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    Hydrogne Internal Combustion Engine

    Mr.Yusuf Mulani

    Ms. Tejashri KhochareCollge of Engineering,

    andhar!ur.

    ABSTRACTHydrogen as a fuel in

    internal combustion engines is a

    solution for the near future to

    realize zero CO2 emissions for

    traffic applications. The

    hydrogen fuelled IC engine is

    ready for that. The storage and

    production of hydrogen, and to

    build the necessary

    infrastructure, are the real

    shortcomings in the general use

    of hydrogen in IC engines.

    Hydrogen-burning

    internal combustion engines trace

    their roots back to some of the

    ery earliest deelopments in

    internal combustion engine

    deelopment. In !"#$ Isaac de

    %ias built the first hydrogen

    internal combustion engine, and

    although the design had serious

    fla&s, it &as a more than '# years

    ahead of the deelopment of

    gasoline internal combustion

    engines (Taylor !)"'*.

    +hen talking about

    hydrogen as a fuel for traffic

    applications, most people make

    the link to fuel cells. +hy +hy

    not a more realistic link to

    internal combustion engines t

    the moment the estimation of the

    number of motor ehicles is

    about "## million. To replace

    them in a relatiely short time by

    fuel cells is impossible. There are

    seeral reasons for conerting the

    gasoline, diesel or natural gas

    engines to hydrogen fuelled

    internal combustion engines.

    This paper gies an

    oerie& of the deelopment of

    hydrogen fuelled IC engines by

    the most important car

    manufactures (ord, /0+,*.

    This oerie& indicates the

    eolution in the deelopment of

    hydrogen fuelled engines

    (different generation of engines*.

    1ey +ords climate change,

    carbon dio3ide, hydrogen,

    technological change, internal

    Combustion engines, fuel cells.

    "igure#. Hydrogen ICE

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    I. I$T%&'(CTI&$

    A. Pollution is Global issue

    E)eryday radios,

    ne*s!a!ers, tele)isions and the

    internet *arn us of energy

    e+haustion, atmos!heric

    !ollution and climate *arming.

    fter fe* hundred years of

    industrial de)elo!ment, *e are

    facing these globality !roblems

    *hile at the same time *e

    maintain a high standard of

    li)ing. The most im!ortant

    !roblem *e are faced *hich is

    *hether *e should go for

    continuous de)elo!ment or die.

    Coal, !etroleum, natural gas,

    *ater and nuclear energy are

    fi)e main energy resources that

    ha)e !layed im!ortant roles and

    ha)e been *idely used by

    human beings.

    B. Statistics of pollution

    -tatistics sho* that, the daily

    consum!tion of !etroleum all

    o)er the *orld today is /

    million barrels, of *hich about

    0/ !er cent is used in

    communications and

    trans!ortation. In this sort of

    consum!tion, about 1/23/ !er

    cent is for automobile use. That

    is to say, auto !etroleum

    constitutes about 40 !er cent of

    the *hole !etroleum

    consum!tion.

    "igure5. C&5 Emission by

    )arious sectors

    6y #77/25/4/

    In accordance *ith this

    calculation. 'aily consum!tion

    of !etroleum by automobiles all

    o)er the *orld is o)er t*o

    million tones

    t the same time as these

    fuels are burnt, !oisonous

    materials such as 0// million

    tones of carbon mono+ides

    8C&9, #// million tones:1;of

    hydro carbons 8HC9, 00/

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    million tones of carbon8C9, 0/

    million tones of nitrogen o+ides

    8$&+9 are emitted into the

    atmos!here e)ery year, se)erely

    !olluting the atmos!here.C. Global Energy in Transition

    "igure4. The age of energy gases2uid fuel essentially !etroleum

    started in about #7// and is near

    the ma+imum no*. In recent

    times gaseous fuel is becoming

    more and more im!ortant.

    "rom early times till no*, *e

    can notice that each successi)e

    fuel has more hydrogen and less

    carbon. In other *ords H?C

    ratio is increasing. &ne can

    therefore !redict that hydrogen

    is ine)itable and the H?C ratio

    *ill go to infinity.

    Technologicalinno)ation,

    rather than de!letion, is

    dri)ing these changes

    T*o moti)ators for the use

    of hydrogen as an energy carrier

    today are@ #9 To !ro)ide a

    transition strategy from

    hydrocarbon fuels to acarbonless society and 59 To

    enable rene*able energy

    sources

    II. C&M6(-TIAE%&E%TIE-

    &"HY'%&

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    im!ortant factor in determining

    *hat com!ression ratio an

    engine can use, since the

    tem!erature rise during

    com!ression is related to thecom!ression ratio. The

    tem!erature rise is sho*n by the

    E>uation@

    B 2#

    T5 T# 8A#?A59

    8#9

    =here@

    A#?A5 the com!ression ratio

    T# absolute initial tem!erature

    T5 absolute final tem!erature

    B ratio of s!ecific heats

    The tem!erature may not

    e+ceed hydrogenDs auto ignition

    tem!erature *ithout causing

    !remature ignition. Thus, the

    absolute final tem!erature limits

    the com!ression ratio. The high

    auto ignition tem!erature of

    hydrogen allo*s larger

    com!ression ratios to be used in

    a hydrogen engine than in a

    hydrocarbon engine.

    C. ig! Flame Speed

    Hydrogen has high flame

    s!eed at stoichiometric ratios.

    (nder these conditions, the

    hydrogen flame s!eed is nearly

    an order of magnitude higher

    8faster9 than that of gasoline.

    This means that hydrogen

    engines can more closely

    a!!roach the

    thermodynamically ideal engine

    cycle. t leaner mi+tures,ho*e)er, the flame )elocity

    decreases significantly.

    ". ig! "iffusi#ity

    Hydrogen has )ery high

    diffusi)ity. This ability to

    dis!erse in air is considerably

    greater than gasoline and is

    ad)antageous for t*o mainreasons. "irstly, it facilitates the

    forma2tion of a uniform mi+ture

    of fuel and air

    E. Clean ydrogen Economy

    CLEAN HYDROGEN ECONOMY FOR THE FUTURE

    Hydrogen production

    H2 (ga!

    H2 (co"preed! H2 (#i$uid! H (o#id c%e"ica#!

    Hydrogen torage

    Hydrogen uti#i&ation

    E %ig%'preure

    cryogenic tan E c%e"ica# reaction

    H2)O2 Fue# ce##*C or Hy+rid engine

    ,ero-e"iion .e%ic#e

    III. HY'%&

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    A. Engine "esign

    The most

    effecti)e

    means of

    controlling !re2ignition and

    FnocF is to re2design the engine

    for hydrogen

    use, s!ecifically the

    "igure. Hy2I.C E

    combustion chamber

    nd the cooling system. disF2

    sha!ed combustion chamber

    8*ith a flat !iston and chamber

    ceiling9 can be used to reduce

    turbulence *ithin the chamber.

    The disF sha!e hel!s, to

    !roduce lo* radial and

    tangential )elocity com!onents

    and does not am!lify inlet s*irl

    during com!ression. -ince

    unburned hydrocarbons are not

    a concern in hydrogen engines,

    a large bore2to2stroFe ratio can

    be used *ith this engine. To

    accommodate the *ider range

    of flame s!eeds that occur o)er

    a greater range of e>ui)alence

    ratios, t*o s!arF !lugs are

    needed. The cooling system

    must be de2signed to !ro)ide

    uniform flo* to all locations

    that need cooling.

    B. Fuel "eli#ery system

    da!ting or re2designing

    the fuel deli)ery system can be

    effecti)e in reducing or

    eliminating !re2ignition.

    Hydrogen fuel deli)ery

    system can be broFen do*n into

    three main ty!es@ centralinjection 8or Gcarbureted9, !ort

    injection and direct injection.

    Central and !ort fuel deli)ery

    systems injection forms the

    fuel2air mi+ture during the

    intaFe stroFe. In the case of

    central injection or a carburetor,

    the injection is at the inlet of the

    air intaFe manifold. In the case

    of !ort injection, itis injected at

    the inlet !ort.

    C. Central $n%ection or

    Carbureted Systems

    The sim!lest method of

    deli)ering fuel to a hydrogen

    engine is by *ay of a carburetor

    or central injection system. This

    system has ad)antages for a

    hydrogen engine. "irstly,

    central injection does not

    re>uire the hydrogen su!!ly

    !ressure to be as high as for

    other methods. -econdly,

    central injection or carburetors

    are used on gasoline engines,

    maFing it easy to con)ert a

    standard gasoline engine to

    hydrogen or a

    gasoline?hydrogen engine.

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    "igure0. 'irect Injection -ystem

    The disad)antage of central

    injection is that it is more

    susce!tible to irregular

    combustion due to !re2ignition

    and bacFfires. The greater

    amount of hydrogen?air mi+ture

    *ithin the intaFe manifold

    com!ounds the effects of !re2

    ignition.

    ". Port $n%ection Systems

    The !ort injection fuel deli)ery

    system injects fuel directly into

    the intaFe manifold at each

    intaFe !ort, rather than dra*ing

    fuel in at a central !oint.

    Ty!ically, the hydrogen is

    injected into the manifold after

    the beginning of the intaFe

    stroFe. t this !oint conditions

    are much less se)ere and the

    !robability for !remature

    ignition is reduced.

    In !ort injection, the air is

    injected se!arately at the

    beginning of the intaFe stroFe to

    dilute the hot residual gases and

    cool any hot s!ots. -ince less

    gas 8hydrogen or air9 is in the

    manifold at any one time, any

    !re2ignition is less se)ere. The

    inlet su!!ly !ressure for !ort

    injection tends to be higher than

    for carbureted or centralinjection systems, but less than

    for direct injection systems.

    "igure . Electronic "uel Injector

    E. "irect $n%ection Systems

    More so!histicated

    hydrogen engines use direct

    injection into the combustion

    cylinder during the com!ression

    stroFe. In direct injection, the

    intaFe )al)e is closed *hen the

    fuel is injected, com!letely

    a)oiding !remature ignition

    during the intaFe stroFe.

    Conse>uently the engine cannot

    bacFfire into the intaFe

    manifold. The !o*er out!ut of a

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    direct injected hydrogen engine

    is 5/J more than for a gasoline

    engine and 5J more than a

    hydrogen engine using a

    carburetor.=hile direct injection sol)es the

    !roblem of !re2ignition in the

    intaFe manifold, it does not

    necessarily !re)ent !re2ignition

    *ithin the combustion chamber.

    In addition, due to the reduced

    mi+ing time of the air and fuel

    in a direct inject2tion engine, the

    air?fuel mi+ture can be non2

    homogenous. -tudies ha)e

    suggested this can lead to

    higher $&+ emissions than the

    non2direct injection systems.

    'irect injection systems re>uire

    a higher fuel rail !ressure than

    the other methods.

    "igure 1. Cryogenic !ortInjection

    F. Cran&case 'entilation

    CranFcase )entilation is e)en

    more im!ortant for hydrogen

    engines than for gasoline

    engines.

    s *ith gasoline engines,unburnt fuel can see! by the

    !iston rings and enter the

    cranFcase. -ince hydrogen has a

    lo*er energy ignition limit than

    gasoline, any unburnt hydrogen

    entering the cranFcase has a

    greater chance of igniting.

    Hydrogen should be !re)ented

    from accumulating through

    )entilation.

    Ignition *ithin the

    cranFcase can be just a startling

    noise or result in engine fire.

    =hen hydrogen ignites *ithin

    the cranFcase, a sudden

    !ressure rise occurs. To relie)e

    this !ressure, a !ressure relief

    )al)e must be installed on the

    )al)e co)er. ty!ical !ressure

    relief )al)e installation is sho*n

    in "igure 3

    "igure 3. ressure %elief Aal)e on

    engine CranFcase

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    E+haust gases can also see!

    by the !iston rings into the

    cranFcase. -ince hydrogen

    e+haust is *ater )a!or, *ater

    can condense in the cranFcase*hen !ro!er )entilation is not

    !ro)ided. The mi+ing of *ater

    into the cranFcase oil reduces

    its lubrication ability, resulting

    in a higher degree of engine

    *ear.

    G.T!ermal Efficiency

    The theoretical

    thermodynamic efficiency of an

    &tto cycle engine is based on

    the com!ression ratio of the

    engine and the s!ecific2heat

    ratio of the fuel as sho*n in the

    e>uation@

    th#2#?8A#?A59LB2#

    859

    =here@

    A#?A5 the com!ression ratio

    B ratio of s!ecific heats

    th theoretical thermodynamic

    efficiency The

    higher the com!ression ratio

    and?or the s!ecific2heat ratio,

    the higher the indicated

    thermodynamic efficiency of

    the engine. The com!ression

    ratio limit of an engine is based

    on the fuelDs resistance to

    FnocF. lean hydrogen mi+ture

    is less susce!tible to FnocF than

    con)entional gasoline and

    therefore can tolerate higher

    com!ression ratios. The

    s!ecific2heat ratio is related to

    the fuelDs molecular structure.

    The less com!le+ the molecularstructure, the higher the

    s!ecific2heat ratio. Hydrogen 8B

    #.9 has a much sim!ler

    molecular structure than

    gasoline and therefore its

    s!ecific2heat ratio is higher than

    that of con)entional gasoline 8B

    #.#9.

    E. Emissions

    The combustion of

    hydrogen *ith o+ygen

    !roduces *ater as its only

    !roduct@

    5H5 &5 5H5& 849

    The combustion of hydrogen

    *ith air ho*e)er cans also !ro2

    duce nitrogen o+ides 8$&+9

    H5 &5 $5 H5& $5 $&+89

    The o+ides of nitrogen are

    created due to the high

    tem!eratures generated *ithin

    the combustion chamber during

    combustion. This high

    tem!erature causes some of the

    nitrogen in the air to combine

    *ith the o+ygen in the air. The

    amount of $&+ formed de!ends

    on@

    The air?fuel ratio

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    The engine com!ression ratio

    The engine s!eed

    The ignition timing

    III. C-E -T('Y&"6M=

    HY'%&

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    "igure##. Emission from uicFly arise due to

    the nature of the hydrogen ICE

    technology that differentiates it

    from fuel cell and gasoline

    )ehicles.

    This !a!er has indicated

    the ad)antages of hydrogen as a

    fuel for s!arF ignited internal

    combustion engines and has

    sho*n that the hydrogen engine

    is gro*ing u!. n o)er)ie* is

    gi)en of the de)elo!ment by car

    manufacturers and also of the

    research at the laboratory of

    Trans!ort Technology

    A. %E"E%E$CE-

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    :#; 6M= Hydrogen 1@ the first

    !remium saloon *ith a bi)alent

    IC engine.

    :5; ce)es -.M. and -mith R.%.@Hybrid and con)entional

    hydrogen engine )ehicles

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