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General overview on natural CO 2 sinks in Austria based on existing literature data – A first step towards the evaluation of possible monitoring sites GOETZL G., BRUESTLE A.K. & BOTTIG M. October 17-19, 2011 Maria Laach, Germany 2 nd CGS Europe Knowledge Sharing Workshop Natural Analogues

General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

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Page 1: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

General overview on natural CO2 sinks in Austria based on existing literature data –

A first step towards the evaluation of possible monitoring sites

GOETZL G., BRUESTLE A.K. & BOTTIG M.

October 17-19, 2011Maria Laach, Germany

2nd CGS Europe Knowledge Sharing WorkshopNatural Analogues

Page 2: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

• Estimated CO2 capacities

(SCHARF & CLEMENS, 2006)

- 11 largest oil & 13 largest gas reservoirs

- 465 MM t CO2 (depleted reservoirs)

The present role of CO2 geological storage in Austria

• Legal Aspects (transposition of EU directive)

- Ban on industrial application of CO2 geological storage

- Exception: Research purposes with maximum load < 100ktons

- Re-evaluation of national CCS law: 2018 (reporting by ministry)

October 17-19, 2011Maria Laach, Germany

2nd CGS Europe Knowledge Sharing WorkshopNatural Analogues

• Public opinion on CCS: quite critical

- 9 methane storage sites

- total capacity: 6.65 Gm³

Austrian Newspaper „Der Standard“, 29.11.2010

Methane storage sites in Austria © RAG Austria, 2011

Page 3: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

CO2 appearances in Austria – two major geological settings

Related to fault systems striking perpendicular to the periadriatic lineament

Tertiary intramontaneous basins (e.g. Vienna Basin, Styrian Basin)

Styrian BasinFormation of the basin through extensional tectonicsPresence of CO2 related to plio-/pleistocene vulcanic activity

Page 4: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

Bad Blumau

Bad Eisenkappel

Bad Schoenau

Wildbad Einoed

Page 5: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

Case Study Bad Blumau

Page 6: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

Bad Blumau

Deeply burried, palaeozoicdolomites of the basement

Highly fractured reservoir

Drillings in the area of an antithetic structure of thepalaeozoic basement

Page 7: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

October 17-19, 2011Maria Laach, Germany

2nd CGS Europe Knowledge Sharing WorkshopNatural Analogues

Case Study Bad Blumau

Key Facts• 2 different reservoirs (basement, Neogene fillings)

• Combined spa, heating facility & ORC electric power generation

• Reinjection neccessary

Page 8: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

October 17-19, 2011Maria Laach, Germany

2nd CGS Europe Knowledge Sharing WorkshopNatural Analogues

Case Study Bad BlumauThe spring „Vulkania“ issue..• Formation T > 120°C

• Outflow T ~ 110°C

• Reservoir Depth ~ 2800m

• Free yield 80l/s (gaslift)

• Production yield 30l/s

• TDS: 17,6 g/l

• Gas : water 9:1(97%CO2)

• Dissolved CO2 ~ 5mg/kg

• CO2 liquified 1.5 t/h!!

• Closed or semi-open aquifer (?)

Page 9: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

Bad Schoenau

Thermal waters and natural CO2 influenced by major fault system confining an intra-mountainous basin (Miocene)

Porous secondary reservoir

Exploration on CO2 for therapeutic reasons!

Page 10: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

Bad Schoenau

Fluids trapped by unsuccessful coal drilling at depth of 230m below surface (in 1953)

High content of SO4-- (related to coaly layers)

67l/min H2O, 227l/min gas (~97%CO2)

Altering eruptive and laminar flow, frequency: 45s

1990: > 100.000 treatments p.a. (bathing, drinking)

Page 11: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

Wildbad EinoedCrystalline and sedimentary rocks of the Middle- Austroalpine are overthrusted by the Upper-Austroalpine Gurktal Nappe

This complex is heavily faulted

Valley follows a NNE

striking fault which

seperates horizontally

lying phyllites from the

eastern side of the

valley (crystalline)

Page 12: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

Wildbad Einoed

High values of diverse trace elements indicate a degasing of the upper mantle

Thermal waters mixed with surface waters

Widespread ascentthrough mass movements

Page 13: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

Wildbad Einoed

Amount of used thermal waters 10l/sec

140 flat boreholes – 10.7 Vol% max. CO2 in the soil air (0.1-2%)

Page 14: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

Bad EisenkappelUpper tertiary fault systems ruptured the eastern part of the Karawanks into huge blocks

Magmatic intrusions

Joints giving way for water and gas

Granites build the valley bottom topped by fluviatile gravel

3He/4He isotopes prove mantle origin

Page 15: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

Bad Eisenkappel

1909: first tapping and balneologic use

Deepest well 120 m – highest mineralization

Widespread gas exhalations in valley

Mixed surface near and deep waters

Used for treatments in form of bathing and drinking

1 proven fatality: builder suffocated in a construction pit. During the night the 10m3 of the pit were filled with CO2 exhalated nearby

Page 16: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

Summary & ConclusionsCO2 appearance in the eastern and southeastern part of Austria

Economical use of natural CO2 (nutrition industry, therapeutical treatments)

Extend studies for possible storage sites including saline aquifers (e.g. Vienna Basin)

No monitoring and no scientific research so far -establish monitoring sites (e.g. Wildbad Einöd)

Page 17: General overview on natural CO sinks in Austria A first ... Workshop... · Bad Blumau Deeply burried, palaeozoic dolomites of the basement ... Case Study Bad Blumau Key Facts •

General overview on natural CO2 sinks in Austria based on existing literature data –

A first step towards the evaluation of possible monitoring sites

CONTACT: [email protected]

October 17-19, 2011Maria Laach, Germany

2nd CGS Europe Knowledge Sharing WorkshopNatural Analogues

THANKS FOR YOUR ATTENTION