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Benzyl alcoholSafety Data Sheetaccording to Regulation (EC) No. 453/2010

Revision date: 16/04/2012 Supersedes: 30/03/2011 Version: 2.1

16/04/2012 EN (English) 1/7

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Substance name : Benzyl alcohol

EC index no : 603-057-00-5

EC no : 202-859-9

CAS No. : 100-51-6

REACH registration No. : 01-2119492630-38-0001

Synonyms : Benzene methanol, Phenylcarbinol, a-Hydroxytoluene, Phenylmethanol,(Hydroxymethyl)benzene, a-Toluenol

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified uses

Main use category : Industrial use,Professional use,Consumer use

Use of the substance/preparation : ES1 : Manufacture of substancesES2 : Formulation of preparations (mixtures)ES3 : Industrial use of chemicalsES4 : Professional uses: Public domain (administration, education, entertainment, services,craftsmen)ES5 : Consumer uses: Private households (= general public = consumers)Most common technical function of the substance :IntermediateUse in laboratoriesSolventPhotosensitive agents and other photo-chemicalsViscosity adjustorsOdour agentsFlow improver

1.2.2. Uses advised against

No additional information available

1.3. Details of the supplier of the safety data sheet

EMERALD KALAMA CHEMICAL B.V.

Havennr. 4322 - Montrealweg 153197 KH Rotterdam-Botlek - THE NETHERLANDST +31 (0)888880500 - F +31 (0)[email protected]

1.4. Emergency telephone number

Country Official advisory body / Company Address Emergency number

THE NETHERLANDS Emerald Kalama Chemical B.V.SHEQ Dept. Emerald Kalama Chemical B.V. Rotterdam

Havennr. 4322 - Montrealweg 153197 KH Rotterdam-Botlek

Chemtell (contractMIS0007388)1-800-255-3924 (USA)+001-813-248-0585 (outsideUSA)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]

Acute Tox. 4 (Inhalation) H332Acute Tox. 4 (Oral) H302Eye Irrit. 2 H319

Full text of H-phrases: see section 16.

Classification according to Directive 67/548/EEC or 1999/45/EC

Xn; R20/22Xi; R36

Full text of R-phrases: see section 16.

Adverse physicochemical, human health and environmental effects

Harmful if swallowed.Harmful by inhalation.

Causes serious eye irritation.
mailto:[email protected]:[email protected]


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2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]

Hazard pictograms (CLP) :

GHS07

CLP Signal word : Warning

Hazard statements (CLP) : H302 - Harmful if swallowedH319 - Causes serious eye irritationH332 - Harmful if inhaled

Precautionary statements (CLP) : P102 - Keep out of reach of childrenP261 - Avoid breathing dust/fume/gas/mist/vapours/spray.P270 - Do no eat, drink or smoke when using this productP271 - Use only outdoors or in a well-ventilated areaP280 - Wear protective gloves/protective clothing/eye protection/face protection.P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing

2.3. Other hazardsOther hazards not contributing to theclassification

: Combustible. The product does not meet the PBT and vPvB classification criteria.

SECTION 3: Composition/information on ingredients

3.1. Substances

Name Product identifier % Classification according toDirective 67/548/EEC

Benzyl alcohol (CAS No.) 100-51-6(EC no) 202-859-9(EC index no) 603-057-00-5(REACH-no) 01-2119492630-38-0001

100 Xn; R20/22Xi; R36

Name Product identifier % Classification according toRegulation (EC) No.1272/2008 [CLP]

Benzyl alcohol (CAS No.) 100-51-6(EC no) 202-859-9(EC index no) 603-057-00-5(REACH-no) 01-2119492630-38-0001

100 Acute T ox. 4 (Inhalati on), H 332Acute Tox. 4 (Oral), H302Eye Irrit. 2, H319

Full text of R-, H- and EUH-phrases: see section 16.

3.2. Mixtures

Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures general : Emergency eye wash fountains and safety showers should be available in the immediate vicinityof any potential exposure.Do not attempt to take action without suitable protective equipmentMove the affected person away from the contaminated area and into the fresh air

Take off contaminated clothes.First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing

Keep victim warm and restedIf not breathing, give artificial respiration.Call a doctor immediately.

First-aid measures after skin contact : Wash with soapy waterRemove all contaminated clothing and footwearIf case of redness or irritation, call a doctor.

First-aid measures after eye contact : Rinse immediately and thoroughly, pulling the eyelids well away from the eye (15 minutesminimum)If irritation persists, consult an eye specialist.

First-aid measures after ingestion : Rinse mouth out with waterNever give anything by mouth to an unconscious person.Take medical advice immediately.

4.2. Most important symptoms and effects, both acute and delayedSymptoms/injuries after inhalation : Headache. Nausea. May cause drowsiness or dizziness. Loss of consciousness. Slightly

irritating to the respiratory system. Cough.

Symptoms/injuries after skin contact : May cause moderate irritation. Redness. Exposure may produce an allergic reaction.

Symptoms/injuries after eye contact : Eye irritation. Redness.


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Symptoms/injuries after ingestion : Nausea. Vomiting. Headache. Disturbances of consciousness.

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Dry powder Carbon dioxide (CO2)For a significant fire:Water sprayFoamDry powder.

5.2. Special hazards arising from the substance or mixture

Fire hazard : Vapours are explosive in air at temperatures higher than the flash pointDuring combustion :Toxic fumes may be released(carbon oxides (CO and CO2)).

5.3. Advice for firefighters

Firefighting instructions : Contain the extinguishing fluids by bunding.

Protection during firefighting : Do not attempt to take action without suitable protective equipmentSelf-contained breathing apparatusComplete protective clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel

Emergency procedures : Avoid contact with skin and eyesKeep away from ignition sources (including static discharges).Explosion-free electrical equipment and lighting with earthConsult an expert immediately.

6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment

For further information refer to section 8 Exposure controls/personal protection" ".

6.2. Environmental precautions

Contain the spilled material by bunding. Do not discharge into drains or rivers.

6.3. Methods and material for containment and cleaning up

For containment : Take up liquid spill into absorbent material, e.g.: sand, earth, vermiculite kieselguhr, powderedlimestonePut into a labelled container and provide safe disposal.Flame proof, lighting, electrical equipment and ventilation.No flames, No sparks. Eliminate all sources of ignition.

Methods for cleaning up : Wash non-recoverable remainder with large amounts of water.

Other information : Dispose of contaminated materials in accordance with current regulations.

6.4. Reference to other sections

For further information refer to section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Ensure good ventilation of the work stationAvoid contact with skin and eyesDo not breathe vapours.Use personal protective equipment as requiredFlame proof, lighting, electrical equipment and ventilation.Keep away from ignition sources (including static discharges).

Hygiene measures : Do not drink, eat or smoke in the workplaceAlways wash hands after handling the product.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures : Provide local exhaust or general room ventilation.Keep in fireproof place.

Storage conditions : Keep in a cool, well-ventilated place away from heatKeep under inert gasKeep container tightly closed.Keep away from incompatible materials

Avoid any contamination of the product by other substances.


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Incompatible materials : ironaluminium.

Storage temperature : -12-50 C

Packaging materials : Ordinary steelpolyethylene.

7.3. Specific end use(s)Not applicable.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Benzyl alcohol (100-51-6)

DNEL/DMEL (Workers)

Acute - systemic effects, dermal 47 mg/kg bodyweight

Acute - systemic effects, inhalation 450 mg/m

Long-term - systemic effects, dermal 9,5 mg/kg bodyweight/day

Long-term - systemic effects, inhalation 90 mg/m

DNEL/DMEL (General population)

Acute - systemic effects, dermal 29 mg/kg bodyweight

Acute - systemic effects, inhalation 40 mg/mAcute - systemic effects, oral 25 mg/kg bodyweight

Long-term - systemic effects,oral 5 mg/kg bodyweight/day

Long-term - systemic effects, inhalation 8,11 mg/m

Long-term - systemic effects, dermal 5,7 mg/kg bodyweight/day

8.2. Exposure controls

Appropriate engineering controls : Ensure good ventilation of the work stationFlame proof, lighting, electrical equipment and ventilation.

Hand protection : Butyl-rubber protective glovesVITON glovesBreakthrough time (min) : > 480Incompatible materials :Nitrile-rubber protective glovesneoprene/natural rubber

Protective gloves made of latex.

Eye protection : Safety spectacles with side shields.

Skin and body protection : Protective clothing.

Respiratory protection : Gas mask with filter type A.

Environmental exposure controls : Take all necessary precautions to avoid the accidental release of the product outside, due to therupture of containers or transfer systems.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Liquid

Colour : Colourless.

Odour : Mildly aromatic.

Odour threshold : Not established.

pH : No data available

Melting point : -15,4 C (1013 hPa) (Handbook)

Boiling point : 205,3 C (1013 hPa) (Handbook)

Flash point : 100,4 C (1013 hPa) (Handbook)

Relat. evapor. rate comp. to butylacetate : No data available

Flammability (solid, gas) : Non f lammable. (expert statement)

Explosive limits : LEL 1,3% / UEL 13%

Vapour pressure : 22,26 Pa (25 C) (Handbook)

Relative vapour density at 20 C : No data available

Relative density : 1,045 (20 C) (Handbook)

Solubility : Material highly soluble in water. (> 1000 mg/l).Water: 40 g/l (25 C) (Handbook)

Log Pow : 1,05 (25 C) (Handbook)

Self ignition temperature : 436 C (1013 hPa) (Handbook)

Decomposition temperature : No data available

Viscosity, kinematic : No data available


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Viscosity, dynamic : 5,84 mPa.s (25 C)

Explosive properties : LEL 1,3% / UEL 13%

Oxidising properties : Not applicable. (expert statement).

9.2. Other information

Other properties : Surface tension : 39 mN/m (20 C) (1 g/l) (OECD 115, EC A.5).

SECTION 10: Stability and reactivity

10.1. Reactivity

To our knowledge, the product does not present any particular risk.

10.2. Chemical stability

Stable at ambient temperature and under normal conditions of use.

10.3. Possibility of hazardous reactions

Air contact may form hazardous compounds. :Benzaldehyde.

10.4. Conditions to avoid

No flames, No sparks. Eliminate all sources of ignitionAir sensitive.

10.5. Incompatible materials

Air.AcidsOxidizing materialsaluminiumIronSynthetic material.

10.6. Hazardous decomposition products

on contact with air. :Benzaldehyde.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Harmful if inhaled. Harmful if swallowed.


LD50 oral rat 1620 mg/kg

LD50 dermal rabbit No data available

LC50 inhalation rat > 4178 mg/m (OECD 403)

Skin corrosion/irritation : Not classified (OECD 404)

Serious eye damage/irritation : Causes serious eye irritation. (OECD 405)

Respiratory or skin sensitisation : Not classified (OECD 406)

Germ cell mutagenicity : Not classified (Based on available data, the classification criteria are not met)

Carcinogenicity : Not classified (Based on available dat a, the classif ication criteria are not met )

Reproductive toxicity : Not classified (Based on available data, the classification criteria are not met)

Specific target organ toxicity (single exposure) : Not classified (Based on available data, the classification criteria are not met)

Specific target organ toxicity (repeatedexposure)

: Not classified (Based on available data, the classification criteria are not met)

Aspiration hazard : Not classified (Based on available data, the classification criteria are not met)

SECTION 12: Ecological information

12.1. Toxicity


LC50 fish 460 mg/l/96h (OECD 203)

EC50 Daphnia 230 mg/l/48h (Daphnia magna) (OECD 202)

EC50 other aquatic organisms 390 mg/l/24h (inhibition of microbial activity)(ISO 8192 / ISO DIS 9509)

NOEC (chronic) 51 mg/l/ 21 d (Daphnia magna) (OECD 211)

ErC50 (algae) 770 mg/l/72h (OECD 201)

12.2. Persistence and degradability


Persistence and degradability Readily biodegradable (OECD 301C & 301A).


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12.3. Bioaccumulative potential


Log Pow 1,05 (25 C) (Handbook)

12.4. Mobility in soil


Mobility in soil No data available

12.5. Results of PBT and vPvB assessment


Results of PBT assessment The product does not meet the PBT and vPvB classification criteria

12.6. Other adverse effects


SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste treatment methods : Dispose of in accordance with relevant local regulations.

SECTION 14: Transport information

In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA

14.1. UN number

UN-No. : 9003 (ADNR)

14.2. UN proper shipping name

Transport document description : UN 9003 (ADNR)

14.3. Transport hazard class(es)

Class (ADNR) : 9 - Miscellaneous dangerous substances and articles

14.4. Packing group

Packing group (UN) : Not applicable

14.5. Environmental hazards

Other information : No supplementary information available.

14.6. Special precautions for user

14.6.1. Overland transport


14.6.2. Transport by sea


14.6.3. Air transport


14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

Not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-Regulations


15.1.2. National regulations


15.2. Chemical safety assessment

A chemical safety assessment has been carried out.

SECTION 16: Other information

Data sources : CSR (Chemical safety report).

Full text of R-, H- and EUH-phrases:

------ Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4

------ Acute Tox. 4 (Oral) Acute toxicity (Oral) Category 4

------ Eye Irri t. 2 Serious Eye Damage/Irritation Category 2


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------ H302 Harmful if swallowed

------ H319 Causes serious eye irritation

------ H332 Harmful if inhaled

------ R20/22 Harmful by inhalation and if swallowed.

------ R36 Irritating to eyes.

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore beconstrued as guaranteeing any specific property of the product.


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ANNEX TO THE SAFETY DATA SHEET

Benzyl alcohol SDS ReferenceSubstance

Exposure scenario 1 Version 1Explanation ofacronyms

SU: Sector of use

PROC: Process category

ERC: Environmental release category

PPE: Personal protection equipment

PC: Product category

Page1 of 4

1 Exposure scenario (1)

Manufacture of substances : Benzyl alcohol

Use descriptors related to the life cyclestage

SU8/9

PROC1/2/3/8b/9

ERC1

Name of contributing environmental scenario(1) and corresponding ERC

1. Manufacture of substances (ERC1)

List of names of contributing workerscenarios (2) and corresponding PROC

1. Use in closed process, no likelihood of exposure (PROC1)

2. Use in closed, continuous process with occasionalcontrolled exposure (PROC2)

3. Use in closed batch process (synthesis or formulation)(PROC3)

4. Transfer of substance or preparation(charging/discharging) from/to vessels/large containers atdedicated facilities (PROC8b)

5. Transfer of substance or preparation into small containers(dedicated filling line, including weighing) (PROC9)

2.1 Contributing scenario (1) controlling environmental exposure

Product characteristic Liquid, 100 % substance in the product

Amounts used Number of sites : 1,8250 t/ year

Emission per site : 300 days/year

Frequency and duration of use Continuous

300 days/year

Environmental factors not influenced by riskmanagement

Dilution factor for surface water : 10 (by default)

(Coastal zone : 100)

Other given operational conditions affectingenvironment exposure

There is practically no disposal or run-off into soil, wastewater,

drains and sewers

Technical conditions and measures atprocess level (source) to prevent release

Local exhaust ventilation

(Efficiency > 99.9 %)

Practically no release to waste water and soil

Technical onsite conditions and measures toreduce or limit discharges, air emissions and

releases to soil

Store in original container.

Keep container tightly closed.

Store in dry, cool, well-ventilated area.Protect from sunlight

Use only organic solvents for cleaning the equipment

Wet scrubber are used to minimize the emission to air

(Efficiency >98 %)

Small spillages:

Soak up small spill with inert solids.

Use suitable disposal containers.

Wash contaminated area with large amounts of water

Significant spillages:

Prevent liquid from entering sewers, watercourses,

underground or low areas

Take up liquid spill into inert absorbent material, e.g.:sand/earth

Recycle or dispose of in compliance with current legislation


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SU: Sector of use





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Explosion-free electrical equipment and lighting with earth

Remove ignition sources.

Organizational measures to prevent/limitrelease from site

All personnel are trained

Conditions and measures related tomunicipal sewage treatment plant

Size of the STP : 2000 m/day (by default)

No release to the sewage treatment plant during manufacturing

Conditions and measures related to externaltreatment of waste for disposal

All waste and organic cleaning solutions are disposed of

by incineration

Conditions and measures related to externalrecovery of waste

Not applicable

2.2 Contributing scenario (2) controlling worker exposure

All Process Categories are covered by this contributing scenario as all Operational Conditions (OCs) and RiskManagement Measures (RMMs) are identical.

PROC1/2/3/8b/9

Product characteristic

Product related conditions, e.g. the concentrationof the substance in a mixture, the physical stateof that mixture (solid, liquid; if solid: level ofdustiness), package design affecting exposure:

Liquid, 100 % substance in the product

Amounts used

Amounts used at a workplace (per task or per

shift); note: sometimes this information is notneeded for assessment of workers exposure

65 t/ days


Frequency and duration of use/exposure

Duration per task/activity (e.g. hours per shift) andfrequency (e.g. single events or repeated) ofexposure

8 hours per day230 days/year

Human factors not influenced by risk management

Particular conditions of use, e.g. body partspotentially exposed as a result of the nature of theactivity :

Body weight : 70 kgRespiration volume : 10 m / 8h per day (light activity)

Other given operational conditions affecting workers exposure

Other given operational conditions: e.g.technology or process techniques determining theinitial release of substance from process intoworkers environment; room volume, whether thework is carried out outdoors/indoors, processconditions related to temperature and pressure:

Wear recommended personal protective equipment.All personnel are trained

Technical conditions and measures at process level (source) to prevent release

Process design aiming to prevent releases andhence exposure of workers; this in particularincludes conditions ensuring rigorouscontainment; performance of containment to bespecified (e.g. by quantification of residual lossesor exposure)


Technical conditions and measures to control dispersion from source towards the workerEngineering controls, e.g. exhaust ventilation, Direct contact with the substance can be practically


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SU: Sector of use





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general ventilation; specify effectiveness ofmeasure :

excluded as the substance is produced in closed systemsand appropriate protective measures are in place


Wear recommended personal protective equipment.

Organisational measures to prevent /limit releases, dispersion and exposure

Specific organisational measures or measuresneeded to support the functioning of particulartechnical measures (e.g. training andsupervision). Those measures need to bereported in particular for demonstrating strictlycontrolled conditions (to justify exposure basedwaiving) :

Store in a dry area (-12.2C / 50 C)

Conditions and measures related to personal protection, hygiene and health evaluation

Personal protection, e.g. wearing of gloves, faceprotection, full body dermal protection, goggles,respirator; specify effectiveness of measure;specify the suitable material for the PPE (whererelevant) and advise how long the protectiveequipment can be used before replacement (ifrelevant) :

Wear recommended personal protective equipment. :Gas mask with filter type AButyl-rubber protective glovesVITON glovesSafety spectacles with side shieldsProtective clothingDo not eat, drink or smoke when using this product

All personnel are trainedAlways wash hands after handling the productEmergency eye wash fountains and safety showers shouldbe available in the immediate vicinity of any potentialexposure.

3 Exposure information and reference to its source

Information for contributing scenario 1

Environmental exposure has been calculated using EUSES v2.1

Exposure estimation PNEC

Fresh water 0,0048 mg/l 1 mg/l

Marine water 0,000461 mg/l 0,1 mg/l

Sediment (freshwater) 0,0248 mg/kg 5,27 mg/kg dwt

Sediment (marine water) 0,00238 mg/kg 0,527 mg/kg dwt

Soil. 0,0534 mg/kg 0,456 mg/kg dwt

STP 0 mg/l 39 mg/l


Workers exposure estimation has been calculated using ECETOC TRA

Only highest figures are presented here for the contributing scenarios for human health

For all calculations, please refer to the CSR

Workers exposure Exposure estimation DNEL

Long-term - systemic effects,dermal

0,686 mg/kg bw/day 9,5 mg/kg bodyweight/day

Long-term - systemic effects,inhalation

2,25 mg/m 90 mg/m/day

Long-term- systemic effects,combined routes

1,01 mg/kg bw/day 9.5 mg/kg bw/day


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4 Guidance to DU to evaluate whether he works inside the boundaries set by the ES

Local exhaust ventilationNo gloves or respiratory protection are required


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Formulation of preparations (mixtures)

Use descriptors related tothe life cycle stage

SU10

PC0/1/3/8/9a/9b/9c/14/15/18/19/20/21/23/24/26/27/28/29/30/31/32/34/35/39

PROC1/2/3/4/5/8a/8b/9/19

ERC2/3

Name of contributingenvironmental scenario (1)and corresponding ERC

1. Formulation of preparations (ERC2)

2. Formulation in materials (ERC3)

List of names ofcontributing workerscenarios (2) andcorresponding PROC

1. Use in closed process, no likelihood of exposure (PROC1)

2. Use in closed, continuous process with occasional controlled exposure(PROC2)

3. Use in closed batch process (synthesis or formulation) (PROC3)

4. Use in batch and other process (synthesis) where opportunity for exposurearises (PROC4)

5. Mixing or blending in batch processes for formulation of preparations* andarticles (multistage and/or significant contact) (PROC5)

6. Transfer of substance or preparation (charging/discharging) from/tovessels/large containers at non-dedicated facilities (PROC8a)

7. Transfer of substance or preparation (charging/discharging) from/tovessels/large containers at dedicated facilities (PROC8b)

8. Transfer of substance or preparation into small containers (dedicated fillingline, including weighing) (PROC9)

9. Hand-mixing with intimate contact and only PPE available (PROC19)


Formulation of preparations (ERC2)Formulation in materials (ERC3)

Product characteristic Liquid, 100 % substance in the product

Amounts used Number of sites : > 1

Annual amount used in region : 10%

Annual amount used per site : 5250 t (ERC2) - 3010 t (ERC3)

Emission per site : 300 days/year (ERC2) - 100 days/year (ERC3)

Frequency and duration ofuse

Continuous

300 days/year (ERC2) - 100 days/year (ERC3)

Environmental factors notinfluenced by riskmanagement



Other given operationalconditions affectingenvironment exposure

There is practically no disposal or run-off into soil, wastewater, drains and sewers

Technical conditions andmeasures at process level(source) to preventrelease




Technical onsite

conditions and measuresto reduce or limit



Store in dry, cool, well-ventilated area.


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discharges, air emissionsand releases to soil

Protect from sunlight


Organizational measuresto prevent/limit releasefrom site


Conditions and measuresrelated to municipalsewage treatment plant


Conditions and measuresrelated to externaltreatment of waste fordisposal

All waste and organic cleaning solutions are disposed of by incineration.

Conditions and measuresrelated to externalrecovery of waste

Not applicable


Formulation of preparations (mixtures)

All Process Categories are covered by this contributing scenario as all Operational Conditions (OCs) and RiskManagement Measures (RMMs) are identical.

PROC1/2/3/4/5/8a/8b/9/19


Product related conditions, e.g.the concentration of thesubstance in a mixture, thephysical state of that mixture(solid, liquid; if solid: level ofdustiness), package designaffecting exposure:

Liquid, 100 % substance in the product

Amounts used

Amounts used at a workplace(per task or per shift); note:sometimes this information isnot needed for assessment ofworkers exposure

0.8 t/ days


Frequency and duration of use/exposure

Duration per task/activity (e.g.hours per shift) and frequency(e.g. single events or repeated)of exposure

8 hours per day230 days/year

Human factors not influenced by risk management

Particular conditions of use, e.g.body parts potentially exposedas a result of the nature of theactivity :

Body weight : 70 kgRespiration volume : 10 m / 8h per day (light activity)


Other given operational

conditions: e.g. technology orprocess techniques determiningthe initial release of substance




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from process into workersenvironment; room volume,whether the work is carried outoutdoors/indoors, processconditions related totemperature and pressure:


Process design aiming toprevent releases and henceexposure of workers; this inparticular includes conditionsensuring rigorous containment;

performance of containment tobe specified (e.g. byquantification of residual lossesor exposure)

Substance release can be practically excluded. Formulation occurs

to a large extent in closed systems.


No waste water is produced

The incidental waste is collected in suitable containers and stored until

disposal

Technical conditions and measures to control dispersion from source towards the worker

Engineering controls, e.g.exhaust ventilation, generalventilation; specify effectivenessof measure :

Direct contact with the substance can be practically excluded as thesubstance is produced in closed systems and appropriate protectivemeasures are in place



Specific organisational

measures or measures neededto support the functioning ofparticular technical measures(e.g. training and supervision).Those measures need to bereported in particular fordemonstrating strictly controlledconditions (to justify exposurebased waiving) :

Store in a dry area (-12.2 C / 50 C)


Personal protection, e.g.wearing of gloves, faceprotection, full body dermalprotection, goggles, respirator;

specify effectiveness ofmeasure; specify the suitablematerial for the PPE (whererelevant) and advise how longthe protective equipment can beused before replacement (ifrelevant) :

Breathing apparatusProtective glovesChemical gogglesProtective clothing

Do not eat, drink or smoke when using this productAlways wash hands after handling the productEmergency eye wash fountains and safety showers should be available inthe immediate vicinity of any potential exposure.

All personnel are trained.




Exposure estimation PNEC

Fresh water 0,226 mg/l (ERC2)

0,0428 mg/l (ERC3)

1 mg/l


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Marine water 0,0226 mg/l (ERC2)

4,26E-03 mg/l (ERC3)

0,1 mg/l

Sediment (freshwater) 1,17 mg/kg (ERC2)

0,221 mg/l (ERC3)

5,27 mg/kg dwt

Sediment (marine water) 0,117 mg/kg (ERC2)

0,022 mg/l (ERC3)

0,527 mg/kg dwt

Soil. 0,0767 mg/kg (ERC2)

0,0264 mg/l (ERC3)

0,456 mg/kg dwt

STP 2,21 mg/l (ERC2)

0,38 mg/l (ERC3)

39 mg/l



Only highest figures are presented here for the contributing scenarios for human health

For all calculations, please refer to the CSR

Workers exposure Exposure estimation DNEL

Long-term - systemiceffects, dermal

1,41 mg/kg bodyweight/day (Industrial use)

1,41 mg/kg bodyweight/day (Professionaluse.)

9,5 mg/kg bodyweight/day

Long-term - systemic

effects, inhalation

4,51 mg/m (Industrial use)

22,5 mg/m (Professional use.)

90 mg/m

Long-term - systemiceffects, combinedroutes

2,05 mg/kg bodyweight/day (Industrial use)4,62 mg/kg bodyweight/day (Professionaluse.)

9,5 mg/kg bodyweight/day


Local exhaust ventilationHand-mixing with intimate contact and only PPE available (PROC19) : Wear gloves (Efficiency : 90%)


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Page1 of 4


Industrial use of chemicals


SU3

PC 0 (PROC 5/7/8a/8b/9/10/13/14/15/19) - spERC ESVOC 3(ERC4); spERC EFCC 4 (ERC4)PC 1 (PROC 5/7/8a/8b/9/10/12/13/14) - spERC ESVOC 5(ERC4)PC 9a/b/c (PROC 5/7/8a/8b/9/10/13) - spERC ESVOC 5(ERC4)PC 14 (PROC 5/8a/8b/9/15/23/24/25) - spERC ESVOC 5(ERC4)

PC 15 (PROC 5/8a/8b/9/15) - spERC ESVOC 5 (ERC4)PC 18 (PROC 7/8a/8b/9/10/13) - spERC ESVOC 5 (ERC4)PC 19 (PROC 1/2/3) - ERC6aPC 24 (PROC 18) - ERC7PC 26 (PROC 5/6/7/8b/10/13/14) - ERC4PC 30 (PROC 8a/8b) - ERC4PC 32 (PROC 13) - ERC4PC 34 (PROC 5/6/7/8a/8b/9/10/13/14) - spERC TEGEWA6(ERC4)PC 35 (PROC 7/8a/8b/9/10/13) - spERC ESVOC 8 (ERC4, 6a)

Name of contributing environmentalscenario (1) and corresponding ERC

Industrial use of processing aids in processes and products, not

becoming part of articles (ERC4)

Industrial use of reactive processing aids (ERC6b)


For the signification of the codes used, see the ECHA guidancechapter R.12 "Use descriptor system"


Industrial use of processing aids in processes and products, not becoming part of articles (ERC4)Industrial use of reactive processing aids (ERC6b)

Product characteristic Liquid 1


PC26 (ERC4) : 5t

PC30 (ERC4) : 50t

PC32 (ERC4) : 5t

PC0 (spERC ESVOC 3) (ERC4) : 5t

PC1,9a,9b,9c,14,15,18 (spERC ESVOC 5) (ERC4) : 510t

PC35 (spERC ESVOC 8) (ERC4) : 100t

PC0 (spERC EFCC 4) (ERC4) : 3000t

PC34 (spERC TEGEWA 6) (ERC4): 5t

PC19 (ERC6a) : 300t

PC35 (spERC ESVOC 8) (ERC6b) : 100t

PC24 (ERC7) : 5t


PC26 (ERC4) : 1 days/year




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Page2 of 4

spERC ESVOC 3 (ERC4) : 300 days/year



spERC EFCC 4) (ERC4) : 220 days/year

spERC TEGEWA 6 (ERC4): 220days/year

ERC6a : 20 days/year

spERC ESVOC 8 (ERC6b) : 20 days/year

ERC7 : 20 days/year

Environmental factors not influenced by riskmanagement



Other given operational conditions affectingenvironment exposure

Avoid release to the environment





Technical onsite conditions and measures toreduce or limit discharges, air emissions andreleases to soil


Store in dry, cool, well-ventilated area.

Protect from sunlight




Conditions and measures related to

municipal sewage treatment plant



Dispose of in accordance with relevant local regulations


Not applicable



Product related conditions, e.g. the concentrationof the substance in a mixture, the physical state ofthat mixture (solid, liquid; if solid: level ofdustiness), package design affecting exposure:

SolidLiquid


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Page3 of 4

activity :


Other given operational conditions: e.g.technology or process techniques determining theinitial release of substance from process intoworkers environment; room volume, whether thework is carried out outdoors/indoors, processconditions related to temperature and pressure:

Wear recommended personal protective equipment.All personnel are trained


Process design aiming to prevent releases andhence exposure of workers; this in particular

includes conditions ensuring rigorouscontainment; performance of containment to bespecified (e.g. by quantification of residual lossesor exposure)

Not applicable

Technical conditions and measures to control dispersion from source towards the worker

Engineering controls, e.g. exhaust ventilation,general ventilation; specify effectiveness ofmeasure :

Not applicable


Specific organisational measures or measuresneeded to support the functioning of particulartechnical measures (e.g. training andsupervision). Those measures need to be

reported in particular for demonstrating strictlycontrolled conditions (to justify exposure basedwaiving) :




Breathing apparatusProtective glovesChemical gogglesProtective clothingDo not eat, drink or smoke when using this product

Always wash hands after handling the productEmergency eye wash fountains and safety showersshould be available in the immediate vicinity of anypotential exposure.





See documents in appendix nr II





Industrial. :


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Page4 of 4

Local exhaust ventilationIndustrial spraying (PROC7) : During spraying wear suitable respiratory equipment (Efficiency : 95%)Professional use (PROC23abc, 24abc, 25abc) :Solid (For a substance content : 100%) :Local exhaust ventilationNo gloves or respiratory protection are required


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Page1 of 4


Professional use


SU22

PC 0 (PROC 5/8a/8b/9/10/11/13/19) - ERC8a/8dPC 1 (PROC 5/8a/8b/9/10/11/13/19) - ERC8a/8dPC 9a/9b9/c (PROC 5/8a/8b/9/10/11/13/19) - ERC8a/8dPC 14 (PROC 8a/8b/9/10/11/13/19/23/24/25) - ERC8a/8dPC 15 (PROC 8a/8b/9/10/11/13/19) - ERC8a/8dPC 18 (PROC 5/8a/8b/10/11/13/19) - ERC8a/8dPC 21 (PROC 8a/8b/15) - ERC8a/8dPC 26 (PROC 5/6/8a/8b/11/13/14/19/21) - ERC8a/8d

PC 30 (PROC 8a/8b) - ERC8a/8dPC 31 (PROC 8b/10/11) - ERC8a/8dPC 32 (PROC 8a/8b/9/10/11) - ERC48a/8dPC 35 (PROC 8a/8b/9/10/11/13/19) - ERC8a/8b/8d/8e


1. Wide dispersive indoor use of processing aids in open

systems (ERC8a)

2. Wide dispersive indoor use of reactive substances in open

systems (ERC8b)

3. Wide dispersive outdoor use of processing aids in open

systems (ERC8d)

4. Wide dispersive outdoor use of reactive substances in open

systems (ERC8e)


For the signification of the codes used, see the ECHA guidancechapter R.12 "Use descriptor system"


Wide dispersive indoor use of processing aids in open systems (ERC8a)Wide dispersive indoor use of reactive substances in open systems (ERC8b)Wide dispersive outdoor use of processing aids in open systems (ERC8d)Wide dispersive outdoor use of reactive substances in open systems (ERC8e)

Product characteristic 1


ERC8a PC0,1,9a,9b,9c,14,15,18,21,26,30,31,32,34,35 : 3685t

ERC8b PC35 : 155tERC8d PC0,1,9a,9b,9c,14,15,18,21,26,31,32,34,35 : 3625t

ERC8e PC35 : 100t

Fraction of the main local source : 0.002



365 days/year

Environmental factors not influenced byrisk management



Other given operational conditionsaffecting environment exposure

Not applicable


Keep container closed when not in use

Dispose of contaminated materials in accordance with current

regulations


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Page2 of 4

Technical onsite conditions and measuresto reduce or limit discharges, airemissions and releases to soil


Avoid release to the environment





Conditions and measures related toexternal treatment of waste for disposal


Conditions and measures related toexternal recovery of waste

Not applicable

2.2 2.2 Contributing scenario (2) controlling worker exposure


Product related conditions, e.g. theconcentration of the substance in a mixture, thephysical state of that mixture (solid, liquid; ifsolid: level of dustiness), package designaffecting exposure:


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Page3 of 4

general ventilation; specify effectiveness ofmeasure :


Specific organisational measures or measuresneeded to support the functioning of particulartechnical measures (e.g. training andsupervision). Those measures need to bereported in particular for demonstrating strictlycontrolled conditions (to justify exposure basedwaiving) :



Personal protection, e.g. wearing of gloves,face protection, full body dermal protection,goggles, respirator; specify effectiveness ofmeasure; specify the suitable material for thePPE (where relevant) and advise how long theprotective equipment can be used beforereplacement (if relevant) :

Breathing apparatusProtective glovesChemical gogglesProtective clothingDo not eat, drink or smoke when using this product

Always wash hands after handling the productEmergency eye wash fountains and safety showers shouldbe available in the immediate vicinity of any potentialexposure.










For a substance content < 5 %No local exhaust ventilationNon industrial spraying (PROC11) :During spraying wear suitable respiratory equipment.

(Efficiency : 95%)Hand-mixing with intimate contact and only PPE available (PROC19) :Wear gloves.(Efficiency 90%)For a substance content >=5% - < 25% :No local exhaust ventilation(Exception : roller application or brushing indoors (PROC10) only in the presence of LEV for a work duration of8 hours)Gloves (90 % efficiency) indoors and outdoorsNon industrial spraying (PROC11) :During spraying wear suitable respiratory equipment.(Efficiency 95%)Maximum duration of 1 hour(s) for mixing/loading operations in non-dedicated facilities (PROC8a) and handmixing (PROC19)

For a substance content >= 25 % :No local exhaust ventilation(Exception : roller application or brushing indoors (PROC10) only in the presence of LEV for a work duration of


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Page4 of 4

8 hours)Gloves (90 % efficiency) indoors and outdoorsNon industrial spraying (PROC11) :During spraying wear suitable respiratory equipment.(Efficiency : 95 %)Maximum duration of 1 hour(s) for mixing/loading operations in non-dedicated facilities (PROC8a) and handmixing (PROC19)Maximum duration of 4 hour(s) for roller application or brushing outdoors (PROC10)Solid (100%) :No LEV and no gloves required (PROC21/23abc/24abc/25abc)


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Page1 of 3


Consumer use


SU21

PC 0,1,9a,9b,9c,18,31,34 (ERC8a/8d) - PC 35(ERC8a/8b/8d/8e)


1. Wide dispersive indoor use of processing aids in open

systems (ERC8a)

2. Wide dispersive indoor use of reactive substances in open

systems (ERC8b)

3. Wide dispersive outdoor use of processing aids in open

systems (ERC8d)4. Wide dispersive outdoor use of reactive substances in open

systems (ERC8e)

List of names of contributing consumerscenarios (2) and corresponding PC andsub-product categories if applicable

1. Other use : Building, construction (equalizers (powders),insulation foam (spray can)) (PC0)

2. Adhesives, sealants (PC1)

3. Coatings and paints, thinners, paint removers (PC9a)

4. Fillers, putties, plasters, modelling clay (PC9b)

5. Finger paints (PC9c)

6. Ink and toners (PC18)

7. Polishes and wax blends (PC31)

8. Textile dyes, finishing and impregnating products; includingbleaches and other processing aids (PC34)

9. Washing and cleaning products (including solvent basedproducts) (PC35)


Wide dispersive indoor use of processing aids in open systems (ERC8a)Wide dispersive indoor use of reactive substances in open systems (ERC8b)Wide dispersive outdoor use of processing aids in open systems (ERC8d)Wide dispersive outdoor use of reactive substances in open systems (ERC8e)

Product characteristic PasteLiquid


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Page2 of 3

environment exposure






None

2.2 Contributing scenario (2) consumer end-use


Product related conditions, e.g. theconcentration of the substance in a mixture,the physical state of that mixture (solid, liquid;if solid: level of dustiness), package designaffecting exposure:

- PC0: covered by PC1, PC9a (up to 25%) and PC9b (up to5%)- PC1:


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Page3 of 3

Safety advice to be communicated toconsumers in order to control exposure, e.g.technical instruction, behavioral advice

Refer to the MSDS before handling or disposing.



None






Consumers exposure estimation has been calculated using ConsExpo 4.1



Acute Consumer Exposure Scenarios:

All acute consumer exposure scenarios are safe with the exception of the wood parquet applicationscenario when using a concentration of 25% BzOH (i.e. RCR < 1 after comparison of the acuteexposure estimates obtained in ConsExpo with the acute/short-term DNELs for BzOH)

Chronic Consumer Exposure Scenarios:

All chronic consumer exposure scenarios are safe with (i.e. RCR < 1 after comparison of the chronicexposure estimates obtained in ConsExpos with the long-term DNELs for BzOH)


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SAFETY DATA SHEETIn accordance with Regulation (EC) 1907/2006 (REACH), Annex II

BENZYL ALCOHOL

Created on November 30, 2010Revised on March 30, 2011

Page 1 of 43

ANNEX IIExposure scenario 3 Industrial usesPC0

WorkersRoute Exposure

concentrations

Leading toxic

end point /

Critical effect

DNEL

Dermal 5.64 mg/kg bw/d Repeated dosetoxicity

9.5 mg/kg bw/d

Inhalation 4.51 mg/m3

Repeated dose

toxicity

90 mg/m3

Long-term -

systemic

effects

Combined

routes

6.29 mg/kg bw/d Repeated dosetoxicity

9.5 mg/kg bw/d

Please note that in the table above the highest exposure values obtained for dermal, inhalation and combined exposure, as

calculated by use of ECETOC TRA for BzOH concentrations of up to 40%, are presented. These exposure values were not

necessarily obtained in the same PROC.

EnvironmentCompartments PEC PNEC PEC/PNEC

ERC4 spERC ESVOC3

Freshwater

4.8E-03 mg/l 1.02 mg/l 4.7E-03

Marine water 4.61E-04 mg/l 0.102 mg/l 4.52E-03

Freshwater sediments 0.0248 mg/kg 5.27 mg/kg 4.7E-03

Marine sediments 2.38E-03 mg/kg 0.527 mg/kg 4.52E-03

spERC EFCC4

Freshwater 4.8E-03 mg/l 1.02 mg/l 4.7E-03

Marine water 4.61E-04 mg/l 0.102 mg/l 4.52E-03

Freshwater sediments 0.0248 mg/kg 5.27 mg/kg 4.7E-03

Marine sediments 2.38E-03 mg/kg 0.527 mg/kg 4.52E-03

Compartments PEC PNEC PEC/PNEC

ERC4 spERC ESVOC3

Agricultural soil

(30 days)2.95E-03 mg/kg 0.456 mg/kg 6.46E-03

Grassland 2.95E-03 mg/kg 0.456 mg/kg 6.46E-03

spERC EFCC4

Agricultural soil

(30 days)0.0391 mg/kg 0.456 mg/kg 0.0857

Grassland 0.0619 mg/kg 0.456 mg/kg 0.1357

Compartments PEC PNEC PEC/PNEC

ERC4 spERC ESVOC3


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BENZYL ALCOHOL


Page 2 of 43

STP 1.05E-06 mg/l 39 mg/l 2.7E-08

spERC EFCC4

STP 0 mg/l 39 mg/l 0

Exposure scenario 4 Professional usesPC0


concentrations

Leading toxic

end point /

Critical effect

DNEL


9.5 mg/kg bw/d


Repeated dosetoxicity

90 mg/m3

Long-term -systemic

effects

Combined

routes

7.49 mg/kg bw/d Repeated dosetoxicity

9.5 mg/kg bw/d


calculated by use of ECETOC TRA for BzOH concentration of 40%, are presented. These exposure values were not necessarily

obtained in the same PROC.

EnvironmentCompartments PEC PNEC PEC/PNEC Discussion

ERC8a*

Freshwater 0.0176 mg/l 1.02 mg/l 0.0172 --

Marine water 1.74E-03 mg/l 0.102 mg/l 0.017 --

Freshwater sediments 0.0908 mg/kg 5.27 mg/kg 0.0172 --

Marine sediments 8.98E-03 mg/kg 0.527 mg/kg 0.017 --

ERC8d**





The ERCs were calculated with the total tonnage of the following product categories and the RCR therefore represents the worst

case:

* PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35

** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35

Compartments PEC PNEC PEC/PNEC Discussion

ERC8a*

Agricultural soil

(30 days)7.11E-03 mg/kg 0.456 mg/kg 0.0156 --

Grassland 3.33E-03 mg/kg 0.456 mg/kg 0.0073 --

ERC8d**Agricultural soil 7.04E-03 mg/kg 0.456 mg/kg 0.0154 --


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BENZYL ALCOHOL


Page 3 of 43

(30 days)



case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35


ERC8a*

STP 0.128 mg/l 39 mg/l 3.28E-03 --

ERC8d**

STP 0.126 mg/l 39 mg/l 3.23E-03 --


case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35

Exposure scenario 5 Consumer usesPC0


ERC8a*





ERC8d**






case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35


ERC8a*

Agricultural soil

(30 days)7.11E-03 mg/kg 0.456 mg/kg 0.0156 --


ERC8d**

Agricultural soil

(30 days)7.04E-03 mg/kg 0.456 mg/kg 6.46E-03 --



case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35



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BENZYL ALCOHOL


Page 4 of 43

ERC8a*

STP 0.128 mg/l 39 mg/l 3.28E-03 --

ERC8d**

STP 0.126 mg/l 39 mg/l 3.23E-03 --


case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35

Exposure scenario 3 Industrial usesPC1


concentrations

Leading toxic

end point /

Critical effect

DNEL Risk

characterisatio

n ratioDermal 0.856 mg/kg bw/d Repeated dose

toxicity9.5 mg/kg bw/d 9.01x10

-2


Repeated dosetoxicity

90 mg/m3

5.01x10-2

Long-term -

systemic

effects

Combined

routes

1.19 mg/kg bw/day Repeated dosetoxicity

9.5 mg/kg bw/d 0.125





ERC4 - spERC ESVOC5*




Marine sediments 0.0135 mg/kg 0.527 mg/kg 0.0256 --

*This spERC was calculated with the total tonnage of the following product categories: PC1, PC9a, b, c, 14, 15, and 18 andtherefore represents the worst case.



Agricultural soil

(30 days)0.0106 mg/kg 0.456 mg/kg 0.0232 --


*This spERC was calculated with the total tonnage of the following product categories: PC1, PC9a, b, c, 14, 15, and 18 and

therefore represents the worst case.



STP 0.215 mg/l 39 mg/l 5.5E-03 --


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BENZYL ALCOHOL


Page 5 of 43

*This spERC was calculated with the total tonnage of the following product categories: PC1, PC9a, b, c, 14, 15, and 18 and


Exposure scenario 4 Professional usesPC1

Workers

Route Exposure

concentrations

Leading toxic

end point /

Critical effect

DNEL Risk

characterisatio

n ratio


9.5 mg/kg bw/d 0.451


Repeated dose

toxicity

90 mg/m3

0.526

Long-term -systemic

effects

Combined

routes

7.49 mg/kg bw/d Repeated dose

toxicity

9.5 mg/kg bw/d 0.788





ERC8a*





ERC8d**






case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35


ERC8a*

Agricultural soil

(30 days)7.11E-03 mg/kg 0.456 mg/kg 0.0156 --


ERC8d**

Agricultural soil

(30 days)

7.04E-03 mg/kg 0.456 mg/kg 0.0154 --



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BENZYL ALCOHOL


Page 6 of 43


case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35


ERC8a*

STP 0.128 mg/l 39 mg/l 3.28E-03 --

ERC8d**

STP 0.126 mg/l 39 mg/l 3.23E-03 --


case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35

Exposure scenario 5 Consumer usesPC1

Consumers

Route Exposure

concentrations

Leading toxic

end point /

Critical effect

DNEL Risk

characterisatio

n ratio

Dermal 12.83 mg/kg

bw/d

Acute toxicity 29 mg/kg bw/d 0.44


Acute toxicity 40 mg/m3

0.513

Oral 0.771 mg/kg

bw/d

Acute toxicity 25 mg/kg bw/d 3.08x10-2

Acute -

systemic

effects

Combined 17.21 mg/kgbw/d

Acute toxicity 25 mg/kg bw/d 0.688

Dermal 0.0513 mg/kg

bw/d

Repeated dose

toxicity

5.7 mg/kg bw/d 9x10-3


Repeated dose

toxicity

8 mg/m3

0.138

Oral 0.0253 mg/kg

bw/d

Repeated dose

toxicity

5 mg/kg bw/d 5.06x10-3

Long-term -

systemic

effects

Combined

routes

0.488 mg/kg

bw/d

Repeated dose

toxicity

5 mg/kg bw/d 9.76x10-2

Please note, that in the table above the highest exposure values obtained for oral, dermal, inhalation and combined exposure, as

calculated by use of ConsExpo, are presented, thus, representing a worst case for each route of exposure


ERC8a*





ERC8d**





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BENZYL ALCOHOL


Page 7 of 43



case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35


ERC8a*

Agricultural soil

(30 days)7.11E-03 mg/kg 0.456 mg/kg 0.0156 --


ERC8d**

Agricultural soil

(30 days) 7.04E-03 mg/kg 0.456 mg/kg 0.0154 --



case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35


ERC8a*

STP 0.128 mg/l 39 mg/l 3.28E-03 --

ERC8d**

STP 0.126 mg/l 39 mg/l 3.23E-03 --


case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35

Exposure scenario 3 Industrial usesPC9a

Workers

Route Exposure

concentrations

Leading toxic

end point /

Critical effect

DNEL Risk

characterisatio

n ratio

Dermal 0.856 mg/kg

bw/d

Repeated dose

toxicity

9.5 mg/kg bw/d 9.01x10-2


Repeated dose

toxicity

90 mg/m3

5.01x10-2

Long-term -

systemic

effects

Combined

routes

1.19 mg/kg bw/d

ay

Repeated dose

toxicity

9.5 mg/kg bw/d 0.125










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BENZYL ALCOHOL


Page 8 of 43


* This spERC was calculated with the total tonnage of the following product categories: PC1, PC9a, b, c, 14, 15, and 18 and




Agricultural soil

(30 days)0.0106 mg/kg 0.456 mg/kg 0.0232 --






STP 0.215 mg/l 39 mg/l 5.5E-03 --



Exposure scenario 4 Professional usesPC9a

Workers Route Exposure

concentrations

Leading toxic

end point /

Critical effect

DNEL Risk

characterisatio

n ratio

Dermal 4.28 mg/kg bw/d Repeated dose

toxicity

9.5 mg/kg bw/d 0.451


Repeated dose

toxicity

90 mg/m3

0.526

Long-term -

systemic

effects

Combined

routes


toxicity

9.5 mg/kg bw/d 0.788





ERC8a*





ERC8d**




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BENZYL ALCOHOL


Page 9 of 43




case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35


ERC8a*

Agricultural soil

(30 days)7.11E-03 mg/kg 0.456 mg/kg 0.0156 --


ERC8d**Agricultural soil

(30 days)7.04E-03 mg/kg 0.456 mg/kg 0.0154 --



case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35


ERC8a*

STP 0.128 mg/l 39 mg/l 3.28E-03 --

ERC8d**

STP 0.126 mg/l 39 mg/l 3.23E-03 --


case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35

Exposure scenario 5 Consumer usesPC9a

Consumers

Route Exposure

concentrations

Leading toxic

end point /

Critical effect

DNEL Risk

characterisatio

n ratio

Dermal 4.17 mg/kg bw/d Acute toxicity 29 mg/kg bw/d 0.144


Acute toxicity 40 mg/m3

0.308

Oral 0.0169 mg/kgbw/d

Acute toxicity 25 mg/kg bw/d 6.76x10-4

Acute -

systemic

effects

Combined 9.12 mg/kg bw/d Acute toxicity 25 mg/kg bw/d 0.365

Dermal 0.0114 mg/kg

bw/d

Repeated dose

toxicity

5.7 mg/kg bw/d 2x10-3


Repeated dose

toxicity

8 mg/m3

4.23x10-3

Oral 9.25x10-5

mg/kg

bw/d

Repeated dose

toxicity

5 mg/kg bw/d 1.85x10-5

Long-term -

systemic

effects

Combined

routes

0.025 mg/kg

bw/d

Repeated dose

toxicity

5 mg/kg bw/d 5x10-3

Please note, that in the table above the highest exposure values obtained for oral, dermal, inhalation and combined exposure, as

calculated by use of ConsExpo, are presented, thus, representing a worst case for each route of exposure.


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ERC8a*





ERC8d**






case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35


ERC8a*

Agricultural soil

(30 days)7.11E-03 mg/kg 0.456 mg/kg 0.0156 --


ERC8d**

Agricultural soil

(30 days)7.04E-03 mg/kg 0.456 mg/kg 0.0154 --



case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35


ERC8a*

STP 0.128 mg/l 39 mg/l 3.28E-03 --

ERC8d**

STP 0.126 mg/l 39 mg/l 3.23E-03 --


case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35

Exposure scenario 3 Industrial usesPC9b

Workers

Route Exposure

concentrations

Leading toxic

end point /

Critical effect

DNEL Risk

characterisatio

n ratio

Dermal 0.856 mg/kg

bw/d

Repeated dose

toxicity

9.5 mg/kg bw/d 9.01x10-2

Long-term -

systemiceffects Inhalation 4.51 mg/m

3Repeated dose 90 mg/m

35.01x10

-2


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toxicity

Combined

routes

1.19 mg/kg bw/d

ay

Repeated dose

toxicity

9.5 mg/kg bw/d 0.125














Agricultural soil

(30 days)0.0106 mg/kg 0.456 mg/kg 0.0232 --

Grassland 4.59E-03 mg/kg 0.456 mg/kg 0.0101 --* This spERC was calculated with the total tonnage of the following product categories: PC1, PC9a, b, c, 14, 15, and 18 and




STP 0.215 mg/l 39 mg/l 5.5E-03 --



Exposure scenario 4 Professional usesPC9b

Workers

Route Exposure

concentrations

Leading toxic

end point /

Critical effect

DNEL Risk

characterisatio

n ratio

Dermal 4.28 mg/kg bw/d Repeated dose

toxicity

9.5 mg/kg bw/d 0.451


Repeated dose

toxicity

90 mg/m3

0.526

Long-term -

systemic

effects

Combined

routes


toxicity

9.5 mg/kg bw/d 0.788


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Page 12 of 43





ERC8a*





ERC8d**






case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35


ERC8a*

Agricultural soil

(30 days)7.11E-03 mg/kg 0.456 mg/kg 0.0156 --


ERC8d**

Agricultural soil

(30 days)7.04E-03 mg/kg 0.456 mg/kg 0.0154 --



case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35


ERC8a*

STP 0.128 mg/l 39 mg/l 3.28E-03 --

ERC8d**

STP 0.126 mg/l 39 mg/l 3.23E-03 --


case: * PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 30, 31, 32, 34, 35/ ** PC0, 1, 9a, 9b, 9c, 14, 15, 18, 21, 26, 31, 32, 34, 35

Exposure scenario 5 Consumer usesPC9b

Consumers

Route Exposureconcentrations

Leading toxicend point /

Critical effect

DNEL Riskcharacterisatio

n ratio


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Page 13 of 43

Dermal 15 mg/kg bw/d Acute toxicity 29 mg/kg bw/d 0.517


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