HD53 Diamond 12% DestainerMATERIAL SAFETY DATA SHEETThis MSDS is prepared in accordance with OSHA 29 CFR 1910.1200

WHMIS CLASS E: Corrosive liquid, WHMIS CLASSC: Oxidizer HCS CLASS: Corrosive Liquid

WHMIS Class D2-B Toxic Oxidizer

WHMIS (Pictograms) WHMIS (Classification) HCS

Section 1. Chemical Product and Company Identi�cationProduct Name/Trade Name Diamond 12% Destainer HD53 Code 6DBDE00Synonym Sodium Hypochlorite CAS # Not Applicable.

Validation Date Jan 21, 2015

In Case of Emergency 800-813-9621

Chemical Family N/A

Chemical Formula Na0C1

Manufacturer/Supplier Diamond Products Protective Clothing

61 Shaver St. PO BOX 1507

Brantford, ON N3T 5V6

519-759-2443

TSCA TSCA Inventory: All components listed or are exempt from

listing

DSL/NDSL All components listed unless noted elsewhere on this

MSDS

Section 2. Information on Hazardous IngredientsName CAS # % by Weight Exposure Limits LC50/LD50

Sodium Hypochlorite (as Na0C1) 7681-52-9 <13 *See Section 8 * See Section 11

Sodium Hydroxide 1310-73-2 <1 *See Section 8 * See Section 11

Section 3. Hazards Identi�cationEmergency Overview Danger! Corrosive. Causes burns to any area of contact. May be fatal if swallowed. Harmful if inhaled.

Potential Health E�ects Inhalation:

Excessive inhalation of vapors, mists or fumes may cause bronchial irritation, coughing, labored breathing

nausea, and pulmonary edema. Additional effects have included circulatory collapse and confusion,

delirium, coma.

Ingestion:

May cause erosion of the mucous membranes. Symptoms include vomiting, circulatory collapse, confusion,

coma, and death. May cause edema of pharynx, glottis, and larynx and perforation of the esophagus,

or stomach. Effects are less damaging at lower concentrations.

Skin Contact:

Contact may cause severe irritation with blistering and eczema, especially at higher concentrations.

Eye Contact:

Contact may cause severe irritation and damage, especially at higher concentrations.

Chronic Exposure: A constant irritant to the eyes and throat.

Aggravation of Pre-Existing Conditions Persons with impaired respiratory function may be more susceptible to the effects of the substance.

Carcinogenic E�ects Not classi�ed or listed by IARC, NTP, OSHA, EU and ACGIH.

Section 4. First Aid MeasuresEye Contact Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids

occasionally. Get medical attention immediately.

Skin Contact Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated

clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean

shoes before reuse.

Inhalation Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Get medical attention immediately.

Ingestion HARMFUL IF SWALLOWED. If ingested, DO NOT induce vomiting. Give large quantities of water to drink

if able to swallow. Get medical attention immediately. Never give anything by mouth to an unconscious

person.

NOTE TO PHYSICIAN: Consider oral administration of sodium thiosulfate solutions if sodium hypochlorite is ingested. Do not

administer neutralizing substances since the resultant exothermic reaction could further damage tissue.

Endotrachael intubation could be needed if glottic edema compromises the airway. For individuals with

significant inhalation exposure, monitor arterial blood gases and chest x-ray.

PC #53 Diamond 12% DestainerSection 5. Fire Fighting MeasuresProducts of Combustion Not considered to be a fire hazard. Substance releases oxygen when heated, which may increase the

severity of an existing fire. Containers may rupture from pressure build-up.

Fire Fighting Media and Instruction Use water spray to cool fire-exposed containers, to dilute liquid, and control vapor. Use any means

suitable for extinguishing surrounding fire.

Special Remarks on Fire Hazards In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing

apparatus with full facepiece operated in the pressure demand or other positive pressure mode.

Special Remarks on Explosion Hazards This solution is not considered to be an exlosion hazard.

Section 6. Accidental Release Measures

In Case of Spill or Leak Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in

Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain

and recover liquid when possible. Collect liquid in an appropriate container or absorb with an inert

material (e.g. vermiculite, dry sand, earth) and place in a chemical waste container. DO NOT use

combustable materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require

reporting spills and releases to soil, water and air in excess of reportable quantaties. The toll free

number for the US Coast Guard National Response Center is (800) 424-8802.

Personal Protection in Case of a * See Section 8

Large Spill

Section 7. Handling and StoragePrecautions Do not get in eyes, on skin or on clothing. Do not breathe mist. Do not taste or swallow. Wash thoroughly

after handling. Use only with adequate ventilation. Avoid contamination. Keep container closed. Avoid

light & heat.

Incompatability Ammonia (chloramine gas may evolve), amines, ammonium salts, aziridine, methanol, phenyl

acetonitrile, cellulose, ethyleneimine, oxidizable metals, acids, soaps, & bisulfates.

Storage Keep in tightly closed container. Store in cool, dry, well ventilated area. Protect against physical

damage. Isolate from incompatables. Containers of this material may be hazardous when empty

since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the

products.

Section 8. Exposure Controls/Personal ProtectionAirborne Exposure Limits: Sodium Hypochlorite: AIHA (WEEL) - STEL - 2 mg/m 3

Sodium Hydroxide: No Information available

OSHA Permissable Exposure Limit Sodium Hypochlorite: (PEL): 0.5 ppm (TWA), 1 ppm (STEL) as Chlorine

Sodium Hydroxide: 2 mg/m 3 Ceiling

ACGIH Threshold Limit Value (TLV): Sodium Hypochlorite: 1 ppm (TWA), 3 ppm (STEL) as Chlorine

Sodium Hydroxide: 2 mg/m 3 Ceiling

Personal Protection Eyes Chemical Safety Goggles and/or full face shield where splasing is possible. Maintain

eye wash station and quick-drench facilities in work area.

Body Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls,

as appropriate, to prevent skin contact.

Respiratory A ventilation system of local and/or general exhaust is recommended to keep employee

exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally

preferred because it can control the emissions of the contaminant at its source, preventing

dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial

Ventilation, A manual of Recommended Practices", most recent edition for details.

If the exposure limit is exceeded, a NIOSH approved full facepiece respirator with an acid

gas cartridge may be worn up to 50 times the exposure limit or the maximum use

concentration specified by the appropriate regulatory agency or respirator supplier, which-

ever is lowest. For emergencies or instances where the exposure levels are not know, use a

full-facepiece positive-pressure, air supplied respirator. WARNING: Air purifying respirators

do not protect workers in oxygen-deficient atmospheres.

Hands Gloves - Impervious

Protective Clothing

(pictogram)

Section 9. Physical and Chemical Properties

Physical State and Appearance Liquid. Odor Chlorine-like odor

Molecular Weight 74.44

pH >10 Color Clear to Yellowish

Boiling/Condensation Point 40⁰ C (104⁰ F) Decomposes slightly

Melting/Freezing Point -15⁰F (12.5%)

Critical Temperature Not Available.

HD53 Diamond 12% DestainerInstability Temperature Not Available.

Speci�c Gravity 1.2 (12.5%)

Vapor Pressure Dependent on Concentration

Vapor Density No information found

Volatility Not Available.

VOC Not available.

Evaporation Rate Not Available.

Dispersion Properties See solubility in water.

Solubility 100% in water

The Product is: Unstable

Auto-ignition Temperature Not available.

Flash Points Not available.

Flammable Limits Not available.

Fire Hazards/Explosion Hazards Not considered to be a fire/explosion hazard. Substance may release oxygen when heated, which may

in Presence of Various Substances increase the severity of an existing fire. Containers may rupture from pressure build-up.

Section 10. Stability and Reactivity DataStability This product slowly decomposes on contact with air. Rate increases with the concentration and

temperature. Exposure to sunlight accelerates decomposition. Sodium hypochlorite becomes less

toxic with age.

Incompatability with Various Substances Ammonia (Chloramine gas may evolve), amines, ammonium salts, aziridine, methanol, phenyl

acetonitrile, cellulose, ethyleneimine, oxidizable metals, acids, soaps, and bisulfates.

AVOID: Conditions of Light, heat and above incompatibles.

Hazardous Decomposition Products This product slowly decomposes on contact with air. Rate increases with the concentration and

temperature. Exposure to sunlight accelerates decomposition. Sodium hypochlorite becomes less

toxic with age.

Section 11. Toxicological InformationRoutes of Entry Skin contact. Eye contact. Inhalation. Ingestion.

Acute E�ects on Humans

Eyes May cause severe irritation and damage, especially at higher concentrration.

Skin Contact may cause severe irritation with blistering and eczema, especially at higher

concentrations.

Inhalation Excessive inhalation of vapors, mists, or fumes may cause bronchial irritation, coughing,

labored breathing, nausea, and pulmonary edema. Additional effects have included

circulatory collapse and confusion, delirium, coma

Ingestion May cause erosion of the mucous membranes. Symptoms may include vomiting, circulatory

collapse, confusion, coma and death. May cause edema of pharynx, glottis, and larynx and

perforation of the esophagus or stomach. Effects are less damaging at lower concentration.

Chronic E�ects on Humans May cause constant irritation to the eyes and throat. Excessive inhalation/ingestion may cause bronchial

irritation, coughing, labored breathing, nausea, vomiting, pulmonary edema, circulatory collapse, edema

of pharynx, glottis, larynx, and perforation of the esophagus or stomach, confusion, delirium, coma and

death.

Aggravation of Pre-Existing Conditions:

Persons with impaired respiratory function may be more susceptible to the effects of this substance.

Toxicity to Animals *See below for more information.

Additional Toxicological Information Sodium Hypochlorite:

No LD50/LC50 information found relating to normal routes of occupational exposure.

Investigated as a tumorigen and mutagen. Irritation data: eye, rabbit, 10 mg - Moderate

Sodium Hydroxide:

Irritation data: skin, rabbit, 500 mg/24 H severe, eye rabbit: 50 ug/24H severe,

Investigated as a mutagen.

Cancer Lists:

** NTP Carcinogen **

Ingredient Known Anticipated IARC Category

Sodium Hypochlorite (as Na0C1) No No 3

(7681-52-9)

Sodium Hydroxide (1310-73-2) No No none

Section 12. Ecological InformationEcotoxicity No information found.

Section 13. Disposal ConsiderationsWaste Information Dilute with water and flush to sewer if local ordinances allow, otherwise, whatever cannot be saved

for recovery or recycling should be managed in an appropriate and approved waste disposal facility.

Processing, use or contamination of this product may change the waste management options. State

and local disposal regulations may differ from federal disposal regulations.

HD53 Diamond 12% Destainer

Dispose of container and unused contents in accordance with federal, state and local requirements.

Waste Stream Not available

Section 14. Transport InformationDOT (U.S.A.)

(Pictograms)

TDG Classi�cation 8

PIN UN, Proper Shipping Shipping name: Hypochlorite Solution, UN1791, PG III

Name, PG

Maritime Transportation Not available.

Special Provisions for Transport Not available.

Section 15. Other Regulatory Information and Pictograms

WHMIS (Classi�cation) WHMIS CLASS E: Corrosive Liquid., WHMIS CLASS C: Oxidizer

WHMIS CLASS D-2B: Toxic

Chemical Inventory Status Part 1

Ingredient TSCA EC JAPAN AUSTRALIASodium Hypochlorite (as Na0C1) (7681-52-9) Yes Yes Yes Yes

Sodium Hydroxide (1310-73-2) Yes Yes Yes Yes

Chemical Inventory Status Part 2 CANADAIngredient KOREA DSL NDSL PHIL

Sodium Hypochlorite (as Na0C1) (7681-52-9) Yes Yes No Yes

Sodium Hydroxide (1310-73-2) Yes Yes No Yes

Federal, State & International Regulations Part 1 **SARA 302** **SARA 313**Ingredient RQ TPQ LIST CHEMICAL CATG.

Sodium Hypochlorite (as Na0C1) (7681-52-9) No No No No

Sodium Hydroxide (1310-73-2) No No No No

Federal, State & International Regulations Part 2 RCRA TSCAIngredient CERCLA 261.33 8 (d)

Sodium Hypochlorite (as Na0C1) (7681-52-9) 100 No No

Sodium Hydroxide (1310-73-2) 1000 No No

Chemical Weapons Convention: No TSCA 12(b): No CDTA: No

SARA 311/312: Acute: Yes Chronic: No Fire: No Pressure: No

Reactivity: No (Mixture/Liquid)

Hazardous Material Health 3 National Fire Flammability

Information System Flammability 0 Protection

(U.S.A.) Reactivity 1 Association Health Reactivity

(U.S.A.)

The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazard

MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product.

Section 16. Other InformationPrepared by Hawco Products Ltd. Verified by A White

Information Contact Hawco Products Ltd./Diamond Products

61 Shaver St. PO BOX 1507

Brantford, ON N3T 5V6

Notice to Reader

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any

liability whatsoever for the accuracy or completeness of the information contained herein.

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with

caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.

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