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AQUIFER STORAGE RECOVERY FEASIBILITY INVESTIGATION PHASE IIA MONITORING WELL PZ-1 VOLUME II -- APPENDIXES PREPARED FOR Upper Guadalupe River Authority Kerrville , Texas December 1989 L..:::=:::============================ CHM HI Ll-

L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

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Page 1: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

AQUIFER STORAGE RECOVERY FEASIBILITY

INVESTIGATION

PHASE IIA MONITORING WELL PZ-1

VOLUME II -- APPENDIXES

PREPARED FOR

Upper Guadalupe River Authority Kerrville , Texas

December 1989

L..:::=:::============================ CHM HI Ll-

Page 2: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

AUSRI/l16.S0

AQUIFER STORAGE RECOVERY FEASIBILITY INVESTIGATION

PHASE IIA: MONITORING WELL PZ-l

Prepared for:

Upper Guadalupe River Authority Kerrville, Texas

By:

CH2M HILL AUSTIN, TEXAS

TEX24486.Al

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Section

1

2

3

4

PREFACE

TABLE OF CONTENTS VGRA PHASE II-A REPORT

Volume I of II - Technical Report

EXECUTIVE SUMMARY

INTRODUCTION

1.1 Project Overview 1.2 Goals of Investigation

FIELD INVESTIGATION METHODOLOGY

2.1 Field Program 2.2 Field Program Implementation and Summary 2.3 Borehole Drilling and Well Installation 2.4 Rock Sampling and Analyses 2.5 Borehole Geophysics and Video Survey 2.6 Well Acidification 2.7 Well Development 2.8 Pump Tests 2.9 Water Sampling and Analyses

FIELD INVESTIGATION RESULTS

3.1 Borehole Stratigraphy 3.2 Rock Core Analyses 3.3 Hydrogeological Properties 3.4 Groundwater and Finished Water Quality 3.5 Plugging Analysis

CONCLUSIONS AND RECOMMENDATIONS FOR ASR PROGRAM

4.1 Conceptual Design of ASR Well 4.2 Storage Potential 4.3 Phase II-B Work Plan 4.4 Phase II-B Schedule 4.5 ASR Program Costs

DFW070/007.50

ES-1

1- 1

1- 1 1- 2

2- 1

2- 1 2- 1 2- 2 2- 4 2- 5 2- 6 2- 6 2- 7 2- 7

3- 1

3- 1 3- 7 3-13 3-15 3-20

4- 1

4- 1 4- 2 4- 6 4- 8 4- 9

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Figures

1-1

3-1 3-2 4-1 4-2

Tables

2-1 2-2

3-1 3-2

3-3 3-4 3-5

Proposed ASR Site Plan

PZ-l Well Completion and Subsurface Stratigraphy Caliper and Acoustic Logs for the Hosston-Sligo Conceptual Design of ASR Test Facility Phase II-B

Sequence of Field Activities Water Quality Parameters and Detection Limits

X-Ray Diffraction Mineral Percentages Permeability, Porosity, Specific Gravity, and Grain Density Results

Cation Exchange Capacity Results Water Quality During WeIl Development Summary of Water Quality

Volume II of II - Appendices A through F

APPENDIXES

A Geologic Logs B Geophysical Logs C Mineralogy, Inc. Report D Pump Test Results E Chemical Data F Geochemical Modelling Results

II

Dfl/OlO/OOl.SO

1- 3

3- 2 3- 6 4- 3 4-10

2- 3 2- 9

3- 9

3-11 3-12 3-16 3-18

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DFW0701014.50

Appendix A GEOLOGIC LOGS

Page 6: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

SHEET I OF JI

PROJECT NUMBER

TEX24486.A J

ROCK CORE LOG

PROJECT A 9 u i fer S tor age and R e c 0 v."ec..:r'--y'-----__ LOCATION _-"U--'G:..:R=A'--'W:.:...=T-'P'----___________ _

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ELEVATION _____ ORIENTATION Vert ical BOREHOLE: Well PZ-J

WATER LEVEL DATE Z117/Wi START: 8 $/"- AI1 FINISH: Ie, os- INSPECTORPe t ::us

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• SHEET

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SHEET ~ OF:J

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DRILLING METHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Failing 1500

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SHEET.) OF ~ PROJECT NUMBER

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ROCK CORE LOG

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SHEET

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SHEET 9' o~ PROJECT NUMBER

TEX24486.AI

ROCK CORE LOG

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PROJECT NUMBER

TEX24486.AI

ROCK CORE LOG

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SHEET II OF·

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Page 17: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

SHEET /~F: PROJECT NUMBER

TEX24486.AI

ROCK CORE LOG

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Page 18: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

PROJECT NUMBER

TEX24486.AI

ROCK CORE LOG

PROJECT Ag u if e r S tor a ge and Re cover y LOCATION_-"U-,G,-,R=A~W,,--=T-=P,--___________ _

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Page 19: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

SHEET /'f OF '3 PROJECT NUMBER

'::EX24486.AI

ROCK CORE LOG

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Page 20: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

PROJECT NUMBER

'I'EX24486.AI

ROCK CORE LOG

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Page 21: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

PROJECT NUMBER

'::EX24486.A 1

ROCK CORE LOG

PROJECT A 9 u i fer S tor age and R e C 0 v "e-'cr....JY'--__ LOCATION _-"U-,G,-,R=Ac-'W~T-=P ____________ _

DRILLING METHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Failing 1500

BOREHOLE: Well PZ-I ELEVATION _____ ORIENTATION Ve r tic a 1

WATER LEVEL

:r f­a. w o

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Page 22: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

SHEET 17 OF J PROJECT NUMBER

~!'.:X24486.AI

ROCK CORE LOG

PROJECT Aq u if e r S tor age and Re cove ry LOCATION_---"UcoG'-'R"-'-'A'-'W~T20P ____________ _

DRILLING METHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Failing 1500 ELEVATION ____ _ ORIENTATION Ve r tic a 1

WATER LEVEL DATE START FINISH:

BOREHOLE: Well PZ-I INSPECTORP e t r u s

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Page 23: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

SHEET /8 OF "? PROJECT NUMBER

~!':X24486.AI

ROCK CORE LOG

PROJECT Ag u i fer S tor age and Re cove ry LOCATlON_~UcoG"-"R,,-A,----,,WCcT,,-,,-P ____________ _

DRILLING METHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Fail ing 1500 ELEVATION ____ _ ORIENTATION Ve r tic a I BOREHOLE: Well PZ-I WATER LEVEL DATE START : FIN SH INSPECTOR Pet ~ u s I .

COMMENTS 0* a: DISCONTINUITIES LITHOLOGY " z- w 0 z<> (/) ID ...J

TESTS (/) ::;; wf- DESCRIPTION MINERALOGY CEMENTATION INSTRUMENTATION

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SHEET 15 OF J

PROJECT NUMBER

7EX24486.AI

ROCK CORE LOG

PROJECT Aquifer Storage and Recovery LOCATION_--""U-"GecR=A'--'W"---'-T-"P ____________ _

DRILLING METHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Failing 1500

ELEVATION _____ ORIENTATION Vert ical BOREHOLE: Well PZ-I

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z- w a z..;> en III ...

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Page 25: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

.... OF ~

PROJECT NUMBER

:'EX24486.AI

ROCK CORE LOG

PROJECT A 9 u i fer S tor age and Re C 0 v e~r-2Y~ __ LOCATION_----"U'-'G~R=A'___'W~T~P ____________ _

DRILLING METHOD Mud Rotary

ELEVATION ____ _ ORIENTATION Ve r tic a 1

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SHEET:(I OF3

PROJECT NUMBER

';:!o:X24486.AI

ROCK CORE LOG

PROJECT Aqu i fe r Storage and Recove ry LOCATION_-"U~G,,-R~A~W~T~P,--___________ _

DRILLING METHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Failing 1500

ELEVATION ____ _ ORIENTATION Ve r tic a 1 BOREHOLE: Well PZ-I

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ROCK CORE LOG

PROJECT Aqu i fe r Storage and Recove ry LOCATION_-"U"'GecR=A'-'W"---"T-'P ____________ _

DRILLING METHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Failing 1500 ELEVATION ____ _ ORIENTATION Ve r tic a 1 BOREHOLE: Well PZ-I

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SHEET2'3 OF' '1 PROJECT NUMBER

7EX24486.AI ~---------------------------------~~~~~~~~--------

ROCK CORE LOG

P ROJ ECT A 9 u i fer S tor age and R e cove ,,--=r~y,-____ LOCA TlON _----'U'--G"--'R'-'A-'--'W'-T~P ________________________ _

DRILLING METHOD Mud Rotary

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SHEET OF l PROJECT NUMBER

'::EX24486.AI

ROCK CORE LOG

PROJECT Aguifer Storage and Recovery LOCATION_----"Uc.:C"--"R'-'-A-'--"WecT"--"-P ____________ _

DRILLINGMETHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Failing 1500 E LEV ATION ____ _ ORIENTATION Ve r tic a 1 BOREHOLE: Well PZ-I

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Page 30: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

PRO.JECT NUMBER

r-______________________________ ~~~~~EX24486.A] ROCK CORE LOG

PROJECT Ag u if e r S tor age and Re C 0 ve"-"-r .... y'--___ LOCATION_~U~G~R~A~~W~T_=_P ____________ _

DRILLING METHOD Mud Rotary

ELEVATION ____ _ ORIENTATION Ve r tic a 1 DRILLERS & EQUIPMENT TWDB-Fai 1 ing ]500

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SHEET;(~ OF 1 PROJECT NUMBER

';EX24486.AI

ROCK CORE LOG

PROJECT Aq u i fe r Storage and Recove ry LOCATION __ U=-=GC-'R"'A=---'W'-T"'-"-P _____________ _

ORILLINGMETHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Fai1ing 1500

ELEVATION _____ ORIENTATION Ve r tic a 1 BORE HOLE: We 11 PZ- I

WATER LEVEL DATE START FINISH: INSPECTORPe t -us L

COMMENTS c* a: DISCONTINUITIES LITHOLOGY " z- W 0 z<> IJ) "' ..J

TESTS IJ) :;; wf- DESCRIPTION MINERALOGY CEMENTATION INSTRUMENTATION

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SHEETP OF~ PROJECT NUMBER

'::EX2.4486.AI

ROCK CORE LOG

PROJECT Aq u i fer S tor age and Re cove ry LOCATION_---'U'-C"'-'-R"A"--'W'-T"'-!oP ____________ _

DRILLINGMETHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Failing 1500

ELEVATION _____ ORIENTATION Ve r tic a 1 BOREHOLE: Well PZ-I

WATER LEVEL DATE START : FINISH INSPECTORPe t rus : . COMMENTS 0* a: DISCONTINUITIES LITHOLOGY t:

z- W c (I) Ol

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PROJECT NUMBER

~ ______________________________ ~ 7EX24486.AI

ROCK CORE LOG

PROJECT Aq u i fe r S tor age and Re cove ry LOCATION~--"U-"G,-,R,,-A,-,---,W,-T=-=.P _______ ~ ____ _

DRILLING METHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Failing 1500 ELEVATION _____ ORIENTATION Vert ical BOREHOLE: Well PZ-I

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SHEE~ OF'

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:EX24486 .A J ---

ROCK CORE LOG

PROJECT A qui fer S tor age and R e C 0 ve r Y LOCA TION _-=-U~G,-,R~A,--,--,W,-T=P ___________ _

DRILLING METHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Failing J500

ELEVATION _____ ORIENTATION Ve r tic a 1 BOREHOLE: Well PZ-J

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PROJECT NUMBER

TEX24486.AI

ROCK CORE LOG

PF" 'J ;r . 9 u i fe r Storage and Re cove ry LOCATION_-=Uc;G::...R=A'--W"-"T'-'P'--___________ _

DFU,:·.'ETHOD Mud Rotary DRILLERS & EQUIPMENT TWDB-Failing 1500

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FORM 0 2113A 5178

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DFW0701014.50

Appendix B GEOPHYSICAL LOGS

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-,>;AS WATER DEVELOPMENT BOARD WATER AVAILABIUTV DATA AND STUDIES SECTION AUSTJIII. TEXAS

STATE WEU NUMB£/! ---,;,,-______ _ FILE NUMBER J!'I -6' PRO.IECT 3 Z. 0 ,

~OTe: THESE LOGS CANNOT BE USED TO FULFIU CONTllAC'TURAL OBUGATIONS.

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CEMENTED FROM: ,$,,"l TO .,., , SCREEN: ~ TO AQUIFER: ________________ ___

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OPERATO" (8) C&'m ~noN: ______________________________________ _

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TEXAS WATER DEVELOPMENT BOARD WATER AVAILABIUTY DATA AND STUDIES 8/iCnON AUSTIN. TEXAS

TYPESOFLOGSTHISDATE: g-z-t1 : ____ -'--__________________ _

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CASING DATA: l 0 ...,," ~,=,,,.e - 3' I OPEN HOU DIA.: _'!O"'L'_' ___________ __

CEMENTED FROM: s", .. ,t TO 3'1 ' SCREEN: ~..\\.\60-----AQUIFER: _________ _

FLUID RESISTIVITY: ____ OHMS AT __ ' F.REMARKS: ______________________ _

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• • 72-1

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TEXAS WATER DEVELOPMENT BOARD STATE WELL NUMBER ~--------FILE NUMBER 89-26 WATER AVAILABILITY DATA AND STUDIES SECTION

AUSTIN. TEXAS PROJECT 3245

NOTE: THESE LOGS CANNOT BE USED TO FULFILL CONTRACTURAL OBLIGATIONS.

lYPES OF LOGS THIS DATE: 9(25(89 :E-lOG :-'JG""R __ :C!.fl ___ : GG : CAL :SOllIC

OPERATOR IS) _CUBu.luM ___ • LOCATION: IIGRA TEST l'fEll • 1

COUNlY: ......IIKJ:JEB~RL... ___ NEARESTTOWN: KERRVTlI F DRILLER: wns. fie CARTY

OWNER:~UG~,R~A~ ________ ADDRESS: ________________________ _

lYPE OF DRILL: CORED BIT SIZE: ....\1..6'_' ___________________________________ _

ALTITUDE OF LAND SURFACE: 1635' LOGGED DEPTH: ----"6"'03"-' ___ DRILLED DEPTH: -,6~2,-7 _' ___ __

FLUID lEVEL: J 97' ± FLUID lYPE: FRESH I'IATER LOG REFERENCE POINT: ..l.C"',R"'OU"'-iu;iD.,JL ... E.,!.Vf,JEL _______ _

CASING DATA: 1..7_" ..i!S.!.TE!;.!E""l _______________ ~OPEN HOLE DIA.: ..£6'-" _______________________ _

CEMENTED FROM: SURF. TO 490' SCREE~PEN HOLE TO _____ AQUIFER: !!HO~S!.::S.!.TO~N!-__________ _

FLUID RESISTIVITY: ___ OHMS AT __ • F. REMARKS: ________________________ _

GAMMA RAY COUNTS PER SECOND ~ TIME CONSTANT 4

RADIATION INCREASES

COUNTS PER SECOND ~ In Ie--

~ DEPTH 5 "=100'

450'

~ SOD'

559'

t--t .-1

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veAS WATER DEVELOPMENT BOARD STATE WELL NUMBeR = ____ _ FILE NUMBER _-.:;."":;,-.;;.2;:.." ____ _ WATER AVAILABILITY DATA AND STUDIES SECTION

.USTIN, TEXAS PROJECT 32.,

10TE: THESE LOGS CANNOT BE USED TO FULFIU CONTRACTURAL OBLIGATIONS.

VPESOFLOGSTHISDATE:9(25(89 : E-LOr, :_G"',R'---_:-l1r! __ : GG ---"CillA' __ : SD'II C

'PERATOR (SI -"C~RI!..!:M,---__ • LOCAnON: UGRA TEST ~~ELL '

:OUNTY: ~K""ER~R'--____ NEARESTTOWN: KERRY! II f DRILLER: TI,DO IIcCARTY

MMNER:~U~G~RA~ _________ ADDRESS: ___ ~ __________________________ ___

MUD ROTA~O -YPEOFDRIU: _ Rffi BIT SIZE: 9 7(8" - 400' 6" 400-"".ll6£27L.:-:J.fJ,.t~ ________ _

U.nTUDE OF LAND SURFACE: .... ' .. 63 ... S ..... ' __ LOGGED DEPTH:4H:' ';>03 ' DRILLED DEPTH: ~ 62.. 7 '

'lUID LEVEL: 197'! FLUID TYPE: FRESH HATER LOG REFERENCE POINT: .:.G"'P.""OU"'''I'''D...JL .... E .... VJ;JEL ____ _

:ASING DATA: -.:,.7_" -'S:.:,T::;EE:.::L'--_______ OPEN HOLE DIA.: ~6~" ____________ _

:EMENTED FROM: SURF. TO ..:;:4",90,,-' __ SCREENPPEN HOL E TO ___ AQUIFER: HC!10!,;!S,"-S TllO[!N ______ _

ILUID RESISnvlTY: ___ OHMS AT __ o F. REMARKS: ________________ _

SELF POTENnAL MIUIVOLTS

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TWOI-0272A

TEXAS WATER DEVELOPMENT BDARO WATER AVAILABIUTY DATA AND STUDIES SECTION AUSTIN. TEXAS

STATE WELL NUMBER _____ _ FILE NUMBER _"-890.:-,,2,,6 _____ _ PROJECT 3245

NOTE: THESE LOGS CANNOT BE USED TO FULFILL CONTRACTURAL OBLIGATIONS.

1'YPESOFlOGSTHISDATE:9(2sI89 : E-LOr. :-'Gl.':,R'--_:"'N'--__ :"GuG __ :"'CA.l.l.l~_: S0tllC

OPERATOR (5) -"C"'RI"'M'--__ • LOCATION: UGRA TEST I·JELL "

COUNrf.E"'R"'R _____ NEARESTTOWN: KERRVILLE DRILLER: THDS. fie CARTY

OWNER~~GR~A~ _________ ADDRESS: _____________________________ ___

1'YPE OF DRIU: CORED BIT SIZE: ...!61.... .. ______________________________ _

ALTITUDE OF LAND SURFACE: -'I~6:.:o3s~' __ LOGGED DEPTH: ,.,6",0,,-3 ' ____ DRILLED DEPTH: ....:062""7_' _____ _

fLUID LEVEl: 197' ± FLUID TYPE: rRESH WATER LOG REfERENCE POINTf",R"'O""UN'-!O.!....k.L ... EVuE"'L _____ _

CASING DATA: _7C" .. ....::..ST"'E"'E.:.L ______________ OPEN HOLE DIA. : 6v_'_' _____________________ _

CEMENTED FROM: SURF. SCREE~PEN HOLE TO ___ AQUIFER:HO'''S::.:Sc:.T;:.:ON'---_______ __

fLUID RESISTIVITY: OHMS AT __ o f. REMARKS: CALIPER TOOL IS OFF APPROXIMATELY

ONE DIVISION----SEE CASING SIZE ON LOG.

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, I

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, '

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TWOB·01S'

TEXAS WATER DEVELOPMENT BOARD WATER AVAILABILITY DATA AND STUDIES SECTION AUSTIN. TEXAS

STATE WELL NUMBER FILE NUMBER 1l9-2G~~ -PROJECT 3245

NOTE: THESE LOGS CANNOT BE USED TO FULFILL CONTRACTURAL OBLIGATIONS.

TYPES OF LOGS THIS DATE: 9/25/89 :E-LOG _G""R,--_: N1-_~ :G-"---~_ . CldA,.L __ : sm'l! C

OPERATOR (S) -,C~R.!JIMc.L ___ . LOCATION: UGRA TEST HEI I '1

COUNTY: .::K"'E"'RR"--____ NEARESTTOWN: KERRY!! IE DRILLER: TWOS. IkCARTY

OWNER:-,U~G~AA~ _______ ADDRESS: _____________________ ___

TYPE Of DRilL: CORED BIT SIZE: _-,,6_" ____________________ ___

ALTITUDE OF LAND SURFACE: .... 1",6",,3,,-5_' __ LOGGED DEPTH: -.::6:::.0::.-3_' ___ DRILLED DEPTH: -,!!62,-!7_' ___ ~

FLUID lEVEL: 197' ± FLUID TYPE: ERESH I·IATER LOG REFERENCE POINT: ~G"'RO"'~'"'II.b!D_.JLJE;J.Y.l..EL"--____ _

CASING DATA: 7" STEEL OPEN HOLE DIA.: :::."_" ____________ _

CEMENTED FROM: SURF. TO -",4-",90,,-' __ SCREEN:OPEtJ HOI FTO ___ AQUIFER: -,-H~O~SS"-,T,,,O~N ______ _

FLUID RESISTIVITY: ___ OHMS AT ~~. f. REMARKS: HELL HAS BEEN ACI DIZED

--CAlIPER----­HOLE DIAMETER IN INCHES

FROM TO

DEPTH 5"=100'

500'

550'

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P, O. 80)1 541332 .;F/f"tJAS/ ;)

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WELL

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DFW0701014.50

Appendix C MINERALOGY, INC. REPORT

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11 ; \

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MINERALOGY INCORPORATED ~~~@~UW(@

SEP 2: 1989 CH2M HILL

AUSTIN ~3~22~3~Eo-s~t~15~t~h~S~tre-e~t~/T~u~ls-o-O~kl-o~h-om--o~7~4~1O~4-/(79~18-)=74-4--~32~3~4 Where Science Gets Down to Earth

August 20, 1989

B. W. Bruns, P.E. Upper Guadalupe River Authority 215 West Water Street Kerrville, TX 78029

SUBJECT

>tc..' R. Ft~~/i::JP; D- P¥A/6-/~N~

J. I?7c.Lf:DQ/ /fLA..t

~~/' /:) . C;L~h~~/1

X-rav diffraction mineralogy, acid insoluble residue analysis, sieve analysis, porosity, permeability, grain density, specific gravity, c~tion exchange capacity, SEM, thin section, energy dis­oursive chemical analysis, and core photographs with descriptions of five (5) samples from four (4) cores from the Kerrville ASR Project.

CONCLUSIONS

The samnles from four cores were:

481.1'-481.8' A gray dolomitic shale with good porosity (24.3%) but little or no permeability. The shale contained silty, sandy. dolomite streaks and burrows with some scattered glauconite grains. Some of the fine micro shell fragments in the shale were recoved by dissolution leaving scattered minor fine dissolution porosity.

511.5'-512.0' A mottled fractured reddish to brownish, silty, sandy dolomite. The fractures were healed by a fine crystalline grayish dolomite. The porosity was good at 19.2%, but the per­meability was low at 4.48 md. vertical permeability and 38.2 md. horizontal permeability.

539.6'-540.3' A fine sandy dolomite grading abruptly into a do­lomite-cemented conglomerate. The conglomerate had 29.8% poros­ity and 1505.0 md. horizontal permeability. The vertical perme­ability was only 24.7 md. The good permeability follows horizon­tal bedding planes containing high variable porosity. The fine

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Augl.1s: FJ. 1_989 Pafe 2 of 4.

sandy dolomite with the conglomerate had 24.7% porosity and 91.6 md. vertical permeability and 95.3 md. horizontal permeability. The lo~ permeability in the crystalline dolomite is due to the fine pore size. Most of the porosity in the dolomites is micro intercrystalline porosity.

552.5'-553.4' A reddish, very fine crystalline, silty dolomite, with light gray to tan irregualr inclusions and streaks. At 552.5'-552.7' the dolomite was tannish with grayish mottles. The porosity was 18.3%. The permeability was very low at 0.32 md. vertical and 1.71 md. horizontal permeability.

The dolomite s~ples were originally deposited as sandy, silty limestone containing shell fragments and scattered glauconite Brains. Dissolution of some shell fragments created vuggy poro­sity in some core examined. The limestone was recrystallized as fine crystalline dolomite with intercrystalline micro porosity.

The clay in these samples is primarily allogenic and was deposited with the fine silt and sand. Some of the illite and mixed-layer illite/smectite is glauconite. Glauconite is the physical form, a greenish pellet and not a mineral.

DISCUSSION OF RESULTS

1. X-RAY MINERALOGY (Table 1) "

Four of the samples were sandy dolomites to dolomitic, silty, sands. One sample was a dolomitic shale. Most of the illite and mixed-la­yer illite/smectite shown in x-ray results is glauconite with the exception of the shale sar.zple at 481'6"-481'7", where most of the reported illite and mixed-layer illite/smectite is not mostly glau­conite pellets. The feldspar in the samples is K-feldspar.

2. ACID RESIDUE ANALYSIS (Table 2)

The acid residues reflect the amount of carbonate present, primarily dolomite.

3. GRAIN SIZE DISTRIBUTION SIEVE ANALYSIS (Table'3)

These samples were fine to very fine-grained with the exception of the con?lomerate at 539.6'. The particle size of the authigenic dolomite in the samples was very fine. This was also reflected in the high norosities with low permeabilities.

----------------

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:'~l. t.. :) r'..:.ns, '::.:::. "~ugust 20. 19139 Page 3 0: 4.

4. POROSITY, PERMEABILITY AND GR.4.I~1 DEtISITY (Table 4)

The porosities were high but permeabilities were generally low due to dolomite crystal size. The horizontal permeability in the conglomerate was excellent, but due to porosity variations from thin bed to thin bed and to pore size changes, the vertical permeabilities were very low. The grain densities were gener­ally high due to the predominance of dolomite in the samples.

5. SPECIFIC GRAVITY (Table 5)

The specific gravity was lowest in the shale (2.42) and was high­est in the conglomerate and the sandy dolomite associated with the conglomerate. The sandy dolomite was 2.63.

6. CATION EXCHANGE CAPACITY (Table 6)

The cation exchange capacity was greatest in the shale (11.1) but was low in other samples, ranging from 0.7 to 4.5 meg/IOO grams. The low cation exchange reflects the low clay percen­tages, particularily the small amounts of the illite/smectite" mixed-layering. Smectite is the clay mineral with the high CEC.

7. SCANNING ELECTRON MICROSCOPE-SEM (Figures 1-5)

The results primarily show the dolomite with fine micro inter­crystalline porosity. Figure 2 (511'11"-512'0") shows dolomite with fine intercrystalline porosity in the left side~f photograph "A" at 50X and on the right-hand side of the photograph, a very fine crystalline vuggy dolomite. Associated with the vugs is very fine intercrystalline porosity.

8. THIN SECTION PHOTOGRAPHS WITH DESCRIPTIONS (Figures 6-10)

The thin section results show the fine crystal size of the dolo­mite. Figure 6 shows a burrow infilled with silt and carbonate in the left side of the photograph. The burrow is perpendicular to the black organic, thin parallel bedding streaks. The porosity is in streaks parallel to bedding planes and varies from thin bed to thin bed.

9. ENERGY DISPURSlVE-CHEMlCAL ANALYSIS (Figures 11-15)

The energy dispursive analysis reflects the mineralogy which is primarily dolomite, a calcium magnesium carbonate, and quartz, which is silica. Energy dispursive analysis does not detect light elements well. A small magnesium peak is indicative of a consid­erable amount of magnesium. Aluminum reflects feldspar and clay. Iron is associated with clay, dolomite, and primarily as red iron oxide staining samples. Potassium reflects the K-feldspar and illite.

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B. vI. Bruns, P.E:. August 20, 1989 Page 4 of 4.

10. THIN SLAB PHOTOGRAPHS AND DESCRIPTIONS (Figure 16-4 pages)

These results show the general physical appearance of the core with descriptions of the core. Most of the core analyized was a fine, sandy, silty, dolomite. The physical appearance and rock properties varied from thin bed to thin bed within each core.

If there are any questions, please call.

A. Jack Nash

AJN/mcj

cc: John S. McLeod

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TABLE OF CONTENTS

X-ray diffraction mineral percentages ............... Table 1

Acid insoluble residue analysis ..................... Table 2

Grain size distribution (sieve analysis) ............ Table 3

Porosity, permeability and grain density ............ Table 4

Specific gravity .................................... Table 5

Cation exchange capacity (CEC analysis) ............. Table 6

Scanning electron microscope (SEM analysis) ..... Figures 1-5

Thin section photographs and descriptions ...... Figures 6-10

Energy dispursive chemical analysis-........... Figures 11-15

Photos of thin slab core with descriptions ........ Figure 16

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IIpp"r Guadalupe River Authority CII2H II ill

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.-t .... .... (J III III

o "" "" -' .... en en 00'0 '0 ~ 11l.-t .-t t-

.-t C1J C1J 0 P-Io< 10< t-

trc 5

4

4

4

4

lit- Imi a a 1d m _xed, 1av 'r

I

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TABLE 2

ACID INSOLUBLE RESIDUE ANALYSIS

DEPTH PERCENT ACID SOLUBLE

481' 6"-481' 7" .......•.....•......... 14.0%

511' 11"-512 '0" .....•.......... ; ..... 71.4%

539'11" ...............•............. 63.7%

540' '\"-540' 1.\" ...................... 54.7%

·552'7"-552'8" ....................... 34.5%

KERRVILLE ASR PROJECT TEX24486.A1

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G~IN SIZE DISTRIBUTION-SIEVE ANALYSIS

TABLE 3

(3 pages)

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Page 1

srEn: A:~ALYS IS

Sample: 481.8 ' ---"------ Well: Kerrville ASR Project

Sieve Size (in microns) Weight Percent

) 2000 Pebbles

< 2000 ..., 1000 Very coarse grained sandstone

< 1000 7 500 Coarse grained sandstone

< 500 > 250 Medium grained sandstone

< 250 ) 125 Fine grained sandstone .7%

< 125 ) 62 Very fine grained sandstone 2.2%

< 62 (pan) Silt and clay 97.1%

..

Sample: ...:5:..,:;1"'2""' • .,;;;0_' ____ _ Well: Kerrville ASR Project

° Sieve Size (m microns) Weight Percent

)2000 Pebbles

( 2000 )1000 Very coarse grained sandstone

< 1000 '> 500 Coarse gOrained sandstone

< 500 7 250 Medium grained sandstone .1%

< 250 )125 Fine grained sandstone .2%

< 125 7 62 Very fine grained sandstone 31.3%

< 62 (pan) Silt and clay 68.4%

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Page 2

SIEVE ;\;,ALYSIS

Sample: 539.6' --~~----------

Well: Kerrville ASR Project

Sieve Size (in microns) Weight Percent

') 2000 Pebbles 4.9%

< 2000 ...., 1000 Very coarse grained sandstone 29.1%

< 1000 ,500 Coarse grained sandstone 25.1%

< 500 > 250 Medium grained sandstone 15.6%

< 250 ) 125 Fine grained sandstone 4.4%

< 125 ) 62 Very fine grained sandstone 6.4%

< 62 (pan) Silt and clay 14.5%

..

Sample: 540.5' ------- Well: Kerrville ASR Project

Sieve Size (in microns) Weight Percent

)2000 Pebbles

(2000 ) 1000 Very coarse grained sandstone trace

< 1000 ) 500 Coarse grained sandstone trace

< 500 ,250 Medium grained sandstone .3%

< 250 )125 Fine grained sandstone 10.7%

< 125 ,62 Very fine grained sandstone 54.4%

< 62 (pan) Silt and clay 34.6%

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Pa.ge 3

SIEVE A.,\ALYSIS

Sample: 552.6' ......:...~~---- Well: Kerryille ASR Project

Sieve Size (in microns) Weight Percent

'1 2000 Pebbles

< 2000 ..., 1000 Very coarse grained sandstone trace

< 1000 ,500 Coarse grained sandstone trace

< 500 > 250 Medium grained sandstone .1%

< 250 ) 125 Fine grained sandstone 1.5%

< 125 ') 62 Very fine grained sandstone 16.0%

< 62 (pan) Silt and clay 82.4%

...

Sample: Well: -----------------Sieve Size (in microns) Weight Percent

)2000 Pebbles

(2000 )1000 Very coarse grained sandstone

< 1000 ) 500 Coarse grained sandstone

< 500 ,250 Medium grained sandstone

< 250 )125 Fine grained sandstone

< 125 ,62 Very fine grained sandstone

< 62 (pan) S11 t and clay

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=8E 1511151. T "' ... 0I"'1'<>mI 70' 0. M.I.

MINERALOGY. INC.

\Jell KERRVILLE ASR PROJECT Field TEX24486.Al

Sample Depth Perme.abUity-md lNumber Descriotion Horb. Vert.

1. 481 '6"-7" Fr. 1.91 .002

2. 511 '11"-512 38.2 4.48

3. 539'11" Fr. 1505. 24.7

4. 540 '~"-1~" 95.3 91.6

5. 552 '7"-8" 1.71 .32

1 . I I .. I i

I I

I

I •

Porosity %

24.3

19.2

29.8

24.7

18.3

I 1

i !

I

I

TAnTY 4

Lab No. 89-336 Date --------State UGRA

Grain Saturat-ion - % PV Density

OU \Jater ~/cc

2.80

2.77

2.79

..1.J.3..

2.75

. I

I I i

i

I . : I

.J

J I I

I • •

i I , I

I

I J

,

j • I

,

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DEPTH

481'6"-481'7"

511 ' 11 "-512' 0"

539'11"

540'~"-540'llz"

552'7"-552'8"

TABLE 5

SPECIFIC GRAVITY

Gray shale with silty dolomitic streaks

Silty dolomitic sand­stone to sandy dolo­mite

Con~lomerate sandstone with silty dolomitic matrix

Silty dolomitic sand­stone to sandy dolo­mite

Silty dolomitic sand­stone to sandy dolo­mite

KERRVILLE ASR PROJECT

TEX24486.Al

SPECIFIC GRAVITY

2.42

2.46

2.58

2.63

2.54

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DEPTH

481'2"

512'0"

539'6"

540'%"

552'7"

TABLE 6

CATION EXCHANGE CAPACITY

CEC (meg/IOO grams

KERRVILLE ASR PROJECT

TEX24486.Al

11.1

1.2

0.7

2.6

4.5

of core)

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SEM ANALYSIS

FIGURES 1-5

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--~~---

FIGURE 1

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

481'6"-481'7"

A&B Black, thin-bedded shale. Small fossil shell fragments. No visible porosity.

C&D Carbonate fragment with pinhole dissolution. Thin-bedded shale platelet shown in photograph at 2000X.

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A.

\'. '. . ~:1't q.. ~. I'i~ .

-

":'!Ii:; ':':f. Y

I ":J!-:1 ~tA·

c.

T5. NO,

50X

500X

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.A1

481'6"-481'7"

,200 1-', B.

, 20 t' , D.

DATE

200X , 50 I-' ,

2000X 5 I-' ,

FIGURE 1.

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FIGURE 2

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

511 '11 "-512 '0"

A&B Sandy dolomite with well-rounded fine sand and silt grains. Intercrystalline porosity and dis­solution of scattered grains on the left side of the photograph at SOX. On the right side of the photograph at SOX is finer crystalline dolo­mite with vuggy and fine dissolution pores.

C&D Dolomite crystals with intercrystalline porosity. Dolomite crystals and a rounded fine sand grain in photograph at 500X.

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A. 50X

c. 500X

TS. NO.

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.A1

511'11"-512'0"

,200 1-', B.

, 20 t' , D.

DATE

200X , 50 I-' ,

2000X 51-',

FIGURE 2.

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1 I _ I

I

J J J

J

J

FIGURE 3

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

539'11"

A&B Dolomite cemented congolomerate pebble in upper left side of photograph at SOX.

C&D Dolomite crystals cementing congolomerate grains. Intercrystalline porosity between dolomite cry­stals.

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I

A. sox

c. 500X

TS. NO.

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.A1

539'11"

,200 1-', B.

,201-', D.

DATE

200X , 501-',

2000X I 5 ...

FIGURE 3.

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FIGURE 4

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

540'%"-540'1%"

A&B Sandy. fine crystalline dolomite. Well-rounded fine sand grains.

C&D Intercrystalline porosity between dolomite grains.

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I

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.A1

< '. ~."..... ;V~\ ..... "'\ .~~ ..... -• __ " "" ..... cot. ~ ~~ ... "':','\ .... <.." ~-"'- po . - ... ~.' .•. ~ 7" ... !'- ," ;.

•. '>,. ......z.: ..... ,..,... v lo.: .' ..... -{" . "I. . ... - .".J">' W' ."" \.. " ""' ." , ~'" ,... "-io';...--- ...... ~ ,'. • ~~ :'" ~ ," • -. '- .' ~~, :1.'..... ' . """",, .... ' .

. ~. "\i~ "._ r., C"!'-.' • _'. ~ ..... '" ..... 'A. ... . _~~...... .,!~ _~. ~_ ' i.~, .... -. 't· ... , _"- .. ~ .. ~,\ .~ .. ,: .. ,,"~~;,,:,,~h\'~'

-". • ". :..:'~ '1>"1 ,''11..:~~ , " ~ '... "\ :"Y",., ';'-0.; \ ~ .... ..,.- .' I) ":,J' :.r ...... "'_' ::;"'~'~I/" ~~(~I;.' ......... ;..:. rf"

. .::...\ ". ~ ........ ~ .... , .Jl>,.'~ ~ ~ ..... ¥'O ... . , ~ ""i. "~~::..'''' ~ .. ,,~ ....... ..;~ .. ~ ~;':"'~ ¥"

~. ~ -~; t) ~ 1'<, ~,,,,.......' "= ~ '"S "~ -., .;"" ~ "- .. ~~ ..... "- .' X-;: ..... ·~ ..

11 \, ~~ ........ _'"\. ...... ~...., ;- .6.:..~ ,. . ·,.l .... ""'-·;~c,.. ~---... .... '~~'lc r ••.•• '.".~. U~~·, ~. \.~.

' •• ~ a.;. '.' ~':\ :::-,.,,"'" ;..".~.~. ~.~.l:~ .... -. '.~.:-.. ~. "-- .~", . ...... ~ ...... '.' ....,- . '., .'(' -- --' :--' ..... '~,'., ", - ~,;... .. ~

-:::0.'_ f ....... _:-"i ".-C_ . ~.' .,'" .'\t.......~_ .. '-. \ r .... ." '. -, - - :. ..... ~. •.••• ('

".,.f ~~"1 .. .. ......... ..,-- "'- " -'.. ." . •• "~'., -' :',.~. ~ ./---. _. • . . !'" ... :-. .....

. , .::11..'......... - ,,' "'.(~) .'~" .'" "!\' .,.., .... ~., .~" ~,' .~ .. 4 '~-. ' ....... .( , .. _ ~;t, ..-/' .~.. r-'.~."" "" - .. /~'" --.. -- ,. .... :; "'\.' ', .... " \\~' , ....

.,' ,_,.~1!'.:,,-~ , .... " -~,"," .. ','"lo.." ,.J~,".A"t'~-...--,·~ ~'~ ....... ' ........ ;. ..... t-,'-\',

"" .\ '!'\.

"

540'\"-540'1\"

00 B.

c. 500X ! 20 t' ! D.

TS. NO. DATE

200X ,50 I-'!

2000X ~

FIGURE 4.

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FIGURE 5

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

552'7"-552'8"

A&B Very fine-grained, silty dolomitic sandstone to -sandy fine crystalline dolomite. No visible ma­cro porosity.

C&D Small di~solution pore with authigenic koalinite crystals and scattered fine dolomite crystals at­tached to the surface of the pore.

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A. sox

c. 500X

TS. NO.

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

552'7"-552'8"

,200 1-', B.

1 20 t'l D.

DATE

200X 1 501-',

~~:..., ... ..--.~ ~ . J. : "1t:~; ...... ,~~". ..i. u~,DI '.; ~

2000X 5\-'1

FIGIJRF 'i

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-- t

THIN SECTION PHOTOGRAPHS AND DESCRIPTIONS

FIGURES 6 - 10

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FIGURE 6

l'PPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.A1

481'6"-481'7"

THIN SECTION PHOTO 40X

THIN SECTION DESCRIPTION

Gray shale, silty dolomitic streaks. Burrows, some con­taining pyrite as scattered inclusions. Scattered silt­size to very fine sand-size glauconite grains. Dolomite occurs as fine to very fine grains and crystals in the silty streaks. The silty streaks contain scattered minor dissolution porosity. No visible porosity except for minor to trace amounts of dissolution porosity associated with the dolomitic silt and very fine dolomitic sand.

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fIG~?i: 6

UPPER Gl'AD.';'U7E RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

481'6"-481'7"

THIN SECTION PHOTO 40X

x-nicols 7HIN SECTION DESCRIPTION

Gray shale, silty dolomitic streaks. Burrows, some con­taining pyrite as scattered inclusions. Scattered silt­size to very fine sand-size glauconite grains. Dolomite occurs as fine to very fine grains and crystals in the silty streaks. The silty streaks contain scattered minor dissolution porosity. No visible porosity except for minor to trace amounts of dissolution porosity associated with the dolomitic silt and very fine dolomitic sand.

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FIGURE 7

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

511 '11"-512 '0"

THIN SECTION PHOTO 40X

THIN SECTION DESCRIPTION

Very fine, silty dolomitic sandstone to sandy dolomite. Sand grains are subrounded. Scattered glauconite grains. Scattered visible fine dissolution pores in half of the sample with pink hematite staining. The grayish-colored part of the sample has vuggy dissolution porosity. The pores are much larger than in the pink part of the sample.

Porosity in the thin section photograph is shown in blue.

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FIGURE 8

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

539' 11"

THIN SECTION PHOTO 40X

THIN SECTION DESCRIPTION

This thin section shows the contact between a very fine dolomitic sand to siltstone and a conglomerate sandstone nade up of rounded quartz and rock fragment grains up to pebble size, cemented by fine crystalline, silty, sandy dolomite. One or two well-rounded dolomite pebble grains. Scattered macro and micro dissolution porosity in the con­glomerate matrix. Some fractured pebbles and grains with inherited healed fractures. Some grains show undulatory extinction due to metamorphic strain. The finer dolomitic sand to siltstone has scattered minor dissolution porosity, and is cemented with red hematite-stained dolomite. There are a few scattered fine glauconite grains. The contact between the fine sand to siltstone and the conglomerate is irregular with scattered coarse grains scattered into the fine siltstone to sandstone. The conglomerate has fair visible macro porosity.

Porosity in the thin section photograph is shown in blue.

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FIGL'P":: 8

UPPER GUADALl'PE RlrER AUTHOF-I-:-Y

KERRVILLE ASR PROJECT TEX24486.Al

539' 11"

THIN SECTION PHOTO 40X

x-nicols THIN SECTION DESCRIPTION

This thin section shows the contact between a very fine dolomitic sand to siltstone and a conglomerate sandstone ~de up of rounded quartz and rock fragment grains up to pebble size, cemented by fine crystalline, silty. sandy dolomite. One or two well-rounded dolomite pebble grains. Scattered macro and micro dissolution porosity in the con­glomerate matrix. Some fractured pebbles and grains with inherited healed fractures. Some grains show undulatory extinction due to metamorphic strain. The finer dolomitic sand to siltstone has scattered minor dissolution porosity. and is cemented with red hematite-stained dolomite. There are a few scattered fine glauconite grains. The contact between the fine sand to siltstone and the conglomerate is irregular with scattered coarse grains scattered into the fine siltstone to sandstone. The conglomerate has fair visible macro porosity.

Porosity in the thin section photograph is shown in blue.

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FIGURE 9

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

540'i:"-540'H"

THIN SECTION PHOTO 40X

THIN SECTION DESCRIPTION

Very fine crystalline, sandy, silty, dolomite. Scat­tered dissolution porosity. Scattered green glaucon­ite grains. Thin-bedded streaks of pink iron-staining, marking thin bedding planes. Some quartz grains are partially replaced by dolomite along grain edges. Mi­nor intercrystalline porosity.

Porosity in the thin section photograph is shown in blue.

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FIGURE 9

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

540'~"-540'1~"

THIN SECTION PHOTO 40X

x-nicols THIN SECTION DESCRIPTION

Very fine crystalline, sandy, silty, dolomite. Scat­tered dissolution porosity. Scattered green glaucon­ite grains. Thin-bedded streaks of pink iron-staining, marking thin bedding planes. Some quartz grains are partially replaced by dolomite along grain edges. Mi­nor intercrystalline ~orosity.

Porosity in the thin section photograph is shown in blue.

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FIGURE 10

UPPER GUADALUPE RIVER ACTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

552'7"-552'8"

THIN SECTION PHOTO 40X

THIN SECTION DESCRIPTION

Thin-bedded, very fine silty dolomitic sand to sandy dolomite. Pink staining from oxidized iron. Scattered thin argillaceous beds. Brownish color in some thin beds may be organic streaks. A few scattered fine sand grains. Scattered fine particle-sized green glauconite grains. Minor amounts of very fine dissolution porosity. Some quartz grains are angular and other grains are well rounded.

Porosity in the thin section photograph is shown in blue.

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ENERGY DISPURSIVE CHEMICAL ANALYSIS

Figures 11-15

~-~~~--------

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FIGURE 11

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.A1

481'6"-481'7"

PR= 5 2SSEC P=128 H=10KEU l:lQ

K Z=14 SI 9 HIT

AQ=10KEV II:!

I

AL

*1 GRAY SHALE

CA

K FE

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I

I

PR= ~1=512

FIGURE 12

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.A1

5-1'11"-512'0"

- -- . -- -.. ;, . ; ~, .. K 2=16

S 24SEC e H=10KEIJ 1 : 1 Q AQ= 1 0KEV

2 CI=I

SI

MG I<

FE

... v

INT

lQ

XES 4KEIJ >:

- , ,

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PP.= U=64

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.A1

539'11"

U' 2=20 CAl

I

S 1598£C

H=U~KEIJ 1:112

:3

CA CONGL

, e I NT;

, AQ= 1 eKEI) 1 ~f , ,

, ':. ~ ,

l , ;

, ,

_. 'L ~ ...

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FIGURE 14

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

5401~"-540'H"

LK Z=20 CA

PR= S 22SEC e HIT

t l =128 H=10KEIJ 1: lQ AQ=10KEI) lQ

I . .. . . . I

Me;

., .,

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, , • , .

FIGURE 15

UPPER GUADALUPE RIVER AUTHORITY

KERRVILLE ASR PROJECT TEX24486.Al

552'7"-552'8"

MLK MODE!' SELECT ELEMENT

K Z=14 SI

PR= S :9SEC " INT

1..'= 128 H= 1 eKEIJ 1: 1 e AQ= 1aKElJ H~

1.

Me;

AL K

5 CA

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DESCRIPTION OF CORE

Figure 16

(4 pages)

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481.1'

481.1' -481. 8 '

Gray, Thin-bedded shale. Light tannish gray-colored dolomite streaks and inclusions. Scatter­ed calcareous micro fossil in­clusions. Scattered burrows in­filled with fine sand.

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539.6'

539.6'-539.10'

Tan to pinkish; coarse-grainec well-rounded, dolomite-cementec conglomerate sand. There is a coarsening upward in particle s from coarse sand to conglomerat sand with pebbles, changing to fine sand at 539.10'.

539.10'-540.0'

A fine-grained dolomitic sandstc to sandy dolomite with mottled gray streaks and inclusions. So grayish, very thin streaks of fi cross bedding.

540.0'-540.3'

Tan to gray, fine-grained dolo­mite-cemented sandstone to sandy fine crystalline dolomite.

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552.5'

552.5'-552.7'

Mottled gray and yellowish fine grained dolomite-cemented sand­stone to sandy fine crystalline dolomite. Some very thin para­llel bedding.

552.7'-553.2'

Red to pink, very fine-grained dolomitic sandstone to sandy fin crystalline dolomite showing slight undulated bedding with white to grayish inclusions.

553.2'-553.4'

Red and pink fine-grained dolo­mitic sandstone to sandy fine crystalline dolomite with tannish grayish-white irregularly shaped blob-like inclusions.

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DFW0701014.50

Appendix D PUMP TEST RESULTS

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PUMP TEST 2 - DRI'MDOWN UGRA SITE WELL PZ-l

TIME DRAW- FLOW DEPTH TO (MIN) DOWN (FT) (GPM) WATER (FT)

0 0 0 204.2 0.1 20 196 224.2

4 43 150 247.2 15 92 150 296.2 30 85.5 148 289.7 65 80.8 150 285 91ZJ 85.5 151ZJ 289.7

121ZJ 81ZJ.8 150 285 151ZJ 83 151ZJ 287.2 185 67 150 271.2 211ZJ 83 151ZJ 287.2 240 81 150 285.2

~~~----.------

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PUHP TEST 2 - mOVERY UGRA sm WILL PZ-1

r' TIHI mov, DIPTH TO RECOVERY RES! DUAL (HIN) TIHE WATIR (IT TIi' mT niT

240,50 8.00 285.28 iRR 20U0 81.06 242.00 U8 223.80 161.33 aH6 18.80 U2.36 1.80 22U6 134.61 a6.60 16.80 242.S0 2.16 220.00 115.52 139.68 15.86 243.58 3.8e 218.60 81.11 131.00 13.80 245.8e 4058 216.80 54.44 135.0e 11.88 249.0e 8.58 214.08 29.29 133.00 9.88 261.00 28.50 212.88 12.13 131.00 1.88 275.66 34.50 2l1.6e 1.91 136.68 6.86 295.eO 54.50 218.00 5.41 129.88 5.88 318.00 69.50 289.50 U6 128.58 5.30

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PU~P TEST 3 - DRAWDCilN POST ACID!1ICmOH UGR! SITH WELL PH 9-21-89

rlHE DRAW- FLOW DEPTH TO IHIN) DOWN (FT) (GP~I WATER (F!i

6 6 6 261 U3 5 155 266 0.3 15 155 216 U i2.8 155 213.8

1 13.1 155 214.1 1.5 13.3 155 214-3

2 13.4 155 21404 2.5 13.55 155 214.55

5 14.1 155 215.1 19 15.3 155 216.3 15 15.7 155 216.7 38 16.4 155 217.4 68 18.2 155 219.2 98 19.25 155 226.25

185 19.6 155 226.6 120 19.95 155 m.95

12U 21.5 175 222.5 121 21.6 175 222.6 122 21.7 175 222.7 125 21.9 175 222.9

127.5 22 175 223 139 22.15 175 223.15 m 22.3 175 223.3 158 22.8 175 223.8 165 23.15 175 22U5 188 23.5 175 224.5 181 25.3 195 226.3 182 25.4 195 226.4 183 25.6 195 226.6 185 25.75 195 226.75 199 26 195 227 195 26.25 195 227.25 21& 26.1 195 227.7 211 28.1 218 229.1 212 28.2 218 229.2 213 28.3 216 229.3 215 28.4 219 229.4 225 28.8 216 229.8 239 29 2!e 236 240 29.25 210 236.25

Tom Q (GALLONS) : 41250

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PUMP TEST 3 POST ACID - RECOVERY UGRA SIn WILL PH 9-21-89

Y' TIME RiCOV. DEPTH TO RECOVERr RESIDUAL [HIN) TIllE TIT' WATKR (f1J (YKiT) (HiT)

240 0 ERR 230.25 0 29.25 240.l 0.1 2401 225 5.25 24 248.2 0.2 1201 221 9.25 20 24e.5 0.5 481 217 13.25 16 241.2 1.2 201 215 15.25 14 242.3 2.3 105 214 16.25 13 244.5 4.5 54 213 17.25 12 248.5 8.5 29 212 18.25 Il 255.6 15.6 16 211 19.25 10 266.9 26.9 10 210 20.25 9

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tUM? TEST NO.4 8 HOuR DURATiON m G?H FLOW VOLUllK UGRA II1P PH mmBKR 22, 1989

TIME DRAHOOWll WmR (HIN) (1IKTJ Lim

0 9 202.4 e.e5 5 297.4 US 9.6 212 8.33 12.6 215 9.75 14.6 217 1.16 15.6 218 1.6 16.6 219 U 11.6 ~~j

3 18.1 228.5 5 17.8 m.2

8.5 18.6 221 10 18.9 221.3 12 19.25 221.65 15 19.66 222.86 38 21.5 223.9 45 22.58 224.98 68 23.46 225.86 75 24.12 226.52 95 25.&2 227.42

185 25.35 227.75 128 25.86 228.26 135 26.33 228.13 158 26.8 229.2 165 27.18 229.58 188 27.55 229.95 195 27.87 238.27 218 2B.36 238.76 225 2B.76 231.16 248 29 231.4 278 29.55 231.95 388 38.84 232.44 365 38.72 233.12 398 31.24 233.64 m 31.56 233.96 458 31.94 234.34 488 32.22 234.62

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Pij~P TKST NU - mom? UGRA SITE wELL PZ-I mmm 22. 1989

r' TIME Rieov. DKPTH TO RKCOVERY RESIDUAL (HIN) TIHE TIT' WAnR (fT) mKT) (flKTJ

!8e e ERR 234.62 6 32.22 480.l e .1 4B61 230 4.62 27.6

480.13 0.l3 3693.397 225 9.62 22.6 486.2 8.2 2401 220 14.62 17 .6

483.75 3.75 129 217 17.62 14.6 487.2 7.2 67.66666 216 18.62 13.6 492.5 12.5 39.4 215 19.62 12.6 589.5 26.5 21.41463 214 26.62 11.6 511.7 31.7 16.14195 213 21.62 18.6 527.5 47.5 11.10526 212 22.62 9.6 549.5 69.5 7.906474 211 23.62 8.6 584,5 184.5 5.593361 210 24.62 7.6

591.25 11!.25 5.314606 299.5 25.12 7.1 617 137 4.593649 28B.8 25.B2 6.4

165e 1170 1.410256 293.65 30.97 1.25

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(

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;--~---~--'-­i r"- .-..

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~.JU: 1L,[:J,; UF 1 hlL it'Jt..J r 'l_l II',J r~. -~ . .-r (,'0 r I" I 1'11111[111':" 1

X (T I 11E.1··CI:IDf<11 I Ni\ If UF f"If II,J I I ~III") :' .11LH"'I)· .. ',.'

Y (Imr;vJl)OWNI-I:O[]l{[)HIATE OF FOINr (I r I~ :;.LILJLlI.JO'L'lCl

F'l1I NT NUM1'ER= 2 X (TIME I-COORDINATE OF POINT (MINI~ 6.0011~D-02 Y (oRAWoOWNI-COORDINATE OF FOINT (FTI= 9.60~~D+l1LJ POINT NUMBER= 3 X (TIME)-COORDINATE OF POINT (MIN)= 3.30~0o-01 Y (oRAWoOWNI-COORoiNATE OF POINT (FT)= 1.260~D+~1 POINT NUMBER= 4 X (TIMEI-COORoINATE OF POINT (MIN)= 7.50000-01 Y (DRAWoOWNI-COORoINATE OF POINT (FT)= 1.46000+01 POINT NUMBER= 5 X (TIME)-COORDINATE OF POINT (MINI= 1.16000+00 Y (oRAWoOWNI-COORoINATE OF POINT (FT)= 1.5600D+01 POINT NUMBER= 6 X (TIMEI-COORDINATE OF POINT (MIN)= 1.60000+00 Y (DRAWoOWNi-cOORoINATE OF POINT (FT)= 1.66000+01 POINT NUMBER= 7 X (TIMEI-COORDINATE OF POINT (MIN)= 2.3000D+00 Y (DRAWDOWN)-COORDINATE OF POINT (FTI= 1.7600D+01 POINT NUMBER= 8 X (TIME)-COORoINATE OF POINT (MINI= 3.0000D+00 Y (DRAWDOWN)-COORoINATE OF POINT (FT)= 1.8100D+01 POINT NUMBER= 9 X (TIME)-COORDINATE OF POINT (MIN)= 8.~,000D+00 Y (DRAWOOWN)-COORoINATE OF POINT (FT)= 1.86000+01 POINT NUMBER= .10 X (TIME)-COORDINATE OF POINT (MIN)= 1.00000+01 Y (ORAWDOWN)-COORDINATE OF POINT (FT)= 1.89000+01 POINT NUMBER= 11 X (TIME)-COORDINATE OF F'OINT (MIN)= 1.20000+01 Y (ORAWDOWN) -COORDINATE OF POINT (FT) = 1. 9250D+01 POINT NUMBER= 12 X '(TIMEI-COORDINATE OF POINT (MIN)= 1.50000+01 Y (DRAWDOWN)-COORDINATE OF POINT (FT)= 1.9660D+01 POINT NUMBER= 13 X (TIME)-COORDINATE OF POINT (MIN)= 3.0000D+01 Y (DRAWDOWN)-COORDINATE OF POINT (FT)= 2.1500D+I2I1 POINT NUMBER= 14 X (TIME)-COORDINATE OF POINT (MIN)= 4.51211211210+1211 Y (DRAWDOWN)-COORDINATE OF POINT (FT)= 2.258I21D+I2I1 POINT NUMBER= 15 X (TIME I-COORDINATE OF POINT (MIN)= 6.00000+01 Y (DRAWDOWN)-COORDINATE OF POINT (FT)= 2.3461210+1211 POINT NUMBER= 16 X (TIMEI-COORDINATE OF POINT (MIN)= 7.501210D+01 Y (DRAWDOWN)-COORDINATE OF POINT (FT)= 2.4120D+01 POINT NUMBER= 17 X (TIMEI-COORDINATE OF POINT (MIN)= 9.5000D+01 Y (DRAWDOWN)-COORoINATE OF POINT (FT)= 2.502I21D+I2I1 POINT NUMBER= 18 X (TIMEI-COORDINATE OF POINT (MIN)= 1.051211210+1212 Y (DRAWDOWNI-COORDINATE OF POINT (FT)= 2.535I21D+01 POINT NUMBER= 19 X (TIMEI-COORDINATE OF POINT (MIN)= 1.200I21D+02 Y (DRAWDOWNI-COORDINATE OF POINT (FTI= 2.5861210+1211 POINT NUMBER= 20 X (TIMEI-COORDINATE OF POINT (MINI= 1.3500D+12I2 Y (DRAWDOWN)-COORDINATE OF POINT (FT)= 2.63300+01 POINT NUMBER= 21 X (TIME)-COOROINATE OF POINT (MIN)= 1.5~00D+m2

._------ - .......... .

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(

i r- --,---f-:-;-L-7-~ --- -----;--:­; ~-----~ ----7~1-I .

,-~--~ I I , I , ,-­i i __ - __ _

PROJECT NO. ________________ _

POINT NUMBERm 22 X (TIME)-COOROINATE OF POINT (MIN)m 1.65~mD+~2 Y (DRAWDOWN)-COORDINATE OF POINT (FT)m 2.718~O+~1 POINT NUMBERm 23 X (TIME)-COORDINATE OF POINT (MIN)m 1.8~~~D+~2 Y (DRAWDOWN)-COORDINATE OF POINT (FT)m 2.755~D+~1 POINT NUMBERm 24 X (TIME)-COORDINATE OF POINT (MIN)m 1.9::'~~D+~2 Y (DRAWDOWN)-COOROINATE OF POINT (FT)= 2.787~0+~1 POINT NUMBERm 25 X (TIME)-COOROINATE OF POINT (MIN)m 2.10000+02 Y (ORAWDOWN)-COORDINATE OF POINT (FT)m 2.836~D+01 POINT NUMBER= 26 X (TIME)-COORDINATE OF POINT (MIN)= 2.2500D+02 Y (ORAWOOWN)-COOROINATE OF POINT (FT)= 2.87600+01 POINT NUMBER= 27 X (TIME)-COORDINATE OF POINT (MIN)m 2.4000D+02 Y (ORAWDOWN)-COORDINATE OF POINT (FT)m 2.90~0D+01 POINT NUMBER= 28 X (TIME)-COORDINATE OF POINT (MIN)= 2.7000D+02 Y (DRAWOOWN)-COORDINATE OF POINT (FT)= 2.9550D+01 POINT NUMBER= 29 X (TIME)-COORDINATE OF POINT (MIN)= 3.0000D+02 Y (DRAWOOWN)-COOROINATE OF POINT (FT)m 3.00400+01 POINT NUMBER= 30 X (TIME)-COORDINATE OF POINT (MIN)= 3.6500D+02 Y (DRAWOOWN)-COOROINATE OF F'OINT (FT)= 3.0720D+01 POINT NUMBER= 31 X (TIME)-COORDINATE OF POINT (MIN)= 3.9000D+02 Y (DRAWDOWN)-COOROINATE OF POINT (FT)m 3.12400+01 POINT NUMBER= 32 X (TIME)-COORDINATE OF POINT (MIN)= 4.20000+02 Y (ORAWDOWN)-COORDINATE OF POINT (FT)= 3.1560D+01 POINT NUMBER= 33 X (TIME)-COORDINATE OF POINT (MIN)= 4.5000D+02 Y (DRAWDOWN)-COOROINATE OF POINT (FT)= 3.19400+01 POINT NUMBER= 34 X (TIME)-COOROINATE OF POINT (MIN)= 4.80000+02 Y (DRAWDOWN)-COORDINATE OF POINT (FT)= 3.2220D+01 PRODUCTION WELL DISCHARGE RATE (GPM)= 2.5000D+02 DISTANCE FROM PRODUCTION WELL (FT)= 1.0000D+00

COMPUTATION RESULTS:

AQUIFER TRANSMISSIVITY (GPD/FT)= 11128.00 AQUIFER STORATIVITY (DIM)= 8.668E-03

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DFW0701014.50

Appendix E CHEMICAL DATA

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/

( \

SAN ANTONIO TESTING lABORATORY

4733 RITIIMAN ROAD 201 t SPRING Sf.

SAN ANI0NIO, TEXAS 78218 BRACKETlVILLE. TEXAS 78832

(512) 599- 7670 (512) 563-2124

RE1)(}}'tt OF CHEXICAI. UAI.YS1S

Upper Guadalupe RivaT Authority P.O. Box 1278 Ker-rvi He, TX 76029

ATTJl: ){r. Charlie 'o'1edenleld

ASR 'iEST

PARAII.h'1·~R

Silica Mg K -Al Cu Kn Zn Cd Sa Na ColClr' Fluid Dcncit..y ~s

YELl, Fl I.:r SRED

RESUl..TS

3.3 lDg/L 48 D1glL

'/ -!) mg/L (). 1 mglL

<.0.02 lDglL 0.0" mglL O. C!4 mp;/L ~O.Ol mg/L <0.01 JUg/L 37 Jagft 39 Color

O.9'i;;! g/mI () tug/L

RHPORT ra. 1&46 Pagel 1

Date Reported: 10-05-89 Date Received: 9-22-89 Sample: Yalar

UGRA ViP FIJISH1ill H2O

RBSUl,l'S

,\,9 rng/L 19 l1Igll. 1.3 Illg/L 0.2 l!lf:/L

{0.02 rug/L <0_01 11lg/L

(L Oti mg/L (0.01 mglL (0.01 mg/l.

1 1 mg/L Unit!. 1 Color Unila

0.991 g/mi <l rng/L

mg/L: g/ml: T~r;t ~nthod:

Ki 111 graDIC P(:![' I.! leT Gr'illII'':; per lH ~ 111 iter K~thods for GIlQ1ll1cal AnalyEl~ of \later and Wastes,

jii'A ·{)00/4 .'/9' 020, RaviGcd March 1983 !::tllndal'd MethorJs for the F.xI'IJnin.,tlon of Vater I'Ind

Vu~tewo.tcr, 16t.h F.dition, 1!'!85

1'e6t Conducted by: Jolin D. Burch

~p.spect!ully Submitted,

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f

LHE'·llt .... L. hf\J(~i, IS l:; Ci'v LJGI;t-4. L~b

(.9 ( 1 71f~9

A!,R I [S I wt=.i.i UGI-{A wrp F INl~;HE.tl (~AlER

Parameter Spl S.., 1 .' Avg Spl 1 =:".,=,==- .":::""'=.:::.-.;;:;:=:::

!J?~~ .. ____ .. __ .F. ___ .. :1.3

. 2.8 2.8

.942 942

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399

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I _.334 ___ .... _~.7~ 331 t _.33..4 ___ .... .J~. ___ .. ·~3~.·= -.....

- TDS._. __ .. ___ E_ .. _-.5.5~ ___ . '. ~91 __ ... _ .. 5~L_.

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- -'£'L_ ... _. ___ f:_.

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262

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J!~J.

.. J~ .. 919.

70 65 68 ._-- ... -.------4......::=---

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0.010 0.011 --- ._---_ ..... __ ....... _-

2.3 2.3

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( "

4733 RITTIMAN ROAD 201 E. SPf~ING ST,

SAN ANTONIO TESTING LABORATORY

SAN ANTONIO, TEXAS 78218 BRACKETTVILLE. TEXAS 78832

(512) 599-7670 (512) 563-2124

UPPER GUADALUPTE RIVER AUTHORITY PAc;iE 4 SAMPLE I. D. : UGRA WTP

FINISHED H20

HALOGENATED AND AROMATIC VOLATILE ORGANICS ======;===========~==~====:~;=~=~===~===~:=:~::=~~=~====~=====~============

I : RESULTS :DETECTION: PARAMETERS IMETHOO: ug/L ILIMITug/L : ANALYST:

======:.===:~::=====:=~;:=~;==~~:~==~==::===~:==~==~~::t~==t:==~=:~===~~=: Bromoform :EPA 624: <5 : 5 : OM :

--------------------------------:-------J-------------:----------;-------: carbon Tetrachloride :EPA 624: <5 : 5 : OM:

--------------------------------;-------:-------------:----------J-------: Chlorobenzene lEPA 624; <S 5: OM : --------------------------------:-------l----------~--:----------1-------1

I Chlorodibromomethane IEPA 624: <5 5 OM I :--------------------------------:-------;-------------;---------- -------: I Chloroethane : EPA 624: <5 150M :

~------------------------------~-:-------:-------------:---------- -------! I 2-Chloroethylvinyl Ether IEPA 624: <5 I 5 DM : :---~----------------------------:-------:---------~---:-~-------- -------: d

! ~~mI~~~g~~~~~;;~~~~~~~~~~~~ · ~~~~~~~ i ~~~~~~~~~~~~.~: ~~:~~~~~~~ · ~~~~~-l J I : Diehl orodifl uoromethane EPA 624: <5 '4-<,' :' 5,' DM' :'>a ~ , -------------------~.;..~---- ... ------ -------. ----------~--, -------~-- -------1'· :-.~-:--:;;;: . : l,l-Dichloroethane . ,EPA 624: <5 i. 5:~:;< OK l':-:;:~ J ---------------------------..:.----: -------I-------------I---'----~·:_-: ----~--1 ,:.",:\'~'-I 1,2-0ichloroethane IEPA 6241 <S ' I 5 : OK; ,--------------------------------:-------:------'----~--:--------~-:-------: , 1,1-Oichloroethl'lene IEPA 624: <S : 5 OM : ---------------------.-- ---------: -------: ------------ -: -- .... ------- : -------:

l,2-0ichlot'opropane :EPA 6241 <5 : 5 : DM : --------------------------------:-------:-------------:----------~-------~. trans-l. 3-Dichloropropylene : EPA 624: <5' : 5 : OM

--------------------------------:-------:------------- :----------1-------1 l.l,2,2-Tetrachioroethane :EPA 6241 <5 : 5 : OM

-------------~------------------:-------:-------------:----------;-------: Tetrachloroethylene 'EPA 624: <S S: DM :

t -------------------------------- -------:-------------:----------1-------: : trans-l,2-0ichloroethylene EPA 624: <5 : 5 : OM ._-------------------------------• -------I-------------:----------I-------~ : i,l,l-Trichloroethane EPA 624: <5 : 5 : OM : ._------------------------------ -------;-------------:----------:-------: 1,l,2-Tt'ichloroethane EPA 624: <S : 5 I OM :

:-------------------------------- -------:-------------:----------:-------: : Trichloroethylene :EPA 624: <S 5: DM :--------------------------------:-------:-------------:----------:-------: : Trichlocofluoromethane !EPP. 624: <5 5 OM =====~====::=======:~=======~==~==~====~~=~=~~======~~========~~=========~=

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(

SAN ANTONIO TESTING lABORATORY

<1733 RITIl(vlAN ROAD 201 E. SPRING ST. SAN ANTONIO. TEXAS 78218

BRACKETNILLE. TEXAS 78832 (5.12) 599-7670 (512) 563-2124

UPPER GUADALUPE RIVER AUTHORITY PAGE 3 SAMPLE 1. 0 _ :

PARAMETERS ;==;==:~==============~========== 1 Vinyl chloride t~-------------------------------IBis(2-chloroethoxy)methane --------------------------------Bis(2-chloroisopropyl)ether

l\SR WEST WELL FILTERED

RESULTS IDETECTION I I METHOD: ug/L ILIMITug/L I ANALYST I ======;'======:~===;=1=;=:======!====;==: EPA 624: <5 I 5 I DM : ---~---:-------------~----------t-------: EPA 6241 <10 : 10 I OM -------:-------------:----------1-------; EPA 624: <10 10 OM:

-------------------------------- -------;-------------:----------:-------~ 1,2-Dichlorobenzene EPA 624: <5 : 5 : OM -----------.-------------------- -------;-------------:------~---:-------: 1,3-Dichlorobenzene EPA 6241 <5 5 OK --------------------------------:-------:------------- I----------:-------~ 1,4-0ichlorobenzene :EPA 6241 <5 I 5, OK I .--------------------------------:-------:------------ -~----------I-------: IBenzyl chloride :EPA 624: <5 1 5/ I OM_: : --------------------------------: -------1-------------: ------~---, ----.:~~-: I Bromobenzene EPA 624: <5 I 5)~»:

f ;;~;~;;~h~~: ------------ -------- ;;~ -~;~ i ---;~ -------- r--~-~~-·--;. --:~~~jrC ! ~hi~;~~~:~~id;b;d;-------------- ;;~-~;~ i ---;~------:- f --::-~;----- -~-~~-'-.l. Pi , _______________________________________ I ______ ~ ____ 2~,~~ ______ ~ _______ ~:~~ ~

i :::~:~:~~.:~~~:-;.---~-~---------- ~:~-~:~ ~ ---~:-:~'_C_~::~~l~L~~ .. ~~~;i S~i_~~;'~I~~' !. :Chloromethane EPA 624' <5 .-~-'." 5-;~"'-' . "DK ... ·:·"';> ,

I ~~g~~~~~~~~:~~~!~~:~~~~ ~~~~~~~~. ~~~ ~m I ~~~~F~~~~~~~ ~~~~p~m~~~~3!~' I 1-------------------------------- -------;-------------;----------:-------: 1 I nibromomethane EPA 624: < 5 I 5 \ DM : ".j~ : - ---- ------- --- - -- ---- -- ---- -- ... - -- - .. - f • , • tj o:ll' - - ,------------- ----------, -------. t '!..' IOichloromethane EPA 624\ <5 5' DM "~l

li~i:i:;:;;;;;~;i~;~;;h;~;-------I;;~-;;;:---~;-------- ----------'-----~-l .• ~ "

_ _ _ __ _ _ ___ _____ _ __ _______ _ _ _____, 5 OM I :,ili _______ ._____________ .. __ • :;4

r::~~~:~:~~:~~~~:---------------- ~:~_~~~! <5 - ~----- ---~~--; •...•. !~.i: 18enzene ,-------------,---------- -------: . ________________________________ EPA 624: <S : 5 OM : lim ! Ethyl Benzene ,;;~-~;~; ---~;--------l----;----- ---~~-- i i Til i ;~;~~~:------------------------- i ;;~-~;;: ---;~--------: ----5------: ---n-M---: [j , f. I :-

.--~-----------------------------!-------:~----------- -:----------:------_. :Xylenes :EI?A 624: <5 : 5 I DM :: =~==~=========~=====~==~:=============~:====~===~=:===~==========:~~~=====~

._------_ ... _---_._-

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(

SAN ANTONIO TESTING lABORATORY

1

1

Ll733 RllTiMAr~ ROAD 201 E SPRING ST.

SAN ANTONIO. TEXAS 78218 BRACKl:lNlLLE TEXAS 78832

(5.12) 599-76701

(512) 56321241

UPPER GUADALUPE RIVER AUTHORITY PAGE 5 SAHPLE LD.: UGRA W'!'P

FINISHED H20

=:==========;==:~~=;==========~=====~::=~==============~===~=;===:=======~= I : RESULTS :DETECTION: :

PARAMETERS :METHOD: uq/L ILIMITuq/L I ANALYST I :===::==~~%=:===~==:::=~:===~~===:=~~;=:=:;===~=;====;=;#======~==I;==~;==: 1 Vinyl Chloride lEPA 6241 <5 : 5 l OM : :--------------------------------:-------:-------------:----------t-------: ISia(2-chloroethoxy)methane lEPA 624: <10 I 10 : OM : :-------------------------~------~-------:-~----~------:--~-------:-------: lBis(2-chloroisopropyl)ether lEPA 624\ <10 I 10 I OM : !-~~-----------------------------:----.--:------------ -:----------:-------: :1,2-Dichlo~obenzene IEPA 624: <S 5 I DM : :--------------------------------:-------i~----------- -;----------1-------; 11,3-Diahlorobenzene lePA 624: <S : 5 : DM I :--------------~-----------------:-------:-------------:----------;-------: :1,4-Dichloroben~ene IEPA 6241 <5 : 5 I DM : 1--------------------------------1--------:------~------:----------:-------: IBenzyl chloride :EPA 624: <5 5 I DM : :-------------------~------------:·------f------------ -:----------:-------: lBromobenzene IEPA 6241 <5 lSI DM : I---------------------~----------:-------:------------ -:.---------:-------:

'IBromomethane lEPA 624: <5 . I 5 I DM I :------~-------------------------:-------:--------~--~ ":----------:-------; IChloroaoetaldehyde :EPA 624\ <5 5: DM. I I--------------------------------I---~---\-------------:----~-----!-------: Il-Chlorohexane tEPA 624: <5' 'I 5 I DM I I ______ --------~----------- ______ I ______ -',-----------__ ' __________ ', _______ ,' C - . ' c. ..--" lChloromethane ... ' ,"~" lEPA 6241 <5, 1- 5 . I .OM :

. f' • ' .. -. ,

1--------------------------------1-------.-------------l----------,----~--I IChloromethylmethyl ether lEPA 6241 <5 15 I DM , _________________________ w ______ : _______ I ___________ • -;----------:-~-----: • 'tS DM :chlorotolucne IEPA 624, <5 I ______ --------------------------~-------:-------------:----------~-------: : Dibromomethane tEPA 624 1 <5 I 5 I DM : ,

______ ~_t _______ I _____________ I,----------I'-------: ------------------------ , .

: Dichloromethane IEPA 624\ <5, : 5 I DM : t I ____ , _____________ t __________ : _______ : , ____________ ~ ___________________ (---, _ t • •

: 1 1 1 2-'l'etrachloroethane I EPA 624 t <5 : 5 t OM ! :_:_:_: __________________________ ~---_---;----~------_ -;----------1-------: :Trichloropropane IEPA 624\ <S . I 5 ~ DM_: t , _______ • _____________ I. __________

c• ____ -(

I--------------------------------: EPA 624: <5 I 5 I DM I IBenzene :: ____________ , __________ : _______ :

:--------------------------------:~;~-~;~i- <s i 5 I DM : ,Ethyl Benzene : ______ ' _____________ 1 __________ 1 _______ : • ________________________________ ._, ' 1

( :oluene !~~~_~~~! ___ ~~ ________ ~,----~-----,---~~--l • - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 1 f , DM'

i!~!=~:!=========~===============~::~=~:!~===~:======= =~====~=====~=======~

1

1

1

1

1

1

1

1

~ 1

i 1 1 1; I .... { I I

, 1

1

1

1

1

1

1

1

1

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(

(

(

SAN ANTONIO TESTING lABORATORY

4733 RITTIMAN ROAD 201 E SPRING ST.

SAN ANTONIO. TEXAS 78218 BR.ACKEnVlllE. TEXAS 78832 (512.) 599-7670

(512) 563-2124

UPPER GUADALUPE RIVER AUTHORITY PAGE 2 SAMPLE 1.0.: ASR WEST WELL

FILTERED

HALOGENATED AND AROMATIC VOLA'i'ILK ORGAlUCS

:=========================~=======:====:==;==;;===:=============;==~===~===

PARAMETERS I I RESULTS I DETECTION I : 'METHOD: ug/LILIMITug/L I ANALYST I

:=~=================;:========;== ~======:~=:~;====~;==:==========J=======: : Bromoform EPA 624' <5 : 5 I OM : ,--------------------------------,

____________________ t __________ ~_------:

I Carbon Tetrachloride EPA 624 < 5 5: DM I l~------------------------------- ----------:-------: I Cblorobenzene ,EPA 624 <5 5 DM :---------------------------~----:------- ------------- ----------:-------: : Chlorodibromomethane IEPA 624, <5 5 DM : :-------------~~-----------------:-------:------------- ---------- -------: : Chi oroethane : EPA 624 4 <5 150M : --------------------------------1------- --- ----------: -----.----- --:---~:;;.-:-. : 2-Chlot:'oethylvinyl Ether IEPA 624 <5 5 DM~,: : _______________ : ______ o __________ t ____________________ : ________________ ~:

I Chloroform E:PA 624 <S 5 DM :' , ----------------~.---------------I .

I Dichlorobromomethane . ----------------..;...:..------ ----~----I . : ',.

I Dicblorodifluoromethane

EPA 624 ~ ~~: ~: ~ ~ ~ ~ ~;: ~~ ~:~~~~::! ~~:~~!I < 5 5., .'0 , DM·.~,,· ,.;.-------------- ---..;~~.~::...:~--. -----..!.~-.~: <5 .... 5'i~>' : ··DM~·t~;

EPA 624

:-------~--------~---~----------- -------: l,l-Dichloroethane . 'EPA 624

--- ----:.-,---- f -.---------I--·---i~ t:: <5 5 DK'-'<~:'

;--------------------------------: 1,2-Dichloroethane EPA 624

:-------------------------------- -------------:----------:----~-~~ : l,l-Dichloroethylene EPA 624 <5 5: OM. I :-------------------------------- ------- ------------- ----------:-------J : 1,2-Dichloropropane EPA 624 <5 5 I OM' I : ----- ...... -------------------------- -- .... ---- ------------- ----------: ----.,;;...~_- t : trans-l,3-0ichloropropylene lEPA 624 <5 5 DM I 1--------------------------------:------- ------~------ ----------:-------: I 1,l,2,2-Tetrachloroethane :EPA 624 <5 5 DK I :-----------------------------~--~-------t-------------.---------- -------1 I Tetrachloroethylene IEPA 624: <5 150M :--------------------------------:-------:-------------;---------- -------~ I trans-l,2-Dichloroethylene lEPA 624: <5 5 DM :--------------------------------:-------:------------- ---------- -------: : l.l/l-Trichloroethane :EPA 624: <5 5 OM : !--------------------------------:-------:------------- ---------- -------1 : l.l,2-Trichloroethane :EPA 624: <5 5 OM , __________ --- ___________________ 1 _______ , ____________ _

, ' , ---------- -------: : Trichloroethylene !EPA 624: <5 5 DK : ,-------------------------- ______ 1 ______ -1------------_ , , . ----------!-------!

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Texaa Water Development Board

Chemical Water Analysis Report

-MfS6. lJ6K A . AIlrw. 6'9 -'i. I

TOTAL ORGANICS FORM TWDB Use Only

Send Reply To: Ground Water Unit Texas Water Development Board P.O. Box 13231 Austin. Texas 78711

Attention: Bag BWAI1Cffl/fRIc ~/.L),IJ.( J

County: K ~R.

Owner: UPPI!If. Gc.IM>'JJ.t.lPG- .Q V~ IJvrllr~/l7 Address: ________________ _

Date Drilled: Depth: ______ _

Collection Point:D"UlAJe6Fl' /lIN( pH _______ _

By: .....:::::$i..:..;~~c:::...----<.At.::.J>~1 M:...:..:.._.f. ______ _

Requested

Work No. _..::3:...2:.. __ 0...:2--____ _

!ACNo.

State Well Number: ____________ _

Date & Time:

~end Copy To Owner

Sampled After Pumping: ___ ..,..-_____ Hours

~ured Yield: ..2 00 GPM

Temperature:

a Estimated

.. ..;2.·7 ·c 7

Specific Conductance: -..9r-:-:.2~7---------­F/

r· Date Received: ", _....c..---' ____ _ Date Reported: I'lOV 9 'i98':1 Laboratory No.: --------

Total Organic Carbon ___ <..::::::...+1 ___ mg/l

890091·,\

• ~ .-.<: ," ,

Page 122: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

Tesas Water Development Board ""--" '-~--

Chemical Water Analysis Report

Send Reply To: Ground Water Unit Texas Water Development Board P.O. Box 13231 Austin, Texas 78711

GWR-tI6RA= -IW- 89-9-/ (Anions)

TWDB Use Only

Work No. -'S=L:...O..:::L _____ _

lAC No.

Attention: Boa Bt,pAITZ-tiR / ti7l/L }J;f)1.D/f-S i

State Well Number:

County: KSR.R.. Date & Time: ---1;'"1I'-u~/;...;:~'-+1-------Owner: cJP~ C:;(lA-Mf"'M- £, V~ ArnNo~~ Send Copy To Owner

Address: KIF~YU.LE= . Sampled After Pumping: _________ Hours

Date Drilled: _____ _ Depth: _____ _ Yield: ____ GPM Q Measured Q Estimated

Collection Point: 1)I~l&ltI("pH _~70_·,,:,*,,::S",,--__ _ Use: litf>r144 t!?1L Temperature: 22.-7 ·c iffJffIRCt-t:.. ~ ..

By: Eqc. ,fi)1J)A-S

Requested Ch

Laboratory No,," ::f

Sulfate

Chloride

Silica

~yty

Total Alkalinity

(00946)

(00941)

(00950)

(00955)

(00415)

(00410)

Iodide (71865)

Cfht~ B.rc.c..rbonc:trL AI~';'i'

'-\

Specific Conductance: 9.:l7,A!MMJ/idn e Z2.·7·c I

,'.,. • - 10 Date Received: .. ,,:.i' ,.: :-•.

,OQT 31 1989 Date Reported: ______ _ -------

mell mg/l

#-{/.~S -d-.. e -r3!

..fI=TlS7 ·t C, t "1 • O. (}6 /, I d.171 ().O

< (I.{)I ~.v mgll

/I Beren (01020)

~ il'74Rid. (82298)

Jto

..::::; 11.lrJ

1).1 s J.r(J

89009I.C

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TWDBONlV Typewrite jBlack ribbon) or Print Plainly Isoft pencil or black ink)

Do not use ball point pen

Texas Department of Health laboratories 1100 West 49th Street

Organization No . .32.02. lab No. ~m~~ ____ 1

Austin, Texas 78756 Work No. ______________ _

Data Collection and Evaluation Section Texas Water Development Board P.O. Box 13231 Austin. Texas 78711-3231

CHEMICAL WATER ANALYSIS REPORT

&tilfpk -I/: LlGRA -MTW-N-9-/ ~K£R.R County

State Well No. -(]]-[ITJ

Owner UPf'fl<. WIlPALU'PC /!JVffl!.. A-t.r1t1o£/ p/{tMJtJ _ Send copy to owner Sample No. 0 BV _____ _

Addre.. t<6Q ViLlE. Well Location _____________ _

Date Drilled ______ DIlI'th ______ _ ft. WBF _________ _ rrITl Source (tVpe of we'"

Producing intervals Water 'evel _________ ft. Sample depth UUJ ft. [ill nT1 Sampled after pumping ..se.\oC!..13:t I ¢~ hrs. Yield _-"',2;0==:...0=. ______ GPM ::;.8S. T~rature °F~C Point of collection 1>fS c..tItIR.t:rr p61tV'[ Appearance ~ear a turbid a cclored a other Use 7lf.s.TWC'lL.- Remarks ________________________________ _

(FOR LAB

OCT 31 lS89 CHEMICAL ANALYSIS ,".. ~,...- \(' ,"-~I~~;(.·~J.

laborator Date Received _______ _ Date Reported _______ _

MGIL' ME/L

Silica 00955 I I

Calcium' 00915 1 0

Magnesium 00925 '( 7

Sodium' 00930 V I Total

: .' '" ~

009$" : o Potassium

, . 10 Man98n .. 01055

,.. ~\ .

J-+-+-+J4-+~ %Na ____ _

a Boron 01020,,,' '.1 SAR ~~~~'-~~~~+-~ ---------

lO Total Iron 01045 . L-~~~~~RSC ______ __

a lother) _______ _ MG/L

Specific Conductance (micromhos/cm3) 00095 _____ /l/......:6..:J''-__

Diluted c_o_n_d_uc_t_an.L;_e_(m_iC_ro_m_h ... xos_'c_m";';_)~":""'.J.2'-__ = I I d~ H31 .. 0" items wHI bE analyzed if checked.

I The bicarbonate reported in this analysis can be converted bv computation (multiplying bV 0.4917) to an equivalent amount of carbonate, and the carbonate figure used in the computation of dissolved solids.

: Nitrogen cycle requires separate sample. J Total Iron and Manganese require separate sample.

lWDB·0148 (Rev.OS·Ol·B7)

MG/L ME/L II

Carbonall • 00445 () (J e ~ ~ 6 • .s ~ r-

Iff) / Bicarbonate 00440

0 .6 ~ r-r-

J3 Sulfite· 00946

2.. 6 ~ er-t-

7.3 Chloride 00940

O • 0 6 t- t-

J I. I Fluoride 00950

() 0 ~ .t-0 I. 0 9 Nitr.te 71851

I '1',. '1 S ..... ~ .' --pH 00403 Tota

, Dissolved Solids '(mid. 9 I ,eaa 6) 70300 [s I 1

Phenolphthalein Alkalinitv as C aCOl 00415 ~

Totel Alkalinity a. C .COl 00410 :J 2.~

.3 "S' 00900 Total Hlrdn_ IS C IC03

l Nitrogen Cycle

"., .. IIOHia .. N 00610 • r- -

.c:: " () I e - r-00615 Nitrite· N •

0 () I e - r-00620 Nitrate - N

e, .. ,;' Ni,r,..," . 00605 e"-,-

Anllyst __________ Checked By ________ _

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DFW070/014.50

Appendix F GEOCHEMICAL MODELING RESULTS

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,,-EQ3NR. vers ton 3245R 11 I

Copyr'ight (e) 1987 The Regents ot the University of Califorfl1a. Lawrence liver"more National Laboratory. All rights reserved.

Supported ~y EOLIB. version 3245R136

Copyright (c) 1987 The Regents of the University of California. Lawrence Livermore National Laboratory. All rights reserved.

Run 11:54:55 12-0C89

--- readln9 the Input file ---input ftle name= kerr2.3t revised=10/11/89 revisor= rg Kerrville. Texas - ASR Projecti Charge No.; TEX2448S.al

Basic data for EQ3 modeling of Kerrville project received from UICk Glanzman/DEN on October 10, 1989.

This is one of four scenarios. 1) Equilibrium for ASR grolJndwater at a pH of 8.2 2) Equilibrium for ASR groundwater at a pH of 7.3

.......

3) Equilibrium for ASR Water Treatment Plant (WTP) rectlarge water 4) Equilibrium of d 50-50 mixture of one of the above ASR

groundwaters alld the WTP water.

,(:,;,t Thts run is for the ~ scenario wtth pH 8.2.

end it. tempe=

rho= fep=

tolbt= 1termx=

0.23000E+02 0.10000E+Ol

-0.10000E+00 O.OOOOOE+OO

o

tdspkg= O.OOOOOE+OO uredox=

toldl= O.OOOOOE+OO

tdspl:

tolsat=

I 2 o o o o o

3 4 [, 6 7 8 9 10 lopt 1-10= lopgl-IO= loprl-l0=

I apr 11-20= lodbl-l0=

-1 o o o o

uebel= none uacton= cl­

nxmod= 0

0 0 0 0 0

datd ftte master species= na+ switch with species:

0 0 0 0 0

jflag= 2 csp= 0.37000E+02

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

O.OfJOOOE+OO

O.OOOOOE+OO

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"'--. aqueous ~pecies accounting for 99~ or more of o2(aq)

species molal cone per cent

o2(aq) 0.437SE-04 100.00

total 100.00

aqueous species accounting for 99% or more of chJcoo-

species

ch3coo­mgch3coo+

total

molal cone

0.4297E-03 0.9796E-OS

per cent

97.58 2.22

99.80

aqueous species accounting for 99% or mOre of nh4+

species

nh4+ nh3 cu(nh3)2+

total

molal cone

0.719BE-05 0.4672E-06 0.1571E-06

per cent

90.17 5.B5 3.94

99.95

'summary of aqueous redox reactions -----

couple eh, va Its pe- log f02

defau I t -0.100 -0.1702E+Ol -57.696 02(aq) Ih20 0.726 0.1235E+02 -1.473 h2(aq) Ih20 -0.100 -0. 1702E+0 I -57.696 eh3coo- Ihc03- -0.364 -0.6200E+Ol -75.687 cut-+ leu+ -0.100 -0. 1702E+0 1 -57.696 fe+++ Ife++ -0.100 -0. 1702E+0 1 -57.696 hs- Is04-- -0.100 -0. 1702E+0 I -57.696 nh4+ In03- 0.160 0.2723E+01 -39.997 n02- In03- -0.100 -0. 1702E+0 1 -57.696

..~

ah, k'ca I

-2.306 16.741 -2.306 -8.401 -2.306 -2.306 -2.306 3.690

-2.306

summary of aqueous non-equilibrium non-redox reactions -----

couple affinity, keal

none

----- summal-Y of stoichiometric mineral saturation states

(minerals with affinities. It. -10 keal are not listed)

mineral log ql k aff, keal state mineral log q/k aff, keal state

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'--

albite -1.704 -2.309 a I bite high -3.036 -4.114 albite low -1.704 -2.309 ameslte-14a 1.438 1.949 ssatd

8nlrph.silica -1.538 -2.084 analc-dehydr -6.395 -8.666 analcime -1.652 -2.238 andalusite -3.271 -4.433 andradi te 2.724 3.692 ssatd anhydr i te -3.062 -4.149 ann i te 3.302 4.475 ssatd anorthi te -4.793 -6.496 antigorite 6.928 9.388 ssatd aragont to 0.930 1.260 ssatd

arttntte -3.624 -4.911 asher-oft Ita -2.020 -2.738 baSS8n its -3.693 -5.004 beideilit-ca 0.797 1.080 ssatd

beldel I It-k 0.345 0.468 satd be I de 1 I It -mg 0.838 1.136 ssatd

beideillt-na 0.314 0.425 satd ber. inite -6.542 -8.865 boehm1 ts -0.820 -1.111 brewsterite- -0.193 -0.262 satd

brucIte -3.092 -4.190 cahpo4.2h20 -2.354 -3.190 calcite 1.095 1.484 ssstd casi205.2h20 -5.214 -7.066 cas04. 112h20 -3.864 -5.236 chabaz t ts 0.447 0.606 ssatd

chalcedony -0.509 -0.690 chalcocite -7.265 -9.845 chamosite-7a 1.615 2.189 ssatd chrysot tie 0.090 o. 123 satd

cllnochl-I4a 3.149 4.267 ssatd c I "lnach 1-78 -0.240 -0.326 satd

eli nopt i l-c8 -2.445 -3.313 cllnoptll-k -1.036 -1.404 cl Inopt I I-mg -6.564 -8.895 cl inaptt 1-08 -6.275 -8.504 clinozoisite -3.852 -5.220 copper 0.616 0.834 ssatd

corundum -3.855 -5.223 cristobal t te -0.791 -1.072 crist.beta.a - 1.236 - 1.675 cronstedt.-1 9.973 13.515 ssatd

eufe02(e) 9.41 I 12.753 ssatd cuprIte - 1.477 -2.002 dachlardlte- -1.78 I -2.413 daphnlte-14a 6.351 8.607 5satd

daphnlte-7a 2.960 4.012 ssatd dawson it e -0.9B2 -1.33 I diaspore 0.035 0.047 satd dlopslde -2.870 -3.8B9 dolomite 3.242 4.393 ssatd dolomite-dis 1.683 2.2Bl ssatd dolomtte-ord 3.242 4.393 ssatd enstatite -2.359 -3.197 epidote 2.363 3.203 ssatd epidote-ord 2.363 3.203 ssatd eplslllbtte -0.193 -0.262 satd epsomtte -5.340 -7.236 erionite-ca . -0.899 -1.219 faujasite-ca 0.441 0.598 ssatd faujasite-na -4.067 -5.511 fayalite -1.626 -2.204 fe(oh)2(ppd) -2.018 -2.734 fe(oh)3(ppd) -0.590 -O.BOO teo(e) -0.532 -0.720 ferrtte-ca 0.252 0.342 satd territe-cu 0.384 0.520 ssatd ferrite-mg 0.828 1.123 ssatd ferri ta-zn 6.652 9.014 ssatd ferrost lite -0.820 - 1.1" fluorapatite 21.583 29.24B ssatd fluorite 0.81B 1.108 ssatd torstertte -5.700 -7.724 garron i te -0.23B -0.323 satd gibbsite 0.844 1.144 ssatd gismondine 1.101 1.491 ssatd g",el int te-ca 0.447 0.606 ssatd gmeltnlte-na -4.046 -5.483 goethite 3.923 5.180 ssatd greena 11 te 1.492 2.022 ssatd

gypsum -2.969 -3.88B ha lite -7.057 -9.563 hedenbergtte -3.873 -5.248 hematite 8.598 11.651 ssatd herCyntte -1.063 - 1.44 I heu 1 and i te-e -0.520 -0.704 heulandite-n -5.013 -6.793 hexahydr I Ie -5.591 -7.577 hun tit e 0.B65 1.173 ssatd hydromagnesi -6.454 -B.746 hydroJlyapati " .282 15.289 ssatd i I lit e 1.590 2.155 ssatd Jade I Ie -3.092 -4.190 k-feldspar U.~21 0.570 ssatd kallcinlte -6.389 -B.65B kalsll He -2.304 -3.122 kao IInite 1.694 2.295 sS8td kieser-tte -7.100 -9.622 kyard te -2.991 -4.054 lansfordi te. -1.936 -2.624 laumontite -0.287 -0.389 satd lawsonite -0.370 -0.501 leonhardtite -6.337 -B.588 I evyne 0.447 0.606 ssatd magnesite 0.506 0.686 ssatd magne tit e 9.183 12.445 ssatd margarite -2.309 -3.129 max imum m'ler 0.421 0.571 ssatd melantertte -7.319 -9.919 mesol tte 2.840 3.B4B ssatd

rnesol ite-ss -2.146 -2.90B rngf2(c) -1. B47 -2.503 mi,ulttSotai te 1.704 2.310 ssatd mn(oh)2(am) -6.013 -8.14B

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~. mnhp04(c) montmor-ca monlmor-na mar'dent ta-k muscovite natrolite nesquehonite nontrontt-k nontronit-na pd-o){yanntte phenglte phi II Ipstte­phlogopl te pseudowo I I as quartz rhodonite rlpldollt-7a saponite-ca saponite-k saponite-na sepiolite s1 11 imanite sRleet tte-Iow snli thsoni te stllblte-k strengtte talc tramclite vivfanite whttlocktte wust t te ztncite zotstte

0.120 1.273 0.857

-0.523 3.532

-3.617 -2.190 9.291 9.259

13.893 1.695

-3.953 2.389

-5.062 -0.236 -4.677

1.321 2.835 2.383 2.352

-2.910 -3.634

1.358 -1.191 -3.829 -3.742

1.609 -2.288 -0.346 5.314

-2.833 -1.472 -3.898

0.162 1.726 1.161

-0.708 4.787

-4.902 -2.967 12.591 12.548 18.827 2.297

-5.357 3.237

-6.859 -0.320 -6.338

1.790 3.842 3.230 3.187

-3.943 -4.925

1.841 -1.614 -5.188 -5.072

2.181 -3.101 -0.469

7.201 -3.840 -1.995 -5.282

sald ssatd ssatd

ssatd

ssatd •• atd ssatd ssatd

ssatd

satd

ssatd ssatd ssatd ssatd

ssatd

ssatd

sald 5satd

15 approx. saturated pure minerals

monohydrocal montmor-m9 montmor-k mordentte-na nahea) ite nephe line nontrontt-ca nontrontt-mg paragonite pentahydrite phi II Ipslte­phllllpslte­prehn'ta pyroJJhyll'te rhodochrosit rlpldo II '-14 5anldlne hlg saponfte-h saponite-mg scolectte siderite smect t te-hig smect t te-rey stllbite-ca st i Ibi te-na sylvite tenorite trldymlte wairaktte wollastonite yugawaral i te zn3(p04)2.4h

o appro~. saturated end-members of specified solid solutions o saturated end-members of hypothetical solid solutions

72 supersaturated pure minerals o supersatd. end-members of specified solid solutions o superoatd. hypothetical solid solution phases

gas

cIo4(9) c02(g) h2(g) h2s(g) n2(g) 02 (9) 52(9) steam

summar'Y of gases -----

fugacity

0.221978E-31 0.208240E-02 0.906970E-13 0.138269E-30 O. 100000E+35 O.OOOOOOE+OO O.OOOOOOE+OO O. 277603E -0 I

log fugacity

-31.65369 -2.68144

-13.04241 -30.85928 87.76520

-57.69581 -61.47081

-1.55658

"-/

0.103 1.385 0.892

-3.142 -5.013 -4.289 9.743 9.784 0.506

-5.925 1.007

-5.736 -1.968 -0.428 -0.866 4.710

-0.791 1.616 2.876 1.606 0.637 1.598 6.759

-0.526 -5.020 -7.331 -5.641 -0.404 -4.762 -4.664 0.134

-4.144

0.140 1.876 1.209

-4.258 -6.793 -5.812 13.203 13.258 0.686

-8.029 1.365

-7.774 -2.667 -0.580 -I. 173 6.383

-1.072 2.191 3.898 2.177 0.864 2.166 9.159

-0.713 -6.803 -9.934 -7.644 -0.548 -6.453 -6.320

0.181 -5.616

satd ssatd ssatd

ssatd ssatd ssatd

ssatd

ssatd

ssatd ssatd ssatd ssatd ssatd ssatd

Sd tcl

Page 129: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

end of output -----pickup fife successfully written -----

reading the input file

no further input found

start time 11:54:55 12-0C89 end time II :55:31 12-0C89

9 completed 11 normal exit

Page 130: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

Uul ca til t:I ~wit\..h

jtl"9-LJuti:l. fi Id

switCh jf I ag­

IHJ it.

IIId~ttil :s.ptH.:lt:1::';;;' (O-plll',) wi th ~pec.:1e!);=

o c.p- O.OOOUOE+UO master species::: c104-with species= -1 csp- O.OOOOOE+OO

ttl~ in~ut f11~ 'las b~~ll suCCt:l~btuly rti~~ ---

reading the datal file ---

the datal file has been successfully rthid ---

Ct:tH:t 4q4 33333 0 0 rrrl'

" 4 4 3 no 0 r r 8et:t:1 q q 33 n n n rrir e q 4 q 3 n nn r r Ottee 'N4 3333 n n r r

4

eq3"r.3245Rlll supported by e41ib.3245R136

in~ut tile OCl.Ult;t";' kt:rrl.3i rtiVistHS..;.IO/II/U9 revisor;;. r9 K~rrville. TeAab - ASR Project, Charge No.: TEX24486.al

Basic tJdta for EQ3 modt:lir19 of Kerrville project receiveo fron' Dick 6Ian~man/OEN on October 10, 1989.

rill ~ I)

2 ) 3) 4)

i~ une ot tuur ~CtHldl·lub.

Eql,llilll-llJIII tor ASR grolJnOwatdi at it J..lH of 8.2 t4u11 ihrium tOI ASR 9roundwater at a pH of 7.3 Equllll)ritllil tOI ASR WattH' Treatment Plant (WTP) r-t;;lchdl Uti Equilibriu~, of d 50-50 Illi~ture of one of the above ASR grounu .... Hers and the WTP water.

Se(cnt\d 1111~ run is tor tilt! ~ ~cerld.rio.

Odtd til~ odtaO,~24tiR54

I atm steam sdturdt ion LUI v~ L.Jatd last modified lBfebBH (uoOr)

-'.

W.at~I'

Page 131: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

nh41" 0.4BB9E-05 99.0B - - - - - - - - - - - - - - - - - - - - - - -

total 99.0B

suu~~ry of aqudous r'ti~o~ r'tUlCt 10ns -----

couple eh. \/0 I ts pa- log f02 ah, kcal

default -0.100 -0.1702E+01 -61.296 -2.306 o2(aq) 11>20 0.786 0.1337E+02 -1.009 16.118 h2(aq) Itl20 -0.100 -0. 1702E+0 I -61.296 -2.306 fa++" Ife"'" -0.100 -0.1702E+01 -61. 296 -2.306 h.- /504-- -0.100 -0.1702E+01 -61.296 -2.306 nh41" In03- 0.223 0.3790E+01 -39.330 5.136 n02- In03- -0.100 -0.1702E+Ol -61.296 -2.306

summary of dqUtiOUS non-aqui I ibrtum non-redo)!', react ions -~,---

couI-Jle affinity, t<cal

none

----- ~ulUmary ot ::.lu'ctllolfl~tric mlfH~rGI Si::t.tUr'i;stiun ~tdte~

(mil1erals witt) dttinilies .11. -10 kcal are not 11sttidl

rninerol 109 q/k <:ift, kcal state mineral 109 q/k

a III i te -1.705 -2.311 a I b i 1 e j) t"gh -3.037 "I b I Ie 10. -1.705 -2.311 alunite -5.022 allies t le-14Cl -0.400 -0.542 amrph.si liea -I. 527 i:lnalc-dt:hydr -6.407 -8.682 analcime -1.663 .... nOd I us t t e -1.524 -2.065 anhydrite -2.720 cinO) te -1.350 - I. 829 anorth ita -4.830 or auCin it e 0.082 0.111 ~CtlU art int ta -,6.263 ashe rof t i te - 2.091 -2.833 bassanite "3.351 LJ~iuell it-cd. 2.562 3.412 ssalll beidall i l-k 2.110 be I de I I I t -mg 2.604 3.528 ssatd beideillt-na 2.07B tJe r I In i t e -5.033 -6.B21 baehmitti 0.049 LJrewslerltt!- -0.189 -0.256 satd brucl te --4. BB5 cohpo4.2t)20 -3.509 -4.755 calcite 0.247 Li:&:.i205.2h20 -6.9BB -9.470 caso4. 1/ 'Lil20 -3.5,2 chalJazile 0.431 0.584 ssatd chalcedony -0.499 c.hamosite-7a 0.262 0.355 satd chrysotlle - 5.268 cl inocl1l-14a -4.04B -5.4~6 eli napt i I-ca -2.399 llinuptll'·k -0.997 -1.351 cl inapti I-RIg - 6. 517 L I inopt i I-ni::l -6.236 -8.451 cl illozohdte -4.B05 LOI'Un(jum -2.118 -2.870 cristobal ite . 0.781 (I'isl.betd.a -I. 225 -1.661 cronstedt.-7 1.9B2 ddchiardl te- -I. 729 -2.343 daphni te-14a 0.368 llapltn i te -7a -3.023 -4.096 dawsoni te -O.Ob!! LJ 1 c:H,por~ 0.903 1.224 ~~at(J diopside -6.437 duiotnlte 1.547 2.097 ssatd dol ami te-dis -0.012 l10 I OJJll te-ora 1.547 2.097 ssatd enstatite -4.142

aff, kegl

-4.115 -6.1l05 -2.070 -2.254 -3.6H6 -6.546 -8.487 -4.541

2.859 2.B16 0.066

-6.620 0.3:'4

-4.77:' -0.676 -7.139 -3.252 --U.BJI -6.512 -1.05B 2.686 0.498

-U.092 -8.72J - 0.0 \{, -5.613

state

sbdll,j ssatu satd

s.:atd

!:;;~i::ltu

sold So t {j

~,",ld

Page 132: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

t:p uotd -1.~l.Iij -l.5Ilb epidote-oru -1.9UB -2.5B6 t!p 5t i ILd ta -0.189 -0 256 satd epsomite -4.997 -6.771 ~, onite-ca -0.880 - I. 193 faujasitt:-cd 0.425 0.575 SSdtu faujasite-na -4.090 -5.543 fayalite -4.716 -6.~91

t~(uh)2(ppu) -3.568 -4.835 t .. (oh)3(PfJ u ) -3.041 '4.120 feo(e) -2.082 -2.821 ferrite-ca -6.443 -8. 711 ferrite-mg -5.865 -7.948 territe-zn 0.104 O. 141.1 siitd ten-o::;. iii t~ -2.360 -3.198 fILJorapC::ititt: 14.610 19./99 S~ald

tluorite -0.815 -1.105 gar ron i te -0.311 -0.422 Sotd U ilJtH; ita 1.712 2.321 ::'~dtU 91smondl n t: 1.064 1.441 sSdtd glli~1 initt:t-(';a 0.431 0.584 ssatd 9Q1el ini ttl-nd '4.069 -0.514

ooeth1 tEl 1.372 1.860 ssatd grsena 11 ta -3.138 -4.252 gypsum -2.527 -3.425 ha lite -7.058 -9.565 nedenbdrl:jite -7.197 -9.753 hamat i tii 3.697 5.010 ::;,scatd

hercynite -0.876 -1.188 heulandite-c -0.505 -0.685 IIC;;IIJ I dluJ t ttt-n -5.005 -6.163 htlxdhyur I tt! -5.246 -7.112 tlunlite -2.522 -3.418 hydroxyapati 4.229 5.731 SSateJ i I lit e 2.635 3.571 ssatd jadeite -3.104 -4.206 k-taldspar 0.420 0.569 ssatd ka) icinite -6.343 -8.595

"'"ls111te -2.325 -3.151 kaolinite 3.451 4.67"/ S;i"llJ

"'i~serite -6.757 -9.156 kyantts -1.244 "1.6B6 lcansfordite -2.783 -3.171 laulllont t tt:: -0.304 -0.412 salll

Idw~onite -0.407 -0.551 leonharcJt i t tt -5.994 -8. 123 I e .... yne 0.431 0.584 ssatd magnt::site 0.340 -0.461 Soatd IIlC:IIgnt:t i t e 2.733 3.703 ssatd margarite -0.609 -0.1125 /IIa/( ,mulJI m'lcr 0.420 0.569 5satd melanteri tt:l: '6.733 -9.124 lIIi;I!)O I I ltt 2.611 3.610 ssatd meso It ttrSS -<.233 -3.U26 muf2(c) -3.479 -4.714 minnesotaitl1 -2.905 -3.937 IIln(oh)2(a.m) -6.946 -9.412 Innhpo4 (c) -0.173 -0.234 5dtU

monohydrocal -0.745 -1.009 montmor-ca 1.877 2.544 sSdtd

montmor-mg 1.989 2.695 s::.,atd montmor-na 1.460 1.978 SSdld

montmor-k 1.495 2.026 ssatd ,"ordeni te-k -0.503 -0.682 ml)("oenite-na. -3.123 -4.232 muscovite 5.268 7.139 :::os", let

nahco It te -4.967 -6.731 natrol!te -3.651 -4.947 lI~ptle I j ne -4.311 -5.842 nesquehonit~ -3.036 -4.114 nontronit-ca 4.871 6.600 ssatd nontronit-k 4.418 5.91l7 S!'.alU

Ilulltronit-Rig 4.912 6 656 ssatd nontronit-na 4.386 5.944 s!:.dtd

~a(ciyon i t~ 2.242 ::1.036 ssatd po-oAyanoittt 6.541 B.864 ~!:lolu

~~lItahYllrite -5.582 -7.564 phengite -0.069 -0.121 SCitu

phillipsite- 0.973 1. 318 ::tsatd phll) ips'lte- -3.99B -5.416 ,Jlli IIIp5 i tt;!- -5.781 -7.834 ph 1 OIlOP I ta "2.991 -4.053 J.Hehnite -3.789 -5.135 pseudowo I I as "6.846 ·fJ.277 ~yruphyllite 1.350 1.830 ssata quartz -0.226 -0.306 satcJ rrloduchros't -0.852 - I. 154 rhodon it e -5.599 -7.588 r- i f. .. 1i do lit - 14 -2.001 - 2.712 rlpldol it-7" '5.391 -7.305 ::,,,,n1d1n8 hig -0.792 -1.074 sapont te-co -2.515 -3.409 siipontte-h -3.438 -4.659 sapon i te-k -2.968 -4.023 sapon! te-mg -2.474 -3.353 sapontte-na -3.000 -4.065 scolecite 1.560 2.141 ~s.at" siderite 0.034 0.046 biltd ::. ill imani t8 - 1.887 -2.551 smectlte-h'lu -0.922 . 1.250 SIII':C t' te-I ow -0.324 -0.439 satu smectite-rev 2.555 3.463 ::'Sc:dd

slIli thson ita - 1. 893 -2.565 sttlbite-co -0.512 -0.694 $t i Ibite-k -3.821 -5.177 stilbite-na -5.012 -6.792 slr'~nglte -5.553 -7.525 sylv1te -1.332 -9.935 t a I c -3.729 -5.053 tridymit& '0. :194 -0.534 vi .... id.flitt:l -3.717 -5.037 wairakite . 4.778 -0.475 whitlut:kitt: 1. 210 1.639 s~atcJ wollastoni tu '6.448 -B.n8 wlI!:.tite -4.397 -5.958 yugawara 11 tti 0.128 0.113 Sdlu

.z inc i ta -3.120 -4.22B zoisite -4.1l50 -6.573

Page 133: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

19 approA. bdt •• rdted plJre mjrl~rdls o approA. saturated end-melllbers at ~~t:!cified 501 id solut ions o Sgt"ldted enu-memlJer5 of hypothetical solid solutions

40 ~u~~rsdtulate~ pure 111\n~I'~ls o supersatd. end-members ot spe~ified solid solutions o supersatd. hypothetical solid solution phases

~UI",lhil'y at gase::. -----

l.Ias

Ch4(1.I) co2(1.I) h2(g) h25(9) 02(1/) 02(1.1) 52(1.1) steam

end of output -----

fU9 a city

0.311068E-23 0.184124E-Ol 0.572260E-ll O.299976E-21 O. 100000E+35 O.OOOOOOE+OO O.OOOOOOE+OO O.277603E-Ol

log fugacity

-23.50714 -1. 73489

-11.24241 -21.52291 97.29711

-61.29581 -46.39808 -1.55658

pickup file successfully written -----

reading the input ftl~

nO further input tound

start time 11:52;46 Bnd t I"'B 11 :53 :09

9 completed 11 norlllal eAit

1~-OC81.1

12-0C89

r--. .~

Page 134: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

',-

E03NR, version 3245RIII

Copyright (c) 1987 The Regents of the University of California, Lawrence Livermore National Laboratory. AI, rights reserved.

Supported by EOLlB. version 3245RI36

Copyright (e) 1987 The Regents of the University of Cal'lfucn1a. lawrence Livermore National Laboratory. All rights reserved.

Run 11:58:45 12-0C89

--- reading the input ftle ---Input file name= kerr3.31 revlsed=10/11/89 Kerrville, Texas - WTP Project: Charge No.:

revisor::: rg TEX24486.al

Basic data for EQ3 modeling of Kerrville project received from Dick Glanzman/DEN on October 10, 1989.

This 1s one of four scenarios. I) Equilibrium for ASR groundwater at a pH of 8.2 2) Equilibrium for ASR groundwater at a pH of 7.3 3) Equilibrium for ASR water Treatment Plarlt (WTP) recharge water 4) Equilibrium of a 50-50 mixture of one of the above ASR

groundwaters and the WTP water.

This run is for the third scenario.

end it. tempe=

rho= fep=

tolbt= itermx=

0.25000E'02 O.IOOOOE'OI

-0.10000E'00 O.OOOOOE·OO

o

tdspky= uredox=

toldl=

O.OOOOOE·OO tdspl=

O.OOOOOE·OO tolsat=

I 2 3 4 5 6 7 B 9 10 loptl-IO= -I 0 0 lopgl-IO= 0 0 0 loprl-IO= 0 0 0

ioprll-20= 0 0 0 lodbl-IO= 0 0 0

uebal= none lJacion= cl-

nxmod= 0 data file master species= na+

switch with species~

0 0 0 0 0

jflag= 2 csp= 0.11000E.02

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

O.OOOOOE·OO

O.OOOOOE.OO

Page 135: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

h2(aq) Ih20 fe++'" Ife++ hs- /504--nh4+ In03-n02- In03-

-0.100 -0. 1U0 -0.100 0.203

-0.100

-0. 1690E+0 I -0. 1690E+0 I -0. 1690E+0 I

0.3440E+OI -0. 1690E+0 I

-59.465 -59.465 -59.465 -38.943 -59.465

-2.306 -2.306 -2.306 4.693

-2.306

summary of aqueous non-equilibrium non-redox reactions -----

couple affinity, keal

none

----- summary of stoichiometric minerai saturation states

(mInerals with affInItIes .It. -10 kcel are not I hted)

mineral

albite alblle low arnrph.stl'ca analcime andradi te annt te aragoni te asherofttte be Ide" It -ca beidelill-mg ber) tnite brewsterite­cahpo4.2h20 cas1205.2h20 chabazlle chamosite-7a clinochl-148 ciinoplil-ca c I I nop I I I -mg cl tnozotstte cdsloball Ie cronstedt.-7 dSJjI'lni te-148 dawsontte dlopslde do I ami I e-d Is enstatite epidote-ord epsomi te faujastte-ca faya lite fe(oh)3(ppd) ferrtte-ca ferr I te-zn fluorapatite garrontte gismondtne 9ma' tnt te-na greenal ite

log q/k

-1.529 -1.529 -1.377 -1.621 -5.763 -2.377 -0.124 -2.312

2.988 3.019

-6.084 0.791

-4.133 -6.279

1.072 -0.338 -1.895 -0.724 -4.865 -3.655 -0.642

1.504 -0.918 -0.960 -5.331 -0.478 -3.610 -0.7" -5.589

1.066 -5.172 -3.012 -5.919 -0.692 13.153 0.892 1.365

-4.188 -3.809

aff, keal

-2.087 - 2.087 -1.879 -2.212 -7.862 -3.243 -0.169 -3.154 4.076 4.119

-8.300 1.079

-5.639 -8.566

1.462 -0.461 -2.586 -0.988 -6.638 -4.986 -0.876

2.052 - I. 252 -1.309 -7.272 -0.652 -4.925 -0.970 -7.624

1.454 -7.056 -4.109 -B.075 -0.944 17.945 I. 21B I.B63

-,- . 713 -5.197

state

satd

ssatd ssatd

ssatd

ssatd saId

ssatd

ssatd

ssatd ssatd ssstd

mineral

alblle high amesite-14a analc-dehydr andalusite anhydri te anorthite artinite bassanite be I de I I I t - k beidal) it-na boehm) te brucite calcite caso4.1/2h20 chalcedony chrysotile cl tnoch'-7a cllnoplll-k cl inopti I-na corundum crist.bata.a dachiardi te­daphnlle-7a diaspore dolomite dolomi te-ord epldole ep I s I I I bite ertonite-ca faujasite-na fe(oh)2(ppd) feo(e) ferrlte-mg ferros iii te fluorite gIbbS ite gmelinite-ca goethi te gypsum

log q/k

-2.84B 0.371

-6.329 -1.467 -3.198 -4.179 -6.164 -3.828

2.319 2.370 0.001

-4.493 0.041

-3.997 -0.363 -3.8BI -5.269 -0.632 -5.338 -2.190 -1.081

1.399 -4.29 i 0.845 1.066 1.066

-0.711 0.791 3.!>29

-4.209 -3.867 -2.376 -5.405 -2.523 -1.121

1.637 1.072 1.380

-3.025

aff. keal state

-3.886 0.506 ssald

-8.635 -2.002 -4.363 -5.702 -8.410 -5.223

3.163 ssatd 3.234 ssald 0.001 satd

-6.129 0.056 satd

-5.453 -0.495 satd -5.295 -7.188 -0.863 -7.282 -2.988 -1.475

1.908 ssatd -5.854

1.153 ssatd 1.455 ssald 1.455 ssald

-0.970 1.079 ssatd 4.815 ssatd

-5.742 -5.275 -3.241 -7.374 -3.442 -1.529

2.233 ssatd 1.462 ssald 1.883 ssald

-4.127

Page 136: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

\ ,--hedenbergtte hercyn1 te heulandtte-n hunt't. Illite k-feldspar kaolinite kyanite lauRiontite leonher-dttte magnesl ts margartte mesoltte Rl9f2(c) mnhpo4(c) fIIontmor-ca mOfltmor-na morCleni te-k muscovite natrallte nesquehonite nontrontt-k nontrontt-na pd o)l:yannite phengtte phlilipstte­phlogopite pseudowo I I as quartz rhodonite rlpldoltt-7a saponite-ca sapon i te-k saponite-na siderite smect i te-hi9 smect t te-rey spinel stllblte-k strengtte trldymt te wairaklte wollastonite yugawaral Ita zoistte

-6.767 -1. 267 -4.615 -3.503

2.791 0.327 3.583

-1.192 0.554

-6.547 -0.604 -0.094

3.237 -3.822 -2.313

2.503 1.952

-0.321 5.040

-3.722 -3.309 4.743 4.795 6.469 0.313

-5.050 -1.963 -6.237 -0.092 -6.523 -4.599 -0.860

·-1.529 -1.471 -0.909 -0.342

3.475 -7.249 -3.901 -6.560 -0.257 -3.857 -5.844 0.938

-3.700

-9.232 -1.728 -6.297 -4.778

3.807 0.447 4.888

-I. 627 0.756

-8.933 -0.823 -0.128

4.416 -5.215 -3.155

3.414 2.663

-0.438 6.876

-5.077 -4.514

6.471 6.542 8.825 0.427

-6.890 -2.678 -8.509 -0.125 -8.899 -6.274 -1.173 -2.086 -2.015 -1.240 -0.467

4.741 -9.890 -5.321 -8.950 -0.351 -5.262 -7.973

1.279 -5.047

ssatd satd ssatd

ssatd

satd ssatd

ssald ssatd satd ssatd

ssatd ssatd ssatd satd

satd

satd ssatd

satd

ssatd

15 approx. saturated pure minerals

hematite heulandite-c hexahydrite hydroxyapatt jade t te kalstlite kieserlte lansfordi te lawsonite levyne magnetite maximum mter mesoltte-ss mlnnesotatte monohydrocal montmor-mg montmor-k mordentte-na naheo) ite nephe) tne nontronit-ca nontronit-mg paragonite pentahydrite phil) ipsite­phi II ipst te­prehntte pyrophyll ite rhodochrosit rip I do Itt - 14 santdine h19 saponite-h sapon i te-mg scolecite sillimanite smectite-low smithsonite sttlbite-ca st t Ibi te-na talc viviani te whitlockite wustite zinctte

o approK. saturated end-members of specified solid solutions o saturated end-members of hypothetical solid solutions

48 supersaturated pure minerals o supersatd. end-members of specified solid solutions o supersatd. hypothetical solid solution phases

----- summary of gases -----

3.719 0.644

-5.823 3.205

-3.063 -2.665 -7.277 -3.099 0.175 1.072 2.452 0.327

-1.578 -3.301 -0.955

2.604 1.904

-2.674 -5.772 -4.384 5.412 5.444 2.287

-6.161 1.764

-6.129 -2.614

1.770 -2.577 - 1.226 -0.872 -1.847 -0.82B

2.290 -1. B26 0.245

-3.365 0.637

-4.622 -2.077 -6.796 0.400

-4.623 -3.947

5.073 0.B79

-7.944 4.373

-4.179 -3.635 -9.928 -4.228 0.239 1.462 3.345 0.447

-2.153 -4.503 -1. 303 3.552 2.597

-3.648 -7.875 -5.981 7.384 7.427 3.120

-8.406 2.407

-8.361 -3.567

2.415 -3.516 -1.672 -1.189 -2.520 -1.130

3.124 -2.49£ 0.334

-4.591 0.870

-6.306 -2.834 -9.272 0.545

-6.307 -5.385

ssatd ssatd

ssatd

satd ssatd ssatd satd

ssatd ssstd

ssatd ssatd ssatd

ssatd

ssatd

ssatd

satd

ssatd

ssatd

Page 137: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

\,:-

gas

ch4(g) c02(g) h2(g) h2s(g) n2(g) 02(g) 52(g) steam

end of output -----

fugacity

0.209994E-26 0.502736E-02 O. 151657E-I I 0.I06547E-24 0.IOOOOOE+35 O.OOOOOOE+OO O.OOOOOOE+OO 0.313105E-OI

pickup file successfully written

readin9 the input file

no further input found

start time 11,58,45 12-0C89 end time 11,59:06 12-0C89

9 completed 'I normal exit

log fugacity

-26.67779 -2.29866

- I 1.81914 -24.97246 93.88885

-59.46454 -5 1.94284

-1.50431

Page 138: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

EQ3NR, version 3245Rlll

Copyright (e) 1987 The Regents of the University of California, Lawrence Livermore National Laboratory. All rights reserved.

Supported by EQLIB, version 324SR136

Copyright (c) 1987 lhe Regents of the University of California, lawrence livermore National laboratory. All rights reserved.

Run 99:49:95 19-0C89

--- readinQ the input file - -input file name- kerr3.3i revised-10/1I/89 revisor- r9 kerrville, lexas - WTP Project; Charge No.: lEX24486.al

Basic data for EQ3 modeling of kerrville project received from Dick Glanzman/DEN on October I~, 1989.

This is one of four scenarios. I) Equi I ibrium for ASR groundwater at a pI! of 8.2 2) Equilibrium for ASR groundwater at a pI! of 7.3 3) Equilibrium for ASR Water Treatment Plant (WTP) recharge water 4) Equilibrium- of a 59-59 mixture of one of the above ASR

groundwaters and the wrp water.

This run is for the third scenario.

endit • tempc- 9.25999E+92

rho- 9 .11l992E .91 tdspkg- 9.99999E'99 tdspl-fep- 0.39000E+99 uredox-

tolbt- 0.00909E+00 toldl- O.OOOOOE+OO tolsat-itermx- 0

1 2 3 4 5 6 7 8 9 10 iopt]-IO- -1 9 0 0 0 9 0 9 0 9 iopgl-19- 0 0 II 0 '" 0 0 0 0 0 ioprl-IO- 9 9 0 0 9 9 9 0 0 0

ioprH-20- 0 9 9 0 0 9 0 0 0 0 iodbl-IO- 9 9 0 0 0 0 9 " 0 9

uebal- none uaci on- c1-

nxmod· 0 data file master species- na.

switch with species-j f1 ag- 2 esp- 9 .IH!99E. 02

9.99099E+00

0.00000E+09

Page 139: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

fe •• t hs­nh4' n02-

Ife' t 1504-­In03-In03-

0.300 0.300 0.31l3 0.300

0.5071E,OI 0.5071Et01 0.5130E.01 0.507lE,01

-32.418 -32.418 -32.183 -32.418

6.919 6.919 6.999 ~.919

summary of aqueous non-equilibrium non-redox reactions

couple affinity. kcal

none

----- summary of stoichiometric mineral saturation states

(minerals with affinities .It. -10 kcal are not listed)

minerai

albite albite low alllrph. silica analcime a"dradi te anorthite artinite b.ssanlte beidell it-k beidel I it-na boehmite brucite calci te cas04.1/2h20 chalcedony chrysot ile elinoehl-·7a ci I nop til - k ci inopt i I-na corundulli crist.beta .• ciachlardite­diaspore dolomite dolomite-ord epldot(' epistilbite erionitc-ca faujasite na fc(oh)3(ppd) ferrite ca ferrite-zn fluorapatite garronite gismo"dine gmel ini te-na gypsum hercyn I te heulandite-n itullti te

log q/k

-1. 530 -I . 530 -1.377 -1.622

2. 389 -4.180 -6.164 -3.828

2.318 2. 370 0.001

-4.493 0.041

-3.997 -0.363 -3.882 -5.269 -0.633 - 5 . 339 -2.190 - 1.081 1. 396 0.845 1.066 1.066 3.365 0.790 3.526

-4.209 I .065 2.234 7.461

13.154 0.891 1. 365

-4.189 -3.025 -3.952 - 4.616 -3.504

aff. kc.1

- 2.087 -2.087 -1.879 -2.212

3.260 -5.703 -8.410 -5.223

3.162 3.233 0.001

-6.129 0.056

-5.453 -0.495 - 5.296 -7.189 -0.864 -7.284 -2.988 -1.475

1.905 1.153 1. 454 1. 4 54 4.591 1.07& 4 _810

-5.743 1. 453 3.047

10.179 17.946

1. 215 1. 862

-5.714 -4.127 -5.392 -6.298 ~4.780

st.te

ssatd

ssatd ssatd satd

satd

satd

ssatd ssatd ssatd ssatd ssatd ssatd ssatd

ssatd ssatd ssatd ssatd ssatd ssald

mineral

albite high amesite-14a .nalc-dehydr and. I us ite anhydrite aragonite asherottite beidellit-ca beidell it-mg ber! inite brewsterite­cahp04.2h20 c.si205.2h20 chabaz it e chamos it e-7. cl illochl-14a cl i nop til .. ca el inopt iI-mg cl inozoisite cristobal ite cronstedt .-7 dawson i t e diopside dolomite-dis enstatite ep Idote··ord epsomi te f.uj.site-ca te(oh)2(ppd) f eo( c) ferrite-mg ferrosilite fluorite gibbsite gme lin i t e - c a goethite hematite heul.ndlte-c hexahydri te hydroxyapa t i

log q/k

-2.849 0.371

-6.330 -1.467 -3.198 -0.1H -2.313

2.987 3.019

-6.083 0.790

-4.133 - 6.279

1.071 -5.709 -1. 896 -0.725 -4.866 -3.655 -0.642

4.286 -0.960 -5.331 -0.479 - 3. 610

3.365 -5.589

1.065 -6.552 .. 5 .061

2.748 -5.209 -1.121

1.637 1.071 5.456

11.671 0.643

- 5.823 ] HI';

aff. kc.l

-3.686 0.506

-8.635 -2.002 -4.363 -0.169 -3.155

4.076 4.116

-8.299 1.078

- 5.639 -8.567 1.461

-7.789 -2.587 -0.989 -6.639 -4.987 -0.876

5.847 -1. 310 -7.273 -0.653 -4.925

4.591 ·-7.624 1.453

-8.939 -6.91l5

3.749 -7.106 -1. 530

2.233 1. 461 7.444

16.196 0.878

-7.944 A ~'7A

state

ss.td

satd

ssald ssatd

ssatd

ssatd

ssatd

ssatd

ssatd

ssatd

ssatd ssatd ssatd ssatd ssatd

Page 140: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

ill it e k-feldspar kaol inite kyanite laumontite leonhardlite magnesite morgarl te mesolile ,"yf2(c) mOflohydrocal mon tmor n.g fuontlllor k ",orden I te-na nahco I I te nepheline nontron i t·,ca non t ron it -my paragonite pentahydrlte phi 11 iPSI te­"hill ipslte­prehnite pyrophyll Ite rhodochrosit ripidollt-14 sapon i le-ca saponlte-k saponite··na siderite smectite-hlg smec tit e- rey spinel st ilbi le-k strenglte tr idymi te whitlockite wus t ite zincite

2.790 0.327 3. 583

-1.193 0.554

-6.547 -0.604 -0.094

3.236 - 3.823 -0.955

2 .61n 1.903

-2.675 -5.772 -4.384 13. 565 13. 596

2.286 -6.161

1. 764 -6.130 -2.615

1 .170 -2.578 -6.597 -0.860 -1.530 -1.478 -3.595 -0.870 4.015

-7.249 - 3. 90 1 -2.483 "·0.257 0.400

-6.449 -3.947

3.8r.l6 r.l.446 4.888

-1.627 0.755

-8.933 -r.l.824 -r.l.128

4.415 -5.215 -1. 304

3.551 2.596

- 3.649 - 7 • 87 5 -5.981 18.5r.l6 18.549

3.119 -8.406

2. 4r.l6 - 8.363 - 3.567

2.415 -3.517 -9.r.lr.lr.l -1.174 - 2. r.l87 -2.016 -4.9r.l4 -1. 187

5.478 -9.89r.l - 5. 313 -3.388 -0.351 0.546

"·8.799 -5.385

ssatd satd ssatd

ssatd

satd ssatd

ssald ssald

ssatd ssatd ssatd

ssa td

ssatd

ssatd

satd ssatd

13 approx. saturated pure minerals

jadeite ka I s I I I te kieserlte lansfordlte lawson i te levyne magnetite maximum micr mesollte-ss mnhpoHc) montmor-ca montmor-na Qlordenile k nlUSCOV 'i te nat.,-olite nesquehonlte nontronlt-k nontronit~na pd oxyan"n I te phengi te ph i II ips i t e­phlogopite pseudowollas quartz rhodon I te sanidlne hlg saponlte-h saponlte-ing scolecite 5111 Imanl te smectite-low smithsonite stilbite-ca st I1bite-na talc wairakite wollastonite yugawaral i te zoisite

o approx. saturated end-members of specified solid solutions r.l saturated end-members of hypothetical solid solutions

55 s"persaturated pure minerals o snpersatd. end-members of speclried sol id solutions o supersald. hypothetical sol id solution phases

gas

ch4(g) co2 (g)

summary of gases -----

fugacity log fugacity

0.r.l0000r.lEIr.l0 -80.77179 0.502497E-r.l2 -2.29887

- 3.063 -2.665 -7.277 -3.099 0.175 1.r.l71 7.919 0.327

-1. 580 - 2.312

2.502 1.951

-0.322 5.04r.l

-3.722 -3.309 12.895 12.947 18.697 0.312

- 5. r.l51 -1. 964 -6.237 -0.092 -6.513 -0.872 -1. 848 -0.829

2.289 -1.827

r.l.1l8 -3.365 0.637

- 4.623 - 2. r.l7 8 -3.858 -5.844 0.937

-3.700

-4.179 - 3. 6 36 ·9.928 -4.228 0.139 1. 461

lr.l.804 0.446

-2.155 -3.154 3.413 2.662

··0.439 6.875

-5.r.l78 -4.515 17.593 17.664 25.5r.l9 0.426

-6.891 -2.679 -8.509 -0.125 -8.899 -1.190 -2.521 -1.131

3.123 -2. 492 0.161

-4.591 11.869

-6.3117 -2.834 -5.263 -7.973 1.279

-5.048

satd ssatd ssatd satd

ssatd ssatd satd ssatd

ssald ssatd ssa I d said

said

ssatd

satd

ssatd

ssald

Page 141: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

h2(9) h2s(g) n 2 (g) 02(9) s2(g) steam

end of output -----

0.454375E -25 0.000000E100 0.100000E.35 0.382253E 32 0.000000E.00 0.313105E-Ol

pickup file successfully written

reading the input file

no rurther input found

start time - 09:40:05 19·0(89 end time - 09:40:30 19-0(89

9 completed 01 normal exit

-25.34259 -79.06627

53.31442 -32 .41765

-133 .08357 -1.50431

Page 142: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

EQ1NR, version 1245Rlll

Copyright (c) 1987 The Regents of the llniversity of California, lawrence livermore National laboratory. All rights reserved.

Support~d by EQlIB, version 1245RI16

Copyright (c) 19B7 The Regents of the llniversity of California, lawrence livermore National Laboratory. All rights reserved.

Run 09:54:19 19-0C89

--- reading the input file ---input file name- kerr4.1i revised-10/IB/89 revisor- rg Kerrville, Texas - ASR Projectj Charge No.: TEX24486.a1

Basic data for EQ3 modeling of Kerrville project received from Dick Glanzman/DEN on October 10, 1969.

This is one of four scenarios. I) Equilibrium for ASR groundwater at a pH of 8.2 2) Equilibrium for ASR groundwater at a pH of 7.3 3) Equilibrium for ASR Water Treatment plant (WTP) recharge water 4) Equilibrium of a 50-50 mixture of one of the above ASR

groundwaters and the WTP water (as an approximation avo value of asr and wtp used)

This run is for the fourth scenario.

endit. tempc- 0.24000E102

rho- 0.10004E101 tdspkg- 0.00000E.00 tdspl- 0.00000E.00 fep- o .10000E 100 uredox-

tolbt- 0.00000E100 toldl- 0.0IJ000E,00 tolsa':- 0.00000E.00 itermx- 0

1 2 3 4 5 6 7 8 9 HI ioptI-I0- -1 0 0 0 0 0 0 0 0 0 iopgI-10- 0 0 0 0 0 0 0 0 0 " toprI--10- 0 0 0 0 0 0 0 0 0 0

ioprll-20- 0 0 0 0 0 0 0 0 0 0 iodbI-10- 0 0 0 0 0 0 0 0 0 0

uebal- none uacion- cI-

nxmod- 0 data file master species- nat

switch with species-jflag- 2 esp' 0.H000E102

Page 143: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

couple

default o2(aq) h2(aq) fett+

/h20 /h20 /fet. /504-­/n03-/n03-

hs­nh4 t

1102-

eh, volts

9.]09 9.778 9. ]09 9.109 9. ]99 9.263 9.199

pe-

9.1696Etlll 9.1319E.92 9. ]696E.91 9.]696E.91 9.1696E"'1 9.4462E'91 II.1696E.91

log f02

-46.819 -9.839

-46.8]9 -46.8111 -46.8111 -35.747 -46.8111

ah, kcal

2.396 17.933

2.396 2.3116 2.3116 6.967 2.3116

summary of aqueous non-equilibrium non-redox reactions

couple affinity, kcal

none

----- summary of stoichiometric mineral saturation states

(minerals with affinities .It. -]11 kcal are not listed)

mineral

alhite albite low ameslte-14a analc-dehydr andalusite anhydr i te anorth I te artinite bassanite beidell it- k beidell it-na boehmite bruci te calcite ca504.1/2h20 chalcedony chrysotile clinochl-7a cl inopt ll-k cllnuvtll na corundum crlst.beta.a dachlardite­daphn it e- 7a diaspore dolomite dolomite-ord epidote eplstllblte erlonlte-ca fauias I te-na re(oh)2(ppd) feo (c) ferrite-mg

log q/k

-1.49] -1.491 9.139

-6.259 -1.434

.-2.969 -4.498 -6.1117 -3.599

2. 355 2.341 9.95]

-4.647 9.194

- 3. 769 -9.423 - 4.433 -6.967 -11.383 -5.5112 -2.]99 -1.145 11.193

-2.351 9.991 1.422 1.422 2. 461 9.431 1.919

-3.915 -3.472 -1.983 1.682

aff, kcal

-2.1128 -2.928 9.177

-8.499 -1.9511 -4.924 - 5.993 - 8.394 -4.881

3. 211 2 3.183 9.979

-6.319 9.264

- 5 .112 -9.575 -6.1128 ·8.249 -9.521 ·7.482 -2.856 -1.557 9.263

-3.197 1. 22 5 1.933 1.933 3.346 9.586 2.597

-5.323 ·4.72] - 2 .697

2.288

state

satd

ssatd ssatd satd

satd

satd

ssa td ssatd ssatd ssa td ssatd ssatd

ssatd

mineral

albite high alunite amrph.sllica anal cime andradite annite aragonite ashcroftite be idell it-ca beidellit-mg ber! inite brewsterite­cahpo4.2h20 casil05.2h20 chabaz it e chamosite-7a cl i noch I 14a cl inoptll-ca cI inopt il-mg cl inozoi si te cristobalite cronstedt.-7 daphni te-Ha dawson it e diopside dolomite-dis enstatite epidote ord epsoml te faujasite-ca faya lite fe(oh)3(ppd) ferrite-ca ferrite-zn

log q/k

-2.817 -6.1171 -1.444 -1. 525 9.736

-9.928 9.929

-1.895 2.872 2.911

-5.449 9.431

-3.711 - 6. 599 9.865 11.515

-2.686 -1. 399 - 5.513 --4.971 -9.7113

9.518 1.1131

-11.389 -5.798 -9.139 -3.826

2. 461 - 5 .279 11.858

-4.445 0.6]2 1. 122 7.51111

aff, kcal

-3.839 -8.255 -1. 963 -2.973

] .1191 -1. 261 9.949

-2.454 3.995 3.958

-7.499 9.586

-5.946 -8.969

1.176 11.7911

-3.652 -1. 9112 -7.497 -5.535 -11.956 12.941

].4112 -11.539 -7.884 -II .176 - 5.U:l2

3. 346 -7.177 1.]67

-6.944 9.832 1. 526

19.198

state

ssatd

satd

ssatd ssatd

ssatd

ssatd ssatd

ssatd ssatd

satd

ssatd

ssatd

ssatd ssatd ssatd

Page 144: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

ferro5i1 he -2.188 -2.975 f1 uorapa t he 14.264 19.394 55atd fluorite -0.944 -1.283 garronite 0.674 0.917 5satd gibbsite 1.701 2.313 55atd gismondine 1.311 1. 783 ssatd gmelinlte-ca 0.865 1. 176 55atd gmelinite-na -3.894 -5.294 goethite 5.014 6.818 ssa td greenal he -2.720 - 3. 699 gyps"In -2.777 -3.775 hedenbergi te -6.693 - 9.100 hemat I t e 10.984 14.935 5satd hercynite -0.773 -1.051 heulanllite-c 0.208 0.283 satd heulandite-n -4.550 -6.187 hexahyd ri te -5.521 -7.508 huntite -2.768 -3.763 hydroxyapati 4.100 5.575 5satd illite 2.902 3.946 ssatd jadeite -2. 966 -4.033 k-- feldspar 0.573 0.779 s5atd kal icinite -6.682 -9.085 kalsil ite - 2 . 312 -3.144 kaolinite 3.587 4.877 ssatll ki e5erite -7.003 -9.522 kyanite -1.157 -1. $73 lan5fordite -2.876 --3.911 humont ite 0.239 0.325 satd lawsonite -0.019 -0.025 satd leonhdrdtite -6.257 - 8.507 levyne 0.865 1.176 ssatd magnesite -0.407 -0.554 magnetite 10.114 13.752 ssatd maryarite -0.201 -0.273 satd maximum mier 0.573 0.779 s5atd mel anteri te -7.145 -9.715 mesolite 3.170 4.311 5satd mesol i te-ss -). 469 -1. 998 mgf2(c) -3.612 - 4.911 mlnne50taite -2.333 -3.172 mn(oh)2(am) -6.845 -9.307 mnhpo4(c) -11.5311 -11.721 monohydrocal -11.8011 -1. 087 montmur-ca 2.286 3.108 ssatd montmor-mg 2.394 3. 255 ssatd montmor· na 1.822 2.477 5satll montmor-k 1. 839 2. 501 ssatd mordcnite-k -0.196 -11.267 satd mordeni te-na -2.756 -3.748 muscovite 5.4111 1.351 ssa td nahcol ite - 5.272 -1.168 nalrol he -3.459 -4.7114 nepheline -4.238 -5.163 ne5quehonlte - 3.108 -4.226 nontronit-ca 12.461 16.943 s5atd nontronit-k 11.944 16.240 55a td nontronit-mg 12.499 16.996 ssatd nontronlt-na H.930 16.221 5satd paragon ite 2.443 3.322 ssatd pd oxyannlte 11.618 23. 95 5 ssatd pentahydrite -5.851 -7.964 phenuite ~.361 11.491 satll phi11ipsite- 1. 530 2.080 5satd phillipsite- -3.959 -5.384 phillipsite- - 5.611 -1.630 phlogopite -2.153 -2.928 prehnite -3.1169 -4.173 pseudowol1a5 -6.5116 -8.846 pyrophyll i te 1.647 2.239 5satd quartz -11.151 -11.205 5atd rhodochrosit -1.062 -1.444 rhodonite -5.423 -1.374 ripidolit-14 -0.919 -1. 2 50 ripldol It-la -4.301 - 5.848 sanldine hig -0.633 -i1.860 saponite-ea -1. 519 -2.066 5aponite-h - 2. 419 -3.311 saponile-k -2.036 -2.169 saponite-mg -1. 480 -2.013 sapoll i te--na -2.0511 -2.788 seo I eci te 2.040 2.174 ssatd siderite -11.169 11.230 satd sill imanite -1. 195 -2.441 smeet ite-hig 0.366 0.491 satd 5meeti te-- low 0.757 1.029 ssatd sn'eet it e- rev 4.532 6.162 5satd smithsonite -2.087 -2.838 spinel -7.322 -9.956 stilbile-ea 0.201 0.274 satd stilblte-k - 3. 4 54 --4.696 stilbi te-na -4.551 -6.197 strenglte -2.336 -3.176 talc -2.145 - 3.732 tri"ymi te -II.1l7 -11.431 said vivlanlte -4.355 - 5.921 wal rak he -4.2114 -5.716 whltlocklte 1.051 1.429 ssatd wol hstonite -6.110 -8.3118 wust Ite -3.918 -5.321 yugawaralite 0.654 11.890 ssatd zincite -3.015 -4.100 zolsite -4.U6 - 5 . 596

17 approx. saturated pure minerals II approx. saturated end-members of specified solid solutions o saturated end-members of hypothetical solid solutions

55 supersaturated pure minerals

Page 145: L..:::=:::============================ · aquifer storage recovery feasibility investigation phase iia monitoring well pz-1 volume ii --appendixes prepared for upper guadalupe river

9 supersatd. end members of specified sol id solutions " supersatd. hypothetical solid solution phases

summary of gases -----

yas

ch4(y) co2 (g) h2(g) h2s(g) n2(g) 02(g) s2(g) steam

----- end of output -----

fugacity

9.900999E.99 9.101511E-01 9.483926E-18 9.909009[,90 9 • 199999E • 3 5 9.999990E+99 9.009990E.99 0.294888E-9l

----- pickup file successfully written

reading the input file

no further input found

start time - 99:54:19 19-0(89 end time - 99:54:46 19-0(89

log fugacity

- 52. 29749 -1.99348

-18.31522 - 59.41362

75.23532 -46.81912 -89.93319 -1. 53934

-------------------------------------------------------------------------------9 completed 91

norma 1 ex it