Large-scaleCCS Transportation Infrastructure in Europe

Cocate technical progress http://projet.ifpen.fr/Projet/cocate

COCATE

Large-scale CCS Transportation Infrastructure in Europe

Cocate technical progress http://projet.ifpen.fr/Projet/cocate2

� 1111stststst January 2010 to 31January 2010 to 31January 2010 to 31January 2010 to 31thththth December 2012December 2012December 2012December 2012

� 9 partners: 9 partners: 9 partners: 9 partners: IFP Energies nouvellesIFP Energies nouvellesIFP Energies nouvellesIFP Energies nouvelles, le Havre , le Havre , le Havre , le Havre DDDDééééveloppementveloppementveloppementveloppement, , , , GeogreenGeogreenGeogreenGeogreen, , , , AccoatAccoatAccoatAccoat, , , , SintefSintefSintefSintef----ER, DNV, ER, DNV, ER, DNV, ER, DNV, TNO, Port of Rotterdam NV, SANERI TNO, Port of Rotterdam NV, SANERI TNO, Port of Rotterdam NV, SANERI TNO, Port of Rotterdam NV, SANERI

� 5 countries involved: France, Denmark, Norway, 5 countries involved: France, Denmark, Norway, 5 countries involved: France, Denmark, Norway, 5 countries involved: France, Denmark, Norway, Netherlands, South AfricaNetherlands, South AfricaNetherlands, South AfricaNetherlands, South Africa

� ResearchResearchResearchResearch Project Project Project Project fundedfundedfundedfunded by the by the by the by the EuropeanEuropeanEuropeanEuropean CommunityCommunityCommunityCommunityunderunderunderunder FP7 for a tFP7 for a tFP7 for a tFP7 for a totalotalotalotal operated budget 4,5 M operated budget 4,5 M operated budget 4,5 M operated budget 4,5 M €€€€ (EC (EC (EC (EC contribution 3M contribution 3M contribution 3M contribution 3M €€€€))))

Project description


ObjectivesObjectivesObjectivesObjectivesDevelop a collecting network of small emitters fumesStudy a CO2 network composed of pipelines, intermediate storage and / or boats will transport the CO2 gathered to the storage sites (off or on-shore in our case).

Source 1

Source 2

Source 3

Source 4

Source 5

…

Pooling Centre

#1

Pooling Centre

#2

Hub

Source x

Rotterdam

Hub Rotterdam

T.1.1.1 Data Collection and

Pooling Scenario definition

T.1.1.2 Flue Gas collecting

network

T.1.1.3 CO2stream network

T.1.1.5 Onshore

pipeline up to Rotterdam

T.1.1.6 Ship up to Rotterdam

T.1.1.2B Alternative

flue gas collecting network


Work Programme

WP1 Global capture to storage transport network

Task 1.1 Definition of a network from sources to sinks Task 1.2 Strategy for deployment

WP2 Collecting network and export lifetime

Task 2.1 Thermodynamics and corrosionTask 2.2 Network Management

WP3 Safety of global capture to storage networkTask 3.1 Development of a Safety Management ToolkitTask 3.2 Risk assessment collecting networkTask 3.3 Export systemsTask 3.4 Risk assessment of integrated CCS chains

WP4 Economical studyTask 4.1 Micro-economic analysis: identification of cost key drivers Task 4.2 Macro-economic analysis: investment strategyTask 4.3 Economic model and application to Le Havre case

WP5 Management and

WP6 dissemination


The following slides present some technical results from The following slides present some technical results from The following slides present some technical results from The following slides present some technical results from the deliverables already emitted.the deliverables already emitted.the deliverables already emitted.the deliverables already emitted.

For each deliverable a public summary is available on For each deliverable a public summary is available on For each deliverable a public summary is available on For each deliverable a public summary is available on COCATE Web Site :COCATE Web Site :COCATE Web Site :COCATE Web Site :

http://projet.ifpen.fr/Projet/cocate

COCATE technical status

CO2 Breakdown of emissions in Le Havre and Port Jérôme areas - 2009

9%

1%

28%

6%

4%

27%

25%

Refinery #1

Refinery #2

Petrochemical industries

Others (Incinerator, car manufacture,glasswork,compressor test platform)

Coal Power Plant

Chemical industries (Ammonia & urea production,industrial gases production)

Cement Factory

TOTAL CO2 EMISSIONS CONSIDERED: 14.5MTCO2/y


85 point sources 85 point sources 85 point sources 85 point sources Post CombustionPost CombustionPost CombustionPost Combustion

14.5Mt14.5Mt14.5Mt14.5MtCO2CO2CO2CO2/Year emitted/Year emitted/Year emitted/Year emitted

Data Collection and Pooling Scenario Definition

Most of the concentrations are ranging from 5 to 15 % which is the typical concentration coming from combustion processes


5 Pooling centers


2 alternative solutions in Le Havre


Characteristics of the flue gases� T T T T fromfromfromfrom 70 to 47070 to 47070 to 47070 to 470°°°°CCCC

� Most of the Most of the Most of the Most of the temperaturetemperaturetemperaturetemperature fromfromfromfrom 100 to 250100 to 250100 to 250100 to 250°°°°C C C C � P P P P fromfromfromfrom belowbelowbelowbelow 1 1 1 1 atmatmatmatm ((((cementcementcementcement factoryfactoryfactoryfactory) to 1.1 ) to 1.1 ) to 1.1 ) to 1.1 barabarabarabara� HHHH2222O O O O fromfromfromfrom 5 to 30%5 to 30%5 to 30%5 to 30%� OOOO2222

� ~50% of the ~50% of the ~50% of the ~50% of the streamsstreamsstreamsstreams have composition have composition have composition have composition fromfromfromfrom 0 to 5%0 to 5%0 to 5%0 to 5%� ~50% of the ~50% of the ~50% of the ~50% of the streamsstreamsstreamsstreams have composition have composition have composition have composition fromfromfromfrom 5 to 10%5 to 10%5 to 10%5 to 10%

� NOxNOxNOxNOx fromfromfromfrom 0.0001 to 0.04%0.0001 to 0.04%0.0001 to 0.04%0.0001 to 0.04%� SOxSOxSOxSOx fromfromfromfrom 0.001 to 0.6%0.001 to 0.6%0.001 to 0.6%0.001 to 0.6%� CO CO CO CO fromfromfromfrom 0.0002 to 0.4%0.0002 to 0.4%0.0002 to 0.4%0.0002 to 0.4%� OtherOtherOtherOther possible components: VOC, Npossible components: VOC, Npossible components: VOC, Npossible components: VOC, N2222O, CHO, CHO, CHO, CH4444, HF, , HF, , HF, , HF, HClHClHClHCl, Ar, , Ar, , Ar, , Ar, HeavyHeavyHeavyHeavy

MetalsMetalsMetalsMetals....� ParticulateParticulateParticulateParticulate mattersmattersmattersmatters fromfromfromfrom 0 to 200mg/Nm0 to 200mg/Nm0 to 200mg/Nm0 to 200mg/Nm3333

Some data are not measured thus not available:particles size, pH


Main assumptions for the design of the pipelines Main assumptions for the design of the pipelines Main assumptions for the design of the pipelines Main assumptions for the design of the pipelines � Flue gases are sent as they are at the bottom of the stack into Flue gases are sent as they are at the bottom of the stack into Flue gases are sent as they are at the bottom of the stack into Flue gases are sent as they are at the bottom of the stack into the the the the

flue gas collecting network;flue gas collecting network;flue gas collecting network;flue gas collecting network;� The design is made for the peak The design is made for the peak The design is made for the peak The design is made for the peak flowrateflowrateflowrateflowrate;;;;� They are just boosted at the level of COThey are just boosted at the level of COThey are just boosted at the level of COThey are just boosted at the level of CO2222 sourcessourcessourcessources� The pipeline diameter cannot exceed 80The pipeline diameter cannot exceed 80The pipeline diameter cannot exceed 80The pipeline diameter cannot exceed 80”””” (maximal value available in (maximal value available in (maximal value available in (maximal value available in

the API 5L standards);the API 5L standards);the API 5L standards);the API 5L standards);� The minimal thickness of the pipeline is calculated using the The minimal thickness of the pipeline is calculated using the The minimal thickness of the pipeline is calculated using the The minimal thickness of the pipeline is calculated using the

Maximal Allowable Operating Pressure and taking into account a Maximal Allowable Operating Pressure and taking into account a Maximal Allowable Operating Pressure and taking into account a Maximal Allowable Operating Pressure and taking into account a corrosion allowance;corrosion allowance;corrosion allowance;corrosion allowance;

� The change in elevation is taken into account;The change in elevation is taken into account;The change in elevation is taken into account;The change in elevation is taken into account;� A heat transfer is considered (with air when pipelines are aeriaA heat transfer is considered (with air when pipelines are aeriaA heat transfer is considered (with air when pipelines are aeriaA heat transfer is considered (with air when pipelines are aerial and l and l and l and

with ground if buried)with ground if buried)with ground if buried)with ground if buried)

Design and report on flue gas pooling network


Flue network:Flue network:Flue network:Flue network:� the routing follows existing networks ;the routing follows existing networks ;the routing follows existing networks ;the routing follows existing networks ;� Pipelines are either aerial or buried (outside of industrial sitPipelines are either aerial or buried (outside of industrial sitPipelines are either aerial or buried (outside of industrial sitPipelines are either aerial or buried (outside of industrial sites)es)es)es)� Total length from 25 to 31 kmTotal length from 25 to 31 kmTotal length from 25 to 31 kmTotal length from 25 to 31 km� Pipeline diameters vary from 2Pipeline diameters vary from 2Pipeline diameters vary from 2Pipeline diameters vary from 2””””7/8 to 807/8 to 807/8 to 807/8 to 80””””. . . . � Powers required at the blowerPowers required at the blowerPowers required at the blowerPowers required at the blower’’’’s level vary from 0.01 to 175s level vary from 0.01 to 175s level vary from 0.01 to 175s level vary from 0.01 to 175 MWeMWeMWeMWe....

First identification of risks:First identification of risks:First identification of risks:First identification of risks:� Pipeline size;Pipeline size;Pipeline size;Pipeline size;� Transport of hot streams;Transport of hot streams;Transport of hot streams;Transport of hot streams;� Leakage;Leakage;Leakage;Leakage;� Corrosion;Corrosion;Corrosion;Corrosion;� Material defect;Material defect;Material defect;Material defect;� Potential collision.Potential collision.Potential collision.Potential collision.

Design and report on flue gas pooling network


Different aspects of the networks defined in D1.1.1 were investiDifferent aspects of the networks defined in D1.1.1 were investiDifferent aspects of the networks defined in D1.1.1 were investiDifferent aspects of the networks defined in D1.1.1 were investigated to identify gated to identify gated to identify gated to identify the potential issues linked to the transport of flue gases at lothe potential issues linked to the transport of flue gases at lothe potential issues linked to the transport of flue gases at lothe potential issues linked to the transport of flue gases at low pressure.w pressure.w pressure.w pressure.

Physical phenomena in the collecting network

Major problems identified in the network are:Major problems identified in the network are:Major problems identified in the network are:Major problems identified in the network are:� Excessive velocitiesExcessive velocitiesExcessive velocitiesExcessive velocities

⇒ large pressure dropslarge pressure dropslarge pressure dropslarge pressure drops⇒ excessive power requirementsexcessive power requirementsexcessive power requirementsexcessive power requirements⇒ large erosion rateslarge erosion rateslarge erosion rateslarge erosion rates

� Large amount of particulate matterLarge amount of particulate matterLarge amount of particulate matterLarge amount of particulate matter⇒ large erosion ratelarge erosion ratelarge erosion ratelarge erosion rate⇒ integrity issue with blowersintegrity issue with blowersintegrity issue with blowersintegrity issue with blowers⇒ large amounts of solids to dispose oflarge amounts of solids to dispose oflarge amounts of solids to dispose oflarge amounts of solids to dispose of

� CorrosionCorrosionCorrosionCorrosion⇒ large corrosion rateslarge corrosion rateslarge corrosion rateslarge corrosion rates⇒ large uncertaintieslarge uncertaintieslarge uncertaintieslarge uncertainties

� RequiredRequiredRequiredRequired power power power power isisisis unrealisticunrealisticunrealisticunrealistic⇒ From 2From 2From 2From 2 106 to 186to 186to 186to 186 106 W (mass flow rate 0.58 W (mass flow rate 0.58 W (mass flow rate 0.58 W (mass flow rate 0.58 106 to 6.08to 6.08to 6.08to 6.08 106 kg/h))))

0

50

100

150

200

250

300

350

-500 -450 -400 -350 -300 -250 -200 -150 -100 -50 0

Distance (m)

Vel

oci

ty (

m/s

)

CPP-3 branchCPP-2 branchCPP-1 branchG branchCPP-2 (with CPP-1) branchNORSDOK


Collecting network recommandations � 77% reduction of 77% reduction of 77% reduction of 77% reduction of PMsPMsPMsPMs mass rate can be obtained if the 4 biggest mass rate can be obtained if the 4 biggest mass rate can be obtained if the 4 biggest mass rate can be obtained if the 4 biggest

sources of sources of sources of sources of PMsPMsPMsPMs are treatedare treatedare treatedare treated� Erosion effects of remaining Erosion effects of remaining Erosion effects of remaining Erosion effects of remaining PMsPMsPMsPMs need to be investigated. Data need to be investigated. Data need to be investigated. Data need to be investigated. Data

needed are needed are needed are needed are PMsPMsPMsPMs size, density, composition, etcsize, density, composition, etcsize, density, composition, etcsize, density, composition, etc…………� Corrosion can be prevented by insulating specific pipes and keepCorrosion can be prevented by insulating specific pipes and keepCorrosion can be prevented by insulating specific pipes and keepCorrosion can be prevented by insulating specific pipes and keeping ing ing ing

the water from condensing or putting internal coating.the water from condensing or putting internal coating.the water from condensing or putting internal coating.the water from condensing or putting internal coating.� Corrosive effects of other components than COCorrosive effects of other components than COCorrosive effects of other components than COCorrosive effects of other components than CO2222 should be should be should be should be

investigatedinvestigatedinvestigatedinvestigated� Decreases of the velocities, pressure drop and power requirementDecreases of the velocities, pressure drop and power requirementDecreases of the velocities, pressure drop and power requirementDecreases of the velocities, pressure drop and power requirement

could be obtained if pipe diameters (or number of parallel pipescould be obtained if pipe diameters (or number of parallel pipescould be obtained if pipe diameters (or number of parallel pipescould be obtained if pipe diameters (or number of parallel pipes) ) ) ) could be increased.could be increased.could be increased.could be increased.

� Decrease of the volume flow rates need to be investigated Decrease of the volume flow rates need to be investigated Decrease of the volume flow rates need to be investigated Decrease of the volume flow rates need to be investigated (separation of CO(separation of CO(separation of CO(separation of CO2222 for the biggest sources)for the biggest sources)for the biggest sources)for the biggest sources)

� Study the feasibility of local absorption and transport the solvStudy the feasibility of local absorption and transport the solvStudy the feasibility of local absorption and transport the solvStudy the feasibility of local absorption and transport the solvent up ent up ent up ent up to the regenerator for the biggest emitter.to the regenerator for the biggest emitter.to the regenerator for the biggest emitter.to the regenerator for the biggest emitter.


� Study on the collecting network will integrate also the hubs desStudy on the collecting network will integrate also the hubs desStudy on the collecting network will integrate also the hubs desStudy on the collecting network will integrate also the hubs design and ign and ign and ign and will be completed by economics and risk analysis.will be completed by economics and risk analysis.will be completed by economics and risk analysis.will be completed by economics and risk analysis.

� On going study on the export system including ship and pipeline On going study on the export system including ship and pipeline On going study on the export system including ship and pipeline On going study on the export system including ship and pipeline transport: design, thermodynamics, corrosion...transport: design, thermodynamics, corrosion...transport: design, thermodynamics, corrosion...transport: design, thermodynamics, corrosion...

� By the end of the project all the developments will be used for By the end of the project all the developments will be used for By the end of the project all the developments will be used for By the end of the project all the developments will be used for the the the the strategy of deployment.strategy of deployment.strategy of deployment.strategy of deployment.

THANKS FOR YOUR ATTENTIONTHANKS FOR YOUR ATTENTIONTHANKS FOR YOUR ATTENTIONTHANKS FOR YOUR ATTENTION

http://projet.ifpen.fr/Projet/cocate

14

Contact: Sandrine [email protected]

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Large-scaleCCS Transportation Infrastructure in Europe