KMK Metals Recycling LimitedCompany Name: KMK Metals Recycling Limited Licence No: W0113- 04 Year: 2019, Visit No: 4 Report No: 2019-166 . Glenside Environmental Services Doc No: GEN2-001rev13

Company Name: KMK Metals Recycling Limited Licence No: W0113-04 Year: 2019, Visit No: 4 Report No: 2019-166

Glenside Environmental Services Doc No: GEN2-001rev13

Rev Date: 19/12/2018 Issued by: QM

Glenside Environmental, Unit 18 Great Island Industrial Park,

Ballincollig, Co. Cork

T: 021 4810016 M: 086 3819387 [email protected] www.glenenv.ie

_______________________________________________________________

Quarter 4 of 2019 Stack Emissions Monitoring Report

for

KMK Metals Recycling Limited

Cappincur Industrial Estate, Daingean Road, Tullamore, Co Offaly

EPA Licence REF: W0113-04; TA-A

_______________________________________________________________

Report No: 2019-166

Monitoring Date: 2nd October 2019

Test report shall not be reproduced except in full, without written approval of the laboratory.

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http://www.glenenv.ie/




Report Summary:

Job Quotation No: 2019-012

Operator Licence No: W0113-04

Operator Name: KMK Metals Recycling Limited

Installation: Cappincur Industrial Estate, Daingean Road, Tullamore, Co Offaly Contact Name: Olivia Brennan

Phone No: 057 934 1634

Monitoring dates: 2nd October 2019

Monitoring Organisation: Glenside Environmental,

Unit 18 Great Island Industrial Park, Ballincollig,

Co. Cork Phone No: (021) 4810016

Email: [email protected]

Report Date: 30th November 2019

Report written by: Ewa Piatek

MCERTS reg No: MM07 799

Competency: Level 2

Function: Team Leader

Endorsements: TE1, TE3, TE4

Report approved by: Ewa Piatek

MCERTS reg No: MM07 799

Competency: Level 2

Function: Team Leader

Endorsements: TE1, TE3, TE4

Signed by: Quality Manager

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mailto:[email protected]




Document Revision History

Version Changes Date Changes By

Rev0 Original report issued 30/11/2019 Ewa Piatek

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TABLE OF CONTENTS

PAGE

1. INTRODUCTION........................................................................................................................ 5 2. OBJECTIVES .............................................................................................................................. 5

2.1. SUBSTANCES TO BE MONITORED AT EACH EMISSION POINT ..................................................... 5 2.2. SPECIAL REQUIREMENTS ........................................................................................................ 5

3. MATERIALS AND METHODS ................................................................................................ 6 3.1. PARTICULATES - ISO9096:2017 (HIGH) OR IS EN 13284-1:2017 (LOW) ................................ 6 3.2. METALS – IS EN 14385:2004& MERCURY – IS EN 13211:2001 ........................................... 6 3.3. VOLUMETRIC FLOW RATE – ISO 16911-1:2013 ..................................................................... 6

4. MONITORING RESULTS ......................................................................................................... 7 4.1. MONITORING RESULTS ........................................................................................................... 7 4.2. MONITORING RESULTS ........................................................................................................... 8 4.3. REFERENCE CONDITIONS ........................................................................................................ 9 4.4. METHODS AND ACCREDITATION STATUS.............................................................................. 10

5. OPERATING INFORMATION............................................................................................... 11 6. MONITORING DEVIATION .................................................................................................. 11 7. ANNEX 1 .................................................................................................................................... 14

7.1. PERSONNEL ........................................................................................................................... 14 8. ANNEX 2 .................................................................................................................................... 15

8.1. DIAGRAM - SAMPLING PLANE OF STACK ................................................................................ 15 8.2. SAMPLING MEASUREMENTS .................................................................................................. 15

9. ANNEX 3 .................................................................................................................................... 16 9.1. RESULTS AND UNCERTAINTY CALCULATIONS FOR STACK A2-5 ............................................ 16 9.2. LABORATORY CERTIFICATES ................................................................................................ 16

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1. Introduction

Glenside Environmental was commissioned by KMK Metals Recycling Limited to perform air emission monitoring at the facility in Cappincur Industrial Estate, Daingean Road, Tullamore, Co Offaly. The monitoring was carried out as required by Licence W0113-04 for the facility. This report presents details of this monitoring programme.

2. Objectives

2.1. Substances to be monitored at each emission point

Sample Locations Parameter

A2-5 Particulates

Metals (Total of Cd+Tl)

Metals (Total of Sb, As, Pb, Cr, Co, Cu, Mn, Ni, V, Be) Chromium

Lead

Mercury

Aluminium

Arsenic

Cadmium

Copper

Iron

Nickel

Zinc

2.2. Special Requirements There were no special requirements for this monitoring campaign.

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3. Materials and Methods This section provides brief details of the methodologies employed to perform the air emission monitoring.

3.1. Particulates - ISO9096:2017 (high) or IS EN 13284-1:2017 (low) A sample stream of gas is extracted from the main gas stream at representative sampling points for 30 minutes, with an isokinetically controlled flow rate and measured volume. The dust entrained in the gas sample is separated by a pre-weighed filter, which is then dried and reweighed. Deposits upstream of the filter in the sampling equipment are also recovered and weighed. The increase of mass of the filter and the deposited mass upstream of the filter are attributed to dust collected from the sampled gas, which allows the dust concentration to be calculated.

3.2. Metals – IS EN 14385:2004& Mercury – IS EN 13211:2001 A known volume of flue gas is extracted representatively from a duct or a chimney during a certain period of time at a controlled flow rate following EN13284-1:2017 (Particulates Standard). The dust in the sampled gas volume is collected on a filter. Thereafter, the gas stream is passed through a series of absorbers containing absorption solutions and the filter passing fractions of the specific elements are collected within these solutions. The results are calculated from the laboratory results divided by air volume sampled and are converted to mg/m3. Results in kg/h are calculated from concentration of pollutant and stack flow rate. All results are corrected to Standard Temperature and Pressure and if required to Reference Oxygen and Dry conditions. LOD values are obtained from laboratory LOD and the same calculations as per results.

3.3. Volumetric Flow Rate – ISO 16911-1:2013 The volumetric airflow rate was determined from stack velocity measurements calculated in accordance with ISO 16911-1:2013. Airflow rate and temperature profiles were performed at pre-calculated intervals across the stack in order to determine the average velocity profile across the stack diameters.

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4. Monitoring Results Tables 4.1 and 4.2 presents the results of the air emission monitoring sampling program carried out at the emission stacks listed below.

4.1. Monitoring Results Results reported are corrected to reference conditions as per Licence requirements.

Emission Point Substances

ELV

CEMS Results

LOD

Results

Uncertainty

Units

Results

Units

Date of Monitoring

Start –End Time of Monitoring

A2-5 Particulates 10 n/a 0.4 0.6 0.02 mg/m3 0.01 kg/h 02/10/2019 10:34-11:34

Blank Particulates n/a n/a 0.4




4.2. Monitoring Results Results reported are corrected to reference conditions as per Licence requirements.

Emission Point Substances

ELV

CEMS Results

LOD

Results

Uncertainty

Units

Results

Units

Date of Monitoring

Start –End Time of Monitoring

A2-5 Aluminium n/a n/a 0.0058 0.2194 0.00717 mg/m3 0.0053 kg/h 02/10/2019 11:56-12:28

Blank Aluminium n/a n/a 0.0058 0.2131 0.00696 mg/m3 n/a kg/h 02/10/2019 11:41-11:46

A2-5 Arsenic n/a n/a 0.0008




Emission Point Substances ELV CEMS Results LOD Results Uncertainty Units Results Units Date of Monitoring Start –End Time of Monitoring

A2-5 Nickel n/a n/a 0.0009 0.0020 0.00007 mg/m3 0.0004 kg/h 02/10/2019 11:56-12:28

Blank Nickel n/a n/a 0.0009 0.0026 0.00009 mg/m3 n/a kg/h 02/10/2019 11:41-11:46

A2-5 Zinc n/a n/a 0.0035 0.0312 0.00102 mg/m3 0.0008 kg/h 02/10/2019 11:56-12:28

Blank Zinc n/a n/a 0.0035 0.0046 0.00015 mg/m3 n/a kg/h 02/10/2019 11:41-11:46

A2-5 Mercury n/a n/a 0.0009




4.4. Methods and Accreditation Status

Sampling Point Determinant Reference Method Accreditation Status Accreditation

Range: Analytical

Method Description

Subcontracted Laboratory

Laboratory Accreditation

Status

A2-5 Velocity,

Temperature, Pressure

ISO 16911-1:2013 INAB

Velocity: 3 – 26 m/s

Temperature: 0-1000oC

Pressure: 30-110 kPa

n/a n/a n/a

A2-5 Mercury IS EN 13211:2011 INAB 0.005 – 0.5 mg/m3 AFS RPS UKAS

A2-5 Metals IS EN 14385:2004 INAB 0.005 – 0.5 mg/m3 ICP MS RPS UKAS

A2-5 Particulates low IS EN 13284:2017 INAB 0.11-50 mg/m3 Gravimetric Analysis RPS UKAS

A2-5 Water Vapour IS EN 14790:2017 INAB 0.9 – 40 % Gravimetric

Analysis n/a n/a

Substances were monitored as per monitoring objectives. Substances were monitored in accordance with the requirements stated in AG2 (Air Emissions Monitoring Guidance Note#2).

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5. Operating Information

Emission Point

Process Status Load

/Feedstock Process Details Fuel /Feedstock

Abatement System

Status of Abatement

System

A2-5 Normal Operation

3-4 tonnes of small household appliances

hourly n/a Bag Filter In Operation

Note: The process occurring in the shed the stack connects to is the dismantling of small household appliances. The small appliances are loaded onto conveyors and passed through machinery/magnetic separators to break down the small household appliances into various smaller fractions. The activity within the shed is mainly mechanical with some hand sorting on the sorting conveyors and movement of forklifts/JCB. All machinery is enclosed and cannot be accessed. The process varies very little on a day-to-day basis.

6. Monitoring Deviation

Requirements of IS EN 15259 for sampling points A2-5

Measurement plane is located as far downstream and upstream from any disturbances, which could change

direction of flow (bends, fans, partially closed dumpers). (IS EN 15259:2007 6.2.1.b) (AG1 2.2 and 2.1)

Compliant, Note: measuring plane is located as far

downstream and upstream from any disturbances.

Measurement Plane is located in a section of duct with at least five hydraulic diameters of straight duct upstream of the

sampling plane. (IS EN 15259:2007 6.2.1.b) (AG1 2.2 and 2.1)

Compliant, Note: measuring plane of duct is located in

a section of duct with five hydraulic diameters of straight duct upstream of the

sampling plane.

Measurement Plane is located in a section of duct with at least two hydraulic diameters of straight duct downstream of the sampling plane (five hydraulic diameters from top of the

stack). (IS EN 15259:2007 6.2.1.b) (AG1 2.2 and 2.1)

Deviation. Note: Measurement plane is not located in

a section of duct with five hydraulic diameters from top of stack (plane is

located close to top of the stack). Measurement Plane is located in a section of duct with

constant shape and cross-sectional area. (IS EN 15259:2007 6.2.1.b) (AG1 2.2 and 2.1)

Compliant. Note: measuring plane is located in a

section of duct with constant shape and cross-sectional area.

Measurement section is clearly identified and labelled. (IS EN 15259:2007 6.2.1.f) (AG1 3.4)

Compliant, Note: measuring section is identified and

labelled.

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Requirements of IS EN 15259:2007 6.2.3.2 for platform,

working space and ports size. A2-5

Appropriate working area. Yes, platform has appropriate size.

Safe access to monitoring point. Yes, access is safe. Sufficient ports number

For circular stacks: Small stacks (1.6m – 4 ports

1 port available. For stacks with diameter




Requirements of IS EN 14385 for Metals A2-5

Probe temperature should be kept at or above 180°C. Yes, probe temperature was kept at 182°C +/-5°C

Absorbers temperature shall be kept below 30°C Yes, absorbers temperature was kept below 30°C +/-2°C. Absorbers efficiency requirement:

If one of the individual metals elements in the last impinger is more than 10% of the total combined

result for that element. (not applicable if the result is less than 1% of the result of total mass of metals or

if the result is less than 30% of the ELV)

n/a

Requirements of IS EN 13211 for Mercury A2-5 Probe temperature should be kept at or above

180°C. Yes, probe temperature was kept at 182°C +/-5°C

The amount of mercury collected in the second absorber shall correspond to less than 5 % of the total amount of mercury in both absorbers or less

than 2 µg/m3, whichever is the greatest.

The amount of Mercury collected is 0.3 µg/m3.

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7. Annex 1

7.1. Personnel

Scientist/Technician Name Position Qualification

Technical Endorsements

MCERTS Number

Ewa Piatek Team Leader Level 2 TE1, TE2, TE3, TE4 MM07 799

Jim Nelligan Trainee Trainee - MM17 1427 Patrick Power Technician Level 1 - MM12 1183

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8. Annex 2

8.1. Diagram - sampling plane of stack

8.2. Sampling measurements

Determinant A2-5 Units

Number of Ports Sampled 1 -

Number of Points Sampled 4 -

Average Velocity v'a 14.5 Uncertainty 0.4 m/s m/s

Average Pressure 102.267 kPa

Average Temperature 20.5 °C

Stack Diameter 0.794 m

Nozzle Size 5.72 mm

Velocity, temperature and pressure measurements are within INAB accreditation range.

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9. Annex 3

9.1. Results and uncertainty calculations for Stack A2-5

9.2. Laboratory Certificates

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Company Name: Doc NoLicence No: Rev Date:Year: 2019 Visit No: 4 Issued by:Sampling Date:Report No: Flow Calculations for A2-5

Ewa Piatek Pat Power

Equipment Used:

Equipment :GEN

Equipment No:

Equipment :GEN

Equipment No:

Millennium 5 console: EQ069Andersen Console: EQ106Probe: EQ071 Pitot Tube: EQ081Probe: EQ107 Pitot Tube: EQ113KIMO - Flow Test: EQ079 Kimo S Pitot Tube (Long) : EQ080KIMO - Flow Test: EQ117 Kimo L Pitot Tube : EQ116Rule: EQ083Laser Distance Meter: EQ089KIMO 115 EQ091

Stack Diameter Measurements

Circular with central point

Circular no central point (tangential)

1 0.7942 0.7943 0.794

Diameter Average: 0.794 m

Stack Area 0.50 m2Sampling Line 1Sampling Points per line 4

Port Depth (m): Port 1: 0.12 Port 2:Wall thickness (m): 0.02

Samplig carried out by: Jim Nelligan

GEN2-002rev2510 July 2019QM

02 October 20192019-166

KMK TullamoreW0113-04

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02 October 20192019-166


Circular no central point

Point NumberPoint position in stack (m)

Points to be marked on

probe

Point position as % of

diameter1 0.05 0.19 6.72 0.20 0.34 25.03 0.60 0.74 75.04 0.74 0.88 93.3

Note: Sampling point should be located either >3% of the

sampling point length or more than 5 cm whichever is the greater value from the inner

duct wall.

Sampling Points Position


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02 October 20192019-166


Static Pressure: Line 1 Line 2

mmH2O Pa mmH2O PaNote: At least once per line.

Reading 1 19 189 19 189Reading 2 19 189 19 189Reading 3 19 189 19 189Reading 4 19 189 19 189Reading 5 19 189 19 189Average: 19.3 189 19.3 189

Pre-Sampling Pitot Tube Checks:CommentsKIMO Pitot EQ080

Mill 5 Pitot EQ081

None None

Internal Leakage Check

Pressurized pressure: 500 Pa 10 mm H2OTime of leak check: 15 s 15 sLeak Check Result: Pass Pass

Equipment range: 500 500

Readings: Tap 1 189 19

Tap 2 189 19

Difference : 0 0

Yes Yes

Requirement:

0.0 0.0

Swirl Check: °

Within requirements



02 October 20192019-166


Absolute pressure of the stack gas:The absolute pressure in the duct is given by the measurement of the atmospheric pressure on the siteand the static pressure measured in the duct.

Barometric (Atmospheric Pressure)Pb 765.8879842 mmHg Note: 1mb = 0.75 mmHg (Since1 atmosphere=1013.25 mb = 760 mmHg)Pstatic 19.27958549 mmH2O 760 mmHg = 101325 PaConversion form mmH2O to mmHg 13.6

Atmospheric Pressure: 102110 PaAtmospheric Temperature: 11.00 °C

Ps = 767.3056008 mmHgAbsolute Pressure

102299 Pa of stack

Result 1: Result 2 Result 3: Results Average:Standard deviation

Stdev as % of the average of

results

Previous measurements

within requirement

Date: 28/01/2019 08/04/2019 12/07/2019CO ppm 15 15 15 15.0 0.0 0.0 YesCO2 % 0.06 0.06 0.06 0.1 0.0 0.0 YesO2 % 20.9 20.9 20.9 20.9 0.0 0.0 Yes

Moisture % 2 1.9 2 2.0 0.1 2.0 Yes

Molecular Weigh of Dry Gas Stream: Molecular weight of stack gas (wet):

Bwo 0.018Md 28.85

CO2 0.06 %Molecular weight of

water:18

O2 20.90 %

CO 0.0015 % CO ppm 15.00 Ms= 28.65

N2 79.04 %

Md= 28.85

Pitot coefficiency Calibration DataCalibration Date: 26/09/2019

Calibration Date: 26/09/2019



EQ080 KIMO - S Pitot Tube Long

EQ116 KIMO - L type EQ081 Mill 5

EQ113 Andersen

m/sec Cp m/sec Cp m/sec Cp m/sec Cp3.05 0.854 3.23 0.99 3.04 0.843 3.08 0.845.19 0.863 5.11 1.011 5.12 0.843 5.04 0.834

10.04 0.868 10.14 1.009 10.14 0.846 10.16 0.84715.14 0.858 15.56 1.011 15.01 0.853 15.1 0.84720.17 0.855 20.83 1.009 20.32 0.854 20.13 0.84825.75 0.856 25.64 1.01 25.65 0.853 25.77 0.848

Previous Measurements:

Note: Standard deviation < 20% of the average of results. (AG2 rev4-May2018 -Appendix 1)

Actual Measurements:

𝑃𝑃𝑠𝑠 = 𝑃𝑃𝑏𝑏 +𝑃𝑃𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆13.6

𝑀𝑀𝑑𝑑 = 44%𝐶𝐶𝐶𝐶𝐶

100+ 3𝐶

%𝐶𝐶𝐶100

+ 𝐶8%𝐶𝐶𝐶𝐶 + %𝑁𝑁𝐶

100𝑀𝑀𝑠𝑠 = 𝑀𝑀𝑑𝑑 1− 𝐵𝐵𝑤𝑤𝑤𝑤 + 18(𝐵𝐵𝑤𝑤𝑤𝑤)


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02 October 20192019-166


Time Start: 10:04 Time End: 10:08

Velocity by Mill 5 Velocity Temperature

Pressure of Stack

ΔPs Pa ΔPs mmH2O √ΔPs mmH2O m/s °C kPaDifferential Pressure

Point 1 166.65 17 4.123 14.2 21 102.299 166.65 PaPoint 2 176.46 18 4.243 14.6 20 102.299 176.46 PaPoint 3 176.46 18 4.243 14.6 21 102.299 176.46 PaPoint 4 176.46 18 4.243 14.6 20 102.299 176.46 PaTotal Average: 17.8 4.2 14.5 20.5 102.299 174.01 Pa

Uncertainty 0.4Higes to Lowest flow ratio: 1.0 :1 Max flow: 14.64Requirement is Duct Flow ratio of max. to min.



02 October 20192019-166


After-Sampling Pitot Tube Checks:CommentsKIMO Pitot EQ080

Mill 5 Pitot EQ081

None None

Internal Leakage Check

Pressurized pressure: 500 Pa 10 mm H2OTime of leak check: 15 s 15 sLeak Check Result: Pass Pass

Equipment range: 500 500

Readings: Tap 1 189 19

Tap 2 188 19

Difference : 1 0

Yes Yes

Requirement:

0.2 0.0

Results:Circular StackStack Diameter: 0.794 m

Average velocity: 14.52 m/s1

Average Temperature: 293.50 KAverage Pressure: 102.299 kPaAverage Moisture: 0.0 %Average Oxygen: 0.00 %

Reference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Moisture: 0 %Reference Oxygen: 0 %

Mass Emissions Calculations:Volumetric Flow Rate 7.19 m3/s = stack area (m2)*velocity(m/s)Volumetric Flow Rate 25881.6 m3/h = voumetric flow rate (m3/s) *60 *60 Volumetric Flow Rate corrected to STP 24311.2 m3/h =volumertic flow rate (m3/hr)*(273*stack pressure)/(stack temperature*101.3)Volumetric Flow Rate corrected to STP and Dry 24311.2 m3/h =volumetric flow rate (m3/hr)*((100-stack moisture)/100)Volumetric Flow Rate corrected to STP, Dry and O2 ref 24311.2 m3/h =volumetric flow rate (m3/hr)*((20.9-measured oxygen)/(20.9-reference oxygen))Uncertainty 1266.9 m3/h

S-tope pitot tube shall be positioned perpendicular to the direction of the flow. The static pressure is than measured using both taps. The difference in the measured static pressure should be < 10Pa

Note: blow through the pitot impact opening until at least 7.6 cm (3.0 in.) H20 velocity head registers on the manometer; then, close off the impact opening. The pressure shall remain stable for at least 15 seconds; (2) do the same for the static

pressure side, except using suction to obtain the minimumof 7.6 cm (3.0 in.) H20.

Check on stagnation and reference pressure taps:

Stagnation and reference taps within requirements?

Difference in the measuredstatic pressure should be less than 0,5 % of the

range of the differential pressurewith aminimum tolerance value of 10 Pa.

Deformities, Burrs, Damage


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02 October 20192019-166


Uncertainty calculation for Velocity and Volume Flow Rate Measurement by Pitot tube EN ISO 16911-1v1.2 Jan-16Constants Characteristics of pressure sensor used for Delta PGas constant 8.314 J/(K.mol) Enter uncertainties as (95%,k=2) where relevant

Range of Delta P transducer 1000 PaResolution of Delta P transducer 1 PaRepeatability of Delta P transducer 2 % of valueDrift of Delta P transducer 0.1 % of range between calibrationsLack of fit of measurement system 0.1 % of rangeUncertainty in Delta P transducer 2.0 Pa

Enter uncertainties as (95%,k=2) where relevant Water vapour m 2 % relativePitot coefficient, 0.8530 Uncertainty in temperature readout system 2.5 °C CO content mea 0 % relativeExpanded uncerta 0.02 Uncertainty in atmospheric pressure transducer 173.4 Pa CO2 content me 0.06 % relative

Uncertainty in duct area measurement 2.0 % O2 content meas 20.90 % relative

Duct dimensionCircularDiameter 0.794 mArea 0.5 m2

All Pressures should be entered in Pascals, Pa

Atmospheric Pressure, Pa

Stack Pressure, Pa

Static Pressure, Pa meas1, Pa meas2, Pa meas3, Pa meas4, Pa meas5, Pa Delta P, Pa

Stack Temperature, C

Water Vapour Content, % CO, ppm CO2, % N2, % O2, %

dry molecular wt, g/mol

stack molecular wt, g/mol

102110 102299 189 166.65 166.65 166.65 166.65 166.65 167 21 2 15 0.06 79.0 20.90 28.85 28.65102110 102299 189 176.46 176.46 176.46 176.46 176.46 176 20 2 15 0.06 79.0 20.90 28.85 28.65102110 102299 189 176.46 176.46 176.46 176.46 176.46 176 21 2 15 0.06 79.0 20.90 28.85 28.65102110 102299 189 176.46 176.46 176.46 176.46 176.46 176 20 2 15 0.06 79.0 20.90 28.85 28.65102110 102299 189.0 174.0 174.0 174.0 174.0 174.0 174.0 20.5 1.8 15.0 0.1 79.0 20.9 28.85 28.65

Dry gas basis

Uncertainty in stack gas compositionEnter uncertainties as (95%,k=2) where relevant


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02 October 20192019-166


Mean density 1.2011 kg/m3

Circular duct

Flow rate 24311.2 m3/hour

Volume flow rate expanded uncertainty 1266.9 m3/hour

Volume flow rate expanded uncertainty 5.2 % of valueVelocity associated uncertaintiesPitot Tube CoefficientExpanded uncertainty (95%, k=2) 0.02Standard uncertainty (Dimensionless) 0.01

Table 1

Delta P Standard uncertanites^2Measurement Point

SD of the mean of the DP measurements

(Standard uncertainty Delta P)^2 u2(Dpi)/4DP2 Velocity (m/s)

Standard uncertainty velocity m/s

Sigma DP See Table 1 1 3.3 3.6 0.000115753 14.2 0.23Resolution uncertainty 0.08 2 3.5 3.8 0.000114051 14.6 0.24Calibration uncertainty 1.00 3 3.5 3.8 0.000114051 14.6 0.24Lack of fit 0.33 4 3.5 3.8 0.000114051 14.6 0.24Drift 0.33 5

67

Molar Mass 8u(H2O) 0.02 9(O2)wet 20.5 10u(O2)wet 2.14 11(CO2)wet 0.1 12u(CO2)wet 0.00 13(CO)wet 0.0 14u(CO)wet 0.00 15Oxygen sensitivity 4.00E-05 16Water sensitivity 1.00E-04 17CO2 sensitivity 1.60E-04 18CO sensitivity 4.00E-08 19

20standard uncertainty 0.000086 kg/mol 0.30 % of value Average 3.5 3.7 0.0 14.5 0.2


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02 October 20192019-166


Temperaturestandard uncertainty 1.25 K 0.43 % of value

Stack static pressurestandard uncertainty 3.78 Pa 2.00 % of value

Stack pressurestandard uncertainty 173.4 Pa 0.17 % of value

Stack gas densitystandard uncertainty 0.0066 kg/m3 0.55 % of value

Standard uncertainty of velocity 0.18 m/sec 1.2 % of value

Expanded uncertainty in velocity 0.4 m/sec 2.4 % of value

Mean velocity 14.52 m/sec

Standard uncertainty of velocity 0.18 m/sec 1.2 % of value

Expanded uncertainty in velocity 0.4 m/sec 2.4 % of value

Volume flow rate associated uncertainties

Circular ductArea uncertainty 0.05 m2

Flow rate standard uncertainty 633.5 m3/h

Volume flow rate expanded uncertainty 1266.9 m3/h

Volume flow rate expanded uncertainty 5.2 % of value

Developed for the STA by David Butterfield & Chris Dimopoulos, NPL


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Company Name: KMK Tullamore Doc No GEN2-002rev25Licence No: W0113-04 Rev Date: 10 July 2019Year: 2019 Visit No: 4 Issued by: QMSampling Date: 02 October 2019Report No: 2019-166 Isokinetic Samplin for A2-5

Equipment : GEN Equipment No: Equipment :GEN

Equipment No:

Millennium 5 console: EQ069Andersen Console: EQ106Probe: EQ080 Pitot Tube: EQ081Probe: EQ107 Pitot Tube: EQ113KIMO - Flow Test: EQ079 Kimo S Pitot Tube (Long) : EQ080KIMO - Flow Test: EQ117 Kimo L Pitot Tube : EQ116Rule: EQ083Laser Distance Meter: EQ089KIMO 115 EQ091Filter Holder: EQ084 Notes: Do not sample point with higher than 15° flow direction from stack axis.Glass Filter Holder EQ085 If the negative flow was founs point aroud it should not be sampledImpingers: EQ072 If the suitable sampling location could not be found double number od sampling point.Impingers: EQ124Nozzle: EQ08747mm GFA FiltersRun Filter Number: Blank Filter Number:

Determination of Nozzle size: K factor:

ΔH@ 60.9 mmHg calculated on the 02/08/2019 ΔH@ Millenium 60.9Tm 21 °C Meter Temperature estimated ΔH@ Andersen 58.2

Vdessired 0.5 m3Ts 0 °C K= 4.07Ps 767.305601 mmHgCp 0.853 S-type pitot tube constant Eastimated Volume Metered:θ 30 minutesBwo 0.02(√(∆𝑃𝑃)) 𝑎𝑎𝑎𝑎𝑎𝑎 4.21ΔP 17.75 mmH2O

Dn2= 25.47 mm2 EstVmstd= 0.64227 m3

Estimated sampling rate: 21.4 l/min 1.2845 m3/hr

Note: Max sampling flow rate is 23l/min

Dn (calculated 5.05 mm 2.7 5.9 10.95.72 mm 4.38 6.86 12.5 it is recommended to use nozzles with an inside diameter exceeding 8 mm. (IS EN 13284-1:2017)5.72 mm 5.72 7.565.72 mm 5.91 9.12Dn= Used

nozzle size5.72 mm 5.87 10.02

Cross sectional Area of the

25.70 mm2 12.45

Availlable Nozzle sizes

Nozzle Measurements:

𝐷𝐷𝑛𝑛2 =𝑉𝑉𝑑𝑑𝑑𝑑𝑠𝑠𝑆𝑆𝑑𝑑𝑑𝑑𝑑𝑑

𝑀𝑀𝑠𝑠(𝑇𝑇𝑠𝑠 + 𝐶73)𝑃𝑃𝑠𝑠

(5.9195 ∗ 10−4)𝐶𝐶𝑝𝑝𝜃𝜃(1 − 𝐵𝐵𝑤𝑤𝑤𝑤)( ∆𝑃𝑃)𝑎𝑎𝑎𝑎𝑎𝑎

𝐾𝐾 = 8.04 ∗ 10−5 ∗ 𝐶𝐶𝑝𝑝2 ∗ ∆𝐻𝐻𝐻𝑇𝑇𝑚𝑚 + 𝐶73𝑇𝑇𝑠𝑠 + 𝐶73

∗𝑃𝑃𝑠𝑠𝑃𝑃𝑏𝑏

∗𝑀𝑀𝑑𝑑𝑀𝑀𝑠𝑠

∗ (1 − 𝐵𝐵𝑤𝑤𝑤𝑤)(𝐷𝐷𝑛𝑛)4

𝐸𝐸𝐸𝐸𝐸𝐸𝑉𝑉𝑚𝑚𝑠𝑠𝑆𝑆𝑑𝑑 = 5.9195 ∗ 10−4 ∗ 𝐶𝐶𝑝𝑝𝑃𝑃𝑠𝑠

𝑀𝑀𝑠𝑠 273+𝑇𝑇𝑠𝑠∗ ( ∆𝑃𝑃)𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐷𝐷𝑛𝑛2𝜃𝜃(1 −𝐵𝐵𝑤𝑤𝑤𝑤)


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0.012845497 m3

Leak Check:Vacum Pressm3 Time Pass/Fail

Before Blank: -7 0 2 min Pass

Before Run: -7 0 2 min Pass

Filtration device used: Instack filtration

Sampling requirements:

ParameterFilter Instack /Outstack

Particulates

“In-stack” 1m3/h - 3m3/h (if gases well above acid dew point),“Out-stack” 1m3/h - 10 m3/h (if gases saturated, if gases below acid dew point)

Moisture n/a

The temperature at the outlet of trapping unit shall not be greater than 4 °C or by checking visually the amount of silica gel having faded in the

last impinger or cartridge. This amount shall not exceed 50 %

Filter temperature

160°C or stack temperature

0

Probe temperature

160°C or stack temperature

0

Sampling time

min. 30 minutes/ for paharmaceutica dust min 1

hour

1 hour for low moisture below 4%/30 minutes for resutls

above 4%

Allowable leak check less than:

Others

When using in-stack filtration, to prevent condensation forming on the filter, the filtration

device should be externally pre-heated to a temperature above the stack gas temperature

or preheated in stack

0

Impingers temperature

0


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Sampling:Stack Diameter 0.794 m Start Time: 10:34:00 End Time:Cross sectional Area of the stack: 0.495 m2 Dry Gas Pressure: 102.110 kPa

Points number: 4 Sampling time at each po 8 min. Note: minimum 3 minutes at each point.

Traverse point number Clock Time Pump Vacuum Velocity Heads

Sqr roots Velocity Heads

Orfice Settings

Calculated

Orfice Settings

Readings

Gas Sample Volume

Stack Temp

Probe Temp Impinger Temp Tc Filter Temp

K Factor Calculate

d

Velocity of the stack

Actual Flow Of Stack

Actual Sampled Volume

Vmstd at the time of measuring at STP

Isokinetic Ratio

mmHg ΔPs √ΔPs ΔH ΔHVm

(m3/1000) (liters)

°C °C °C °C Inlet °C Outlet °Cm/s m3/min m3 m3 %

0 -3 17 4.123 63.676 65 7864 21 163 3 18 18 3.75 14.21 422.181 5 -3 17 4.123 63.676 65 7973 21 163 3 18 18 3.75 14.21 422.18 0.11 0.1031 102.241 10 -3 17 4.123 63.676 65 8087 21 163 2 18 18 3.75 14.21 422.18 0.22 0.2109 104.581 15 -3 18 4.243 67.421 65 8198 21 163 3 18 18 3.75 14.62 434.42 0.33 0.3159 101.492 20 -3 18 4.243 67.421 65 8307 21 163 2 18 18 3.75 14.62 434.42 0.44 0.4190 100.952 25 -3 18 4.243 67.421 65 8421 21 163 2 18 18 3.75 14.62 434.42 0.56 0.5269 101.552 30 -3 18 4.243 67.421 65 8534 21 163 2 18 18 3.75 14.62 434.42 0.67 0.6338 101.793 35 -3 18 4.243 67.537 65 8645 21 163 3 18 19 3.75 14.62 434.42 0.78 0.7386 101.683 40 -3 18 4.243 67.653 65 8756 21 163 3 19 19 3.76 14.62 434.42 0.89 0.8433 101.583 45 -3 18 4.243 67.653 65 8867 21 163 3 19 19 3.76 14.62 434.42 1.00 0.9480 101.504 50 -3 18 4.243 67.653 65 8978 21 163 3 19 19 3.76 14.62 434.42 1.11 1.0526 101.444 55 -3 18 4.243 67.653 65 9088 21 163 3 19 19 3.76 14.62 434.42 1.22 1.1563 101.304 60 -3 18 4.243 67.653 65 9199 21 163 3 19 19 3.76 14.62 434.42 1.34 1.2610 101.26

Average: 17.77 4.22 65.00 20.50 163.00 2.69 #DIV/0! 18.38 18.46 14.53 431.60 As %1335.00 1.3

Gas Sample Temperature at Dry Gas

Meter

11:34:00


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Circular StackStak Diameter: 0.794 m

Average Flow corrected for wall effect: 14.53 m/sAverage Temperature: 293.50 KAverage Pressure: 102.299 kPaAverage Moisture: 0.00 %Average Oxygen: 0.00 %

Reeference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Moisture: 0 %Reference Oxygen: 0 %

Mass Emissions Calculations:Volumetric Flow Rate 7.19 m3/sVolumetric Flow Rate 25895.9 m3/h

Flow Rate corrected to STP 24324.7 m3/h

24324.7 m3/h

24324.7 m3/h

Note: If the results of isokinetic sampling are to be reported as mass emission, than the flow rate used during isokinetic sampling shall be used.

Volumetric Flow Rate corrected to STP and Dry

Volumetric Flow Rate corrected to STP, Dry and O2 ref


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Company Name: KMK Tullamore Doc No GEN2-002rev25Licence No: W0113-04 Rev Date: 10 July 2019Year: 2019 Visit No: 4 Issued by: 0 QMSampling Date: 02 October 2019Report No: 2019-166 Moisture Record and Calculations for A2-5

Equipment used:

Balance: EQ056Weights: EQ063

Balance Check:

Initial Weight: Balance Reading:100g 100.1500g 499.9800g (combined 100g,200g,500g) 799.9

Before

Readings:Impinger 1 + Connection Impinger 2+Connection

Impinger 3+Connection

Impinger 4+Connection Sum:

1 789.6 786.8 648.8 1098.7 3323.92 789.6 786.8 648.8 1098.7 3323.93 789.6 786.8 648.8 1098.7 3323.94 789.6 786.8 648.8 1098.7 3323.95 789.6 786.8 648.8 1098.7 3323.96 789.6 786.8 648.8 1098.7 3323.97 789.6 786.8 648.8 1098.7 3323.98 789.6 786.8 648.8 1098.7 3323.99 789.6 786.8 648.8 1098.7 3323.9

10 789.6 786.8 648.8 1098.7 3323.9Standard Deviation: 0 0 0 0 0Averge: 789.6 786.8 648.8 1098.7 3323.9

After

Readings:Impinger 1+Connection Impinger 2+Connection

Impinger 3+Connection

Impinger 4+Connection Sum:

1 807.6 787.1 648.9 1098.8 3342.42 807.6 787.1 648.9 1098.8 3342.43 807.6 787.1 648.9 1098.8 3342.44 807.6 787.1 648.9 1098.8 3342.45 807.6 787.1 648.9 1098.8 3342.46 807.6 787.1 648.9 1098.8 3342.47 807.6 787.1 648.9 1098.8 3342.48 807.6 787.1 648.9 1098.8 3342.49 807.6 787.1 648.9 1098.8 3342.4

10 807.6 787.1 648.9 1098.8 3342.4Standard Deviation: 0 0 0 0 0Averge: 807.6 787.1 648.9 1098.8 3342.4

Note: If balance is moved to other location balance check has to be repeated.


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Air Volume corrected to STP: 1.260985797 m3

Efficiency: 99.46 %

Stack Conditions:

Average Temperature: 293.5 KAverage Pressure: 102.299 kPaAverage Moisture: 0.00 %Average Oxygen: 0.00 %

24311.24 m3/hr

Reference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Oxygen: 0 %Reference Moisture: 0 %

Results :At Standard Temperature and Pressure corrected O2 ref Uncertainty

g/m3 14.7 14.7 2.8 Overall uncertainty is 19.36 % of the measured value% 1.8 1.8 0.3

Note: Overall uncertainty should be lower than +/-20% of the measured value



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Moisture Uncertainty CalculationsMeasured concentration 1.8 % (at STP)Measured Quantities Symbol Value Standard uncertainty UnitsSampled Volume Vm 1.260985797 uVm 0.001 m3Sampled gas Temperature Tm 293.5 uTm 2 kSampled gas Pressure ρm 102.299 uρm 1 kPaEfficiency Ɛ 99.46 %Oxygen content O2,m 0 uO2,m 0.1 % by volumeWater collected in condensation stage 18.50Water collected in adsorption stage 0Wate collected in addidional unit 0.1Water collected in trapping unit m 18.60 um 0.00 gIntermediate calculationsVwc 226.0985797 ^2

11.9 142.5 Efficiency uncertainty 0.03-2.2 5.0 support 0.03-0.8 0.6 calculations 0.00

√water in trapping unit 4.3

water in adsorption stage 0.0Uncertainty Efficiency^2 0.0Volume ^2 1.1Sensityvity coefficiency 615.1Uncertainty efficiency 0.00

Repatability standard devWeight in the field st 0.0 0.0Sampled Volume 0.002 0.0Sampled gas Temperature 0.02 0.0Sampled gas Pressure 0.3 0.2Combined measurement uncertainty 0.17 %

Expanded uncertainty as percentage of measured value 19.36 % measured of value expressed with a level of confidence of 95%(Using a coverage factor k=2)

Expanded uncertainty in units of measurement 0.35 % of water vapour


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Company Name: KMK Tullamore Doc No GEN2-002rev25Licence No: W0113-04 Rev Date: 10 July 2019Year: 2019 Visit No: 4 Issued by: QMSampling Date: 02 October 2019Report No: 2019-166 Particulates Results Calculations for A2-5

Paticulates Data:

Certs Results: mg Date analysis completed:LOD Filter: 0.04 14/10/2019

LOD Nozzle Wash: 0.5 Sample reference number:

Blank Filter: 0.04 1085192Blank Nozzle Wash: 0.5 1085194Run Filter: 0.25 1085191Run Nozzle Wash: 0.5 1085193

0.54Blank 0.54Run 0.75

1.260985797 m3

1.284008019 m3

Stack ConditionsAverage Temperature: 293.5 KAverage Pressure: 102.299 kPaAverage Moisture: 0.00 %Average Oxygen: 0.00 %

24311.24 m3/h

Reference ConditionsReference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Oxygen: 0 %Reference Moisture: 0 %

Particulates Results :mg/m3 mg/m3 kg/hr Uncertainty

corrected to O2 mg/m3LOD 0.4 0.4 0.01 n/aBlank 0.4 0.4 0.01 0.01 Blank result is: 4 % of ELVRun 0.6 0.6 0.01 0.02 If the blank result is higher than requirements of ELV result should be rejected


the field blank value does not exceed 10 % of the lowest emission limit value set for the process or 0,5 mg/m3, whichever is greater;

Dry Air Volume corrected to STP:

Wet Air Volume corrected to STP:


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Particulates Uncertainty Run CalculationsUncertainty calculation for EN 13284 Determination of low range mass concentration of dust, Manual Gravimetric Methodrev14Limit value (ELV) 10 mg.m-3 Reference oxygen 0 % by volumeMeasured concentration 0.6 mg.m-3 (at reference conditions)Measured Quantities Symbol Value Standard uncertainty Units Uncertain Uncertain Requirement of stdSampled Volume Vm 1.284008019 uVm 0.001 m3 0.08


Particulates Uncertainty Blank CalculationsUncertainty calculation for EN 13284 Determination of low range mass concentration of dust, Manual Gravimetric Methodrev14Limit value (10% of ELV) 1 mg.m-3 Reference oxygen 0 % by volumeMeasured concentration 0.4 mg.m-3 (at reference conditions)Measured Quantities Symbol Value Standard uncertainty Units Uncertain Uncertain Requirement of stdSampled Volume Vm 1.284008019 uVm 0.001 m3 0.08


Equipment : GEN Equipment No: Equipment :GEN

Equipment No:

Millennium 5 console: EQ069Andersen Console: EQ106Probe: EQ080 Pitot Tube: EQ081Probe: EQ107 Pitot Tube: EQ113KIMO - Flow Test: EQ079 Kimo S Pitot Tube (Long) : EQ080KIMO - Flow Test: EQ117 Kimo L Pitot Tube : EQ116Rule: EQ083Laser Distance Meter: EQ089KIMO 115 EQ091Filter Holder: EQ084 Notes: Do not sample point with higher than 15° flow direction from stack axis.Glass Filter Holder EQ085 If the negative flow was founs point aroud it should not be sampledImpingers: EQ072 If the suitable sampling location could not be found double number od sampling point.Impingers: EQ124Nozzle: EQ08747mm GFA FiltersRun Filter Number: Blank Filter Number:

Determination of Nozzle size: K factor:

ΔH@ 60.9 mmHg calculated on the 02/08/2019 ΔH@ Millenium 60.9Tm 21 °C Meter Temperature estimated ΔH@ Andersen 58.2

Vdessired 0.5 m3Ts 0 °C K= 4.07Ps 767.305601 mmHgCp 0.853 S-type pitot tube constant Eastimated Volume Metered:θ 30 minutesBwo 0.02(√(∆𝑃𝑃)) 𝑎𝑎𝑎𝑎𝑎𝑎 4.21ΔP 17.75 mmH2O

Dn2= 25.47 mm2 EstVmstd= 0.64227 m3

Estimated sampling rate: 21.4 l/min 1.2845 m3/hr

Note: Max sampling flow rate is 23l/min

Dn (calculated 5.05 mm 2.7 5.9 10.95.72 mm 4.38 6.86 12.5 it is recommended to use nozzles with an inside diameter exceeding 8 mm. (IS EN 13284-1:2017)5.72 mm 5.72 7.565.72 mm 5.91 9.12Dn= Used

nozzle size5.72 mm 5.87 10.02

Cross sectional Area of the

25.70 mm2 12.45

Availlable Nozzle sizes

Nozzle Measurements:

𝐷𝐷𝑛𝑛2 =𝑉𝑉𝑑𝑑𝑑𝑑𝑠𝑠𝑆𝑆𝑑𝑑𝑑𝑑𝑑𝑑

𝑀𝑀𝑠𝑠(𝑇𝑇𝑠𝑠 + 𝐶73)𝑃𝑃𝑠𝑠

(5.9195 ∗ 10−4)𝐶𝐶𝑝𝑝𝜃𝜃(1 − 𝐵𝐵𝑤𝑤𝑤𝑤)( ∆𝑃𝑃)𝑎𝑎𝑎𝑎𝑎𝑎

𝐾𝐾 = 8.04 ∗ 10−5 ∗ 𝐶𝐶𝑝𝑝2 ∗ ∆𝐻𝐻𝐻𝑇𝑇𝑚𝑚 + 𝐶73𝑇𝑇𝑠𝑠 + 𝐶73

∗𝑃𝑃𝑠𝑠𝑃𝑃𝑏𝑏

∗𝑀𝑀𝑑𝑑𝑀𝑀𝑠𝑠

∗ (1 − 𝐵𝐵𝑤𝑤𝑤𝑤)(𝐷𝐷𝑛𝑛)4

𝐸𝐸𝐸𝐸𝐸𝐸𝑉𝑉𝑚𝑚𝑠𝑠𝑆𝑆𝑑𝑑 = 5.9195 ∗ 10−4 ∗ 𝐶𝐶𝑝𝑝𝑃𝑃𝑠𝑠

𝑀𝑀𝑠𝑠 273+𝑇𝑇𝑠𝑠∗ ( ∆𝑃𝑃)𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐷𝐷𝑛𝑛2𝜃𝜃(1 −𝐵𝐵𝑤𝑤𝑤𝑤)


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0.012845497 m3

Leak Check:Vacum Pressm3 Time Pass/Fail

Before Blank: -8 0 2 min PassAfter Blank: -8 0 2 min Pass

Before Run: -9 0 2 min PassAfrer Run: -9 0 2 min Pass

Filtration device used: Outstack filtration

Sampling requirements:

ParameterFilter Instack /Outstack

Metals Outstack0

When using titanium equipment the temperature shall be maintained at 180°C or

higher. 0 Impinger should be kept below 30°C.The length of connections (tubing) from

sampling probe to the absorbers shall be


Sampling:Stack Diameter 0.794 m Start Time: 11:56:00 End Time:Cross sectional Area of the stack: 0.495 m2 Dry Gas Pressure: 102.110 kPa

Points number: 4 Sampling time at each po 8 min. Note: minimum 3 minutes at each point.

Traverse point number Clock Time Pump Vacuum Velocity Heads

Sqr roots Velocity Heads

Orfice Settings

Calculated

Orfice Settings

Readings

Gas Sample Volume

Stack Temp

Probe Temp Impinger Temp Tc Filter Temp

K Factor Calculate

d

Velocity of the stack

Actual Flow Of Stack

Actual Sampled Volume

Vmstd at the time of measuring at STP

Isokinetic Ratio

mmHg ΔPs √ΔPs ΔH ΔHVm

(m3/1000) (liters)

°C °C °C °C Inlet °C Outlet °Cm/s m3/min m3 m3 %

0 -3 17 4.123 63.894 65 256 21 183 12 19 19 3.76 14.21 422.181 4 -3 17 4.123 63.894 65 348 21 183 12 19 19 3.76 14.21 422.18 0.09 0.0867 107.501 8 -3 17 4.123 63.894 65 439 21 183 12 19 19 3.76 14.21 422.18 0.18 0.1725 106.912 12 -3 18 4.243 67.653 65 529 21 183 12 19 19 3.76 14.62 434.42 0.27 0.2574 103.332 16 -3 18 4.243 67.653 65 619 21 183 12 19 19 3.76 14.62 434.42 0.36 0.3422 103.053 20 -3 18 4.243 67.769 65 702 21 183 12 19 20 3.76 14.62 434.42 0.45 0.4203 101.263 24 -3 18 4.243 67.885 65 825 21 183 12 20 20 3.77 14.62 434.42 0.57 0.5360 107.614 28 -3 18 4.243 67.885 65 915 21 183 12 20 20 3.77 14.62 434.42 0.66 0.6206 106.794 32 -3 18 4.243 67.885 65 1025 21 183 12 20 20 3.77 14.62 434.42 0.77 0.7240 109.01

Average: 17.67 4.20 65.00 20.50 183.00 12.00 #DIV/0! 19.33 19.44 14.49 430.34 As %769.00 9.0

12:28:00

Gas Sample Temperature at Dry Gas

Meter


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Circular StackStak Diameter: 0.794 m

Average Flow corrected for wall effect: 14.49 m/sAverage Temperature: 293.50 KAverage Pressure: 102.299 kPaAverage Moisture: 0.00 %Average Oxygen: 0.00 %

Reeference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Moisture: 0 %Reference Oxygen: 0 %

Mass Emissions Calculations:Volumetric Flow Rate 7.17 m3/sVolumetric Flow Rate 25820.5 m3/h

Flow Rate corrected to STP 24253.9 m3/h

24253.9 m3/h

24253.9 m3/hVolumetric Flow Rate corrected to STP, Dry and

O2 ref

Note: If the results of isokinetic sampling are to be reported as mass emission, than the flow rate used during isokinetic sampling shall be used.

Volumetric Flow Rate corrected to STP and Dry


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Company NamKMK Tullamore Doc No GEN2-002rev25Licence No: W0113-04 Rev Date: 10 July 2019Year: 2019 Visit No: 4 Issued by: QMSampling Date02 October 2019Report No: 2019-166 Metals resuls Calculations for A2-5

Run Lab Results LOD Filter LOD Probe W LOD Impingers Filter Rince Impinger 1&2 Impinger 3 Impinger 5 Impnger 6Cert Number

µg µg µg/l µg µg µg/l µg/l µg/l µg/lAluminium 0.5 1 10 151 2 22 51 n/a n/aAntimony 0.4 0.2 0.2 0.4 0.2 0.2 0.2 n/a n/aArsenic 0.2 0.3 0.3 0.2 0.3 0.3 0.3 n/a n/aBerylium 0.2 0.1 0.1 0.2 0.2 0.1 0.1 n/a n/aCadmium 0.2 0.3 0.2 0.2 0.3 0.2 0.2 n/a n/aChromium 0.3 0.3 0.1 0.5 0.3 40.0 3.0 n/a n/a

Cobalt 0.2 0.3 0.2 0.2 0.3 0.2 0.7 n/a n/aCopper 0.2 0.4 0.4 0.2 0.4 0.4 3.0 n/a n/a

Iron 2 2 2 11 0.4 104 17 n/a n/aLead 0.3 0.2 0.2 0.3 0.2 5.0 9.0 n/a n/a

Manganese 0.2 0.2 0.2 0.2 0.2 8.0 3.0 n/a n/aNickel 0.5 0.1 0.2 1 0.1 0.7 3.0 n/a n/a

Selenium 0.2 0.5 0.2 0.2 0.2 0.2 0.2 n/a n/aThallium 0.2 0.2 0.2 0.2 0.2 0.2 0.2 n/a n/a

Vanadium 0.2 0.2 0.1 0.2 0.20 0.1 0.2 n/a n/aZinc 1 1 2 3 1 90 21 n/a n/a

Mercury 0.03 0.5 0.5 0.03 0.03 0.5 0.5 0.5 0.5

Solutions Volume Rince Impinger 1 Impinger 3 Impinger 4 Impinger 5 ml 190 90 105 115


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BlankLab Results Filter Rince Impinger 1&2&3 Impinger 5&6Cert number

µg µg µg/l µg/l µg/l µg/lAluminium 153 2 10 n/aAntimony 0.4 0.2 0.2 n/aArsenic 0.2 0.3 0.3 n/aBerylium 0.2 0.2 0.1 n/aCadmium 0.2 0.3 0.2 n/aChromium 1 0.6 0.1 n/a

Cobalt 0.2 0.3 0.2 n/aCopper 0.2 0.4 0.4 n/a

Iron 14 5 2 n/aLead 0.3 1 0.2 n/a

Manganese 0.2 0.2 0.2 n/aNickel 0.9 1 0.2 n/a

Selenium 0.2 0.5 0.2 n/aThallium 0.2 0.2 0.2 n/a

Vanadium 0.2 0.20 0.1 n/aZinc 2 1 2 n/a

Mercury 0.03 0.5 0.5 0.5

Solutions Volume Impinger 1&2&3 Impinger 5ml 210 200

Metals Mercury0.723966288 m3 0.723966288 m30.737183973 m3 0.737183973 m3

Stack Conditions:Temperature: 293.5 KPressure: 102.299 kPa Oxygen: 0.00 % Moisture: 0.00 %

24311.24 m3/hrVolumertic Flow Rate corrected to STP O2 ref and Moisture

Wet Air Volume corrected to STP:Dry Air Volume corrected to STP:


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Reference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Oxygen: 0 %Reference Moisture: 0 %

Results :mg in sampling train

mg in sampling train

mg in sampling train

mg/m3 at STP/Dry

mg/m3 at STP/Dry

mg/m3 at STP/Dry

Corrected to reference oxygen

Corrected to reference oxygen

Corrected to reference oxygen kg/hr

LOD Run Blank LOD Run Blank LOD Run Blank Run Aluminium 0.0043 0.1618 0.1571 0.0058 0.2194 0.2131 0.0058 0.2194 0.2131 0.0053Antimony 0.0007 0.0007 0.0006 0.0009 0.0009 0.0009 0.0009 0.0009 0.0009 0.00002Arsenic 0.0006 0.0006 0.0006 0.0008 0.0008 0.0008 0.0008 0.0008 0.0008 0.00002Berylium 0.0003 0.0004 0.0004 0.0004 0.0006 0.0006 0.0004 0.0006 0.0006 0.00001Cadmium 0.0006 0.0006 0.0005 0.0008 0.0008 0.0007 0.0008 0.0008 0.0007 0.00002Chromium 0.0006 0.0087 0.0016 0.0009 0.0118 0.0022 0.0009 0.0118 0.0022 0.0003Cobalt 0.0006 0.0006 0.0005 0.0008 0.0008 0.0007 0.0008 0.0008 0.0007 0.00002Copper 0.0007 0.0009 0.0007 0.0010 0.0013 0.0009 0.0010 0.0013 0.0009 0.00003Iron 0.0046 0.0327 0.0194 0.0062 0.0443 0.0263 0.0062 0.0443 0.0263 0.0011Lead 0.0006 0.0023 0.0013 0.0008 0.0031 0.0018 0.0008 0.0031 0.0018 0.0001Manganese 0.0005 0.0022 0.0004 0.0006 0.0030 0.0006 0.0006 0.0030 0.0006 0.00007Nickel 0.0007 0.0015 0.0019 0.0009 0.0020 0.0026 0.0009 0.0020 0.0026 0.00005Selenium 0.0008 0.0005 0.0007 0.0010 0.0006 0.0010 0.0010 0.0006 0.0010 0.00002Thallium 0.0005 0.0005 0.0004 0.0006 0.0006 0.0006 0.0006 0.0006 0.0006 0.00002Vanadium 0.0004 0.0004 0.0004 0.0006 0.0006 0.0006 0.0006 0.0006 0.0006 0.00001Zinc 0.0026 0.0230 0.0034 0.0035 0.0312 0.0046 0.0035 0.0312 0.0046 0.0008Mercury 0.0006 0.0003 0.0007 0.0009 0.0004 0.0010 0.0009 0.0004 0.0010 0.00001

Total of Metals 0.0187 0.2372 0.1903 0.0254 0.3218 0.2581 0.0254 0.3218 0.2581 0.0078

Total of Cd and Tl 0.0010 0.0010 0.0010 0.0014 0.0014 0.0013 0.001 0.001 0.001 0.00003

Total of Sb, As, Pb, Cr, Co, Cu, Mn, Ni, V, Be 0.0056 0.0183 0.0086 0.0075 0.0248 0.0117 0.01 0.02 0.01 0.0006


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Efficiency

Efficiency Requirement

s ELV

Result as percentage of

ELV

Blank Result as percentage of ELV

Result as % of the total

mass of metals Note: Blank result should be < 10% of ELV

%Aluminium 2.84 10 #DIV/0! #DIV/0! 68.2Antimony 2.74 10 #DIV/0! #DIV/0! 0.3Arsenic 4.62 10 #DIV/0! #DIV/0! 0.2

Berylium 2.10 10 #DIV/0! #DIV/0! 0.2

Cadmium 3.24 10 #DIV/0! #DIV/0! 0.2Chromium 3.11 10 #DIV/0! #DIV/0! 3.7Cobalt 10.48 10 #DIV/0! #DIV/0! 0.3 For example ELVs for metals may be:Copper 28.54 10 #DIV/0! #DIV/0! 0.4 • Cd and Tl combined – 0.05 mg/m3Iron 4.68 10 #DIV/0! #DIV/0! 13.8 • Sb, As, Pb, Cr, Co, Cu, Mn, Ni, V combined – 0.5 mg/m3Lead 35.84 10 #DIV/0! #DIV/0! 1.0 • mercury – 0.05 mg/m3Manganese 12.33 10 #DIV/0! #DIV/0! 0.9Nickel 17.96 10 #DIV/0! #DIV/0! 0.6Selenium 3.95 10 #DIV/0! #DIV/0! 0.2

Thallium 3.95 10 #DIV/0! #DIV/0! 0.2

Vanadium 4.12 10 #DIV/0! #DIV/0! 0.2Zinc 8.22 10 #DIV/0! #DIV/0! 9.7Mercury 18.55 5 #DIV/0! #DIV/0! 0.1

ELV Total of Metals #DIV/0! #DIV/0!

Total of Cd and Tl #DIV/0! #DIV/0!

Total of Sb, As, Pb, Cr, Co, Cu, Mn, Ni, V, Be #DIV/0! #DIV/0!

However, for each group the requirement to pass the absorber efficiency check shall not apply:

• to individual metal element(s), where the individual mass of the element in the final result is less than 1% of the result for the total

mass of metals in the group; or• if the total combined result for the metals in the group is less

than 30% of the ELV.

If the blank result is higher than requirements of ELV result should be rejected

If one of the metal elements in the last impinger is more than 10% of the total combined metals (i.e. the filter, probe rinse and

impingers) collected then the result shall be rejected, unless the total result is less than 30% of the ELV.

If one of the individual metal elements in the last impinger (e.g. Sb) is more than 10% of the total combined metals for that individual element (i.e. the filter, probe rinse and impingers)

collected, then the result for all the metals in that group shall be rejected.


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Uncertainty mg/m3

Blank Uncertainty mg/m3

Aluminium 0.00717 0.00696Antimony 0.00003 0.00003Arsenic 0.00003 0.00002Berylium 0.00002 0.00002Cadmium 0.00002 0.00002Chromium 0.00038 0.00007Cobalt 0.00003 0.00002Copper 0.00004 0.00003Iron 0.00145 0.00086Lead 0.00010 0.00006Manganese 0.00010 0.00002Nickel 0.00007 0.00009Selenium 0.00002 0.00003Thallium 0.00002 0.00002Vanadium 0.00002 0.00002Zinc 0.00102 0.00015Mercury 0.00001 0.00003

Total of Metals 0.01051 0.00843

Total of Cd and Tl 0.00004 0.00004

Total of Sb, As, Pb, Cr, Co, Cu, Mn, Ni, V, Be 0.00081 0.00038


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Metals Uncertainty Run CalculationsMeasured concentration 0.2 mg.m-3 (at reference conditions)Measured Quantities Symbol Value Standard uncertainty Units Uncertainty as pUncertainty at Requirement of stdSampled Volume Vm 0.737183973 uVm 0.001 m3 0.14


Metals Uncertainty Blank CalculationsMeasured concentration 0.2 mg.m-3 (at reference conditions)Measured Quantities Symbol Value Standard uncertainty Units Uncertainty as pUncertainty at Requirement of stdSampled Volume Vm 0.737183973 uVm 0.001 m3 0.14

Test Certificate Date 19/11/2019

Glenside Environmental

Unit 18

Great Island Industrial Estate

Innishmore

Ballincollig

Cork

Client Order No. 2019-166KMKTullamoreQ3

WK19-10434Certificate No.

Issue No. 1

Contact 28/10/2019Date ReceivedEwa Piatek

Description 10 Samples for Metals and Mercury Technique ICP Stack

Sample No. 1084134 166-05 Mercury A2-5 Imp 5 Method

M112-BSEN13211(U)

Date 19/11/2019Test Certificate


1Issue No.

Client Glenside Environmental

Sample No. 1084138 166-09 Metals Imp 1&2 Method

in house(N)78 µg/lAluminium

M31 (MCERTS)(U)



1Issue No.


Sample No. 1084140 166-11 Metals Rinse Method

in house(N)125 µgAluminium

M31 (MCERTS)(U)



1Issue No.


Sample No. 1084142 166-13 Metals Imp Blank Method

in house(N)4 µgAluminium

M31 (MCERTS)(U)



1Issue No.


Approved By Date

Mateusz LisowskiTested By 06/11/2019Date

Joanne Dewhurst

Operational

For and on authority of RPS Laboratories Ltd.

Method Symbols (U) Analysis is UKAS Accredited

(N) Analysis is not UKAS Accredited

Concentration values (mg/m3 and ppm) are not covered by the scope of UKAS accreditation.

Results stated as ml are refering to the sample volume.

Analysis carried out on samples 'as received'

This document may not be reproduced other than in full, except with the written approval of the issuing laboratory.

RPS Laboratories terms and conditions apply - a copy is available on request.

19/11/2019

19/11/2019

RPS Environmental Management Ltd trading as RPS laboratories. Unit 12. Waters Edge Business Park. Modwen

Road. Salford. M5 3EZ

Page 5 of 5

Page 51 of 53

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Test Certificate Date 29/11/2019

Glenside Environmental

Unit 18

Great Island Industrial Estate

Innishmore

Ballincollig

Cork

Client Order No. -


Issue No. 1

Contact 29/10/2019Date ReceivedEwa Piatek

Description 4x filters + washes for particulates Technique Gravimetric

Sample No. 1085190 168-01 Particulates A2-5 Filter Run Method

D9 (MCERTS)(U)0.25 mgTotal particulate matter

Sample No. 1085191 166-02 Particulates A2-5 Filter Blank Method

D9 (MCERTS)(U)



1Issue No.


Approved By Date

Tony DruryTested By 28/11/2019Date

Joanne Dewhurst

Operational

For and on authority of RPS Laboratories Ltd.

Method Symbols (U) Analysis is UKAS Accredited

(N) Analysis is not UKAS Accredited

Concentration values (mg/m3 and ppm) are not covered by the scope of UKAS accreditation.

Results stated as ml are refering to the sample volume.

Analysis carried out on samples 'as received'

This document may not be reproduced other than in full, except with the written approval of the issuing laboratory.

RPS Laboratories terms and conditions apply - a copy is available on request.

29/11/2019

RPS Environmental Management Ltd trading as RPS laboratories. Unit 12. Waters Edge Business Park. Modwen

Road. Salford. M5 3EZ

Page 2 of 2

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EPA Export 25-04-2020:12:30:18

1. KMK Tullamore Q4 2019TABLE OF CONTENTSPAGE

1. Introduction2. Objectives2.1. Substances to be monitored at each emission point2.2. Special Requirements

There were no special requirements for this monitoring campaign.3. Materials and Methods3.1. Particulates - ISO9096:2017 (high) or IS EN 13284-1:2017 (low)3.2. Metals – IS EN 14385:2004& Mercury – IS EN 13211:20013.3. Volumetric Flow Rate – ISO 16911-1:2013

4. Monitoring Results4.1. Monitoring Results4.2. Monitoring Results4.3. Reference Conditions4.4. Methods and Accreditation Status

5. Operating InformationNote: The process occurring in the shed the stack connects to is the dismantling of small household appliances. The small appliances are loaded onto conveyors and passed through machinery/magnetic separators to break down the small household appliance...6. Monitoring Deviation7. Annex 17.1. Personnel

8. Annex 28.1. Diagram - sampling plane of stack8.2. Sampling measurements

9. Annex 39.1. Results and uncertainty calculations for Stack A2-59.2. Laboratory Certificates

2. KMK Tullamore Stack calc Q4 2019 final1. Flow2.Isokinetic SamplingMoistureParticulates2.Isokinetic Sampling (2)Metals

CofA metalsCofA part

Documents

KMK Metals Recycling LimitedCompany Name: KMK Metals Recycling Limited Licence No: W0113- 04 Year: 2019, Visit No: 4 Report No: 2019-166 . Glenside Environmental Services Doc No: GEN2-001rev13