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27 May 2015 Townsville, Queensland, Australia Subproject 2 Geology of the Mt Carlton high- sulphidation deposit Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac Corral and Mark Stokes EGRU, JCU [email protected] Introduction to the Mt Carlton deposit and the purpose of this project Recent work and preliminary results Forward plan Contents of talk

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Page 1: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

27 May 2015Townsville, Queensland, Australia

Subproject 2 Geology of the Mt Carlton high-

sulphidation deposit

Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac Corral and Mark Stokes

EGRU, [email protected]

• Introduction to the Mt Carlton deposit and the purpose of this project

• Recent work and preliminary results

• Forward plan

Contents of talk

Page 2: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

Significance• Best indication for porphyry mineralisation in this region Highest potential to find a porphyry deposit Boost exploration interest in north Queensland

Sillitoe, 2010

The Mt Carlton deposit

• Located ~150 km south of Townsville

From Evolution Mining

Page 3: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

• High-sulphidationepithermal (Au-Ag-Cu) deposit

• Current total resources: 20 Mt @ 2.5 g/t Au, 36 g/t Ag and 0.28% Cu (Dec 2013)

• Open pit mining commenced in 2013

The Mt Carlton deposit

The V2 pit at Mt Carlton

• Located in the northern Bowen Basin

• Hosted in the Lizzie Creek Volcanic Group – which comprises rhyoliticto andesitic volcanics and terrestrial sediments

• Additional LS- and HS epithermal and porphyry mineralisation in the area

The Mt Carlton deposit

Mt Dillon

Mt Abbot

Matrimony ridge

Otter ridge

Stockyard Creek

The SpringsEuri Creek

Bee Hill

Hill Top

Motley RidgeAlbion

Southern

Delta Beta

BV5 Bowhunters

Mount Vista

Sansons

Delvin Pocket Mt Pool

Robard CreekOakey Creek

Quartz HillSullivans Reward

Pinnacle

Gold Creek

BoundaryPower

Line

BV8

Ortiz

StrathmoreCastle

Capsize

Mt Carlton

Herbert Creek

Boundary

Lionel Diggings

Map courtesy of Ian Withnall

Page 4: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

To help exploration by identifying zoning patterns and through better understanding of the genesis and controlling factors of the deposit

To help locate the surface projection of the linked porphyry by applying vectors in lithocaps (Chang et al., 2011 and others)

Estimate the depth of the linked porphyry (uplift history, vertical zonation)

Feed information and geological understanding to the regional metallogeny analysis (Subproject #1) and prospectivity analysis (Subproject #9)

Purpose of this project

Recent work and preliminary results

Page 5: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

• Literature review on regional geology and epithermal-porphyry systems

• First field season at Mt Carlton (2.5 months): Core logging (6.6 km) of 3 sections across the Mt Carlton deposit, with

focus on protolith control, alteration and mineralisation styles Short Wave Infra-Red (SWIR) spectrometry on core to characterise

alteration zonation (1046 analyses) Initial structural observations (next talk)

• Detailed paragenetic study of alteration and mineralisation assemblages, using optical and electron microscopy (42 thin sections)

• Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples (U-Pb)

• O-H isotope analysis of Mt Carlton groundwater (3 samples)

• Sample preparation for dating, fluid inclusions and isotope analysis (samples selected, ongoing)

What has been done?

Preliminary cross section

From Evolution mining

Page 6: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

Preliminary cross section -protolith• Basement:

monzogranite, part of the Urannah batholith (GoQ, 2013)

• Andesite rhyodacite porphyry andesite-dacite rhyodacitevolcaniclastics + sediments andesite-dacite trachyte (not shown)

• Mineralisation is hosted in the rhyodacite units

NE-SW profile across A39 and V2

Morrison, 2010 Cummings, 2012

Limit of drilling

Preliminary cross section -protolith• Stratigraphy

similar to previous work (Morrison, 2010; Cummings, 2012; mine geologists)

• however, dome shape not obvious

NE-SW profile across A39 and V2

Morrison, 2010 Cummings, 2012

Limit of drilling

Page 7: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

Preliminary cross section -alteration• Alteration strongly

controlled by protolith

• Qtz-alu-py and qtz-dick/kao-pyalteration confined mainly to rhyodaciteunits

• Andesites-dacitesshow mainly illite-montmorillonite-pyrite alteration above and below the AA zone

• The basement has illite-chlorite-pyrite alteration

NE-SW profile across A39 and V2

Limit of drilling

Preliminary cross section

Alunite show low-T compositions throughout the deposit (determined by OH peak at ~1480 nm in SWIR spectra)

however, zonation visible between V2 and A39 (similar to the mines’ observations)

preliminary documentation of hydrothermal breccia distribution indicate that it is localised to V2 and to the NE

NE-SW profile across A39 and V2

Page 8: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

Alteration and mineralisation paragenesis

• Foundation of applying vectors and advanced analytical programs

Paragenesis table

Page 9: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

Stage 1 – hydrothermal alteration

Stage 1 – hydrothermal alteration• The main alteration

stage show typical assemblages of HS epithermal deposits

• Unusual features include coarse alunite veins (plumose alunite?) and euhedralgypsum, which occur in the advanced argillic zones

alu

qtz

gyp

alu

Page 10: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

Stage 1 – deep alteration

• Deep alteration in the granite basement consist of pervasive illite-chlorite-pyrite (SCC) assemblages

• Below the V2 pit pyrite veins with quartz-illitealteration occur

illite-chlorite

py with qtz-ill halo

py

illqtz-ill

Stage 2 – mineralisation

• Stage 2a: high-sulphidation Au-Ag-Cu ore

• Stage 2b: intermediate-sulphidation Zn-Pb-Au ore

• Stage 2c: intermediate-sulphidation Cu-Au ore

Page 11: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

• The main high-sulphidation mineralisation stage is dominated by enargite and pyrite

• Occur as hydrothermal breccias and veins (in porphyry host rocks) and disseminations (in tuffaceous host rocks)

• Common minerals include tetrahedrite, galena, sphalerite, bornite, barite, chalcocite, covellite and chalcopyrite

• Typically associated with silicic halos in wall rock

Stage 2a: Au-Cu-Ag mineralisation (HS)

enqtz

en

ttd

py

cct

en

bor

nau

• The HS mineralisation stage is rich in native gold, mainly associated with enargite

• How much Au is hosted in e.g. enargite and pyrite?

Stage 2a: Au-Cu-Ag mineralisation (HS)

en

native Au

en

native Au

Page 12: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

• Silver-dominated minerals include:

acanthite Ag2(S,Te)

naumannite Ag2(Se,Te)

jalpaite Ag3Cu(S,Te)2

electrum

Stage 2a: Au-Cu-Ag mineralisation (HS)

acanthite

naumannite

naumannite

?jalpaite

goldfieldite

?jalpaite

electrum

• Stage 2 is an intermediate-sulphidationassemblage dominated by sphalerite

• Accompanied by galena, pyrite and barite as well as native gold

Stage 2b: Zn-Pb-Au mineralisation (IS)

sphgal

sph

bar

sph

galgal

Page 13: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

• Stage 2b base metal mineralisation is cut by a later Cu-Au mineralisation stage dominated by tennantite

• Common minerals in this stage are chalcopyrite, galena, chalcocite and barite

• Minor amounts of goldfieldite(Cu12Te4S13) and native gold

Stage 2c: late Cu-Au mineralisation (IS)

gal

ttt

ccpdic(late)

tttpy

sph

ccp

Goldfieldite with internal zoning due to variable As-content. White inclusions are galena.

Stage 3 – post-mineralisation

Page 14: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

Stage 3 – post-mineralisation

• Stage 3a: bluish-translucent dickitecuts main-stage alteration as well as mineralisation assemblages

• Stage 3b: gypsum veins are very common in predominantelythe andesitic units. Textures indicate they are tension veins emplaced during post-mineralisation shearing

Dickite vein cutting mineralisation

Gypsum veins in andesite at V2. Photo Paul Dirks

dickite

enargite gypsum

andesite

265

270

275

280

285

290

295

300

305

Ag

e (M

a)

Zircon U-Pb LA-ICP-MS; this study

Zircon, SHRIMP, literature

Mo Re-Os; Capsize porphyry; this study

Alunite Ar-Ar; V2; this study

Wall rock and mineralisation ages at Mt Carlton district

Basement granitoid

Lizzie Creek Volcanic Group

Porphyritic intrusions in Lizzie

Creek volcanics

Trachyte

Capsize, late-mineral

Below V2

Chang, 2015

Page 15: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

Preliminary observations• Stratigraphic logging conforms well with previous work – but the lack of dome

shape needs to be investigated

• Hydrothermal alteration show typical assemblages of HS deposits, and is strongly controlled by protolith

• Vectors developed using alunite composition and hydrothermal breccia distribution suggest that A39 is distal to V2

• Three distinct mineralisation stages in the deposit

• 1. high-sulphidation Au-Ag-Cu ore (enargite-pyrite) 2. intermediate-sulphidation Zn-Pb-Au ore (sphalerite-galena-pyrite) 3. intermediate-sulphidation Cu-Au ore (tennantite)

• Preliminary dating (Ar-Ar of alunite vein) give age of 284 +/- 2 Ma – overlap with host rocks and Capsize porphyry. More detailed dating work to come.

Upcoming work Purpose Method

Refine stratigraphy 1) Core logging, field observations2) Whole rock data – F content

Age of deposit 1) Ar-Ar dating of alunite (vein and disseminated type) from both V2 and A39.

Surface vectors to porphyry 1) Hydrothermal breccia2) Silicic zone3) Grade zonation (Leapfrog model)4) Mineral chemistry (e.g. alunite and pyrite

composition, texture)

Fluid temperature zonation 1) S isotopes in pyrite-alunite pairs 2) Fluid inclusion microthermometry

Fluid composition zonation 1) O-H isotopes (alunite, dickite-kaolinite, groundwater)2) S isotopes (alteration & mineralisation)3) Fluid inclusion composition by LA-ICP-MS

Depth to porphyry 1) Vertical alteration zonation2) (U-Th)/He + fission track thermochronology

DHNARAM Courteney <[email protected]>DHNARAM Courteney <[email protected]>

Page 16: Fredrik Sahlström, Zhaoshan Chang, Paul Dirks, Isaac ... · PDF fileMatrimony ridge Otter ridge Stockyard Creek ... • Dating of 1 alunite sample (Ar-Ar) and 2 host rock samples

Acknowledgements

• Evolution Mining; Roric Smith, Genesio Circosta, David Hewitt, Mick Pocock, Tyron Edgar, Jim Dugdale, Ned Howard, Matthew Obiri-Yeboah

• Geological Survey of Queensland

• JCU Mineral Separation Lab (MSL) and Advanced Analytical Centre (AAC), U Michigan Ar-Ar lab and U Alberta Re-Os lab

• JCU research team

Thank you for listening!