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You are what you eat 1 Macronutrients: fats, proteins, carbohydrates Vitamins and minerals Hydrophobic Hydrophilic Essential amino acids OH vitamin A (retinol) O OH HO O HO HO vitamin C

Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

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Page 1: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

You are what you eat

1

Macronutrients: fats, proteins, carbohydrates

Vitamins and minerals Hydrophobic Hydrophilic

Essential amino acids

OH

vitamin A (retinol)

O

OHHO

OHO

HO

vitamin C

Page 2: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Nutritional periodic Table

2

Page 3: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Essential amino acids

3

H2N

O

OHmethionine

S

H2N

O

OHvaline

H2N

O

OH

HOthreonine

H2N

O

O

phenyl alanine

H2N

O

OHleucine

H2N

O

OHisoleucine

H2N

O

OHHN tryptophan

H2N

O

OH

NH2

lysine

H2N

O

OH

N

HN

histidine

Page 4: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Essential fatty acids

HO

O

Linoleic acid

HO

O

α-Linolenic acid

Page 5: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Caloric “Need”

5

Page 6: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Energy use

6

Page 7: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Feeling the heat

7

How long would you have to walk to “burn off” a snickers bar? (271 Calories per snickers; 280 Calories per hour for walking)

271 Calories × 1 hr280 Calories

= 0.97 hr

Page 8: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

The average human needs about 2000 Cal per day. Times 4 that’s ~8000 kJ per day. 8 Snickers bars! 12 12 oz. Cokes! Want a more balanced diet? How about 6 Snickers bars and 3 Cokes?

Feeling the Heat

9 Cal/gè3500 Calories/lb

Page 9: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Feeling the heat

9

How long would you have to jog to lose a pound of fat? (3500 Calories per pound; 590 Calories per hour for jogging)

3500 Calories × 1 hr590 Calories

= 5.9 hr

Page 10: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Feeling the Heat Globally

World Population

7 billion As of October 31, 2011

China 1.3 billion (19.2%)

India 1.2 billion (17%) European Union 500 million (7.1%)

USA 315 million (4.5%) Indonesia 238 million (3.3%)

Brazil 197 million (2.8%) Pakistan 181 million (2.6%) Nigeria 170 million (2.4%)

Page 11: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Feeling the Heat Globally

Feeding the World

7 billion (7 x 109) people As of October 31, 2011

8000 kJ per person per day

3 million (3 x 106) kJ per person per year

7 billion x 3 million = 21 x 1015 kJ = 21 x 1018 J

1 Exajoule (EJ) = 1018 J

21 EJ to feed the world

21 x 1018 J x 1 tank of gas/2.1 x 109 J = 10 billion (US passenger fleet = 250 million; fill up 50 times/year = 12.5 billion)

21 x 1018 J x 1 Snickers bar/1.0 x 106 J = 21 trillion (2 billion sold in 2011)

Page 12: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Feeling the Heat Globally

Energy Use in 2011

7 billion (7 x 109) people As of October 31, 2011

21 EJ to feed the world

World 540 EJ – 100% (with 1.3 billion people) 77 GJ/person China 115 EJ – 21.3% (with 1.3 billion people) 88 GJ/person

USA 100 EJ – 18.5% (with 315 million people) 317 GJ/person EU 74 EJ – 13.8% (with 500 million people) 148 GJ/person

Former SU 45 EJ – 8.3% (with 285 million people) 158 GJ/person

Page 13: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Feeling the Heat Globally

1 kgoe – 4.4 x 107 J (not 1010 as the caption says) 1000 kgoe/person = 44 GJ/person

Based on countries shown on the graph such as Hong Kong, it is possible to substantially reduce energy consumption without necessarily decreasing quality of life.

Page 14: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Reactive Nitrogen

Dinitrogen gas is 78% of the atmosphere, but it’s inert (i.e. useless) to the vast majority of living things…reactive forms are more useful but also potentially more dangerous:

Plants can use these forms

pollutants

fertilizer

greenhouse gas

in aerosols

Page 15: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

Redox in the Nitrogen Cycle

•  1) Nitrogen fixation by soil bacteria

•  2) Nitrification

•  3) Denitrification

N(0) N(-III) N(-III)

N(III) N(V)

N(II) N(tricky) N(0)

Page 16: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

The Nitrogen Cycle

Page 17: Macronutrients: fats, proteins, carbohydrates Essential amino …franklin.chem.colostate.edu/chem103/2013/l15/nutrition... · 2013. 8. 14. · vitamin C. Nutritional periodic Table

C-BNF = reactive nitrogen created from cultivation of legumes, rice, and sugarcane

N2(g) + 3 H2(g) à 2 NH3(g) Fe cat

Haber-Bosch process:

Link Between Reactive Nitrogen and Population Growth