Magnetical Behavior

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    MAGNETICAL BEHAVIOR

    All materials of the world respond to the presence of a magnetic field, there is no

    "non-magnetic" materials, due to the fact that everything is composed of atoms

    whose electrons revolve around these, similarly in which one exhale carrier current

    generates a magnetic field.

    The way in which we measure the response between electrons and atoms

    determines if this is very magnetic or little magnetic.

    Clasification ofMagnetic

    Materials

    Ferromagnetic

    Ferrimagnetic

    Antiferromagnetic

    Paramagnetic

    Superparamagnetic

    Diamagnetic

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    We can find the magnetic behavior of the materials in their atoms.

    The orbital motion of the electron around the nucleus and the spin of the electron

    around its own axis cause separate magnetic moments.

    The nucleus of the atoms also has a spin, however the magnetic moment is much

    lower compared to the electron, so it is neglected.

    The magnetic moment of an electron due to its rotation is known as the Bohr

    magneton.

    MAGNETICAL BEHAVIOR

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    We can consider that the electrons in materials are like elementary magnets. If the

    magnetic moments due to electrons could be aligned in the same direction, the Earth

    would be a magnetic site. Fortunately this is not the case, since the magnetic moments

    associated with the spin of the electron and its orbital motion are cancelled in most

    materials, leaving only a few materials that are magnetic.

    We describe several effects that make the majority of the materials 'not magnetic:

    The Pauli exclusion principle: a single orbital can be occupied only by two electrons with opposite

    spins (represented upward and the other downward ).

    Cancellation between the orbital moments: in a layer fulfilled the spin and orbital moments are

    cancelled with each other.

    The cancellation of the magnetic moments for some individual atoms when these forms crystalline

    structures

    MAGNETICAL BEHAVIOR

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    MAGNETIZATION, PERMEABILITY AND THE

    MAGNETIC FIELD

    When a electric current is passed by a coil it produces a magnetic field (h); the intensity of

    the field is given by:

    n = number of turns

    l = coil length

    I = current

    When a magnetic field is applied in a vacuum, it induces

    magnetic flux lines. The set of lines of flux are called

    density flow or inductance,and is related to the magnetic

    field by means of:

    B = inductance

    H = magnetic field

    0 = magnetic permeability of vacuum

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    When we place a material within the magnetic field, the magnetic-flux density is

    determined by the manner in which induced and permanent magnetic dipoles interactwith the field. The flux density now is:

    = permeability of the material in the field

    If the magnetic moments reinforce the applied field, then > 0 a greater number oflines of flux that can accomplish work are created, and the magnetic field is magnified.

    If the magnetic moments oppose the field, however,0 > .

    We can describe the influence of the magnetic material by the relative permeabilityr ,

    where:

    MAGNETIZATION, PERMEABILITY AND THE

    MAGNETIC FIELD

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    The magnetization M represents the increase in the inductance due to the core

    material, so we can rewrite the equation for inductance as

    The magnetic susceptibility m

    , which is the ratio between magnetization and the

    applied field, gives the amplification produced by the material:

    Both r and m refer to the degree to which the material enhances the magnetic field

    and are therefore related by

    For ferromagnetic and ferrimagnetic materials, the terms r y m depends on the

    applied field (H) in wich 0M >>

    0H. Thus, for these materials:

    MAGNETIZATION, PERMEABILITY AND THE

    MAGNETIC FIELD

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    DIAMAGNETIC, PARAMAGNETIC,

    FERROMAGNETIC, FERRIMAGNETIC, AND

    SUPERPARAMAGNETIC MATERIALS

    Diamagnetismo: A magnetic field acting on any atom induces

    a magnetic dipole for the entire atom by influencing the

    magnetic moment caused by the orbiting electrons. These

    dipoles oppose the magnetic field, causing the magnetization

    to be less than zero.

    Paramagnetismo: When materials have unpaired electrons,a net magnetic moment due to electron spin is associated

    with each atom. When a magnetic field is applied, the

    dipoles align with the field, causing a positive magnetization.

    Because the dipoles do not interact, extremely large

    magnetic fields are required to align all of the dipoles. In

    addition, the effect is lost as soon as the magnetic field is

    removed.

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    Ferromagnetismo: Ferromagnetic behavior is caused by the

    unfilled energy levels in the 3dlevel of iron, nickel, and

    cobalt. Similar behavior is found in a few other materials,

    including gadolinium (Gd). In ferromagnetic materials, the

    permanent unpaired dipoles easily line up with the imposed

    magnetic field due to the exchange interaction, or mutual

    reinforcement of the dipoles. Above the Curie temperature,

    ferromagnetic materials behave as paramagnetic materials.

    Antiferromagnetismo: In materials such as manganese,

    chromium, MnO, and NiO, the magnetic moments producedin neighboring dipoles line up in opposition to one another in

    the magnetic field, even though the strength of each

    dipole is very high. These materials are antiferromagnetic

    and have zero magnetization.

    DIAMAGNETIC, PARAMAGNETIC,

    FERROMAGNETIC, FERRIMAGNETIC, AND

    SUPERPARAMAGNETIC MATERIALS

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    Ferrimagnetism: In ceramic materials, different ions

    have different magnetic moments. In a magnetic

    field, the dipoles of cationA may line up with the

    field, while dipoles of cation B oppose the field.

    Because the strength or number of dipoles is not

    equal, a net magnetization results.

    Superparamagnetism: When the grain size of

    ferromagnetic and ferrimagnetic materials falls

    below a certain critical size, these materials behave

    as if they are paramagnetic. The magnetic dipole

    energy of each particle becomes comparable to

    the thermal energy. This small magnetic moment

    changes its direction randomly (as a result of the

    thermal energy).

    DIAMAGNETIC, PARAMAGNETIC,

    FERROMAGNETIC, FERRIMAGNETIC, AND

    SUPERPARAMAGNETIC MATERIALS

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    DIAMAGNETIC, PARAMAGNETIC,

    FERROMAGNETIC, FERRIMAGNETIC, AND

    SUPERPARAMAGNETIC MATERIALS

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    DOMAIN STRUCTURE AND THE HISTERESIS

    LOOP

    Within the single crystal or polycrystalline structure of a ferromagnetic or ferrimagnetic

    material, a substructure composed of magnetic domains is produced, even in theabsence of an external field. This spontaneously happens because the presence of many

    domains in the material, arranged so that the net magnetization is zero, minimizes the

    magnetostatic energy. Domains are regions in the material in which all of the dipoles are

    aligned in a certain direction. In a material that has never been exposed to a magnetic

    field, the individual domains have a random orientation. Application of a magnetic field

    (poling) will coerce many of the magnetic domains to align with the magnetic fielddirection.

    Boundaries, called Bloch walls, separate the individual magnetic domains. The Bloch

    walls are narrow zones in which the direction of the magnetic moment gradually and

    continuously.

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    Movement of Domains in a Magnetic Field: When a magnetic field is imposed on the

    material, domains that are nearly lined up with the field grow at the expense ofunaligned domains. In order for the domains to grow, the Bloch walls must move; the

    field provides the force required for this movement.

    Initially, the domains grow with difficulty, as it increases the intensity of the field,

    domains with favourable orientation grow more easily, and at the same time, also

    increases the permeability.

    DOMAIN STRUCTURE AND THE HISTERESIS

    LOOP

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    When the field is removed, the resistance offered by the domain walls prevents

    regrowth of the domains into random orientations.

    As a result, many of the domains remain oriented near the direction of the original

    field and a residual magnetization, known as the remanance (Mr) is present in the

    material. In this case de material acts like a permanent magnet.

    The magnetic field needed to bring the induced magnetization to zero is the coercivity

    HC of the material. This is a microstructure-sensitive property.

    If we apply a magnetic field in the opposite

    direction, the domains will start to align in

    the direction of the applied field, in which

    the magnetization and the field form a

    hysteresis loop.

    DOMAIN STRUCTUREAND THE HISTERESIS

    LOOP

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    THE CURIE TEMPERATURE

    When the temperature of a ferromagnetic or ferrimagnetic material is increased, the added

    thermal energy increases the mobility of the domains, making it easier for them to become

    aligned, but also preventing them from remaining aligned when the field is removed.

    Consequently, saturation magnetization, remanance, and the coercive field are all reduced

    at high temperatures.

    If the temperature exceeds the Curie temperature (Tc), ferromagnetic or ferrimagnetic

    behavior is no longer observed. Instead, the material behaves as a paramagnetic material.

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    APPLICATION OF MAGNETIC

    MATERIALS

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