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Industrial Water
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* Modern high-pressure boilers must be supplied
with feed water of high purity.
* As the water evaporates the concentration of
impurities in the liquid phase rise, dissolved and
entrained impurities accumulate, heat transferdeteriorates and boiler tubes are overheated, porous
sludges, crystalline scales, and other coatings appear
on the boiler metal.* Rising concentrations of specific soluble impurities
cause metal corrosion.
Boiler Feed-Waters
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•
The most important boiler precipitates consist of silica iron,
suspended matter, and oil in addition to calcium and
magnesium as bicarbonates and sulfates. The principalfactors in corrosion are DO, CO2,
• low pH, and deficient alkalinity, can promote corrosion.
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Boiler waters are kept to specification by one or more of the following techniques:
(1) External treatment for the removal of impuritiesfrom the raw water
(2) Internal treatment for the conditioning of water within the boiler
(3) Blowdown for the removal of concentrates andsludges
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Cooling Water
• Water is the common coolant of the process industries
• Water has a high heat capacity, is almost universallyavailable, and is easy to transport and apply.
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• Especially in re-circulating systems must cooling water
be treated to inhibit corrosion/ scales formation,
sediment deposition, and microbial growths.
The most important water properties affecting corrosion
are oxygen and other dissolved gases, dissolved or
suspended solids, pH, velocity, temperature, andmicrobic growths.
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Irrigation water
Irrigation waters should not contain more than the limit the
following substances:
Sodium-5 mg/l
Boron — 0.5 mg/1Chlorides-5.3 mg/1
Sulphates — 10 mg/1
Total salts —
700 mg/l Specific conductivity — 1000 micro-mhos.
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Excessive salinity at root-zone level leads in
succession to leaf burn, leaf drop, twig dieback, and
plant destruction. Salinity effects are largely osmotic.
High sodium exchange breaks down soil structures,
seals pores, and interferes with drainage, in extreme
cases of soil breakdown the pH of the soil may rise tothe level of alkali soils. Although traces of boron are
essential for plant growth, high concentrations are
injurious. Chlorides are generally more injurious than
sulfates, because chlorides are relatively more solubleand more toxic to some plants and because sulfates
are precipitated as calcium sulfate.
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A free chlorine residual of at least 0.4 ppm must be
maintained throughout the pool. The alkalinity of thewater shall beat least 50 ppm, and a pH greater than
7.2 but less than 8.2 shall be maintained. Pool waters
should be highly transparent so as to keep divers
from colliding with bathers swimming under water.
To avoid rapid multiplication of saprophytic
bacteria, pool temperatures should not be raised
above 78 °F.
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Softening
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Ion Exchange
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