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Page 1: Iit1I - Oita University

Iit1I

1噸

⑪ロ0

。。〃..|’

6口。。D

⑤qの0-

...・・イ0

16.、。

0.

h.’。・

ワ4●

0q◇、。‐

11

仔)3al VOL.!(1957/58) WEAR

〆へ、

T一坪

FRICTIONANDABRASIONOFRUBBER

A,SCHALLAMACH

TⅡβBriljsハRlJbbBrPron1にers,RBseqrcハAssocm/ioFI`Ireノu,)ノリIQur(ノpIICi/γ(GrFnlBrWjDリ

SmVMARY

●●●●●●●●●●●●●●

Expe「imentaIevidenceisadducedfortheviewthatTubberfrictioni日simiIarincharactcrtovis‐couslIowandthcrc(oreoincontras上tosolidfTictionOnotnecessarilyaccompanic(lbyabrasion・ThistheoryimpIiesthatthefoTcesofTubberfrictionarepToportionaltothetrKUcarcaofcontact・ThetrueaTeaofcontactisdete「mine〔lbyelasticdeformatiouuofthcasperiticsonthcrubbersⅡrfaceowiththeTesultthatAmontonsolawisnotobeyedbyrubber・Thelaw乳ofTubberfricti⑪IMlrc《】e(luccdfTomsimplemodelsandsatisfactoTilyconfirmedbyexpenment.

Ab「aSi6noIrubberiSduetomechanicalfailureundefthetractivestrcSscsproducc(lfrictionally bytheasPeritiesofthetrack、Inthisprocess、certainpeTiodicstructurcsaLrcortcncrcatcdonabraded rubberwhichhavebeencalledooAbTasionPatterns'0.AbrasionpattcruuHaTclouundtoincreasethc rateofabrasiom;adistinctionisthereloremadebetweenopIntrinsicAbrasioIBp,,OCCRuTringimthc absenceofpattemsⅡand,`PattemAbrasion,,、BothtypesofabrasioIuaTctroatc〔ltlhcorcticaIly,andqualitativeagTeementwiththeexperimentalresuItsisobtaincd・ThephenomenonofpatternabTasionhastheimportan上conscquencctlMuttllcrCIativcab「asi⑥n

Tatingofanytwocompoqmdscandependpronouncedlyonthccon〔litiolMmItIuetcst.

ZUSHMMEjVFASSmVC

ExperimenteⅡeGriindewerdenda【iirangefijhTtOdassGummircibM、galsdcnwiskcscnFIicsscuuwcsensiihnlichanzusehenistmnddeswege、OimCegensatzzurfestcnRcibung・nichtnotwendiger-weisemitAbriebvcrbumdenistNachdi⑥serTheoriesin(ldieReiblIngslGTiMtedcsCummisdcAvalBrcn BcriibTungsf1iicheproPoTtioTlal・DiewahreBcriihrtungslliichci5t(lⅡrchoPIastiscI1cDcfornMLtion〔lcrUnebenheitenaufderGummiobeTIlacIlebestimmtpmitdcmErgcbniH.(kus筒GlommiAmoH1tons,GesetznichtfoIgt、DieGesetzederGummireibungwe「denaus⑥iIuIachcJuModeⅡenabgcIeitctundexperimentellzufriedeTlstellendbestiitigt, AbriebentstehtdurChmechaniScllesVersagendesGummisuIuterdenvondenUncbenllcitcn

derSpurdurchReibunghewor摩rufenenZugspannungen・I、【lies⑥mVorgangcntstellcnhiiMiggewiSseperiodischeStTukturen,。i⑥Riffelformationen(abrasionpattcTnS)gcnanntwcrdenEswurdegefundenpdassRiffClfOrmationendieAbTiebs-GeschwindigkcitcrhIihen;eswiTd(IC昌wegenHmterschiedenzwiscben,OeigentlichemAbrieb'oOderauftTitt・wcnnkcincRiffclnentstcllcul,u、〔10,RiffelabTiebo0,Theoretisch6BehandlungbeiderAbriebsartenfiihrtzuqlIalitativerUbereinstim-mungmitdenexperimentellenResultaten.

DieErscheinungderRiffelformationenhatdiewichtigeFolgeo〔lassdierelativcAbTiebszahIzweieTbeliebigenGummimischungenwesentlichvondenVe庵uchsbedingungenabhtingeTlkann.

1.INTRODUCTION

ModernworknonthemechanismofslidingfrictionandfrictionalweaTofsolidshas

broughttolighttheimportantroleplayedintheseproccsscsbythemicrotopography oftherubbingsurfaceswhoseroughnessmakesthetruearcaofcontactsmallandpro‐ duceshighpressureswheretheasperitiesmeet、Undertheinflucnceoftheselocalstresscs, irreversiblejunctionsareformedbetweentherubbingmcmbers,andtIlefrictional workdoneinslidingistheenergynecessaTytobreakthcsejunctions、Tllus,friction

Reにrβ〃CBSかイエ7

Page 2: Iit1I - Oita University

385 FRICTIONANDAlM《ASIONOFI(UBBIZI《VOL、1(1957/56)

olsolidsisaconcomitantolabTasion,alM1tllcf「ictio】1allorceisproportionaltotllctrucarUiLofco1Utact・

IJ1contrast,rubbcTlrictionisnotncccssarilvaccompallicdbyabrasion・RoTll,DRIscoLLAN1)HoLT2wcrctlUcfirsttoslM)wtIlatevc1laltcTp「olongcdslidingonI〕Iatc

glassrubbcrsamplcssullernoabrasivcw(`iIr.,I1lcrcisnocvidenceforrubbcTforming irrc《,c「siblcjunctionswitbtrackmatcri;l脂11111c開svcrylliglltemperaturesarcsustaincdduringsliding`andtheoriginofrubbcrlricIioInmlIstl〕csoughtinasourccotherthanthatoISOlidlrictionAsuggestionastoi吟IDrigiIlwiⅡbcmadeinthefollowingsection、

Inspiteoftllisdiflerencebetweenrubbl9rilndsolidlriction,thelineofattackwhich hasprovedsosuccessfulintbetheoryo⑬11i(llrictioncanwithadvantagebebrought tobearonrubbeTfriction・Attentionmu馬LIU【)wcverDbcpaidtothefactthatrubber

鰯erallycxpcricncesfrictionandwearllnlhrcoluditionsdifferentfromthosecomm・nlI1substanccssucl1asmctalsandfibrcs.]《ⅡI〕berhardlyい'erslidesonotherTubber‐

likematerialsbutontTacksgrosslydissinlil8Lrll・omiti】】surfacctexture,chcmicalcon‐stitutionandclasticbcbaviouT,roadsurflcKoHl)(〕ingthcmostobviousandimpoTtant

examples、Itwillbcshowninthesubsc(111《、lltlmgesthattheconceptoflocalstTessconcentrationsjntheareaofcontactbclwtocl1TuI)bcrandtrackgoesalongwayin

accountingfortheobservcdeffects.

11㎡側11畷一口、‐ノ師団、-ノ■巴印11ノ区巴■、1ノーⅢE甲、‐ノさ区『、Iノニ藤Iノ団匹■、-ノ四匹印~ノ四匹■’1ノ必■■1ノ欧底四I”■皿■1/■阯

’-,40.Ⅱ凸■9

FREQUENTLY1J5I2l)SYMBOLS

TruearどiloIC⑪】ltact

LineardimCmsionofabrasivegTain

E1asticmo〔llllusdcfinedbyeqn.(エo)FTictional[orcc

Normalloa(I

NominaIIMDrIMll〕rcssurc

Radiusol(、111.vnturco(asperities

Spacingo「;,l)rilHionl〕atlcrns

TemperatumI、C

Temperatur0・`'K

Slidingvclocily

Abrasionp(Prunitarea Coefficie21to【Iriction

Forcefaclor(l(1Iinedbyeqn.(6)

1卸j〃EFLA〃JrQ)ITUⅡβmr

U】・VELOClTYANDTEMPERATUl(EDl2lnENDI2NCEOFRUBBE】RFRICTION

DynamicrubberfTictionhasasmallbut〔lclilIitcpositivevelocitycoefficientatlowspeedsIfiTstdemonstratedbyRoTHclnノ.2.TlIisc(fecthastheinterestingconsequence tl1atrubbercanslideonahorizontaltrackatconstantvelocitywhenaconstant

tauUgentialforceisapplied・InthisstateofmotionthetangentialfoTceis,nfcourse,cqualtothcfrictionalforce・TllcvclocitycocfficientbeingsmaU,small diIferencesinthctangcntialforceproducc]argcdifferencesintheslidingvelocity、

AmcasuTiHugmcthodbascdonthiscIfu(B13iHtllercforcvervsensitive,Itisfound

ルル姥"“sノウ・イJ7

”j11j

‐。0ⅢⅢNun■P

Page 3: Iit1I - Oita University

90-レ

ートロー・『...1.19F..、 0。■巳兵

.几・牛。■‐

①D p●

_・of。 Ⅱ

OP

 ̄U

1l 3s6 VOL.】(1057/58)A・SCHAIIAMACH

expeTlmel1tally,however,thattheactualslidingbehaviollrofrubberiscoml〕licatcd

bytimeamddistanceeffectswhich,thouglltransient,canconsiderablyrctardattain-

mentofasteadystate、ThisisexemplifiedbyFig、エ.Thcgraphsgivethesliding

velocitiesofanacetone-extractedunfilledvulcanizatcofnaturalrubberonafinely groundg1asstrackattwodifferenttangentialfOrces,thelargerforcehavingbeen

appliedaftertheexpenmentwiththelowerfoTce、Itmaybementionedlleretllatin●

certainmeasurementsitisadvisabletoextractthesamplesinordertopreventcontam-◆

inationofthetTackbyimpuritiesoozingoutofthesamples,Thisprecautionisessen-

tialwhenexperimentsarecarriedoutatvariabletemperature,fortherateatwhich

thccontaminationoccursincreaseswithincreasingtemperature.

T●■

0.2

〈…官u)1

ll `1 :I

0.8

'01 05IOI5 DiStanceに、)

Fig.Ⅱ.Slidingvelocityofanacetone-extractedunfiUedvulcaniznteofnaturalrubberonlincly groundglassplottedagainstslidingdistance・Normalload,6.44kg,TangentiaIl⑥TCC:(in).5.Skg;(b),7.Skg・Cu、.e(c):curve(b)TepIottedaslog[u-o・ooo36)cm/SCC]・lFromrcL3.

11

Withapullingforceof5.8kg,theslidingvelocitydecreasesmpidlythroughoutthe experimentandthesampleeventuallystops・Despitetheinitialmotionproducedbyit,5.8kgisobviouslylowerthantheequilibriumfOrceofstaticfriction・Onmcreasingthetangentialforcet07.8kgthesamplestartsanew,slowsdownagainbut,incontrast tothepreviouscase,reachesafinitesteady-statevelocity・WhcntllcwlIuesofthissecondcurvearere-plottedaslog(u-usteadystate)tllestraightlinc(c)jsobtained、TheeffectsillustratedbyFig・エhavetheircounterpartinasloWriscoftllcfrictionalfoTcewhenthesampleismovedatconstantvelocityjaswassllownbyRoTIIpハノノ.2. Thephenomenonappearstobeduetosurfaceconditioningolthcsamplc;onabrasivc trackswherethesurfaceisconstantlyrenewedtheeffectisabsentorverysmalLFor thisreason,mostexperimentalresultshavebeenobtainedonabrasives.S】idingveloc-itiesgiveninthefoUowingtwographs(Figs、2and3)aTeallsteady-statevalues、況歌ycllEes力.乎工7

。?

、、

、 、

、 、追

(_、 、

( 、b 、

V、~-- 、ミ

K 、

Page 4: Iit1I - Oita University

’■。‐峪勺・廿・。Ⅲ卜-6-11Ⅲ?,?‐6肌‐・曲一u69jo印

387 v(Ll('057/58) F1《ICTION3MV1)MIIいSl()NOIF】《UBBIZl(

TllcnlostintCrcstingl〕TOI)crtyolslidingwlDcitiusisthcirl〕ronounccdtcmpcraturc

dCI〕cndcncc、Fig.2givesthelogarithmofthu莇lidilugvclocityonsiliconcarbidcpapcr

oftllcnaturalrubbercompoundTefcrrcdtoi】lIrig・rasfunctionofthereciprocalab‐

solutetcmpcrature,thetangemtialforcebeingIllul〕aramcter・Tllecurvescanbeap‐

proximatc〔Itostraightlinesandbedescribc(lI1yc(luation(1)

[,Cl,,Isl6lIItIor“=..!'cxl)(-ノゴ'ノノ17.)(【)

where.{’andE'arcconstants・

Theforccdcpendenceofthcslidingvelocityc8u】bcdcrivcdfromthecurvesofFig、Z

byinterpolation,thcresultbeingshowninFig._ルDefiningstaticfrictionasthatvalue

oIthctangentialforceatwhichthevelocityapI)roacheszero,afigureofabout5kgis

obtai、cdforslidingonsilicoLcarbidccloth・Atforcesaboveabout7kg,thecurves

arc縄lrlystraiglltlincsoindicatingthatancxponcntialrelationbctwcenslidingveloc‐ityandlrictionalforceobtainsatsufficicntlyhighdTaggingforces・

Eqn.(Ⅱ)isstronglyreminiscentoftherelationbetweenfluidityandtemperature

observedinviscousflowandalsoinotherphenomenagenerallyreferTedtoasrate

processes・Intheseprocesses,theelementaryparticle,orcomplexofparticlesinvolved

intl1cprocessarctlloughttobeconfinedtopotentialwellsofdepthE’fromwhich

fi、:、!!

い,.■O0p0p■□●Dq0C0B・■■▽己■■■9■●●90●■■□G1Ⅱ■ワ0.06‐⑪。。‐‐。

0ヶ.600派Ⅱい‐いIⅢ噸○M、?‐胡,川L』、叩1..口’□い●小口ひ0‐f11hrL河。、-,,ⅡⅢⅡⅢ‐ケーコ啼川ⅢⅢ化肝p“Ⅲ肌Mn川

-1

j8g05I◆●

一…:

(u、功一EuE-1)1m□一

(。U

いへ〔臣

Uこ』ユ

〉ユ四.

11

-3

-4

、46810

kg

10.iH.』、筒lc6MIy-statcsIidingvclociticsattwoIuIDu1DcrautuTegouusiliconcarbideclothplottcd ;lgHuinsttangentiaMorce・DataderivcdfromFig・色.FTomrCf、3.

IOy7(7,.K)

Fig.」.:tCady-己tmt⑪slidingvelocityoIannCc-tonc・cxtractcdllnfilledvul画nizateofnatural

rubbeTon$iliconcarbideclothplottedagainst reciprocaliubsolutetcmpemturcforvarioustan-gcntialIorCCS・Normalload,6.44kg・Fromref3.

Eどん"'IC“カィJ7

L〆

illll ℃

40 ソ /

Page 5: Iit1I - Oita University

■ご■11

●b

ら+p■。

●P+

■●●

シーザ■。巴

■F0■①■

①PP

▲9-0 脚(

。L■ロ0■旧■0■■■■0ⅡⅡ164

JSS VOL.’(Ⅱ957/58) A、3CllALLAMACll

tbcycancscapeonlywhentlleyattainthrouglutIUeTmalcollisionkincticcnergycqual to,orexcecdingE'・TherateoftllejumpsisproportionaltothcBoltzmannfactor

e~EYRT.lntheabsenceofextemalstress,thedirectionofcscapcismndombutan applicdstresstendstodirectthejumpsinsucI1awayastorclicvctIIcstress・

Ithasbeensuggested3thatinfTictionalslidingofTubbertl1cmolecuIarforceficlds olTubberandtTackinterlockatthctrueareaofcontact,similartothcintcraction

bctwcenparal1elmolecularlayersinlaminarviscousflow,6m(lt1lattl1cfrictionalforce

ofrubberisakintoviscousforces・Nobreakingofmolccularboll〔lsandtbcrcforcl1o

frictionalwearneedbeiiWokedtoaccountforthefrictionalforccinthispicturc、TbcstrcssdepcndcnccoftlMBslidingvelocitysbowninFig・J511ggcststI】atrul〕1〕cr

frictionresemblesnon-NewtonianratherthanNewtonianflowintl1attllcvclocityis notproportionaltotbetangentialstress、FollowingEYRINco,thiseffectisthoughtto beduetoamo〔lificationoftheintermolecularfieldbytllcl8lrgctalugcntialstresscsoccurriI1ginrubberfrictionwhicheffectivelylowcrtl1ecncrgybarricrsurroundingtllc potentialwcll・IntheregionwheretllclogaritllmoftheslidiI1gvelocityisproportionaltothetangentialforce,theresultsshowninFigs・zand3canbccxprcssc〔lbyc(111.(2):

、=UOeXlD-(母一γF)ノノf】.(」)

whereuoandγareconstants,EnistlleactivationenergyimdF`tIlclrictio1mllorcc・Tllcexperimentallydeterminedactivatio11energicsarclリ,8s()cal/molclOrsli(li11gon groundglassandI6,160cal/moleonsiliconcarbidc・Itisintcrcstingto1lotcthattlIcactivationenergyfordielectricrelaxationhastIIesimiIaTvilIlIcofal〕out17,()〔)〔)cal/mole,suggestingthatthemovingcomplexcsarcoftllesamcordcrolmagnitudciIu tbetwoprocesses・

Thetemperaturecoefficientoft]uefrictionalfo「ccaLsdcrivU(lf「omc(111.(2)istllc1l givenbyeqn(3):

…ルー-;'・壇ヂI31Tlliscoefficientisalwaysnegativebecauseoftllcllighvalucof7ぃvllicll,Klscstim8Ltc〔l

lromFig、2,amountstoIo13cm/sec*.

Ⅲ.

lIliII!

i■ !.

*TIoePlDysicaIsignificanceof〃oisasIollows:lfAisthelengthoftIHejumpe型ecutedbythemovimgcompIcxcsaItc「3ⅡCCC汁邑fuliLctiviLtiun,tIwn

pノスisthetransitionrateA・whichmaYbewrittenasEB-yF

A=Aoexp--- 尺丁

AcCordingtotbcru〔limentm『ytheorylinedoutaboveDAosbo811〔IbctIocI・Cl⑬'6hntvibmtiuIMll[rc-qllencyofthemoI・ingcomplexes、WithIo-7cmasalikelyvall8coljLAoisIo2og⑪c-lwhichisclcarly toohiglubymanyoT【IersofmagnitudeforthisinterpretationtobcwLIi(LTl0claTgcvallIc⑪[ACnnbeaccoMntedfoT⑪nthebasisofatheowduetoEYRuNc・wluicIoc。nsi〔IC厩anctiwLtioninlDh>・昂icalprocessesasacluemicalreaction4・Inthistheory‘dueconsiderationiHgivcntotlucI6LctthdLttIlcnumberoIcomplexeshavingatanytimetheactiwLtiouucncrgyEhi&、《Dts(DlclylD『(〕IDorti⑥naItiDtIucBoltzmanuuIacto「exp-EbノノピTbutisa】soproportionaItotIuemtioofthcooIuluubcru化itcsavaiILul〕IctoactivatedcompIexestotluenlImberofsitesattluedispo&alofll【)tiLctMhtcqlcolllIDIcxes・lro「tlli3rcascnotheconstantAoisactuuaIIytl1epro(lluctofthcvibrationlrcqHIcncvKMU(ItlucTaLtiUo【帥tu島iluC

tIuctwo苗tatcs、ThisratioisintroduucedinEYRINc・stlueo「ya5cxl〕`:1sノルJSi田cHlⅡu(lcuutr⑪IDyufactiwution・AlmrgeAoaccordinglyindicatesthattherenremanymurclDu餅siblc臼itc団hr8LctivHltcdthanIornotactivatedcomplcxes・Tl】ispointhdlsbecIldisclIsscdin(化tioiIbyl《八uz31ANN笛7.ルノBrBDlpBsp・イエフ

*

Page 6: Iit1I - Oita University

380 VOL、1(1057/5N) 】F1(ICTlONANDAIBIいSI()N(〕IFI《UBlB)ZR

WorkoIuthい'clocitydcl〕⑥】】(IcnccofrubbcrlTicliu】1901mrrcfcrredtohasbcuJ1carric〔loutatvelociticsnotexcccdingabOutlcm/SCC・WithI1ighcrvelocities,slidingat

constaJlttangentialforccbccomesunstable,I〕「[・HlIIuMLblybecauscofthetempeTatuTcriscdllctodissipationoIfTictionalcnergy・ItIlIlPIlID19comcsncccssaTytoreversctllc

tecll】】i(luea1】dmcasuTcfrictionalforcesatl)「'0瓢9riI)cdvclocitics・ExperimcntslMwcbcc】1carricdoutwhicllalIowcdtlUcfTictionKlllL.、I)cr6LturcTisctobcmeasuTedattllc

samctimc5・Tllcsli(lcrwasatllcrmocouplegiviI1KH1gcomctTiccontactareaofabout

lmm曾wllichwasprcsscdagainstarotatingrII1’1)c『(lisc・Figs.+(a)and(b)givethcrcsuItsobtail1c〔lona】11mfilledandacarbonbl81clK-IilIc(lcoml〕oundof、naturalrubbcr,

ItwiIlbcsccllthattllcinitialincrcascoftllcco(91(icic】ILoffrictio】1witl1incrcnsi】ngvcloc‐

ityisnotmaintaincdatI1igllcrspeedsbutgivcHwitytoagraLdualdecrcase・Tllcloa〔ldcl〕cndcnccoftI1ecocfficicntoffrictionmadcい'i〔lclutintIlescgrapluswillbctrcatcdindctailinlatcrscctions・

TI】eco11sidcrablctcml〕craturcTiscisal〕proxim6Ltclyl〕roI〕ortioI1altot】uesquarcroot

orthcvclocity・ThisdcI〕cndcncehasbccnl)rcdic(c〔lulcorcticaIlybyJAI2Gl§l《`forvcry

lliglwclocitybutal〕pcaTstobcvalidforawidcrr61U1gctllangivenbyJAEGElt`st1)cory、ItciLl1bcsluowntllatt1lcobscm'cddccrcascI〕Itllccocfficicntoffrictiomat】ligbcr

vcIociticsagrccs(lu8lIitativclywithtllctllc()Ty《'「1.111〕1)crfrictioD1exp「csscdbyc(1,.(2)iIaⅡowiLl1cci田mHM1《PfortllcsimultaH1coll5化l1lll(、r8lturcrisc・Thccomparisomcanbc

oI〕ly《llIKlIitdlIivcbせじ&Luscitisncccssarytocxlr6I1)()l8Ltcfromrc5ultsobtai】lcdatvcloc‐itic3bClowlcm/scctovclociticsrcaching-l《〕IlclI1/sじc、Assumingtllatthetcmpcraturc

riSc()bcystIlcTUlation

Jノーハノii (4)

'

DUI

I9B0 91‐

91‐I

suggc筋(c〔11〕Vtl1ccxl,crinlcI1talc、.i〔lence,iIIl(I別11)s1illltingcqn.(4)ineqn.(2),t]〕e ̄

IrictioIl6Llforcci息givc】11)yu(11】.(5):

γノー鷹"-'f(7,,MV可'`'8ヂ (5)

whcrc7bisroomlcml)crilturcintllcabsolutc蔦c6Ilc・Tllcshapcolthecurvcpredicted

l)yc〔IHI.(5)issllownillFig.」(c),whicbhasbcc11cillclllKltcdwiththefolIowil1gnumeTicalvalues:E〃=20,()o(〕cal/molc,To=30()。K,r=5(l〔1Kcm~lscclandl'0=エol3cmscc-1・TIDiscum・ercproduccstllcsalientfeaturcsolllIc⑪l〕erimentalcurves,anditappcaTs

tIlHlttllcdecrcascofthccoefficicntoffTictioIUwi(Ilincrcasingvelocitycan1argelybe

attributcdtothcfrictiomaltcmperaturcri5c.

Ni

111.LOA】)、EIC】2N、】:NC)§OFlRUBBI§I(】了[《lCTl(〕NONSMOOTHSURFACES

Tllcviuwsolltllc】1aturcofrubbcrfrictionI〕lItlorwardintbeprccedingsectionimply

tIMlttl】clTictiol1allorccisI)rol)ortionaltotIlctrucarc&lofcontacM,andthusconform

witIlllDU1IIcoryoIsolidfrictio】Ibricflyr□.iいⅦ(lintllclNTItoDucTIoN,Thefrictional

lorccノ『脂dlccordinglygivcnbyc(111(6)

盃=リ、...l (6)

ルノ”cjI“sハリJ7

U

ll,I

Page 7: Iit1I - Oita University

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[・認

Fig.4.FrictionaltempcTatqDTerisc・fIノ組ndcccflicientso(frictionノ41〕lottcdng81illstsli《lingvcIocity(a),onanunIilIedvulcanizateofnatluralrubber;(b),onanatuuTalTml〕bcrtyrctTcadcompoIundfiⅡedwith45p・P.h・MPCblack,TheaveTagenormalloads(glaregiveninbrackcts.(c),thcorcticalvelocitydependenceoftbcfrictionalforce,calculatedfromeqn.(5)C「apIIs(a)and(b)l「om「c『、5.

庇らた”)Ic6sP.“7

/~へ~ 必(ユ2)

/,

/~~

~と2(66)-

一一面7(壷1一一 一戸一

100200a00Vcm/sesOO

--、 〆

二一

一:極

ワー

--

≦<璽一必(フ91

"jnE幻L

--------

r~、、、

、、、

100200300

vcny 400

SeC

Page 8: Iit1I - Oita University

VOL.!([057/58) F】(ICTIONjWDAllIぃH1()NOFItUIBBI2I《 301

11

anditwillbcassumedthatvelocityandtclⅡl)crKuturceIfcctsmvolveonlytheforce

factoT9D、Intheabsenceofayieldpressurc,itisnotadmissibletoputApropoTtional totllcIIormalload,asisdoncinthetheoryofsolidfrictionwberesllapeandsizeof

thcsurfaccaspcriticsareimmateriaLAnassumptionhastbereforetobemadeabout

tl1caspe「itiesonrubbersurfaceswhicbisc(m《lucivetotreatmentbytheoryormodel

cxpcrimentwitI1outbcingtoofar-Ietchcd、FroIuIbothpointsofviewitisadvantageous toiLl)proximatethcTubbersurfacctoana「「;l)'()IiLlcntical,closclyspaccdhemispheres

ofr51dius'7.ThismodelismeanttoapplynIllytoconventionalIymouldedsamples・ Itisfurtherassumedthattheelasticbellavi()llroftllcrubbercan,forthestrainsoc-

curring]1ercJbcdescribedbyasingleelasticc《DIlHt:111tEwllicbwiUbedefinedpresently,

ItfollowsfromdimensionalconsiderationstllmIIIlctruearcaofcontactwithanideally

snIm熟、thplaneundcrthcnominalpressure′mustobeyarclationoftheform

、イーグ:ど`bIWE)p'‘ (7)

-0や8△|■廿廿Ⅱ01巳81■0106■□09口q箔010B・DC・・10-・己■BJq

.■●7-‐

’○伯ロロⅥ□Ⅱ山一叩ⅡⅢ印叩肌止ⅢⅢ0仇l川ⅡいⅢ小10041’w・旧0忠’■・P』DhuJJ研Ⅱ

wherethec'sandβ'sareconstants、Aplottじdagainst(》/E)shouldyieldauniversal

curveforrubbersofdifferentstiffness,TIlec()efficientoffrictionderivedfromeqns.

(6)and(7)is:

浜=wEどclJwE)p'0-1 (8)

:…!!

andnolongercontail1stllcradiusγoftIlcaspcritics,

Modelexperimentsontbecompressionofla「gehcmisphcres7haveshownthatthc

rcsultslitquitcaccumte】ythce(luation〆

孝l=c⑪n筋t、/W3 (9)

Tllissimplerelatio11agrecswiththcthcorcticalexpressionderivedbyHERTz8from

classicalelasticitytl1coryforsphericalcontacts,e(1,.(r(〕)

(#、$!、

』-(誌,)シ,(1.1wIlcnthePoisson

l2〔1,.(Iu)willbc

Thccocfficient

ratiol1astllevalue&a1,1J「()l1riiLtcforrubl〕cr・Listhenormalload・uscdtodcIinctbceffMiwIllodIlIuSE・

offrictionresultingfrolII,’''''3.(H)and(9)isthcn:

/8=(WlI)(/'ノノ!)-V, (皿) q

whercnumericalconstantsllavebeenal〕H[)「|)(DIliI1thc「actor9D、ThcasperitiesonTubbersurfacesare,11(DwIwcr,notisolatedanddonotdeformin-

dcpcndentlyfromcachothcrbutwillj【)篇tい'筒tlIeVbarrcloutduringcompression、

Tlliswillcausedcl〕Klrtu「cfromc(1,.(11),I)M1Il)illHmorcI〕ronouncedastl】eloadin-

crcas(Dsa】1〔ltbcasl)criticsHLrcsqucczcdjlll()i1部)lidl〕l〔)ckprcsenti】lgacoI1tactarca

(ICPじ、〔IingonlyIittlcoD1tbeloa〔LThissc(Iuじ11c(、()lい'cntsllasbccI1followcdbymcamsofasccondmodclcxl〕c「imcntinwI1icI1as(Io18llmP5巴tDf25smallllemisphercswascom-

pressedunder・varinbleload・Fig.5showstIlL:cIDntKlctarcasunder3differentpressuresna化〃"“3,.ダエァ ニリーー00.

Page 9: Iit1I - Oita University

蝋L■割。■I.

voL1(Ⅱ057/58) A・SCHALLAMACH 302

、●■ 0

日■■

■06

⑨⑦③④④

⑨①④⑥①

③③③、⑨

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r111

鋤勧③懲趨

②懲鯵⑲鰯

船側船側鮒⑨鐘鰯④愚

ab.c

Fig.5.ContactaTeaofmodelrubbeTsKDrlaccunder3dillercntl〕rcssonTcs:(a).色.Ⅱ4kg/cm2;(b),7.75kg/cm2;(c),66..kg/cmg・Rcducedo85x.

■◆■

の●■』

anddemonstratesllowtheasperitiesatfirstdeformwithoutmutllalintcrlerenccias

isseenfromthecircuIaTshapeoftheircontactareas,butatl1igl)erloadscloscupfinally

intoablunteds〔luarepatternwithlittlespaceleftintheinteTstices・TI1caTcasof

contactunderthcvariousloadshavebeenmeasurcd」usingonlythcimUerOhcmispheres

astbeouterhemispheresaresubjecttoendeffects、Tl1eareasodctermincd,whcndivid‐

edbythenormalloadandmultip1iodwit11thceffectivcmodulusEofthcmodcl, E

shouldaccordingtoeqn(8)representauniversalcuWeoIthcproduct(テノ`)when plottedagainst(,/E).ThiscurveisshowninthelogaritllmicplotofFi9.6.Atvalues

ofけ/E)lowerthano、エ,thecuTvehasbeencontinuedasstraightlineofslopc-J/3

wellestablishedbytl1cmodelexperimentswithlaTgesingle】lcmisphcTes,Tl】ispTessuTc

regionmaybecalIedHertzianregionincontrasttothesaturationrangeathigher

pressures・

TheexpeTiTnentalpointsmarkedinFig.6havebeenobtainedonplateglasstracks,

■ ▲、Ⅱ

け▽■0

9■P6L■0●■■‐OG■■■■■■0509869.0566

ロケ■

-1.0 エ

ミレ。

。 □、

0.5

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-OS

~~a。‐1.5‐I。‐0.50,.9,。÷CLSFig.6.LoaddependcnccofthecoefficientofrubbcrlrictiononpIategIass、Fl8111inc:tlhcorcticalcuTvedeterminedbymeansoIeqn.(】Ⅱ)andthcmodclexperimcntofl7i9.5.AtoD.《l)'namicfrjctionato、oo2I6cm/sec、E,staticlTictionVa]uesIorAtoDITomrcL7・foTEIromrcf、0.

ルル”"“s力.“7

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Page 10: Iit1I - Oita University

l'

VOL.’(1957/58) ITRICTIONANDAlIIいHIlINOIrlRUBBER 393

wllichmaybeconsideredideallysmoot1lc()n1IDarcdwiththeTubber,andshowthe

cxtcntolagrcemcntwiththesimplctheorylin【!(loutabovc・Themeasurementscarried

outwithcompoundsAtoDwercdetermin8Lti(DIlH(〕Itl)ccocfficientOfdynamicfriction,

theonlyarbitraryconstantusedinfittiIlgI11じpDi】ItstothGcurvcbeingtllcforce

constantP.TablelgivesdetailsofEand帆.

16

OO

TAMI」11

ノハハRmOUz o,Ag/rUjJ2 a00IPo8fルイ『、、

9仏

I11

luu1rillc〔lnatlumIrlubl〕cx・

unfillc〔lnatQu「a1rubbcr

lD11lille(111atluralrubber

UUatumIrlII〕l)crIiⅡc〔I

witl1うCl〕.P」】、1-いFblacIに

11.8H

18.3 』().0

,,,I

ABCl

{J望0戸

◎lP1

q■℃

P99の』Ⅱ

ll M

il

・11.0 IC・47 」彌鰄、

ThevaluesforcompoundEarecoefficientsoIstaticfrictionreplottedfromacurve

givcnbyTIIrRIoN,、Inthiscase,themoduluswasnotknownandhadtobeadjusted togivcbestfit・Tbcprcssurescmployedillt]lcdyl1amicfrictionexperimentswcre

notlargccB1oughtobringmutualintcrfcrcncc(〕ltllcaspcritiesintoplayandcovGr

onlytl1cHcrtzianrange・Thctheoryisobcy('1111(’1℃untillowvaluesof(カノE)arcreachcdwhcrctllccoefliciel】toffrictio1waTicslcsHwiⅡ11M)TmaIloadtha】1cxpccted・TIllRIoN,s

staticfrictionvaluesreachwellintothesatur;LIi〔)nrangeandagreewiththetheoretical

cu「vc,I-IiglIcrprcssuresllavebcencmp10yc〔11)yl北NNY1o,w1】oinvcstigatedthcfrictionoIanumberofcompouJldsonpolishedstcc11111〕ricatcdwitholiveoiLHisrcsultsare

giveninFi9.7andshowthatatlargeno「mall[DHL(1sUlccoeffici(mtoffrictionisnca「ly invcrsclyproportionaltothepressurG`inagTじじmcntwitllFig、6..

DENNYfittedhisresultstothecmpiTicalc(111.(T2)tIIctypcofwhichhadfirstl〕eGn

suggestcdbyTlllRIoND:

鰊】"』」-,+[swAi,)(』贄)

⑪。心00

llBPd■■Ⅱ▽6.ローマP■■0‐0』可

面剋

◇勺p●■0dB口・OC0Pjp・一

pPI

p・。

IIlj

IoP4 Io-。 lo-z IO-I Io p/gb

Fig・7.CoclIicientsof〔lvnamicfrictiononpolis1Ic《IHLcuIIlobricatedwitholiveoi]・FuUcurvecal-び

cll1atedfromcqn・(【。)・FiguresmaTl[edagainstc〔)10,1〕oⅡ、〔lsarcBSllardncsSes・VelocitVo・oYcm/sec・FrOmTeflD. ̄

庇e/β搾りICBS力.¥エア

。■

…:蝋鶏&

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八 |●

Page 11: Iit1I - Oita University

0△■pF0i0■0日■■■■■Ⅱ0ⅡⅡⅡ996ⅡP+‐・●000■100

VOL、1(1957/58) 八.SCHATエAMACII394 ~チョ

レ‐

whereAisamaterialconstant(nottheareaofcontact1)andEo,thccompressionmodulus・

Accordingtoeqn.(エ2)thecoefficientoffrictionbecomescoI1stantatlowpressurcs、

Aseriousdeparturefromthetheoryontheloaddepcndenceofrubbcrlrictionas

representedbythefullcurveinFig、OoccursthereforeoI1Iyatlowloads,Itissuggestcd

thatthisdiscrepanCyarisesfromthefactthatrubberasperities,eveni(theycanbe

approximatedtohemispheres,arenotidenticalbutstatisticallydistributedinsize・

TheinHuenceofthisinhomogeneitywiUbemostpronouncedatlownormalloadswI1en

onlytIlelargeraspeTitiesareincontactWiththetrackbecausconincrcasingtheload thetrueareaofcontactincreasesatagreaterratethanwitIlidenticalasperities・A

quantitativeestimateofthiseffectcanbeobtainedbyassumingthattheradiioftl】e

asperitieshaveadistributionfunction/(i')。'becomingzeroforamaximumradius

γ,,!“・Atlowpressure,whereonlythelargestasperitiesareinvolved,thedistribution

functioncanbereplacedbyitstangent,say

丑一・=

一過】

/(r)`l′=conSt.(7,Mm-γ)〔lr ('3)

Assuming,fUrthermore,thevalidityofHERTz,sequationsbothforaTeaofcontactand

compressionofhemispheres,thecalculationhastheresultthat ’0

so

/JloWWEノーCOnSt,け/万)-V, (】4) 11

0’100

81■●

ARcIIARD]lhascarriedoutasimnarcalculation,makingtheassumptionthatthe

asperitiesareidenticalhemispheresevenlydistributedondiffCrentlevels・Thecoeffi-

cientoffrictionisinthiscaseproportionaltop-nA.Itwillbeseenthereforethatany

inbomogeneityoftherubbersuTfacetendstoreducethepressuredependenceofthc

coefficientoffriction・Itshouldalsobeborneinmindthatmacroscopicallyimperlcct

contactbetweenrubberandtrack,whichmayeasilyoccuTundcrlowloads,willaffect

thefrictionalbehaviourinasimilarway・Thisproblemwillbediscusscdinmo「edetail

whendealingwithfrictiononroughsurfaces・

RATNERANDSoKoLsKAvAユ2havesuggestedthefollowingscmi-empiricalrelation betweenthecoefficientofstaticrubberfrictionandJlormalloadL:

ijl l:I

一宇

・11 61

●の

浜-浬.。+」/LA (Ⅱ5)

whereAand/Jooarematerialconstants,andハistheShorehardnessdividedbymo,

Atlowloads,eqn.(r5)givesaloaddependencedifficulttodistinguishexperimentally

fromthatgivenbyeqn.(I4),butathigherloadseqn.(I5)yields,whenplottedlogarith‐

mically,acurveconvexagainstthelogL-axis,Inthisessemtialrespect,RATNERAND

SoKoLsKAYADsresultsdifferfromthoseobtainedbyTHIRION,DENNYandtheauthor・

Thedivergenceisconnectedwiththepostulationofafinitecoefficie、toffrictionノJco atinfiniteload,putforwardbyRATNERANDSoKoLsKAY八.Weshallreturntothis

point-attheendofsection8・

況伊化”'jcGs沙.\'7勺今

勺吊

Page 12: Iit1I - Oita University

v(L1('リ57/58) 151《IC・I・【()SIASII)AIllぃHII0N()lFI《11ⅡIlIil8 .)OS

1V・STI《liHsC()NCI2NTIい゛rI()N§()N】(ulllBlil(Sul(IFAC】§S

WlM1「ul)bcl・sli〔IcsovcrKlsurlKlccwitbasl〕(91.iIil9HcomI)ariLblcto,orla「gCrtllKmtlIosc

(DlltllcrlIbIxP「10cKllstrcssconccntratio11§811.Cl)1.【、(IIIC[(16111(laI〕raHioI1cnsuc目、11】t「cKltiI1K

lMiIll8utt(・「,81(liIIicultyalriHじHontDltllc(;r(q81い・61「i(、tyillHlIillxP8ul(lH11arl)Iwsi局()ltll,‘

ILHI)uritic乳l(〕l〕ccxpect⑯〔1011(lillcrc1】ttrackHJIlKcIl(?「;11,onlyHnmⅡareas()ftIlcaspcritics

wiⅡiml〕iIlgc《)llthcrubl〕cr・Itiskllowl1Ir()IlwDli(1KじQmctrytllatasmallrcgi(〕n1ofal1y

coIltimMjlls5urI81ccca11I〕cal〕l)roximatc〔1t()ilnlPⅡiI)馬0i〔1.EmployingasI〕Ilcrcasm()(lcl

iLsI〕eritywoⅡ1(1tlluTcforcU1otscriouslyresIri(:(KlOII《、rality・WhcntI1cloa〔loncachKlsper‐

ityis篇()11iglltI1atpllncturcoraI〕prccial山1)ullI、lr8ltiol1()IthcrⅡ1〕bcroccllT,acone

nlaybccll(〕scnasrcl〕rescntativcaspe「ity・

FoⅡowiI1gsIlcllconsidcratio】1s,mo〔lcluxl〕(・I・iIn⑪11⑬llavcl)cenmadcinwhicllrubbcr

surfaccswcrcscmtchcdbyasmallluemisplM)r1,13(1mm(liam.)andbyanee(Ilel4under

co榊Icdc`’11【litiol鳩.Provi鼠ionwasalsom:MIMI〕rrcCDrdingtI1cinstantancollSt「activoYorL-j.

I2x81ml)lcHo(trKlccs]cItl)ytllcl〕llIntl)()iI11()Iltw〔)〔1i「hrcntcompou】1〔lsa「csllowl)

inFig.8.Thesepbotogmphshavel〕eentakl・nwiI11ol)Iiquciuuminatiol1fromtllcright‐

1Mm(lside;thedirectionofslidingisdowlIw6l「(I.()nthesofteroftherubberslUardly

aI1ysur(ace〔lamagciscreatedundcraloa(l()に59(、)butunder8()gadiscontil1uous

traccispToducc〔lconsistiJIgoflateraltc81rHilUl・(〕:bithetrack,oIleofwhicbisseenin

Fig.H(b).Fig.8(c),Bbowi】1gtllcsamct「acUiltl('wCrmagnification,dcmonstmtcstlle

pUrio(licI1aturcofthc瓢lrlacc〔IamagcwIlicIlIl6L:bccl1attributedtoastick-slipmccIl‐

al1iHm・ThcruI〕I〕crKhdhcrcsIrictionaⅡytotllUhcmisI〕hcricalpointal】dislocalIy

tcasedoutiI1tl)cdirectionofslidinguntiltllcelasticrestoringforceexceedslimiting

Irictionandthcrubborsnal)sback、Tllctracconthehardercompound,Fig.8(d),is

similarintypcbuttllctearsarcshallowcI・’1cHBrcgularandmoreclqselysl〕aced・It

lMIsnotbccUlI)ossiblctol)『o〔luccsignificanいllrfKlcc〔lamagconcarbonさloa〔lcdtyrc

t「cKLdcoml〕oundsundcrthcconditionsoftIlcHCcxl)erimcnts.

r…

6△■■し▲PdB▽・凸

、。●ら‐0▲、■■■■日日■■の0‐●日日Ⅱ■06000

0lb6。‐卜IlUTP0。△。.

’ abcd

lri8、8.Tracc局(、IalDlooIutlDointmovingdownwaTdontwounfilIcdvulcanizatesofnaturalruUbbcrwitlutlDcfoll`〕wingmo(llIIi:(a>,(I〕)an〔l(c),J【、5kg/cm理;((1),Y8.3kg/cmg.Normalloa〔lsandmagni〃cati()ns:(a),乞59,3()×;(b)’8o9,3o×;(c)8og,uox;(。),8o9,3oXPllotograpIls(c)and(。)fromTcLl。.

JPC化”D8resP・ィJ7

11

Page 13: Iit1I - Oita University

Zrナ・‘3,.W謎ヨノヲヨ

゛P1IOSm1uDu1

-I(llaHTjo①31,①⑪Illu⑥⑨a』oJDu1lゼパqp3onpo』duo11nq!』1s1pssa」。s1℃つ1コ⑨」o3lIL・(q)・6.月!』

‐I‐Cl■Ⅱ00

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.c1.J⑨』luo」』・』ap1IBIuuo11a1」jJouo11ou」1Iu11u5'HuuJ』⑪I'ul1』o〔l(111」u1uo11I1q1」1511)5s⑪』JsJoa」81.31(lo11sEISo1oqI〔1.(u)・6.51J

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Page 14: Iit1I - Oita University

v()Lu(rO57/58) 307 FRICTIONANDAIB1RASI()NOlFRUllRI:1t

Thcst「CSS(listributionpToducingtcarslikl9tlIoscshowninFi9.811asI〕ccnstu(licd

byilwcstigatingphoto-elasticallythestrcss《畷iLroun(lthcareaofcolltactintllc2-(limcnsionKLlanalogo】1,cmployingacyliI1(lrM1Hli〔IcrontrKmspa「entrubbcrl3、ThoTcsultisshowninFig.,(a).ItwiUbeseclltlMlttlleTcisastrcssconccntTationatthc rearolthearcaofcontact,asindicatedbythcclosespacingoftheisochromaticsin

thatregion・Tbisstressconcentration,occurrillgnearafreesurface,mustbepredom-

inantlytcnsileincharacter・AnyfailuredllUtofrictionalstresswouldtheTeforebcexpectedtoconsistinopeningoftcar:bcIlindtheslideratrightanglestothe directionofsliding,asconfirmcdbytheexl)crimcntalevidence・

ThestrcssdistributionofFig.,(a)conformsqualitativelytoclassicaltheoTy・In

plancstrainalineforceactingunderanyanglconthesurfaceofasemi-infinitcsolid

l繩ICC…11「CmdialSt『essdist『ibution、

10,0‐r

0-

筋〃』

I』

ユー宛一一⑪』

汀wllcrcOisthedistancefromtbcpointofal)l〕licationandOistheanglcbctwcenQandtllcloadLThclincsofe(IualstressarecirclessymmetricaltoLandpassingthrough

tllcI)ointofapl)lication・Fig.0(b)reproducesthisstressdistributionloracoefficient

()flrictionof2;thereisastrikingsimilaritybetweenFigs.O(a)and(b). WIlctllc「tbestrcssconcentrationbcl1in〔ltlucsliderreachesacriticalvalucornot

(1Cl]Cl】(1s,othcTthingsbcingcqual,onth〔91》11Ⅱ[(ICformationproducedbytheslidcr,

tlUatistosay,onthcrclativcmagnitudc(〕Ilri(9ti(DlMul(lstilfncss、Thismayconvcni(mtly

bccxprcsscdbyt1lcratio0D/だ、Thcabsc1lCl9n(tl1arsfromthetraccofthcbluntpoint

o】Itllcstilftyrctrcadsamplcisthere[()run(Dlncc(jssarilyductoanysuperiorityin

八ilc圏trclIgtllovcrthatofapurcguml)utmayrcsultf「omitshighcrmodulus・Wllcnrubberisscratchedwithance(ⅡCIIlllctmctiveforcesarelargert]Ianinthe

casco(abluntpointbccausco【mecl1anic811l・Ill8M1glcmelltbetweenrubbcral1dneedle・

Animl〕ortantconscquenccofthisdiffuTLPncI2i時tllfltsurfaccdamagecausc。')ytlle

needlecanbemoreseverethanblunt-1)oiIlldamageandleadtoactualdctachment

ofrubbcrI)articles;thatistosay,tlIencC〔ⅡL1calncflcctprimitiveabrasioninitsfirst

l〕assageovcrtherubberandthereforetak心(11(Bsurfacedamageonestepfartherthan

thCbluntpoint・WhetherthisoccursorIl()l〔ICI)cI1dSonthcmechanicalst「engthof

tbccompound・

Ancc〔llctraLceoI1thcsofterofthetwollIl[iⅡlxlvulcal】izatesofFig、8,sllownin

l7ig.r(〕(a),isverysimilartothatleftbytlMl1)Iulltl〕oint;thetearresistanceofthis

coml)oundisquitchighandamountsto7・r21Wcmasdefi】IedbyRIvLINANDTHoMAsl5・

ThcharderunfilledvulcanizateofFig.8((1)1M鴫tl】clowertearresistanceof456kg/cm;

assccnfromFig・I0(b)theneedleheretc8lrsoutclongatedgrooves,thetracegiving

theimpressionofanincipientscdringmn「k・Tl1cf()rmationofthcsegroovcsisexplainedbytllcskctchinFig・TI・Thefamilvofcllrvu筋馴l(lwnareoriginallyequidistantrefcrcnce

雄作”"“$沙.“7

『、と’

蟹。、

11,I

Page 15: Iit1I - Oita University

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VOL、1(エ957/58) 398 A・SCHATJAMACH

。『いい。巳

二■ 二》二▲{二⑤←

Fig.】o・Needletraceson3diflerBntvu】canizatesofnaturalrubber.(a).unfilled.E=ⅡⅡ.5kg/cm2,】oad8og`magn、13×;(b),unfilled,E=18.3kg/cm2,load5og,ma9,.3o×;(cMilledwith5opp.h、MPCblack,load8og,magn、3o×・Photographs(a)and(b)Iromrefl6.

linesmarkedonthesurfaceoftherubberatrightanglestothedirectionofmotion・

Theirsubsequentdistortionindicatesthestraindistributionaroundtheentangled

needle・A1thoughthestressconcentrationishighestinfTontoftheneedle,no

cuttingoccursherebecausefailureispreventedbyfrictionaladherenceaTound thecircumferenceoftheneedle・Therubbertcarsinsteadwhereitfirstloses

contactwiththeneedle,thetearsproceedingroughlyatrightanglestomaximum

stress,alongthedottedUnesAftertheneedlehaspassedandtherubberrelaxes,

thereg1onaroundthetearstuTnsbackthroughalmost9ooandtbusgivcsrisetothe

gToovesseeninFi9.IC(b).Itmaybementionedinpassingtbattbisinterpretationof

needletracesprovidesalsothereasonwhyitisdifficult,ifnotimpossible,tocutsoft

Tubbercleanlywithadryknifeblade

TheneedletraceonareinforcedcompoundshowninFig.(IOC)differsfromall

bih10D0BP△■■■■P■■q■■■U0■0巴。。’a免押0.6■.■・■●7011.●.p90■■■■▽0.‐9-0.0

■Iu0■■■|■■■■■■:■■■Ⅱ■■■■■■■■■p0D92■■■■Ⅱ■10-010■0▽■■010000410Il5IP6

I‐。‐|’00.9,06リ’0‐◆0100..Ⅲlu1‐’-4▲▼。■■、■■■00

1 f’

I ご§§ 6

E二塾

Fig.、LDiagTammaticTepresentationoftwostagesinthedeformationofarubbersurlacebyaneedle・TheshadedciTcleisthecross-sectionofthemeedle・

Rc化”"“s力.“7

0凸

Page 16: Iit1I - Oita University

P1I oO

OII

1Il

il

VOL、1(rO57/58) FRICTIONANDAnRASl()N⑪IFRUnBlm 301

othcrtraccsinbcingcol)timlousbuti葛otllcrWiHI:馬inlil8LI・lotluatSIIowninFig.r()(b).ItlMlsbccnpointedoutintIlcoriginalpublicati()IoIItIMltaI1cedletracewillbecontinu‐

ouswl1enthcTatioofelastictofrictionallorco9scxcccdsacertaincriticalvaluc、

TlIccxccl〕tionalbchaviourofreinforccdrlII)I)urbothwithregardtoblunt-pointan〔ltollcc(llctraccshasbccIIattributedtotheirgrcatcrstiffmess・Itwould,however,beprcmaturctodmwconclusionsfTomthcscnM)(1clcxperimentsastotheabrasionrc‐

sistallccofIiⅡcdrubbじ「5.Thcrcasonwhytbcrc篇lo1tscaImotbcappIicdwit1Doutp「ovisoswiⅡbcdiscussc〔lintIUefolIowingsection.

0006,60

1F. ,E

OO

Iri

ll O V・TIlESURFACECONDITIONOFABIいIllil)、!『lLLlZD】《UBBERCOMIDOUNDS

a紐溢il;P鯛}磯臓墓嚇;師W:W:lfi艦:搬弧鯛騨filler,mostoftl1estiffeningislostbypreviousdMormation、Thephenomenonhasbeen studiedbyMuLLINs16andmoreTecentlybyMuLLINsANDToBINl7・Onceafilled

comI〕oundhasbeenpre-stressed,itsmodulusisIowerthanthatofthevirginmateriaIatallstresseslowerthanthepre-stress・The8lbsolutcvaIueofthemodulusandthe

stress-straincurvcofpre-stressedfilledrubberresemblethoseofunfilledrather

thanIilledcompounds,Ifthcabrasionprocessgocshand-in-handwiththecontinuous

productionofIargelocalstressesofthekindsugRcstcdbythescratchingexperiments, thcUffcctivestiffnessofthesurfaceoffilledrubbc「ssIlouldbeaffectedinasimilarway・Ithasthereforebeenassumed18thattbesurlaccofabradedfilledrubbeTcompounds iscovcredbyathin,constantlyrenewedskillthcclasticpropertiesofwbicharenot matcriaⅡydiffcrcntfromthoseofunfiIlcdvlI1ciLIlimtes・Forthisreason,itwouldnotbcappropriatctoequatethestiffnesseffectivcintheabrasionmechanismwiththe

conventiomallydeterminedstiffnessoffresh§amples・

TlIecxistenccoItllctoplayeronabradcds81mplesbasbeendemonstratedbymeans W鰻Merprc-strcssingphenomenonwbicIlijlcarbonblack-filledcompoundsrunspamⅡelwiththesofteningeffect・Black-filll9《IC〔Dmpoundswhennewhavearelativelylowclectricalresistancewhichhowever,incrtP815csTapidlyondeformation・Thiseffect

l】asbccnintcrprctcdasbeingduetothebrciI1《(l(jwIUoIanoriginalIyexistingcarboLblackstructure・Tllepostulatedsoftskino】1Klb「HMlcdblack-filledrubbersshouldtherc-

forealsobedistinguishedbyhighelectricalrcsistance、Experimentsmhavebeenmade inwhichbothnewandabradedsamplesslidovcrasmoothmetaltrackwhilstthe

resistancebetweentrackandsamp1ewasdetermined・Theresultofmeasurements

carriedoutwithatypicaltyretreadcompou】I(lofnaturalrubberfilledwith5opp.h・olHAFblackattwolow-fre〔luencyalternaIillgvoltagcsisshowninFig.r2,whereimpedanceisgivenasfunctionoftheslidillgtiII】c・TheimpedanceofthenewsamplerisessharplyonsettingtheapparatusinmotiuIMLndTcachesasteady-statevalueabout Iourtimeshigherthantheoriginalfigure・Tbじrcisnosignificantdifferencebetween

tlleimpedancesatthetwodifferentfrequcllcics・Afterabrasion,theimpedancehasbccomclrequency-dependentanditsequilibriumvaluehas,comparedwitllthe Ireshsample,risenabout6、Stimcsatエエoscc-1,andabout26timesat2rsec-1,彫化「6,8CCS力.チェア I

lIlii

Page 17: Iit1I - Oita University

111

・I働‐

VOL.】(エリ57/58)400 A・SCHAUlAⅢACH Pn1

D■● 。 ̄

00■■Ⅱ■けりBlPBⅡ■■■90仏■■■Ⅱp0b5ロケ■●0口!■■P▲■Ⅱ0

■■

丁〃吟と

70

■可■900G.006590.℃■■■■。.▲■も■0|■POC‐0.0011-0002口■■□・I000■■■■■■▽。,0■‐1009■■け。:

P4◇-F■■ロ■■B■bUAU●J0■■■■■■■DqCUrP■60■■▼05。■60□■1人■■00と■DPF●LIB▲■6.00■00■-0。Ⅱ!●・9.0

6.。‐。0.00I。16l0Bロ一・・・6口●.■b‐01710680‐■9■080.0◆・・可0-0

0■9or’00‐■‐巾■。‐COロ.

Fig.Ⅱ色・ImpedancechaTlgesduringslidingofacaTbonblack-fiuedJMutRIraImbbcTvhuIcanizate

PlottedagainstslidiTlgtime.(a),newsample;(b)and(c),⑬bradedsamplGVelocity,o・oq1I6c/sec・FromTefl9.

幹,■閂'

TheinitialincreaseoftheimpedanceofthefreshsampLisduetodeformationof

therubberasperitieswhichaTeshearedduringsliding・Thefrequency-dependeJIceoftheimpedanceafterabrasionindicatesthatthecurrentthroughthesamplehasalarge capacitivecomponent・TheinteTpretationofthisresultisthatstructurebreakdown

inthesurfacelayerhasgonesofarthatthefiUerpartic1esarealmostcomp】etelyisolatedfromeachother・Thelayerhas,forpracticalpurposes,becomeadielectric・Thatthis

effectisreaUyduetochangesinthesurfaceandnotinthebulkolthesamplccanbe showninthefollowingway・

If,insteadofapp1yinganalternatingvoltage,adirectvoltageisconnectedacross thesample,thedirectcurrentvoltagedropisconcentratedinthesurfaceskinand, thelayerbeingthin,shouldproduceahighelectricfieldstrength・This,initstum, shouldgiveTisetoelectrostaticattractionbetweGnsampleandtTack,incrcasethe normalloadandthereforealsothefrictionalforce・Thisexpectationhasbeenborne

outbyexpenmentascanbeseeninFig・ェ3Moderatevoltagcssufficetoincreasethe●

frictionalforceconsiderably,thusgivingindependentproofo(the・cxistenccofan

inhomogeneouslayerontopofthesample・ThetimeeffcctssllowninFig・ェ3arediscussedintheoriginalpublication,

AnestimateforthethicknessofthelayeTcanbeobtaincdfromtheincreaseinfTic-

"β/βγ…BSP¥'7

けい

gU●

。‐■OU10p,I?‐pDq0ニロロ■●曰090-.8,-‐|■■Ⅱ8●・hB6-,Ⅲ■11守叶一B-B0ILI・00’1◇山!。I-09℃

21c/畠cc (c)

ロムーヶヶマ

110C/Sec F-F-函や記再や

(b) @屯一勺や屯屯-

〆。

/…

21q/SCC,110(

久暉与が…が己や/seC(Cl ■鋲一一~午一

ノ〆’

目三舎8仁::E一2 【し巴。■・』。

Cs50 02J

00 QO

0.02

Cs5 5

OIO20 Minut:?

Page 18: Iit1I - Oita University

VOL.I(Ⅱ057/58) FRICTIONAN】)AIjIいSIONOFRUBBER 4m

■■

団『--W■■■■

苗■図画■、円■■■

5seo 6s70

Minutes

k9

■■■■---

70758085909510010511011512012S130

(`識、,、MinuLeS△09.K3.Thceffectofd.c,potentialsonthe(rictiUDnnlforceofanabraded・caTbonblack-loaded sampIe・Abscissa,sIidingtime,FTomrcflo.

tionalforceundertheinfluenceoftheappliedd.c、potentiaIdifferenceifanassumption ismadeonthedielectricconstantofthelayer、Thecalculationhasshownthatthe

ordcrofmagnitudcofthelayerislo-2cm.

VLINTRINSICAI9RASION

Tojudgefromtheprecedingsection,nodistinctionneedbemadebetweenfilled

andunfiIlcdrubbersifapictureoftheab「a5ioD]mechanismisdeducedfromourscratch-

ingexpcrimcnts、Thcqualitativediffercnccinsurfaccdamageonfilledandunfilled compoundsobservedduringthatinvestigationcanbeatt「ibutedtothefactthatit

wascarricdoutwithsampleswhicllhadundCrgonenoprc-stressingeflects・

御earingtllcscconsiderationsinmmd,atheoryofabmsionl3haSbeenbuiltupon[IleresultsillustratedbyFig8・IthasbeenassumedthattearsacrossthepathoftrackasperitiesaTethefiTstand,attlucsKlluI(Btime,「ate-determiningstageintI1eabra-sionproccss,tbedctachmemtoftheabm(l(P(11)Klrticleduringsubsequentpassesofthe abrasiveoverthetearbeinggoverncdbyKLmcchanismsimilartothatdiscussedin

conncctionwitllFig・rr・ThevolumeoIlIlcabradedpaTticlehasbeentakentobe

proportionaltotI1ecubeofthelengtholtIlcoTigimaltears・Inspectionofthephoto‐graphsinFig,sindicatesthattheseteKmmrcofthesameoTderofmagnitudeastl1e widthofthetrace,Ithasthereforebecna雛umcdthatlengtlloftearanddiameteroftbearcaofcontactareproportionaltoe8Ldl()Ihersothatitonlyremainstodetermine thcarcaofcontactundcrvariousconditiuIls・ModelcxperimentsinwhichanumberofcompoundslMwebeenindentedbyalargL9爵l〕IICrchavesbownthatthediameterofcontactnfoIlowstoagoodapproximatiol1lhccllbcrootlaw

D■0口。し

0白・BCqP▲■■■■0ⅡⅡq・I・‐●6↑■0■00

,fP7 Q。

、=cuu腺Lクリ、 (Ⅱ6)

whicI111asalsobcenlbundvalidforthccoIIIID1℃&sionofrubbcrspheTes,Itfollowsfrom ルル施川“5カ.“7

240V 。、 / ̄

声--ヶ 2qOV

・叩「

■■■■■■■■■■■■■■

■■■■■■■■■■■■■

一一顔、。「

--J

k9

aO 5101520253035404s

朝v} ̄

120V on ア

こ= ̄ ‘ 屯一炉- ̄

1割↑05 0

0Z a

Page 19: Iit1I - Oita University

| I ’ VOL、1(1957/58) 4oz A・SCHAIT-AMACH

eqn.(エ6)anddimensionalconsiderationsthattheabrasivewcarIl'pcrunitarcaof

sampleshouldbegivenbyeqn.(r7):

W-colust.γ(,/E) (】7)

whereγistheradiusofcurvatureatthetipoftlIeabrasivcgrain,Accordingtoc(ln`(I7),

rubberabrasionshouldincreaselineaT1ywithincreasingnoTmaIload,

WhenattemptingtoverifyexperimeiitallyatheoreticaIloaddepcndenceofTubbeT

abrasion,caremustbetakentoavoidcontaminationofthetrackbyimpuritiesissuing

fromtheTubber,Asinthecaseoffrictionexpenmentsprcviouslyreferredto,thiscan

beachievedbyacetone-extractionofthesamples・TheerraticnatureoftI1eresults

obtainedotherwiseisiUustratedbyFig.r4.Twotyretreadsamplesofnaturalrubber

oneofwhichhadbeenextractedjwererepeatedlyabradedeachonitsowntrackof

6ocmlengthUnderaloadof2.r4kg,themteofabrasionoftheextTactedsamplere‐

mainedreasonablyconstantbuttherateofthenot-extractedsampledecreasedsteadily

tovelylowva1ues・ThetrackbecameprogressivelydaTkerintheprocess・Underthehigherloadof8・I4kgOtherateofabrasionoftheextractedsampledecTeasedsIiglltlybuttheabrasionofthenot-extractedsamplei"〃Base‘considerably,whilstagradllal

■否

口印萩

P⑤ロ十

(●■■ワニ■日日ⅡⅡⅡⅡⅡⅡⅡⅡⅡⅡⅡⅡⅡⅡⅡⅡⅡⅡⅡⅡⅡuBBU・クユヮニタⅡ。■■ⅡⅡⅡⅡ■ⅡⅡ00口■日日日日口0■Ⅱ0口■曰■ⅡⅡⅡ、’二仏□・△■■■■■■■Ⅱ■■■■Ⅱ■■00■■■■■■■■■■■■U00D

E。」奇E」E・扇Epく

10 20Runs 30

[ⅡⅡⅡⅡ[ⅡⅢⅡⅡⅡⅡⅡ[ⅡⅡⅡⅡⅢⅢⅢ[1-----」5

仁。」奇E・Eo-⑪P』:

50

-1■Ⅱ口巳1■0P。

0.0

510RunS15

Fig.】4.VariationsintherateofabrasionoIanot-extractedandancxtTnctcdnatu「aIrubben,IDI ̄canizatefilledwith5op・P.h・MpCblackwhenusingrcPcatedlytIBcsamcsiliconcarbidct「ack(Icngtlu160cm).

尺どん”〃“s少・“7

■、

 ̄ ̄~宅ヨ

---へIood■2.14kg

--

eX2卜QCt。 ̄

Gd

notext「DCted

声一一員

 ̄_

。 ~~ eXLrcEqed

Ioodp8、14

 ̄-ず cftrQck

dfromhere

Page 20: Iit1I - Oita University

11-

巳CO

voL1(エ957/58) FRICTIONANDAIBl(ASIONOFRUBBER 4o3

●『’d□Ⅱ

clcaringofthistrackwasobserved・InthM8Ltt⑥I・casetl】esampleappearedtofuI1ctionlikearubbereraser・Ingeneral,ithasbcc】11(〕uI1dthatcontaminationofthctrack

becomesprogressivelymoreseriouswith〔lccru81singrateofabrasion・ItalsotcndstobemoretroublesomewithsyntheficthanwithnKltumlrubbcr・

ThercsultsgiveninFig、r5l1avebeenobtdlinu〔lwithflatextractedandvacuum-dried

samplcsonfreshabrasive(GaTnetpaperwitlMLmcallgrainsizeofo、エ3mm).Further-

more,thedirectionofabrasionwasreve「slxl81ncrc8lcllTunof64cminordertoprevent theformationofso-calledabrasionpatterjlswhicharethesubjectofthefollowing section・AbrasiontakingplaceunderthcseconditioJ1swiUbeca11ed‘`intrinsic,,abra-

sionFig・エ5showsthattheproportionaliIyofintrinsicabrasionandnormalloadgivenbyeqn.(r7)isconfirmedbyexperimc1It.

00

llj il1 Od

+■8

li lli lll

11

(;蝉,、、

■●‐■9。。▲■▲■r0ⅡⅡ■0日日●’0■。。■0。

■已巴

■U

Fig.Ⅱ5.IntrinsicabrasioTlplottedagainstnoTmalI1rc錨lIrc,Compounds:A,KryIene(・・Coldrubber,,)fiⅡedwitlu5op.p、h・HAFbIack;BtoD・natuTHuITllbI】cTIilledwith:B,5op・P.h・HAFblack;C075p.p、h・fincthc「maIblack;、,I3op・ph・PKltljluHon`sactivatcdCaCO3・Velocity,o、66cm/sec,Fromrcf.nコ.

I Eqn.([7)predictsalsothatabrasionshouldbcproportionaltotheradiusofcurvatureof

tllcgrainbutindcpendentofitssize、Twodistinctpossibilitiesarisehere・InthecaseofRりん形"“s力.乎'7

/ ′

/ ′

'

CsCS

R】凸

2 1

0 1

Za nEuCE計ETgoE28Lcく2

S c 2 2 ,打k P

5 0 唖

Page 21: Iit1I - Oita University

VOL](エ957/58) 404 A・SCHALLAMACH 》碑(’

「11

polyhedralgrainsofdifferentgradethereisnoaレアjoγjreasonw]lytI1eslla「pnessofthe cornersshouldbeaffectedbytheiTsizesothatabrasiomshouldbcindependentofthe

coarsenessoftheabrasiveThisconclusionhasbeentestedbycarryingoutabrasion experimentsongaTnetpapersofdiffeTentgTades;tHeresultisgiveninTablelL ●●

~ ̄ワー

TABLE’’

八m】RASION】NJO-3Cm3/m,cm:ONCAR】VETFAP正ROFDII;【『HRENTCOARSl2肘皿S局.(IFT(】mrc(.1コ.)

GmilU8ir6DjDl0DU 0.6J 、.『] ⑪ぶり

NDrojllUIpPFssMrB』jbg化DDI00.33 I・鞠0.53ル89⑰.J]ルUf●■

NaturaIrllbberwith

5op.p」、、HAFbIackNatuuTalrubbcrwitIU75p.p、h・

fincthermaIbUnck

Kry1enewith5olp、P.}u、HAFblack

1.606.001.766.82】.8J8.97

浬○OIO,Cs空.97J3.OS3.$3J3.70

J.、135.,61.837.5◎空.RIuOIo

P・ユ・ユ

TablelIshowsthatwhilstabrasionisnotstrictlyindepcndentofthccoarscncssof

theabrasive,analmostfivefoldincreaseingrainsizeleadsintheworstcasetonomore

than70%increaseinabrasion

lncontrasttopolyhedralgrains,wearonabrasivesu「faccswhichcanbeapproxim-

atedtoclose-packedspheresshouldbeproportionaltotheg「ainsizc・Sucllabrasivcs

arenotavailablebutToadsurfacesmayfallintothiscategory、AfewexpeTiments

havebeenmadconconcreteroadsofdiffercntrougImessandithasbccnfound】3tllat

inthisspecificinstanceabrasiononacoarsetrackwasalmostfouTtimcshighcrthan

⑪nasmoothertrack・A1thoughitwasnotpossibletomakeaquantitativccomparison

betweenthetworoughnesses,theresultconfirmsthatthelawsolabrasiondepcndin

partonthenatureofthetrack,

Thetestsofthetheoryofintrinsicabrasiondiscussedsofarconcerno】11ytheinflucncc

ofextemalparametersontherateofabrasion・Animportanttcstofanytheorymust

bewhetheritallowstheTelativeintrinsicabrasionTesistancesofamytwocompounds

tobepredictedfromtheiTphysicalproperties・IntbisrespectonIybroadly〔Iualitative

relationshavebeenascertameduptonow.Ithasbeenpointcdoutinscctionlvthat

theoriginalteaTsassumedtobethedominantfactorinabrasionresistanceareducto

tensilefailuTe,Abrasionshouldthereforeincreasewithdecreasingtensilestrength,

Accordingtoeqn.(r7),abrasionshouldalsoincreasewithdecrcasingstifiness・Itis

interestingtonoteinthiscontextthatinempiricalattempts2otocoTrclateab「asion

withphysicalpropertiesithasbeenfoundpossibletoestablishcouTclationequations

ofthetype

け0

晶沙0lIIIIIIIlIIl仏r0IⅡⅡI80IIIII-N切iI0IIIlIIIIIIl脇6

● ̄

■己■

●●

芦靜

’ Ⅱ′=αo+nlxS】loTcluardnesS+、鴬xtcn&i】cHtrcngtlu

where、。,n1anda2areconstants・Statisticalworkofthiskinddocsl1ot,ofcoursc,

involveaphysicalpictuTeoftheabrasionproccss・

庇β/erB0I“sP・ヂJ7

‐・I’11‐‐I‐i-1‐-‐‐‐↑

Page 22: Iit1I - Oita University

00

VOL.’(1057/5s) FIRICTIONANI〕AIlIいSIONOlrl《UlB1BEIR 405

’1

InassessingTelativcabrasionvalucsfr()mtcnsilcstTcngthandstiffness,two(Iuali‐ ficationsmustbetakenintoconsideration.T11(D9itiffncssopcratinginabrasionistbat ofthchiglllyprcstressedtop1ayerwhicl1isl()wcrlhKlntl1atoftl1ebulkmaterial、Second‐

lylbccauseofthesmallscalcoftbeelemcllmry6LI)ruLsio】Iproccsstl1elocalratcsofclong-ationarcvcryhigh・IfforcxamplethcconmcIKlrcaL1〕ctweenabrasivegrainandrubberisaboutl/Ioommindiameter,aslidingvclocil)'()11cm/sccwillgivearateofcxtcnsion‐

to-l)「cakofaboutl()。,()()()%/SCC・Atsuchratc5,tcnsilcstrengthmayapprcciablydilleTlromthatdctcrmincdbyconventionalmctho(1日.GI(1:ENsMITH21hasrecentIystudiedthcwLriatiomoftcnsilcstrengthwithratcolelongationofrubbercompounds

andllasloundtl1attl】ctcnsilestrengthofunfilledGR-Sincrcasespronounccdlywithincrcasingratcofelongation,Thiscompoundoffersthereforeanopportunitytoinves‐

liliWW,11;:11::iIilWlWi臘鰯謡::{!:1噸91.MjWi鶉篭iWWi謡ImcasurcmcntsandGI(EI§NsMITH,sdataarcgivcninFig・エ6.Intheエ,000-fO1drangeof

vclociticscovered,tensilestrengthasfuncti〔》l】ofmte伽andintrinsicabrasionresistance

(asscssedhereasthereciprocalofabradedwciglltforagiventracklengtb)asfunctio11

ofveIocityobeythcsamepowerlawwithintbclimitsofcxperimentale「ro「・Tbisresult

appcarstobcconfirmatoryevidencefortlUccl()HCconncctionbetweentcnsilestrength andintrinsicabl・asion.

11

‐I!■

19町.‐00代Ⅷ

''’ ''1

lil l1:

} M1

q円鳴川Ⅳ仙川悩侶ⅢⅢ叩61旧川叱il0NW川旧・秘○k川肛Ⅲ川Ⅷ川Ⅲ租刈曰旧、ⅡⅡⅢⅢJⅢ小Ⅷn1lIhjⅢⅡ剖咀■■Ⅲ泗旧用Ⅵ91・仙測1Ⅱ四月R川咀叩刊60口Ⅱ別呵?J1心も09860冊J冊凹冊III1Ua囚刎

■。□

Ⅶ.】gmo-帽

「 ̄

EQ且

’’1‐‐‐‐lil l--llFlllll

1.5 1

-06 1.4

/纈鰄i、

三C(7’1.3

1.2

I 1.1

1゜

0 ①--1。 ̄ ̄Br

VeIoこity・CrTySeCRoQeJSeC-0

1『i9.86.Logaritbmo【thcintrimiicabmsionrcsi$tanccinmg-1ploヒヒcdagainstslidingveIocity;andIDg『lritIMno(tcnsiIestrcngtluinkg/cm2lDlcttc(lnK6IilIHtrKltcMelongmtionoianunfiⅡcdGR-SvlIcilni腿61t@.仇uⅡl)oiJ1t5;int「in高ic5ul】「a爵ionrc苛istiuIuc⑭(札「.).1.cI1HilcstrcJ1gtll《IatalTomrcLg8.

VILT11EABIぃ5IIDNlDATT12l《SI

WllenrubbcTisabradedwithoutchangUol【lircction,sctsofpaTaUellidgesareoften

foundontllcsuTfaccoftI1csamplesatrightKuluHlcstothcdircctionofmotionwhicll

R6化rejUcDsP.J'7

・05 ’ ’

-0L6 ○〃〃/

-ロブ

-08 ,'《◎

・09 / ′

-1。

、/ 10~・10~ご10~ロ11010

Page 23: Iit1I - Oita University

$.

ll toI

406 VOL.’(Ⅱ957/58) A・SCIlALLAMACH

havebeencaUed。`abrasionpatterns''18.FourexamplcsaTeshowninFig.r7.These

particularphotographshavebcenobtainedduringcxpcTimcntsca「ricdoutunder

laboTatoryconditionsonactualroadsurfaces,whe「eforreasonstobcdiscusscdpTesent-

1ythephenomenonismorereadilyproducedthanoncommercialabrasives,Another

advantageofwoTkingonroadsurfacesisthattheneedforextractionislargelyobviated

sinceToaddustpreventstheworsteffectsofsmearing・TbcHlctionolthedustisnot

understoodindetailbutappearstobesimjlartotbatofpou】ICC.

●。

1,11111

■■

SAQ

0,▲』一

⑪し。

1選

3筵

●●◆

‐。■ロ■00.■↑-00』■・0086-‐例▽・10●00■0tfq・凸■I▲■Ⅱ■■■■500■■|■□■■ロ

ロ406日■Ⅱ凸■■■■■日■■■■0■■■■■■■■06■5■0V0巳■■■■0h,01■DLdI■■061■■■7071■000口U0l■ら■■■。

pcS

41

1 1・・

pcC

'

Fig.17.AbTasionpatteTnsontwodiflerentcaTbonbIack-IiⅡedvlIlcanizatcsofnaturalrubbe「.

(a)and(c),45P.p,hHAF;(b)and(。),25p・P,11.HAF・TTacks:(a)and(1))`Iiu1ctarmac;(c)and(。),coaTseconcTete,DiTectionofabTasionupward、Magn・IC、Sx.]・■

Fig・エ7exhibitsclcarlytwooftherelevantcharactcristicsofabrasionPatterns・TheirintensityincreaseswithincreasingcoarsenessofthetTack・anditalsoincTeases

withdecTeasingstiffnessofthecompound・Athird,andpossiblVthemostimportantpTopcrtyofabTasionpatternsisthattheyincreascthcrateofab「asion、Thishasbeen

slDownbythefollowingexperiment・Twosamplesoltbcsamecoml)oundwereabradedonthesametrackbutonlvonewasallowedtodevelopapattcrn・Ontheothersample,formationofpatternwaspTeventedbyperiodicallvchangingthcdirectionofabrasion ◆

by,0..Inotherwor〔1s,t]lecomparisonsampleuI1(lcrwcntol】lyintrinsicabTasion、The庇ど/BrBj8ces力.fJ71J

●q-

I ▲.□

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VOL、1(I,57/58) F1《ICTIONANDABIRASI(〕N()1$ItUBBJZR 407

ratesofabrasioninthetwoseriesofmeasurcmcntsareshowninFig、r8aslunction

oftbclcngtlloftheabrasivepath・Asseenfromcurvc(a),thcrateofabrasionatcon‐

stantdirectionincreasesforaconsiderabletinlcbcforebecomingconstantandtlle

patteTnbaslullydevcloped・Inintrinsicabrasion,cuTvc(b),onlylittlechangeoccursin

theinitialstagcsoftheexpeTimcnLandtbefinalvalueoftherateofabrasionislower

thantbatofthcsamp1eonwI1icllapatternllasfo「me。.

`、願、、

2550Z510.0m

Fig.1s.’《iltco【alDr繩ionolaHnunfiⅡcdwIcaMuiimlCuD「lMltouralrllIDbcrplottedagaiJustdistancetnwellc《1.(a),sampIcab「adcdiruconstantdircctioIu;(ID),(Iircctionofabrasionchangedby9ooevery5ocm、Track:siliconcmrbidccloth,Fromref・M1.

■■■■■■■q■NⅡrⅢⅣⅣ■0■■円■、円呵■1■w『】■■■0■■Ⅱ川則mmrJ小出川口500m咀泪泪口■■ずわ■と■』■]■■二m旧■■■■■□■■泪泪■■。』■ロロⅡⅢ00001Ⅱ|■匹円■冊■■■■q口咀■■■0J可■Pb■●■。■■j▽0⑭■■■▽●OHJp宙℃Ⅳ『0000200.トー且ロロロロⅡ■■□幻『

01116,0,。ClリーーロB0II0001I・I‐↓I6I0q0.‐010IIL1.-■。□ⅡⅢ10071,-『0.。●ロリリ-8。。6:■09Iけ’二■

Thcexplanationoftheadditionalwearcausudbyabrasionpatternsemergesfrom am緬mimationofthcirprofiles・Cr・sssectionstllr・ughtwodifferentabrasionpattemsarcrcI)Toducc〔linFig,10andsbow,firstofall,tllatthcphenomenonasitoccuTson

tyresrcscmblcsinallessentialsitslaboratory-producedcounterpart、Thesawteeth

seeninbothp「ofilespointagainstthedirectionoIabrasion,Whenmovingovertrackor road,tIleyarcbentbackward,thusexposingtllcirundersidctoabrasionandprotecting fromabmsionpartofthesurfaceintheirrcar・This・givesrisetothepeculiar``under-cuttingD,effects・TheteethwearprogressivelytIliImcruntilthecrestsarebodilytornofflcavingbluntedges,someofwhicharesccninFig・l9Inthemeantime,theridgescontinuctogrowoutoftheunderlyingbulkmuLtcrialandtllepatternistoaceTtain

degreeself-perpetuating,Whenkeepingapatterl1lM1dcrobservationduringanabrasion experiment,itisfOundthatitmaintainsitsgclluralconfigurationforshorttimesbut movesasawholeacrossthesurfaceinthediructionofabrasion18.Thereasonisthat

theattackoftlueabrasiveontherubberhas,Klsitwcre,aforwardcomponent・BecauseofthegTeatdifferenceinscaIebetwecnthesizeoftheparticlescomingoff

inintrinsicabrasionandthealmostmacroscopicsizeofthecrestsseeninFig.Ⅱ9.the additionalvolumelossduetoabrasionpatternscanconstituteasignificantproportion Jfe化”w6sP、イェフ

」;〕イ■

(b)

/:

〆/-,

E奇E0 3

0 2

0 1

Page 25: Iit1I - Oita University

4o8 VOL.’(1057/58) A・SCHAIIAMACH

ABRASION--

(□) ●

』』

。△

(b) ■。

lSig・’0.IDrofilesolabmsionpatterns:(a),unliIled、'lulcauuizatcolnatmTalrubber・abTadedun〔ler】、6kg/cm2onsiliconcarbidccloth,magn、5×;(b)・woTntyrcslIr【ace、luorizontalmagn3ox・vcrticalmagn.+25×・FTomref、18.

躯騨

oftbetotalabrasivewear・ThiscontributiontoabrasionwiIlbcrcferrcdtoas``patternabrasion,,…

AsdifferentcompQundshavcdiffeTentpropcnSitiestopattcmformation,theTelative abrasionratingofgivenrubbersamplesdePends,intheprcscnceofabmsionpatterns, ontheintensityofthepatterns,andnogenerallyvalidfigurccanbcassignedtoit・ATatingcanbequotedonlyforagive、testorforglvenconditionsofwear,Thisis

cleaTlyshownbytherelativeabrasionfiguresobtainedfoTthetwosamplesshownin Figエ7.TheintTinsicabrasionsofthesecompoundsareverynearlyequalbutonceapattemhasdevelopedonthem,theabrasionofthesoftercompoundishigherthantbe abrasionofthehardeTcompound,asshowninTablellL

b`ID

,⑪。●0-0T‐00▽01■■090●Br。‐。玉ひ』00.9可0●,●0■■■■■■Ⅱ‐05

0b・’0■■T■●▲q0B0JD1■■■|■■■■■日日Ⅱ、■▽●▽。■■■▽GAZ■z05■■■BBB■■|■000◇‐O0L7000■G・qn690q0●.I■

-‐0.0-0□叩印叶いⅡIu0IPI・釦門Zlm●P-‐・わ,‐0-。,

。①

Fdr

B●

丑やむ

TABLEIIl

ltATIo,】N%,oFTHEABRAsIoNoFANATuRALRuEBERcoMPouNDFHLLMDwITH雪5P.】,.】1.HAFmLAcKToABRAsloHoFAcoMPouNDFILLEDwITH45pp.h・HAFBLAcKoNDlFFERENTTRAcKs(sceFig.】7)

●●

SCD

lntrinSicabmEion

FinetaTmac

CoaTseconcrete

】00

】I`1

135

}寵

WithequallydevelopedpatteTns,therelativeratesoIpattemab「asionmaybe expectedtodependonthemechanicalstrengthoftheTubbcr・CompaTisonwithexperi‐mentallydeterminedstrengthdatashouldinpTincipalbeeasieTheTethaninthecase

ofintrinsicabrasionsincethelaTgerscaleofthephenomenonrcducestheratesofstTain byseveralordersofmagnitude・Anexampleofsimilar-sizedpattemsgivingdifferentrelativeratesofpatternabrasionisprovidedbycarbonbIack-fiUedcompoundsof natura1rubberandGR-S・Abrasionpattemsproducedonthesecompoundswhemslidingoverdifferentroadsurfacingsareshowni、Fig.20.Thissctofphotograpbsindicatescertamdifferenccsintheappearanceoftheabradedsurfaceswhichmaybedueto differentmechanismsoffailureoperatingonthetwocompounds. RどんrGD8姥sかギエフ

ごc

Page 26: Iit1I - Oita University

 ̄、

Page 27: Iit1I - Oita University

VOL.I(rO57/58) 410 八.SCHAU-UAMACll

thefollowingconditions.A"simpleextelusion''("trousers'0)l5teartestpiecewasperiod‐ icallyloadedwithanadequateweightuntilthesamplewastornthrough・Thenumber

ofcyclesnecessarytoachievethiswastakentobeameasureofresistancetotearprop-

agation、Thesampleswere1mmthickand254cmwide,tbcweightwas414gand

theperiodoftheloadingcycle0.82sec,Whenstartingtlletear,tbeloadwasapplied

foro、36secduringeachcyclebutthistimedecreasedtoabout0.14secwhentlletear

wascompleted,TableVgivestheresultsobtainedwithtbetwocompoundsrGIerred toinTablelV・Thetotallengthofthetearwasl0.5mm.

TAnlEV

NUMBEROFCVCT-FRTOFAULUREJNTEARPROUDACATION

■「

JVqI■mlmbbFr

ノjlIafUc,iIハゴ0カ.P.A、LLIFCjf-SrバレylBuufノ

ノ川創EDilA5oP.Pハ〃(F

▲4咀已

・1

●q

SamPleNoI 2

COCo

o2つ◎z

(己Ⅱ『IC一

月Jo三BQ)

o(U『Jo

z40Ⅲ4。

4りⅡo

つ』 11

86so 922 、Team

ロ0

らげ

InspiteoftbeconsiderablescatteroftheGR-Svalues,tbcbetterresistancetoteaT‐

propagationofnaturalrubberundertheconditionsofthiscxperimentappearstobe

wellestablished・NogeneTalapplicabilityisclaimedfortlleparticularnumericalvalues

inTableV,butitwillbeseenthattheobserveddiffeTenceinpattemabrasiononnatural

rubberandGR-Scompoundsagreesqualitativelywiththedifferencesinmecllanical

strengtbthougbttogoveTnpatter】labTasion、SimilaTresultshavebcenobtail1edwitll

otheTsyntheticrubbers・

AsimpletheoryofabTasionpattemshasbeendevelopcdinclosccom】cctionwith

thetheoryofintrinsicabrasionl3、Theprofilesofabrasio】】pattcrnssllowninFig、I9

makeitclearthatthephenomenonmustbeginwithpartoftheabradedTubbcrsurfacc

beingpulledoutandelongatedinthediTectionofabrasio】1.Itllasbeensuggeste〔lthat

thisinitialstepisfacilitatedbylipsofthetypeseeninFi9.8(b)whicIla「ethrownup

behindteaTsacrossthetrackofanabrasivegrain・Becauseofinhomogeneitiesoftlle

materialoTbecauseofhig]】pressureexercisedbyexceptionallytallgrains,someofthese

teaTsandlipswillbelargerthantheaverage,Astheabrasivcl1assesoverthelipsand

stTetchesthemouttheywillcoveroneormoretearsinthcirrearandprotectthem

fromfurtherdamagebeforetluelipsretract・ThusalinearpeTiodicstructuTeisinitiated

which,however,doesnotyetconstituteanabrasionpattcmbccauseofthelackof

lateralalignmenLWhenabradedrubbeTsurlacesarecxaminedduTingcarlystages

ofpatterndevelopment,suchincipientformationsaTeindcedobservedassllownin

Fig、2r(a).ThesefragmentaryabrasionpatteTnsmustbccxpcctedtomig「atcacross

thesurfaceinthesamewayascompletepatteTnsbutthcrateofmigrationissubject

torandomeffectsandoccasionallytworidgesegmentscomcabreastandlincupwith

respecttoeachother、Thedevelopmentofthcpatternistllcreforearelativclyslow

process;itsgrowthisillustratedbytberemainingphotographsinFi9.2r・

庇どん”D8ccs力・イェフ

◆・jT|□●d6B▼0■580T0,.0▽040

I GQ●

n℃FJ

■●

q●●

PC■

。P

■U■

11

’ ⑤●

Page 28: Iit1I - Oita University

VOL、1(1057/5s)I?】(IcTIo知wDAIjlい筋l()NoFlRulmIER -1m

JUJIl Fig.■1.DcvcIol)mentofanabrasionpattcrnolU6ulluluuIiIIcdvIlIcanizatcofnatu「alTuubber・Track:g几rnctl》611】c『.'〕jらtmncetravclIed2(a),Igocm;(b),130cm;(c),2+ocm;(。),l3ocm;(e),7二ocm;

撫恩恥1.s×

Forthismechanismtofunction,thesti「[UIC弱oItherubbermustbelowenoughtoallowclongationofsufficicntmagnitudet()《](PcllTun〔lcrthetangentialstrcssproducedbytheasperiticsoftheabrasive・TheorigiI1illll1(〕。ulusoffilledcompoundsofthetyretreadtypeistoohighforthispuTposea】lq1KLpilttcrndevelopsonsucbsamplesonlyaftcrasoftenedtoplayerhasbcencrcatc(11)yI)rc-stressing・Iftherateofabrasionishigh,t11issurfaccskiniswornawayassoIjllKLsformcd,an(litbccomcsdifficultto

produceanabrasionpatternunderthesccollI1itions・TI1ispointisillustratedbyFi9.22.Atypicaltyrctreadcompoundo[naturalrllbl)crwasabradedunderotberwiscidentical

clrcumstancesongarnctandemerypaper・Abrasiononthegarnetbeingrapid,onlyvestigcsofanabTasionl〕atternaTeformed,whereasapronouncedpattemdcvelopsontllcblunteremcrypal)cr・SimilareffectshKlvebeenobscrvcdwhencomparingrubbersurfmccsabradcdonfrcshandrepcatedlyuscdspccimcnsofthcsameabrasivc,This

isals()oneofthercasonswhyabrasionpattcmsIormwithgreatcreasconroadsurfac-

綴uIIillll側:Yb鶏継(,既|h;;::1W;認『鯨蝋…[hmtwh…ridgcsbccomccomparablcinsizcwiththe[limImsionsoftheabrasivCgrain,thesllape

Fig.二苫.SHUTiaccofanatlIr61IrubbervⅡlcaIliz5lt1PIiⅡIF《IwiLlu5oI〕.!〕、lu.’いFbIacI《mbm(le〔l:(a)ongarnetI〕iuper;(b),onemeTyl〕aper,Magn.【o・Bx」dTIjIuDrcI,週2.

尺"Brgjlcどsjb,fJ7

Page 29: Iit1I - Oita University

lli認仮

’ VOL.’(TO57/58) 4画 A・SCHALLAMACII

(a) (b)

Fig.二3.SurfaceofanaturaIrlubbervulcanizatefiⅡedwith5op.p、hHAFl》Iackal〕mdcdongaTnetpaper(aⅢilluminationparaIleltothe【lirectionofabrasion;(b),atriglutimgIcstothedircctionMabTasionMagn・IC×.

1 11 ofthegrainsbecomesimportant、IntIIecaseoffilledrubbcrstlIcrcisatendencyfor

theabrasiveparticlestoploughthroughtberidgesandpToduccscoTingmaTks・Tl1is

effectisshownbythephotographsinFig、z3whicharetwopicturcsofthesameabraded

rubbersuTface;theonlychangemadewhentakingthephotographswastoalterthe

incidenceoftheiuumination、Incase(a),tllelightwasparaIleltothedirectionof

abrasionandshowsupawclldefinedifnotveryintensepattern;i】1case(b),wl1crethc

liglltwasatTightanglestothedirectionofabrasion,onlyscoril1gmarksarcsecn,

Becauseofthelackofcontinuityintheridges,suchapattcrnmaybecalleda``pseudo-

abTasionpatteTn'0.IngeneraLnoscoringma「kscanbediscovcrcdonToad-aI〕Tadedrubbersurfaces・

Inthcprevious1ypublishedtheoryofab「asionpattcms13itbasbecnassumedtllat

theiTspacingdependsonlyonthesizeofthelipsfromwhichtbeyoTiginate・Tllislip

beingsolelydeterminedbytbelengthoftbeteaT,ithasbeemdedllcedthattbesI〕acing

slisgivenbyeqn.(r8):

‘,-…(詩ハツ。 (18)

111

''1

'’ ''’ ''’

1li

Ill l

Iil

ll’

●o

b●

whereγistheradiusofcurvatuTcoftbeabrasivcg「ainatthcpointofcontactan〔M,

thesizeofthegrain・Eqn.(18)hasbeentestedbotbastoloadandgrai昨sizedel)endcncc

byexperimentsonacommercialabrasive(gametpaper)andhasbcenfoundtorcprc‐ senttheexpe「imentalfindingsTemarkablywell、Fig、エフshows,however,thatc〔ln.(18)

willnotadequatelVdescribepatternsproducedonroadsurfaccs・

Thedifferenceinthespacingsofthepatternonthctwocoml)oundsoldilIcrent

stiffnessshowninthisfiguTeislargeTthanpredictedbyc〔1,.(r8)accordingtowlIich

thespacingshouldbeproportionaltotheinversecuberootoftbcmodulus,TIIcratio ofmoduliofthese2mbbersis1.85,givingatheoreticalratioofspacingsequaltoonly

l:Ⅱ.225.ThedifferenceinstiffnessoftheabradedsuTfaccswillactuallybecvcnsmaller

than工.85becauseofpTe-stressingeffects,

ItissuggestedthatonroadsurfacesorgeneTallyonabrasivcswitllgrainsoflarge

radiusofcurvaturetheasperitiesinsteadofcuttingth「oughtheridgcsglideoveTthem

andelongatethembyfriction・ThespacingisthendeteTminedbytheequilibriumof

fTictionalandelasticTestoTingfoTcesJtisshowninthenextsectionthatthefrictional

forceF/ofasphericalgrainwiththediametermisgivenbythec〔luation(20)パノーconsL7`【2(カノE)リ。

庇e/〃β加“sP.“7

qL

11‐

b・下

|■

Page 30: Iit1I - Oita University

1! VOL.I(1057/58) FRIcTIONANl〕AnIい葡I()N()lfItIJllIBl§I《

+13

Assuming,furthermorc,Hooke・slawtohol〔l「urthelocalelongation,thcretractivelo「ccJFrmustbcgivcl1byarclationoftbc「〔Drm

ノア「=c《DnHt.s『Uノゴ

whcrcNisthcsl)acinga11〔い,t1lcdiamctcToltllcarcaolco、tact、Substitutinglor《I「romc(111.(r6)andc(IllatingI7an〔11「,rcsulIsilItllcfollowingexpressionfo「tllespacing:

.-…:鋤(;)り゛,`,lwI)CTO((sthcdiameteroftheclose-packc(ISI)I】cricalabrasivegrains・Thise(luationgivcsastronger〔lcpendenceofthcspKlcingsonbothmodulusandpressurethanc(1m.(r8),butinpracticeitisdiflicultto(1riuwasba「pdivi〔linglinebetweenthetwo91i鱒Qs.;lsissccnfromtheexperimentalrIDHlI1IHgiveninTabIeVI.

TAIlLliVl

SFAClNCSOFAERASIONPA1・TIilRN筍pRODUCEDONTARMAC・

NATURALRUBBmRVULCANIZATI鶴UrILLI§DWUTIlCAIREONBLACK

51nciク09イリDIDクリ

妬ハル「“"化J81

ざゴルPJh.〃・IFJJWルアmJMFD81

f5pP.A、〃`IF ⅡI

Pressure,o,66kg/cm= lnrcs田ure・望.68kg/cm2rP

〔D・当Oo

ID腋17⑪

1.H⑪

Ⅱ、68

雪.2Z

0.Ⅱ55 0.男I之

u、37

Inthistable,「pistlleratiooftbespaciIlg381ttllctwop「essures・ItstheoTeticalvalue

is,accordingtoeqn.(r8),(2.68/0.66)Iノ,=1.5()5,6uldKlccordingtoeqn.(Ⅱ9),(2.68/0.66)ソ, =2.18,TllcratioofthcspacingsonthctwI〕c()mpoundsis妬Assuming,asaguide,thatthcmtioofthemoduliisI.85,'cis,altcTc(111.(I8),(1.85)'/3=L225andafter cqn.(r,),1.351V,=2.604.Itappearsthercforc[romthclimitedexperimentaIevide、Ce

洲鯉IIWA麓麗鰹瞬::1W&鑑|恕:!:;fp……、'm・ItsI}ouI(IlinallybcmcntionedthatabrasionpattcrnscanhaveconsideTablediag-

U1osticvaIuewhendctcrminingthemodcofwcnrtakingplaceu】1derconditionsnotacccssiblcto〔lircctobservation,Thisappli(PslD&lTticularlytotyreswheretl]erelativemotionbctwccntyrcandtrackcanbcde〔111(?,'(1[「omabrasionpattcms23.

V111.FJRICTIONO鷲!((》U〔;llSURITACIZS

AbTasionofrubbeTasenvisagcdinthel)I・['c(DlIil1gsectionsisaconsequenceoflocal lrictionalstressessctupbytheaspcritiesoftlIL9Lmckanddoesnot』incontTasttosolidIriction,reactonthcfrictionalforces・Friction(DnrougllsurfacescantluerefoTebetreatedbymctllodssimilartotl1oseemployed(orlrictiononsmoothsurfaces,without

regardbeingpaidtoanymechanicalfailuTecI1瓢liI1giH1thewakeofthetrackasperities・NocaIculationisnecessarytoseethattllcclDcfficicntoffrictionisloweronarough

thanonasmoothsurfaccbecauseofthesmallcrareaofcontact・ThisisshownbythefollowingdataobtaincdwithanextractGdsamplcofanaturalrubberty「etTeadcom- I)oundongIassgroundwithsiIiconcarbidcofdifferentgrade・ルノPrFJI“sp・ィJ7

、pO

Ill

illlll

Page 31: Iit1I - Oita University

'1 11

' 4Ⅱ4 VOL、1(1057/58) 八.SCHATⅡAMACII

9s〒

5▲

TABLEV11

COEFFlClENToFFHUCTUOlvONCRoUNDcLAsS.(lFromrcI・訓)

Diameterofsilicon

carbidegrainomm CocHicientulfTiction

PIatcglass

望・79

o・oc7

L36

0.oィZ

Ll8

o・Ll【

】.ニロ

Theessentialdifferencebetweenrubberfrictiononsmoothandroughsurfaceslies,

however,intheirloaddependence・The・reasonforthisdivcrgenceistbatoIuarough

trackboththetmeandtheapparentareaofcontactdependontheload,Aquantitative

estimateoftheeffectcanbederivedfromthemodelemployedinthethcOryofintrinsic

abrasion・Thetipsofthetrackasperitiesareagaintakentobesphericalandlargecom‐

paTedwiththerubberasperities、Grossdeformationoftherubberbytluctrackasperities isassumedtoobeyHertz,sequationsforsl〕hericalcontacts,andtbetrucareaofcontact

contributedbyeachTubberasperitytobeproportionalto(ノケノノE)ツ。,whercWistllc localpressure・Thecalculationhastheresultthatthefrictionalforccproduccdbyatrackasperityis

01

毬R毬R

(=o) Fノーヮ(カノE)・ノ.‘1V・洲.▲■■■■、■■■■、■■■■■■■■■■■■■■■■凸P9‐Ⅱ●しけ■6日■、▽.■V6■■PDBB■■■■■・0●0凸0lb■■EDF■q0.6『OS。●0■■ロロ、Ⅱリーーーム■Ⅱワ9009■1■口000■曰Ⅱ‐0●000-‐06‐1-もBGBT000

’。‐095090■■■■0,■■■■■■7600■■■■■■000Ⅱ90■■■■6■■凸■■■■■lUG■0F0.0‐’00001.70↓▲■■■■1010‐II9h0i9I0■■■DllBU■5c●□■0?q・IDし’・B90

D6‐‐‐‐0■。‐ⅢH0●Ⅲp6Lw-0い67.0P’0。‐ⅢIⅡPu刮○』H1‐帆0‐‐’。‐-‐Our‐片‐00口■。‐0-1-09I。‐’90宮98□。.‐‐

可,.●可,.●

and

似一c…農('|`'γ・('/歴1-V. い)の己の己

1 1。

whereristheTadiusofcurvatureanddthesizeofthetTackasperities・Therclation

(21)wasfirstproposedinaslightlydifferentformbyLINcoLN2`、Eqn.(20)hasbeenconfirmedexpeTimentallyl3withanumberofcompoundsat

pressuresuptoabout2.5kg/cm2・Fig.24givesthecoefficientoflrictionofthreedifferentcompoundsonsiliconcarbidepaperatpressuresuptoneaTlylokg/cmaAt higherpressure,eqn.(2r)fails,theCbefficientoffTictiondecrea5ingmorerapidlywith increasingpressurethanpredicted・Thereasonforthisdiscrel〕ancyisinallpTobability

●の

O■。

「.』:詞1

li

;I‐1

、▲-ozOO-ZO40.60.巳1.L

Iogoop ●

Fig・全4.LogaTithmsofcoefficientsoffrictiononsiliconcaTbidcpal〕cr・gra(IcI8o,PlottedagainstlogaTithmofnoTmalpTeSSure.(a),unfilledvuIcanizateofnatural「ubbcr;(b),vlllcanizateolnatuTal rubbcTfiuedwitln5op.p」】・HAFblack;(c),vulcanizateofGR-S(】《「沖、c)liⅡc〔lwith5op.p」u・HAFblack、Velocity,ooo2I2cm/sec、

庇どん”"“s,、イz7

=⑤

・Q2

・0.1 (□)

|::L マーローロ

、一T-g皇----1b)L0.1 ̄へ゜

ぞ-↑:;~--具~

エO  ̄

-04-0200.2OLA0.608-1.0

Page 32: Iit1I - Oita University

VOL.’(Iリ57/58) lPl(ICTIONANl〕AlII(AHIIDN()Iflt【TlBI2ElR+15

ab

Fig.」5.Fricti〔)、;KII()】.c山I1IriIlg月tart(〕(m《〕ljoDll,TIⅢ.【ⅡIuI》Ii仰lqIdP(〕IrtIlccnvcluI)ci叶6Lmca釦lrcofthetHungcntiaIlorcc、NormKlII〕「c錨lurc,u,二SIWじIio笘川`'1.IIIll川(lvluIcmnizatcoIniutⅡralrIIIDber;(b),umtⅡralTlIl〕bcr【ilIc(lwjthうop.p」9.卜いITljlKl〔:1L

fm1mm9、

cd

Fig、33(cい・ulcallimtcoIGR-月(I<rylcnc)fiIlc`lwiLlI5UI'.[)」1.1いFbIacI`;(。昨u鳥(c).blltsampIcloa《I“IwitlI」.」3k円/c、笘lor5miu1utcsIDcforetIMP⑥xlDcrim(Buut・Track:garnetpal)どr,grain5izeo・ユ91mm.

牌turatioIIcffectsimilartothat(lemonstr`llcdinFig、5forthecaseoff]atcontacts.L_a(lditioIltomutualintcrferencebetweelll・uIDburaspcritics,saturatiollcanhcrcbe

produccdbytherubberfillingthegapsbetwccntllctrackasperities(DENNY1o). ItisHlttimesobservedthattheforcencccssarvtostartasampleonaroughtrack

isgreKlturtbant]lefo「ccof(lynamicfriction瓢lIficicI1ttokeepitinmotion・Thispheno-menonof1`startil】gfriction'・hasbeeninveHtigKLtedinanumberofexperiments・Thetimcdcpendenceofthetangentialforcew【lsrCco「dedduringtbcstartingperiod,tlledeflectionofthe(lvnamometerlMwingbeencuI1vcrtcdintotheout-of-balancecurrent

ofa2oo()scc-lalternatingcurrentbridge・RCI〕resentativeTesultsarethcoscillogramsinFi9.25,whichshowtheenvelol〕eoft]1u〕lIt-ol-balancecurrentasfunctionoftime

(fromlefttorigbt).WiththeunfillednHltIlriLlx・ubbcrvulcanizatc(a),thcforcerises monotonouslyuntilthesamplebeginslIDIl1Iwcal1dthcforcebecomcsconstant,but

whentllccompoundisfilledwith5opI)」1.11AITI〕Mck(b)thefrictiomLlforccl〕assest】]TougllKLsligbtmaximllmattllcstart、111iHcllcctismorepronouncedwiththeblack-lillcdGR-Scompound(c).Thetmnsitioll〔romrcsttomotionishereKlccompanicdbyavibmtionwhichtakessometimeto《licout・TheexccssofstartinglrictionoverdynamiclrictioniK)crIjascswiththCtin1ljlhCsamplchasbeenincontactwiththe Eβに”DlpEsP・fJ7

守0

Page 33: Iit1I - Oita University

lll 4m A・SCHAT-1-AMACH VOL.】(r957/58)、ざい

、 ̄

track.Itcanalsobeincreasedbykeepingthesampleunderahigbloadbeforesta「ting theexperiment,asshownbytheoscillogTamFig25(。).TableVIIIgivestypical numericalresults.

) ,、

TABLEVIII

ExCESSOFSTARTI1wGFRIcTlONOvERDYNAMJcFRJCTOONoNGARNETPAPER・GRAlNsIZEo,臼OmmNoTmalpressure,1.28kg/cm2

ら ̄一君

!。

MUf

fub6Fr

”0/dlJcT

M21.rIUbbfr D

JoPp.&.HHjG TA6sdwF,ロルァ

ウol81iPOUIFIdf”loUwl

K〃比DUBD5oPP.A、〃JIF

7”sdUDjJごロα昨「38"iDwoM” 2.二JAHノ「0,82

COD"PoIlDwノ

ロ〃

Excess`% 57.8 ◎ 7.Ⅱ Ⅱ5.5 33.3 114

‐‐-0

iJWl NoticingtheabsenceoftheeffectinuJufillednaturalrubbe「,tlleconclusiondrawn

fromtheseresultsisthatstartingfTictiononroughsurfacesisduetoplasticdeformation

ofthesamplebythetrackasperities,pToducingpermanentset、Atthcbeginningofmovement,workmustbedoneindeformingtheTubberwhichhassaggcddowninto

theintersticesbctwcentrackasperities・Inpractice,stal・tingfrictionwiUbedifficult

todistinguishfromstaticIriction,anditispossiblethatthefinitecoefficientofstatic

frictionatinfinitemormalloadfoundbyRATNERANDSoKoLsI<AYA12isamechanical

hindTanceeffectsimilarincharactertostartingfrictionItisinterestingtonotein

thiscontextthatinarecentpublication2qRATNERANDLjwRENT,Evhaveindel〕en-

dentlydemonstratedthedifferencebetweenstartingfrictionandstaticfriction

Theoccurrenceofstartingfrictionindicatesthepossibilityofanegativcvclocity coefficientofrubberfrictionandcantherefoTeundercertainconditionsinducciL

stabilitiesduringsUding・Stick-slipphenomenaare,infact,oftenencolmteredinfriction

expe「imentswithfilledGR-Scompounds,Startingfrictionmayalsohaveimportant

conscquenceswhenrubberissubjectedtointcrmittentsliding,as,forcxamplc,oIltbe

circumferenceoftyres.

□0泗14●0F05

■△

。△Ⅱ■□、、菫■■■日◆■■■■■■■b■■■■■■■■Ⅱ■■■■■P●0町‐j、●7●■■■■■■■凸■■■0■□0●00.■’000▲U■■且■10。

-艀q臼q臼

の ̄

1X・CONCLUSIONS

TheworkTeportedinthispaperisafirstattempttoelucidatcsomeolthcmostim-

portantfactoTsgoveTningfrictionandabTasionphenomena,VeryideaIizedmodclshad

tobechoseninoTdertoTeducethedifficultiesinberentinthesubjecttomanagcable

proportions,andatbestonlysemi-quantitativeagrecmentbetweeI1theoryandexl〕cri-mentcanbeexpected・Withintheselimits,theassumptionthatlocaIstressconcentra-

tionsproducedbyfrictionaltractionarethecauseofabrasiomhasbeenjustifiedby

theavailableevidence,abTasionthusemergingasapurelymecbanicalproccss,In

comingtothisconclusiontheoriginoffrictionalforceshasbeencomplctclydivorccd

fromabTasionbuttheexistenceofstartingfriction,discussedatthcendofthcIast

section,tbrowsdoubtonthegeneralvalidityofthishypothcsis・Ifmcchanicalcntanglc-

mentcanplayasignificantroleinrubberfriction,effectssimilartothosHeproduced

whenscratchingrubberwithaneedlemaybeofgreateTimportancethanhasbeen

assumedinthepresenttreatmentoftI1esubject・Itshouldalsobementioncdthatno

theoryis,asyet,availableforthemechanismofstaticfriction・

丘e/ergオlcesp.イェフ

▽ bL

◆■-

Page 34: Iit1I - Oita University

。Ⅱ01-0600Ⅱ8FⅡdp9l‐f010h■0■|■7909冊r0ⅡumJ咄■■皿旧Ⅲ□B旬日rDI・日70■■価0砒和・0

VOL.’(Ⅱ957/58) FRICTIOSlANDABRASI()NOFRUBBER 417

ItIIasbeendemonstratedthattherclKLtivewearresistanceofanytwo

compoundsisnotaconstantbutcandependpronouncedlyontheconditionsof

testing・Thisvariabilityisduetothelormationofabrasionpatternswhichdevelopondifferentcompoundswithdifferentintensityandwhosecontributiontothetotal

abrasivcloss〔lcpendsonthemechanicalstrengtlIofthecompound,Abrasionpatterns

arethoughttoinHuencerelativeratesoftyreweaTlmderdifferentconditionsofservice聖

butnospccificreferencehasbeenmadeinthispaI〕crtotyres,forthefollowingreason・

Tyrcwcaroccurswhenthereisrelativemolionintheareaofcontactbetweenthe

circumfcrcnceofthctyreandtheroadandistllcreforeintimatelyconnectedwiththe

mccIMmicsofsIippingwheels・Tllisisatopicofsomecomplexityinvolvingthelarge‐

scaIcelasticpropcrtiesofthewheel,differencesinwhichmayovershadowdifferences

if11鯛、、cabrasionTesistanceofthctyretread・Thcsameconsiderationsapplytoab「asionmachincswbicharcdesignedtoimitateconditionsencounteredbytyresandemp1oy

smallrotatingsamplesundergoingvariousformsofsljpInspiteofitsintricacy,thG

problemisamcnabIctotheoreticalwork81n(181I〕rcliminaryresulthasbeengivenin

an(xurlicrl〕ublication22・Itishopedtoprc3(911t6lII1oreadvancedapproachtoitinthenearluture.

尺EFEノl/idVC〃S

117.P、IBowDENAsIDI〕、TABoR,Frir/ioIoaDIUノ.lrljriWiDlIo/StMjds,OxfordURliv・Press,London,】054.

2F.L・ROTH,R・LDRIscoLLANDW.L・HoLT,ノ.ノイィ.s1.`イ'(・AIjV(I'ABI《「.S/α'o`(MHS,28(19+」)439.3A・SclIALLA3IAcH.」〕roc・PAys・SOC.(Lo9udoI叩.ノノ.“(uリ53)386.811.EwuNG,ノ.Cハcj肌P〃ys・ロイ(1936)2835A・ScllALLAMAcH,TraJls、ノリns/、Rllbberノブ8..,32(Iqj5n)1.1」.‘J・CJAEc囮R,ノ.P'oc・Roy・SDC・NS、1M,76(】⑪I当)2。]7A.ScHALLAMAc1H,P「oc・PAys、SOC.(LoDuapDl),ノノ,65(Iリ5忽)657.8STIMosIlENKoANDjN・GooDuER,丁比oryuノノ:Jlusl化ijy,McGmw-HillBool[Company,NcwYorkpu”1.

01,.THI8GloN,ノfβt'.g`'1.aloouノハ08に,2コ(1046)IOU、

1級:鯛鮒jH`jIf鯛縫(爵'1鰍,:bWiI1リ湖17』‘U2⑤.B・RATN匹RANDMDSoKoLsKAYA・DCハノ《'`イルIAWノ.Mlu0ル5.s.S・尺.,”(u95I)43Ⅱ、l3AScII人LL`wAclLP'0c・PAys・Soc.(LOM。").Im7(lリ5.1)883.MA.ScHALLA]UAcIH、ノ.ルノylllerScj..,(Ⅱ9.2)385.15m5.RlvLINANnA・GTHoMAs,ノPCノy"IDパイf,」('(Ⅱ953)z0L8oL、MuLLINs,ノ.JfMb6pl況必seqrpハ.J6(Ⅱ947)275;ノ.ノ'Ays、GCCノjoidCAel恥,ゴヂ(【950)239.UTL・NluLLINsjwpN.R・ToBIN,Pro広.。「‘RIM'blP’7W川.CuIV.LoMoll,rl54,p,307.IuA・SCIlALLAMACIl・TmllS・mSイ./TlIbbeグノ"。.、28(lリ5二)?50.1,A・SCIいLLAMAcIl,Proc,PAys、SOC.(LoDl`oⅢ),B,“(【953)8【7.20J.M・BuIsTANDO.L・DJwI塵,丁r`1,1s.〃s1.ノfⅢ地rノ”.、空(【946)68.21H、W、GRElZNs3IlTlI,IInpublisluedwork、22A・ScIIALLハMAcHu,KpMfscハllAIu,GlljjMli,Son〔lerluc【t,,arrgi/e00.,(Ⅱ955)色7;R116berC舵,几、1.

7“〃ICノ.,ニワ(uO36)78【、23ME、GoucI1.J.}LlIARD3lANANDRJ・McLMlIfN,711111s・ノ"sノ.ノrl1bberノ'1..,32(Ⅱ956)二7.20A・SCIIALLAMAC】I,パOノノOMjr.,J\』(【955)U65.25n.LlNcoLN,JWllIrc.J72110う3)u60.20s、11.1《ATNl:RANDMV・LAvRENTDEv,DoMM此1A'01/,MJllAS.S、5.J(.,JOB(【956)+61.27W.’[AuzMANN・ノにzノ.JVoderllPAys鯵.J子(894』)、」.

ReceivedDeccmbcT5,Ⅱ957

jll 、!’

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