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Typical Sources Groundwater Mine Wastewater Oil/Gas Produced Water Example Influent TDS 1200 - 3000 ppm SO 4 800 - 1500 ppm Ca 100 - 500 ppm Mg 100 - 300 ppm Na 0 - 250 ppm Cl 0 - 350 ppm Example Effluent TDS 500 - 1500 ppm SO 4 250 - 500 ppm Ca <50 ppm Mg <30 ppm Na 0 - 250 ppm Cl 0 - 350 ppm Typical Uses Process Water Drinking Water Irrigation Water Various Applications DESALX ® Minimum or Zero Liquid Discharge Without Saline Brines Clean TeQ Water - Tailored technologies for your water challenges Robust Contaminant Removal Clean TeQ Water’s DESALX ® builds on our CIF ® (continuous ionic filtration) technology, which automatically moves resins between vertical columns after adsorption to regenerate them and acts as a fixed bed filter for solids. DESALX ® removes multivalent cations such as calcium and magnesium in the first CIF ® stage, and then removes multivalent anions such as sulphate in the second CIF ® step. DESALX ® reduces the TSS, TDS, trace metals and hardness of the water without removing monovalent ions such as sodium and chloride, allowing water to be reused or in some cases even to drink, without producing liquid brines. Site Synergy While in many situations DESALX ® is a Reverse Osmosis alternative, saving CAPEX and OPEX and removing the brine problem, it can also compliment RO. By removing suspended solids and scale forming ions DESALX ® can be a pre-treatment for RO, reducing system cost, operating cost, and increasing the life of the membranes, and the total system recovery. A Range of Benefits ü Removes di- and tri-valent cations and anions through a complimentary process ü Efficient calcium, magnesium, and sulphate removal for brackish water ü A low volume of gypsum based sludge as the only waste stream ü No scaling/fouling issues and no blocking up, even with high suspended solids ü Very low OPEX, typically 0.4-0.8 USD/m 3 AUS Office: (+61) 3 9797 6300 | CN Office: (+86) 136 3657 4021 | www.cleanteqwater.com | [email protected] Species Unit Before Precipitation Before DESALX® After DESALX® Flow rate (m 3 /h) 83.3 83 71 pH - 6.8 4.5 6.0-9.0 Total Dissolved Solids ppm 7,400 7,400 5,848 Calcium ppm 300 300 85 Magnesium ppm 321 321 96 Sulphate ppm 1515 1515 700 Iron (soluble) ppm 1 5 0.1 Total Arsenic (soluble) ppm 0.5 0.03 0.03 Antimony (soluble) ppm 13 0.05 0.05 ZLD Potential Leaving sodium and chloride in the water prevents the production of saline brines, and instead only creates gypsum solids through lime precipitation. If lime precipitation isn’t available on site, a high-density sludge clarifier can be used for dewatering the brine, creating low hazard sludge waste (25-50% w/w). A Golden Solution Clean TeQ Water installed a 2MLD water treatment plant at a gold mine in Australia. The mine has an excess of water from dewatering underground mines, which requires treatment before being reinjected into an aquifer for storage. The feed water was high in hardness, sulphates, antimony and arsenic. The antimony and arsenic were reduced using precipitation before proceeding to DESALX ® , which produced water suitable for aquifer reinjection. At times the DESALX ® effluent will be sent to a Reverse Osmosis plant which upgrades the water for re-use without intermediate steps.

Minimum or Zero Liquid Discharge Without Saline Brines · Typical Sources Groundwater Mine Wastewater Oil/Gas Produced Water Example Influent TDS 1200 -3000 ppm SO 4 800 -1500 ppm

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Page 1: Minimum or Zero Liquid Discharge Without Saline Brines · Typical Sources Groundwater Mine Wastewater Oil/Gas Produced Water Example Influent TDS 1200 -3000 ppm SO 4 800 -1500 ppm

Typical Sources

Groundwater

Mine Wastewater

Oil/Gas Produced Water

Example Influent

TDS 1200 - 3000 ppm

SO4 800 - 1500 ppm

Ca 100 - 500 ppm

Mg 100 - 300 ppm

Na 0 - 250 ppm

Cl 0 - 350 ppm

Example Effluent

TDS 500 - 1500 ppm

SO4 250 - 500 ppm

Ca <50 ppm

Mg <30 ppm

Na 0 - 250 ppm

Cl 0 - 350 ppm

Typical Uses

Process Water

Drinking Water

Irrigation Water

Various Applications

DESALX®

Minimum or Zero Liquid Discharge Without Saline Brines

Clean TeQ Water - Tailored technologies for your water challenges

Robust Contaminant RemovalClean TeQ Water’s DESALX® builds on our CIF® (continuous ionicfiltration) technology, which automatically moves resins betweenvertical columns after adsorption to regenerate them and acts as afixed bed filter for solids. DESALX® removes multivalent cationssuch as calcium and magnesium in the first CIF® stage, and thenremoves multivalent anions such as sulphate in the second CIF®

step.

DESALX® reduces the TSS, TDS, trace metals and hardness of thewater without removing monovalent ions such as sodium andchloride, allowing water to be reused or in some cases even todrink, without producing liquid brines.

Site SynergyWhile in many situations DESALX® is a Reverse Osmosisalternative, saving CAPEX and OPEX and removing the brineproblem, it can also compliment RO. By removing suspendedsolids and scale forming ions DESALX ® can be a pre-treatmentfor RO, reducing system cost, operating cost, and increasingthe life of the membranes, and the total system recovery.

A Range of Benefitsü Removes di- and tri-valent cations and anions through a

complimentary process

ü Efficient calcium, magnesium, and sulphate removal forbrackish water

ü A low volume of gypsum based sludge as the only wastestream

ü No scaling/fouling issues and no blocking up, even withhigh suspended solids

ü Very low OPEX, typically 0.4-0.8 USD/m3

AUS Office: (+61) 3 9797 6300 | CN Office: (+86) 136 3657 4021 | www.cleanteqwater.com | [email protected]

Species Unit Before Precipitation Before DESALX® After DESALX®

Flow rate (m3/h) 83.3 83 71

pH - 6.8 4.5 6.0-9.0

Total Dissolved Solids

ppm 7,400 7,400 5,848

Calcium ppm 300 300 85

Magnesium ppm 321 321 96

Sulphate ppm 1515 1515 700

Iron (soluble) ppm 1 5 0.1

Total Arsenic (soluble)

ppm 0.5 0.03 0.03

Antimony (soluble)

ppm 13 0.05 0.05

ZLD PotentialLeaving sodium and chloride in the water prevents the productionof saline brines, and instead only creates gypsum solids throughlime precipitation. If lime precipitation isn’t available on site, ahigh-density sludge clarifier can be used for dewatering the brine,creating low hazard sludge waste (25-50% w/w).

A Golden SolutionClean TeQ Water installed a 2MLD water treatment plant at a goldmine in Australia. The mine has an excess of water from dewateringunderground mines, which requires treatment before beingreinjected into an aquifer for storage. The feed water was high inhardness, sulphates, antimony and arsenic. The antimony andarsenic were reduced using precipitation before proceeding toDESALX®, which produced water suitable for aquifer reinjection. Attimes the DESALX® effluent will be sent to a Reverse Osmosis plantwhich upgrades the water for re-use without intermediate steps.