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33 INTRODUCTION Pollution of river bodies has become a major and global problem that is becoming critical in developing nations of the world because of inadequacy or non existence of surface water quality protection measures and sanitation. Lagoons, rivers and streams are sinks for wastes. Wastes are most often discharged into receiving water bodies with little or no regard to their assimilative capacities. This in effect makes pollution of river bodies a global issue that has no respect for national or international boundaries. The degrees of pollution and natural purification are measurable physically, biologically and chemically (Longe and Omole 2008). Hence a comprehensive river water quality monitoring programme is becoming a necessity in order to safeguard public health and to protect the valuable fresh water resources. Whereas water monitoring for different purposes is well defined, the overall water quality is sometimes difficult to evaluate from a large number of samples and parameters (Chapman 1992). Analysis of any monitored parameter, either in alone or group according to a common feature, provides partial information on the overall water quality (pesce and Wunderlin 2000). Traditional approaches for assessing water quality are based on the comparison of experimentally determined parameter values with the existing local normative. However, it does not provide a global vision on the spatial and temporal trends in the overall water quality (Debels et al. 2005). Mathematical computation modeling of river water quality is possible but requires an extensive validation. Besides it requires previous knowledge of hydraulics and hydrodynamics. To overcome these difficulties, a water quality index (WQI) was developed which is a numeric expression transforming large quantities of water characterization data into a single number, representing water quality level (Sanchez et al 2006; Bordalo et al. 2006). The WQI is a dimensionless number with values ranging Journal of Indian Water Resources Society, Vol 32, No. 12, JanuaryApril, 2012 ASSESSMENT OF WATER QUALITY STATUS OF HOLY RIVER KSHIPRA USING WATER QUALITY INDEX R.C. Gupta 1 , Ajay K. Gupta 2 and R.K. Shrivastava 3 ABSTRACT In this paper attempt is being made to assess the water quality of Kshipra, a holy river flowing through Ujjain city. Parameters namely Temperature, pH, Turbidity, Total Solids, Dissolved Oxygen (DO), Biochemical Oxygen Demand (BOD), Phosphate, Ammonia and Fecal Coliform ( F.C.) were determined at important locations of River Khan and Kshipra for summer, monsoon and winter seasons in the year 2010. Assessment was made through Water Quality Index (WQI), a single number representing large quantities of data. US National Sanitation Foundation WQI was calculated for each set of data with and without Phosphate parameter. The results shows that Kshipra River water is of medium to bad quality and Khan River water is the major cause of pollution in Kshipra River. The study also revealed that Kshipra River water is unsuitable even for bathing. Key words: Water Quality Parameter, Khan River, Kshipra River, Water Quality Intex. 1. Selection Grade Lecturer, Civil Engineering, Govt. Polytechnic College, Ujjain (M.P.) Email: [email protected] 2. Associate Professor, Civil Engineering,Govt. Engineering College, Ujjain (M.P.) 3. Professor, Civil Engg., S.G.S. Institute of Technology and Science, Indore (M.P.) Manuscript No.: 1309

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J. Indian Water Resour. Soc., Vol. 32, No. 1-2, January-April, 2012 33 INTRODUCTION Pollution of river bodies has become a major and global problem that is becoming critical indevelopingnationsoftheworldbecause ofinadequacyornonexistenceofsurface waterqualityprotectionmeasuresand sanitation.Lagoons,riversandstreamsare sinksforwastes.Wastesaremostoften dischargedintoreceivingwaterbodieswith littleornoregardtotheirassimilative capacities.Thisineffectmakespollutionof riverbodiesaglobalissuethathasno respectfornationalorinternational boundaries.Thedegreesofpollutionand naturalpurificationaremeasurable physically,biologicallyandchemically (LongeandOmole2008).Hencea comprehensiveriverwaterquality monitoringprogrammeisbecominga necessity in order to safeguard public health andtoprotectthevaluablefreshwater resources.Whereaswatermonitoringfor differentpurposesiswelldefined,the overallwaterqualityissometimesdifficult toevaluatefromalargenumberofsamples andparameters(Chapman1992).Analysis ofanymonitoredparameter,eitherinalone orgroupaccordingtoacommonfeature, providespartialinformationontheoverall waterquality(pesceandWunderlin2000). Traditionalapproachesforassessingwater qualityarebasedonthecomparisonof experimentally determined parameter values withtheexistinglocalnormative.However, itdoesnotprovideaglobalvisiononthe spatialandtemporaltrendsintheoverall waterquality(Debelsetal.2005). Mathematical computation modeling of river waterqualityispossiblebutrequiresan extensivevalidation.Besidesitrequires previousknowledgeofhydraulicsand hydrodynamics.Toovercomethese difficulties, a water quality index (WQI) was developedwhichisanumericexpression transforminglargequantitiesofwater characterizationdataintoasinglenumber, representingwaterqualitylevel(Sanchezet al 2006; Bordalo et al. 2006). The WQI is a dimensionlessnumberwithvaluesranging JournalofIndianWaterResourcesSociety, Vol32,No.12,JanuaryApril,2012ASSESSMENTOFWATERQUALITY STATUSOFHOLYRIVERKSHIPRAUSINGWATERQUALITYINDEX R.C. Gupta1, Ajay K. Gupta2 and R.K. Shrivastava3 ABSTRACT In this paper attempt is being made to assess the water quality of Kshipra, a holy river flowing throughUjjaincity.ParametersnamelyTemperature,pH,Turbidity,TotalSolids,Dissolved Oxygen (DO), Biochemical Oxygen Demand (BOD), Phosphate, Ammonia and Fecal Coliform( F.C.) were determined at important locationsof River Khan and Kshipra for summer, monsoon and winter seasons in the year 2010. Assessment was made through Water Quality Index (WQI), asinglenumberrepresentinglargequantitiesofdata.USNationalSanitationFoundationWQI was calculated for each set of data with and without Phosphate parameter. The results shows that KshipraRiverwaterisofmediumtobadqualityandKhanRiverwateristhemajorcauseof pollutionin KshipraRiver.ThestudyalsorevealedthatKshipraRiverwaterisunsuitable even for bathing. Key words: Water Quality Parameter, Khan River, Kshipra River, Water Quality Intex. 1. Selection Grade Lecturer, Civil Engineering, Govt. Polytechnic College, Ujjain (M.P.)Email:[email protected] 2. Associate Professor, Civil Engineering,Govt. Engineering College, Ujjain (M.P.) 3. Professor, Civil Engg., S.G.S. Institute of Technology and Science, Indore (M.P.) Manuscript No.: 1309 J. Indian Water Resour. Soc., Vol. 32, No. 1-2, January-April, 2012 34 between0and100.Ahigherindexvalue represents a good water quality (Cude, 2001; PandeyandSundaram,2002).This numericalindexcanbeusedasa managementtoolinwaterquality assessment.WQIalsopermitsthe assessmentofchangesinwaterqualityand toidentifywaterqualitytrends(Chapman 1992).BasedontheresultsofWQI,river watercanbeclassifiedforthepurposeof various uses. TheKshipraRiverhasbeenconsideredas casestudybecauseitisaholyriverof MalwaregionofMadhyaPradeshand thousands of pilgrims take a holy dip all the year round. The objective of this study is to establish the water quality status of the river for all seasons of a year. The results reported herewillprovidebase-linedataforframing suitable remedial action plan. STUDY AREA RiverKshipraisoneofthesacredriversof India.ItoriginatesfromKokriBardihills (747metreshigh)about11km.eastof Indore. After travelling a distance of 70 km. throughIndoredistrict,itentersUjjain district.ItreceivesitstributaryriverKhan justupstreamofUjjainandriverGambhir nearMehidpurd/sof Ujjain before merging with river Chambal. Total length of the river isabout195kms(Tyagietal.2003).The riverisnotperennialandflowsonlyduring monsoons.Duringthecourseoftheriver from the origin to just before the Ujjain city i.e.uptoadistanceofabout70Kms.,some small villages are situated along the bank of theriverandtherearenormaladditions and abstractions of water. The real problem with theriverstartsassoonasitentersthe territoryofUjjaincityhavingapopulation overfivelacs.There,RiverKhancoming fromIndorecitymergeswithitatTriveni Sangam.RiverKhanisthebiggestsource ofcontaminationtoRiverKshipracarrying highorganiccontent,chemicalsandheavy metals.Anothermajorsourceof contaminationisthedomesticwastewater generatedfromUjjaincity.Abouthalfof 110MLDofwastewatergeneratedis dischargeddirectlyintotheriver.Thus about20Kmstretchoftheriverishighly pollutedandevenunsuitableforbathing.ManyoftheimportantghatslikeTriveni ghat,RamghatandSiddhvatghatare situatedinthisstretchwherehundredsof pilgrimstakeaholydipdaily.During Simhasthafairwhichisorganizedevery twelveyears,abouttwocroresofpilgrims visit Ujjain in a months time to take a holy dip in the river.Thus about 20 km stretch of the river in the vicinity of the Ujjain city has beenchosenunderstudybecauseofits religiousimportance.Fig.1showsthe locationofimportantghatsandsampling points on the course of the river. Sampling Points Sampling points have been decided in such a waysoastocoverallimportantpointsand ghats so that results obtained will depict the truestatusoftheriverandimpactof tributariesonit.Fig.1showsthedetailsof the sampling stations. Sampling Station Description 1At Khan River (before the confluence with Kshipra River) 2At Kshipra River (before the confluence with Khan River) 3At Triveni Sangam (confluence of Khan River and Kshipra River) 4At Gaughat 5At Ramghat 6At Siddhwat Ghat Fig1:LocationofImportantGhatsand Sampling Stations J. Indian Water Resour. Soc., Vol. 32, No. 1-2, January-April, 2012 35 Station 1 and 2 will depict the true status of KhanRiverandKshipraRiverrespectively before confluence while station 3 will depict theinfluenceofKhanRiveronKshipra River. Station 3, 4, 5 and 6 are the important bathingghatsonriverKshipra.Samples were collected for three seasons i.e. summer, monsoonandwinterintheyear2010to assessthevariationofcharacteristicsover thefullyear.Sampleswerecollectedand examinedstrictlyinaccordancewiththe StandardMethodsfortheExaminationof Water and Wastewater (APHA 1998). Water Quality Index Therearevariouswaterqualityindicesto comparevariousphysicochemicaland biologicalparameterssuchasBhargava method,Hortonsmethod,Delphimethod etc.(PandeyandSundaram2002;Chetana andSomshekhar1997;RamandAnandh 1996).Howevermostoftheseindicesare basedonthefirstwaterqualityindex developedbyBrown,etal.(1970)which waslatersupportedbytheUSNational SanitationFoundation(NSF).Forthis reasonBrownsindexisalsoreferredas NSFWQI.Thisindexissimilarinstructure toHortonsindexbutwithmuchgreater vigour in selecting parameters, developing a commonscaleandassigningweightsfor whichelaborateDelphicexercisewere performed.Thisisamultiplicativeformof indexandhasbeenwidelyfieldtestedand appliedtodatafromanumberof geographicalareasallovertheworldto calculateWQIofvariouswaterbodiesfor whichcriticalpollutionparameterswere considered.NSFWQIisanexcellent management and general administrative tool in communicating water quality information (Samantrayetal.2009).Themathematical expression for NSF WQI is given by: p NSF WQI = Wi Ii i=1 Where Iiisthesubindexforithwaterquality parameter, Wiistheweight(intermsofimportance) associated with ith water quality parameter p is the number of water quality parameters.TheNSFWaterQualityLegendisgivenin Table1.Table2showstheparameters consideredforcalculatingWQIandthere relativeweights.Whentestresultsfrom fewer than nine measurements are available, relativeweightsforeachparameteris preservedandscaledthetotalsothatthe range remains 0-100. RESULTS PhysicalparametersnamelyTemp., TurbidityandTotalSolids,chemical parametersnamelypH,DO,BOD, Phosphate,Ammoniaandbiological parameter namely Fecal Coliform have been analyzedatlocationsshowninFig1. Parameterswereselectedforassessingthe bathingwaterqualitystatusatimportant ghats of the river. Seven parameters namely pH,Turbidity,T.S.,DO,BOD,Phosphate and F.C. has been considered for calculating WQI.Table3showsthewaterqualitydata at each station during summer (S), monsoon (M)andwinter(W)seasons.FurtherNSF WQIwascalculatedforeachstationwith andwithoutPhosphateparameter.Thiswas doneinordertoassesstheimpactof phosphate on overall water quality. Presence ofPhosphateindicatestheuseoffertilizers incatchmentareaoftheriver.Table4 summarizes the WQI. J. Indian Water Resour. Soc., Vol. 32, No. 1-2, January-April, 2012 36 Table 1: NSFWaterQualityLegend Range0-2525-5050-7070-9090-100 QualityVery BadBadMediumGoodExcellent Table 2:Water Quality Parameters and Weigths ParameterD.O.F.C.pHB.O.D.Temp. change Total Phosphate NitratesTurb idity T.S. Weight0.170.160.110.110.100.100.100.080.07 Table 3:Water Quality Data at Sampling Stations Location SeasonTemp. (0C) pHTurbidity (NTU) T. S. (Mg/l) DO (Mg/l) BOD (Mg/l) Phosphate (Mg/l) Ammonia (Mg/l) F. C. (MPN/ 100ML) 1 S M W 34 26 26 8.2 7.5 7.5 56 210 48 1200 1500 1050 4.3 7.8 6.1 36 28 18 5.9 4.5 5.1 7.2 8.2 6.2 2000 650 2550 2 S M W 34 26 25 7.5 7.3 8.0 16 500 32 650 1150 800 6.0 6.8 7.3 7.0 4.2 8.0 0.85 1.1 1.2 3.2 3.6 2.8 940 310 1400 3 S M W 35 27 26 8.3 7.4 8.4 26 600 40 950 1200 950 5.2 5.8 6.2 12.0 6.8 13.6 1.2 1.6 2.1 5.8 4.6 3.4 1200 460 2500 4 S M W 35 26 26 8.4 7.6 8.3 23 650 45 1070 1320 950 4.8 6.0 6.4 13.2 6.7 15.1 1.6 1.9 2.1 5.8 6.6 5.9 1750 470 2480 5 S M W 34 27 27 8.57.6 8.5 26 650 46 1150 1400 900 4.8 6.2 7.3 14 6.2 15.6 2.1 1.8 2.2 5.6 7.2 5.7 2000 500 2440 6 S M W 34 27 26 8.5 8.2 8.5 28 600 50 1150 1450 2480 3.9 6.3 7.0 15.0 7.2 15.8 1.9 2.0 2.2 6.2 6.8 6.1 2000 500 2480 J. Indian Water Resour. Soc., Vol. 32, No. 1-2, January-April, 2012 37 Table 4: Water Quality Indices with and without Phosphate Parameter StationSeasonWQI With PhosphateWithout Phosphate 1 S M W 32 44 42 36 48 47 2 S M W 56 54 52 58 56 55 3 S M W 45 48 43 47 50 45 4 S M W 41 47 44 43 50 46 5 S M W 40 49 44 42 52 47 6 S M W 36 46 43 37 49 46 Thewaterqualityindexdataareplotted stationwiseandseasonwise.Fig.2&3 showsthevariationofWQIateachstation withrespecttoseasons.Fig.4&5shows thevariationofWQIforeachseasonwith respecttostations2,3,4,5&6pertaining toRiverKshipra.Followingobservations are made looking to these data and charts: Fig 2: Variation of WQI at each station w.r.t. season (With Phosphate) Fig 3: Variation of WQI at each station w.r.t. season (Without Phosphate) Fig 4: Variation of WQI for each season w.r.t. stations (With Phosphate) J. Indian Water Resour. Soc., Vol. 32, No. 1-2, January-April, 2012 38 Fig 5: Variation of WQI for each season w.r.t. stations (Without Phosphate) DISCUSSION1)AsperNSFwaterqualitylegend(Table 1), Khan River water is of bad quality and theKshipraRiverwaterisofmediumto bad quality. 2)Acloselookatthewaterqualitydataof KshipraRiveratallghatsindicates that exceptpH&DOotherparameterslike BOD & F. C. do not satisfy the class B waterqualitystandardsasprescribedby CPCB (pH = 6-8.5, DO > 5 mg/l, BOD < 3mg/l&MPN/100ml