Material Safety Data Sheet.docx Alerrrr

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MATERIALSAFETYDATASHEET

ZOUAIMIA L 33425UTM BROOKLYN OCEAN PARKWAY NEW YORK CITY USAVRT-ULTRAMAR CANADA

ID SHEET

DATA SHEET

1.ProductandCompanyIdentification

Materialname

Version#

Issuedate

Revisiondate

Supersedesdate

MSDSNumber

Productuse

Synonym(s)

Manufacturer/Supplier

GeneralAssistance

Emergency

2.HazardsIdentification

Physicalstate

Appearance

Emergencyoverview

OSHAregulatorystatus

Potentialhealtheffects

Routesofexposure

EyesSkin

Inhalation

Ingestion

Targetorgans

DIESEL FUELS


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ZOUAIMIA L33425UTMBROOKLYN OCEANPARKWAY NEWYORK CITY USAVRT-ULTRAMARCANADAD

I

E

S

E

L

F

U

E

L

S

0

3

0

9

-

N

o

v

e

m

b

e

r

-

2

0

1

0

2

5

-

J

une-201304-November-2012

102Refinery feedstock.DieselFuels AllGrades, DieselFuelNo.2, FuelOilNo.2, HighSulfurDieselFuel, LowSulfurDieselFuel, UltraLowSulfurDieselFuel, CARB (CaliforniaAirResourceBoard)DieselFuel,Off-RoadDieselFuel, DyedDieselFuel, X GradeDieselFuel, X-1DieselFuel, R5ULSD, B5ULSDSeesection16forcompleteinformation.ValeroMarketing& Supply Company andAffiliatesP.O. Box 696000

SanAntonio, TX 78269-6000210-345-4593

24HourEmergency 866-565-52201-800-424-9300(CHEMTRECUSA)

Liquid.

Liquid(may bedyedred).WARNING!Combustibleliquidandvapor. May beignitedby heat, sparks orflames. Heat may causethecontainers toexplode.

Harmfulif inhaledorswallowed. May beharmfulif absorbedthroughskin. Aspirationmay cause

lungdamage. Irritatingtoeyes, respiratory systemandskin. Inhighconcentrations, vapors andspray mists arenarcotic andmay causeheadache, fatigue, dizziness andnausea. Suspect cancerhazard-may causecancer. Prolongedexposuremay causechronic effects. Dieselexhaust hasbeenreportedtobeanoccupationalhazardduetoNIOSH-reportedpotentialcarcinogenicproperties. Hydrogensulfide, ahighly toxic gas, may bepresent orreleased. Signs andsymptomsof overexposuretohydrogensulfideincluderespiratory andeyeirritation, dizziness, nausea,coughing, asensationof dryness andpaininthenose, andloss of consciousness. Odordoes notprovideareliableindicatorof thepresenceof hazardous levels intheatmosphere. Toxic toaquaticorganisms. May causelong-termadverseeffects intheaquatic environment. Thetoxicologicalproperties of this materialhavenot beenfully investigated.Static accumulatingflammablematerials canbecomeelectrostatically chargedeveninbondedandgroundedequipment. Sparks may ignitematerialandvapormay causeflashfire(orexplosion).

This product is consideredhazardous under29CFR1910.1200(HazardCommunication).

Inhalation. Ingestion. Skincontact. Eyecontact.Contact may irritateorburneyes. Eyecontact may result incornealinjury.May beharmfulif absorbedthroughskin. Irritatingtoskin. Frequent orprolongedcontact maydefat anddry theskin, leadingtodiscomfort anddermatitis.Harmfulif inhaled. Irritatingtorespiratory system. Inhighconcentrations, vapors andspray mistsarenarcotic andmay causeheadache, fatigue, dizziness andnausea. May causebreathingdisorders andlungdamage. May causecancerby inhalation. Prolongedinhalationmay beharmful.Harmfulif swallowed. Ingestionmay result invomiting; aspiration(breathing)of vomitus intolungsmust beavoidedas evensmallquantities may result inaspirationpneumonitis. Irritatingtomouth,throat, andstomach.Blood. Eyes. Liver. Respiratory system. Skin. Kidneys. Centralnervous system.

3541 Version #: 03 Revison date: 25-June-2013 Print date: 25-June-2013 1 / 13

Prepared by 3E Company


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ZOUAIMIA L33425UTMBROOKLYN OCEANPARKWAY NEW YORKCITY USAVRT-ULTRAMARCANADA

Chroniceffects

Signsandsymptoms

Potentialenvironmentaleffects

Suspect cancerhazard-may causecancer. Liverinjury may occur. Kidney injury may occur.Exposuremay causelungcancerandalsonotedapositiveassociationwithanincreasedrisk ofbladdercancer. May causecentralnervous systemdisorder(e.g., narcosis involvingaloss ofcoordination, weakness, fatigue, mentalconfusionandblurredvision)and/ordamage. Frequent orprolongedcontact may defat anddry theskin, leadingtodiscomfort anddermatitis.Irritationof noseandthroat. Irritationof eyes andmucous membranes. Skinirritation.Unconsciousness. Cornealdamage. Narcosis. Decreaseinmotorfunctions. Behavioralchanges.Edema. Liverenlargement. Jaundice. Conjunctivitis. Proteinuria. Defattingof theskin. Rash. Thetoxicologicalproperties of this product havenot beenthoroughly investigated. Useappropriateprecautions.Toxic toaquatic organisms. May causelong-termadverseeffects intheaquatic environment.

3.Composition/InformationonIngredients

Components

Fuels, diesel, no. 2

Biodiesel-Fatty acidmethylesters

Fuels, diesel, C9-18-alkanebranchedandlinear

n-Nonane

Octane(Allisomers)

Hexane(Otherisomers)

Naphthalene

n-Heptane

n-Hexane

CAS#

68476-34-6

67762-38-3

1159170-26-9

111-84-2

111-65-9

96-14-0

91-20-3

142-82-5

110-54-3

Percent

85-100

0-5

0-5

1-3

1-2

0-1

0-1

0-1

0-1

4.FirstAidMeasures

Firstaidprocedures

Eyecontact

Skincontact

Inhalation

Ingestion

Notestophysician

Generaladvice

5.FireFightingMeasures

Flammableproperties

ExtinguishingmediaSuitableextinguishing

mediaUnsuitableextinguishing

media

Protectionoffirefighters

Protectiveequipmentandprecautionsforfirefighters


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ZOUAIMIA L33425UTMBROOKLYNOCEANPARKWAY NEWYORK CITY USAVRT-ULTRAMARCANADAFirefighting

equipment/instructions

SpecificmethodsHazardouscombustionproducts

Wearfullprotectiveclothing, includinghelmet, self-containedpositivepressureorpressuredemandbreathingapparatus, protectiveclothingandfacemask. Withdrawimmediately incaseof risingsoundfromventingsafety devices orany discolorationof tanks duetofire. Fight firefrommaximumdistanceoruseunmannedhoseholders ormonitornozzles. Movecontainers fromfireareaif youcandoit without risk. Intheevent of fire, cooltanks withwaterspray. Coolcontainersexposedtoflames withwateruntilwellafterthefireis out. Formassivefire, useunmannedhoseholders ormonitornozzles; if this is impossible, withdrawfromareaandlet fireburn. Waterrunoffcancauseenvironmentaldamage. Usecompatiblefoamtominimizevaporgenerationas needed.

Intheevent of fireand/orexplosiondonot breathefumes.Carbonmonoxide. CarbonDioxide. Sulfuroxides. Nitrogenoxides (NOx). Hydrocarbons. Hydrogensulfide.

6.AccidentalReleaseMeasures

Personalprecautions

Environmentalprecautions

Methodsforcontainment

Methodsforcleaningup

Keepunnecessary personnelaway. Localauthorities shouldbeadvisedif significant spills cannotbecontained. Keepupwind. Keepout of lowareas. Ventilateclosedspaces beforeentering. Donot touchdamagedcontainers orspilledmaterialunless wearingappropriateprotectiveclothing.SeeSection8of theMSDS forPersonalProtectiveEquipment.If facility oroperationhas an"oilorhazardous substancecontingency plan", activateitsprocedures. Stay upwindandaway fromspill. Wearappropriateprotectiveequipment includingrespiratory protectionas conditions warrant. Donot enterorstay inareaunless monitoringindicatesthat it is safetodoso. Isolatehazardareaandrestrict entry toemergency crew. Flammable.ReviewFirefightingMeasures, Section5, beforeproceedingwithcleanup. Keepallsources ofignition(flames, smoking, flares, etc.)andhot surfaces away fromrelease. Containspillinsmallestpossiblearea. Recoveras muchproduct as possible(e.g. by vacuuming). Stopleak if it canbedonewithout risk. Usewaterspray todispersevapors. Usecompatiblefoamtominimizevaporgenerationas needed. Spilledmaterialmay beabsorbedby anappropriateabsorbent, andthenhandledinaccordancewithenvironmentalregulations. Prevent spilledmaterialfromenteringsewers, stormdrains, otherunauthorizedtreatment ordrainagesystems andnaturalwaterways.Contact fireauthorities andappropriatefederal, stateandlocalagencies. If spillof any amount ismadeintooruponnavigablewaters, thecontiguous zone, oradjoiningshorelines, contact the

NationalResponseCenterat 1-800-424-8802. Forhighway orrailways spills, contact Chemtrec at1-800-424-9300.Eliminateallignitionsources (nosmoking, flares, sparks, orflames inimmediatearea). Localauthorities shouldbeadvisedif significant spillages cannot becontained. Stopleak if youcandosowithout risk. This materialis awaterpollutant andshouldbepreventedfromcontaminatingsoilorfromenteringsewageanddrainagesystems andbodies of water. Dikethespilledmaterial,wherethis is possible. Prevent entry intowaterways, sewers, basements orconfinedareas.Usenon-sparkingtools andexplosion-proof equipment.

SmallSpills: Absorbspillwithvermiculiteorotherinert material, thenplaceinacontainerforchemicalwaste. Cleansurfacethoroughly toremoveresidualcontamination. This materialanditscontainermust bedisposedof as hazardous waste.

Otherinformation

7.HandlingandStorage

Handling

Storage

LargeSpills: Useanon-combustiblemateriallikevermiculite, sandorearthtosoak uptheproduct

andplaceintoacontainerforlaterdisposal. Prevent product fromenteringdrains. Donot allowmaterialtocontaminategroundwatersystem. Shouldnot bereleasedintotheenvironment.

Cleanupinaccordancewithallapplicableregulations.

Eliminatesources of ignition. Avoidspark promoters. Ground/bondcontainerandequipment.Thesealonemay beinsufficient toremovestatic electricity.Wearpersonalprotectiveequipment. Avoidbreathingdust/fume/gas/mist/vapors/spray. Avoidcontact witheyes, skin, andclothing. Donot tasteorswallow. Avoidprolongedexposure. Useonlywithadequateventilation. Washthoroughly afterhandling. Theproduct is combustible, and heatingmay generatevapors whichmay formexplosivevapor/airmixtures. DO NOT handle, storeoropennearanopenflame, sources of heat orsources of ignition. Protect materialfromdirect sunlight.Takeprecautionary measures against static discharges. Allequipment usedwhenhandlingtheproduct must begrounded. Usenon-sparkingtools andexplosion-proof equipment. Whenusing, donot eat, drink orsmoke. Avoidreleasetotheenvironment.

Flammableliquidstorage. Donot handleorstorenearanopenflame, heat orothersources of


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ZOUAIMIA L33425UTMBROOKLYN OCEANPARKWAY NEWYORK CITY USA

VRT-ULTRAMAR CANADA

ignition. This materialcanaccumulatestatic chargewhichmay causespark andbecomeanignitionsource. Thepressureinsealedcontainers canincreaseundertheinfluenceof heat. Keepcontainertightly closedinacool, well-ventilatedplace. Keepaway fromfood, drink andanimalfeedingstuffs. Keepout of thereachof children.

DIESEL FUELS3541 Version #: 03 Revison date: 25-June-2013 Print date: 25-June-2013 3 / 13



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ZOUAIMIA L 33425UTM BROOKLYNOCEAN PARKWAY NEW YORK CITYUSA

VRT-ULTRAMAR

CANADA\Form

Vaporandaerosol.3541 Version #: 03 Revison date: 25-June-2013 Print date: 25-June-2013 4 / 13



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ZOUAIMIA L 33425UTM BROOKLYNOCEAN PARKWAY NEW YORK CITYUSAVRT-ULTRAMAR CANADAValue3500mg/m3

1000ppm1760mg/m3


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3541 Version #: 03 Revison date: 25-June-2013 Print date: 25-June-2013 5 /

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Material Safety Data Sheet.docx Alerrrr