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NET-LITE TEL : +609-567 4662 FAX : +609-566 4459 EMAIL : [email protected] A66 METRODE WELDING CONSUMABLES HIGH STRENGTH Ni-Mo LOW ALLOY Alloy type A range of Mn-Ni-Mo low alloy consumables covering tensile strength requirements from 620MPa (90ksi) up to 825MPa (120ksi). Some are designed for as-welded applications whilst others are predominantly used following a stress relief PWHT. Materials to be welded These consumables are used for a variety of high strength steels. Depending on strength requirements, some examples are: Tufmet 1NiMo API 5A L80; BS 4360 grade 55F; RQT 601 (Corus); HY80; Navy Q1(N). E11018-M Q1(N); HY80; RQT 701 (Corus); QT445; NAXTRA 70; Hystal77. Tufmet 3NiMo HY80 & Q1(N); possibly HY100 & Q2(N). Applications All the consumables are used for a range of high strength low alloy steels. The E11018-M and Tufmet 3NiMo electrodes in particular are used for military applications by the MoD and US Navy for construction and repair of naval craft and submarines. The Tufmet 1NiMo was developed for the offshore industry where high strength and –50°C toughness is required in the as-welded condition. All of the consumables also have applications for general structural steel fabrications in HSLA steels, which may be used for cranes, earth moving equipment, and other highly stressed structural components. Microstructure The microstructure of all the consumables is predominantly ferrite; some will contain high proportions of acicular ferrite for optimum as-welded toughness (eg. Tufmet 1NiMo and Tufmet 3NiMo). Welding guidelines Preheat according to base material and thickness, although materials likely to be welded by the higher strength consumables will normally require 100°C minimum preheat. With some HSLA steels interpass temperatures above 200°C may result in a reduction of strength and toughness. PWHT generally dependent on base material and application, the solid wire ER110S-G is not recommended for applications requiring PWHT. Further information can be found under each individual product. Related alloy groups The 1NiMo.B electrode (data sheet A-61) is used for applications requiring maximum retained strength after extended PWHT. The MnMo consumables (data sheet A-50) may be suitable for some of the same applications. Products available Process Product Specification MMA Tufmet 1NiMo AWS E9016-G E11018-M AWS E11018-M Tufmet 3NiMo AWS E12016-G TIG/MIG ER110S-G AWS ER110S-G

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A66METRODEWELDING CONSUMABLES

HIGH STRENGTH Ni-Mo LOW ALLOY

Alloy typeA range of Mn-Ni-Mo low alloy consumables coveringtensile strength requirements from 620MPa (90ksi) upto 825MPa (120ksi). Some are designed for as-weldedapplications whilst others are predominantly usedfollowing a stress relief PWHT.

Materials to be weldedThese consumables are used for a variety of highstrength steels. Depending on strength requirements,some examples are:Tufmet1NiMo

API 5A L80; BS 4360 grade 55F;RQT 601 (Corus); HY80; NavyQ1(N).

E11018-M Q1(N); HY80; RQT 701 (Corus);QT445; NAXTRA 70; Hystal77.

Tufmet3NiMo

HY80 & Q1(N);possibly HY100 & Q2(N).

ApplicationsAll the consumables are used for a range of highstrength low alloy steels. The E11018-M and Tufmet3NiMo electrodes in particular are used for militaryapplications by the MoD and US Navy for constructionand repair of naval craft and submarines. TheTufmet 1NiMo was developed for the offshoreindustry where high strength and –50°C toughness isrequired in the as-welded condition.

All of the consumables also have applications forgeneral structural steel fabrications in HSLA steels,which may be used for cranes, earth movingequipment, and other highly stressed structuralcomponents.

MicrostructureThe microstructure of all the consumables ispredominantly ferrite; some will contain highproportions of acicular ferrite for optimum as-weldedtoughness (eg. Tufmet 1NiMo and Tufmet 3NiMo).

Welding guidelinesPreheat according to base material and thickness,although materials likely to be welded by the higherstrength consumables will normally require 100°Cminimum preheat.

With some HSLA steels interpass temperatures above200°C may result in a reduction of strength andtoughness.

PWHT generally dependent on base material andapplication, the solid wire ER110S-G is notrecommended for applications requiring PWHT.Further information can be found under each individualproduct.

Related alloy groupsThe 1NiMo.B electrode (data sheet A-61) is used forapplications requiring maximum retained strength afterextended PWHT.

The MnMo consumables (data sheet A-50) may besuitable for some of the same applications.

Products available

Process Product SpecificationMMA Tufmet 1NiMo AWS E9016-G

E11018-M AWS E11018-M

Tufmet 3NiMo AWS E12016-G

TIG/MIG ER110S-G AWS ER110S-G

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A67METRODEWELDING CONSUMABLES

General Data for all MMA ElectrodesStorage 3 hermetically sealed ring-pull metal tins per carton, with unlimited shelf life. Direct use from tin will give

hydrogen <5ml/100g weld metal during 8h working shift.For electrodes that have been exposed:Redry 250 – 300°C/1-2h to ensure H2 < 10ml/100g, 300 – 350°C/1-2h to ensure H2 < 5ml/100g. Maximum420°C, 3 cycles, 10h total.Storage of redried electrodes at 100 – 200°C in holding oven, or 50 – 150°C in heated quivers: no limit, butmaximum 6 weeks recommended.

Fume data Fume composition, wt % typical:

Fe Mn Ni Cr Cu F OES (mg/m3)

14 <7 <0.5 <0.5 0.2 18 5

TUFMET 1NiMo All-positional MMA electrode with high strength and toughness

Product description MMA electrode with a low hydrogen basic flux on a high purity mild steel core wire. Moisture resistant coatingensures very low weld metal hydrogen levels. Provides minimum strength of 620MPa (90ksi) in the as-weldedand stress-relieved condition.

Recovery is about 110% with respect to core wire, 65% with respect to whole electrode.

Specifications AWS A5.5 E9016-GDIN 8529 (EY 5576 Mn1NiMo B)Approval: Statoil R-SF-163

ASME IX Qualification QW432 F-No 4, QW442 A-No 10

Composition C Mn Si S P Ni Mo(weld metal wt %) min 0.030 1.30 0.25 -- -- 0.6 --

max 0.075 1.80 0.60 0.02 0.02 1.0 0.3typ 0.05 1.5 0.35 0.008 0.01 0.85 0.15

All-weld mechanical Typical values as-welded and PWHT min As-welded PWHT 600°C/4-8hproperties Tensile strength MPa 620-730 670 630

0.2% Proof stress MPa 550-660 600 525Elongation on 4d % 20 28 --Elongation on 5d % 20 25 --Impact energy 0°C J -- -- 130

- 50°C J 60 >100 >100

Operating parameters AC (OCV: 60V min) or DC -veOperation on DC+ve is not as favourable as above,ø mm 2.5 3.2 4.0 5.0min A 60 80 100 140max A 100 140 180 240

Packaging data ø mm 2.5 3.2 4.0 5.0length mm 350 450 450 450kg/carton 13.5 15.0 18.0 16.8pieces/carton 663 447 300 180

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A68METRODEWELDING CONSUMABLES

E11018-M All-positional MMA electrode with high strength and toughness

Product description MMA electrode with a low hydrogen basic, metal powder type, flux on a high purity mild steel core wire.Moisture resistant coating ensures very low weld metal hydrogen levels.

Conforms to military electrode specification used for Q1(N) and HY80 type steels used in naval construction byMoD and US Navy. Also suitable for similar high strength steels requiring a minimum strength of 760MPa(110ksi) in the as-welded and stress-relieved condition.

Recovery is about 120% with respect to core wire, 65% with respect to whole electrode.

Specifications AWS A5.5 E11018-MBS 2493 2NiMo.BHDIN 8529 (EY 6965 Mn2NiCrMo B)

ASME IX Qualification QW432 F-No 4, QW442 A-No 12

Composition C Mn Si S P Cr Ni Mo V(weld metal wt %) min -- 1.30 -- -- -- -- 1.50 0.25 --

max 0.10 1.80 0.60 0.030 0.030 0.40 2.50 0.50 0.05typ 0.05 1.7 0.35 0.012 0.012 0.2 2.2 0.4 0.02

All-weld mechanical Typical as welded and PWHT min As-welded PWHT 620°C/2hproperties Tensile strength MPa 760 820 830

0.2% Proof stress MPa 680-760 730 760Elongation on 4d % 20 23 --Elongation on 5d % 20 22 16Reduction of area % -- 65 --Impact energy + 20°C J -- 125 --

- 50°C J 30 80 40Lateral expansion - 50°C mm (mils) -- 0.9 (37) --

Operating parameters DC +ve or AC (OCV: 70V min)

ø mm 2.5 3.2 4.0 5.0min A 70 80 100 140max A 110 140 180 240

Packaging data ø mm 2.5 3.2 4.0 5.0length mm 350 380 450 450kg/carton 12.0 14.1 16.2 16.8pieces/carton 582 381 234 153

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A69METRODEWELDING CONSUMABLES

TUFMET 3NiMo All-positional MMA electrode with high strength and toughness

Product description MMA electrode with a low hydrogen basic flux on a high purity mild steel core wire. Moisture resistant coatingensures very low weld metal hydrogen levels.

The electrode was specially designed for welding HY80 and Q1(N) castings which are N+T following welding.Also suitable for other high strength steels requiring minimum tensile strength of about 820MPa (120ksi) in the as-welded and stress-relieved condition; or yield strength up to about 800MPa in the as-welded condition.

Recovery is about 110% with respect to core wire, 65% with respect to whole electrode.

Specifications AWS A5.5 E12016-GApprovals: MoD NES 769 for Q1(N) in Q+T condition.

ASME IX Qualification QW432 F-No 4, QW442 A-No 10

Composition C Mn Si S P Cr Ni Mo(weld metal wt %) min 0.02 0.8 -- -- -- 0.6 3.5 0.4

max 0.06 1.5 0.5 0.025 0.025 1.0 4.5 0.8typ 0.045 1.2 0.4 0.01 0.015 0.8 4 0.5

All -weld mechanical Q+Tproperties

Typical values: min As-weldedStress relieved600-620°C/1h

900°C/1-6h WQ +635-650°C/1-6h WQ

Tensile strength MPa 830 950 920 710-7700.2% Proof stress MPa 740 870 870 590-660Elongation on 4d % 14 20 22 --Elongation on 5d % -- 18 20 20-25Reduction of area % -- 55 58 65-70Impact energy 0°C J -- 65 -- --

- 50°C J -- 45 30 65-135CTOD - 5°C mm -- -- -- >0.46

Operating parameters DC +ve or AC (OCV: 70V min)

ø mm 3.2 4.0 5.0min A 80 100 140max A 140 180 240

Packaging data ø mm 3.2 4.0 5.0length mm 380 450 450kg/carton 13.8 17.7 16.5pieces/carton 381 267 156

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A70METRODEWELDING CONSUMABLES

ER110S-G High strength solid TIG and MIG wire

Product description Solid copper wire for TIG and MIG welding of Q+T steels requiring as-welded tensile strength up to about760MPa (110ksi). It is not recommended for applications requiring PWHT.

Specifications AWS A5.28 ER110S-G (Classified on the basis of mechanical properties in the as-welded condition)BS EN ISO 16834-A (Mn3Ni1CrMo)

ASME IX Qualification QW432 F-No 6, QW442 A-No 12

Composition C Mn Si S P Cr Ni Mo V Cu(wire wt %) min 0.05 1.4 0.4 -- -- 0.2 1.2 0.2 0.04 --

max 0.12 1.8 0.8 0.020 0.020 0.4 1.8 0.4 0.13 0.25typ 0.1 1.6 0.5 0.01 0.01 0.3 1.4 0.3 0.09 0.1

All-weld mechanical MAG MAGproperties Typical values as welded min TIG Ar+5%CO2 Ar+20%CO2

Tensile strength MPa 760 940 835 7300.2% Proof stress MPa 660 870 740 660Elongation on 4d % 15 23 21 21Impact energy - 20°C J -- 120 60 50Hardness cap/mid HV -- 300 280 255

* Minimum values for AWS ER110S-G MAG welds are typically obtained with low CO2 contentshielding gases; more oxidising gases give AWS ER100S-G properties, as shown above.

Typical operating TIG MIGparameters Shielding Argon Ar + 5-20%CO2 *

Current DC- DC+Diameter 2.4mm 1.2mmVoltage 120A, 14V 280A, 26V* Ar + 5%CO2 provides the highest strength and best impact properties, see above. Other proprietary gas

mixtures also suitable.

Packaging data ø mm TIG MIG1.0 -- 20kg spool1.2 -- 15kg spool1.2 -- 20kg spool2.4 5kg tube --

Fume data MIG fume composition (wt %) (TIG fume negligible)

Fe Mn Cr3 Ni Mo Cu OES (mg/m3)

50 10 1 0.4 <1.5 1.2 5

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A71METRODEWELDING CONSUMABLES

1NiMo.B

Product descriptionMMA electrode with low hydrogen basic flux coating onhigh purity mild steel core wire. Moisture resistant coatingensures very low weld metal hydrogen levels.

Recovery is about 120% with respect to the core wire, 65%with respect to whole electrode.

SpecificationsAWS A5.5 E9018-GBS EN 757 E 55 4 1NiMo B 32Approvals TÜV, DNV

ASME IX QualificationQW432 F-No 4, QW442 A-No 10.

Materials to be weldedASTM A302 grades C &D.

A508 class 1, 1A, 2 & 3.A533 grades A-D, class 1 & 2.

AISI 4130 and similar alloys.BS 1501 grades 271 & 281.

3604 grades HFS 591 & CFS 591.DIN 15NiCuMoNb5 (1.6368).

ApplicationsDesigned for welding low alloy steels used for pressurevessels (often thick wall) and other applications where highstrength must be maintained after extended, or multiple,PWHT cycles. These steels may also be used at modestelevated temperature and tests have shown typically 15%reduction in tensile strength at +300°C compared to the roomtemperature values for 1NiMo.B weld metal.

It is also used for welding type 4130, and other high strengthsteels, requiring good sub-zero toughness for oilfield andwell-head equipment. In comparison with the MnMo types(data sheet A-50) 1NiMo.B has improved resistance tosoftening at high tempering parameters.

MicrostructureIn the PWHT condition the microstructure consists oftempered high strength ferrite.

Welding guidelinesPreheat and PWHT requirements dependent on base material.

Composition (weld metal wt %)C Mn Si S P Cr Ni Mo Cu

min 0.04 1.0 -- -- -- -- 0.8 0.20 --max 0.07 1.4 0.5 0.020 0.025 0.3 1.2 0.50 0.10typ 0.06 1.2 0.3 0.01 0.01 0.1 1.0 0.4 0.05

All-weld mechanical propertiesPWHT 610-650°C/1-6h min typicalTensile strength MPa 620-780* 640-7000.2% Proof stress MPa 530 ** 540-630Elongation on 4d % 17 24-30Elongation on 5d % -- 21-26Reduction of area % -- 70Impact energy - 20°C J -- 75-110

- 40°C J -- 60- 60°C J -- 45

Hardness HV -- 220* Maximum according to DIN 8529 is optional.** Meets 550MPa minimum (DIN) according to yield

point.

ParametersDC +ve orAC (OCV: 70V min)ø mm 2.5 3.2 4.0 5.0min A 70 80 100 140max A 110 140 180 240

Packaging dataø mm 2.5 3.2 4.0 5.0length mm 350 350 450 450kg/carton 12.9 13.5 16.8 18.0pieces/carton 546 369 240 171

Storage3 hermetically sealed ring-pull metal tins per carton, withunlimited shelf life. Direct use from tin will give hydrogen<5ml/100g weld metal during 8h working shift.For electrodes that have been exposed:Redry 250-300°C/1-2h to ensure H2 <10ml/100g, 300-350°C/1-2h to ensure H2 <5ml/100g. Maximum 420°C, 3cycles, 10h total.Storage of redried electrodes at 100-200°C in holding ovenor 50-150°C in heated quiver: no limit, but maximum 6weeks recommended. Recommended ambient storageconditions for opened tins (using plastic lid): < 60% RH,>18°C.

Fume dataFume composition, wt % typical:

Fe Mn Ni Cr Cu Pb F OES (mg/m3)14 5 0.5 <0.1 <0.2 <0.1 18 5