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Hydrogne Internal Combustion Engine
Mr.Yusuf Mulani
Ms. Tejashri KhochareCollge of Engineering,
andhar!ur.
ABSTRACTHydrogen as a fuel in
internal combustion engines is a
solution for the near future to
realize zero CO2 emissions for
traffic applications. The
hydrogen fuelled IC engine is
ready for that. The storage and
production of hydrogen, and to
build the necessary
infrastructure, are the real
shortcomings in the general use
of hydrogen in IC engines.
Hydrogen-burning
internal combustion engines trace
their roots back to some of the
ery earliest deelopments in
internal combustion engine
deelopment. In !"#$ Isaac de
%ias built the first hydrogen
internal combustion engine, and
although the design had serious
fla&s, it &as a more than '# years
ahead of the deelopment of
gasoline internal combustion
engines (Taylor !)"'*.
+hen talking about
hydrogen as a fuel for traffic
applications, most people make
the link to fuel cells. +hy +hy
not a more realistic link to
internal combustion engines t
the moment the estimation of the
number of motor ehicles is
about "## million. To replace
them in a relatiely short time by
fuel cells is impossible. There are
seeral reasons for conerting the
gasoline, diesel or natural gas
engines to hydrogen fuelled
internal combustion engines.
This paper gies an
oerie& of the deelopment of
hydrogen fuelled IC engines by
the most important car
manufactures (ord, /0+,*.
This oerie& indicates the
eolution in the deelopment of
hydrogen fuelled engines
(different generation of engines*.
1ey +ords climate change,
carbon dio3ide, hydrogen,
technological change, internal
Combustion engines, fuel cells.
"igure#. Hydrogen ICE
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I. I$T%&'(CTI&$
A. Pollution is Global issue
E)eryday radios,
ne*s!a!ers, tele)isions and the
internet *arn us of energy
e+haustion, atmos!heric
!ollution and climate *arming.
fter fe* hundred years of
industrial de)elo!ment, *e are
facing these globality !roblems
*hile at the same time *e
maintain a high standard of
li)ing. The most im!ortant
!roblem *e are faced *hich is
*hether *e should go for
continuous de)elo!ment or die.
Coal, !etroleum, natural gas,
*ater and nuclear energy are
fi)e main energy resources that
ha)e !layed im!ortant roles and
ha)e been *idely used by
human beings.
B. Statistics of pollution
-tatistics sho* that, the daily
consum!tion of !etroleum all
o)er the *orld today is /
million barrels, of *hich about
0/ !er cent is used in
communications and
trans!ortation. In this sort of
consum!tion, about 1/23/ !er
cent is for automobile use. That
is to say, auto !etroleum
constitutes about 40 !er cent of
the *hole !etroleum
consum!tion.
"igure5. C&5 Emission by
)arious sectors
6y #77/25/4/
In accordance *ith this
calculation. 'aily consum!tion
of !etroleum by automobiles all
o)er the *orld is o)er t*o
million tones
t the same time as these
fuels are burnt, !oisonous
materials such as 0// million
tones of carbon mono+ides
8C&9, #// million tones:1;of
hydro carbons 8HC9, 00/
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million tones of carbon8C9, 0/
million tones of nitrogen o+ides
8$&+9 are emitted into the
atmos!here e)ery year, se)erely
!olluting the atmos!here.C. Global Energy in Transition
"igure4. The age of energy gases2uid fuel essentially !etroleum
started in about #7// and is near
the ma+imum no*. In recent
times gaseous fuel is becoming
more and more im!ortant.
"rom early times till no*, *e
can notice that each successi)e
fuel has more hydrogen and less
carbon. In other *ords H?C
ratio is increasing. &ne can
therefore !redict that hydrogen
is ine)itable and the H?C ratio
*ill go to infinity.
Technologicalinno)ation,
rather than de!letion, is
dri)ing these changes
T*o moti)ators for the use
of hydrogen as an energy carrier
today are@ #9 To !ro)ide a
transition strategy from
hydrocarbon fuels to acarbonless society and 59 To
enable rene*able energy
sources
II. C&M6(-TIAE%&E%TIE-
&"HY'%&
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im!ortant factor in determining
*hat com!ression ratio an
engine can use, since the
tem!erature rise during
com!ression is related to thecom!ression ratio. The
tem!erature rise is sho*n by the
E>uation@
B 2#
T5 T# 8A#?A59
8#9
=here@
A#?A5 the com!ression ratio
T# absolute initial tem!erature
T5 absolute final tem!erature
B ratio of s!ecific heats
The tem!erature may not
e+ceed hydrogenDs auto ignition
tem!erature *ithout causing
!remature ignition. Thus, the
absolute final tem!erature limits
the com!ression ratio. The high
auto ignition tem!erature of
hydrogen allo*s larger
com!ression ratios to be used in
a hydrogen engine than in a
hydrocarbon engine.
C. ig! Flame Speed
Hydrogen has high flame
s!eed at stoichiometric ratios.
(nder these conditions, the
hydrogen flame s!eed is nearly
an order of magnitude higher
8faster9 than that of gasoline.
This means that hydrogen
engines can more closely
a!!roach the
thermodynamically ideal engine
cycle. t leaner mi+tures,ho*e)er, the flame )elocity
decreases significantly.
". ig! "iffusi#ity
Hydrogen has )ery high
diffusi)ity. This ability to
dis!erse in air is considerably
greater than gasoline and is
ad)antageous for t*o mainreasons. "irstly, it facilitates the
forma2tion of a uniform mi+ture
of fuel and air
E. Clean ydrogen Economy
CLEAN HYDROGEN ECONOMY FOR THE FUTURE
Hydrogen production
H2 (ga!
H2 (co"preed! H2 (#i$uid! H (o#id c%e"ica#!
Hydrogen torage
Hydrogen uti#i&ation
E %ig%'preure
cryogenic tan E c%e"ica# reaction
H2)O2 Fue# ce##*C or Hy+rid engine
,ero-e"iion .e%ic#e
III. HY'%&
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A. Engine "esign
The most
effecti)e
means of
controlling !re2ignition and
FnocF is to re2design the engine
for hydrogen
use, s!ecifically the
"igure. Hy2I.C E
combustion chamber
nd the cooling system. disF2
sha!ed combustion chamber
8*ith a flat !iston and chamber
ceiling9 can be used to reduce
turbulence *ithin the chamber.
The disF sha!e hel!s, to
!roduce lo* radial and
tangential )elocity com!onents
and does not am!lify inlet s*irl
during com!ression. -ince
unburned hydrocarbons are not
a concern in hydrogen engines,
a large bore2to2stroFe ratio can
be used *ith this engine. To
accommodate the *ider range
of flame s!eeds that occur o)er
a greater range of e>ui)alence
ratios, t*o s!arF !lugs are
needed. The cooling system
must be de2signed to !ro)ide
uniform flo* to all locations
that need cooling.
B. Fuel "eli#ery system
da!ting or re2designing
the fuel deli)ery system can be
effecti)e in reducing or
eliminating !re2ignition.
Hydrogen fuel deli)ery
system can be broFen do*n into
three main ty!es@ centralinjection 8or Gcarbureted9, !ort
injection and direct injection.
Central and !ort fuel deli)ery
systems injection forms the
fuel2air mi+ture during the
intaFe stroFe. In the case of
central injection or a carburetor,
the injection is at the inlet of the
air intaFe manifold. In the case
of !ort injection, itis injected at
the inlet !ort.
C. Central $n%ection or
Carbureted Systems
The sim!lest method of
deli)ering fuel to a hydrogen
engine is by *ay of a carburetor
or central injection system. This
system has ad)antages for a
hydrogen engine. "irstly,
central injection does not
re>uire the hydrogen su!!ly
!ressure to be as high as for
other methods. -econdly,
central injection or carburetors
are used on gasoline engines,
maFing it easy to con)ert a
standard gasoline engine to
hydrogen or a
gasoline?hydrogen engine.
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"igure0. 'irect Injection -ystem
The disad)antage of central
injection is that it is more
susce!tible to irregular
combustion due to !re2ignition
and bacFfires. The greater
amount of hydrogen?air mi+ture
*ithin the intaFe manifold
com!ounds the effects of !re2
ignition.
". Port $n%ection Systems
The !ort injection fuel deli)ery
system injects fuel directly into
the intaFe manifold at each
intaFe !ort, rather than dra*ing
fuel in at a central !oint.
Ty!ically, the hydrogen is
injected into the manifold after
the beginning of the intaFe
stroFe. t this !oint conditions
are much less se)ere and the
!robability for !remature
ignition is reduced.
In !ort injection, the air is
injected se!arately at the
beginning of the intaFe stroFe to
dilute the hot residual gases and
cool any hot s!ots. -ince less
gas 8hydrogen or air9 is in the
manifold at any one time, any
!re2ignition is less se)ere. The
inlet su!!ly !ressure for !ort
injection tends to be higher than
for carbureted or centralinjection systems, but less than
for direct injection systems.
"igure . Electronic "uel Injector
E. "irect $n%ection Systems
More so!histicated
hydrogen engines use direct
injection into the combustion
cylinder during the com!ression
stroFe. In direct injection, the
intaFe )al)e is closed *hen the
fuel is injected, com!letely
a)oiding !remature ignition
during the intaFe stroFe.
Conse>uently the engine cannot
bacFfire into the intaFe
manifold. The !o*er out!ut of a
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direct injected hydrogen engine
is 5/J more than for a gasoline
engine and 5J more than a
hydrogen engine using a
carburetor.=hile direct injection sol)es the
!roblem of !re2ignition in the
intaFe manifold, it does not
necessarily !re)ent !re2ignition
*ithin the combustion chamber.
In addition, due to the reduced
mi+ing time of the air and fuel
in a direct inject2tion engine, the
air?fuel mi+ture can be non2
homogenous. -tudies ha)e
suggested this can lead to
higher $&+ emissions than the
non2direct injection systems.
'irect injection systems re>uire
a higher fuel rail !ressure than
the other methods.
"igure 1. Cryogenic !ortInjection
F. Cran&case 'entilation
CranFcase )entilation is e)en
more im!ortant for hydrogen
engines than for gasoline
engines.
s *ith gasoline engines,unburnt fuel can see! by the
!iston rings and enter the
cranFcase. -ince hydrogen has a
lo*er energy ignition limit than
gasoline, any unburnt hydrogen
entering the cranFcase has a
greater chance of igniting.
Hydrogen should be !re)ented
from accumulating through
)entilation.
Ignition *ithin the
cranFcase can be just a startling
noise or result in engine fire.
=hen hydrogen ignites *ithin
the cranFcase, a sudden
!ressure rise occurs. To relie)e
this !ressure, a !ressure relief
)al)e must be installed on the
)al)e co)er. ty!ical !ressure
relief )al)e installation is sho*n
in "igure 3
"igure 3. ressure %elief Aal)e on
engine CranFcase
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E+haust gases can also see!
by the !iston rings into the
cranFcase. -ince hydrogen
e+haust is *ater )a!or, *ater
can condense in the cranFcase*hen !ro!er )entilation is not
!ro)ided. The mi+ing of *ater
into the cranFcase oil reduces
its lubrication ability, resulting
in a higher degree of engine
*ear.
G.T!ermal Efficiency
The theoretical
thermodynamic efficiency of an
&tto cycle engine is based on
the com!ression ratio of the
engine and the s!ecific2heat
ratio of the fuel as sho*n in the
e>uation@
th#2#?8A#?A59LB2#
859
=here@
A#?A5 the com!ression ratio
B ratio of s!ecific heats
th theoretical thermodynamic
efficiency The
higher the com!ression ratio
and?or the s!ecific2heat ratio,
the higher the indicated
thermodynamic efficiency of
the engine. The com!ression
ratio limit of an engine is based
on the fuelDs resistance to
FnocF. lean hydrogen mi+ture
is less susce!tible to FnocF than
con)entional gasoline and
therefore can tolerate higher
com!ression ratios. The
s!ecific2heat ratio is related to
the fuelDs molecular structure.
The less com!le+ the molecularstructure, the higher the
s!ecific2heat ratio. Hydrogen 8B
#.9 has a much sim!ler
molecular structure than
gasoline and therefore its
s!ecific2heat ratio is higher than
that of con)entional gasoline 8B
#.#9.
E. Emissions
The combustion of
hydrogen *ith o+ygen
!roduces *ater as its only
!roduct@
5H5 &5 5H5& 849
The combustion of hydrogen
*ith air ho*e)er cans also !ro2
duce nitrogen o+ides 8$&+9
H5 &5 $5 H5& $5 $&+89
The o+ides of nitrogen are
created due to the high
tem!eratures generated *ithin
the combustion chamber during
combustion. This high
tem!erature causes some of the
nitrogen in the air to combine
*ith the o+ygen in the air. The
amount of $&+ formed de!ends
on@
The air?fuel ratio
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The engine com!ression ratio
The engine s!eed
The ignition timing
III. C-E -T('Y&"6M=
HY'%&
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"igure##. Emission from uicFly arise due to
the nature of the hydrogen ICE
technology that differentiates it
from fuel cell and gasoline
)ehicles.
This !a!er has indicated
the ad)antages of hydrogen as a
fuel for s!arF ignited internal
combustion engines and has
sho*n that the hydrogen engine
is gro*ing u!. n o)er)ie* is
gi)en of the de)elo!ment by car
manufacturers and also of the
research at the laboratory of
Trans!ort Technology
A. %E"E%E$CE-
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:#; 6M= Hydrogen 1@ the first
!remium saloon *ith a bi)alent
IC engine.
:5; ce)es -.M. and -mith R.%.@Hybrid and con)entional
hydrogen engine )ehicles
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