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Groups (families) Vertical columns Group # = # of valence electrons (# of electrons
in outer shell) 18 groups or families Some properties repeat in an orderly way Example – Li, Na, K, Rb, Cs, and Fr are all soft
metals which react violently with water.
Periods Horizontal rows (7 rows)
Period # = All elements in a period have electrons on the same energy level.
History of the Groupings within Periodic Table☺Dmitri Mendeleev looked for patterns
within the properties of elements.☺Mendeleev organized elements by
atomic mass.☺He found patterns where the properties
were repeated at regular intervals☺Mendeleev was able to predict
properties of elements not yet discovered in 1871.
History Continued☺Arranging the periodic table by atomic
mass is not foolproof. Once the protons were discovered 40 years later, Henry Moseley arranged the elements by atomic number. This removed problems in the original table.
Groups (families)1
2
3 4 5 6 7 8 9 10
11 12
13
14
15
16
17
18
Alk
ali
Meta
lsA
lkalin
e
Eart
h
Halo
gen
sN
ob
le
Gases
Oxyg
en
Fam
ily
Nit
rog
en
Fam
ily
Carb
on
Fam
ily
Boro
n F
am
ilyB CN O
H
Group 1 metals Called alkali metals. They all react violently with nonmetals.
They have 1 valence electron which they lose very easily.
Li is the least reactive, Fr is the most reactive They are all soft They are not found in nature because they
are so reactive.
Why?
Group 2 metals
Called Alkaline Earth Metals
They have 2 valence electrons.
They are harder and less reactive than group 1 metals.
Group 17Called halogens
Most reactive nonmetals
They all have 7 valence electronsThey react with metals to form
“salts”
Why?
Group 18
Called Noble gasesThey don’t react
They have 8 valence electrons (except Helium)This is a full outer level (Octet Rule)
Why?
Metals, Non-metals, & Metalloids
METALS- to the left of the staircase; tend to lose electrons easily; form positive ions
NON-METALS- to the right of the staircase; tend to gain electrons easily; form negative ions
METALLOIDS- border the staircase (exceptions are Al and Po)
BSiGe
AsSb
TeAtMETALS
METALLO
IDS
MetalsMost elements are metals
Metals are good conductors of heat and electricity
Metals are ductile (can be squeezed into a wire)
Metals are malleable (can be hammered or bent)
Transition MetalsGroups 3 – 12
They have many different propertiesLess reactive than alkaline earth metals
Some are fairly non-reactive (Cu, Ag, Au)Tungsten has the highest melting pointMercury is a liquid with high density
Metals can be mixed together (alloy) to produce desirable properties.
Periodic TrendsAtomic RadiusIonization EnergyElectron AffinityElectronegativity
IonDefinitionIon: an atom that has gained or lost electrons
Cation = Positively charged atom + Anion = negatively charged atom -(anion has an n like negative)
Atomic Radius Definition
The distance from the nucleus to the boundary of the surrounding cloud of electrons.
Period Trend Radius decreases as you go across. The nucleus become more positive and it pulls the
electrons in tighter Group Trend
Radius increases as you go down. There are more energy levels so the electrons are at a
greater distance from the nucleus
Atomic Radius Atomic radii decrease from left to right across a
period and increase down a group as shown below
Atomic Radius As you go across the period, there are
more protons (greater effective nuclear charge) and therefore a greater attraction pulls the electrons closer to the nucleus and decreases the size of the atom
Ionization Energy
Definition Energy required to remove an electron from an atom
of an element. If an electron is easy to remove, it takes little energy
Period Trend Ionization Energy increases as you go across. The nucleus become more positive and therefore it is
harder to pull electrons off. Group Trend
Ionization Energy decreases as you go down. As you go down the number of energy levels
increases, therefore the electrons are farther away from the nucleus and are more easily removed.
Ionization Energy
Electron Affinity Definition
Energy change when an atom gains an electron Period Trend
Electron Affinity increases as you go across. (The value becomes more negative – meaning more
exothermic – electrons are more easily gained) Group Trend
General trend is to decrease (become more positive) as you go down a group.
It is more difficult to add electrons to larger atoms [outer E levels are farther away from the positive nucleus.]
Bigger Atom!
Electron Affinity
Electronegativity Definition
The tendency of an atom to attract electrons to itself when it is combined with another atom.
Assigned numbers 0-4
Period Trend Electronegativity increases as you go across.
Group Trend Electronegativity decreases as you go down.
The most electronegative element is Fluorine (F)The least electronegative element is Cesium (Cs)