80

Hg 200.6

81

Tl 204.4

82

Pb 207.2

83

Bi 209.0

84

Po (209)

85

At (210)

86

Rn (222)

87

Fr (223)

88

Ra (226)

89

Ac (227)

104

Rf (261)

105

Db (262)

106

Sg (266)

107

Bh (264)

108

Hs (269)

109

Mt (268)

110

Uun (271)

111

Uuu (272)

112

Uub (277)

Periodic table adapted from: www.swansontec.com/selement.htm

Page 13: Monatomic Ions Variable and Fixed. Fixed Variable

Column 13 Fixed Column 13 loses three electrons.

Only aluminum is fixed in this column

1+ 1 The Periodic Table of the Elements 18

1

H 1.008

2+ 2

3+ 13 14 15 16 17

2

He 4.003

3

Li 6.941

4

Be 9.012

5

B 10.81

6

C 12.01

7

N 14.01

8

O 16.00

9

F 19.00

10

Ne 20.18

11

Na 22.99

12

Mg 24.31 3 4 5 6 7 8 9 10 11 12

13

Al 26.98

14

Si 28.09

15

P 30.97

16

S 32.07

17

Cl 35.45

18

Ar 39.95

19

K 39.10

20

Ca 40.08

21

Sc 44.96

22

Ti 47.87

23

V 50.94

24

Cr 52.00

25

Mn 54.94

26

Fe 55.85

27

Co 58.93

28

Ni 58.69

29

Cu 63.55

30

Zn 65.39

31

Ga 69.72

32

Ge 72.61

33

As 74.92

34

Se 78.96

35

Br 79.90

36

Kr 83.80

37

Rb 85.47

38

Sr 87.62

39

Y 88.91

40

Zr 91.22

41

Nb 92.91

42

Mo 95.94

43

Tc (98)

44

Ru 101.1

45

Rh 102.9

46

Pd 106.4

47

Ag 107.9

48

Cd 112.4

49

In 114.8

50

Sn 118.7

51

Sb 121.8

52

Te 127.6

53

I 126.9

54

Xe 131.3

55

Cs 132.9

56

Ba 137.3

57

La 138.9

72

Hf 178.5

73

Ta 180.9

74

W 183.8

75

Re 186.2

76

Os 190.2

77

Ir 192.2

78

Pt 195.1

79

Au 197.0

80

Hg 200.6

81

Tl 204.4

82

Pb 207.2

83

Bi 209.0

84

Po (209)

85

At (210)

86

Rn (222)

87

Fr (223)

88

Ra (226)

89

Ac (227)

104

Rf (261)

105

Db (262)

106

Sg (266)

107

Bh (264)

108

Hs (269)

109

Mt (268)

110

Uun (271)

111

Uuu (272)

112

Uub (277)

Periodic table adapted from: www.swansontec.com/selement.htm

Page 14: Monatomic Ions Variable and Fixed. Fixed Variable

Column 15Column 15 gains three electrons to obtain the noble gas configuration of column 18

1+ 1 The Periodic Table of the Elements 18

1

H 1.008

2+ 2

3+ 13 14

3- 15 16 17

2

He 4.003

3

Li 6.941

4

Be 9.012

5

B 10.81

6

C 12.01

7

N 14.01

8

O 16.00

9

F 19.00

10

Ne 20.18

11

Na 22.99

12

Mg 24.31 3 4 5 6 7 8 9 10 11 12

13

Al 26.98

14

Si 28.09

15

P 30.97

16

S 32.07

17

Cl 35.45

18

Ar 39.95

19

K 39.10

20

Ca 40.08

21

Sc 44.96

22

Ti 47.87

23

V 50.94

24

Cr 52.00

25

Mn 54.94

26

Fe 55.85

27

Co 58.93

28

Ni 58.69

29

Cu 63.55

30

Zn 65.39

31

Ga 69.72

32

Ge 72.61

33

As 74.92

34

Se 78.96

35

Br 79.90

36

Kr 83.80

37

Rb 85.47

38

Sr 87.62

39

Y 88.91

40

Zr 91.22

41

Nb 92.91

42

Mo 95.94

43

Tc (98)

44

Ru 101.1

45

Rh 102.9

46

Pd 106.4

47

Ag 107.9

48

Cd 112.4

49

In 114.8

50

Sn 118.7

51

Sb 121.8

52

Te 127.6

53

I 126.9

54

Xe 131.3

55

Cs 132.9

56

Ba 137.3

57

La 138.9

72

Hf 178.5

73

Ta 180.9

74

W 183.8

75

Re 186.2

76

Os 190.2

77

Ir 192.2

78

Pt 195.1

79

Au 197.0

80

Hg 200.6

81

Tl 204.4

82

Pb 207.2

83

Bi 209.0

84

Po (209)

85

At (210)

86

Rn (222)

87

Fr (223)

88

Ra (226)

89

Ac (227)

104

Rf (261)

105

Db (262)

106

Sg (266)

107

Bh (264)

108

Hs (269)

109

Mt (268)

110

Uun (271)

111

Uuu (272)

112

Uub (277)

Periodic table adapted from: www.swansontec.com/selement.htm

Page 15: Monatomic Ions Variable and Fixed. Fixed Variable

Column 16Column 15 gains four electrons to obtain the

noble gas configuration of column 18

1+ 1 The Periodic Table of the Elements 18

1

H 1.008

2+ 2

3+ 13 14

3- 15

2- 16 17

2

He 4.003

3

Li 6.941

4

Be 9.012

5

B 10.81

6

C 12.01

7

N 14.01

8

O 16.00

9

F 19.00

10

Ne 20.18

11

Na 22.99

12

Mg 24.31 3 4 5 6 7 8 9 10 11 12

13

Al 26.98

14

Si 28.09

15

P 30.97

16

S 32.07

17

Cl 35.45

18

Ar 39.95

19

K 39.10

20

Ca 40.08

21

Sc 44.96

22

Ti 47.87

23

V 50.94

24

Cr 52.00

25

Mn 54.94

26

Fe 55.85

27

Co 58.93

28

Ni 58.69

29

Cu 63.55

30

Zn 65.39

31

Ga 69.72

32

Ge 72.61

33

As 74.92

34

Se 78.96

35

Br 79.90

36

Kr 83.80

37

Rb 85.47

38

Sr 87.62

39

Y 88.91

40

Zr 91.22

41

Nb 92.91

42

Mo 95.94

43

Tc (98)

44

Ru 101.1

45

Rh 102.9

46

Pd 106.4

47

Ag 107.9

48

Cd 112.4

49

In 114.8

50

Sn 118.7

51

Sb 121.8

52

Te 127.6

53

I 126.9

54

Xe 131.3

55

Cs 132.9

56

Ba 137.3

57

La 138.9

72

Hf 178.5

73

Ta 180.9

74

W 183.8

75

Re 186.2

76

Os 190.2

77

Ir 192.2

78

Pt 195.1

79

Au 197.0

80

Hg 200.6

81

Tl 204.4

82

Pb 207.2

83

Bi 209.0

84

Po (209)

85

At (210)

86

Rn (222)

87

Fr (223)

88

Ra (226)

89

Ac (227)

104

Rf (261)

105

Db (262)

106

Sg (266)

107

Bh (264)

108

Hs (269)

109

Mt (268)

110

Uun (271)

111

Uuu (272)

112

Uub (277)

Periodic table adapted from: www.swansontec.com/selement.htm

Page 16: Monatomic Ions Variable and Fixed. Fixed Variable

Column 17Column 17 gains one electron to obtain the

noble gas configuration of column 18

1+ 1 The Periodic Table of the Elements 18

1

H 1.008

2+ 2

3+ 13 14

3- 15

2- 16

1- 17

2

He 4.003

3

Li 6.941

4

Be 9.012

5

B 10.81

6

C 12.01

7

N 14.01

8

O 16.00

9

F 19.00

10

Ne 20.18

11

Na 22.99

12

Mg 24.31 3 4 5 6 7 8 9 10 11 12

13

Al 26.98

14

Si 28.09

15

P 30.97

16

S 32.07

17

Cl 35.45

18

Ar 39.95

19

K 39.10

20

Ca 40.08

21

Sc 44.96

22

Ti 47.87

23

V 50.94

24

Cr 52.00

25

Mn 54.94

26

Fe 55.85

27

Co 58.93

28

Ni 58.69

29

Cu 63.55

30

Zn 65.39

31

Ga 69.72

32

Ge 72.61

33

As 74.92

34

Se 78.96

35

Br 79.90

36

Kr 83.80

37

Rb 85.47

38

Sr 87.62

39

Y 88.91

40

Zr 91.22

41

Nb 92.91

42

Mo 95.94

43

Tc (98)

44

Ru 101.1

45

Rh 102.9

46

Pd 106.4

47

Ag 107.9

48

Cd 112.4

49

In 114.8

50

Sn 118.7

51

Sb 121.8

52

Te 127.6

53

I 126.9

54

Xe 131.3

55

Cs 132.9

56

Ba 137.3

57

La 138.9

72

Hf 178.5

73

Ta 180.9

74

W 183.8

75

Re 186.2

76

Os 190.2

77

Ir 192.2

78

Pt 195.1

79

Au 197.0

80

Hg 200.6

81

Tl 204.4

82

Pb 207.2

83

Bi 209.0

84

Po (209)

85

At (210)

86

Rn (222)

87

Fr (223)

88

Ra (226)

89

Ac (227)

104

Rf (261)

105

Db (262)

106

Sg (266)

107

Bh (264)

108

Hs (269)

109

Mt (268)

110

Uun (271)

111

Uuu (272)

112

Uub (277)

Periodic table adapted from: www.swansontec.com/selement.htm

Page 17: Monatomic Ions Variable and Fixed. Fixed Variable

Common Monatomic Variable Ions

Symbols and Charges for Monatomic Ions Variable Charge

Symbol (Stock system) Systematic name

Common name

Symbol (Stock system) Systematic name

Common name

Cu+ copper(I) cuprous Ni2+ nickel(II) nickelous Cu2+ copper(II) cupric Ni3+ nickel(II) nickelic Au+ gold(I) aurous Au3+ gold(III) auric Sn2+ tin(II) stannous Cr2+ chromium(II) chromous Sn4+ tin(IV) stannic Cr3+ chromium(III) chromic Pb2+ lead(II) plumbous Mn2+ manganese(II) manganous Pb4+ lead(IV) plumbic Mn3+ manganese(III) manganic Fe2+ iron(II) ferrous Hg2

2+ mercury(I) mercurous Fe3+ iron(III) ferric Hg2+ mercury(II) mercuric Co2+ cobalt(II) cobaltous Co3+ cobalt(III) cobaltic

Page 18: Monatomic Ions Variable and Fixed. Fixed Variable

Variable Monatomic Ions• The transition monatomic ions have many

different oxidation charges (charge of the ion)• Many variable monatomic ions have common

names as well as the stock system name.• Learning the ions is difficult. Using your

chunking skills makes it much easier to memorize.

• There are many variable ion in the transition metals.

• The ions that are presented are only the common variable ions with common names.

Page 19: Monatomic Ions Variable and Fixed. Fixed Variable

The Stock system name uses Roman numerals for the charge of the ion.

Symbols and Charges for Monatomic Ions Variable Charge

Symbol (Stock system) Systematic name

Common name

Symbol (Stock system) Systematic name

Common name

Cu+ copper(I) cuprous Ni2+ nickel(II) nickelous Cu2+ copper(II) cupric Ni3+ nickel(III) nickelic Au+ gold(I) aurous Au3+ gold(III) auric Sn2+ tin(II) stannous Cr2+ chromium(II) chromous Sn4+ tin(IV) stannic Cr3+ chromium(III) chromic Pb2+ lead(II) plumbous Mn2+ manganese(II) manganous Pb4+ lead(IV) plumbic Mn3+ manganese(III) manganic Fe2+ iron(II) ferrous Hg2

2+ mercury(I) mercurous Fe3+ iron(III) ferric Hg2+ mercury(II) mercuric Co2+ cobalt(II) cobaltous Co3+ cobalt(III) cobaltic

•Copper (I)

•Cu1+

•Tin (IV)

•Sn4+

Page 20: Monatomic Ions Variable and Fixed. Fixed Variable

Common Naming System• According to IUPAC

naming compounds with common names is typically used when the ion does not have more than two oxidation states.

Symbols and Charges for Monatomic Ions Variable Charge

Symbol (Stock system) Systematic name

Common name

Symbol (Stock system) Systematic name

Common name

Cu+ copper(I) cuprous Ni2+ nickel(II) nickelous Cu2+ copper(II) cupric Ni3+ nickel(II) nickelic Au+ gold(I) aurous Au3+ gold(III) auric Sn2+ tin(II) stannous Cr2+ chromium(II) chromous Sn4+ tin(IV) stannic Cr3+ chromium(III) chromic Pb2+ lead(II) plumbous Mn2+ manganese(II) manganous Pb4+ lead(IV) plumbic Mn3+ manganese(III) manganic Fe2+ iron(II) ferrous Hg2

2+ mercury(I) mercurous Fe3+ iron(III) ferric Hg2+ mercury(II) mercuric Co2+ cobalt(II) cobaltous Co3+ cobalt(III) cobaltic

Page 21: Monatomic Ions Variable and Fixed. Fixed Variable

Some words to remember for common naming

• -ous is less – The charge of the ion is the lower oxidation

number– Example Ferrous is Fe2+

• -ic is more– The charge of the ion is the higher oxidation

number– Example Ferric is Fe3+

Page 22: Monatomic Ions Variable and Fixed. Fixed Variable

Cr, Mn, Fe, Co, Ni For common naming

2+ -ous is less, 3+ -ic is more Pattern on the periodic chart

1+ 1 The Periodic Table of the Elements 18

1

H 1.008

2+ 2

3+ 13 14

3- 15

2- 16

1- 17

2

He 4.003

3

Li 6.941

4

Be 9.012

Example: Chromous 2+ Chromic 3+ 5

B 10.81

6

C 12.01

7

N 14.01

8

O 16.00

9

F 19.00

10

Ne 20.18

11

Na 22.99

12

Mg 24.31

3 4 5

II III - ous -ic 2+ and 3+

6 7 8 9 10 11 12

13

Al 26.98

14

Si 28.09

15

P 30.97

16

S 32.07

17

Cl 35.45

18

Ar 39.95

19

K 39.10

20

Ca 40.08

21

Sc 44.96

22

Ti 47.87

23

V 50.94

24

Cr 52.00

25

Mn 54.94

26

Fe 55.85

27

Co 58.93

28

Ni 58.69

29

Cu 63.55

30

Zn 65.39

31

Ga 69.72

32

Ge 72.61

33

As 74.92

34

Se 78.96

35

Br 79.90

36

Kr 83.80

37

Rb 85.47

38

Sr 87.62

39

Y 88.91

40

Zr 91.22

41

Nb 92.91

42

Mo 95.94

43

Tc (98)

44

Ru 101.1

45

Rh 102.9

46

Pd 106.4

47

Ag 107.9

48

Cd 112.4

49

In 114.8

50

Sn 118.7

51

Sb 121.8

52

Te 127.6

53

I 126.9

54

Xe 131.3

55

Cs 132.9

56

Ba 137.3

57

La 138.9

72

Hf 178.5

73

Ta 180.9

74

W 183.8

75

Re 186.2

76

Os 190.2

77

Ir 192.2

78

Pt 195.1

79

Au 197.0

80

Hg 200.6

81

Tl 204.4

82

Pb 207.2

83

Bi 209.0

84

Po (209)

85

At (210)

86

Rn (222)

87

Fr (223)

88

Ra (226)

89

Ac (227)

104

Rf (261)

105

Db (262)

106

Sg (266)

107

Bh (264)

108

Hs (269)

109

Mt (268)

110

Uun (271)

111

Uuu (272)

112

Uub (277)

Periodic table adapted from: www.swansontec.com/selement.htm

Page 23: Monatomic Ions Variable and Fixed. Fixed Variable

Cu, Ag, and Au are all 1+Cu is 1+ and 2+Au is 1+ and 3+

(The 3rd row down)-ous is less, -ic is more

1+ 1 The Periodic Table of the Elements 18

1

H 1.008

2+ 2

3+ 13 14

3- 15

2- 16

1- 17

2

He 4.003

3

Li 6.941

4

Be 9.012

5

B 10.81

6

C 12.01

7

N 14.01

8

O 16.00

9

F 19.00

10

Ne 20.18

11

Na 22.99

12

Mg 24.31

3 4 5 6 7 8 9 10

1+ and

varied 11 12

13

Al 26.98

14

Si 28.09

15

P 30.97

16

S 32.07

17

Cl 35.45

18

Ar 39.95

19

K 39.10

20

Ca 40.08

21

Sc 44.96

22

Ti 47.87

23

V 50.94

24

Cr 52.00

25

Mn 54.94

26

Fe 55.85

27

Co 58.93

28

Ni 58.69

29

Cu 63.55

30

Zn 65.39

31

Ga 69.72

32

Ge 72.61

33

As 74.92

34

Se 78.96

35

Br 79.90

36

Kr 83.80

37

Rb 85.47

38

Sr 87.62

39

Y 88.91

40

Zr 91.22

41

Nb 92.91

42

Mo 95.94

43

Tc (98)

44

Ru 101.1

45

Rh 102.9

46

Pd 106.4

47

Ag 107.9

48

Cd 112.4

49

In 114.8

50

Sn 118.7

51

Sb 121.8

52

Te 127.6

53

I 126.9

54

Xe 131.3

55

Cs 132.9

56

Ba 137.3

57

La 138.9

72

Hf 178.5

73

Ta 180.9

74

W 183.8

75

Re 186.2

76

Os 190.2

77

Ir 192.2

78

Pt 195.1

79

Au 197.0

80

Hg 200.6

81

Tl 204.4

82

Pb 207.2

83

Bi 209.0

84

Po (209)

85

At (210)

86

Rn (222)

87

Fr (223)

88

Ra (226)

89

Ac (227)

104

Rf (261)

105

Db (262)

106

Sg (266)

107

Bh (264)

108

Hs (269)

109

Mt (268)

110

Uun (271)

111

Uuu (272)

112

Uub (277)

Periodic table adapted from: www.swansontec.com/selement.htm

Page 24: Monatomic Ions Variable and Fixed. Fixed Variable

Zn, Cd, and HgAll are 2+

Hg22+ is diatomic

Stock system name Mercury (I)-ous is less, -ic is more

1+ 1 The Periodic Table of the Elements 18

1

H 1.008

2+ 2

3+ 13 14

3- 15

2- 16

1- 17

2

He 4.003

3

Li 6.941

4

Be 9.012

Hg22+

5

B 10.81

6

C 12.01

7

N 14.01

8

O 16.00

9

F 19.00

10

Ne 20.18

11

Na 22.99

12

Mg 24.31 3 4 5 6 7 8 9 10

11

2+

12

13

Al 26.98

14

Si 28.09

15

P 30.97

16

S 32.07

17

Cl 35.45

18

Ar 39.95

19

K 39.10

20

Ca 40.08

21

Sc 44.96

22

Ti 47.87

23

V 50.94

24

Cr 52.00

25

Mn 54.94

26

Fe 55.85

27

Co 58.93

28

Ni 58.69

29

Cu 63.55

30

Zn 65.39

31

Ga 69.72

32

Ge 72.61

33

As 74.92

34

Se 78.96

35

Br 79.90

36

Kr 83.80

37

Rb 85.47

38

Sr 87.62

39

Y 88.91

40

Zr 91.22

41

Nb 92.91

42

Mo 95.94

43

Tc (98)

44

Ru 101.1

45

Rh 102.9

46

Pd 106.4

47

Ag 107.9

48

Cd 112.4

49

In 114.8

50

Sn 118.7

51

Sb 121.8

52

Te 127.6

53

I 126.9

54

Xe 131.3

55

Cs 132.9

56

Ba 137.3

57

La 138.9

72

Hf 178.5

73

Ta 180.9

74

W 183.8

75

Re 186.2

76

Os 190.2

77

Ir 192.2

78

Pt 195.1

79

Au 197.0

80

Hg 200.6

81

Tl 204.4

82

Pb 207.2

83

Bi 209.0

84

Po (209)

85

At (210)

86

Rn (222)

87

Fr (223)

88

Ra (226)

89

Ac (227)

104

Rf (261)

105

Db (262)

106

Sg (266)

107

Bh (264)

108

Hs (269)

109

Mt (268)

110

Uun (271)

111

Uuu (272)

112

Uub (277)

Periodic table adapted from: www.swansontec.com/selement.htm

Page 25: Monatomic Ions Variable and Fixed. Fixed Variable

Sn, Pb 2+ and 4+

-ous is less, –ic is moreTin and Lead are two and four.

1+ 1 The Periodic Table of the Elements 18

1

H 1.008

2+ 2

3+ 13 14

3- 15

2- 16

1- 17

2

He 4.003

3

Li 6.941

4

Be 9.012

5

B 10.81

6

C 12.01

7

N 14.01

8

O 16.00

9

F 19.00

10

Ne 20.18

11

Na 22.99

12

Mg 24.31 3 4 5 6 7 8 9 10 11 12

13

Al 26.98

14

Si 28.09

15

P 30.97

16

S 32.07

17

Cl 35.45

18

Ar 39.95

19

K 39.10

20

Ca 40.08

21

Sc 44.96

22

Ti 47.87

23

V 50.94

24

Cr 52.00

25

Mn 54.94

26

Fe 55.85

27

Co 58.93

28

Ni 58.69

29

Cu 63.55

30

Zn 65.39

31

Ga 69.72

32

Ge 72.61

33

As 74.92

34

Se 78.96

35

Br 79.90

36

Kr 83.80

37

Rb 85.47

38

Sr 87.62

39

Y 88.91

40

Zr 91.22

41

Nb 92.91

42

Mo 95.94

43

Tc (98)

44

Ru 101.1

45

Rh 102.9

46

Pd 106.4

47

Ag 107.9

48

Cd 112.4

49

In 114.8

50

Sn 118.7

51

Sb 121.8

52

Te 127.6

53

I 126.9

54

Xe 131.3

55

Cs 132.9

56

Ba 137.3

57

La 138.9

72

Hf 178.5

73

Ta 180.9

74

W 183.8

75

Re 186.2

76

Os 190.2

77

Ir 192.2

78

Pt 195.1

79

Au 197.0

80

Hg 200.6

81

Tl 204.4

82

Pb 207.2

83

Bi 209.0

84

Po (209)

85

At (210)

86

Rn (222)

87

Fr (223)

88

Ra (226)

89

Ac (227)

104

Rf (261)

105

Db (262)

106

Sg (266)

107

Bh (264)

108

Hs (269)

109

Mt (268)

110

Uun (271)

111

Uuu (272)

112

Uub (277)

2+, 4+

Periodic table adapted from: www.swansontec.com/selement.htm