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    Mini-Seminar

    Dr. James Throne, Instructor

    8:00-8:50 - Technology of SheetHeating

    9:00-9:50 - Constitutive EquationsApplied to Sheet Stretching

    10:00-10:50 - Trimming asMechanical Fracture

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    Mini-Seminar

    Advanced Topics in Thermoforming

    Part 1: 8:00-8:50

    Technology of Sheet Heating

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    Lets

    begin!

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    Mini-SeminarAdvanced Topics in Thermoforming

    All materials contained herein are the intellectualproperty of Sherwood Technologies, Inc., copyright1999-2006

    No material may be copied or referred to in anymanner without express written consent of thecopyright holder

    All materials, written or oral, are the opinions ofSherwood Technologies, Inc., and James L. Throne,PhD

    Neither Sherwood Technologies, Inc. nor James L.Throne, PhD are compensated in any way bycompanies cited in materials presented herein

    Neither Sherwood Technologies, Inc., nor James L.Throne, PhD are to be held responsible for anymisuse of these materials that result in injury ordamage to persons or property

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    Mini-SeminarAdvanced Topics in Thermoforming

    This mini-seminar requires you to have aworking engineering knowledge of heattransfer and stress-strain mechanics

    Dont attend if you cant handle theoryand equations

    Each mini-seminar will last 50 minutes,followed by a 10- minute bio break

    Please turn off cell phones PowerPoint presentations are available at

    the end of the seminar for downloadingto your memory stick

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    Part 1: Technology of Sheet Heating

    Outline Fundamentals

    Dimensionless Groups - Definitions Radiation Explained Arithmetic Energy Dome Radiant Heat Transfer Equation Ditto - Where is the Problem? Problem Solved! No?

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    Part 1: Technology of Sheet Heating

    Fundamentals Conduction

    Convection Radiation

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    CONDUCTION Solid-solid energy interchangeMoving thermal energy through sheetMoving thermal energy, sheet to mold

    In very thin sheet, conduction is used to movethermal energy from heater to sheet throughdirect contactImportant Parameters

    Thermal conductivityHeat capacity or Enthalpy

    Part 1: Technology of Sheet Heating

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    CONVECTION Fluid-solid energy interchangeSheet heating (or cooling) during sheetheating in oven

    Free surface cooling in mold cavityPrimary way of heating very thick sheetImportant Parameters

    Convective heat transfer coefficientAir velocity, temperatureRecrystallization, recrystallization rate

    Part 1: Technology of Sheet Heating

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    Part 1: Technology of Sheet Heating

    Convection heat transfer coefficient values

    Fluid h(Btu ft2 hr

    oF)

    Quiescent air 0.8 - 2Air with fan 2 - 5Air with blower 5 - 20Air/water mist 50 - 100Fog 50 - 100Water spray 50 - 150

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    Part 1: Technology of Sheet Heating

    Dimensionless Groups - DefinitionsBiot number Bi = hL/kFourier number Fo = aq /L2

    h convective heat transfer coefficientL half-thickness (heating on both sides)k thermal conductivitya thermal diffusivity, k/ r cpq timer densitycp specific heat

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    RADIATION Electromagnetic energy interchange at adistanceMethod commonly used to heat all but verythin or very thick sheet

    Important parametersHeater temperatureHeater and sheet emissivitiesThin-gauge sheet transmissivitySheet, heater geometry, spacing

    Part 1: Technology of Sheet Heating

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    Part 1: Technology of Sheet Heating

    Radiation Fundamentals Black body, gray body, real body Emissivity and absorptivity

    Energy interchange Wavelength-dependent energy transmission in

    the far-infrared region Semi-transparency in thin-gauge sheet

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    Part 1: Technology of Sheet Heating

    Dimensionless Groups - DefinitionsRadiation Biot number Bi r = h rL/kRadiation number Rad = LFF gs /k

    hr radiative heat transfer coefficientL half-thickness (heating on both sides)k thermal conductivityF View factorFg Emissivity factors Stefan-Boltzmann constant

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    Part 1: Technology of Sheet Heating

    Radiation concepts - Explained Emissivity, e, absorptivity, a , considered

    similar Emissivity = 1, black body Emissivity between 0 and 1 and wavelength-

    independent, gray body

    Typical polymer emissivity, 0.90 < e < 0.95 Typical polymer emissivity, e=e l),

    absorptivity, a=a l) Thin films semi-transparent, t = t l)

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    The Black Body EnergyCurve, ShowingIncreasing EnergyOutput (logarithmic

    scale, left axis),Shifting of PeakWavelength toShorter Values WithIncreasing HeaterTemperature

    Part 1: Technology of Sheet Heating

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    So What is Wavelength?

    Visible Wavelength of light: 0.4 - 0.7 mmNear-infrared: 0.7 - 2.5 mmFar-infrared (most TFing): 2.5 - 15 mm (+)

    Part 1: Technology of Sheet Heating

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    So What is Wavelength?

    Visible Wavelength of light: 0.4 - 0.7 mmNear-infrared: 0.7 - 2.5 mmFar-infrared (most TFing): 2.5 - 15 mm (+)

    Part 1: Technology of Sheet Heating

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    Part 1: Technology of Sheet Heating

    Radiation concepts - Explained Energy interchange between heater [source]

    and sheet [sink]

    What you see is what you heat! Wavelength symbol is l , units are microns

    [mm] For l < 0.38 mm, ultraviolet

    For 0.38 < l < 0.7 mm, visible For 0.7 < l < 2.5 mm, near infrared For 2.5 < l < 100 mm, far infrared Most thermoforming, l between 3 and 15 mm

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    Part 1: Technology of Sheet Heating

    IR scans for thin-gage polymers

    Note key 3.5 mm and 8 mm wavelengths

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    Part 1: Technology of Sheet Heating

    Wavelength-DependentTransmissionThrough ThinFilms ofPS

    PE

    and PVC

    [Thank you, Ircon!]

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    Part 1: Technology of Sheet Heating

    IR scans for thin-gage polymers

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    Thick - or Heavy-Gauge Heating, ShowingTemperature Profile Through Sheet

    Part 1: Technology of Sheet Heating

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    Thin-Gauge Heating ,Showing RadiantEnergy Absorbing andTransmitting ThroughFlat TemperatureProfile Sheet

    Part 1: Technology of Sheet Heating

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    Part 1: Technology of Sheet Heating

    Radiation is extremely complex Diffuse v. specular surface (textured v.

    polished sheet) Planar v. curved surface (effect of sag) Effect of pigment (differential energy

    absorption at surface)

    Radio-opaque v. volumetric absorbing Internal reflection v. transmission Reflection, absorption at multilayer interface

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    Part 1: Technology of Sheet Heating

    Radiation is extremely complex This morning we consider only the simplest of

    radiant energy transfer, viz, diffuse radiationfrom gray body heaters to planar, radio-opaque, unpigmented, gray body, single layer,amorphous sheet

    If time, we look at a slightly more complexsituation

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    Emissivity - What isit anyway? Incoming radiation iseither:

    Absorbed by theplasticReflected from theplasticTransmittedthrough the plastic

    Part 1: Technology of Sheet Heating

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    An ideal material

    absorbs all incomingradiation ( a =1)An ideal material emitsall of its energy ( e=1)

    That ideal material iscalled a black bodyMost real materialshave absorptivities,emissivities less than

    one [1]Plastics, rusty,oxidized metals haveemissivities of 0.9-

    0.95

    Part 1: Technology of Sheet Heating

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    Part 1: Technology of Sheet Heating

    Conduction Heat Transfer - Assumptions One-dimensional (thickness) Transient (time-dependent)

    Initial sheet temperature independent of sheetthickness Step change in surface temperature Surface temperature independent of sheet

    thickness Thermal properties independent of temperature Surface temperature same on both sides of

    sheet

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    Part 1: Technology of Sheet Heating

    Conduction Heat Transfer - Equation

    T(x, q) is instant temperature, q is time, a is thermaldiffusivity, x is distance into sheet

    BC1: T(x,0) = T i BC2: T(0, q) = T oBC3: (symmetry about the centerline

    of the sheet)

    2

    2

    xT T =a q or

    0== L x x

    T k

    = xT k

    xT c p q

    r

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    Part 1: Technology of Sheet Heating

    Conduction Heat Transfer -Dimensionless Equation

    Y = (T-To)/(Ti-To),Fo = aq /L2, x = x/L

    2

    2

    x = Y

    FoY

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    Part 1: Technology of Sheet Heating

    Convection Heat Transfer - Assumptions One-dimensional (thickness) Transient (time-dependent)

    Initial sheet temperature independent of sheetthickness Surface temperature dependent on thermal

    gradient, convection heat transfer coefficient

    Environmental temperature independent of sheetthickness Thermal properties independent of temperature Convection condition same on both sides of

    sheet

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    Part 1: Technology of Sheet Heating

    Convection Heat Transfer - Equation

    T(x, q) is instant temperature, q is time, a is thermal diffusivity, xis distance into sheet

    BC1; T(x,0) = T i

    BC2:

    BC3: (symmetry about the centerlineof the sheet)

    2

    2

    x

    T T =a q

    )(0 a x T T h xT

    k ==

    0== L x x

    T k

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    Part 1: Technology of Sheet Heating

    Convection Heat Transfer -Dimensionless Equations

    Y = (T-Ta)/(Ti-Ta),Fo = aq /L2, x = x/L, Bi=hL/k

    2

    2

    x = Y

    FoY

    Y BiY

    ==0x x

    01

    ==x x

    Y

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    Part 1: Technology of Sheet Heating

    Convection Heat Transfer - Graph

    Surface

    Centerline

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - Assumptions One-dimensional (thickness) Transient (time-dependent)

    Initial sheet temperature independent of sheetthickness Surface temperature dependent on radiant

    heat flux, fourth-power of temperature

    differences

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - Assumptions

    Geometric factors independent of sheet, heater

    shapes Radiant properties independent of temperature Diffuse surface absorption only (radio-opaque) Radiant boundary conditions same on both sides

    of sheet

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - Equation

    T(x, q) is instant temperature, q is time, a isthermal diffusivity, x is distance into sheet

    BC1: T(x,0) = T i

    BC2:

    BC3: (symmetry about the centerlineof the sheet)

    2

    2

    xT T =a

    q

    0== L x x

    T k

    ( )4*4*

    0 sh g

    xT T FF x

    T == s

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhat is F g?

    Fg is gray body correction factor for non-blackbody radiationIf sheet, heater emissivities ( es, eh) are

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - Equation What is F?

    F is view factor, a geometric parameterF is the measure of average fraction of energy

    transferred from the heater to the sheetsurface

    In other words, what you see is what you heat

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    Part 1: Technology of Sheet Heating

    What do heaters heat?All visible surfacesPlastic sheetHeater reflectorsOther heaters (esp. with transparent sheet)Pin-chain rails

    Heater guardsObjects outside the oven edgesOven sidewalls, shields, bafflesSag bands and other sheet supports

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    The View Factor Heaters heat what they see! Heating efficiency - From a given heater

    decreases in proportion to the square of the

    distance to the sheet, E prop.to 1/Z2

    Oven efficiency depends on minimizing energytransfer to non-sheet - rails, oven walls, etc.

    Part 1: Technology of Sheet Heating

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhat is F?

    Often the view factor is given as a number(0

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    Part 1: Technology of Sheet Heating

    Radiative Heat Transfer -Dimensionless Equations

    Y = (T-T h)/(T i-T h), Fo = aq /L2, x = x/L, Bi r=hrL/khr = radiative heat transfer coefficient

    01

    ==x x

    Y 2

    2

    x = Y

    Fo

    Y :

    :

    ( )( )2*2*** sh sh g r T T T T FF h = s

    Y BiY

    r ==0x x

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    Part 1: Technology of Sheet Heating

    Combined Conduction, Convection, RadiationEquation with Boundary Conditions

    2

    2

    x = Y

    FoY

    01

    ==x x

    Y Y Bi BiY

    r =

    =][

    0x x : :

    Keep in mind that these equations assumetemperature-independent physicalproperties and equal boundary conditionson both sides of the sheet

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    Part 1: Technology of Sheet Heating

    Combined Conduction, Convection, RadiationEquation with Boundary Conditions

    Parabolic equation with nonlinear boundaryconditions Two methods of solution

    Finite Element Analysis [FEA]

    Finite Difference Equations [FDE]

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    Part 1: Technology of Sheet Heating

    Combined Conduction, Convection, RadiationFinite Difference Equation with Boundary

    Conditions

    where 0 and N represent the top and bottomsurfaces of the sheet and where...

    ( ) iiii T FoT T FoT )1(11' = ( ) ( ) ( )4*04*0,0000,010'0 222 T T FoRad T BiT FoT T FoT T ha =

    ( ) ( ) 4*4*,,1' 222 N N h N N N N a N N N N T T FoRad T BiT FoT T FoT T =

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    Part 1: Technology of Sheet Heating

    Combined Conduction, Convection, RadiationFinite Difference Equation with Boundary

    Conditions

    k xFF Rad i g i /, s =where

    = =

    1

    1

    0

    21 N

    ii

    N avg T

    T T N

    T Average temp:

    =

    ih

    ih

    i s

    i si g F

    FF ,

    ,

    12,

    ,,

    111/1

    e

    e

    e

    e F12 is the average viewfactor, es is the sheetemissivity, e

    h is the heater

    emissivity

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    Part 1: Technology of Sheet Heating

    Combined Conduction, Convection, RadiationFinite Difference Equation with Boundary

    Conditions

    This equation is easily solved using Fortran orQ-Basic The calculated time-dependent sheet

    temperature is based on an average value for

    the energy transferred between the heater andthe surface, viz, a fixed value for the viewfactor, F

    This result may not apply to many practicalcases

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    Part 1: Technology of Sheet Heating

    The Energy Dome Cannot be predicted using average value for

    view factor, F Needs first principles in radiation

    [What is the Energy Dome?]

    [More importantly, how do you calculate it?]

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    Part 1: Technology of Sheet Heating

    The Energy DomeConcept When a sheet of finite

    dimensions is heateduniformly with a heater

    of similarly finitedimensions The center of the sheet

    is hotter than the edges The edges of the sheet

    are hotter than thecorners

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhere is the problem?

    The use of a constant value for F, the view factor

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhere is the problem?

    Consider the energyinterchange betweendifferential elementson the sheet and onthe heater

    Here, directioncosines and the solidangle radius, r, aredefined

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhere is the problem?

    The energy interchange between a heater elementdA1 and a sheet surface element dA 2 is given as

    where cos f i are the direction cosines definedearlier, and r is the distance between the twoelements

    ( ) =2 1

    212214*4*

    21coscos

    A A sh g dAdA

    r T T F q

    f f

    s

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhere is the problem?

    The equation assumes all heater elements havethe same temperature and all sheet surfaceelements have the same temperature

    The double integral correctly represents theview factor integrated over all heater elementsand all sheet surface elements

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhere is the problem?

    Now replace the differential elements withdiscrete elements, A1 and A2

    ( ) = 212 214*4*21 coscos21

    A Ar

    T T F q A A

    sh g

    f f s

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhere is the problem?

    For each of the planar heater and sheetelements, r, the spherical radius, is given as:

    222 z y xr =

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhere is the problem?

    The direction cosines and the term for r arenow combined in the double summation equation. When the local sheet and heater temperatures

    are also moved inside the double summation, the

    following equations obtain...

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhere is the problem?

    For the energy transfer from one heaterelement to all sheet elements

    For the energy transfer from all heaterelements to one sheet element

    ( ) ( )=

    2

    24*4*

    2222

    2

    121 A

    sh g AT T z y x

    z A F q

    s

    ( ) ( )= 14*4*2222

    2

    2211

    AT T z y x

    z A F q sh

    A g

    s

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhere is the problem?

    These are the new radiation boundary conditionequations They are now combined with the traditional

    convection boundary conditions

    And the finite difference equation is solved foreach heater element and each sheet element

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhere is the problem?

    As an example, a 7 x 7 matrix heaterinterchanges energy with a 7 x 7 matrix sheet The FDE is solved 49 x 49 times for each time

    step

    Because the equation is parabolic, no iterationis necessary

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhere is the problem?

    If all 49 heater elements have the sametemperature, the result is the energy dome, aspredicted

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    Part 1: Technology ofSheet Heating

    The net %energyreceived byeach elementwhen heatertemps areequaleverywhere

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    Part 1: Technology of Sheet Heating

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    Part 1: Technology of Sheet Heating

    Radiant Heat Transfer - EquationWhere is the problem?

    If the temperatures of the heater elements arenow changed by trial and error so that theentire sheet heats at the same rate, theenergy dome is flattened

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    Part 1: Technology of Sheet Heating

    The % valuesrepresent thelocal heaterflux outputchange fromthe original100%

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    Part 1: Technology of Sheet Heating

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    Part 1: Technology of Sheet Heating

    Problem Solved!

    No?

    What Assumptions Need to beRelaxed?

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    Part 1: Technology of Sheet Heating

    Problem Solved! No?What Assumptions Need to be Relaxed?

    1. Most models assume planar sheet (sheet sagsduring heating. Does this affect local heating?Art Buckel says no. Is he right?)

    [Note: cosine geometry gets brutal. The 2D modelhas been solved using catenary equations to

    describe sheet surface. The 3D model usingparabolic hyperboloid equations to describesheet surface has not. Read 4Q06 TechArticle for additional information.]

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    Part 1: Technology of Sheet Heating

    Problem Solved! No?What Assumptions Need to be Relaxed?

    2. Models assume wavelength-independent (andtherefore, temperature-independent) sheet andheater emissivities

    3. Model designed for cut sheet. What about roll-fed sheet? (Roll-fed sheet clamped on twosides, endless, multiple shots in oven)

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    Part 1: Technology of Sheet Heating

    Problem Solved! No?What Assumptions Need to be Relaxed?

    4. Convection boundary condition assumes constantair temperature, constant convection heattransfer coefficient (in thin-gauge, sheetstart-stop during transit through oven)

    5. Model designed for opaque sheet (Semi-transparent sheet is heated by volumetricenergy absorption)

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    Part 1: Technology of Sheet Heating

    Problem Solved! No?What Assumptions Need to be Relaxed?

    6. Model does not include role of pigment, fillerin sheet heating (Solid particles change thermalproperties, absorption characteristics)

    7. Model assumes amorphous polymers, so latentheat of fusion, phase boundary are not

    included8. For combustion radiant heaters, the role of

    the absorption and reradiation of combustiongases (H 2O, CO 2) needs to be included

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    Part 1: Technology of Sheet Heating

    Problem Solved! No?What Assumptions Need to be Relaxed?

    9. Diffuse absorption, reflection, reradiation fromoven walls, etc., need to be included

    10. Most models assume uniform radiant heating,

    air environment on both sides of sheet (Radiantheaters are usually at different temperatures,air is trapped against underside of sheet)

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    Part 1: Technology of Sheet Heating

    Problem Solved! No?What Assumptions Need to be Relaxed?

    11. Model assumes monolayer. Multilayerlaminates involve interfacial reflection andlocalized absorption, as well as interfacialconduction

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    Part 1: Technology of Sheet Heating

    Okay, give us an example of how just oneof these assumptions can be relaxed!

    Number 5Radio-opacity v. volumetric absorption or

    diathermanousity Beers law: Wavelength -dependent absorption is

    exponentially dependent on depth into the

    plasticPrimary assumptions: Sheet remains planar; onlydiffuse absorption, reflection

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    Part 1: Technology of Sheet Heating

    Reflectivity andtransmissivity of athick semi-transparent sheetof plastic

    Properties aredetermined throughray tracing

    Okay, give us an example of how just oneof these assumptions can be relaxed!

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    Part 1: Technology of Sheet Heating

    Okay, give us an example of how just oneof these assumptions can be relaxed!

    Transmission is given as

    Where k2 is the Beers law absorption coefficient,l 0 is the wavelength of the incident energy andd/cos q2 is the distance the radiant beamtravels through the plastic in one pass

    20222 cos/4cos/ q l q k t d k d ee ==

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    Part 1: Technology of Sheet Heating

    Okay, give us an example of how just oneof these assumptions can be relaxed!

    Reflectivity at the interface of the sheet surfaceis usually given in terms of the relative indices

    of refraction at the interface

    2

    2

    21

    2112

    1

    1

    =

    =

    plastic

    plastic plasticair n

    nnn

    nn

    r

    r

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    Part 1: Technology of Sheet Heating

    Okay, give us an example of how just oneof these assumptions can be relaxed!

    Reflectivity from the sheet is given as

    Where r is the reflectivity at both inner andouter sheet surfaces and t is the transmissivityof a single pass through the sheet. Note: thesevalues are wavelength-dependent!

    ( )=22

    22

    11

    1t r t r

    r sheet R

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    Part 1: Technology of Sheet Heating

    Okay, give us an example of how just oneof these assumptions can be relaxed!

    Transmissivity through the sheet is given as

    ( )22

    2

    1

    1

    t r

    t r =

    sheet

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    Part 1: Technology of Sheet Heating

    Okay, give us an example of how just oneof these assumptions can be relaxed!

    Absorptivity within the sheet is given as

    ( )( ) rt

    t r =1

    11 sheet

    A

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    Part 1: Technology of Sheet Heating

    Okay, give us an example of how just oneof these assumptions can be relaxed!

    The general heat conduction equation now includesa term, q, for volumetric energy absorption:

    ( ) xT q xT

    xT c p ,l q

    r

    =

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    Part 1: Technology of Sheet Heating

    Okay, give us an example of how just oneof these assumptions can be relaxed!

    Has this problem been solved? Yes, analytically, inthe 1970s [Progelhof, Quintiere and Throne]for coextruded clear PMMA-pigmented ABS.The general effect of increasing volumetricabsorption is a flattening of the time-dependent temperature profile.

    Viz, the instant surface temperature does notincrease as rapidly as with radio-opaque sheetwhile the instant internal temperatures increasemore rapidly

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    Part 1: Technology of Sheet Heating

    End of

    Part 1

    Technology of Sheet Heating

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    Part 1: Technology of Sheet Heating

    Part 2

    Constitutive Equations Applied to SheetStretching

    Begins promptly at 9:00!