1
266 U.S. BUREAU OF CHEMISTRY NOTES. [J. F. I. 2 3 per cent. of saturated acids and 72.5 per cent. of unsaturated acids as determined by the lead-salt-ether method. The iodine value (Hanus) of the unsaturated acids was 142.2, th.e saponifi- cation number was 199.4, and the mean molecular weight was 281. 3 . In addition to the separation and identification of stearic and arachidic acids, a small amount of myristic ~icid was found which has not been pr.eviously reported as occurring in cottonseed oil. The following table gives the percentages of the acids found from which the corresponding glycerides were calculated: Acid. Per cent in Original Per cent in OriginaI Oil Acids. Oil Glycerides. Myristic ...................... o.32 0.34 Palmitic ...................... i9.io 20.04 Stearic ....................... 1.9o 1.96 Arachidic ...................... 56 .58 Oleic ......................... 33.i5 35.17 Linolic ....................... 39.35 41.74 Galvanomagnetic Effect Parallel to the Lines of Force and Perpendicular to the Current. LA Rosa and A. SELLERIO. (Comp- tes Rendus, June 14, I92O.)--If an electric current flows along a sheet of bismuth, the ends of two wires joined to a galvanometer may be put in contact with two points on the bismuth so located that they are at the same potential. In this case no current flows through the instrument. If, now, a strong magnetic field is ap- plied with its lines of force at right angles to the sheet of bismuth, a current shows itself in the galvanometer. The magnetic field has distorted the lines of flow of the current (Hall effect). The two experimenters placed a cylinder of bismuth between the poles of a Weiss electromagnet with its axis parallel to the lines of force. A current was sent from one side of the cylinder to the other and the ends of the wires from the galvanometer were soldered to points on the end of the cylinder which were at the same potential, when the magnetic field was absent. When the field was excited there was a permanent deflection of the gal- vanometer, which was reversed in direction when the field was reversed. The deflections in the directions were by no means alike in size. The authors conjecture that there are two effects superimposed, one of which reverses with the field while the other does not. The difference between this new phenomenon and the Hall effect is in this, that in the latter the effect is perpendicular to the direction of the current, while in the newly discovered effect it is manifested along the magnetic lines of force. G. F. S.

Galvanomagnetic effect parallel to the lines of force and perpendicular to the current : La Rosa and A. Sellerio. (COmptes Rendus, June 14, 1920.)

  • Upload
    gfs

  • View
    212

  • Download
    0

Embed Size (px)

Citation preview

2 6 6 U . S . B U R E A U OF C H E M I S T R Y NOTES. [J. F. I.

2 3 per cent. of sa tura ted acids and 72.5 per cent. of unsa tu ra ted acids as de te rmined by the lead-sal t -e ther method. T h e iodine value ( H a n u s ) of the unsa tu ra ted acids was 142.2, th.e saponifi- cat ion n u m b e r was 199.4, and the mean molecular weight was 281. 3 .

In addi t ion to the separa t ion and identification of stearic and arachidic acids, a small a m o u n t of myr is t ic ~icid was found which has not been pr.eviously repor ted as occur r ing in cot tonseed oil.

The fol lowing table gives the percentages of the acids found f r o m which the cor responding glycerides were calculated:

Acid. Per cent in Original Per cent in OriginaI Oil Acids. Oil Glycerides.

Myr i s t i c . . . . . . . . . . . . . . . . . . . . . . o.32 0.34 Palmitic . . . . . . . . . . . . . . . . . . . . . . i9.io 20.04 Stearic . . . . . . . . . . . . . . . . . . . . . . . 1.9o 1.96 Arachidic . . . . . . . . . . . . . . . . . . . . . . 56 .58 Oleic . . . . . . . . . . . . . . . . . . . . . . . . . 33.i5 35.17 Linolic . . . . . . . . . . . . . . . . . . . . . . . 39.35 41.74

Galvanomagne t i c Effec t Para l le l to the L ines of Force and Perpend icu la r to the Current . LA Rosa and A. SELLERIO. (Comp- tes Rendus, June 14, I92O. ) - - I f an electric cur rent flows a long a sheet of b i smuth , the ends of two wires joined to a g a l v a n o m e t e r m a y be put in contac t wi th two points on the b i smuth so located tha t they are at the same potential . In this case no cur ren t flows th rough the ins t rument . If, now, a s t rong magne t ic field is ap- plied wi th its lines of force at r ight angles to the sheet of b ismuth , a cur rent shows itself in the ga lvanomete r . T h e magne t i c field has d is tor ted the lines of flow of the cur rent (Hal l effect) .

The two exper imen te r s placed a cyl inder of b i smuth be tween the poles of a Wei s s e l ec t romagne t wi th its axis parallel to the lines of force. A current was sent f rom one side of the cyl inder to the other and the ends of the wires f rom the g a l v a n o m e t e r were soldered to points on the end of the cyl inder which were at the same potential , when the magne t i c field was absent. W h e n the field was excited there was a p e r m a n e n t deflection of the gal- vanomete r , which was reversed in direction when the field was reversed. T h e deflections in the direct ions were by no means alike in size. T h e au thors conjec ture tha t there are two effects super imposed , one of which reverses wi th the field while the o ther does not. The difference be tween this new phenomenon and the Hal l effect is in this, tha t in the la t ter the effect is perpendicular to the direction of the current , while in the newly discovered effect it is mani fes ted a long the magne t i c lines of force.

G. F. S.