Material Safety Data Sheet - img0.fastenal.com MATERIAL SAFETY DATA SHEET 3M Fire Protection Products Retail POS Kit 03/30/2004 Page 2 of 2

3M MATERIAL SAFETY DATA SHEET 3M Fire Protection Products Retail POS Kit 03/30/2004

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Material Safety Data Sheet

Copyright, 2004, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properlyutilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement isobtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profitthereon.

PRODUCT NAME: 3M Fire Protection Products Retail POS Kit MANUFACTURER: 3M

DIVISION: Consumer Safety and Light Management

ADDRESS: 3M Center St. Paul, MN 55144-1000

EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)

Issue Date: 03/30/2004 Supercedes Date: Initial Issue

Document Group: 19-1014-0

ID Number(s):

98-0400-5494-6

This product is a kit or a multipart product which consists of multiple, independently packaged components. An MSDS foreach of these components is included. Please do not separate the component MSDSs from this cover page. The documentnumbers of the MSDSs for components of this product are:

17-8259-8, 16-3772-7, 16-0641-7, 09-5451-1, 09-2236-9

No revision information is available.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTYOF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OFTRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method ofuse or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquelywithin the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for aparticular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer mayhave resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.

3M MATERIAL SAFETY DATA SHEET 3M Fire Protection Products Retail POS Kit 03/30/2004

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MATERIAL SAFETY DATA SHEET 3M Firedam 150+ Caulk, Blue 05/05/10

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Copyright, 2010, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon.

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: 3M Firedam 150+ Caulk, Blue - DiscontinuedMANUFACTURER: 3M

DIVISION: Building & Commercial Services Division

ADDRESS: 3M CenterSt. Paul, MN 55144-1000


Issue Date: 05/05/10Supercedes Date: 02/07/08


Product Use:Intended Use: Fire ProtectionSpecific Use: Caulk used as a passive fire protection.

SECTION 2: INGREDIENTS

Ingredient C.A.S. No. % by WtCalcium Carbonate 1317-65-3 55 - 65Polyvinyl Acetate 107175-81-5 30 - 35Acrylic Emulsion 70677-00-8 7 - 12Mineral Spirits 64742-88-7 5 - 10Water 7732-18-5 5 - 10Plasticizer 27138-31-4 3 - 5Ethylene Glycol 107-21-1 1 - 3Titanium Dioxide 13463-67-7 1 - 3Surfactant 9016-45-9 < 1pH Stabilizer 124-68-5 0 - 1Colorant 147-14-8 < 1

SECTION 3: HAZARDS IDENTIFICATION

3.1 EMERGENCY OVERVIEW


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Specific Physical Form: PasteOdor, Color, Grade: Blue paste with low odorGeneral Physical Form: Solid Immediate health, physical, and environmental hazards: May cause target organ effects.

3.2 POTENTIAL HEALTH EFFECTS

Eye Contact:Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision.

Skin Contact:Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.

Inhalation:Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain.

May be absorbed following inhalation and cause target organ effects.

Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May be absorbed following ingestion and cause target organ effects.

Target Organ Effects:Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea,

slowed reaction time, slurred speech, giddiness, and unconsciousness.

Prolonged or repeated exposure may cause: Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.

SECTION 4: FIRST AID MEASURES

4.1 FIRST AID PROCEDURES

The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed.

Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention.


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Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.

Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.

If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention.

SECTION 5: FIRE FIGHTING MEASURES

5.1 FLAMMABLE PROPERTIES

Autoignition temperature Not ApplicableFlash Point Not ApplicableFlammable Limits - LEL Not ApplicableFlammable Limits - UEL Not ApplicableOSHA Flammability Classification: Not Applicable

5.2 EXTINGUISHING MEDIANon-combustible. Choose material suitable for surrounding fire.

5.3 PROTECTION OF FIRE FIGHTERS

Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).

Unusual Fire and Explosion Hazards: Not applicable.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Accidental Release Measures: Ventilate the area with fresh air.Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Collect as much of the spilled material as possible. Clean up residue with detergent and water.

In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations.

SECTION 7: HANDLING AND STORAGE

7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. For industrial or professional use only. Avoid contact with oxidizing agents.


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7.2 STORAGEStore away from oxidizing agents. Store in a cool, dry place.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 ENGINEERING CONTROLSUse with appropriate local exhaust ventilation. Use in a well-ventilated area.

8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)

8.2.1 Eye/Face ProtectionAvoid eye contact.The following eye protection(s) are recommended: Indirect Vented Goggles.

8.2.2 Skin ProtectionAvoid skin contact. Avoid prolonged or repeated skin contact.

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl RubberFluoroelastomer (Viton)Neoprene.

8.2.3 Respiratory ProtectionUnder normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection.

8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

8.3 EXPOSURE GUIDELINES

Ingredient Authority Type Limit Additional InformationEthylene Glycol ACGIH CEIL, as aerosol 100 mg/m3 Ethylene Glycol CMRG CEIL, as vapor and

aerosol100 mg/m3

Calcium Carbonate OSHA TWA, respirable fraction

5 mg/m3

Calcium Carbonate OSHA TWA, as total dust 15 mg/m3 Mineral Spirits CMRG TWA 100 ppm Titanium Dioxide ACGIH TWA 10 mg/m3 Titanium Dioxide CMRG TWA, as respirable

dust5 mg/m3

Titanium Dioxide OSHA TWA, as total dust 15 mg/m3

SOURCE OF EXPOSURE LIMIT DATA:ACGIH: American Conference of Governmental Industrial HygienistsCMRG: Chemical Manufacturer Recommended GuidelineOSHA: Occupational Safety and Health AdministrationAIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)


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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Specific Physical Form: PasteOdor, Color, Grade: Blue paste with low odorGeneral Physical Form: Solid Autoignition temperature Not ApplicableFlash Point Not ApplicableFlammable Limits - LEL Not ApplicableFlammable Limits - UEL Not Applicable

Specific Gravity 1.45 [Ref Std: WATER=1]

Melting point No Data Available

Volatile Organic Compounds 14.51 % weight Percent volatile 24 %VOC Less H2O & Exempt Solvents 246.1 g/l

SECTION 10: STABILITY AND REACTIVITY

Stability: Stable.

Materials and Conditions to Avoid: 10.1 Conditions to avoidNone known

10.2 Materials to avoidStrong oxidizing agents

Hazardous Polymerization: Hazardous polymerization will not occur.

Hazardous Decomposition or By-Products

Substance ConditionCarbon monoxide During CombustionCarbon dioxide During Combustion

SECTION 11: TOXICOLOGICAL INFORMATION

Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components.


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SECTION 12: ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATION

Not determined.

CHEMICAL FATE INFORMATION

Not determined.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Method: Dispose of waste product in a sanitary landfill. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste.

EPA Hazardous Waste Number (RCRA): Not regulated

Since regulations vary, consult applicable regulations or authorities before disposal.

SECTION 14:TRANSPORT INFORMATION

ID Number(s):98-0400-5569-5, 98-0400-5577-8, 98-0400-5580-2, 98-0400-5581-0, 98-0400-5582-8

Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material.

SECTION 15: REGULATORY INFORMATION

US FEDERAL REGULATIONSContact 3M for more information.

311/312 Hazard Categories:Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes

Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA):

Ingredient C.A.S. No % by WtEthylene Glycol 107-21-1 1 - 3

STATE REGULATIONSContact 3M for more information.


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CHEMICAL INVENTORIESThe components of this product are in compliance with the chemical notification requirements of TSCA.

Contact 3M for more information.

INTERNATIONAL REGULATIONSContact 3M for more information.

WHMIS: Hazardous

This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.

SECTION 16: OTHER INFORMATION

NFPA Hazard ClassificationHealth: 2 Flammability: 0 Reactivity: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities.

HMIS Hazard ClassificationHealth: 2 Flammability: 0 Reactivity: 0 Protection: X - See PPE section.

Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and Coatings Association (NPCA).

Reason for Reissue: Added new sku

Revision Changes:Section 1: Product use information was modified.Copyright was modified.Section 7: Handling information was modified.Section 8: Engineering controls information was modified.Section 8: Skin protection phrase was modified.Section 8: Eye/face protection information was modified.Section 8: Skin protection - recommended gloves information was modified.Section 1: Trade name status was modified.


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Section 14: ID Number(s) Template 1 was modified.Section 8: Exposure guidelines ingredient information was modified.Section 10.1 Conditions to avoid heading was added.Section 10.2 Materials to avoid heading was added.Section 6: Personal precautions information was added.Section 6: Environmental procedures information was added.Section 6: Methods for cleaning up information was added.Section 10: Materials to avoid physical property was added.Section 10: Conditions to avoid physical property was added.Section 6: Release measures information was deleted.Section 10: Materials and conditions to avoid physical property was deleted.Section 8: Exposure guidelines legend was deleted.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.

3M MSDSs are available at www.3M.com

MATERIAL SAFETY DATA SHEET 3M Brand Fire Barrier CP-25WB+ 04/01/10

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PRODUCT NAME: 3M Brand Fire Barrier CP-25WB+ MANUFACTURER: 3M






Product Use:Intended Use: Fire ProtectionSpecific Use: Used as Firestop in buildings.


Ingredient C.A.S. No. % by WtZINC BORATE 2335 138265-88-0 15 - 40Polymer Trade Secret 10 - 30Water 7732-18-5 10 - 30Sodium Silicate 1344-09-8 10 - 30Ethylhexyldiphenyl Phosphate 1241-94-7 3 - 7Iron Oxide 1309-37-1 1 - 5Polyethylene Glycol 25322-68-3 1 - 5OXIDE GLASS CHEMICALS 65997-17-3 1 - 3



Specific Physical Form: PasteOdor, Color, Grade: Red with negligible odorGeneral Physical Form: Solid


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Immediate health, physical, and environmental hazards:



Skin Contact:Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.


Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.

May be harmful if swallowed.


Target Organ Effects:Prolonged or repeated exposure may cause:

Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.





Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse.


If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never


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give anything by mouth to an unconscious person. Get medical attention.










Accidental Release Measures: Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode.Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible.Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Collect as much of the spilled material as possible. Clean up residue.



7.1 HANDLINGFor industrial or professional use only. Avoid eye contact with dust or airborne particles. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.

7.2 STORAGEStore away from areas where product may come into contact with food or pharmaceuticals. Store in a cool, dry place.


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8.1 ENGINEERING CONTROLSUse in a well-ventilated area.


8.2.1 Eye/Face ProtectionAvoid eye contact.The following eye protection(s) are recommended: Indirect Vented Goggles.

8.2.2 Skin ProtectionAvoid skin contact.

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl RubberNeoprene.




Ingredient Authority Type Limit Additional InformationIron Oxide ACGIH TWA, respirable

fraction5 mg/m3

Iron Oxide OSHA TWA, as fume 10 mg/m3 OXIDE GLASS CHEMICALS 3M TWA, as dust 10 mg/m3 Polyethylene Glycol AIHA TWA, as particulate 10 mg/m3



Specific Physical Form: PasteOdor, Color, Grade: Red with negligible odorGeneral Physical Form: Solid Autoignition temperature Not ApplicableFlash Point Not ApplicableFlammable Limits - LEL Not ApplicableFlammable Limits - UEL Not Applicable


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Melting point No Data Available

Solubility in Water CompleteVolatile Organic Compounds < 1 % weight VOC Less H2O & Exempt Solvents < 1 g/l


Stability: Stable.

Materials and Conditions to Avoid: 10.1 Conditions to avoidNone known

10.2 Materials to avoidNone known



Substance ConditionCarbon monoxide Not SpecifiedCarbon dioxide Not SpecifiedOxides of Phosphorus Not Specified





Not determined.



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Not determined.


Waste Disposal Method: For quantities <100 lbs. (50kg): dispose of waste product in a sanitary landfill. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste.




ID Number(s):42-0016-4710-8, 42-0016-4715-7, 42-0016-4716-5, 98-0400-5380-7, 98-0400-5381-5, 98-0400-5382-3, 98-0400-5383-1, 98-0400-5406-0, 98-0400-5456-5, 98-0400-5463-1, 98-0400-5610-7




311/312 Hazard Categories:Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No


Ingredient C.A.S. No % by WtZINC BORATE 2335 (ZINC COMPOUNDS) 138265-88-0 15 - 40





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WHMIS: Hazardous





HMIS Hazard ClassificationHealth: 2 Flammability: 1 Reactivity: 0 Protection: X - See PPE section.

Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and Coatings Association (NPCA).

Reason for Reissue: Reissued to make corrections in tables.

Revision Changes:Section 8: Eye/face protection information was modified.Section 8: Skin protection - recommended gloves information was modified.Section 14: ID Number(s) Template 1 was modified.Section 2: Ingredient table was modified.Section 10: Materials to avoid physical property was modified.Section 10: Conditions to avoid physical property was modified.


3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may


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have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.


MATERIAL SAFETY DATA SHEET 3M Fire Barrier MP+ Stix 10/22/09

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PRODUCT NAME: 3M Fire Barrier MP+ Stix MANUFACTURER: 3M






Product Use:Intended Use: Passive fire protection in industrial applications


Ingredient C.A.S. No. % by WtZinc Borate 138265-88-0 10 - 30Styrene-Butadiene Polymer 9003-55-8 10 - 30Sodium Silicate 1344-09-8 10 - 30Petrolatum 8009-03-8 10 - 15Polybutylene 9003-29-6 7 - 13Melamine Phosphate 41583-09-9 5 - 10Glass Wool 65997-17-3 5 - 7Butadiene-Styrene-Meta-Divinylbenzene Polymer 26471-45-4 1 - 5Rayon Fiber None 1 - 5Water 7732-18-5 1 - 5Amorphous Silica 112945-52-5 1 - 54,4'-Isopropylidenediphenol-Epichlorohydrin Polymer 25068-38-6 1 - 5Alpha-Methylstyrene-Isoamylene-Piperylene Polymer 62258-49-5 1 - 5ROSIN 8050-09-7 0.1 - 1




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Specific Physical Form: PuttyOdor, Color, Grade: Red putty with negligible odorGeneral Physical Form: Solid Immediate health, physical, and environmental hazards: May cause allergic skin reaction.



Skin Contact:Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness.

Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.


Ingestion:May be harmful if swallowed.

Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.


Target Organ Effects:Prolonged or repeated exposure may cause:

Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination.






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Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse.


If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention.










Accidental Release Measures: Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode.Dispose of collected material as soon as possible.Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Clean up residue.



7.1 HANDLINGFor industrial or professional use only. Avoid skin contact. Decontaminate work surfaces frequently to avoid exposure by contact. Avoid eye contact. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.


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7.2 STORAGEStore away from areas where product may come into contact with food or pharmaceuticals.


8.1 ENGINEERING CONTROLSUse in a well-ventilated area.


8.2.1 Eye/Face ProtectionAvoid eye contact.The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.

8.2.2 Skin ProtectionAvoid skin contact.

Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber, Neoprene, Nitrile Rubber.




Ingredient Authority Type Limit Additional InformationGlass Wool 3M TWA, as dust 10 mg/m3 ROSIN ACGIH TWA Reduce

exposure to as low as possible

Sensitizer, see limit column



Specific Physical Form: PuttyOdor, Color, Grade: Red putty with negligible odorGeneral Physical Form: Solid Autoignition temperature Not ApplicableFlash Point Not ApplicableFlammable Limits - LEL Not Applicable


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Flammable Limits - UEL Not Applicable


Melting point Not ApplicableSolubility In Water No Data Available

Volatile Organic Compounds 0 % weight Kow - Oct/Water partition coef No Data AvailablePercent volatile No Data AvailableVOC Less H2O & Exempt Solvents 0 g/l


Stability: Stable.

Materials and Conditions to Avoid: 10.1 Conditions to avoidNone known 10.2 Materials to avoidNone known



Substance ConditionCarbon monoxide Not SpecifiedCarbon dioxide Not Specified





Not determined.



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Not determined.


Waste Disposal Method: For quantities <100 lbs. (50kg): dispose of waste product in a sanitary landfill. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste.




ID Number(s):42-0016-4776-9, 44-0042-9356-7, 98-0400-5417-7




311/312 Hazard Categories:Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes


Ingredient C.A.S. No % by WtZinc Borate (ZINC COMPOUNDS) 138265-88-0 10 - 30



All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS.


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Reason for Reissue: Changed SOS for RM's

Revision Changes: Not Applicable




MATERIAL SAFETY DATA SHEET 3M™ Fire Barrier Pillow and 3M™ Fire Barrier Self-Locking Pillow 01/31/2008

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This material safety data sheet (MSDS) is provided as a courtesy in response to a customer request. This product is not regulated under, and a MSDS is not required for this product by the OSHA Hazard Communication Standard (29 CFR 1910.1200) because, when used as recommended or under ordinary conditions, it should not present a health and safety hazard. However, use or processing of the product not in accordance with the product's recommendations or not under ordinary conditions may affect the performance of the product and may present potential health and safety hazards.


PRODUCT NAME: 3M™ Fire Barrier Pillow and 3M™ Fire Barrier Self-Locking Pillow MANUFACTURER: 3M






Product Use:Intended Use: Fire Protection


Ingredient C.A.S. No. % by WtExpantrol Flexible Intumescent Strips Mixture 40 - 60Fiber Mineral Wool Mixture 35 - 55Adhesive Mixture 1 - 3Plastic Film 9002-88-4 1 - 3Hook & Loop Fastner Mixture 0 - 3Tape Mixture 0 - 2



Odor, Color, Grade: Mineral fiber pillow with intumescent covering in a red plastic pillow.General Physical Form: Solid


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Immediate health, physical, and environmental hazards: The environmental properties of this product present a low environmental hazard. This product, when used under reasonable conditions and in accordance with the 3M directions for use, should not present a health hazard. However, use or processing of the product in a manner not in accordance with the product's directions for use may affect the performance of the product and may present potential health and safety hazards.


Eye Contact:No health effects are expected.

Skin Contact:No health effects are expected.

Inhalation:No health effects are expected.

Ingestion:No health effects are expected.

3.3 POTENTIAL ENVIRONMENTAL EFFECTS

This substance does not leach metals or other RCRA (Resource Conservation and Recovery Act) listed TCLP (Toxic Characteristic Leaching Procedure) hazardous substances at concentrations that would make the product a hazardous waste.




Eye Contact: No need for first aid is anticipated.

Skin Contact: No need for first aid is anticipated.

Inhalation: No need for first aid is anticipated.

If Swallowed: No need for first aid is anticipated.



Autoignition temperature No Data AvailableFlash Point No Data AvailableFlammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data AvailableOSHA Flammability Classification: Not Applicable

5.2 EXTINGUISHING MEDIAMaterial will not burn.


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Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated.



Accidental Release Measures: Not applicable.


7.1 HANDLINGThis product is considered to be an article which does not release or otherwise result in exposure to a hazardous chemical under normal use conditions.

7.2 STORAGENot applicable.


8.1 ENGINEERING CONTROLSNot applicable.


8.2.1 Eye/Face ProtectionNot applicable.

8.2.2 Skin ProtectionNot applicable. Gloves are not required.


8.2.4 Prevention of SwallowingNot applicable.


None Established


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Odor, Color, Grade: Mineral fiber pillow with intumescent covering in a red plastic pillow.

General Physical Form: Solid Autoignition temperature No Data AvailableFlash Point No Data AvailableFlammable Limits - LEL No Data AvailableFlammable Limits - UEL No Data Available

Specific Gravity No Data Available

Solubility in Water NilPercent volatile 0 %VOC Less H2O & Exempt Solvents 0 g/l


Stability: Stable.

Materials and Conditions to Avoid: None known



Substance ConditionCarbon monoxide Not SpecifiedCarbon dioxide Not Specified

Hazardous Decomposition: Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous decomposition products may occur as a result of oxidation, heating, or reaction with another material.





Not applicable.


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Not applicable.


Waste Disposal Method: Dispose of waste product in a sanitary landfill. As a disposal alternative, incinerate in an industrial or commercial facility.




ID Number(s):98-0400-5421-9, 98-0400-5422-7, 98-0400-5423-5, 98-0400-5472-2, 98-0400-5473-0, 98-0400-5474-8




311/312 Hazard Categories:Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - No Delayed Hazard - No


CHEMICAL INVENTORIESThis product is an article as defined by TSCA regulations, and is exempt from TSCA Inventory listing requirements.



ADDITIONAL INFORMATIONProduct is RoHS Compliant



NFPA Hazard Classification


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Health: 0 Flammability: 0 Reactivity: 0 Special Hazards: None


HMIS Hazard ClassificationHealth: 0 Flammability: 0 Reactivity: 0 Protection: E

Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings Association (NPCA).

Reason for Reissue: The MSDS has been revised because 3M has adopted the 16-section ANSI/ISO format. The potential hazards of the product have not changed. We encourage you to reread the MSDS and review the information.

Revision Changes:Section 1: Product name was modified.Section 1: Product use information was modified.Section 1: Division name was modified.Copyright was modified.Page Heading: Product name was modified.Section 9: Property description for optional properties was modified.Section 14: ID Number Heading Template 1 was added.Section 14: ID Number(s) Template 1 was added.Section 2: Ingredient table was added.Section 8: Exposure guidelines information - none - was added.




3M MATERIAL SAFETY DATA SHEET 3M FireBarrier(TM) Sealant IC 15 WB 03/31/2006

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Copyright, 2006, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properlyutilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement isobtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profitthereon.


PRODUCT NAME: 3M FireBarrier(TM) Sealant IC 15 WB - DiscontinuedMANUFACTURER: 3M

DIVISION: Building Safety Solutions Dept

ADDRESS: 3M Center St. Paul, MN 55144-1000




Product Use:Specific Use: Fire Barrier Sealant


Ingredient C.A.S. No. % by Wt CALCIUM CARBONATE 1317-65-3 35 - 45 WATER 7732-18-5 18 - 28 COPOLYMER Unknown 17 - 27 HYDRATED ZINC BORATE 138265-88-0 3 - 7 SODIUM SILICATE 1344-09-8 3 - 7 2-ETHYLHEXYLDIPHENYL PHOSPHATE 1241-94-7 1 - 5 ZINC BORATE 1332-07-6 0.5 - 1.5



Specific Physical Form: Viscous LiquidOdor, Color, Grade: Light yellow viscous liquid with a mild odorGeneral Physical Form: LiquidImmediate health, physical, and environmental hazards: May cause severe eye irritation. May cause severe skin irritation.


Eye Contact:


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Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, andimpaired vision.

Skin Contact:Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.

Inhalation:Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and noseand throat pain.

Ingestion:Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting.



The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices arefollowed.

Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.

Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medicalattention. Wash contaminated clothing and clean shoes before reuse.


If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconsciousperson. Get immediate medical attention.



Autoignition temperature No Data Available Flash Point > 220 ºF [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available OSHA Flammability Classification: Not Applicable

5.2 EXTINGUISHING MEDIAMaterial will not burn. Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam).

5.3 PROTECTION OF FIRE FIGHTERSSpecial Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus(SCBA).

Unusual Fire and Explosion Hazards: Not applicable. No unusual fire or explosion hazards are anticipated. Non-flammable:ordinary combustible material.

Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decompositioninformation.


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Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for moreinformation on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should becleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanicalventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignitionsource and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drainsand build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover withbentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry.Collect as much of the spilled material as possible. Clean up residue with detergent and water. Collect the resulting residuecontaining solution. Place in a metal container approved for transportation by appropriate authorities. Seal the container. Dispose ofcollected material as soon as possible.

In the event of a release of this material, the user should determine if the release qualifies as reportable according tolocal, state, and federal regulations.


7.1 HANDLINGDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid breathing of vapors,mists or spray. Avoid prolonged or repeated skin contact. Avoid eye contact with vapors, mists, or spray. Keep out of the reach ofchildren. For industrial or professional use only. Use general dilution ventilation and/or local exhaust ventilation to control airborneexposures to below Occupational Exposure Limits. If ventilation is not adequate, use respiratory protection equipment.

7.2 STORAGEStore under normal warehouse conditions.


8.1 ENGINEERING CONTROLSUse with appropriate local exhaust ventilation.


8.2.1 Eye/Face ProtectionAvoid eye contact. Avoid eye contact with vapors, mists, or spray.

8.2.2 Skin ProtectionGloves not normally required. Avoid prolonged or repeated skin contact.

8.2.3 Respiratory ProtectionUnder normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoidbreathing of vapors, mists or spray.

8.2.4 Prevention of SwallowingDo not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable.


Ingredient Authority Type Limit Additional Information


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CALCIUM CARBONATE ACGIH TWA 10 mg/m3 CALCIUM CARBONATE OSHA TWA, respirable 5 mg/m3 Table Z-1 CALCIUM CARBONATE OSHA TWA, as total dust 15 mg/m3 Table Z-1 POLYETHYLENE GLYCOLS AIHA TWA, as aerosol 10 mg/m3

SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)


Specific Physical Form: Viscous Liquid Odor, Color, Grade: Light yellow viscous liquid with a mild odor General Physical Form: Liquid Autoignition temperature No Data Available Flash Point > 220 ºF [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available Boiling point >=95 ºF Density No Data Available Vapor Density No Data Available Vapor Pressure No Data Available Specific Gravity 1.4 pH 8 - 9 Melting point No Data Available Solubility in Water Moderate Hazardous Air Pollutants No Data Available Percent volatile 20 % VOC Less H2O & Exempt Solvents No Data Available


Stability: Stable.

Materials and Conditions to Avoid: None known



Substance Condition Methane Not Specified Carbon monoxide Not Specified Carbon dioxide Not Specified Oxides of Phosphorus Not Specified


Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or itscomponents.


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Not determined.


Not determined.


Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposalalternative, dispose of waste product in a facility permitted to accept chemical waste.




ID Number(s):42-0016-4738-9, 42-0016-4739-7, 42-0016-4740-5, 98-0400-5449-0, 98-0400-5450-8, 98-0400-5451-6, 98-0400-5452-4, 98-0400-5455-7, 98-0400-5462-3

Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for thismaterial.


US FEDERAL REGULATIONS Contact 3M for more information.

311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes


Ingredient C.A.S. No % by Wt HYDRATED ZINC BORATE (ZINCCOMPOUNDS)

138265-88-0 3 - 7

ZINC BORATE (ZINC COMPOUNDS) 1332-07-6 0.5 - 1.5

STATE REGULATIONS Contact 3M for more information.

CHEMICAL INVENTORIES


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NFPA Hazard Classification Health: 1 Flammability: 0 Reactivity: 0 Special Hazards: None

National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that arepresented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on theinherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known tobe generated in significant quantities.

HMIS Hazard Classification Health: 1 Flammability: 0 Reactivity: 0 Protection: X - See PPE section.

Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. Theseratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergencysituations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and CoatingsAssociation (NPCA).

Revision Changes:Section 1: Division name was modified.Copyright was modified.Section 5: Unusual fire and explosion hazard information was modified.Section 7: Handling information was modified.Section 8: Eye/face protection phrase was modified.Section 8: Skin protection phrase was modified.Section 8: Prevention of swallowing information was modified.Section 1: Trade name status was modified.

DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTYOF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OFTRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method ofuse or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquelywithin the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for aparticular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer mayhave resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.


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