12 Nordic Symposium on Catalysis

May 28-30,2006

Trondheim, Norway

Energy and Environmental CatalysisCatalysis in Nordic Countries

0NTNUInnovation and Creativity

Catalysis GroupDepartment of Chemical Engineering

Norwegian University of Science and Technology

Norwegian Chemical Society, Division for Catalysis

- EXTENDED ABSTRACTS -

o

Programme

Time Sunday May 28 2006The meeting takes place at Statoil R&D, Rotvoll, Trondheim.

16.30 Coffee, registration

17.15 Official opening, welcome

17.30 Statoil presentation

18.00 Session 1: Industrial catalysis

18.30

18.40

19.00

19.20

19.40

Nordic Keynote Lecture -1

Discovery of new technical catalysts based on insight.Claus Hviid Christensen. Center for Sustainable

Chemistry, Dept. of Chemistry, DTU, Denmark.

Short break

and Green

1-1 Catalyst structure as a basis for development, performance and

scale-up of the Statoil FT-catalystE. Rvtter. D. Schanke, S. Eri, H. Wigum, T. Hulsund Skagseth, E.

Bergene, J. Walmsley, A. Olafsen, R. Myrstad, A. Lindvag, P.

Midgley, I. Arslan, M. Shannon. Statoil, Norway/SINTEF,Norway/University of Cambridge, UK.

I-2 Monitoring of retrofit SCR systems.M. Larsson. Emission Technology Group, Sweden.

I-3 Optimization of the yield from an

dehydrogenation reactor with Cr203 catalyst.P. Roterud. Borealis, Norway.

industrial propane

I-4 Ring opening of naphthenic molecules in diesel fuels.R.G. Eaebera. D.D. Whitehurst. S.I. Andersen, G. Hytoft and K.G.

Knudsen. HaldorTops0e A/S, Denmark.

Reception, Statoil, Rotvoll.UB/TIB Hannover 89

119 832 992

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Time Monday May 29 2006.The meeting takes place at NTNU. Room: EL-5

8:00 Coffee, registration

Plenary Lecture-18:30 Structural requirements and activation pathways in reactions of methane

on small metal clusters.

Enrique Iglesia. College of Chemistry, University of California at Berkeley,.USA.

Session 2: Hydrogen Production.

9:20 0-1 M0S2 nanoparticles as catalysts for hydrogen evolution.J. Bonde, K.P. J0rgensen, T.F. Jaramillo, T. Morante, J.H. Nielsen,I. Chorkendorff, P.G. Moses ,S. Horch, J. K. Norskov. Dept. of Physics,DTU, Denmark.

9:40 0-2 M catalysts for sorption enhanced steam methane reforming.E. Ochoa-Fernandez, C. Lacalle, K.O. Christensen, M. Ronning, D.Chen, A. Holmen. Dept. of Chemical Engineering, NTNU, Norway.

10:00 Coffeebreak/Poster session

Session 3: Natural Gas Conversion.NTNU. Room: EL-5

10:30 0-3 Discovery ofnew technical methanation catalysts based oncomputational screening.J. Sehested, K.K. Larsen, A.L.Kustov, A.M. Frey. T. Johannessen, T.Bligaard, M.P. Andersson, J.K. N0rskov, C.H. Christensen. Dept. ofChemistry/Dept. of Physics, DTU, Denmark/Haldor Topsoe A/S, Denmark.

10:50 0-4 Study of cobalt particle size effects on selectivity in the Fischer-Tropsch synthesis.S. Loqdberq. 0. Borg, A. Holmen, S. Jaras, Chemical Technology, KTH.Sweden/Dept. of Chemical Engineering, NTNU, Norway.

11:10 0-5 Conversion of methanol to hydrocarbons over HZSM-5: The identityand the operation ofthe hydrocarbon pool.M. Bi0rgen, S. Svelle, J. Nerlov, F. Joensen, U. Olsbye, K.-P. Lillerud.Dept. of Chemistry, University of Oslo, Norway/Haldor Tops0e, Denmark.

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Session 4: Carbon Nanofibers.

NTNU. Room: EL-6

10:30 0-6 Role of surface oxygen in the preparation and deactivation of carbonnanofiber supported cobalt catalysts.Z. Yu. 0. Borg, D. Chen, E. Rytter, A. Holmen. Dept. of ChemicalEngineering, NTNU, Norway/Statoil, Norway.

10:50 0-7 Carbon nanofibers grown over graphite supported nickel catalyst:Relationship between octopus-like growth mechanism and macro-shaping.C. Pham-Huu, R. Vieira, B. Louis. A. Carvalho, J. Amadou, T. Dintzer,M.J. Ledoux. Strasbourg, France/Instituto Nacional de PesquisasEspaciais, Brasil.

11:10 0-8 Carbon nanofiber formation on nickel nanoclusters studied by ab initio

density functional theory calculations.F. Abild-Pedersen, J.K. N0rskov, J.R. Rostrup-Nielsen, J. Sehested andS. Helveg. Dept. of Physics, DTU/Haldor Tops0e, Denmark.

11.30 Lunch

Session 5: Catalytic NOx reduction.NTNU, Room: EL-5

12.30 Nordic Keynote Lecture-2NOx chemistry on BaO: Insights from electronic structure calculations.Henrik Gronbeck. Competence Centre for Catalysis, Chalmers Universityof Technology, Sweden.

13:00 0-9 Trends in catalytic NO decomposition on different transition metalsurfaces.

H. Falsig. J. Raas-Hansen, A.L. Kustov, C.H. Christensen, T. Bligaardand J.K. Narskov, Dept. of Physics/Dept. of Chemistry, DTU, Denmark.

13:20 0-10 The influence of Ni load and support material on catalysts for theselective catalytic oxidation of ammonia in gasified biomass.S. Nassos, E. Elm Svensson, M. Boutonnet and S. Jaras. Chemical

Technology, KTH, Sweden.

13:40 0-11 EPR Spectroscopic Characterization of Cu Interactions on

Alternative Oxide Catalysts for DeNOx.

S. B. Rasmussen, M. Kustova, J. Due-Hansen, A. Kustov, R. Fehrmann

and C.H. Christensen. Dept. of Chemistry, DTU, Denmark.

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Session 6: Catalyst discovery.NTNU. Room: EL-6

13:00 0-12_Microkinetic modelling as a tool in catalyst discovery.A. Skrvcka, P. Stoltze, W. van Well. Aalborg University, Denmark.

13:20 0-13 Multitubular reactor design as an advanced tool for three-phase

catalytic reactions.P. Maki-Arvela, K. ErSnen, T. Salmi, D. Yu. Murzin. Process Chemistry

Centre, Abo Akademi University, Finland.

13:40 0-14 Supported ionic liquid phase (SILP) catalysis: A new concept for

continuous, fixed-bed methanol carbonylation.A. Riisager, B. J0rgensen, M. Haumann, P. Wasserscheid and R.

Fehrmann. Dept. of Chemistry, DTU, Denmark/Erlangen, Germany.

14.00 Coffee break/Poster Session

Session 7: Hydrogen Technology.NTNU. Room.: EL-5

Nordic Keynote Lecture-314.30 Pd-based thin films in catalytic membrane reactor applications.

Hilde Johnsen Venvik. Dept. of Chemical Engineering, NTNU, Norway.

15.00 0-15 Kinetics of the water-gas shift reaction over microstructured

platinum/ceria/ alumina catalysts.G. Germani. Y. Schuurman, C. Mirodatos, Haldor Tops0e AS, Denmark/

IRC-CNRS, Villeurbanne, France.

15.20 0-16 Hydrogen from commercial diesel fuel using rhodium catalysts:

performance of kilowatt-scale reformer.M. Nilsson. B. Lindstrom, L.J. Petterson, Chemical Technology, KTH,

Sweden/Volvo PowerCell, Sweden.

15.40 0-17 Development ofnanostructured Pt-based electrocatalyst for high

temperature polymer electrolyte fuel cells.

ST. Briskebv. M. Tsypkin, S. Tang, S. Sunde, R. Tunold, I. Kvande,D. Chen. Dept. Materials Science and Technology/Dept. of Chemical

Engineering, NTNU, Norway.

16.00 Poster Session/Refreshments

19.30 Boat/Dinner at Munkholmen. Transport by bus from NTNU at 19.00

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Time Tuesday May 30 2006.The meeting takes place at NTNU. Room: EL-5

8.30 Plenary Lecture - 2 (Francois Gault Lecture):Designing Oxidation Catalysts.Graham Hutchinqs. Department of Chemistry, Cardiff University, UK.

Session 8 - Fundamentals.

NTNU. Room: EL-5

9.20 0-18 Adsorption of H2 and 02 and catalytic formation of water on small

platinum clusters in a cluster beam experiment.M. Andersson and A. Rosen. Dept. of Physics, Goteborg University,Sweden.

9.40 0-19 Structure Sensitivity of Benzene Hydrogenation on Pt(111) and

Pt(100): A Surface Vibrational Spectroscopic and Kinetic Study.K.M. Bratlie, L.D. Llores and G.A. Somorjai. Dept. of Chemistry,

University of California, Berkeley. USA.

10.00 Coffee break/Poster Session

Session 9 - Materials and SynthesisNTNU. Room: EL-5

10:30 O-20 A systematic study on the influence of the deposition-precipitationmethod when used to incorporate Pt into the SBA-15 mesostructure.

S. Chvtil. W.H. Glomm, I. Kvande, Z. Tiejun, J.C. Walmsley, E.A. Blekkan,

Dept. of Chemical Engineering, NTNU/SINTEF, Norway.

10:50 0-21 Consecutive Heterometal-Grafting on Periodic Mesoporous Silica

SBA-15.

M. Schnitzlbaumer and R, Anwander. Dept. of Chemistry, University of

Bergen, Norway.

11:10 0-22 Nanocrystalline Cu-Ce-Zr mixed oxide catalysts for clean fuel

application.F. Huber. H. Venvik, M. Ronning, J. Walmsley, A. Holmen. Dept. of

Chemical Engineering, NTNU /SINTEF, Norway.

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Session 10 - Catalytic Combustion.

NTNU. Room: EL-6

10:30 0-23 The stability ofpalladium-based catalysts for catalytic combustion of

methane in gas turbines.

K. Persson, A. Ersson, S. Colussi, A. Trovarelli, K. Jansson, S.G. Jaras.

KTH, Sweden/Universita di Udine, Italy/Arrhenius Laboratory, Sweden.

10:50 0-24 Pilot-scale investigation of Pt/alumina catalysts deactivation by

organosilicon in the total oxidation of hydrocarbons.A.C. Larsson, M. Rahmani, K. Arnby, M. Ssohrabi, M. Skoglundh, N.

Cruise, M. Sanati. VSxjo University, Sweden/Chalmers University of

Technology, Sweden/Amir-Kabir University of Technology, Iran/PerstorpFormox, Sweden.

11:10 0-25 Comparative study of CH3OH and SH3SH removal from air over

modified Pd-H-ZSM-5 catalysts.A.V. Kucherov, S. Ojala, K. Slovetskaya, I.M. Sinev, R. Keiski and L.M.

Kustov. Zelinski Institute of Organic Chemistry, Moscow, Russia/Oulo,Finland.

11.30 Lunch

Session 11 - Emission Control for Diesel Engines.12.30 NTNU. Room: EL-5

Nordic Keynote Lecture-4

Diesel powered vehicles - can we meet the future emission limits or not?Kalle Arve, K. ErSnen and D. Yu. Murzin. Process Chemistry Centre, Abo

Akademi, Finland.

13:00 0-26 Diesel particulate abatement via catalytic wall-flow filters: regeneration

parameters study.E. Cauda, D. Fino, G. Saracco, V. Specchia. Dept. Materials Science and

Chemical Engineering, Politecnico di Torino, Italy.

13:20 0-27 Electrochemical removal of NOx on perovskites and the influence of

applying BaO in the perovskite.V.L.E. Simonsen, M.M. Johnsen, K.K. Hansen. Ris0 National Laboratory,Denmark.

13:40 0-28 Structural changes in air aged and poisoned diesel catalysts.T. Kanerva, V. Kroger, K. Rahkamaa-Tolonen, M. Vippola. T. Lepisto,R.L. Keiski. Tampere University of Technology, Finland/University of

Oulu, Finland/Ecocat Oy, Finland.

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Session 12 - Refinery processes.NTNU. Room: EL-6

13:00 0-29 Towards the production of "Green" gasoline. A study on thedimerization of 1-butene over Beta zeolite.

J.I. Villeaas. N. Kumar, T. Heikkila, V-P. Lehto, T. Salmi, D. Yu. Murzin.

Process Chemistry Centre, Abo Akademi, Finland.

13:20 O-30 Ring opening of decalin overmetal modified microporous and

mesoporous molecular sieve catalysts.N. Kumar. A.L. Garay, D. Kubicka, T. Salmi, D.Yu. Murzin, T. HeikkilS, V.-P. Lehto. Process Chemistry Centre, Abo Akademi/Laboratory ofIndustrial Physics, Turku University, Finland.

13:40 0-31 Hydrodeoxygenation ofaromatic and aliphatic oxygen-containingcompounds on sulphided NiMo/AI203and CoMo/Ah03.Q.I. Senol. E.-M. Ryymin, T.-R. Viljava and A.O.I. Krause, Laboratory ofIndustrial Chemistry, HUT, Finland.

14:00 Coffee break/Poster "take down".

14:30 Plenary Lecture - 3 (Norwegian Chemical Society Industry Lecture)NTNU. Room: EL-5

Car in a Hot Tin Tube

Hugh Stitt. Johnson Matthey, UK.

15:00 Concluding remarks, end of conference.

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Poster Presentations

Natural gas conversion

P1 Pareto-optimal methanation catalysts.M.P. Andersson, T. Bligaard, K.E. Larsen, J. Greeley, T. Johannessen,

J.K. Norskov, A. Kustov, C.H. Christensen. Dept. of Physics/Dept. of

Chemistry/Dept. of Chemical Engineering, DTU, Denmark.

P2 Hydrocarbon production via Fischer-Tropsch synthesis from CO-rich

syngas over different Co-Fe/AI203 bimetallic catalysts.D. Tristantini. B. Gevert, S. Logdberg, A.Holmen. Dept. Materials and

Surface Chemistry, Chalmers University of Technology, Sweden/KTH,

Stockholm, Sweden/NTNU, Norway.

P3 Effect ofpresence ofNOx during calcination on the Fischer-Tropschsynthesis activity and selectivity^0. Borq, S. Storsaeter, S. Eri, E. Rytter, E.A. Blekkan, A. Holmen. Dept. of

Chemical Engineering, NTNU, Norway/ Statoil, Trondheim, Norway.

P4 CO hydrogenation on Co/y-AI203 and CoRe/y-AI203 studied by SSITKA.V. Fnaseth. A. Holmen. Dept. of Chemical Engineering, NTNU,

Trondheim, Norway.

P5 A study of supported rhodium catalysts for partial oxidation of methane.S. Eriksson. M. Boutonnet, S. Jaras. Chemical Technology, KTH,Stockholm, Sweden.

P6 Reduction/oxidation behaviour of Lao.5Sro.sFeyC01.yO3s perovskite oxidesstudied by TEOM-MS^E. Bj0rqum, D. Chen, H.L. Lein, T. Grande, A. Holmen. Dept. of Chemical

Engineering/Dept. of Materials Science and Engineering, NTNU,Trondheim, Norway.

P7 Vanadium supported on hexagonal mesoporous silica: active and stable

catalysts in the oxidative dehydrogenation of propane.K. Petr. C. Libor, B. Roman, A. Jifi. Dept. of Physical Chemistry,University of Pardubice, Czech Republic.

P8 A first-principles characterization of ammonia synthesis on Fe(111)^A. Hellman. K. Honkala, S. Dahl, J. K. N0rskov. Dept. of Physics, DTU,Lyngby/Haldor Tops0e A/S, Denmark.

P9 The effect of aging time on the performance Cu/ZnO/Zr02 catalysts in

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methanol synthesis from C02 and H2lR. Raudaskoski R. Lenkkeri, M. Niemela and R. L. Keiski. Dept. of

Process and Environmental Engineering, University of Oulu, FinlandA/TT

Processes, Finland.

P10 Methanol synthesis from C02 and H2 over Cu/ZnO/Zr02/AI203 catalystR. Raudaskoski. M. Niemela, R. Lenkkeri, R. L. Keiski. Dept. of Process

and Environmental Engineering, University of Oulu, Finland/VTT

Processes, Finland.

P11 Computer-assisted search for new ammonia synthesis catalysts.T.R. Munter. T. Bligaard, J. Greeley, J.K. N0rskov, C.H. Christensen.

CAMP, NanoDTU/ Dept. of Chemistry,, Lyngby, Denmark.

P12 The production ofethene via oxidative dehydrogenation of ethane over

Pt-Sn monoliths.

S.F. Hakonsen. B. Silberova, A. Holmen. Dept. of Chemical Engineering,NTNU, Trondheim, Norway.

P13 Methyl halide conversion to light olefins over a SAPO-34 catalyst.S. Svelle. S. Aravinthan, U. Olsbye, I.M. Dahl. Center for Materials

Science and Nanotechnology, Dept. of Chemistry, University of

Oslo/SINTEF Materials and Chemistry, Oslo, Norway.

P14 In situ XPS investigation of Pt(Sn)/Mg(AI)0 catalysts during ethane

dehydrogenation.A. Virnovskaia. S. J0rgensen, U. Olsbye, E. Kleimenov, A. Knop-Gericke,

R. SchlSgl, Dept. of Chemistry, University of Oslo, Norway/Dept. of

Inorganic Chemistry, Fritz-Haber-lnstitut der Max-Planck-Gesellschaft,

Berlin, Germany.

Hydrogen and fuel cells

P15 Autothermal reforming ofsimulated fuels on ZnD2 supported bimetallic

Rh/Pt catalysts.A. Gutierrez. R.K. Kaila, A.O.I. Krause, Laboratory of Industrial Chemistry,

HUT, Helsinki, Finland.

P16 Steam reforming ofmethanol: Kinetic modeling and experimental results.

S. Patel, K.K. Pant. Dept. of Chemical Engineering, Indian Institute of

Technology, New Delhi, India.

P17 Modelling ofsteam reforming ofa hydrocarbon fuelin a monolithic

reactor.

D. Creaser. Chemical Reaction Engineering, Chalmers University of

Technology, GQteborg, Sweden.

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P18 Impact of fly ash from biomass gasification on deactivation ofreforming

catalysts.J. Einvall. S. Albertazzi, C. Hulteberg. F. Basile, A.-C. Larsson, E.

Gustafsson, J. Brandin, F. Trifiro, M. Sanati. Vaxjb" University, School of

Technology and Design, Sweden/Dipartimento di Chimica Industriale e

dei Materiali, Bologna University, Italy/Catator AB, Lund, Sweden.

P19 Activity of rhodium-based catalysts for CO preferential oxidation in H2-rich

gases.C. Galletti, S. Fiorot, S. Specchia, G. Saracco, V. Specchia. Materials

Science and Chemical Engineering Dept. - Politecnico di Torino, Torino,

Italy.

P20 Catalytic oxidation ofhydrogen overAu/Ti02 catalysts.H. Dvrbeck, N. Hammer, M. R0nning, E.A. Blekkan. Dept. of Chemical

Engineering, NTNU, Trondheim, Norway.

P21 The hydrogen splitting rate on some transition metals at 1 bar hydrogen

pressure in presence of CO.

M. Johansson, O. Lytken, I. Chorkendorff, Center for Individual

Nanoparticle Functionality (CINF), DTU, Lyngby, Denmark.

P22 Electrocatalysts forproton exchange membrane water electrolysis.A. Lervik, A. Marshall, M. Tsypkin, S. Sunde, R. Tunold. Dept. of MaterialsScience and Engineering, NTNU, Trondheim, Norway.

P23 Identification of valence shifts in Au during the water-gas shift reaction.

N. Hammer, I. Kvande, D. Chen, M. Renning. Dept. of Chemical

Engineering, NTNU, Trondheim, Norway.

P24 Shift catalysts in biomass generated synthesis gas.I. Kirm, M. Sanati, J. Brandin. Vaxjo university, School of Technologyand Design, Sweden/Catator AB, Lund, Sweden.

P25 Modeling and simulation of C02 selective water gas shift membrane

reactor for hydrogen purification.S.K. Wirawan. M. Petersson, D. Creaser. Dept. of Chemical Reaction

Engineering, Chalmers University of Technology/Volvo Technology,Gothenburg, Sweden.

P26 Pt-PBI-carbon black nanocomposite as electrocatalysis for protonexchange membrane fuel cells.

S. Tang, Q. Xin, and G. Sun, M. R0nning, P. Chen. ST. Briskeby, M.

Tyspkin, S. Sunde, R. Tunold. Dalian Institute of Chemical Physics,Chinese Academy of Sciences, Dalian, China/ Dept. of Chemical

Engineering/ Dept. of Materials Science and Engineering, NTNU, Norway.

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Materials/fundamentals

P27 On the preparation methods for carbon nanofiber supported Pt-cataiysts.Kvande

,N. Hammer, M. R0nning, D. Chen, ST. Briskeby, M. Tsypkin, S.

Sunde, R.Tunold. Dept. of Chemical Engineering/Dept. of MaterialsScience and Engineering, NTNU, Trondheim, Norway.

P28 Adsorption and desorption kinetics of C02 on a Cu/Zr02 catalyst.T. Keskitalo, M. Niemela, A.O.I. Krause, Laboratory of IndustrialChemistry, HUTA/TT, Finland.

P29 Surface organometallic chemistry ofperiodic mesoporous organosilicas:Generation of surface-confined zinc and yttrium centers.Y. Liang, R. Anwander. Dept. of Chemistry, UiB, Bergen, Norway.

P30 Alumina prepared from pseudo-boehmite via calcination in steam.O. Ohrman, A. Carlsson, S. Helveg, A. Molenbroek and P.L. Hansen.Haldor Tops0e A/S, Lyngby, Denmark.

P31 Variable temperature EPR study of Cu-mordenite catalysts: Influence ofthe S1O2/AI2O3 molar ratio.F. Chavez Rivas. R. Zamorano Ulloa, V. Petranovskii, A. Simakov. I.Hernandez Perez. Dept. de Fisica, Escuela Superior de Fisica yMatematicas/Centro de Ciencias de la Materia Condensada,

UNAM/Departamento de Ciencias Basicas, UAM-Azcapotzalco, Mexico.

P32 Textural and Spectroscopic Characterization of Vanadium-Zirconia

Catalysts.T.L. Balderas, A.J. Castro, P.I. Hernandez, M.R. Lopez, G.E. Rojas, P.R.Suarez, F. ChaVez Rivas. Depto. Ciencias Basicas, UniversidadAutonoma Metropolitana-A/ Centra de Investigaciones en Energia,UNAM, /Estudios de Posgrado, Escuela Superior de Ingenieria Quimicae Industrias Extractivas-IPN/Depto. Fisica, Escuela Superior de Fisica yMatematicas, IPN, Mexico.

P33 Reaction intermediates in high temperature catalytic water formationstudied with cavity ringdown spectroscopy.S. Hemdal, A. Johansson, M. Andersson, and A. Rosen. Dept. of Applied

Physics, Chalmers University of Technology, Dept. of Physics GoteborgUniversity, Goteborg, Sweden.

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P34 Nanomaterials for hydrogenation and dehydrogenation reactions.

K. Rovik. C.H. Christensen, S. Dahl, I. Chorkendorff, Center for Individual

Nanoparticle Functionality (CINF)/ Dept. of Chemical Engineering/Centerfor Sustainable and Green Chemistry, Dept. of Chemistry, DTU/ Haldor

Tops0e A/S, Lyngby, Denmark.

P35 Catalytic properties ofoxide nanoparticles applied in gas sensors.

D. Lutic, M. Strand, A. Lloyd-Spetz, M. Sanati. Dept. of Chemistry, VSxjoUniversity, Vaxjo/S-SENCE and Div. of Applied Physics, Linkoping

University, Sweden.

P36 Carbon monoxide poisoning of Pt (111) catalyzed H2/D2 exchange studied

by high-pressure scanning tunneling microscopy, high-pressure X-rayphotoelectron spectroscopy and sum frequency generation.M. Montano. K. Bratlie, M. Salmeron and G. Somorjai. Dept. of Chemistry,University of California/Materials Science Dept, Lawrence BerkeleyNational Lab, Berkeley, USA.

P37 Supported /3-zeolite on preshaped (1-SiC as clean Friedel-Crafts liquidphase catalyst.G. Wine, M.-J. Ledoux, C. Pham-Huu, European Laboratory of Catalysisand Surface Sciences, Strasbourg, France.

P38 Effect of graphitic platelet orientation on the properties of carbonnanofiber supported Pd catalysts.T.-J. Zhao. Y.-C. Dai, W.-K. Yuan, D. Chen, A. Holmen. UNILAB, State

Key Laboratory of Chemical Reaction Engineering, East China Universityof Science and Technology, Shanghai, China/Dept. of Chemical

Engineering, NTNU, Norway.

P39 An investigation of C02 and H2 on copper deposited on a platinum (111)single crystal.N. Schumacher. I. Chorkendorff. Center for Individual NanoparticleFunctionality, DTU, Lyngby, Denmark.

P40 Molecular Dynamics Simulation of the Binding of Platinum Clusters to

Graphite Sheets.

C.F. Sanz-Navarro. P.-O. Astrand, M. R0nning, D. Chen, A.C.T van Duin,W.A. Goddard III. Dept's of Chemistry and Chmical Engineering, NTNU,Norway/California Institute of Technology, Pasadena, USA.

P41 Shape selective Meerwein-Ponndorf-Verley reduction over aluminium-

grafted mesoporous silica SBA-1.C. Zapilko. R. Anwander. Dept. of Chemistry, UiB, Bergen, Norway.

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Fine Chemicals

P42 Catalytic partial oxidation of crotonaldehyde.P. Cicmanec, K. Syslova, J. Tichy. Dept. of Physical Chemistry, Universityof Pardubice, Czech Republic.

P43 Direct ammoxidation ofpropane over zeolites with trace of iron.

R. Bulanek. F. Castek. Dept. of Physical Chemistry, University of

Pardubice, Czech Republic.

P44 Dibenzothiophene Oxidation on Heteropolyacid Catalysts.M.A.K. Medina, M.R. Lopez, G.E. Rojas, P.R. Suarez, A.J. Castro, P.I.

Hernandez, F. Chavez Rivas. Depto. Ciencias Basicas, Universidad

Autonoma Metropolitana-A/Centro de Investigaciones en Energfa,UNAM/Estudios de Posgrado, Escuela Superior de Ingenieria Quimica eIndustrias Extractivas/ Depto. Fisica, Escuela Superior de Ffsica yMatematicas. IPN, Mexico.

P45 Investigating the enantioselective site ofpyruvate hydrogenationconducted in the gas-phase.N. Dutnmer. R. Jenkins, S. Bawaked, D.J. Willock, G.J. Hutchings, Cardiff

University, UK.

P46 Water effect on the kinetics of the dehydrogenation of 1-pentanol to di-N-

pentyl ether (DNPE).R. Bringue, J. Teiero, M. Iborra, J.F. Izquierdo, C. Fite, F. Cunill. Chemical

Engineering Dept. University of Barcelona, Spain.

P47 Selective Catalytic Oxidation ofAlcohols to Aldehydes by Dioxygen.P. Lahtinen. J. U. Ahmad, T. Repo and M. Leskela. Laboratory of

Inorganic Chemistry, Dept. of Chemistry, University of Helsinki, Finland.

Environmental catalysis

P48 Perovskite supported on hexaaluminate for high temperature catalyticcombustion of methane.

E. E. Svensson, M. Boutonnet, S.G. Jaras, Chemical Technology, KTH,

Stockholm, Sweden.

P49 Electrochemical reduction of NO and 02 on spinels.D. Find, M. Lilliedal, R. Petersen, V.L.E. Simonsen, K. Kammer, Materials

Research Dept, Ris0 National Laboratory, Roskilde, Denmark.

P50 Electrochemical removal of NOx on K2NiF4-structures.

L. N0rskov. V.L.E. Simonsen, K.K. Hansen. Materials Research Dept,

Riso National Laboratory, Roskilde, Denmark.

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P51 Physical and chemical characterization ofpotassium deactivation of an

SCR catalyst for biomass combustion.A.-C. Larsson, J. Einvall, A. Andersson, M. Sanati. Vaxjo Univ., Sweden.

P52 Evaluation of a novel laboratory-scale phosphorus poisoning procedurefor exhaust gas catalysis.V. Kroger, E. Turpeinen, U. Lassi, K. Kynkaanniemi, R.L. Keiski. Dept. of

Process and Environmental Engineering, University of Oulu/Central

Ostrobothnia University of Applied Sciences, Dept. of Technology,

Kokkola, Finland.

P53 Drinkable and waste water nitrates catalytic reduction over Pd-based

nanostructured polymer catalysts.V. Matveeva, E. Sulman, A. Gavrilenko, M. Sulman. Tver State Technical

University, Tver, Russia.

P54 Characterization ofphosphorus poisoning on Pt and oxides containing

diesel catalyst components.V. Kroger. T. Kanerva, U. Lassi, K. Rahkamaa-Tolonen, M. Vippola' R.L.

Keiski. Dept. of Process and Environmental Engineering, University of

Oulu/Tampere University of Technology, Institute of MaterialsScience/Central Ostrobothnia University of Applied Sciences, Dept. of

Technology, Kokkola/Ecocat Oy, Oulu, Finland.

P55 Mesoporous Fe-containing ZSM-5 and ZSM-12 zeolite single crystal

catalysts for selective catalytic reduction of nitric oxide byammonia.M. Kustova, K. Egeblad, A. Kustov, C.H. Christensen. Center forSustainable and Green Chemistry, Dept. of Chemistry, DTU, Lyngby,Denmark.

P56 The effect of La203 on dynamic OSC over the Pd/OSC/AI203-based

catalysts.T. Kolli, R.L. Keiski, Dept. of Process and Environmental Engineering,University of Oulu, Finland.

P57 Radioisotope tracer study of co-reactions of methanol with ethanol: Using11C-labelled methanol over alumina, H-ZSM-5 and Cu-ZSM-5.

E. Sarkadi-Priboczki. Z. Kovacs, N. Kumar, T. Salmi, D.Yu. Murzin.

Institute of Nuclear Research of the Hungarian Academy of Sciences,Debrecen, Hungary/Laboratory of Industrial Chemistry, Process

Chemistry Centre, Abo Akademi University, Finland.

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Refinery processes

P58 A density functional study of the hydrodesulfurization reaction pathway of

thiophene on MoS2 based catalysts.P.G. Moses. B. Hinnemann, J.K. N0rskov, H. Tops0e. Center for Atomic-scale Materials Physics (CAMP), Nano DTU/HaldorTops0e A/S, Lyngby,Denmark.

P59 Deposition of CoO onto MoOs/Al203 hydrodesulfurization catalysts bysolvent assisted spreading.L. Kaluza. M. Zdrazil. Institute of Chemical Process Fundamentals,

Academy of Sciences of the Czech Republic, Prague, Czech Republic.

P60 Investigation of hydrodearomatization ofprehydrogenatedgas oil fractionson Pt,Pd/H-USY catalysts.G. Nagv. J. Hancsok, Z. Varga, G. Polczmann. Dept. of Hydrocarbon and

Coal Processing, University of Veszprem, Hungary.

P61 Adsorption of aromatic dione on Pt surface: A DFT Study.V. Nieminen. D.Yu. Murzin, A. Taskinen. Process Chemistry Centre, Lab.

of Industrial Chemistry/Dept. Physical Chemistry, Abo Akademi

University, Finland.

P62 Upgrading of gas oils: the HDS kinetics of dibenzotiophene and itsderivatives in real gas oil.

Z. Varga, J. Hancsok, G. Nagy, G. Polczmann, D. Kallo. Dept of

Hydrocarbon and Coal Processing, University of Veszprem/ChemicalResearch Center, Institute of Chemistry, Hungarian Academy Sciences,

Budapest, Hungary.

P63 HDS and HDN of FCC gasoline spiked with benzotiophene over PtPd/H-

USY.

J. Hancs6k, S. Magyar, K. Juhasz, D. Kallo. Dept of Hydrocarbon and

Coal Processing, University of Veszprem/Chemical Research Center,Institute of Chemistry, Hungarian Academy of Sciences, Budapest,

Hungary.

P64 A DFT study on benzene adsorption over tungsten sulfides.

R. Koide. E.J.M. Hensen , R.A. Van Santen, J.F. Paul, S. Cistol , E.

Payen, H. Nakamura. Schuit Institute of Catalysis, Eindhoven University of

Technology, Eindhoven, The Netherlands/Laboratoire de Catalyze de

Lille, Villeneuve, France/ Japan Energy Corporation, Saitama, Japan.

P65 Cracking of vacuum residue from athabasca bitumen in a thin film.

E.S. Wangen, E.A. Blekkan, W.C. McCaffrey, S. Kuznicki, A. Hoff.

Norwegian University of Science & Technology, Trondheim, University of

Alberta, Edmonton, Canada, Statoil R&D, Trondheim, Norway.

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P66 Production of ultra-low sulfur fuels by selective catalytic oxidation.

JT. Sampanthar, D. Jian, I. K. Surjami. Institute of Chemical and

Engineering Sciences, Agency for Science and Technology, Singapore.

18