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Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
4.8 Fabry-Perot optical resonator
a. Separation of the modes is,
∆υm = υ f =c
2L=
(3×108 m s-1)
2(0.5 m)= 3×108 Hz = 300 MHz.
The finesse is
F =
πR1/ 2
1− R=
π 0.991 / 2
1− 0.99= 312.6
and each mode width, spectral width, is
δυm =υ f
F=
3×108
312.6 = 9.6××××105 Hz = 960 kHz.
b Cavity mode nearest to the emission wavelength is
m =
2L
λ / n=
2(200×10−6)
(1300× 10−9)/ 3.7=1138.46 i.e. m = 1138.
Separation of the modes is,
∆υm = υ f =
c /n2L
=(3×108 m s-1) / 3.7
2(200×10−6 m)= 2.03×1011 Hz
The finesse is
F =
πR1/ 2
1− R=
π 0.81/ 2
1− 0.8 = 14.05
and each mode width, spectral width, is
δυm =υ f
F=
2.03× 1013
14.05 = 1.4×1010 Hz.
4.10 Threshold current and power output from a laser diode
a If Nph is the coherent radiation photon concentration, then only half of the photons, 1/2Nph, in the cavity would be moving towards the output face of the crystal at any instant. It takes ∆t = nL/c seconds for photons to cross the laser cavity length L.
Po = Energy flow per unit time in cavity towards face× Transmittance
=
hcλ
12 Nph( )dWL( )
∆t
Transmittance
=
hc
λ
12 Nph( )dWL( )
Lnc
1− R( )
=hc2NphdW
2nλ
1− R( )
and I =
Optical Power
Area=
Po
dW=
hc2Nph
2nλ
1− R( )
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
where R is the reflectance of the crystal face.
b Consider one round trip through the cavity. The length L is traversed twice and there is one reflection at each end. The overall attenuation of the coherent radiation after one-round trip is
RRexp[−α(2L)]
where R is the reflectance of the crystal end.
Equivalently we can represent this reduction by an effective or a total loss coefficient αt such that after one round trip, the reduction factor is
exp[−αt(2L)]
Equating the two,
RRexp[−α(2L)] = exp[−αt(2L)]
and rearranging,
αt = α +
1
2Lln
1
R2
c The reflectance is
R =
n −1
n +1
2
=3.5−1
3.5+1
2
= 0.309
The total loss coefficient is
αt = α +
1
2Lln
1
R2
=1000 m−1 +
1
60×10−6 m−1 ln1
0.3092
= 2.06×104 m-1.
∴ τ ph =
ncαt
=3.5
(3×108 m s−1)(2.06× 108 m−1)= 5.7×10-13 s (0.57 ps)
Coherent radiation is lost from the cavity after, on average, 0.57 ps.
For the above device, threshold current density Jth ≈ 500 A cm-2 and τsp ≈ 10 ps, d ≈ 0.25 µm,
From Jth =nthed
τ sp
we have, nth ≈Jthτ sp
ed≈
(500×104 A m-2)(10 ×10−9s)
(1.6×10−19C)(0.25×10−6m)≈ 1.25×1024 m-3 or 1.2×102×102×102×1018181818 cm-3
Now, the current density corresponding to I = 30 mA is
J = I/(WL) = (0.05 A)/[10×60×10-610-6 m2)] = 833×104 A m-2.
And, N ph ≈τ ph
edJ − J th( ) ≈
(5.7×10−13s)
(1.6×10−19C)(0.25×10−6m)(833−500)×104 A m-2
≈ 4.7×1×1×1×1000019191919 photons m-3
The optical power is
Po =hc 2N phdW
2nλ
1−R( )
= (6.62×10−34 J s)(3×108 m s-1)2(4.7×1019 m-3)(0.25×10−6 m)(10×10−6 m)
2(3.5)(1310×10−9 m)× 1− 0.309( )
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
≈ 0.00053 W or 0.53 mW.
Intensity = Optical Power / Area = Po / (dW)
= (0.00053)/[0.25×10×10-310-3 mm2)] = 223 W mm-2.
This intensity is right at the crystal face over the optical cavity cross section. As the beam diverges, the intensity decreases away from the laser diode.
4.12 Laser diode efficiency
a The external quantum efficiency ηEQE, of a laser diode is defined as
ηEQE =Number of output photons from the diode per unit second( )Number of injected electrons into diode per unit second( )
∴ ηEQE =Optical Power / hυDiode Current / e
=Po /Eg
I / e=
ePo
IEg
The external differential quantum efficiency, ηEDQE, of a laser diode is defined as
ηEDQE =Increase in number of output photons from diode per unit second( )
Number of injected electrons into diode per unit second( )
∴ ηEDQE =(Change in Optical Power) / hυ
(Change Diode Current) / e=
∆Po /Eg
∆I / e=
e
Eg
dPo
dI
The external power efficiency, ηEPE, of the laser diode is defined by
ηEPE =Optical ouput power
Electical input power=
Po
IV=
Po
IV
eEg
eEg
=ePo
IEg
Eg
eV
∴ ηEPE =ePo
IEg
Eg
eV
= ηEQE
Eg
eV
b 670 nm laser diode
Eg ≈ hc/λ = (6.626×10-34)(3×108)/[(670×10-9)(1.6×10-19)] = 1.85 eV,
so that ηEQE =(1.6×10−19 C)(2×10−3 Js−1)
(80 ×10−3 A)(1.85 eV×1.6×10−19 eV/J)= 0.0135 or 1.35%
ηEDQE =e
Eg
dPo
dI
=
(1.6×10−19 C)
(1.85 eV×1.6×10−19 C)
3×10−3 − 2×10−3 Js−1
82×10−3 − 80 ×10−3 A
= 0.27 or 27%.
ηEPE =Po
IV=
2 ×10−3W
(80×10−3A )(2.3 V)= 0.011 or 1.1%
c 1310 nm laser diode
Eg ≈ hc/λ = (6.626×10-34)(3×108)/[(1310×10-9)(1.6×10-19)] = 0.9464 eV,
so that ηEQE =(1.6× 10−19 C)(3×10−3 Js−1)
(40×10−3 A)(0.9464 eV×1.6×10−19 J/eV)= 0.079 or 7.9%
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
∴ ηEDQE =e
Eg
dPo
dI
=
(1.6×10−19 C)
(0.9464 eV×1.6×10−19 C)
4 ×10−3 − 3×10−3 Js−1
45×10−3 − 40 ×10−3 A
= 0.21 or 21%.
and ηEPE =Po
IV=
3×10−3W
(40 ×10−3A )(1.4 V)= 0.054 or 5.4%
4.15 The SQW laser
The lowest energy levels with respect to the CB edge Ec in InGaAs are determined by the energy of an electron in a one-dimensional potential energy well
εn =h2n2
8me*d2
where n is a quantum number 1, 2, …, εn is the electron energy with respect to Ec in InGaAs, or εn = En − Ec.
Using d = 10×10-9 m, me* = 0.04me and n = 1 and 2, we find the following electron energy levels
n =1 ε1=εn =h2n2
8me* d2 =
(6.626×10−34 )2(1)2
8(0.04× 9.11×10−31)(10 ×10−9)2 = 1.51×10-20 J = 0.094 eV
n = 2 ε2 = 0.376 eV
Using d = 10×10-9 m, mh* = 0.44me and n = 1, the hole energy levels below Ev is
n =1 ′ ε n =h2n2
8mh* d2 =
(6.626×10−34 )2(1)2
8(0.44× 9.11×10−31)(10 ×10−9)2 = 1.37×10-21 J = 0.00855 eV
The wavelength light emission from the QW laser with Eg = 0.70 eV is
λQW =hc
Eg + ε1 + ′ ε 1=
(6.626×10−34)(3×108)
(0.70+ 0.094+ 0.00855)(1.602×10−19)= 1545××××10 -9 m (1545 nm)
The wavelength of emission from bulk InGaAs with Eg = 0.70 eV is
λg =hc
Eg
=(6.626×10−34 )(3×108)
(0.70)(1.602×10−19) = 1771××××10 -9 m (1771 nm)
The difference is λg − λQW = 1771 - 1545 = 226 nm.
4.16 A GaAs quantum well
The lowest energy levels with respect to the CB edge Ec in GaAs are determined by the energy of an electron in a one-dimensional potential energy well
εn =h2n2
8me*d2
where n is a quantum number 1, 2, …, εn is the electron energy with respect to Ec in GaAs, or εn = En − Ec. Thus,
n =1 ε1=εn =h2n2
8me* d2 =
(6.626×10−34 )2(1)2
8(0.07×9.11×10−31)(8×10−9)2 = 0.0839 eV
n = 2 ε2 = 0336 eV
n = 3 ε3 = 0.755 eV
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
Note: Whether ε3 is allowed depends on the depth of the QW and hence on the bandgap of the sandwiching semiconductor.
The hole energy levels below Ev is
′ ε n =h2n2
8mh* d2 =
(6.626×10−34)2(1)2
8(0.47× 9.11×10−31)(8×10−9)2 = 0.0125 eV
The wavelength of emission from bulk GaAs with Eg = 1.42 eV is
λg =hc
Eg
=(6.626×10−34 )(3×108)
(1.42)(1.602×10−19) = 874×10 -9 m or 874 nm.
Whereas from the GaAs QW, the wavelength is,
λQW =hc
Eg + ε1 + ′ ε 1=
(6.626×10−34)(3×108)
(1.42+ 0.0839+ 0.0125)(1.602×10−19)
= 818×10 -9 m or 818 nm.
The difference is λg − λQW = 874 − 818 =56 nm. 5.1 Bandgap and photodetection
a Given, λ = 600 nm, we need Eph = hυ = Eg so that,
Eg = hc/λ = (6.626×10-34 J s)(3×108 m s-1)/(600×10-9 m)
= 2.07 eV
b A = 5×10-2 cm2 and Ilight = 20×10-3 W/cm2. The received power is
P = AIlight = (5×10-2 cm2)(20×10-3 W/cm2) = 10-3 W
Nph = number of photons arriving per second = P/Eph
= (10-3 W)/(2.07×1.60218 ×10-19 J/eV)
= 2.9787×1015 Photons s-1.
= 2.9787×1015 EHP s-1.
c For GaAs, Eg = 1.42 eV and the corresponding wavelength is
λ = hc/ Eg = (6.626×10-34 J s)(3×108 m s-1)/(1.42 eV × 1.6 ×10-19 J/eV)= 873 nm
The wavelength of emitted radiation due to EHP recombination is therefore 873 nm.
It is not in the visible region (it is in the IR).
d For Si, Eg = 1.1 eV and the corresponding cut-off wavelength is,
λg = hc/ Eg = (6.626×10-34 J s)(3×108 m s-1)/(1.1 eV × 1.6 ×10-19 J/eV)= 1120 nm
Since the 873 nm wavelength is shorter than the cut-off wavelength of 1120 nm, the Si photodetector can detect the 873 nm radiation (Put differently, the photon energy corresponding to 873 nm, 1.42 eV, is larger than the Eg, 1.1 eV, of Si which mean that the Si photodetector can indeed detect the 873 nm radiation)
5.2 Absorption coefficient
a If Io is the intensity of incoming radiation (energy flowing per unit area per second), Ioexp(−αd) is the transmitted intensity through the specimen with thickness d (Figure 5.17) and thus Io[1− exp(−αd)] is the “absorbed” intensity. If Γph is the number of photons arriving per unit area per unit second (the
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
photon flux), then Γph = Io/hυ where hυ is the energy per photon. Thus the number of photons absorbed per unit volume per unit second of sample is
n ph =
AΓph
Ad=
Io 1− exp(−αd)[ ]hυd
=Io 1− exp(−αd)[ ]
dhυ
b For Ge, α ≈ 5.2 × 105 m-1 at 1.5 µm incident radiation (from figure 5.3).
∴ 1− exp(−αd) = 0.9
∴ d =1
αln
1
1− 0.9
=
1
5.2×105 ln1
1− 0.9
= 4.428×10−6 m = 4.428 µm.
For In0.53Ga0.47As, α ≈ 7.5 × 105 m-1 at 1.5 µm incident radiation (Figure 5.3).
d =1
7.5×105 ln1
1− 0.9
= 3.07×10−6m = 3.07 µm.
c The quantum efficiency is unity. Therefore the collected electrons per unit area per unit second is equal to the absorbed photons per unit area per unit second. So, the current density (current per unit area),
[ ] [ ]
hc
de
h
deJ ph
)exp(1)exp(1 αλυ
α −−=
−−= oo II
Given, Io = 100 µW mm-2 = 100 × 10-6 × 106 W m-2 = 100 W m-2,
81.108100.310626.6
9.0105.11001060218.1834
619
=×××
×××××= −
−−
phJ A m-2 =10.881 mA/cm2.
NOTE: We neglected any light reflection from the surface of the semiconductor crystal (100% efficient AR coating assumed).
5.3 Ge Photodiode
a At λ = 850×10-9 m, from the responsivity vs. wavelength curve we have R = 0.25 A/W. From the definitions of quantum efficiency (QE) η and responsivity we have,
%36.5)m10850()C1060218.1(
)A/W25.0()ms103(Js)10626.6(919
1834
=×××
××××== −−
−−
λη
e
hcR
Similarly, we can calculate quantum efficiency at other wavelengths. The results are summarized in the following table.
Wavelength, (nm) 850 1300 1550
Responsivity R, (A/W) 0.25 0.57 0.73
Quantum efficiency η, (%) 36.5 54.3 58.4
b Given, photocurrent Iph = Id = 0.3 µA = 0.3×10-6 A and area, A = 8×10-9 m2, the incident optical power,
Po = Iph/R = (0.3×10-6 A)/(0.73 A W-1) = 4.1096 × 10-7 W
Light intensity, Io = P0/A = (4.1096 ×10-7 W)/(8×10-9 m2) = 51.4 W m-2 or 5.14 mW cm-2.
c From semiconductor data under Selected Semiconductors, for most semiconductors dEg/dT is negative, Eg increases with decreasing temperature. Stated differently, α vs λ curve shifts towards shorter λ with decreasing T. The change in α with T means that the amount of optical power absorbed in the depletion region and hence the quantum efficiency will change with temperature. The peak
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
responsivity will shift to lower wavelengths with decreasing temperature. If maximum photogeneration requires a certain absorption depth and hence a certain αmax, then the same αmax will occur at a lower wavelength at lower temperatures. In Figure 5Q3, maximum responsivity corresponds to αmax which occurs at λmax at high T and at λ′max at lower T.
Figure 5Q3.
λ
Absortion coefficient = 1/δ
Low THigh T
λmaxλ′max
αmax
The absorption coeff icient depends on the temperature
d Dark current (∝ exp(−Eg/kT)) will be drastically reduced if we decrease the temperature. Reduction of dark current improves SNR.
e The RC time constant = 100 × (4×10-12) = 0.4 ns. The RC time constant is comparable to the rise time, 0.5 ns. Therefore, the speed of response depends on both the rise time and RC time constant. (It is not simply 0.4 ns + 0.5 ns.)
5.4 Si pin Photodiodes
a For type A, responsivity RA = 0.2 A/W at 450 nm wavelength light.
Given, intensity Io = 1 µW cm-2 = 10-8 W mm-2 and area A = 0.125 mm2.
Power, P0 = IoA = (10-8 W mm-2)× (12.5 mm2) = 1.25 × 10-7 W.
Photocurrent, Iph = RAP0 = (0.2 A/W)× (1.25 × 10-7 W) = 2.5 × 10-8 A = 25 nA.
Quantum efficiency, %1.55)m10450()C1060218.1(
)A/W2.0()ms103(Js)10626.6(919
1834
=×××
××××== −−
−−
λη
e
hcA
AR
For type B, responsivity RB = 0.12 A/W at 450 nm wavelength light.
Photocurrent, Iph = RBP0 = (0.12 A/W)× (1.25 × 10-9 W) = 1.5 × 10-10 A = 0.15 nA.
Quantum efficiency, %1.33)m10450()C1060218.1(
)A/W12.0()ms103(Js)10626.6(919
1834
=×××××××== −−
−−
λη
e
hcB
BR
b, c Photocurrent and quantum efficiency can be calculated for other wavelengths in the same way. The values are summarized in the following table.
Table 5Q4 Summarized values for photocurrent and quantum efficiency.
Wavelength, nm Type A Type B
Responsivity, A/W
Photocurrent, nA
Quantum efficiency, %
Responsivity, A/W
Photocurrent, nA
Quantum efficiency, %
450 0.20 25 55.1 0.12 15 33.1
700 0.46 57 81.5 0.46 57 81.5
1000 0.15 19 18.6 0.40 50 50
d Quantum efficiency depends on the wavelength and also on the device structure. Both devices use a Si crystal , but, at a given wavelength such as 450 nm, for A, QE = 55.1% and for B, QE = 33.1%.
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
ηmaximum =
hcReλ
=(6.62×10−34 J s)(3×108 m s-1)(0.78 A W-1)
(1.6×10−19 C)(1210×10−9 m) ≈ 0.80
5.6 Maximum QE
The relationship between the responsivity R and the quantum efficiency (QE) η is,
R =
ηeλhc
or η =
hc
e
Rλ
The QE is maximum when dη/dλ = 0, thus differentiating the above expression with respect to λ we have,
dηdλ
=hc
eλdRdλ
+hcR
e
d
dλ1
λ
= 0
hc
eλdRdλ
−hcR
e
1
λ2
= 0 ∴
dRdλ
−Rλ
= 0 i.e.
dRdλ
=Rλ
0
0.2
0.4
0.6
0.8
1
800 1000 1200 1400 1600 1800Wavelength(nm)
The responsivity of anInGaAspin photodiode
Responsivity(A/W)
60040020000
0
0.10.20.3
0.40.5
0.60.70.8
0.5 1 1.5 2Wavelength(µm)
The responsivity of a commercial Gepnjunction photodiode
Responsivity(A/W)Tangent through origin
00
0.1
0.2
0.3
0.4
0.5
0.6
200 400 600 800 1000 1200Wavelength(nm)
A B
The responsivity of two commercial Sipin photodiodes
Responsivity(A/W)
0
Figure 5Q6
We can find the maximum QE by drawing a tangent to the R vs. λ curve that passes through the origin as in the three examples below. The actual graphical values are listed in Table 5Q6. For example for the InGaAs pin photodiode, the maximum QE is
ηmaximum =
hcReλ
=(6.62×10−34 J s)(3×108 m s-1)(0.78 A W-1)
(1.6×10−19 C)(1210×10−9 m) ≈ 0.80
Table 5Q6
InGaAs pin Si-pin-A Si-pin-B Ge photodiode
λ (nm) 1210 700 810 1500
R (A/W) 0.78 0.46 0.57 0.71
Maximum QE 0.80 0.81 0.87 0.57
Maximum QE % 80% 81% 87% 57%
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
5.12 The APD and excess avalanche noise
a We can find the value of x by plotting F vs. M on a log-log plot, which is shown in Figure 5Q12. From the plot, the index x = 0.857. The fit shows that, F = 1.095M.8571 which agrees well with the equation, F ≈ Mx.
1
10
1 10
Exc
ess
nois
e fa
ctor
Multiplication
F = (1.095)M0.857
Excess noise factor F vs. Mfor a GE APD; from Scansen andKasap 1992.
Figure 5Q12
b Given, Ido = 0.5 µA, M = 6, B=500 MHz and x = 0.857. From Equation (12) §5.10, the SNR can be written as,
SNR=Signal PowerNoise Power
=M2I pho
2e Ido + I pho( )M2 +x B[ ]
∴ M2Ipho
2 − 2eM2 + xB SNR( )[ ]Ipho − 2eM2+ x B SNR( )Ido[ ]= 0 (2)
Solving this quadratic Equation (2) with a SNR = 1 for Ipho we find,
Ipho = 1.9665×10-8 A or 19.665 nA
If Po is the incident optical power, then by the definition of responsivity, R = Ipho/Po,
Po = Ipho/R = (1.9665×10-8 A)/(0.8 A/W) = 2.458×10-8 W or 24.58 nW.
c Solving this quadratic Equation (2) with a SNR = 10 for Ipho we find,
Ipho = 6.4832×10-8 A or 64.665 nA
The incident optical power,
Po = Ipho/R = (6.4832×10-8 A)/(0.8 A/W) = 8.104×10-8 W or 81.04 nW.
Note: Although the SNR has gone up by a factor of 10, the required increase in the incident optical power is only a factor of 3.3.
6.3 Solar cell driving a load
a The solar cell is used under an illumination of 1 kW m-2. The short circuit current has to be scale up by 1000/600 = 1.67. Figure 6Q3-2 shows the solar cell characteristics scaled by a factor 1.67 along the current axis. The load line for R = 20 Ω and its intersection with the solar cell I−V characteristics at P which is the operating point P. Thus,
I′ ≈ 22.5 mA and V′ ≈ 0.45 V
The power delivered to the load is
Pout = Ι′V′ = (22.5×10-3)(0.45V) = 0.0101W, or 10.1 mW.
This is not the maximum power available from the solar cell. The input sun-light power is
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
Pin = (Light Intensity)(Surface Area) = (1000 W m-2)(4 cm2 × 10-4 m2/cm2) = 0.4 W
The efficiency is
η = 100Pout
Pin
= 1000.010
0.4= 2.50
0 which is poor.
b Point M on Figure 6Q3-2 is probably close to the maximum efficiency point, I′ ≈ 23.5 mA and V′ ≈ 0.44 V. The load should be R = 18.7 Ω, close to the 20 Ω load. At 600 W m-2 illumination, the load has to be about 30 Ω as in Figure 6.8 (b). Thus, the maximum efficiency requires the load R to be decreased as the light intensity is increased. The fill factor is
FF =ImVm
IscVoc
=(23.5 mA)(0.44 V)
(27 mA)(0.50 V)≈ 0.78
c The solar cell is used under an illumination of 400 W m-2. The short circuit current has to be scale up by 400/600 = 0.67. Figure 6Q3-2 shows the solar cell characteristics scaled by a factor 0.67 along the current axis. Suppose we have N identical cells in series, and the voltage across the calculator is Vcalculator. The current taken by the calculator is 3 mA in the voltage range 3 to 4 V and the calculator stops working when Vcalculator < 3 V. The cells are in series so each has the same current and equal to 3 mA, marked as I′ in Figure 6Q-2. The voltage across one cell will be V′ = Vcalculator/N. which is marked in Figure 6Q3-2. V′ = 0.46 V. Minimum number of solar cells in series = N = 3 / 0.46 = 6.5 or 7 cells , since you must choose the nearest higher integer.
If we want the calculator continue to work under low intensity levels, then we can connect more cells in series until we reach about 4 V; N = 4 V / 0.46 V = 8.7 or 9 cells in series.
The easiest estimate for the minimum required light intensity is the following: The calculator will stop working when the light intensity cannot provide energy for the solar cell to deliver the 3 mA calculator current. The short circuit current at 400 W m-2 is 11 mA in Figure 6Q3-2. Thus
Minimum light intensity=3 mA
11 mA400 W m−2=109 W m-2
V′V
I (mA)
0.60.4
?0
0
?0
The load line for R = 20 (I-V for the load)
I-V for a solar cell under anillumination of 1000 Wm-2.
P
0.2
I′
?0
M
V′V
I (mA)
0.60.4
?0
0
?0
I−V for a solar cell under anillumination of 400 W m-2.
P
0.2
I′ 3 mA
Figure 6Q3-1 Figure 6Q3-2
6.4 Open circuit voltage
The short circuit current is the photocurrent so that at
Isc2 = Isc1
I2I1
= 50 mA( ) 50 W m−2
100 W m−2
= 25 mA
Assuming n = 1, the new open circuit voltage is
Voc2 = Voc1 +
nkBT
eln
I2I1
= 0.55+1 0.0259( )ln 0.5( )= 0.508 V
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
Assuming n = 2, the new open circuit voltage is
Voc2 = Voc1 +
nkBT
eln
I2I1
= 0.55+ 2 0.0259( )ln 0.5( )= 0.467 V
6.5 Shunt resistance .
a Figure 6Q5-1 shows the equivalent circuit with the series resistance removed. The currents flowing into node A sum to zero (Kirchoff’s current law). Currents into a node are positive and those leaving a node are negative. Thus,
−I + Iph − Id − (V/Rp) = 0
∴ I = − I ph + Id +V
Rp
= − I ph + Io exp(eV
nkBT) −1
+
V
Rp
which is the required equation.
A′
Iph Rp RLV
IIph
Id
Solar cell Load
B
A
Figure 6Q5-1
b Plots of I vs. V for different values of Rp are shown in Figure 6Q5-2.
Rp =
Rp = 1000 Ω
Rp = 100 Ω
Voltage (V)
Current (mA)
Figure 6Q5-2
Conclusion: Lower Rp decreases the OC voltage and reduces the available output power.
6.6 Series connected solar cells
Consider two cells in series. Then there are two Rs in series and two pn junctions in series. If I is the total current through the devices then the voltage across one pn junction is
Vd =V − I(2Rs )
2
Thus, I = − Iph + Io expVd
nVT
−1
= − Iph + Io exp
V − I(2Rs )
2nVT
−1
∴ I ≈ − Iph + Io expV − I(2Rs )
2nVT
since Vd > nVT
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
Rearranging we find the following:
2 Cells in series:
V = 2nVT lnI + Iph
Io
+ 2Rs I
1 Cell: V = nVT lnI + Iph
Io
+ Rs I
Figure 6Q6-1 shows the I-V characteristics for 1 cell and 2 cells in series. Notice that the OC voltage for the series cells is twice the OC voltage for one cell.
1 cell
Iph = 10 mA
2 cells in series
Current in mA
Voltage
Figure 6Q6-1
Since Power = IV we can plot the power delivered as a function of current as shown in Figure 6Q6-2. Maximum power corresponds to
1 cell: I ≈ 7.7 mA, V ≈ 0.3 V, P ≈ 2.3 W
2 cell: I ≈ 7.7 mA, V ≈ 0.58 V, P ≈ 4.5 W
Power in mW
Current in mA
2 cells in series
1 cell
4.5 mW
2.3 mW
-7.7 mA
Figure 6Q6-2
6.7 Series connected solar cells
A
Iph1
V
Id1
Rs2
RL
I
Two different solar cells in series
Iph2
Id2
Rs1
Iph2
Iph2
V1
V2
I
Figure 6Q7-1
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
The equivalent circuit is shown in Figure 6Q7-1. The current through both the devices has to be the same. Thus, for cell 1
I = − Iph1 + Io1 expVd1
n1VT
−1
= −Iph1 + Io1 exp
V1 − IRs1
n1VT
−1
∴ V1 − IRs1
n1VT
= lnI + Iph1
Io1
−1
∴ V1 = n1VT lnI + I ph1
Io1
−1
+ IRs1
For cell 2 I = − Iph1 + Io2 expVd 2
n2VT
−1
= −Iph 2 + Io2 exp
V2 − IRs2
n2VT
−1
∴ V2 = n2VT lnI + I ph 2
Io2
+1
+ IRs2
But V = V1 + V2
∴ V = n1VT lnI + Iph1
Io1
+1
+ IRs1 + n2VT ln
I + I ph2
Io2
+ 1
+ IRs 2
We can now substitute Io1 = 25×10-6 mA, n1 = 1.5, Rs1 = 10 Ω, Io2 = 1×10-7 mA, n2 = 1, Rs2 = 50 Ω and then plot V vs. I (rather I vs. V since we can calculate V from I) for each cell and the two cells in series as in Figure 6Q7-2. Notice that the short circuit is determined by the smallest Isc cell. The total open circuit voltage is the sum of the two.
Cell 1
Voltage
Current(mA)
Cell 2
Cell 1 in series with 2
Figure 6Q7-2
6.11 Maximum Power and Fill Factor
The current through a solar cell is I = − I ph + Io expV
nVT
so that the power is P = IV = − I phV + IoV expV
nVT
At maximum power dP/dV = 0 when V = Vm
dP
dV= − Iph + Io exp
V
nVT
+ Io
V
nVT
expV
nVT
∴ dP
dV= − Iph + Io exp
Vm
nVT
1+
Vm
nVT
= 0
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
∴ 1+Vm
nVT
exp
Vm
nVT
=
Iph
Io
and since Vm >> nVT,
∴ Vm
nVT
exp(Vm
nVT
) ≈Iph
Io
(1)
Consider the current at maximum power,
Im = − Iph + Io expVm
nVT
Substitute for the exponential term,
Im = − Iph + Io
nVT Iph
VmIo
∴ Im = − Iph 1−nVT
Vm
(2)
The product ImVm is the maximum power from which we can calculate the FF.
NOTE: We can obtain better expressions for the maximum power voltage Vm as follows:
We have to find Vm by solving,
f (Vm) =Vm
nVT
exp(Vm
nVT
) −Iph
Io
= 0 (3)
Let vm = Vm/(nVT), a = Iph/Io and voc = Voc/(nVT). From Example 6.3.2 we know that
voc =Voc
nVT
= lnI ph
Io
= ln a
Thus, Eq. (3) that we have to solve is f (vm ) = vm exp(vm) − a = 0 (4)
We can use Newton’s approximation. If xo is an approximate solution, then a better solution is
x1 = xo −f (xo )df
dx
xo
Let x =V/(nVT), Since a = Iph/Io which is something like (10 mA cm-2)/(10 nA cm-2) = 106, we take xo, the rough solution, to be such that Eq. (4) becomes
f(xo) ≈ vocexp(xo) − a = 0
so that xo = lna
voc
= voc − lnvoc
A better solution is when
x1 = xo −xoe
x o − a
(xo +1)exo=
xo(xo +1)ex o − xoex o + a
(xo + 1)ex o
∴ x1 =xo
2ex o + a
(xo +1)ex o
Substituting xo = voc − ln(voc) and a = exp(voc),
Solutions for Optoelectronics and Photonics: Principles and Practices Chapter 4/5/6
x1 =(voc − ln vm )2evoc −ln v m + evoc
(voc − lnvoc +1)ev oc − lnv oc
Thus, vm =(voc − ln vm )2evoc −ln vm + evoc
(voc − lnvoc +1)evoc − lnv oc (5)
As an example, let us apply this to Example 6.3.1 where Voc ≈ 0.480 V, taking n =1, voc = 18.46, vm = 15.72 and Vm = 0.41 V.
The fill factor FF is FF =ImVm
IscVoc
≈− Iph 1−
nVT
Vm
Vm
− IphVoc
=1−
1
vm
vm
voc
(6)
Questions 6.9 gives FF as FF ≈voc − ln(voc + 0.72)
voc + 2 (7)
Using Example 6.3.1 where Voc ≈ 0.480 V, voc = 18.46, vm = 15.72 leads to
FF = 0.80 from Eq. (6) whereas FF = 0.76 from Eq. (7).
6.12 Energy band diagram
a
Ec
Ev
Ec
EFp
M
EFn
eVo
p nE
o
Evnp
No illumination
VI
np
Eo–E
e(Vo–V)
eV
Ec
EFn
Ev
Ev
Ec
EFp
SCL
Illumination
Figure 6Q12-1
b
Ev
Ec
Ev
Ec
(i) (ii) Figure 6Q12-2
Possible energy band diagrams for a semiconductor that has a decreasing bandgap are shown in Figure 6Q11-2 (i) and (ii). The photogenerated electron "rolls” down Ec. The hole also "rolls" down its own energy hill either towards the right, (i), or left, (ii), depending on how Ec and Ev vary along the device. Obviously in Figure 6Q12-2(ii) there is a photogenerated current and a voltage across the device. It is possible, in principle, to fabricate a device that has the right bandgap variation and the right doping variation to give the energy band diagram in Figure 6Q12-2(ii) and hence function as a solar cell.