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APPLICATION BULLETIN | Elevance Clean ® | Transportation MRO ELEVANCE CLEAN ® – TRANSPORTATION MRO Cleaning is a critical step preceding the scheduled maintenance and unscheduled repairs that keep commercial fleets in service. Maintaining semi-truck, rail car, locomotive, automobile and aircraft fleets requires cleaning products that deliver a high degree of performance and efficiency for both in-field and in-shop uses. This is not a trivial task, as many soils have been exposed to high temperatures over extended periods of time, making parts and other surfaces especially resistant to cleaning. At the same time, increasing regulations on the volatile organic compound (VOC) content in formulated cleaning products have made cleaning even more difficult. Restrictions on the use of traditional ingredients, such as aromatic hydrocarbons and d-limonene, represent another hurdle to achieving acceptable cleaning performance. The improved safety profile of Elevance Clean ® ingredients gives you the ability to develop products that meet your customers’ most challenging cleaning needs. Grease, Oil, Tar, Asphalt and Sealcoat Removal Consumer and Industrial Ingredients 1 OSHA Standard 29 CFR 1910.106 2 Directive 2004/42/CE of the European Parliament and the Council 3 Title 40 CFR 59.203 – Standards for consumer products (U.S.) Figure 1. ASTM D93 | Flash Point by Pensky-Martens Closed Cup Tester. Elevance Clean ® ingredients are non-flammable in accordance with OSHA designations, imparting an added element of safe handling and transportation. 0.0 25.0 50.0 75.0 100.0 125.0 150.0 175.0 200.0 OXIDATION ONSET TEMPERATURE (°C) 178.9 Elevance Clean 1000 Elevance Clean 1200 165.0 126.1 Methyl Soyate 138.8 167.3 Aromatic 150™ 174.2 d-LIMONENE Methyl Caprylate/ Caprate 0 50 100 150 200 250 300 350 Elevance Clean 1000 Elevance Clean 1200 METHYL SOYATE 333 AROMATIC 150 d-LIMONENE RHODIASOLV ® IRIS INITIAL BOILING POINT (°C) 250° C 1 216° C 2 233 267 184 176 196 0 Elevance Clean 1000 Elevance Clean 1200 20 40 60 80 100 120 140 160 180 200 102 127 93° C 1 62 METHYL SOYATE 43 130 AROMATIC 150 98 d-LIMONENE RHODIASOLV ® IRIS FLASH POINT (CLOSED CUP, ºC) Figure 3. ASTM E2009 | Oxidation Onset Temperature Using Pressurized Differential Scanning Calorimeter. Elevance Clean ® ingredients demonstrate higher oxidative stability and lower vapor pressure at elevated temperatures relative to other solvents, affording a better safety profile. Figure 2. ASTM D2887 | Boiling Range Distribution of Petroleum Fractions by Gas Chromatography. Elevance Clean ® 1200 exceeds VOC exempt classification requirements for the EU and U.S. 2,3 Elevance Clean ® 1000 is an LVP-VOC. It meets VOC exempt classification requirements for the U.S. only. 3 The Elevance Clean ® 1200 product line consists of two products containing the same active material. Elevance Clean ® 1200XA is a cleaning ingredient without added fragrance. Elevance Clean ® 1200HT is Elevance Clean ® 1200XA with fragrance added. The technical performance of both products is identical. All references to Elevance Clean ® 1200 in this document refer to both products.

Grease, Oil, Tar, Asphalt and - Renewable Sciences · 2016. 7. 13. · Grease, Oil, Tar, Asphalt and Consumer and Industrial Ingredients Sealcoat Removal 1OSHA Standard 29 CFR 1910.106

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  • APPLICATION BULLETIN|Elevance Clean® | Transportation MRO

    ELEVANCE CLEAN® – TRANSPORTATION MRO

    Cleaning is a critical step preceding the scheduled

    maintenance and unscheduled repairs that keep

    commercial fl eets in service. Maintaining semi-truck,

    rail car, locomotive, automobile and aircraft fl eets

    requires cleaning products that deliver a high degree

    of performance and effi ciency for both in-fi eld and

    in-shop uses. This is not a trivial task, as many

    soils have been exposed to high temperatures over

    extended periods of time, making parts and other

    surfaces especially resistant to cleaning.

    At the same time, increasing regulations on the

    volatile organic compound (VOC) content in formulated

    cleaning products have made cleaning even more

    diffi cult. Restrictions on the use of traditional

    ingredients, such as aromatic hydrocarbons and

    d-limonene, represent another hurdle to achieving

    acceptable cleaning performance. The improved

    safety profi le of Elevance Clean® ingredients gives

    you the ability to develop products that meet your

    customers’ most challenging cleaning needs.

    Grease, Oil, Tar, Asphalt and Sealcoat RemovalConsumerandIndustrialIngredients

    1OSHAStandard29CFR1910.1062Directive2004/42/CEoftheEuropeanParliamentandtheCouncil3Title40CFR59.203–Standardsforconsumerproducts(U.S.)

    Figure 1. ASTM D93 | Flash Point by Pensky-Martens Closed Cup Tester. ElevanceClean®ingredientsarenon-flammableinaccordancewithOSHAdesignations,impartinganaddedelementofsafehandlingandtransportation.

    0.025.050.075.0

    100.0125.0150.0175.0200.0

    OXIDATION ONSET TEMPERATURE (°C)

    178.9

    Elevance Clean™ 1000

    Elevance Clean™ 1200

    165.0

    126.1

    Methyl Soyate

    138.8167.3

    Aromatic150™

    174.2

    d-LIMONENE Methyl Caprylate/Caprate

    050100150200250300350

    Elevance Clean™ 1000

    Elevance Clean™ 1200

    METHYL SOYATE

    333

    AROMATIC150™

    d-LIMONENE RHODIASOLV®IRIS

    INITIAL BOILING POINT (°C)

    250°

    C1

    216°

    C2

    233 267

    184 176196

    0Elevance

    Clean™ 1000Elevance

    Clean™ 1200

    20406080100120140160180200

    102127

    93°

    C1 62

    METHYL SOYATE

    43

    130

    AROMATIC150™

    98

    d-LIMONENE RHODIASOLV®IRIS

    FLASH POINT (CLOSED CUP, ºC)

    Figure 3. ASTM E2009 | Oxidation Onset Temperature Using Pressurized Differential Scanning Calorimeter.ElevanceClean®ingredientsdemonstratehigheroxidativestabilityandlowervaporpressureatelevatedtemperaturesrelativetoothersolvents,affordingabettersafetyprofile.

    Figure 2. ASTM D2887 | Boiling Range Distribution of Petroleum Fractions by Gas Chromatography.ElevanceClean®1200exceedsVOCexemptclassificationrequirementsfortheEUandU.S.2,3ElevanceClean®1000isanLVP-VOC.ItmeetsVOCexemptclassificationrequirementsfortheU.S.only.3

    TheElevanceClean®1200productlineconsistsoftwoproductscontainingthesameactivematerial.ElevanceClean®1200XAisacleaningingredientwithoutaddedfragrance.ElevanceClean®1200HTisElevanceClean®1200XAwithfragranceadded.Thetechnicalperformanceofbothproductsisidentical.

    AllreferencestoElevanceClean®1200inthisdocumentrefertobothproducts.

  • Industry Certifications

    •VOC-exempt(40CFR59.203—Standardsforconsumerproducts(U.S.)

    •TSCA-listedandREACh-registered

    •CaliforniaARBLVPVOC(CARBMethod310)

    •ReadilybiodegradablebyOECDMethod301

    •Non-flammable(ASTMD-93)byOSHAstandard29CFR1910.106

    •ReviewedbyEPA’sSaferChoiceprogramandqualifiesforuseinSaferChoice-labeledproducts

    •FreeofcomponentslistedEUDangerousSubstancesDirective(RegulationNo.1272/2008)

    •ListedintheUSDABioPreferred®catalogue

    ELEVANCE CLEAN® | TRANSPORTATION MRO

    Grease and Oil Removal

    Inmanymaintenanceandrepairoperations,itisnecessarytoremovegreasesandoilsbeforeperformingthesefunctions.ThesuperiorperformanceandimprovedsafetyprofileofElevance Clean® ingredients allow formulators to overcome the cleaning shortcomings resulting from tighter restrictions on VOCs and powerful but enviromentally harmful surfactants like alkylphenol ethoxylates.

    Applications

    ElevanceClean®ingredientsareextremelyeffectiveandcanbeformulatedtoboostcleaningperformanceinproductstargetedtoremovemanycommonandhard-to-treatsoils.Eachoneisapowerfulpenetrantfortoughsoilsthat,whenusedinformulatedcleaningproducts,providessuperiorcleaningperformance.

    Targetsoilsincludebutarenotlimitedto:

    Soil ElevanceClean®1200 ElevanceClean®1000

    GearGrease X X

    Asphalt X X

    CrudeOil X X

    Lubricants X

    Tar X X

    IndustrialOil X

    Sealcoat X X

    Motor Oil & Lithium Grease Removal by Immersion Cleaning

    ElevanceClean®solventsaremuchmoreeffectiveintheremovaloftenacious,persistentgreaseinimmersioncleaning,meetingandexceedingevenaromaticsolventperformance.

    Lithium Complex Grease Removal by Mechanical Cleaning

    ASTMD4488|TestingCleaningPerformanceofProductsIntendedforUseonResilientSurfaces

    Figure 5. Multi-Purpose Lithium Grease Removal

    Figure 4. Motor Oil & Lithium Grease Removal

    0.0

    1.0

    0.5

    2.0

    1.5

    3.0

    2.5

    3.52.9

    2.1

    0.6

    1.3

    0.10.4

    % REMOVAL PER CYCLE

    Elevance Clean™ 1200

    Elevance Clean™ 1000

    d-Limonene Aromatic 150™ MethylSoyate

    RhodiaSolv®IRIS

    Testing Methodology Section: 1

    Multi-Purpose Lithium Grease RemovalCuredlithiumgrease|3"x3"0.5-mm-thickfilmcenteredon3"x6"plate|24hcure@80C|10mLsolvent-imbibedcellulosesponge|Gardnerscrubapparatus|Cycledtoachieve80%removal(visual)|Imageanalysisquantification

    0

    20

    10

    40

    30

    60

    50

    21.4

    Elevance Clean™ 1200

    Elevance Clean™ 1000

    Isopar™ L Aromatic 150™

    22.5

    Exxsol™ D60

    50.1

    Methyl Soyate

    22.3

    50.148.1

    AVERAGE TIME (MINUTES) TO COMPLETE REMOVAL

  • ELEVANCE CLEAN® | TRANSPORTATION MRO

    Asphalt/Tar Removal Using Water-Based Formulations

    ModifiedASTMD4488|TestingCleaningPerformanceofProductsIntendedforUseonResilientSurfaces

    Asphalt/Tar Removal Using Solvent-Based Formulations

    Tar, Asphalt and Sealcoat Removal

    FormulatingcleaningproductswithElevanceClean®ingredientsprovidestheneededcleaningstrengthinremovingthesedifficult-to-removesoils.UseofElevanceClean®ingredientsinformulationscanmakethecleaningprocessbothmoreeffectiveandefficient.Thisiscriticalinapplicationssuchascleaningasphaltandtarfromtrucks,railcarsandautomotiveparts.ElevanceClean®1200retainsitscleaningperformanceatcoldtemperatures,reducingtheneedtocleanequipmentatcolderambientconditionsorduringwintermonths.

    Ingredient % by Weight

    ElevanceClean®1200 5

    BIO-SOFT®N91-6orEmpilan®KR6 5

    BIO-SOFT®D-40 12.5

    Dowanol™DPnB 5

    Water 72.5

    Ingredient % by Weight

    ElevanceClean®1200 0.5

    BIO-SOFT®N91-6orEmpilan®KR6 2.5

    AMMONYX®LOorUfanonCAPB 0.5

    SodiumCitrate 0.5

    Water 96

    ElevanceClean®1200notonlydoesanexcellentjobatremovingasphaltandtaratambienttemperatures,butexcelsatremovingthesechallengingsoilsatlowtemperaturesforbothroutine,low-concentrateformulationsandmoreconcentratedsprayandrinseformulations(usedformoreheavilysoiledsurfaces).

    Figure 6. Asphalt Spray and Rinse Cleaning Performance. Higher-concentrationsprayandrinseformulationusingdifferentcleaningagents.

    Figure 7. Asphalt Removal by Mechanical Cleaning (low-concentration, ready-to-use formulation).Low-concentrationsprayandrinseformulationforroutinecleaningusingdifferentcleaningagents.

    Testing Methodology Section: 3

    Asphalt/Tar Removal - Water-Based FormulationsModifiedASTMD4488|TestingCleaningPerformanceofProductsUsingGardnerAbrasionTester5mLformulation-imbibedcellulosesponge.Gardnerscrubapparatusiscycledtoachieve80%removal(visual).Imageanalysisquantification.3"x6"x1/8"stainlesssteelplatesarecoatedinauniformfilmwithdrivewayasphaltsealcoat.Thesoiledtestspecimensarecuredfor24hat23Cpriortotesting.Cellulosespongesareimbibedwith5mLofeachtestformulationandtheautomatedabrasiontestensues.TheGardnerscrubapparatusiscycled30timesatarateof30cyclesperminute.Cleaningisquantifiedusingimageanalysissoftware.

    0%

    10%

    20%

    30%

    40%

    50%

    60%

    70%

    80%

    90%

    100%

    30%

    20%

    75%

    50%

    90%

    AMBIENT TEMPERATURE (25°C)

    5% 5% 5%

    15%

    80%

    COLD TEMPERATURE (-10°C)

    AVG % ASPHALT REMOVED IN 30 CYCLES

    ISOPAR™ M

    ISOPAR™ HMINERAL SPIRITSELEVANCE CLEAN™ 1200

    METHYL LAURATE

    0%

    10%

    20%

    30%

    40%

    50%

    60%

    70%

    80%

    90%

    100%

    76.4%74.8%

    78%

    46.4%

    71%

    90%

    AMBIENT TEMPERATURE (25°C) COLD TEMPERATURE (-10°C)

    AVG % ASPHALT REMOVED IN 30 CYCLES

    DOWANOL™ DPnB

    d-LIMONENE

    ELEVANCE CLEAN™ 1200

    0.00

    10.00

    20.00

    30.00

    40.00

    50.00

    60.00

    70.00

    80.00

    90.00

    100.00

    39.59

    12.88

    81.35

    20.11

    83.99

    29.92

    79.37

    6.90

    54.34

    10.12

    62.35

    95.98

    Elevance Clean™ 1000

    Elevance Clean™ 1200

    d-Limonene Exxsol™ D60 Exxsol™ D110 Isopar™ L

    % ASPHALT REMOVAL

    40 CYCLES

    20 CYCLES

    Figure 8. Asphalt Spray and Rinse Cleaning Performance. Higher-concentrationnon-aqueoussprayandrinseformulationusingcleaningagents.

    Testing Methodology Section: 2

    Asphalt/Tar Removal - Solvent-Based Formulations3"x6"x1/16"stainlesssteelplatepaintedwithauniformfilmofdrivewaysealcoattar|24hcure@23C|5mLsolvent-imbibedcellulosesponge|Gardnerscrubapparatus|Formulation:80%solvent,10%emulsifier,10%rinseaid.

  • LEVERAGE THE SUPERIOR CLEANING PERFORMANCE OF ELEVANCE CLEAN® 1200 TO BUILD YOUR BUSINESS.

    ELEVANCE CLEAN® | TRANSPORTATION MRO

    TO LEARN MORE AND REQUEST A SAMPLE:

    FOR CLEAN 1000:

    FOR CLEAN 1200:

    www.elevance.com/clean1000

    www.elevance.com/clean1200 877-215-2795 [email protected]

    HeadquarteredinWoodridge,Ill.,ElevanceRenewableSciences,Inc.isahigh-growthspecialtychemicalcompanythatcreatesnovelspecialtychemicalsthatperformbetterfromrenewablefeedstocks,makingtheproductsthatindustryandconsumersuseeverydaybetter.Usingaproprietarytechnologycalledolefinmetathesis,thecompanyhelpsindustrydeliverproductsthatexceedtheperformanceofexistingproductswhileleavingasmallerenvironmentalfootprint—foruseinpersonalcareproducts,detergentsandcleaners,engineeredpolymers,lubricantsandadditivesandotherspecialtychemicalsmarkets.Visitwww.elevance.com.

    Copyright©2016ElevanceRenewableSciences.Allrightsreserved

    Typical Formulations

    Table 1. Ready-to-Use (1)

    Ingredient % by Weight

    ElevanceClean®1200 5

    BIO-SOFT®N91-6orEmpilan®KR6 5

    Calsoft®L40 12.5

    STEPANATE®SXS-40 5

    Water 72.5

    TOTAL 100

    Table 2. Ready-to-Use (2)

    Ingredient % by Weight

    ElevanceClean®1200 0.5

    BIO-SOFT®N91-6orEmpilan®KR6 2.5

    AMPHOSOL®CAorAMMONYX®LO 0.5

    SodiumCitrate 0.5

    Water 96

    TOTAL 100

    Table 3. Dilutable Concentrate (1)

    Ingredient % by Weight

    ElevanceClean®1200 20

    Tergitol™15-S-7orSynperonic™L7 10

    Calsoft®L40 25

    STEPANATE®SXS 6

    EDTADisodiumSalt 0.3

    Water Balanceto100

    Table 4. Dilutable Concentrate (2)

    Ingredient % by Weight

    ElevanceClean®1000 24

    BIO-SOFT®N91-6orEmpilan®KR6 60

    Dowanol™DPM 16

    TOTAL 100

    Table 5. Spray and Rinse (1)

    Ingredient % by Weight

    ElevanceClean®1200orElevanceClean®1000 80

    Tomadol®91-2.5orBerol®533 10

    Dowanol™DPM 10

    TOTAL 100

    Table 6. Spray and Rinse (2)

    Ingredient % by Weight

    ElevanceClean®1200orElevanceClean®1000 90

    Tergitol™15-S-7orSynperonic™L7 5

    Tergitol™15-S-9orSynperonic™A9 5

    TOTAL 100

    Asof07-13-2016