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7/31/2019 Magnetical Behavior
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MAGNETICAL BEHAVIOR
All materials of the world respond to the presence of a magnetic field, there is no
"non-magnetic" materials, due to the fact that everything is composed of atoms
whose electrons revolve around these, similarly in which one exhale carrier current
generates a magnetic field.
The way in which we measure the response between electrons and atoms
determines if this is very magnetic or little magnetic.
Clasification ofMagnetic
Materials
Ferromagnetic
Ferrimagnetic
Antiferromagnetic
Paramagnetic
Superparamagnetic
Diamagnetic
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We can find the magnetic behavior of the materials in their atoms.
The orbital motion of the electron around the nucleus and the spin of the electron
around its own axis cause separate magnetic moments.
The nucleus of the atoms also has a spin, however the magnetic moment is much
lower compared to the electron, so it is neglected.
The magnetic moment of an electron due to its rotation is known as the Bohr
magneton.
MAGNETICAL BEHAVIOR
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We can consider that the electrons in materials are like elementary magnets. If the
magnetic moments due to electrons could be aligned in the same direction, the Earth
would be a magnetic site. Fortunately this is not the case, since the magnetic moments
associated with the spin of the electron and its orbital motion are cancelled in most
materials, leaving only a few materials that are magnetic.
We describe several effects that make the majority of the materials 'not magnetic:
The Pauli exclusion principle: a single orbital can be occupied only by two electrons with opposite
spins (represented upward and the other downward ).
Cancellation between the orbital moments: in a layer fulfilled the spin and orbital moments are
cancelled with each other.
The cancellation of the magnetic moments for some individual atoms when these forms crystalline
structures
MAGNETICAL BEHAVIOR
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MAGNETIZATION, PERMEABILITY AND THE
MAGNETIC FIELD
When a electric current is passed by a coil it produces a magnetic field (h); the intensity of
the field is given by:
n = number of turns
l = coil length
I = current
When a magnetic field is applied in a vacuum, it induces
magnetic flux lines. The set of lines of flux are called
density flow or inductance,and is related to the magnetic
field by means of:
B = inductance
H = magnetic field
0 = magnetic permeability of vacuum
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When we place a material within the magnetic field, the magnetic-flux density is
determined by the manner in which induced and permanent magnetic dipoles interactwith the field. The flux density now is:
= permeability of the material in the field
If the magnetic moments reinforce the applied field, then > 0 a greater number oflines of flux that can accomplish work are created, and the magnetic field is magnified.
If the magnetic moments oppose the field, however,0 > .
We can describe the influence of the magnetic material by the relative permeabilityr ,
where:
MAGNETIZATION, PERMEABILITY AND THE
MAGNETIC FIELD
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The magnetization M represents the increase in the inductance due to the core
material, so we can rewrite the equation for inductance as
The magnetic susceptibility m
, which is the ratio between magnetization and the
applied field, gives the amplification produced by the material:
Both r and m refer to the degree to which the material enhances the magnetic field
and are therefore related by
For ferromagnetic and ferrimagnetic materials, the terms r y m depends on the
applied field (H) in wich 0M >>
0H. Thus, for these materials:
MAGNETIZATION, PERMEABILITY AND THE
MAGNETIC FIELD
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DIAMAGNETIC, PARAMAGNETIC,
FERROMAGNETIC, FERRIMAGNETIC, AND
SUPERPARAMAGNETIC MATERIALS
Diamagnetismo: A magnetic field acting on any atom induces
a magnetic dipole for the entire atom by influencing the
magnetic moment caused by the orbiting electrons. These
dipoles oppose the magnetic field, causing the magnetization
to be less than zero.
Paramagnetismo: When materials have unpaired electrons,a net magnetic moment due to electron spin is associated
with each atom. When a magnetic field is applied, the
dipoles align with the field, causing a positive magnetization.
Because the dipoles do not interact, extremely large
magnetic fields are required to align all of the dipoles. In
addition, the effect is lost as soon as the magnetic field is
removed.
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Ferromagnetismo: Ferromagnetic behavior is caused by the
unfilled energy levels in the 3dlevel of iron, nickel, and
cobalt. Similar behavior is found in a few other materials,
including gadolinium (Gd). In ferromagnetic materials, the
permanent unpaired dipoles easily line up with the imposed
magnetic field due to the exchange interaction, or mutual
reinforcement of the dipoles. Above the Curie temperature,
ferromagnetic materials behave as paramagnetic materials.
Antiferromagnetismo: In materials such as manganese,
chromium, MnO, and NiO, the magnetic moments producedin neighboring dipoles line up in opposition to one another in
the magnetic field, even though the strength of each
dipole is very high. These materials are antiferromagnetic
and have zero magnetization.
DIAMAGNETIC, PARAMAGNETIC,
FERROMAGNETIC, FERRIMAGNETIC, AND
SUPERPARAMAGNETIC MATERIALS
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Ferrimagnetism: In ceramic materials, different ions
have different magnetic moments. In a magnetic
field, the dipoles of cationA may line up with the
field, while dipoles of cation B oppose the field.
Because the strength or number of dipoles is not
equal, a net magnetization results.
Superparamagnetism: When the grain size of
ferromagnetic and ferrimagnetic materials falls
below a certain critical size, these materials behave
as if they are paramagnetic. The magnetic dipole
energy of each particle becomes comparable to
the thermal energy. This small magnetic moment
changes its direction randomly (as a result of the
thermal energy).
DIAMAGNETIC, PARAMAGNETIC,
FERROMAGNETIC, FERRIMAGNETIC, AND
SUPERPARAMAGNETIC MATERIALS
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DIAMAGNETIC, PARAMAGNETIC,
FERROMAGNETIC, FERRIMAGNETIC, AND
SUPERPARAMAGNETIC MATERIALS
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DOMAIN STRUCTURE AND THE HISTERESIS
LOOP
Within the single crystal or polycrystalline structure of a ferromagnetic or ferrimagnetic
material, a substructure composed of magnetic domains is produced, even in theabsence of an external field. This spontaneously happens because the presence of many
domains in the material, arranged so that the net magnetization is zero, minimizes the
magnetostatic energy. Domains are regions in the material in which all of the dipoles are
aligned in a certain direction. In a material that has never been exposed to a magnetic
field, the individual domains have a random orientation. Application of a magnetic field
(poling) will coerce many of the magnetic domains to align with the magnetic fielddirection.
Boundaries, called Bloch walls, separate the individual magnetic domains. The Bloch
walls are narrow zones in which the direction of the magnetic moment gradually and
continuously.
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Movement of Domains in a Magnetic Field: When a magnetic field is imposed on the
material, domains that are nearly lined up with the field grow at the expense ofunaligned domains. In order for the domains to grow, the Bloch walls must move; the
field provides the force required for this movement.
Initially, the domains grow with difficulty, as it increases the intensity of the field,
domains with favourable orientation grow more easily, and at the same time, also
increases the permeability.
DOMAIN STRUCTURE AND THE HISTERESIS
LOOP
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When the field is removed, the resistance offered by the domain walls prevents
regrowth of the domains into random orientations.
As a result, many of the domains remain oriented near the direction of the original
field and a residual magnetization, known as the remanance (Mr) is present in the
material. In this case de material acts like a permanent magnet.
The magnetic field needed to bring the induced magnetization to zero is the coercivity
HC of the material. This is a microstructure-sensitive property.
If we apply a magnetic field in the opposite
direction, the domains will start to align in
the direction of the applied field, in which
the magnetization and the field form a
hysteresis loop.
DOMAIN STRUCTUREAND THE HISTERESIS
LOOP
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THE CURIE TEMPERATURE
When the temperature of a ferromagnetic or ferrimagnetic material is increased, the added
thermal energy increases the mobility of the domains, making it easier for them to become
aligned, but also preventing them from remaining aligned when the field is removed.
Consequently, saturation magnetization, remanance, and the coercive field are all reduced
at high temperatures.
If the temperature exceeds the Curie temperature (Tc), ferromagnetic or ferrimagnetic
behavior is no longer observed. Instead, the material behaves as a paramagnetic material.
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APPLICATION OF MAGNETIC
MATERIALS
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