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仔)3al VOL.!(1957/58) WEAR
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T一坪
FRICTIONANDABRASIONOFRUBBER
A,SCHALLAMACH
TⅡβBriljsハRlJbbBrPron1にers,RBseqrcハAssocm/ioFI`Ireノu,)ノリIQur(ノpIICi/γ(GrFnlBrWjDリ
SmVMARY
●●●●●●●●●●●●●●
Expe「imentaIevidenceisadducedfortheviewthatTubberfrictioni日simiIarincharactcrtovis‐couslIowandthcrc(oreoincontras上tosolidfTictionOnotnecessarilyaccompanic(lbyabrasion・ThistheoryimpIiesthatthefoTcesofTubberfrictionarepToportionaltothetrKUcarcaofcontact・ThetrueaTeaofcontactisdete「mine〔lbyelasticdeformatiouuofthcasperiticsonthcrubbersⅡrfaceowiththeTesultthatAmontonsolawisnotobeyedbyrubber・Thelaw乳ofTubberfricti⑪IMlrc《】e(luccdfTomsimplemodelsandsatisfactoTilyconfirmedbyexpenment.
Ab「aSi6noIrubberiSduetomechanicalfailureundefthetractivestrcSscsproducc(lfrictionally bytheasPeritiesofthetrack、Inthisprocess、certainpeTiodicstructurcsaLrcortcncrcatcdonabraded rubberwhichhavebeencalledooAbTasionPatterns'0.AbrasionpattcruuHaTclouundtoincreasethc rateofabrasiom;adistinctionisthereloremadebetweenopIntrinsicAbrasioIBp,,OCCRuTringimthc absenceofpattemsⅡand,`PattemAbrasion,,、BothtypesofabrasioIuaTctroatc〔ltlhcorcticaIly,andqualitativeagTeementwiththeexperimentalresuItsisobtaincd・ThephenomenonofpatternabTasionhastheimportan上conscquencctlMuttllcrCIativcab「asi⑥n
Tatingofanytwocompoqmdscandependpronouncedlyonthccon〔litiolMmItIuetcst.
ZUSHMMEjVFASSmVC
ExperimenteⅡeGriindewerdenda【iirangefijhTtOdassGummircibM、galsdcnwiskcscnFIicsscuuwcsensiihnlichanzusehenistmnddeswege、OimCegensatzzurfestcnRcibung・nichtnotwendiger-weisemitAbriebvcrbumdenistNachdi⑥serTheoriesin(ldieReiblIngslGTiMtedcsCummisdcAvalBrcn BcriibTungsf1iicheproPoTtioTlal・DiewahreBcriihrtungslliichci5t(lⅡrchoPIastiscI1cDcfornMLtion〔lcrUnebenheitenaufderGummiobeTIlacIlebestimmtpmitdcmErgcbniH.(kus筒GlommiAmoH1tons,GesetznichtfoIgt、DieGesetzederGummireibungwe「denaus⑥iIuIachcJuModeⅡenabgcIeitctundexperimentellzufriedeTlstellendbestiitigt, AbriebentstehtdurChmechaniScllesVersagendesGummisuIuterdenvondenUncbenllcitcn
derSpurdurchReibunghewor摩rufenenZugspannungen・I、【lies⑥mVorgangcntstellcnhiiMiggewiSseperiodischeStTukturen,。i⑥Riffelformationen(abrasionpattcTnS)gcnanntwcrdenEswurdegefundenpdassRiffClfOrmationendieAbTiebs-GeschwindigkcitcrhIihen;eswiTd(IC昌wegenHmterschiedenzwiscben,OeigentlichemAbrieb'oOderauftTitt・wcnnkcincRiffclnentstcllcul,u、〔10,RiffelabTiebo0,Theoretisch6BehandlungbeiderAbriebsartenfiihrtzuqlIalitativerUbereinstim-mungmitdenexperimentellenResultaten.
DieErscheinungderRiffelformationenhatdiewichtigeFolgeo〔lassdierelativcAbTiebszahIzweieTbeliebigenGummimischungenwesentlichvondenVe庵uchsbedingungenabhtingeTlkann.
1.INTRODUCTION
ModernworknonthemechanismofslidingfrictionandfrictionalweaTofsolidshas
broughttolighttheimportantroleplayedintheseproccsscsbythemicrotopography oftherubbingsurfaceswhoseroughnessmakesthetruearcaofcontactsmallandpro‐ duceshighpressureswheretheasperitiesmeet、Undertheinflucnceoftheselocalstresscs, irreversiblejunctionsareformedbetweentherubbingmcmbers,andtIlefrictional workdoneinslidingistheenergynecessaTytobreakthcsejunctions、Tllus,friction
Reにrβ〃CBSかイエ7
385 FRICTIONANDAlM《ASIONOFI(UBBIZI《VOL、1(1957/56)
olsolidsisaconcomitantolabTasion,alM1tllcf「ictio】1allorceisproportionaltotllctrucarUiLofco1Utact・
IJ1contrast,rubbcTlrictionisnotncccssarilvaccompallicdbyabrasion・RoTll,DRIscoLLAN1)HoLT2wcrctlUcfirsttoslM)wtIlatevc1laltcTp「olongcdslidingonI〕Iatc
glassrubbcrsamplcssullernoabrasivcw(`iIr.,I1lcrcisnocvidenceforrubbcTforming irrc《,c「siblcjunctionswitbtrackmatcri;l脂11111c開svcrylliglltemperaturesarcsustaincdduringsliding`andtheoriginofrubbcrlricIioInmlIstl〕csoughtinasourccotherthanthatoISOlidlrictionAsuggestionastoi吟IDrigiIlwiⅡbcmadeinthefollowingsection、
Inspiteoftllisdiflerencebetweenrubbl9rilndsolidlriction,thelineofattackwhich hasprovedsosuccessfulintbetheoryo⑬11i(llrictioncanwithadvantagebebrought tobearonrubbeTfriction・Attentionmu馬LIU【)wcverDbcpaidtothefactthatrubber
鰯erallycxpcricncesfrictionandwearllnlhrcoluditionsdifferentfromthosecomm・nlI1substanccssucl1asmctalsandfibrcs.]《ⅡI〕berhardlyい'erslidesonotherTubber‐
likematerialsbutontTacksgrosslydissinlil8Lrll・omiti】】surfacctexture,chcmicalcon‐stitutionandclasticbcbaviouT,roadsurflcKoHl)(〕ingthcmostobviousandimpoTtant
examples、Itwillbcshowninthesubsc(111《、lltlmgesthattheconceptoflocalstTessconcentrationsjntheareaofcontactbclwtocl1TuI)bcrandtrackgoesalongwayin
accountingfortheobservcdeffects.
11㎡側11畷一口、‐ノ師団、-ノ■巴印11ノ区巴■、1ノーⅢE甲、‐ノさ区『、Iノニ藤Iノ団匹■、-ノ四匹印~ノ四匹■’1ノ必■■1ノ欧底四I”■皿■1/■阯
’-,40.Ⅱ凸■9
FREQUENTLY1J5I2l)SYMBOLS
TruearどiloIC⑪】ltact
LineardimCmsionofabrasivegTain
E1asticmo〔llllusdcfinedbyeqn.(エo)FTictional[orcc
Normalloa(I
NominaIIMDrIMll〕rcssurc
Radiusol(、111.vnturco(asperities
Spacingo「;,l)rilHionl〕atlcrns
TemperatumI、C
Temperatur0・`'K
Slidingvclocily
Abrasionp(Prunitarea Coefficie21to【Iriction
Forcefaclor(l(1Iinedbyeqn.(6)
7
1卸j〃EFLA〃JrQ)ITUⅡβmr
●
綱
U】・VELOClTYANDTEMPERATUl(EDl2lnENDI2NCEOFRUBBE】RFRICTION
DynamicrubberfTictionhasasmallbut〔lclilIitcpositivevelocitycoefficientatlowspeedsIfiTstdemonstratedbyRoTHclnノ.2.TlIisc(fecthastheinterestingconsequence tl1atrubbercanslideonahorizontaltrackatconstantvelocitywhenaconstant
tauUgentialforceisapplied・InthisstateofmotionthetangentialfoTceis,nfcourse,cqualtothcfrictionalforce・TllcvclocitycocfficientbeingsmaU,small diIferencesinthctangcntialforceproducc]argcdifferencesintheslidingvelocity、
AmcasuTiHugmcthodbascdonthiscIfu(B13iHtllercforcvervsensitive,Itisfound
ルル姥"“sノウ・イJ7
”j11j
‐。0ⅢⅢNun■P
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.几・牛。■‐
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OP
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expeTlmel1tally,however,thattheactualslidingbehaviollrofrubberiscoml〕licatcd
bytimeamddistanceeffectswhich,thouglltransient,canconsiderablyrctardattain-
mentofasteadystate、ThisisexemplifiedbyFig、エ.Thcgraphsgivethesliding
velocitiesofanacetone-extractedunfilledvulcanizatcofnaturalrubberonafinely groundg1asstrackattwodifferenttangentialfOrces,thelargerforcehavingbeen
appliedaftertheexpenmentwiththelowerfoTce、Itmaybementionedlleretllatin●
certainmeasurementsitisadvisabletoextractthesamplesinordertopreventcontam-◆
inationofthetTackbyimpuritiesoozingoutofthesamples,Thisprecautionisessen-
tialwhenexperimentsarecarriedoutatvariabletemperature,fortherateatwhich
thccontaminationoccursincreaseswithincreasingtemperature.
T●■
0.2
〈…官u)1
h
ll `1 :I
0.8
'01 05IOI5 DiStanceに、)
Fig.Ⅱ.Slidingvelocityofanacetone-extractedunfiUedvulcaniznteofnaturalrubberonlincly groundglassplottedagainstslidingdistance・Normalload,6.44kg,TangentiaIl⑥TCC:(in).5.Skg;(b),7.Skg・Cu、.e(c):curve(b)TepIottedaslog[u-o・ooo36)cm/SCC]・lFromrcL3.
11
Withapullingforceof5.8kg,theslidingvelocitydecreasesmpidlythroughoutthe experimentandthesampleeventuallystops・Despitetheinitialmotionproducedbyit,5.8kgisobviouslylowerthantheequilibriumfOrceofstaticfriction・Onmcreasingthetangentialforcet07.8kgthesamplestartsanew,slowsdownagainbut,incontrast tothepreviouscase,reachesafinitesteady-statevelocity・WhcntllcwlIuesofthissecondcurvearere-plottedaslog(u-usteadystate)tllestraightlinc(c)jsobtained、TheeffectsillustratedbyFig・エhavetheircounterpartinasloWriscoftllcfrictionalfoTcewhenthesampleismovedatconstantvelocityjaswassllownbyRoTIIpハノノ.2. Thephenomenonappearstobeduetosurfaceconditioningolthcsamplc;onabrasivc trackswherethesurfaceisconstantlyrenewedtheeffectisabsentorverysmalLFor thisreason,mostexperimentalresultshavebeenobtainedonabrasives.S】idingveloc-itiesgiveninthefoUowingtwographs(Figs、2and3)aTeallsteady-statevalues、況歌ycllEes力.乎工7
。?
I
、、
、
、 、
、 、追
(_、 、
( 、b 、
V、~-- 、ミ
K 、
’■。‐峪勺・廿・。Ⅲ卜-6-11Ⅲ?,?‐6肌‐・曲一u69jo印
387 v(Ll('057/58) F1《ICTION3MV1)MIIいSl()NOIF】《UBBIZl(
TllcnlostintCrcstingl〕TOI)crtyolslidingwlDcitiusisthcirl〕ronounccdtcmpcraturc
dCI〕cndcncc、Fig.2givesthelogarithmofthu莇lidilugvclocityonsiliconcarbidcpapcr
oftllcnaturalrubbercompoundTefcrrcdtoi】lIrig・rasfunctionofthereciprocalab‐
solutetcmpcrature,thetangemtialforcebeingIllul〕aramcter・Tllecurvescanbeap‐
proximatc〔Itostraightlinesandbedescribc(lI1yc(luation(1)
[,Cl,,Isl6lIItIor“=..!'cxl)(-ノゴ'ノノ17.)(【)
where.{’andE'arcconstants・
Theforccdcpendenceofthcslidingvelocityc8u】bcdcrivcdfromthecurvesofFig、Z
byinterpolation,thcresultbeingshowninFig._ルDefiningstaticfrictionasthatvalue
oIthctangentialforceatwhichthevelocityapI)roacheszero,afigureofabout5kgis
obtai、cdforslidingonsilicoLcarbidccloth・Atforcesaboveabout7kg,thecurves
arc縄lrlystraiglltlincsoindicatingthatancxponcntialrelationbctwcenslidingveloc‐ityandlrictionalforceobtainsatsufficicntlyhighdTaggingforces・
Eqn.(Ⅱ)isstronglyreminiscentoftherelationbetweenfluidityandtemperature
observedinviscousflowandalsoinotherphenomenagenerallyreferTedtoasrate
processes・Intheseprocesses,theelementaryparticle,orcomplexofparticlesinvolved
intl1cprocessarctlloughttobeconfinedtopotentialwellsofdepthE’fromwhich
fi、:、!!
い,.■O0p0p■□●Dq0C0B・■■▽己■■■9■●●90●■■□G1Ⅱ■ワ0.06‐⑪。。‐‐。
0ヶ.600派Ⅱい‐いIⅢ噸○M、?‐胡,川L』、叩1..口’□い●小口ひ0‐f11hrL河。、-,,ⅡⅢⅡⅢ‐ケーコ啼川ⅢⅢ化肝p“Ⅲ肌Mn川
0
-1
j8g05I◆●
一…:
2
』
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一
11
-3
-4
、46810
kg
10.iH.』、筒lc6MIy-statcsIidingvclociticsattwoIuIDu1DcrautuTegouusiliconcarbideclothplottcd ;lgHuinsttangentiaMorce・DataderivcdfromFig・色.FTomrCf、3.
IOy7(7,.K)
Fig.」.:tCady-己tmt⑪slidingvelocityoIannCc-tonc・cxtractcdllnfilledvul画nizateofnatural
rubbeTon$iliconcarbideclothplottedagainst reciprocaliubsolutetcmpemturcforvarioustan-gcntialIorCCS・Normalload,6.44kg・Fromref3.
Eどん"'IC“カィJ7
L〆
許
illll ℃
40 ソ /
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。L■ロ0■旧■0■■■■0ⅡⅡ164
JSS VOL.’(Ⅱ957/58) A、3CllALLAMACll
tbcycancscapeonlywhentlleyattainthrouglutIUeTmalcollisionkincticcnergycqual to,orexcecdingE'・TherateoftllejumpsisproportionaltothcBoltzmannfactor
e~EYRT.lntheabsenceofextemalstress,thedirectionofcscapcismndombutan applicdstresstendstodirectthejumpsinsucI1awayastorclicvctIIcstress・
Ithasbeensuggested3thatinfTictionalslidingofTubbertl1cmolecuIarforceficlds olTubberandtTackinterlockatthctrueareaofcontact,similartothcintcraction
bctwcenparal1elmolecularlayersinlaminarviscousflow,6m(lt1lattl1cfrictionalforce
ofrubberisakintoviscousforces・Nobreakingofmolccularboll〔lsandtbcrcforcl1o
frictionalwearneedbeiiWokedtoaccountforthefrictionalforccinthispicturc、TbcstrcssdepcndcnccoftlMBslidingvelocitysbowninFig・J511ggcststI】atrul〕1〕cr
frictionresemblesnon-NewtonianratherthanNewtonianflowintl1attllcvclocityis notproportionaltotbetangentialstress、FollowingEYRINco,thiseffectisthoughtto beduetoamo〔lificationoftheintermolecularfieldbytllcl8lrgctalugcntialstresscsoccurriI1ginrubberfrictionwhicheffectivelylowcrtl1ecncrgybarricrsurroundingtllc potentialwcll・IntheregionwheretllclogaritllmoftheslidiI1gvelocityisproportionaltothetangentialforce,theresultsshowninFigs・zand3canbccxprcssc〔lbyc(111.(2):
、=UOeXlD-(母一γF)ノノf】.(」)
whereuoandγareconstants,EnistlleactivationenergyimdF`tIlclrictio1mllorcc・Tllcexperimentallydeterminedactivatio11energicsarclリ,8s()cal/molclOrsli(li11gon groundglassandI6,160cal/moleonsiliconcarbidc・Itisintcrcstingto1lotcthattlIcactivationenergyfordielectricrelaxationhastIIesimiIaTvilIlIcofal〕out17,()〔)〔)cal/mole,suggestingthatthemovingcomplexcsarcoftllesamcordcrolmagnitudciIu tbetwoprocesses・
Thetemperaturecoefficientoft]uefrictionalfo「ccaLsdcrivU(lf「omc(111.(2)istllc1l givenbyeqn(3):
…ルー-;'・壇ヂI31Tlliscoefficientisalwaysnegativebecauseoftllcllighvalucof7ぃvllicll,Klscstim8Ltc〔l
lromFig、2,amountstoIo13cm/sec*.
Ⅲ.
lIliII!
i■ !.
*TIoePlDysicaIsignificanceof〃oisasIollows:lfAisthelengthoftIHejumpe型ecutedbythemovimgcompIcxcsaItc「3ⅡCCC汁邑fuliLctiviLtiun,tIwn
pノスisthetransitionrateA・whichmaYbewrittenasEB-yF
A=Aoexp--- 尺丁
AcCordingtotbcru〔limentm『ytheorylinedoutaboveDAosbo811〔IbctIocI・Cl⑬'6hntvibmtiuIMll[rc-qllencyofthemoI・ingcomplexes、WithIo-7cmasalikelyvall8coljLAoisIo2og⑪c-lwhichisclcarly toohiglubymanyoT【IersofmagnitudeforthisinterpretationtobcwLIi(LTl0claTgcvallIc⑪[ACnnbeaccoMntedfoT⑪nthebasisofatheowduetoEYRuNc・wluicIoc。nsi〔IC厩anctiwLtioninlDh>・昂icalprocessesasacluemicalreaction4・Inthistheory‘dueconsiderationiHgivcntotlucI6LctthdLttIlcnumberoIcomplexeshavingatanytimetheactiwLtiouucncrgyEhi&、《Dts(DlclylD『(〕IDorti⑥naItiDtIucBoltzmanuuIacto「exp-EbノノピTbutisa】soproportionaItotIuemtioofthcooIuluubcru化itcsavaiILul〕IctoactivatedcompIexestotluenlImberofsitesattluedispo&alofll【)tiLctMhtcqlcolllIDIcxes・lro「tlli3rcascnotheconstantAoisactuuaIIytl1epro(lluctofthcvibrationlrcqHIcncvKMU(ItlucTaLtiUo【帥tu島iluC
tIuctwo苗tatcs、ThisratioisintroduucedinEYRINc・stlueo「ya5cxl〕`:1sノルJSi田cHlⅡu(lcuutr⑪IDyufactiwution・AlmrgeAoaccordinglyindicatesthattherenremanymurclDu餅siblc臼itc団hr8LctivHltcdthanIornotactivatedcomplcxes・Tl】ispointhdlsbecIldisclIsscdin(化tioiIbyl《八uz31ANN笛7.ルノBrBDlpBsp・イエフ
*
380 VOL、1(1057/5N) 】F1(ICTlONANDAIBIいSI()N(〕IFI《UBlB)ZR
WorkoIuthい'clocitydcl〕⑥】】(IcnccofrubbcrlTicliu】1901mrrcfcrredtohasbcuJ1carric〔loutatvelociticsnotexcccdingabOutlcm/SCC・WithI1ighcrvelocities,slidingat
constaJlttangentialforccbccomesunstable,I〕「[・HlIIuMLblybecauscofthetempeTatuTcriscdllctodissipationoIfTictionalcnergy・ItIlIlPIlID19comcsncccssaTytoreversctllc
tecll】】i(luea1】dmcasuTcfrictionalforcesatl)「'0瓢9riI)cdvclocitics・ExperimcntslMwcbcc】1carricdoutwhicllalIowcdtlUcfTictionKlllL.、I)cr6LturcTisctobcmeasuTedattllc
samctimc5・Tllcsli(lcrwasatllcrmocouplegiviI1KH1gcomctTiccontactareaofabout
lmm曾wllichwasprcsscdagainstarotatingrII1’1)c『(lisc・Figs.+(a)and(b)givethcrcsuItsobtail1c〔lona】11mfilledandacarbonbl81clK-IilIc(lcoml〕oundof、naturalrubbcr,
ItwiIlbcsccllthattllcinitialincrcascoftllcco(91(icic】ILoffrictio】1witl1incrcnsi】ngvcloc‐
ityisnotmaintaincdatI1igllcrspeedsbutgivcHwitytoagraLdualdecrcase・Tllcloa〔ldcl〕cndcnccoftI1ecocfficicntoffrictionmadcい'i〔lclutintIlescgrapluswillbctrcatcdindctailinlatcrscctions・
TI】eco11sidcrablctcml〕craturcTiscisal〕proxim6Ltclyl〕roI〕ortioI1altot】uesquarcroot
orthcvclocity・ThisdcI〕cndcncehasbccnl)rcdic(c〔lulcorcticaIlybyJAI2Gl§l《`forvcry
lliglwclocitybutal〕pcaTstobcvalidforawidcrr61U1gctllangivenbyJAEGElt`st1)cory、ItciLl1bcsluowntllatt1lcobscm'cddccrcascI〕Itllccocfficicntoffrictiomat】ligbcr
vcIociticsagrccs(lu8lIitativclywithtllctllc()Ty《'「1.111〕1)crfrictioD1exp「csscdbyc(1,.(2)iIaⅡowiLl1cci田mHM1《PfortllcsimultaH1coll5化l1lll(、r8lturcrisc・Thccomparisomcanbc
oI〕ly《llIKlIitdlIivcbせじ&Luscitisncccssarytocxlr6I1)()l8Ltcfromrc5ultsobtai】lcdatvcloc‐itic3bClowlcm/scctovclociticsrcaching-l《〕IlclI1/sじc、Assumingtllatthetcmpcraturc
riSc()bcystIlcTUlation
Jノーハノii (4)
'
DUI
I9B0 91‐
91‐I
suggc筋(c〔11〕Vtl1ccxl,crinlcI1talc、.i〔lence,iIIl(I別11)s1illltingcqn.(4)ineqn.(2),t]〕e ̄
IrictioIl6Llforcci息givc】11)yu(11】.(5):
γノー鷹"-'f(7,,MV可'`'8ヂ (5)
whcrc7bisroomlcml)crilturcintllcabsolutc蔦c6Ilc・Tllcshapcolthecurvcpredicted
l)yc〔IHI.(5)issllownillFig.」(c),whicbhasbcc11cillclllKltcdwiththefolIowil1gnumeTicalvalues:E〃=20,()o(〕cal/molc,To=30()。K,r=5(l〔1Kcm~lscclandl'0=エol3cmscc-1・TIDiscum・ercproduccstllcsalientfeaturcsolllIc⑪l〕erimentalcurves,anditappcaTs
tIlHlttllcdecrcascofthccoefficicntoffTictioIUwi(Ilincrcasingvelocitycan1argelybe
attributcdtothcfrictiomaltcmperaturcri5c.
Ni
111.LOA】)、EIC】2N、】:NC)§OFlRUBBI§I(】了[《lCTl(〕NONSMOOTHSURFACES
Tllcviuwsolltllc】1aturcofrubbcrfrictionI〕lItlorwardintbeprccedingsectionimply
tIMlttl】clTictiol1allorccisI)rol)ortionaltotIlctrucarc&lofcontacM,andthusconform
witIlllDU1IIcoryoIsolidfrictio】Ibricflyr□.iいⅦ(lintllclNTItoDucTIoN,Thefrictional
lorccノ『脂dlccordinglygivcnbyc(111(6)
盃=リ、...l (6)
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Fig.4.FrictionaltempcTatqDTerisc・fIノ組ndcccflicientso(frictionノ41〕lottcdng81illstsli《lingvcIocity(a),onanunIilIedvulcanizateofnatluralrubber;(b),onanatuuTalTml〕bcrtyrctTcadcompoIundfiⅡedwith45p・P.h・MPCblack,TheaveTagenormalloads(glaregiveninbrackcts.(c),thcorcticalvelocitydependenceoftbcfrictionalforce,calculatedfromeqn.(5)C「apIIs(a)and(b)l「om「c『、5.
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VOL.!([057/58) F】(ICTIONjWDAllIぃH1()NOFItUIBBI2I《 301
11
anditwillbcassumedthatvelocityandtclⅡl)crKuturceIfcctsmvolveonlytheforce
factoT9D、Intheabsenceofayieldpressurc,itisnotadmissibletoputApropoTtional totllcIIormalload,asisdoncinthetheoryofsolidfrictionwberesllapeandsizeof
thcsurfaccaspcriticsareimmateriaLAnassumptionhastbereforetobemadeabout
tl1caspe「itiesonrubbersurfaceswhicbisc(m《lucivetotreatmentbytheoryormodel
cxpcrimentwitI1outbcingtoofar-Ietchcd、FroIuIbothpointsofviewitisadvantageous toiLl)proximatethcTubbersurfacctoana「「;l)'()IiLlcntical,closclyspaccdhemispheres
ofr51dius'7.ThismodelismeanttoapplynIllytoconventionalIymouldedsamples・ Itisfurtherassumedthattheelasticbellavi()llroftllcrubbercan,forthestrainsoc-
curring]1ercJbcdescribedbyasingleelasticc《DIlHt:111tEwllicbwiUbedefinedpresently,
ItfollowsfromdimensionalconsiderationstllmIIIlctruearcaofcontactwithanideally
snIm熟、thplaneundcrthcnominalpressure′mustobeyarclationoftheform
、イーグ:ど`bIWE)p'‘ (7)
、
、
-0や8△|■廿廿Ⅱ01巳81■0106■□09口q箔010B・DC・・10-・己■BJq
.■●7-‐
’○伯ロロⅥ□Ⅱ山一叩ⅡⅢ印叩肌止ⅢⅢ0仇l川ⅡいⅢ小10041’w・旧0忠’■・P』DhuJJ研Ⅱ
wherethec'sandβ'sareconstants、Aplottじdagainst(》/E)shouldyieldauniversal
curveforrubbersofdifferentstiffness,TIlec()efficientoffrictionderivedfromeqns.
(6)and(7)is:
浜=wEどclJwE)p'0-1 (8)
:…!!
andnolongercontail1stllcradiusγoftIlcaspcritics,
Modelexperimentsontbecompressionofla「gehcmisphcres7haveshownthatthc
rcsultslitquitcaccumte】ythce(luation〆
孝l=c⑪n筋t、/W3 (9)
Tllissimplerelatio11agrecswiththcthcorcticalexpressionderivedbyHERTz8from
classicalelasticitytl1coryforsphericalcontacts,e(1,.(r(〕)
(#、$!、
』-(誌,)シ,(1.1wIlcnthePoisson
l2〔1,.(Iu)willbc
Thccocfficient
ratiol1astllevalue&a1,1J「()l1riiLtcforrubl〕cr・Listhenormalload・uscdtodcIinctbceffMiwIllodIlIuSE・
offrictionresultingfrolII,’''''3.(H)and(9)isthcn:
/8=(WlI)(/'ノノ!)-V, (皿) q
whercnumericalconstantsllavebeenal〕H[)「|)(DIliI1thc「actor9D、ThcasperitiesonTubbersurfacesare,11(DwIwcr,notisolatedanddonotdeformin-
dcpcndentlyfromcachothcrbutwillj【)篇tい'筒tlIeVbarrcloutduringcompression、
Tlliswillcausedcl〕Klrtu「cfromc(1,.(11),I)M1Il)illHmorcI〕ronouncedastl】eloadin-
crcas(Dsa】1〔ltbcasl)criticsHLrcsqucczcdjlll()i1部)lidl〕l〔)ckprcsenti】lgacoI1tactarca
(ICPじ、〔IingonlyIittlcoD1tbeloa〔LThissc(Iuじ11c(、()lい'cntsllasbccI1followcdbymcamsofasccondmodclcxl〕c「imcntinwI1icI1as(Io18llmP5巴tDf25smallllemisphercswascom-
pressedunder・varinbleload・Fig.5showstIlL:cIDntKlctarcasunder3differentpressuresna化〃"“3,.ダエァ ニリーー00.
蝋L■割。■I.
voL1(Ⅱ057/58) A・SCHALLAMACH 302
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②懲鯵⑲鰯
船側船側鮒⑨鐘鰯④愚
ab.c
Fig.5.ContactaTeaofmodelrubbeTsKDrlaccunder3dillercntl〕rcssonTcs:(a).色.Ⅱ4kg/cm2;(b),7.75kg/cm2;(c),66..kg/cmg・Rcducedo85x.
■◆■
の●■』
anddemonstratesllowtheasperitiesatfirstdeformwithoutmutllalintcrlerenccias
isseenfromthecircuIaTshapeoftheircontactareas,butatl1igl)erloadscloscupfinally
intoablunteds〔luarepatternwithlittlespaceleftintheinteTstices・TI1caTcasof
contactunderthcvariousloadshavebeenmeasurcd」usingonlythcimUerOhcmispheres
astbeouterhemispheresaresubjecttoendeffects、Tl1eareasodctermincd,whcndivid‐
edbythenormalloadandmultip1iodwit11thceffectivcmodulusEofthcmodcl, E
shouldaccordingtoeqn(8)representauniversalcuWeoIthcproduct(テノ`)when plottedagainst(,/E).ThiscurveisshowninthelogaritllmicplotofFi9.6.Atvalues
ofけ/E)lowerthano、エ,thecuTvehasbeencontinuedasstraightlineofslopc-J/3
wellestablishedbytl1cmodelexperimentswithlaTgesingle】lcmisphcTes,Tl】ispTessuTc
regionmaybecalIedHertzianregionincontrasttothesaturationrangeathigher
pressures・
TheexpeTiTnentalpointsmarkedinFig.6havebeenobtainedonplateglasstracks,
■ ▲、Ⅱ
け▽■0
9■P6L■0●■■‐OG■■■■■■0509869.0566
ロケ■
-1.0 エ
ミレ。
。 □、
0.5
0.0
-OS
~~a。‐1.5‐I。‐0.50,.9,。÷CLSFig.6.LoaddependcnccofthecoefficientofrubbcrlrictiononpIategIass、Fl8111inc:tlhcorcticalcuTvedeterminedbymeansoIeqn.(】Ⅱ)andthcmodclexperimcntofl7i9.5.AtoD.《l)'namicfrjctionato、oo2I6cm/sec、E,staticlTictionVa]uesIorAtoDITomrcL7・foTEIromrcf、0.
ルル”"“s力.“7
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。、、へも父
l'
VOL.’(1957/58) ITRICTIONANDAlIIいHIlINOIrlRUBBER 393
wllichmaybeconsideredideallysmoot1lc()n1IDarcdwiththeTubber,andshowthe
cxtcntolagrcemcntwiththesimplctheorylin【!(loutabovc・Themeasurementscarried
outwithcompoundsAtoDwercdetermin8Lti(DIlH(〕Itl)ccocfficientOfdynamicfriction,
theonlyarbitraryconstantusedinfittiIlgI11じpDi】ItstothGcurvcbeingtllcforce
constantP.TablelgivesdetailsofEand帆.
16
OO
TAMI」11
ノハハRmOUz o,Ag/rUjJ2 a00IPo8fルイ『、、
9仏
I11
luu1rillc〔lnatlumIrlubl〕cx・
unfillc〔lnatQu「a1rubbcr
lD11lille(111atluralrubber
UUatumIrlII〕l)crIiⅡc〔I
witl1うCl〕.P」】、1-いFblacIに
11.8H
18.3 』().0
,,,I
ABCl
{J望0戸
◎lP1
q■℃
P99の』Ⅱ
ll M
il
・11.0 IC・47 」彌鰄、
ThevaluesforcompoundEarecoefficientsoIstaticfrictionreplottedfromacurve
givcnbyTIIrRIoN,、Inthiscase,themoduluswasnotknownandhadtobeadjusted togivcbestfit・Tbcprcssurescmployedillt]lcdyl1amicfrictionexperimentswcre
notlargccB1oughtobringmutualintcrfcrcncc(〕ltllcaspcritiesintoplayandcovGr
onlytl1cHcrtzianrange・Thctheoryisobcy('1111(’1℃untillowvaluesof(カノE)arcreachcdwhcrctllccoefliciel】toffrictio1waTicslcsHwiⅡ11M)TmaIloadtha】1cxpccted・TIllRIoN,s
staticfrictionvaluesreachwellintothesatur;LIi〔)nrangeandagreewiththetheoretical
cu「vc,I-IiglIcrprcssuresllavebcencmp10yc〔11)yl北NNY1o,w1】oinvcstigatedthcfrictionoIanumberofcompouJldsonpolishedstcc11111〕ricatcdwitholiveoiLHisrcsultsare
giveninFi9.7andshowthatatlargeno「mall[DHL(1sUlccoeffici(mtoffrictionisnca「ly invcrsclyproportionaltothepressurG`inagTじじmcntwitllFig、6..
DENNYfittedhisresultstothecmpiTicalc(111.(T2)tIIctypcofwhichhadfirstl〕eGn
suggestcdbyTlllRIoND:
鰊】"』」-,+[swAi,)(』贄)
!
⑪。心00
llBPd■■Ⅱ▽6.ローマP■■0‐0』可
面剋
◇勺p●■0dB口・OC0Pjp・一
pPI
p・。
IIlj
IoP4 Io-。 lo-z IO-I Io p/gb
Fig・7.CoclIicientsof〔lvnamicfrictiononpolis1Ic《IHLcuIIlobricatedwitholiveoi]・FuUcurvecal-び
cll1atedfromcqn・(【。)・FiguresmaTl[edagainstc〔)10,1〕oⅡ、〔lsarcBSllardncsSes・VelocitVo・oYcm/sec・FrOmTeflD. ̄
庇e/β搾りICBS力.¥エア
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VOL、1(1957/58) 八.SCHATエAMACII394 ~チョ
レ‐
whereAisamaterialconstant(nottheareaofcontact1)andEo,thccompressionmodulus・
Accordingtoeqn.(エ2)thecoefficientoffrictionbecomescoI1stantatlowpressurcs、
Aseriousdeparturefromthetheoryontheloaddepcndenceofrubbcrlrictionas
representedbythefullcurveinFig、OoccursthereforeoI1Iyatlowloads,Itissuggestcd
thatthisdiscrepanCyarisesfromthefactthatrubberasperities,eveni(theycanbe
approximatedtohemispheres,arenotidenticalbutstatisticallydistributedinsize・
TheinHuenceofthisinhomogeneitywiUbemostpronouncedatlownormalloadswI1en
onlytIlelargeraspeTitiesareincontactWiththetrackbecausconincrcasingtheload thetrueareaofcontactincreasesatagreaterratethanwitIlidenticalasperities・A
quantitativeestimateofthiseffectcanbeobtainedbyassumingthattheradiioftl】e
asperitieshaveadistributionfunction/(i')。'becomingzeroforamaximumradius
γ,,!“・Atlowpressure,whereonlythelargestasperitiesareinvolved,thedistribution
functioncanbereplacedbyitstangent,say
丑一・=
一過】
/(r)`l′=conSt.(7,Mm-γ)〔lr ('3)
Assuming,fUrthermore,thevalidityofHERTz,sequationsbothforaTeaofcontactand
compressionofhemispheres,thecalculationhastheresultthat ’0
so
/JloWWEノーCOnSt,け/万)-V, (】4) 11
0’100
81■●
ARcIIARD]lhascarriedoutasimnarcalculation,makingtheassumptionthatthe
asperitiesareidenticalhemispheresevenlydistributedondiffCrentlevels・Thecoeffi-
cientoffrictionisinthiscaseproportionaltop-nA.Itwillbeseenthereforethatany
inbomogeneityoftherubbersuTfacetendstoreducethepressuredependenceofthc
coefficientoffriction・Itshouldalsobeborneinmindthatmacroscopicallyimperlcct
contactbetweenrubberandtrack,whichmayeasilyoccuTundcrlowloads,willaffect
thefrictionalbehaviourinasimilarway・Thisproblemwillbediscusscdinmo「edetail
whendealingwithfrictiononroughsurfaces・
RATNERANDSoKoLsKAvAユ2havesuggestedthefollowingscmi-empiricalrelation betweenthecoefficientofstaticrubberfrictionandJlormalloadL:
ijl l:I
一宇
・11 61
●の
謝
浜-浬.。+」/LA (Ⅱ5)
whereAand/Jooarematerialconstants,andハistheShorehardnessdividedbymo,
Atlowloads,eqn.(r5)givesaloaddependencedifficulttodistinguishexperimentally
fromthatgivenbyeqn.(I4),butathigherloadseqn.(I5)yields,whenplottedlogarith‐
mically,acurveconvexagainstthelogL-axis,Inthisessemtialrespect,RATNERAND
SoKoLsKAYADsresultsdifferfromthoseobtainedbyTHIRION,DENNYandtheauthor・
Thedivergenceisconnectedwiththepostulationofafinitecoefficie、toffrictionノJco atinfiniteload,putforwardbyRATNERANDSoKoLsKAY八.Weshallreturntothis
point-attheendofsection8・
況伊化”'jcGs沙.\'7勺今
勺吊
v(L1('リ57/58) 151《IC・I・【()SIASII)AIllぃHII0N()lFI《11ⅡIlIil8 .)OS
1V・STI《liHsC()NCI2NTIい゛rI()N§()N】(ulllBlil(Sul(IFAC】§S
WlM1「ul)bcl・sli〔IcsovcrKlsurlKlccwitbasl〕(91.iIil9HcomI)ariLblcto,orla「gCrtllKmtlIosc
(DlltllcrlIbIxP「10cKllstrcssconccntratio11§811.Cl)1.【、(IIIC[(16111(laI〕raHioI1cnsuc目、11】t「cKltiI1K
lMiIll8utt(・「,81(liIIicultyalriHじHontDltllc(;r(q81い・61「i(、tyillHlIillxP8ul(lH11arl)Iwsi局()ltll,‘
ILHI)uritic乳l(〕l〕ccxpect⑯〔1011(lillcrc1】ttrackHJIlKcIl(?「;11,onlyHnmⅡareas()ftIlcaspcritics
wiⅡiml〕iIlgc《)llthcrubl〕cr・Itiskllowl1Ir()IlwDli(1KじQmctrytllatasmallrcgi(〕n1ofal1y
coIltimMjlls5urI81ccca11I〕cal〕l)roximatc〔1t()ilnlPⅡiI)馬0i〔1.EmployingasI〕Ilcrcasm()(lcl
iLsI〕eritywoⅡ1(1tlluTcforcU1otscriouslyresIri(:(KlOII《、rality・WhcntI1cloa〔loncachKlsper‐
ityis篇()11iglltI1atpllncturcoraI〕prccial山1)ullI、lr8ltiol1()IthcrⅡ1〕bcroccllT,acone
nlaybccll(〕scnasrcl〕rescntativcaspe「ity・
FoⅡowiI1gsIlcllconsidcratio】1s,mo〔lcluxl〕(・I・iIn⑪11⑬llavcl)cenmadcinwhicllrubbcr
surfaccswcrcscmtchcdbyasmallluemisplM)r1,13(1mm(liam.)andbyanee(Ilel4under
co榊Icdc`’11【litiol鳩.Provi鼠ionwasalsom:MIMI〕rrcCDrdingtI1cinstantancollSt「activoYorL-j.
I2x81ml)lcHo(trKlccs]cItl)ytllcl〕llIntl)()iI11()Iltw〔)〔1i「hrcntcompou】1〔lsa「csllowl)
inFig.8.Thesepbotogmphshavel〕eentakl・nwiI11ol)Iiquciuuminatiol1fromtllcright‐
1Mm(lside;thedirectionofslidingisdowlIw6l「(I.()nthesofteroftherubberslUardly
aI1ysur(ace〔lamagciscreatedundcraloa(l()に59(、)butunder8()gadiscontil1uous
traccispToducc〔lconsistiJIgoflateraltc81rHilUl・(〕:bithetrack,oIleofwhicbisseenin
Fig.H(b).Fig.8(c),Bbowi】1gtllcsamct「acUiltl('wCrmagnification,dcmonstmtcstlle
pUrio(licI1aturcofthc瓢lrlacc〔IamagcwIlicIlIl6L:bccl1attributedtoastick-slipmccIl‐
al1iHm・ThcruI〕I〕crKhdhcrcsIrictionaⅡytotllUhcmisI〕hcricalpointal】dislocalIy
tcasedoutiI1tl)cdirectionofslidinguntiltllcelasticrestoringforceexceedslimiting
Irictionandthcrubborsnal)sback、Tllctracconthehardercompound,Fig.8(d),is
similarintypcbuttllctearsarcshallowcI・’1cHBrcgularandmoreclqselysl〕aced・It
lMIsnotbccUlI)ossiblctol)『o〔luccsignificanいllrfKlcc〔lamagconcarbonさloa〔lcdtyrc
t「cKLdcoml〕oundsundcrthcconditionsoftIlcHCcxl)erimcnts.
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lri8、8.Tracc局(、IalDlooIutlDointmovingdownwaTdontwounfilIcdvulcanizatesofnaturalruUbbcrwitlutlDcfoll`〕wingmo(llIIi:(a>,(I〕)an〔l(c),J【、5kg/cm理;((1),Y8.3kg/cmg.Normalloa〔lsandmagni〃cati()ns:(a),乞59,3()×;(b)’8o9,3o×;(c)8og,uox;(。),8o9,3oXPllotograpIls(c)and(。)fromTcLl。.
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Thcst「CSS(listributionpToducingtcarslikl9tlIoscshowninFi9.811asI〕ccnstu(licd
byilwcstigatingphoto-elasticallythestrcss《畷iLroun(lthcareaofcolltactintllc2-(limcnsionKLlanalogo】1,cmployingacyliI1(lrM1Hli〔IcrontrKmspa「entrubbcrl3、ThoTcsultisshowninFig.,(a).ItwiUbeseclltlMlttlleTcisastrcssconccntTationatthc rearolthearcaofcontact,asindicatedbythcclosespacingoftheisochromaticsin
thatregion・Tbisstressconcentration,occurrillgnearafreesurface,mustbepredom-
inantlytcnsileincharacter・AnyfailuredllUtofrictionalstresswouldtheTeforebcexpectedtoconsistinopeningoftcar:bcIlindtheslideratrightanglestothe directionofsliding,asconfirmcdbytheexl)crimcntalevidence・
ThestrcssdistributionofFig.,(a)conformsqualitativelytoclassicaltheoTy・In
plancstrainalineforceactingunderanyanglconthesurfaceofasemi-infinitcsolid
l繩ICC…11「CmdialSt『essdist『ibution、
10,0‐r
0-
筋〃』
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0
c
ユー宛一一⑪』
汀wllcrcOisthedistancefromtbcpointofal)l〕licationandOistheanglcbctwcenQandtllcloadLThclincsofe(IualstressarecirclessymmetricaltoLandpassingthrough
tllcI)ointofapl)lication・Fig.0(b)reproducesthisstressdistributionloracoefficient
()flrictionof2;thereisastrikingsimilaritybetweenFigs.O(a)and(b). WIlctllc「tbestrcssconcentrationbcl1in〔ltlucsliderreachesacriticalvalucornot
(1Cl]Cl】(1s,othcTthingsbcingcqual,onth〔91》11Ⅱ[(ICformationproducedbytheslidcr,
tlUatistosay,onthcrclativcmagnitudc(〕Ilri(9ti(DlMul(lstilfncss、Thismayconvcni(mtly
bccxprcsscdbyt1lcratio0D/だ、Thcabsc1lCl9n(tl1arsfromthetraccofthcbluntpoint
o】Itllcstilftyrctrcadsamplcisthere[()run(Dlncc(jssarilyductoanysuperiorityin
八ilc圏trclIgtllovcrthatofapurcguml)utmayrcsultf「omitshighcrmodulus・Wllcnrubberisscratchedwithance(ⅡCIIlllctmctiveforcesarelargert]Ianinthe
casco(abluntpointbccausco【mecl1anic811l・Ill8M1glcmelltbetweenrubbcral1dneedle・
Animl〕ortantconscquenccofthisdiffuTLPncI2i時tllfltsurfaccdamagecausc。')ytlle
needlecanbemoreseverethanblunt-1)oiIlldamageandleadtoactualdctachment
ofrubbcrI)articles;thatistosay,tlIencC〔ⅡL1calncflcctprimitiveabrasioninitsfirst
l〕assageovcrtherubberandthereforetak心(11(Bsurfacedamageonestepfartherthan
thCbluntpoint・WhetherthisoccursorIl()l〔ICI)cI1dSonthcmechanicalst「engthof
tbccompound・
Ancc〔llctraLceoI1thcsofterofthetwollIl[iⅡlxlvulcal】izatesofFig、8,sllownin
l7ig.r(〕(a),isverysimilartothatleftbytlMl1)Iulltl〕oint;thetearresistanceofthis
coml)oundisquitchighandamountsto7・r21Wcmasdefi】IedbyRIvLINANDTHoMAsl5・
ThcharderunfilledvulcanizateofFig.8((1)1M鴫tl】clowertearresistanceof456kg/cm;
assccnfromFig・I0(b)theneedleheretc8lrsoutclongatedgrooves,thetracegiving
theimpressionofanincipientscdringmn「k・Tl1cf()rmationofthcsegroovcsisexplainedbytllcskctchinFig・TI・Thefamilvofcllrvu筋馴l(lwnareoriginallyequidistantrefcrcnce
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二■ 二》二▲{二⑤←
Fig.】o・Needletraceson3diflerBntvu】canizatesofnaturalrubber.(a).unfilled.E=ⅡⅡ.5kg/cm2,】oad8og`magn、13×;(b),unfilled,E=18.3kg/cm2,load5og,ma9,.3o×;(cMilledwith5opp.h、MPCblack,load8og,magn、3o×・Photographs(a)and(b)Iromrefl6.
linesmarkedonthesurfaceoftherubberatrightanglestothedirectionofmotion・
Theirsubsequentdistortionindicatesthestraindistributionaroundtheentangled
needle・A1thoughthestressconcentrationishighestinfTontoftheneedle,no
cuttingoccursherebecausefailureispreventedbyfrictionaladherenceaTound thecircumferenceoftheneedle・Therubbertcarsinsteadwhereitfirstloses
contactwiththeneedle,thetearsproceedingroughlyatrightanglestomaximum
stress,alongthedottedUnesAftertheneedlehaspassedandtherubberrelaxes,
thereg1onaroundthetearstuTnsbackthroughalmost9ooandtbusgivcsrisetothe
gToovesseeninFi9.IC(b).Itmaybementionedinpassingtbattbisinterpretationof
needletracesprovidesalsothereasonwhyitisdifficult,ifnotimpossible,tocutsoft
Tubbercleanlywithadryknifeblade
TheneedletraceonareinforcedcompoundshowninFig.(IOC)differsfromall
bih10D0BP△■■■■P■■q■■■U0■0巴。。’a免押0.6■.■・■●7011.●.p90■■■■▽0.‐9-0.0
■Iu0■■■|■■■■■■:■■■Ⅱ■■■■■■■■■p0D92■■■■Ⅱ■10-010■0▽■■010000410Il5IP6
I‐。‐|’00.9,06リ’0‐◆0100..Ⅲlu1‐’-4▲▼。■■、■■■00
1 f’
I ご§§ 6
E二塾
Fig.、LDiagTammaticTepresentationoftwostagesinthedeformationofarubbersurlacebyaneedle・TheshadedciTcleisthecross-sectionofthemeedle・
Rc化”"“s力.“7
0凸
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il
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othcrtraccsinbcingcol)timlousbuti葛otllcrWiHI:馬inlil8LI・lotluatSIIowninFig.r()(b).ItlMlsbccnpointedoutintIlcoriginalpublicati()IoIItIMltaI1cedletracewillbecontinu‐
ouswl1enthcTatioofelastictofrictionallorco9scxcccdsacertaincriticalvaluc、
TlIccxccl〕tionalbchaviourofreinforccdrlII)I)urbothwithregardtoblunt-pointan〔ltollcc(llctraccshasbccIIattributedtotheirgrcatcrstiffmess・Itwould,however,beprcmaturctodmwconclusionsfTomthcscnM)(1clcxperimentsastotheabrasionrc‐
sistallccofIiⅡcdrubbじ「5.Thcrcasonwhytbcrc篇lo1tscaImotbcappIicdwit1Doutp「ovisoswiⅡbcdiscussc〔lintIUefolIowingsection.
0006,60
1F. ,E
OO
Iri
ll O V・TIlESURFACECONDITIONOFABIいIllil)、!『lLLlZD】《UBBERCOMIDOUNDS
a紐溢il;P鯛}磯臓墓嚇;師W:W:lfi艦:搬弧鯛騨filler,mostoftl1estiffeningislostbypreviousdMormation、Thephenomenonhasbeen studiedbyMuLLINs16andmoreTecentlybyMuLLINsANDToBINl7・Onceafilled
comI〕oundhasbeenpre-stressed,itsmodulusisIowerthanthatofthevirginmateriaIatallstresseslowerthanthepre-stress・The8lbsolutcvaIueofthemodulusandthe
stress-straincurvcofpre-stressedfilledrubberresemblethoseofunfilledrather
thanIilledcompounds,Ifthcabrasionprocessgocshand-in-handwiththecontinuous
productionofIargelocalstressesofthekindsugRcstcdbythescratchingexperiments, thcUffcctivestiffnessofthesurfaceoffilledrubbc「ssIlouldbeaffectedinasimilarway・Ithasthereforebeenassumed18thattbesurlaccofabradedfilledrubbeTcompounds iscovcredbyathin,constantlyrenewedskillthcclasticpropertiesofwbicharenot matcriaⅡydiffcrcntfromthoseofunfiIlcdvlI1ciLIlimtes・Forthisreason,itwouldnotbcappropriatctoequatethestiffnesseffectivcintheabrasionmechanismwiththe
conventiomallydeterminedstiffnessoffresh§amples・
TlIecxistenccoItllctoplayeronabradcds81mplesbasbeendemonstratedbymeans W鰻Merprc-strcssingphenomenonwbicIlijlcarbonblack-filledcompoundsrunspamⅡelwiththesofteningeffect・Black-filll9《IC〔Dmpoundswhennewhavearelativelylowclectricalresistancewhichhowever,incrtP815csTapidlyondeformation・Thiseffect
l】asbccnintcrprctcdasbeingduetothebrciI1《(l(jwIUoIanoriginalIyexistingcarboLblackstructure・Tllepostulatedsoftskino】1Klb「HMlcdblack-filledrubbersshouldtherc-
forealsobedistinguishedbyhighelectricalrcsistance、Experimentsmhavebeenmade inwhichbothnewandabradedsamplesslidovcrasmoothmetaltrackwhilstthe
resistancebetweentrackandsamp1ewasdetermined・Theresultofmeasurements
carriedoutwithatypicaltyretreadcompou】I(lofnaturalrubberfilledwith5opp.h・olHAFblackattwolow-fre〔luencyalternaIillgvoltagcsisshowninFig.r2,whereimpedanceisgivenasfunctionoftheslidillgtiII】c・TheimpedanceofthenewsamplerisessharplyonsettingtheapparatusinmotiuIMLndTcachesasteady-statevalueabout Iourtimeshigherthantheoriginalfigure・Tbじrcisnosignificantdifferencebetween
tlleimpedancesatthetwodifferentfrequcllcics・Afterabrasion,theimpedancehasbccomclrequency-dependentanditsequilibriumvaluehas,comparedwitllthe Ireshsample,risenabout6、Stimcsatエエoscc-1,andabout26timesat2rsec-1,彫化「6,8CCS力.チェア I
lIlii
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P4◇-F■■ロ■■B■bUAU●J0■■■■■■■DqCUrP■60■■▼05。■60□■1人■■00と■DPF●LIB▲■6.00■00■-0。Ⅱ!●・9.0
6.。‐。0.00I。16l0Bロ一・・・6口●.■b‐01710680‐■9■080.0◆・・可0-0
0■9or’00‐■‐巾■。‐COロ.
Fig.Ⅱ色・ImpedancechaTlgesduringslidingofacaTbonblack-fiuedJMutRIraImbbcTvhuIcanizate
PlottedagainstslidiTlgtime.(a),newsample;(b)and(c),⑬bradedsamplGVelocity,o・oq1I6c/sec・FromTefl9.
幹,■閂'
TheinitialincreaseoftheimpedanceofthefreshsampLisduetodeformationof
therubberasperitieswhichaTeshearedduringsliding・Thefrequency-dependeJIceoftheimpedanceafterabrasionindicatesthatthecurrentthroughthesamplehasalarge capacitivecomponent・TheinteTpretationofthisresultisthatstructurebreakdown
inthesurfacelayerhasgonesofarthatthefiUerpartic1esarealmostcomp】etelyisolatedfromeachother・Thelayerhas,forpracticalpurposes,becomeadielectric・Thatthis
effectisreaUyduetochangesinthesurfaceandnotinthebulkolthesamplccanbe showninthefollowingway・
If,insteadofapp1yinganalternatingvoltage,adirectvoltageisconnectedacross thesample,thedirectcurrentvoltagedropisconcentratedinthesurfaceskinand, thelayerbeingthin,shouldproduceahighelectricfieldstrength・This,initstum, shouldgiveTisetoelectrostaticattractionbetweGnsampleandtTack,incrcasethe normalloadandthereforealsothefrictionalforce・Thisexpectationhasbeenborne
outbyexpenmentascanbeseeninFig・ェ3Moderatevoltagcssufficetoincreasethe●
frictionalforceconsiderably,thusgivingindependentproofo(the・cxistenccofan
inhomogeneouslayerontopofthesample・ThetimeeffcctssllowninFig・ェ3arediscussedintheoriginalpublication,
AnestimateforthethicknessofthelayeTcanbeobtaincdfromtheincreaseinfTic-
"β/βγ…BSP¥'7
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(`識、,、MinuLeS△09.K3.Thceffectofd.c,potentialsonthe(rictiUDnnlforceofanabraded・caTbonblack-loaded sampIe・Abscissa,sIidingtime,FTomrcflo.
tionalforceundertheinfluenceoftheappliedd.c、potentiaIdifferenceifanassumption ismadeonthedielectricconstantofthelayer、Thecalculationhasshownthatthe
ordcrofmagnitudcofthelayerislo-2cm.
VLINTRINSICAI9RASION
Tojudgefromtheprecedingsection,nodistinctionneedbemadebetweenfilled
andunfiIlcdrubbersifapictureoftheab「a5ioD]mechanismisdeducedfromourscratch-
ingexpcrimcnts、Thcqualitativediffercnccinsurfaccdamageonfilledandunfilled compoundsobservedduringthatinvestigationcanbeatt「ibutedtothefactthatit
wascarricdoutwithsampleswhicllhadundCrgonenoprc-stressingeflects・
御earingtllcscconsiderationsinmmd,atheoryofabmsionl3haSbeenbuiltupon[IleresultsillustratedbyFig8・IthasbeenassumedthattearsacrossthepathoftrackasperitiesaTethefiTstand,attlucsKlluI(Btime,「ate-determiningstageintI1eabra-sionproccss,tbedctachmemtoftheabm(l(P(11)Klrticleduringsubsequentpassesofthe abrasiveoverthetearbeinggoverncdbyKLmcchanismsimilartothatdiscussedin
conncctionwitllFig・rr・ThevolumeoIlIlcabradedpaTticlehasbeentakentobe
proportionaltotI1ecubeofthelengtholtIlcoTigimaltears・Inspectionofthephoto‐graphsinFig,sindicatesthattheseteKmmrcofthesameoTderofmagnitudeastl1e widthofthetrace,Ithasthereforebecna雛umcdthatlengtlloftearanddiameteroftbearcaofcontactareproportionaltoe8Ldl()Ihersothatitonlyremainstodetermine thcarcaofcontactundcrvariousconditiuIls・ModelcxperimentsinwhichanumberofcompoundslMwebeenindentedbyalargL9爵l〕IICrchavesbownthatthediameterofcontactnfoIlowstoagoodapproximatiol1lhccllbcrootlaw
D■0口。し
0白・BCqP▲■■■■0ⅡⅡq・I・‐●6↑■0■00
,fP7 Q。
、=cuu腺Lクリ、 (Ⅱ6)
whicI111asalsobcenlbundvalidforthccoIIIID1℃&sionofrubbcrspheTes,Itfollowsfrom ルル施川“5カ.“7
240V 。、 / ̄
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eqn.(エ6)anddimensionalconsiderationsthattheabrasivewcarIl'pcrunitarcaof
sampleshouldbegivenbyeqn.(r7):
W-colust.γ(,/E) (】7)
whereγistheradiusofcurvatureatthetipoftlIeabrasivcgrain,Accordingtoc(ln`(I7),
rubberabrasionshouldincreaselineaT1ywithincreasingnoTmaIload,
WhenattemptingtoverifyexperimeiitallyatheoreticaIloaddepcndenceofTubbeT
abrasion,caremustbetakentoavoidcontaminationofthetrackbyimpuritiesissuing
fromtheTubber,Asinthecaseoffrictionexpenmentsprcviouslyreferredto,thiscan
beachievedbyacetone-extractionofthesamples・TheerraticnatureoftI1eresults
obtainedotherwiseisiUustratedbyFig.r4.Twotyretreadsamplesofnaturalrubber
oneofwhichhadbeenextractedjwererepeatedlyabradedeachonitsowntrackof
6ocmlengthUnderaloadof2.r4kg,themteofabrasionoftheextTactedsamplere‐
mainedreasonablyconstantbuttherateofthenot-extractedsampledecreasedsteadily
tovelylowva1ues・ThetrackbecameprogressivelydaTkerintheprocess・Underthehigherloadof8・I4kgOtherateofabrasionoftheextractedsampledecTeasedsIiglltlybuttheabrasionofthenot-extractedsamplei"〃Base‘considerably,whilstagradllal
■否
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Fig.】4.VariationsintherateofabrasionoIanot-extractedandancxtTnctcdnatu「aIrubben,IDI ̄canizatefilledwith5op・P.h・MpCblackwhenusingrcPcatedlytIBcsamcsiliconcarbidct「ack(Icngtlu160cm).
尺どん”〃“s少・“7
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clcaringofthistrackwasobserved・InthM8Ltt⑥I・casetl】esampleappearedtofuI1ctionlikearubbereraser・Ingeneral,ithasbcc】11(〕uI1dthatcontaminationofthctrack
becomesprogressivelymoreseriouswith〔lccru81singrateofabrasion・ItalsotcndstobemoretroublesomewithsyntheficthanwithnKltumlrubbcr・
ThercsultsgiveninFig、r5l1avebeenobtdlinu〔lwithflatextractedandvacuum-dried
samplcsonfreshabrasive(GaTnetpaperwitlMLmcallgrainsizeofo、エ3mm).Further-
more,thedirectionofabrasionwasreve「slxl81ncrc8lcllTunof64cminordertoprevent theformationofso-calledabrasionpatterjlswhicharethesubjectofthefollowing section・AbrasiontakingplaceunderthcseconditioJ1swiUbeca11ed‘`intrinsic,,abra-
sionFig・エ5showsthattheproportionaliIyofintrinsicabrasionandnormalloadgivenbyeqn.(r7)isconfirmedbyexperimc1It.
00
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伊
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Fig.Ⅱ5.IntrinsicabrasioTlplottedagainstnoTmalI1rc錨lIrc,Compounds:A,KryIene(・・Coldrubber,,)fiⅡedwitlu5op.p、h・HAFbIack;BtoD・natuTHuITllbI】cTIilledwith:B,5op・P.h・HAFblack;C075p.p、h・fincthc「maIblack;、,I3op・ph・PKltljluHon`sactivatcdCaCO3・Velocity,o、66cm/sec,Fromrcf.nコ.
I Eqn.([7)predictsalsothatabrasionshouldbcproportionaltotheradiusofcurvatureof
tllcgrainbutindcpendentofitssize、Twodistinctpossibilitiesarisehere・InthecaseofRりん形"“s力.乎'7
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polyhedralgrainsofdifferentgradethereisnoaレアjoγjreasonw]lytI1eslla「pnessofthe cornersshouldbeaffectedbytheiTsizesothatabrasiomshouldbcindependentofthe
coarsenessoftheabrasiveThisconclusionhasbeentestedbycarryingoutabrasion experimentsongaTnetpapersofdiffeTentgTades;tHeresultisgiveninTablelL ●●
~ ̄ワー
TABLE’’
八m】RASION】NJO-3Cm3/m,cm:ONCAR】VETFAP正ROFDII;【『HRENTCOARSl2肘皿S局.(IFT(】mrc(.1コ.)
GmilU8ir6DjDl0DU 0.6J 、.『] ⑪ぶり
NDrojllUIpPFssMrB』jbg化DDI00.33 I・鞠0.53ル89⑰.J]ルUf●■
NaturaIrllbberwith
5op.p」、、HAFbIackNatuuTalrubbcrwitIU75p.p、h・
fincthermaIbUnck
Kry1enewith5olp、P.}u、HAFblack
1.606.001.766.82】.8J8.97
浬○OIO,Cs空.97J3.OS3.$3J3.70
J.、135.,61.837.5◎空.RIuOIo
P・ユ・ユ
TablelIshowsthatwhilstabrasionisnotstrictlyindepcndentofthccoarscncssof
theabrasive,analmostfivefoldincreaseingrainsizeleadsintheworstcasetonomore
than70%increaseinabrasion
lncontrasttopolyhedralgrains,wearonabrasivesu「faccswhichcanbeapproxim-
atedtoclose-packedspheresshouldbeproportionaltotheg「ainsizc・Sucllabrasivcs
arenotavailablebutToadsurfacesmayfallintothiscategory、AfewexpeTiments
havebeenmadconconcreteroadsofdiffercntrougImessandithasbccnfound】3tllat
inthisspecificinstanceabrasiononacoarsetrackwasalmostfouTtimcshighcrthan
⑪nasmoothertrack・A1thoughitwasnotpossibletomakeaquantitativccomparison
betweenthetworoughnesses,theresultconfirmsthatthelawsolabrasiondepcndin
partonthenatureofthetrack,
Thetestsofthetheoryofintrinsicabrasiondiscussedsofarconcerno】11ytheinflucncc
ofextemalparametersontherateofabrasion・Animportanttcstofanytheorymust
bewhetheritallowstheTelativeintrinsicabrasionTesistancesofamytwocompounds
tobepredictedfromtheiTphysicalproperties・IntbisrespectonIybroadly〔Iualitative
relationshavebeenascertameduptonow.Ithasbeenpointcdoutinscctionlvthat
theoriginalteaTsassumedtobethedominantfactorinabrasionresistanceareducto
tensilefailuTe,Abrasionshouldthereforeincreasewithdecreasingtensilestrength,
Accordingtoeqn.(r7),abrasionshouldalsoincreasewithdecrcasingstifiness・Itis
interestingtonoteinthiscontextthatinempiricalattempts2otocoTrclateab「asion
withphysicalpropertiesithasbeenfoundpossibletoestablishcouTclationequations
ofthetype
◆
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芦靜
’ Ⅱ′=αo+nlxS】loTcluardnesS+、鴬xtcn&i】cHtrcngtlu
where、。,n1anda2areconstants・Statisticalworkofthiskinddocsl1ot,ofcoursc,
involveaphysicalpictuTeoftheabrasionproccss・
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InassessingTelativcabrasionvalucsfr()mtcnsilcstTcngthandstiffness,two(Iuali‐ ficationsmustbetakenintoconsideration.T11(D9itiffncssopcratinginabrasionistbat ofthchiglllyprcstressedtop1ayerwhicl1isl()wcrlhKlntl1atoftl1ebulkmaterial、Second‐
lylbccauseofthesmallscalcoftbeelemcllmry6LI)ruLsio】Iproccsstl1elocalratcsofclong-ationarcvcryhigh・IfforcxamplethcconmcIKlrcaL1〕ctweenabrasivegrainandrubberisaboutl/Ioommindiameter,aslidingvclocil)'()11cm/sccwillgivearateofcxtcnsion‐
to-l)「cakofaboutl()。,()()()%/SCC・Atsuchratc5,tcnsilcstrengthmayapprcciablydilleTlromthatdctcrmincdbyconventionalmctho(1日.GI(1:ENsMITH21hasrecentIystudiedthcwLriatiomoftcnsilcstrengthwithratcolelongationofrubbercompounds
andllasloundtl1attl】ctcnsilestrengthofunfilledGR-Sincrcasespronounccdlywithincrcasingratcofelongation,Thiscompoundoffersthereforeanopportunitytoinves‐
liliWW,11;:11::iIilWlWi臘鰯謡::{!:1噸91.MjWi鶉篭iWWi謡ImcasurcmcntsandGI(EI§NsMITH,sdataarcgivcninFig・エ6.Intheエ,000-fO1drangeof
vclociticscovered,tensilestrengthasfuncti〔》l】ofmte伽andintrinsicabrasionresistance
(asscssedhereasthereciprocalofabradedwciglltforagiventracklengtb)asfunctio11
ofveIocityobeythcsamepowerlawwithintbclimitsofcxperimentale「ro「・Tbisresult
appcarstobcconfirmatoryevidencefortlUccl()HCconncctionbetweentcnsilestrength andintrinsicabl・asion.
11
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1『i9.86.Logaritbmo【thcintrimiicabmsionrcsi$tanccinmg-1ploヒヒcdagainstslidingveIocity;andIDg『lritIMno(tcnsiIestrcngtluinkg/cm2lDlcttc(lnK6IilIHtrKltcMelongmtionoianunfiⅡcdGR-SvlIcilni腿61t@.仇uⅡl)oiJ1t5;int「in高ic5ul】「a爵ionrc苛istiuIuc⑭(札「.).1.cI1HilcstrcJ1gtll《IatalTomrcLg8.
VILT11EABIぃ5IIDNlDATT12l《SI
WllenrubbcTisabradedwithoutchangUol【lircction,sctsofpaTaUellidgesareoften
foundontllcsuTfaccoftI1csamplesatrightKuluHlcstothcdircctionofmotionwhicll
R6化rejUcDsP.J'7
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406 VOL.’(Ⅱ957/58) A・SCIlALLAMACH
havebeencaUed。`abrasionpatterns''18.FourexamplcsaTeshowninFig.r7.These
particularphotographshavebcenobtainedduringcxpcTimcntsca「ricdoutunder
laboTatoryconditionsonactualroadsurfaces,whe「eforreasonstobcdiscusscdpTesent-
1ythephenomenonismorereadilyproducedthanoncommercialabrasives,Another
advantageofwoTkingonroadsurfacesisthattheneedforextractionislargelyobviated
sinceToaddustpreventstheworsteffectsofsmearing・TbcHlctionolthedustisnot
understoodindetailbutappearstobesimjlartotbatofpou】ICC.
 ̄
●。
1,11111
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ロ406日■Ⅱ凸■■■■■日■■■■0■■■■■■■■06■5■0V0巳■■■■0h,01■DLdI■■061■■■7071■000口U0l■ら■■■。
pcS
41
1 1・・
pcC
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Fig.17.AbTasionpatteTnsontwodiflerentcaTbonbIack-IiⅡedvlIlcanizatcsofnaturalrubbe「.
(a)and(c),45P.p,hHAF;(b)and(。),25p・P,11.HAF・TTacks:(a)and(1))`Iiu1ctarmac;(c)and(。),coaTseconcTete,DiTectionofabTasionupward、Magn・IC、Sx.]・■
Fig・エ7exhibitsclcarlytwooftherelevantcharactcristicsofabrasionPatterns・TheirintensityincreaseswithincreasingcoarsenessofthetTack・anditalsoincTeases
withdecTeasingstiffnessofthecompound・Athird,andpossiblVthemostimportantpTopcrtyofabTasionpatternsisthattheyincreascthcrateofab「asion、Thishasbeen
slDownbythefollowingexperiment・Twosamplesoltbcsamecoml)oundwereabradedonthesametrackbutonlvonewasallowedtodevelopapattcrn・Ontheothersample,formationofpatternwaspTeventedbyperiodicallvchangingthcdirectionofabrasion ◆
by,0..Inotherwor〔1s,t]lecomparisonsampleuI1(lcrwcntol】lyintrinsicabTasion、The庇ど/BrBj8ces力.fJ71J
●q-
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VOL、1(I,57/58) F1《ICTIONANDABIRASI(〕N()1$ItUBBJZR 407
ratesofabrasioninthetwoseriesofmeasurcmcntsareshowninFig、r8aslunction
oftbclcngtlloftheabrasivepath・Asseenfromcurvc(a),thcrateofabrasionatcon‐
stantdirectionincreasesforaconsiderabletinlcbcforebecomingconstantandtlle
patteTnbaslullydevcloped・Inintrinsicabrasion,cuTvc(b),onlylittlechangeoccursin
theinitialstagcsoftheexpeTimcnLandtbefinalvalueoftherateofabrasionislower
thantbatofthcsamp1eonwI1icllapatternllasfo「me。.
`、願、、
2550Z510.0m
Fig.1s.’《iltco【alDr繩ionolaHnunfiⅡcdwIcaMuiimlCuD「lMltouralrllIDbcrplottedagaiJustdistancetnwellc《1.(a),sampIcab「adcdiruconstantdircctioIu;(ID),(Iircctionofabrasionchangedby9ooevery5ocm、Track:siliconcmrbidccloth,Fromref・M1.
■■■■■■■q■NⅡrⅢⅣⅣ■0■■円■、円呵■1■w『】■■■0■■Ⅱ川則mmrJ小出川口500m咀泪泪口■■ずわ■と■』■]■■二m旧■■■■■□■■泪泪■■。』■ロロⅡⅢ00001Ⅱ|■匹円■冊■■■■q口咀■■■0J可■Pb■●■。■■j▽0⑭■■■▽●OHJp宙℃Ⅳ『0000200.トー且ロロロロⅡ■■□幻『
01116,0,。ClリーーロB0II0001I・I‐↓I6I0q0.‐010IIL1.-■。□ⅡⅢ10071,-『0.。●ロリリ-8。。6:■09Iけ’二■
Thcexplanationoftheadditionalwearcausudbyabrasionpatternsemergesfrom am緬mimationofthcirprofiles・Cr・sssectionstllr・ughtwodifferentabrasionpattemsarcrcI)Toducc〔linFig,10andsbow,firstofall,tllatthcphenomenonasitoccuTson
tyresrcscmblcsinallessentialsitslaboratory-producedcounterpart、Thesawteeth
seeninbothp「ofilespointagainstthedirectionoIabrasion,Whenmovingovertrackor road,tIleyarcbentbackward,thusexposingtllcirundersidctoabrasionandprotecting fromabmsionpartofthesurfaceintheirrcar・This・givesrisetothepeculiar``under-cuttingD,effects・TheteethwearprogressivelytIliImcruntilthecrestsarebodilytornofflcavingbluntedges,someofwhicharesccninFig・l9Inthemeantime,theridgescontinuctogrowoutoftheunderlyingbulkmuLtcrialandtllepatternistoaceTtain
degreeself-perpetuating,Whenkeepingapatterl1lM1dcrobservationduringanabrasion experiment,itisfOundthatitmaintainsitsgclluralconfigurationforshorttimesbut movesasawholeacrossthesurfaceinthediructionofabrasion18.Thereasonisthat
theattackoftlueabrasiveontherubberhas,Klsitwcre,aforwardcomponent・BecauseofthegTeatdifferenceinscaIebetwecnthesizeoftheparticlescomingoff
inintrinsicabrasionandthealmostmacroscopicsizeofthecrestsseeninFig.Ⅱ9.the additionalvolumelossduetoabrasionpatternscanconstituteasignificantproportion Jfe化”w6sP、イェフ
己
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ABRASION--
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lSig・’0.IDrofilesolabmsionpatterns:(a),unliIled、'lulcauuizatcolnatmTalrubber・abTadedun〔ler】、6kg/cm2onsiliconcarbidccloth,magn、5×;(b)・woTntyrcslIr【ace、luorizontalmagn3ox・vcrticalmagn.+25×・FTomref、18.
躯騨
oftbetotalabrasivewear・ThiscontributiontoabrasionwiIlbcrcferrcdtoas``patternabrasion,,…
AsdifferentcompQundshavcdiffeTentpropcnSitiestopattcmformation,theTelative abrasionratingofgivenrubbersamplesdePends,intheprcscnceofabmsionpatterns, ontheintensityofthepatterns,andnogenerallyvalidfigurccanbcassignedtoit・ATatingcanbequotedonlyforagive、testorforglvenconditionsofwear,Thisis
●
cleaTlyshownbytherelativeabrasionfiguresobtainedfoTthetwosamplesshownin Figエ7.TheintTinsicabrasionsofthesecompoundsareverynearlyequalbutonceapattemhasdevelopedonthem,theabrasionofthesoftercompoundishigherthantbe abrasionofthehardeTcompound,asshowninTablellL
b`ID
,⑪。●0-0T‐00▽01■■090●Br。‐。玉ひ』00.9可0●,●0■■■■■■Ⅱ‐05
0b・’0■■T■●▲q0B0JD1■■■|■■■■■日日Ⅱ、■▽●▽。■■■▽GAZ■z05■■■BBB■■|■000◇‐O0L7000■G・qn690q0●.I■
-‐0.0-0□叩印叶いⅡIu0IPI・釦門Zlm●P-‐・わ,‐0-。,
。①
Fdr
B●
丑やむ
TABLEIIl
ltATIo,】N%,oFTHEABRAsIoNoFANATuRALRuEBERcoMPouNDFHLLMDwITH雪5P.】,.】1.HAFmLAcKToABRAsloHoFAcoMPouNDFILLEDwITH45pp.h・HAFBLAcKoNDlFFERENTTRAcKs(sceFig.】7)
●●
SCD
lntrinSicabmEion
FinetaTmac
CoaTseconcrete
】00
】I`1
135
}寵
WithequallydevelopedpatteTns,therelativeratesoIpattemab「asionmaybe expectedtodependonthemechanicalstrengthoftheTubbcr・CompaTisonwithexperi‐mentallydeterminedstrengthdatashouldinpTincipalbeeasieTheTethaninthecase
ofintrinsicabrasionsincethelaTgerscaleofthephenomenonrcducestheratesofstTain byseveralordersofmagnitude・Anexampleofsimilar-sizedpattemsgivingdifferentrelativeratesofpatternabrasionisprovidedbycarbonbIack-fiUedcompoundsof natura1rubberandGR-S・Abrasionpattemsproducedonthesecompoundswhemslidingoverdifferentroadsurfacingsareshowni、Fig.20.Thissctofphotograpbsindicatescertamdifferenccsintheappearanceoftheabradedsurfaceswhichmaybedueto differentmechanismsoffailureoperatingonthetwocompounds. RどんrGD8姥sかギエフ
ごc
[
 ̄、
VOL.I(rO57/58) 410 八.SCHAU-UAMACll
thefollowingconditions.A"simpleextelusion''("trousers'0)l5teartestpiecewasperiod‐ icallyloadedwithanadequateweightuntilthesamplewastornthrough・Thenumber
ofcyclesnecessarytoachievethiswastakentobeameasureofresistancetotearprop-
agation、Thesampleswere1mmthickand254cmwide,tbcweightwas414gand
theperiodoftheloadingcycle0.82sec,Whenstartingtlletear,tbeloadwasapplied
foro、36secduringeachcyclebutthistimedecreasedtoabout0.14secwhentlletear
wascompleted,TableVgivestheresultsobtainedwithtbetwocompoundsrGIerred toinTablelV・Thetotallengthofthetearwasl0.5mm.
1
TAnlEV
NUMBEROFCVCT-FRTOFAULUREJNTEARPROUDACATION
■「
JVqI■mlmbbFr
ノjlIafUc,iIハゴ0カ.P.A、LLIFCjf-SrバレylBuufノ
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InspiteoftbeconsiderablescatteroftheGR-Svalues,tbcbetterresistancetoteaT‐
propagationofnaturalrubberundertheconditionsofthiscxperimentappearstobe
wellestablished・NogeneTalapplicabilityisclaimedfortlleparticularnumericalvalues
inTableV,butitwillbeseenthattheobserveddiffeTenceinpattemabrasiononnatural
rubberandGR-Scompoundsagreesqualitativelywiththedifferencesinmecllanical
strengtbthougbttogoveTnpatter】labTasion、SimilaTresultshavebcenobtail1edwitll
otheTsyntheticrubbers・
AsimpletheoryofabTasionpattemshasbeendevelopcdinclosccom】cctionwith
thetheoryofintrinsicabrasionl3、Theprofilesofabrasio】】pattcrnssllowninFig、I9
makeitclearthatthephenomenonmustbeginwithpartoftheabradedTubbcrsurfacc
beingpulledoutandelongatedinthediTectionofabrasio】1.Itllasbeensuggeste〔lthat
thisinitialstepisfacilitatedbylipsofthetypeseeninFi9.8(b)whicIla「ethrownup
behindteaTsacrossthetrackofanabrasivegrain・Becauseofinhomogeneitiesoftlle
materialoTbecauseofhig]】pressureexercisedbyexceptionallytallgrains,someofthese
teaTsandlipswillbelargerthantheaverage,Astheabrasivcl1assesoverthelipsand
stTetchesthemouttheywillcoveroneormoretearsinthcirrearandprotectthem
fromfurtherdamagebeforetluelipsretract・ThusalinearpeTiodicstructuTeisinitiated
which,however,doesnotyetconstituteanabrasionpattcmbccauseofthelackof
lateralalignmenLWhenabradedrubbeTsurlacesarecxaminedduTingcarlystages
ofpatterndevelopment,suchincipientformationsaTeindcedobservedassllownin
Fig、2r(a).ThesefragmentaryabrasionpatteTnsmustbccxpcctedtomig「atcacross
thesurfaceinthesamewayascompletepatteTnsbutthcrateofmigrationissubject
torandomeffectsandoccasionallytworidgesegmentscomcabreastandlincupwith
respecttoeachother、Thedevelopmentofthcpatternistllcreforearelativclyslow
process;itsgrowthisillustratedbytberemainingphotographsinFi9.2r・
庇どん”D8ccs力・イェフ
◆・jT|□●d6B▼0■580T0,.0▽040
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VOL、1(1057/5s)I?】(IcTIo知wDAIjlい筋l()NoFlRulmIER -1m
JUJIl Fig.■1.DcvcIol)mentofanabrasionpattcrnolU6ulluluuIiIIcdvIlIcanizatcofnatu「alTuubber・Track:g几rnctl》611】c『.'〕jらtmncetravclIed2(a),Igocm;(b),130cm;(c),2+ocm;(。),l3ocm;(e),7二ocm;
撫恩恥1.s×
Forthismechanismtofunction,thesti「[UIC弱oItherubbermustbelowenoughtoallowclongationofsufficicntmagnitudet()《](PcllTun〔lcrthetangentialstrcssproducedbytheasperiticsoftheabrasive・TheorigiI1illll1(〕。ulusoffilledcompoundsofthetyretreadtypeistoohighforthispuTposea】lq1KLpilttcrndevelopsonsucbsamplesonlyaftcrasoftenedtoplayerhasbcencrcatc(11)yI)rc-stressing・Iftherateofabrasionishigh,t11issurfaccskiniswornawayassoIjllKLsformcd,an(litbccomcsdifficultto
produceanabrasionpatternunderthesccollI1itions・TI1ispointisillustratedbyFi9.22.Atypicaltyrctreadcompoundo[naturalrllbl)crwasabradedunderotberwiscidentical
clrcumstancesongarnctandemerypaper・Abrasiononthegarnetbeingrapid,onlyvestigcsofanabTasionl〕atternaTeformed,whereasapronouncedpattemdcvelopsontllcblunteremcrypal)cr・SimilareffectshKlvebeenobscrvcdwhencomparingrubbersurfmccsabradcdonfrcshandrepcatedlyuscdspccimcnsofthcsameabrasivc,This
isals()oneofthercasonswhyabrasionpattcmsIormwithgreatcreasconroadsurfac-
綴uIIillll側:Yb鶏継(,既|h;;::1W;認『鯨蝋…[hmtwh…ridgcsbccomccomparablcinsizcwiththe[limImsionsoftheabrasivCgrain,thesllape
Fig.二苫.SHUTiaccofanatlIr61IrubbervⅡlcaIliz5lt1PIiⅡIF《IwiLlu5oI〕.!〕、lu.’いFbIacI《mbm(le〔l:(a)ongarnetI〕iuper;(b),onemeTyl〕aper,Magn.【o・Bx」dTIjIuDrcI,週2.
尺"Brgjlcどsjb,fJ7
lli認仮
’ VOL.’(TO57/58) 4画 A・SCHALLAMACII
(a) (b)
Fig.二3.SurfaceofanaturaIrlubbervulcanizatefiⅡedwith5op.p、hHAFl》Iackal〕mdcdongaTnetpaper(aⅢilluminationparaIleltothe【lirectionofabrasion;(b),atriglutimgIcstothedircctionMabTasionMagn・IC×.
1 11 ofthegrainsbecomesimportant、IntIIecaseoffilledrubbcrstlIcrcisatendencyfor
theabrasiveparticlestoploughthroughtberidgesandpToduccscoTingmaTks・Tl1is
effectisshownbythephotographsinFig、z3whicharetwopicturcsofthesameabraded
rubbersuTface;theonlychangemadewhentakingthephotographswastoalterthe
incidenceoftheiuumination、Incase(a),tllelightwasparaIleltothedirectionof
abrasionandshowsupawclldefinedifnotveryintensepattern;i】1case(b),wl1crethc
liglltwasatTightanglestothedirectionofabrasion,onlyscoril1gmarksarcsecn,
Becauseofthelackofcontinuityintheridges,suchapattcrnmaybecalleda``pseudo-
abTasionpatteTn'0.IngeneraLnoscoringma「kscanbediscovcrcdonToad-aI〕Tadedrubbersurfaces・
Inthcprevious1ypublishedtheoryofab「asionpattcms13itbasbecnassumedtllat
theiTspacingdependsonlyonthesizeofthelipsfromwhichtbeyoTiginate・Tllislip
beingsolelydeterminedbytbelengthoftbeteaT,ithasbeemdedllcedthattbesI〕acing
slisgivenbyeqn.(r8):
‘,-…(詩ハツ。 (18)
1
111
''1
'’ ''’ ''’
1li
Ill l
Iil
ll’
●o
b●
whereγistheradiusofcurvatuTcoftbeabrasivcg「ainatthcpointofcontactan〔M,
thesizeofthegrain・Eqn.(18)hasbeentestedbotbastoloadandgrai昨sizedel)endcncc
byexperimentsonacommercialabrasive(gametpaper)andhasbcenfoundtorcprc‐ senttheexpe「imentalfindingsTemarkablywell、Fig、エフshows,however,thatc〔ln.(18)
willnotadequatelVdescribepatternsproducedonroadsurfaccs・
Thedifferenceinthespacingsofthepatternonthctwocoml)oundsoldilIcrent
stiffnessshowninthisfiguTeislargeTthanpredictedbyc〔1,.(r8)accordingtowlIich
thespacingshouldbeproportionaltotheinversecuberootoftbcmodulus,TIIcratio ofmoduliofthese2mbbersis1.85,givingatheoreticalratioofspacingsequaltoonly
l:Ⅱ.225.ThedifferenceinstiffnessoftheabradedsuTfaccswillactuallybecvcnsmaller
than工.85becauseofpTe-stressingeffects,
ItissuggestedthatonroadsurfacesorgeneTallyonabrasivcswitllgrainsoflarge
radiusofcurvaturetheasperitiesinsteadofcuttingth「oughtheridgcsglideoveTthem
andelongatethembyfriction・ThespacingisthendeteTminedbytheequilibriumof
fTictionalandelasticTestoTingfoTcesJtisshowninthenextsectionthatthefrictional
forceF/ofasphericalgrainwiththediametermisgivenbythec〔luation(20)パノーconsL7`【2(カノE)リ。
庇e/〃β加“sP.“7
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1! VOL.I(1057/58) FRIcTIONANl〕AnIい葡I()N()lfItIJllIBl§I《
+13
Assuming,furthermorc,Hooke・slawtohol〔l「urthelocalelongation,thcretractivelo「ccJFrmustbcgivcl1byarclationoftbc「〔Drm
ノア「=c《DnHt.s『Uノゴ
whcrcNisthcsl)acinga11〔い,t1lcdiamctcToltllcarcaolco、tact、Substitutinglor《I「romc(111.(r6)andc(IllatingI7an〔11「,rcsulIsilItllcfollowingexpressionfo「tllespacing:
.-…:鋤(;)り゛,`,lwI)CTO((sthcdiameteroftheclose-packc(ISI)I】cricalabrasivegrains・Thise(luationgivcsastronger〔lcpendenceofthcspKlcingsonbothmodulusandpressurethanc(1m.(r8),butinpracticeitisdiflicultto(1riuwasba「pdivi〔linglinebetweenthetwo91i鱒Qs.;lsissccnfromtheexperimentalrIDHlI1IHgiveninTabIeVI.
TAIlLliVl
SFAClNCSOFAERASIONPA1・TIilRN筍pRODUCEDONTARMAC・
NATURALRUBBmRVULCANIZATI鶴UrILLI§DWUTIlCAIREONBLACK
51nciク09イリDIDクリ
妬ハル「“"化J81
ざゴルPJh.〃・IFJJWルアmJMFD81
f5pP.A、〃`IF ⅡI
Pressure,o,66kg/cm= lnrcs田ure・望.68kg/cm2rP
〔D・当Oo
ID腋17⑪
1.H⑪
Ⅱ、68
雪.2Z
0.Ⅱ55 0.男I之
u、37
Inthistable,「pistlleratiooftbespaciIlg381ttllctwop「essures・ItstheoTeticalvalue
is,accordingtoeqn.(r8),(2.68/0.66)Iノ,=1.5()5,6uldKlccordingtoeqn.(Ⅱ9),(2.68/0.66)ソ, =2.18,TllcratioofthcspacingsonthctwI〕c()mpoundsis妬Assuming,asaguide,thatthcmtioofthemoduliisI.85,'cis,altcTc(111.(I8),(1.85)'/3=L225andafter cqn.(r,),1.351V,=2.604.Itappearsthercforc[romthclimitedexperimentaIevide、Ce
洲鯉IIWA麓麗鰹瞬::1W&鑑|恕:!:;fp……、'm・ItsI}ouI(IlinallybcmcntionedthatabrasionpattcrnscanhaveconsideTablediag-
U1osticvaIuewhendctcrminingthemodcofwcnrtakingplaceu】1derconditionsnotacccssiblcto〔lircctobservation,Thisappli(PslD&lTticularlytotyreswheretl]erelativemotionbctwccntyrcandtrackcanbcde〔111(?,'(1[「omabrasionpattcms23.
V111.FJRICTIONO鷲!((》U〔;llSURITACIZS
AbTasionofrubbeTasenvisagcdinthel)I・['c(DlIil1gsectionsisaconsequenceoflocal lrictionalstressessctupbytheaspcritiesoftlIL9Lmckanddoesnot』incontTasttosolidIriction,reactonthcfrictionalforces・Friction(DnrougllsurfacescantluerefoTebetreatedbymctllodssimilartotl1oseemployed(orlrictiononsmoothsurfaces,without
regardbeingpaidtoanymechanicalfailuTecI1瓢liI1giH1thewakeofthetrackasperities・NocaIculationisnecessarytoseethattllcclDcfficicntoffrictionisloweronarough
thanonasmoothsurfaccbecauseofthesmallcrareaofcontact・ThisisshownbythefollowingdataobtaincdwithanextractGdsamplcofanaturalrubberty「etTeadcom- I)oundongIassgroundwithsiIiconcarbidcofdifferentgrade・ルノPrFJI“sp・ィJ7
、pO
Ill
illlll
ロ
'1 11
' 4Ⅱ4 VOL、1(1057/58) 八.SCHATⅡAMACII
9s〒
5▲
TABLEV11
COEFFlClENToFFHUCTUOlvONCRoUNDcLAsS.(lFromrcI・訓)
Diameterofsilicon
carbidegrainomm CocHicientulfTiction
PIatcglass
望・79
o・oc7
L36
0.oィZ
Ll8
o・Ll【
】.ニロ
Theessentialdifferencebetweenrubberfrictiononsmoothandroughsurfaceslies,
however,intheirloaddependence・The・reasonforthisdivcrgenceistbatoIuarough
trackboththetmeandtheapparentareaofcontactdependontheload,Aquantitative
estimateoftheeffectcanbederivedfromthemodelemployedinthethcOryofintrinsic
abrasion・Thetipsofthetrackasperitiesareagaintakentobesphericalandlargecom‐
paTedwiththerubberasperities、Grossdeformationoftherubberbytluctrackasperities isassumedtoobeyHertz,sequationsforsl〕hericalcontacts,andtbetrucareaofcontact
contributedbyeachTubberasperitytobeproportionalto(ノケノノE)ツ。,whercWistllc localpressure・Thecalculationhastheresultthatthefrictionalforccproduccdbyatrackasperityis
01
毬R毬R
(=o) Fノーヮ(カノE)・ノ.‘1V・洲.▲■■■■、■■■■、■■■■■■■■■■■■■■■■凸P9‐Ⅱ●しけ■6日■、▽.■V6■■PDBB■■■■■・0●0凸0lb■■EDF■q0.6『OS。●0■■ロロ、Ⅱリーーーム■Ⅱワ9009■1■口000■曰Ⅱ‐0●000-‐06‐1-もBGBT000
’。‐095090■■■■0,■■■■■■7600■■■■■■000Ⅱ90■■■■6■■凸■■■■■lUG■0F0.0‐’00001.70↓▲■■■■1010‐II9h0i9I0■■■DllBU■5c●□■0?q・IDし’・B90
D6‐‐‐‐0■。‐ⅢH0●Ⅲp6Lw-0い67.0P’0。‐ⅢIⅡPu刮○』H1‐帆0‐‐’。‐-‐Our‐片‐00口■。‐0-1-09I。‐’90宮98□。.‐‐
可,.●可,.●
and
似一c…農('|`'γ・('/歴1-V. い)の己の己
1 1。
whereristheTadiusofcurvatureanddthesizeofthetTackasperities・Therclation
(21)wasfirstproposedinaslightlydifferentformbyLINcoLN2`、Eqn.(20)hasbeenconfirmedexpeTimentallyl3withanumberofcompoundsat
pressuresuptoabout2.5kg/cm2・Fig.24givesthecoefficientoflrictionofthreedifferentcompoundsonsiliconcarbidepaperatpressuresuptoneaTlylokg/cmaAt higherpressure,eqn.(2r)fails,theCbefficientoffTictiondecrea5ingmorerapidlywith increasingpressurethanpredicted・Thereasonforthisdiscrel〕ancyisinallpTobability
●の
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、▲-ozOO-ZO40.60.巳1.L
Iogoop ●
Fig・全4.LogaTithmsofcoefficientsoffrictiononsiliconcaTbidcpal〕cr・gra(IcI8o,PlottedagainstlogaTithmofnoTmalpTeSSure.(a),unfilledvuIcanizateofnatural「ubbcr;(b),vlllcanizateolnatuTal rubbcTfiuedwitln5op.p」】・HAFblack;(c),vulcanizateofGR-S(】《「沖、c)liⅡc〔lwith5op.p」u・HAFblack、Velocity,ooo2I2cm/sec、
庇どん”"“s,、イz7
=⑤
・Q2
・0.1 (□)
|::L マーローロ
、一T-g皇----1b)L0.1 ̄へ゜
ぞ-↑:;~--具~
エO  ̄
ロ
0
-04-0200.2OLA0.608-1.0
‐
VOL.’(Iリ57/58) lPl(ICTIONANl〕AlII(AHIIDN()Iflt【TlBI2ElR+15
ab
Fig.」5.Fricti〔)、;KII()】.c山I1IriIlg月tart(〕(m《〕ljoDll,TIⅢ.【ⅡIuI》Ii仰lqIdP(〕IrtIlccnvcluI)ci叶6Lmca釦lrcofthetHungcntiaIlorcc、NormKlII〕「c錨lurc,u,二SIWじIio笘川`'1.IIIll川(lvluIcmnizatcoIniutⅡralrIIIDber;(b),umtⅡralTlIl〕bcr【ilIc(lwjthうop.p」9.卜いITljlKl〔:1L
fm1mm9、
cd
Fig、33(cい・ulcallimtcoIGR-月(I<rylcnc)fiIlc`lwiLlI5UI'.[)」1.1いFbIacI`;(。昨u鳥(c).blltsampIcloa《I“IwitlI」.」3k円/c、笘lor5miu1utcsIDcforetIMP⑥xlDcrim(Buut・Track:garnetpal)どr,grain5izeo・ユ91mm.
牌turatioIIcffectsimilartothat(lemonstr`llcdinFig、5forthecaseoff]atcontacts.L_a(lditioIltomutualintcrferencebetweelll・uIDburaspcritics,saturatiollcanhcrcbe
produccdbytherubberfillingthegapsbetwccntllctrackasperities(DENNY1o). ItisHlttimesobservedthattheforcencccssarvtostartasampleonaroughtrack
isgreKlturtbant]lefo「ccof(lynamicfriction瓢lIficicI1ttokeepitinmotion・Thispheno-menonof1`startil】gfriction'・hasbeeninveHtigKLtedinanumberofexperiments・Thetimcdcpendenceofthetangentialforcew【lsrCco「dedduringtbcstartingperiod,tlledeflectionofthe(lvnamometerlMwingbeencuI1vcrtcdintotheout-of-balancecurrent
ofa2oo()scc-lalternatingcurrentbridge・RCI〕resentativeTesultsarethcoscillogramsinFi9.25,whichshowtheenvelol〕eoft]1u〕lIt-ol-balancecurrentasfunctionoftime
(fromlefttorigbt).WiththeunfillednHltIlriLlx・ubbcrvulcanizatc(a),thcforcerises monotonouslyuntilthesamplebeginslIDIl1Iwcal1dthcforcebecomcsconstant,but
whentllccompoundisfilledwith5opI)」1.11AITI〕Mck(b)thefrictiomLlforccl〕assest】]TougllKLsligbtmaximllmattllcstart、111iHcllcctismorepronouncedwiththeblack-lillcdGR-Scompound(c).Thetmnsitioll〔romrcsttomotionishereKlccompanicdbyavibmtionwhichtakessometimeto《licout・TheexccssofstartinglrictionoverdynamiclrictioniK)crIjascswiththCtin1ljlhCsamplchasbeenincontactwiththe Eβに”DlpEsP・fJ7
守0
=
lll 4m A・SCHAT-1-AMACH VOL.】(r957/58)、ざい
、 ̄
」
track.Itcanalsobeincreasedbykeepingthesampleunderahigbloadbeforesta「ting theexperiment,asshownbytheoscillogTamFig25(。).TableVIIIgivestypical numericalresults.
) ,、
TABLEVIII
ExCESSOFSTARTI1wGFRIcTlONOvERDYNAMJcFRJCTOONoNGARNETPAPER・GRAlNsIZEo,臼OmmNoTmalpressure,1.28kg/cm2
ら ̄一君
!。
MUf
fub6Fr
”0/dlJcT
M21.rIUbbfr D
JoPp.&.HHjG TA6sdwF,ロルァ
ウol81iPOUIFIdf”loUwl
K〃比DUBD5oPP.A、〃JIF
7”sdUDjJごロα昨「38"iDwoM” 2.二JAHノ「0,82
COD"PoIlDwノ
ロ〃
Excess`% 57.8 ◎ 7.Ⅱ Ⅱ5.5 33.3 114
‐‐-0
iJWl NoticingtheabsenceoftheeffectinuJufillednaturalrubbe「,tlleconclusiondrawn
fromtheseresultsisthatstartingfTictiononroughsurfacesisduetoplasticdeformation
ofthesamplebythetrackasperities,pToducingpermanentset、Atthcbeginningofmovement,workmustbedoneindeformingtheTubberwhichhassaggcddowninto
theintersticesbctwcentrackasperities・Inpractice,stal・tingfrictionwiUbedifficult
todistinguishfromstaticIriction,anditispossiblethatthefinitecoefficientofstatic
frictionatinfinitemormalloadfoundbyRATNERANDSoKoLsI<AYA12isamechanical
hindTanceeffectsimilarincharactertostartingfrictionItisinterestingtonotein
thiscontextthatinarecentpublication2qRATNERANDLjwRENT,Evhaveindel〕en-
dentlydemonstratedthedifferencebetweenstartingfrictionandstaticfriction
Theoccurrenceofstartingfrictionindicatesthepossibilityofanegativcvclocity coefficientofrubberfrictionandcantherefoTeundercertainconditionsinducciL
stabilitiesduringsUding・Stick-slipphenomenaare,infact,oftenencolmteredinfriction
expe「imentswithfilledGR-Scompounds,Startingfrictionmayalsohaveimportant
conscquenceswhenrubberissubjectedtointcrmittentsliding,as,forcxamplc,oIltbe
circumferenceoftyres.
□0泗14●0F05
蝿
■△
。△Ⅱ■□、、菫■■■日◆■■■■■■■b■■■■■■■■Ⅱ■■■■■P●0町‐j、●7●■■■■■■■凸■■■0■□0●00.■’000▲U■■且■10。
-艀q臼q臼
の ̄
1X・CONCLUSIONS
TheworkTeportedinthispaperisafirstattempttoelucidatcsomeolthcmostim-
portantfactoTsgoveTningfrictionandabTasionphenomena,VeryideaIizedmodclshad
tobechoseninoTdertoTeducethedifficultiesinberentinthesubjecttomanagcable
proportions,andatbestonlysemi-quantitativeagrecmentbetweeI1theoryandexl〕cri-mentcanbeexpected・Withintheselimits,theassumptionthatlocaIstressconcentra-
tionsproducedbyfrictionaltractionarethecauseofabrasiomhasbeenjustifiedby
theavailableevidence,abTasionthusemergingasapurelymecbanicalproccss,In
comingtothisconclusiontheoriginoffrictionalforceshasbeencomplctclydivorccd
fromabTasionbuttheexistenceofstartingfriction,discussedatthcendofthcIast
section,tbrowsdoubtonthegeneralvalidityofthishypothcsis・Ifmcchanicalcntanglc-
mentcanplayasignificantroleinrubberfriction,effectssimilartothosHeproduced
whenscratchingrubberwithaneedlemaybeofgreateTimportancethanhasbeen
assumedinthepresenttreatmentoftI1esubject・Itshouldalsobementioncdthatno
theoryis,asyet,availableforthemechanismofstaticfriction・
丘e/ergオlcesp.イェフ
▽ bL
◆■-
。Ⅱ01-0600Ⅱ8FⅡdp9l‐f010h■0■|■7909冊r0ⅡumJ咄■■皿旧Ⅲ□B旬日rDI・日70■■価0砒和・0
VOL.’(Ⅱ957/58) FRICTIOSlANDABRASI()NOFRUBBER 417
ItIIasbeendemonstratedthattherclKLtivewearresistanceofanytwo
compoundsisnotaconstantbutcandependpronouncedlyontheconditionsof
testing・Thisvariabilityisduetothelormationofabrasionpatternswhichdevelopondifferentcompoundswithdifferentintensityandwhosecontributiontothetotal
abrasivcloss〔lcpendsonthemechanicalstrengtlIofthecompound,Abrasionpatterns
arethoughttoinHuencerelativeratesoftyreweaTlmderdifferentconditionsofservice聖
butnospccificreferencehasbeenmadeinthispaI〕crtotyres,forthefollowingreason・
Tyrcwcaroccurswhenthereisrelativemolionintheareaofcontactbetweenthe
circumfcrcnceofthctyreandtheroadandistllcreforeintimatelyconnectedwiththe
mccIMmicsofsIippingwheels・Tllisisatopicofsomecomplexityinvolvingthelarge‐
scaIcelasticpropcrtiesofthewheel,differencesinwhichmayovershadowdifferences
if11鯛、、cabrasionTesistanceofthctyretread・Thcsameconsiderationsapplytoab「asionmachincswbicharcdesignedtoimitateconditionsencounteredbytyresandemp1oy
smallrotatingsamplesundergoingvariousformsofsljpInspiteofitsintricacy,thG
problemisamcnabIctotheoreticalwork81n(181I〕rcliminaryresulthasbeengivenin
an(xurlicrl〕ublication22・Itishopedtoprc3(911t6lII1oreadvancedapproachtoitinthenearluture.
尺EFEノl/idVC〃S
117.P、IBowDENAsIDI〕、TABoR,Frir/ioIoaDIUノ.lrljriWiDlIo/StMjds,OxfordURliv・Press,London,】054.
2F.L・ROTH,R・LDRIscoLLANDW.L・HoLT,ノ.ノイィ.s1.`イ'(・AIjV(I'ABI《「.S/α'o`(MHS,28(19+」)439.3A・SclIALLA3IAcH.」〕roc・PAys・SOC.(Lo9udoI叩.ノノ.“(uリ53)386.811.EwuNG,ノ.Cハcj肌P〃ys・ロイ(1936)2835A・ScllALLAMAcH,TraJls、ノリns/、Rllbberノブ8..,32(Iqj5n)1.1」.‘J・CJAEc囮R,ノ.P'oc・Roy・SDC・NS、1M,76(】⑪I当)2。]7A.ScHALLAMAc1H,P「oc・PAys、SOC.(LoDuapDl),ノノ,65(Iリ5忽)657.8STIMosIlENKoANDjN・GooDuER,丁比oryuノノ:Jlusl化ijy,McGmw-HillBool[Company,NcwYorkpu”1.
01,.THI8GloN,ノfβt'.g`'1.aloouノハ08に,2コ(1046)IOU、
1級:鯛鮒jH`jIf鯛縫(爵'1鰍,:bWiI1リ湖17』‘U2⑤.B・RATN匹RANDMDSoKoLsKAYA・DCハノ《'`イルIAWノ.Mlu0ル5.s.S・尺.,”(u95I)43Ⅱ、l3AScII人LL`wAclLP'0c・PAys・Soc.(LOM。").Im7(lリ5.1)883.MA.ScHALLA]UAcIH、ノ.ルノylllerScj..,(Ⅱ9.2)385.15m5.RlvLINANnA・GTHoMAs,ノPCノy"IDパイf,」('(Ⅱ953)z0L8oL、MuLLINs,ノ.JfMb6pl況必seqrpハ.J6(Ⅱ947)275;ノ.ノ'Ays、GCCノjoidCAel恥,ゴヂ(【950)239.UTL・NluLLINsjwpN.R・ToBIN,Pro広.。「‘RIM'blP’7W川.CuIV.LoMoll,rl54,p,307.IuA・SCIlALLAMACIl・TmllS・mSイ./TlIbbeグノ"。.、28(lリ5二)?50.1,A・SCIいLLAMAcIl,Proc,PAys、SOC.(LoDl`oⅢ),B,“(【953)8【7.20J.M・BuIsTANDO.L・DJwI塵,丁r`1,1s.〃s1.ノfⅢ地rノ”.、空(【946)68.21H、W、GRElZNs3IlTlI,IInpublisluedwork、22A・ScIIALLハMAcHu,KpMfscハllAIu,GlljjMli,Son〔lerluc【t,,arrgi/e00.,(Ⅱ955)色7;R116berC舵,几、1.
7“〃ICノ.,ニワ(uO36)78【、23ME、GoucI1.J.}LlIARD3lANANDRJ・McLMlIfN,711111s・ノ"sノ.ノrl1bberノ'1..,32(Ⅱ956)二7.20A・SCIIALLAMAC】I,パOノノOMjr.,J\』(【955)U65.25n.LlNcoLN,JWllIrc.J72110う3)u60.20s、11.1《ATNl:RANDMV・LAvRENTDEv,DoMM此1A'01/,MJllAS.S、5.J(.,JOB(【956)+61.27W.’[AuzMANN・ノにzノ.JVoderllPAys鯵.J子(894』)、」.
ReceivedDeccmbcT5,Ⅱ957
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