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voestalpine Grobblech GmbH www.voestalpine.com/grobblech High-strength thermomechanically rolled fine-grain steels Technical terms of delivery

High-strength thermomechanically rolled fine-grain · PDF filethermomechanically rolled fine-grain steels ... High-strength thermomechanically rolled fine-grain steels ... Union NiMoCr

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Page 1: High-strength thermomechanically rolled fine-grain · PDF filethermomechanically rolled fine-grain steels ... High-strength thermomechanically rolled fine-grain steels ... Union NiMoCr

voestalpine Grobblech GmbH

www.voestalpine.com/grobblech

High-strengththermomechanicallyrolled fine-grain steelsTechnical terms of delivery

Page 2: High-strength thermomechanically rolled fine-grain · PDF filethermomechanically rolled fine-grain steels ... High-strength thermomechanically rolled fine-grain steels ... Union NiMoCr

2Technical terms of delivery for heavy plates alform high-strength June 2008.

Subject to change pursuant to further development.The current version is available at www.voestalpine.com/grobblech

High-strengththermomechanically

rolled fine-grain steels

alform® M

Steel grades

alform 700 Malform 960 M

More information you will findin our technical terms of delive-ry for thermomechanically rolled steels.

2

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3Technical terms of delivery for heavy plates alform high-strength June 2008. 3

alform 700 M, alform 960 M

alform 700 M and alform 960 M are high-strength, thermomechanically rolled, weldable fine-grain structural

steels with good cold forming and bending properties.

alform 700 M and alform 960 M are produced via the LD-route.

Production process

Table 1:Steel grades

Steel grades

Steel grades

Steel grades

alform 700 M

alform 960 M

The alloying concept provides very low carbon contents and low carbon equivalents, which aims in very good weldability. The high-strength grades provide special advantages in areas, where weight savings are of great importance, e.g. for mobile cranes, concrete pump cars and vehicles.

The technical terms of delivery apply for plate thickness from 8 - 60 mm for alform 700 M and for plate thickness from 10 - 15 mm for alform 960 M.

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4Technical terms of delivery for heavy plates alform high-strength June 2008. 4

Table 3:Carbon

content andequivalent

Chemical composition

Table 2:Chemical

composition

Heat analysis

Guaranteed values

mass in %

C Si Mn P S Altot. Cr Mo Ni V1) Nb1) Ti1) B

Steel grades max. max. max. max. max. min. max. max. max. max. max. max. max.

alform 700 M 0.12 0.60 2.10 0.020 0.008 0.020 1.50 0.50 2.00 0.12 0.06 0.05 0.0050

alform 960 M 0.12 0.60 1.70 0.020 0.008 0.020 1.50 0.70 2.00 0.12 0.06 0.05 0.0050

1) The total of Nb, V und Ti must not exceed 0.22 %.

The chemical composition of alform 700 M is according to EN 10149-2 for steel grade S700MC. The chemical composition of

alform 960 M is according to EN 10025-6 for steel grade S960QL1.

Carbon equivalent

Standard values for carbon content and carbon equivalent

Plate thickness C CEV1) CET2) PCM3)

Steel grades mm % % % %

alform 700 M15 0.04 0.43 0.26 0.18

40 0.06 0.47 0.26 0.19

alform 960 M 10 - 15 0.08 0.56 0.31 0.24

1) CEV = C + Mn/6 + (Cr + Mo + V)/5 + (Ni + Cu)/15, according to IIW2) CET = C + (Mn + Mo)/10 + (Cr + Cu)/20 + Ni/40, according to SEW 0883) PCM = C + Si/30 + (Mn + Cu + Cr)/20 + Ni/60 + Mo/15 + V/10 + 5*B, according to API 5L

As-delivered condition

Plates of alform 700 M are delivered in a thermomechanical rolled condition with accelerated cooling.Exceptionally conventional quenching and tempering is permitted. Plates of alform 960 M are deliveredin a thermomechanically rolled condition with accelerated cooling and tempering.

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5Technical terms of delivery for heavy plates alform high-strength June 2008. 5

Mechanical properties

Table 4:Mechanical

properties

Mechanical properties in as-delivered condition

Plate thickness Yield strength Tensile strength1) Fracture elongation1) Notch impact

range YS min. Rm L0 = 5,65 √ S0 energy2), min.

Steel grades mm MPa MPa min., % J

8 < 15 700 770 - 1,050 10 40

alform 700 M > 15 < 50 680 770 - 1,050 12 40

> 50 < 60 650 770 - 1,050 12 40

alform 960 M 10 < 15 960 980 - 1,150 10 30

1) Tensile test in accordance with EN 10002 on transverse samples.2) Notch impact bending test in accordance with EN 10045 on Charpy-V longitudinal samples at –40 °C.

The mean value from 3 individual samples must reach the specified requirements. No individual value may be below 70 % of the gua-

ranteed mean value. For thicknesses < 10 mm, samples similar to Charpy-V with dimensions of 10 x 7.5 mm are tested. The guaran-

teed value is reduced in proportion to the sample cross-section.

The mechanical properties of alform 960 M are according to EN 10025-6 for steel grade S960QL1.

Test unit

Unless otherwise agreed upon ordering, 40 t of a heat or a smaller portion is used as test unit for the mechanical properties. The test unit must consist of plates with the same steel grade and the samethickness range for the yield strength according to table 4.

Scope of testing

Quality testing includes the tensile test. The notch impact bending test is carried out on longitudinalsamples at –40 °C. A different sample position or testing temperature must be agreed on request. The heat analysis is provided as proof of the chemical composition.

Unless otherwise agreed, tolerances pursuant to EN 10029 (thickness tolerance according to class A,flatness tolerance according to class N), and surface finish according to EN 10163-A1 are valid.

Quality test

Tolerances and surface finish

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6Technical terms of delivery for heavy plates alform high-strength June 2008.

Type of certificate accordig to EN 10204 must be agreed upon ordering.

Material testing certificate

In general, marking consists of:voestalpine symbolSteel grade designationHeat numberPlate number

Marking

Cold forming

Plates of alform 700 M and alform 960 M provide good cold forming properties.On condition that cut edges have been ground very smooth and that the bending pro-cess is done skillfully 90°-bending without cracks is guaranteed for die-radius of mini-mum 3 x plate thickness for alform 700 M and for die-radius of minimum 4 x platethickness for alform 960 M.

Hot forming and heat treatment

Heavy plates of alform 700 M and alform 960 M are in thermomechanically rolled condition and are intended for cold forming. Hot forming and stress relief annealingare possible up to 580 °C. Tensile strength of alform 700 M will decrease within theguaranteed values in table 4 compared to delivery condition due to heat input.Normalising and quenching and tempering deteriorate the microstructure of TMCP-steels and therefore are not to be processed.

Welding

General information Thermomechanically rolled high-strength steels alform 700 M and alform 960 M haveexcellent weldability, which results of a low carbon equivalent (CEV), and in particu-lar, a low carbon content (C). The low CEV and C values provide reduced hardening inthe heat-affected zone (HAZ) of welds. This leads to greater resistance to cold cracking(picture 1). However, despite this advantage, in view of the high yield point of thesteel grade, it is advisable to take extra care during welding. The generally valid andaccepted rules for the welding of low-alloyed, higher-strength fine-grain structuralsteels according to EN 1011-2 and STAHL-EISEN Werkstoffblatt (SEW) 088 must beobserved.

Processing guidelines

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7Technical terms of delivery for heavy plates alform high-strength June 2008.

Weld preparation, thermal cuttingWeld preparation can take the form by machining or thermal cutting. In the case ofthe latter, preheating is not required for plate thickness up to 20 mm at a workpiecetemperature above +5 °C. Prior to welding the weld edges must be dry and clean.

Welding processAll standard automatic and manual welding processes can be employed. Inert gasshielded welding (GMAW, IGSW) with solid wire has the advantage of providing very low hydrogen content in the weld material and is also especially suitable with regardto cold cracking resistance.

Filler materials and welding conditions (preheating, welding parameters)The selection of the filler materials should result in a weld that matches the chemicalcomposition and the mechanical-technological properties of the base material.

For welding alform 700 M ER 110 S-G wires according to AWS A 5.28 are proven forinert gas shielded welding. Type E11018-G basic-coated stick electrodes according toAWS A 5.5 are suitable for shielded metal arc welding, and the wire-powder combi-nation ~ F 10 A4-EM2-M2 according to AWS A 5.23-97 is suitable for submerged arcwelding. Recommended filler materials for alform 700 M und alform 960 M are givenin table 5.

Picture 1: Hardening

in HAZ400

380

360

340

320

300

280

260

0.5 1.21.11.00.80.70.6 0.9 1.3 1.4

Arc energy [kJ/mm]

Max

. har

dne

ss in

HA

Z [H

V10

]

alform 960 Malform 700 M

Hardening in heat-affected zone (HAZ)

heat-affected zone (HAZ)

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8Technical terms of delivery for heavy plates alform high-strength June 2008.

Picture 2:Recommended

preheatingtemperature

Recommended preheating temperature, alform 700 M and alform 960 M

0 10 20 30

Plate thickness [mm]

200

180

160

140

120

100

80

60

40

20

0

40 50 60

Min

imum

pre

heat

ing

tem

per

atur

e [°

C]

SAW (7 ml/100 g WM)

GMAW (3 ml/100 g WM)

Table 5:Recommended

welding consumables

As a result of their high strength, such welded joints show a higher tendency to coldcracking, which can be minimised by the selection of suitable welding conditions.The tendency to crack formation in the HAZ, in general, is distinctly lower than in theweld metal due to the lower hardening characteristics of the base metal. For reasonsof cold cracking prevention, the hydrogen content in the weld material should be verylow (HD < 3 ml/100g WM). This is guaranteed by inert gas shielded welding with solidwire. Basic electrodes and welding powder for submerged arc welding must be sub-jected to secondary drying. The instructions of the manufacturer concerning dryingand the method of use to obtain the required hydrogen criterion must be adhered to.The risk of cold cracking can be minimised by moderate preheating in accordancewith picture 2, even in case of unfavourable combinations between heat input andplate thickness.

Base material Welding process – consumable

Steel grades SMAW GTAW GMAWSAW

wire flux

FOX EV 85 NiCrMo 2.5-IG NiCrMo 2.5-IG 3 NiCrMo 2.5-UP BB 24

alform 700 MPhoenix SHNi2K100 –

Union NiMoCr/Union S 3 NiMoCr UV 421 TT

Union X85

alform 960 M– – X90-IG – –

Phoenix SHNi2K130 – Union X96/X90 – –

You will find more information at www.boehler-welding.com and www.t-put.com. Experienced welding engineers are at your disposal.

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9Technical terms of delivery for heavy plates alform high-strength June 2008.

To ensure the high strength and impact properties of the weld (base material, HAZ and filler metal) cooling times t8/5 of 3 - 15 seconds and interpass temperatures of < 150 °C are desirable. Cooling timest8/5 above 15 seconds are permitted under special conditions (e.g. overmatching, ...) but are to be provenby the welder in every case. Standard values for the arc energies to maintain the given cooling times are contained in picture 3.

Standard value for cooling time t8/5 acc. to EN 1011-2 annex B, alform 700 M and alform 960 M

Minimum number Plate thickness (mm)of weld layers ˜ 3

Picture 3:Standard

valuecooling time

0.2 0.4 0.6

Heat input Q=K*E [kJ/mm]

60

58

56

26

24

22

20

18

16

14

12

10

8

6

0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4 2.6 2.8

80

3

20

3

Preheating temperature [°C]

Cooling time t8/5 [s]

0.4 0.6 0.8 1.2 1.4 1.6 1.8 2.01.0

Arc energy E [kJ/mm]

2.2 2.4 2.6 2.8 3.0 3.2

80

6

20

6

80

9

20

9

80

15

20

15

Pla

te t

hick

ness

[mm

]

Manual electric arc and GMAW (K=0.85)

Recommended working range

20

18

16

14

12

10

8

6

2-d

imen

sion

al t

herm

al c

ond

uctio

n

26 -

56

60

58

56

26

24

22

21

3-d

imen

sion

al t

herm

al c

ond

uctio

n

Precondition for high notch impact energy in the welded joint is multi-layer welding, in which thenumber of weld layers is calculated on the basis of the following approximation:

Following appropriate checking (e.g. using process tests according to EN 15614-1), other welding con-ditions can be selected, if the properties of the welded joint correspond with the requirements made onthe component.

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10Technical terms of delivery for heavy plates alform high-strength June 2008.

Dimensions

alform 700 M

Thickness

(mm)

60

55

50

45

40

35

30

25

20

15

10

8

1,50

0

1,60

0

1,70

0

1,80

0

1,90

0

2,00

0

2,10

0

2,20

0

2,30

0

2,40

0

2,50

0

2,60

0

2,70

0

2,80

0

2,90

0

3,00

0

Wid

th

(mm

)

Maximum length: 12,750 mm

Different dimensions on request.

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11Technical terms of delivery for heavy plates alform high-strength June 2008.

Dimensions

alform 960 M

Maximum length: 12,750 mm

Different dimensions on request.

Thickness

(mm)

25

24

23

22

21

20

19

18

17

16

15

14

13

12

11

10

9

8

1,50

0

1,60

0

1,70

0

1,80

0

1,90

0

2,00

0

2,10

0

2,20

0

2,30

0

2,40

0

2,50

0

2,60

0

2,70

0

2,80

0

2,90

0

3,00

0

Wid

th

(mm

)

Page 12: High-strength thermomechanically rolled fine-grain · PDF filethermomechanically rolled fine-grain steels ... High-strength thermomechanically rolled fine-grain steels ... Union NiMoCr

voestalpine Grobblech GmbHvoestalpine-Straße 34020 Linz, AustriaT. +43/50304/15-9440F. +43/50304/[email protected]/grobblech