Foto Frontpage: Lab-on-chip system, PD Dr. Stefan ...€¦ · 2 Foto Frontpage: Lab-on-chip system, PD Dr. Stefan Thalhammer, Helmholtz Research Centre Munich. Foto page 2: view on

1

2

Foto Frontpage: Lab-on-chip system, PD Dr. Stefan Thalhammer, Helmholtz Research Centre Munich.

Foto page 2: view on Saint-Petersburg State Institute of Technology.

3

Organizers

Saint-Petersburg State Institute of Technology (Technical University) Hall of Senate of the University 26 Moskovsky Prospect Saint-Petersburg, RU-190013/Russia www.spbtechnologicaluniversity.com/default.aspx

Klöckner Pentaplast Europa Klöckner Pentaplast GmbH & Co.KG P.O.Box 1165, 56401 Montabaur Industriestraße 3-5 D-56412 Heiligenroth/Germany www.kpfilms.com

Cluster Nanotechnology/ Nanoinitiative Bayern GmbH Josef-Martin-Weg 52/ Campus Hubland Nord D-97074 Würzburg/Germany www.nanoinitiative-bayern.de

4

The overall aim of the German-Russian network NanoBRIDGE is to intensify the scientific and technical cooperation in nanotechnology especially in biomedical applications, in nanoanalytics and applied nanotechnology. Russian and German partners are to benefit equally from joint research and development projects, scientific and technical events and exchanges of experts, young scientists and students to enhance their international competitiveness in a strong and sustainable way. NanoBRIDGE offers expertise in • nanostructures, nanophotonics and nanooptics for

- biomedical diagnostics - therapeutic applications such as drug-delivery for implants and pharmaceuticals - genetic engineering and gene transfections

• selective sensors in medicine and technology • improvement of biocompatibility of implants • laser techniques in surgery • nanoanalytics for the characterization and optimization of material properties • production and development of coatings for the improvement of interfacial properties • education and training The NanoBRIDGE partners have extensive experience in international cooperation and in publicly funded as well as in bilateral research and development projects. NanoBRIDGE supports partners from Russia in the initiation of research projects, company start-ups in Germany, in joint ventures and trade. NanoBRIDGE organizes workshops, seminars and conferences as well as exchanges of scientists, experts and students.

www.nanobridge.owwz.de

5

Project Partners NanoBRIDGE

The project NanoBRIDGE is funded by the International Bureau (IB) of the German Federal Ministry for Education and Research (BMBF). Duration: 01 April 2012 - 31 March 2014 The project is part of the initiative "Research in Germany - Land of Ideas"

6

Project Partners NanoBRIDGE Germany

East-West-Science Centre (OWWZ) University of Kassel UniKasselTransfer Dr. Gabriele Gorzka T: +49 561 804 3609 @: [email protected] www.owwz.de marcotech oHG c/o Center for Nanotechnology Prof. Dr. Lothar Heinrich T: +49 251 836 3410 @: [email protected] www.marcotech.de CeNTech GmbH Center for Nanotechnology Dr. Holger Winter T: +49 251 53406 200 @: [email protected] www.centech.de Cluster Nanotechnology Nanoinitiative-Bayern GmbH Dr. Peter Grambow T: +49 931 31 89374 @: [email protected] www.nanoinitiative-bayern.de SmartMembranes GmbH Monika Lelonek T: +49 345 4780 251 @: [email protected] www.smartmembranes.de

7

Laser Research Centre, University of Munich Dr. Michael Fedorov T: +49 89 7095 4870 @: [email protected] http://lfl.life.klinikum.uni-muenchen.de Transfer Centre Nano-electrochemistry University of Saarland Physical Chemistry Prof. Dr. Rolf Hempelmann T: +49 681302 4750 @: [email protected] www.tne-uds.de University of Greifswald Institute for Pharmacy Prof. Dr. Werner Weitschies T:. +49 3834 86 4813 @: [email protected] http://pharm1.pharmazie.uni-greifswald.de/Techno/Index.htm University of Münster Physical Institute Dr. Cristian A. Strassert T: +49 251 5340 6840 @: [email protected] http://www.uni-muenster.de/Physik.PI/Institut/ University of Duisburg-Essen Institute for Inorganic Chemistry Prof. Dr. Matthias Epple T: +49 201 183 2413 @: [email protected] http://www.uni-due.de/chemie/ak_epple// Klöckner Pentaplast GmbH & Co. KG Klöckner Pentaplast Europa Prof. Dr. Christian Kohlert T: +49 2602 / 915 - 357 @: [email protected] www.kpfilms.com

8

Project Partners NanoBRIDGE Russia

Technical University Tomsk TPU Nano-Centre and Department “Nanomaterials and Nanotechnologies” Prof. Dr. Oleg Khasanov T: +7 3822 427242 @: [email protected] http://tpu.ru/en/academics/institutes/htp/nmnt/ St. Petersburg National Research University of Information Technologies, Mechanics and Optics Prof. Dr. Vladimir N. Vasilyev Prof. Dr. Tigran Vartanyan Tel:7(812)3239184 @: [email protected] http://en.ifmo.ru/ Saint-Petersburg State Institute of Technology (Technical University) Prof. Dr. Tamara Chistyakova Tel: +79219379215 @: [email protected] http://www.spbtechnologicaluniversity.com

9

PROGRAM

July 2, 2012 19.00 h Open get together Hotel Moskva Bar “Vosem”, 8th Floor

German-Russian Nanotechnology Forum

Venue: Saint-Petersburg State Institute of Technology (TU), 26, Moskovsky Prospect,

Saint Petersburg 190013, Main Entrance, Auditorium 61

July 3, 2012 09.30 h Registration

10.00 h Welcome by the organizers

• Prof. Tamara Chistyakova Saint-Petersburg State Institute of Technology (TU)

• Prof. Christian Kohlert, Klöckner Pentaplast Rus • Dr.-Ing. Peter Grambow

Cluster Nanotechnology/Nanoinitiative Bayern GmbH

10.30 h Plenary session

• Development of nanotechnology and nano-educational programs in Russia

Tatyana Lubovskaya, Rusnano Nano-educational program in Saint-Petersburg State Institute of Technology (TU) Prof. Tamara Chistyakova Saint-Petersburg State Institute of Technology (TU)

• Nanotechnology research in Saint-Petersburg State Institute of Technology (TU) Prof. Anatoly Malygin Saint-Petersburg State Institute of Technology (TU)

• German-Russian Network NanoBRIDGE Dr. Gabriele Gorzka, East-West-Science Centre University of Kassel

12.00 h Buffet style lunch, poster presentation

13.00 h Visit of Musee of State Institute and Educational Training Centre for Nanospecialists Saint-Petersburg State Institute of Technology (TU)

14.00 h Presentations (16.00 h coffee break 30 min.)

• Nano-education

• Scientific topics Moderation: Prof. Lothar Heinrich Marcotech

• Application and development topics Moderation: Dr.-Ing. Peter Grambow Cluster Nanotechnologie/Nanoinitiative Bayern GmbH

18.00 h Presentation of the summaries

10

Closing remarks Dr. Gabriele Gorzka

21.00 h-23.30 h

Get together on boat on river Newa / Buffet style dinner Departure of boat: 21.00 h Meeting point: Kanal, Moika 39

July 4, 2012 10.00 h Departure by bus from Hotel Moskva

10.30 h Visit of center for films and nanotechnology Klöckner Pentaplast Rus and Saint-Petersburg Institute of Technology (TU)

12.00 h Common lunch

13.00 h End of official program

Transfer to the airport Pulkovo possible.

Sightseeing tour by bus for interested participants.

11

NANOTECHNOLOGY FORUM

Saint Petersburg, July 3-4, 2012

LIST OF POSTERS

Poster

No.

Name

Position / Company /

Institution

Poster Title

1

Dipl.-Biol., M.Sc. Nicole Burghardt

Project Coordinator German-Russian Cooperation Network Biotechnology East-West-Science Centre, University of Kassel, Germany

German-Russian Cooperation Network Biotechnology.

2

Jürgen Fehmer

Sales Director, TSE Systems GmbH, Germany

Development of Nanoparticle Aerosol Generation and Analysis Systems.

3

Dr.-Ing. Peter Grambow

Project Manager NanoSilber Network c/o Nanoinitiative Bayern GmbH Wuerzburg/Germany

The responsible development of nanosilver throughout the entire product life cycle.

4

Dr. Uwe Reichel

Fraunhofer Institute for Ceramic Technologies and Systems IKTS, Hermsdorf/ Germany Research Scientist, Project Leader

Ceramic nanomaterials – Research & Development.

12

5 Dr. Kristina Riehemann Institute of Physics, University of Muenster, Institute of Physiology II, University of Muenster, Nanostic Institute, Group Leader and Center for Nanotechnology, Muenster/ Germany

Inflammation induced surface alteration of endothelial cell.

6

Dr. Nina Sergeeva

Researcher of the theoretical foundations of Materials Technology Saint-Petersburg State Technological Institute (Technical University)

Orange luminescence of colloidal zinc sulfide in the presence of sodium chloride.

7

Jürgen Spielvogel

Division Manager Environmental Monitoring & Nano Instrumentation Palas GmbH, Karlsruhe/ Germany

A NEW NANOPARTICLE COUNTER (UF-CPC)“.

8

Prof. Anton Starovoytov

Associate Professor St. Petersburg National Research University of Information Technologies, Mechanics and Optics , Russia

Influence of Electron Density Distribution in a Molecule on Equilibrium Component Composition of Cyanine Thin Films.

9

Dr. Maxim Sychov

Head of Department of Theoretical Fundamentals of Materials Science Saint-Petersburg Institute of Technology (TU)

Medical plants decontamination by low temperature plasma Bogma M.1), Potekhina T.2), Eruzhin A.3), Manoilova L.M.1) Gavrilenko I.3) Sychov M.M.3)

10 Dipl.-Ing. Nikita Toropov

Ph.D Student, St. Petersburg National Research University of Information Technologies, Mechanics and Optics , Russia St. Petersburg National Research University of IT, Mechanics and Optics

Optical absorption and fluorescence of cyanine dye thin films in the near field of silver nanoparticles.

13

POSTER ABSTRACTS

14

Curriculum Vitae Dipl.-Biol., M.Sc. Nicole Burghardt Diploma of Biology – Focus Biochemistry at Kassel University (2005), Research Assistant at East-West-Science Center at Kassel University (2005 - 10), Master of Landscape Management & Environmental Planning at Kassel University (2009), Project Coordinator of the German-Russian Cooperation Network Biotechnology (since 2011), Free-lancing in the field of Biology, Landscape Management and Environmental Planning (since 2009)

German-Russian Cooperation Network Biotechnology

The objectives of the Network are to initiate and establish cooperation between companies and scientific institutions in both countries and furthermore to provide a systematic and sustainable basis for cooperation in traditional fields, as for example molecular biology or biochemistry, as well as in younger research areas such as the environmental and resource management. The service offerings of the cooperation network include the implementation of events as well as the allocation of specialized information, publication of trends and cooperation opportunities in a monthly newsletter and individual services for project teams. Especially bilateral projects are attended result-oriented for: this includes consultation on funding, application and project management involving patenting, marketing of products and setting up businesses. This consulting offer addresses German and Russian experts from science and business, focusing especially on small and midsize enterprises interested in cooperating with institutions and partners in the field of biotechnology.

Poster Abstract Development of Nanoparticle Aerosol Generation and Analysis Systems TSE Systems has decades of experience in developing and manufacturing highinhalation exposure systems, consisting of components like liquid aerosol or dust generators, whole body, nose only, or cell culture exposure units, Daco control ananalysis tools and integrated safety devices. In recent years, great hopes have been pinned on properties and economics of nanomaterials, which are now in use in fields as diverse as pharmacology, materials science, insulators and conductors, and many more. On the other hand, safety risks upon exposure have been postulated, but as yet only limited data on health hazards are available. This is in part due to the unavailability of standardized testing equipment. TSE Systems has developed modular instrumentation to reliably generate nanoparticle aerosols with narrow particle size distribution from different materials, the EUsing state-of-the-art electrospray technology, the Eindividual aerosol droplets with reduced subsequent aggregation. Nanoparticles can be generated reproducibly for risk assessment and health hazard investigations. The nanoparticle generator core module can be adapted to the researchers needs. The E-Spray NanoGen is accompanied by our advanced nanomaterial analysis instrument, the NanAeroSpec, functioning both as a spectrometer with nonCondensation Particle Counter with noninhalation exposure systems to integrate nanomaterial investigation capabilities.

15

Curriculum Vitae Jürgen Fehmer – Sales Director TSE Systems GmbH, Bad HomburgSince: 01/2011 Position: Sales Director Eastern Europe & PJA Genomika, Moscow 05/2010 – 12/2010 Position: Business Development Director Parallabs, Moscow 10/2005 – 04/2010 Position: Business Development Director

Geneworx AG, Oberhaching 09/2004 – 09/2005 Position: Chief Executive Officer Protedyne Europe GmbH, Martinsried03/2002 – 09/2004 Position: Managing Director a1-Biotech GmbH, Planegg 10/1998 – 03/2002 Position: General Manager UniEquip Laborgerätebau und- vertriebs GmbH, Planegg 09/1982 – 10/1998 Position: Trainee sales and marketing Siemensstr.21 / 61352 Bad HomburgT: +49-6172-789-0 F: +49-6172-789E-Mail: [email protected]

Development of Nanoparticle Aerosol Generation and Analysis

experience in developing and manufacturing highinhalation exposure systems, consisting of components like liquid aerosol or dust generators, whole body, nose only, or cell culture exposure units, Daco control and regulation software, analysis tools and integrated safety devices.

In recent years, great hopes have been pinned on properties and economics of nanomaterials, which are now in use in fields as diverse as pharmacology, materials science, insulators and onductors, and many more. On the other hand, safety risks upon exposure have been postulated,

but as yet only limited data on health hazards are available. This is in part due to the unavailability of standardized testing equipment.

ped modular instrumentation to reliably generate nanoparticle aerosols with narrow particle size distribution from different materials, the E-Spray NanoGen Advanced.

art electrospray technology, the E-Spray NanoGen embeds nanoparticles iindividual aerosol droplets with reduced subsequent aggregation. Nanoparticles can be generated reproducibly for risk assessment and health hazard investigations. The nanoparticle generator core module can be adapted to the researchers needs.

ay NanoGen is accompanied by our advanced nanomaterial analysis instrument, the NanAeroSpec, functioning both as a spectrometer with non-radioactive neutralizer, and a Condensation Particle Counter with non-toxic working fluid. These developments extend ouinhalation exposure systems to integrate nanomaterial investigation capabilities.

Sales Director

TSE Systems GmbH, Bad Homburg

Position: Sales Director Eastern Europe & Middle East

Position: Business Development Director


Protedyne Europe GmbH, Martinsried

vertriebs GmbH,

and marketing

Siemensstr.21 / 61352 Bad Homburg 789-500

Development of Nanoparticle Aerosol Generation and Analysis

experience in developing and manufacturing high-quality complete inhalation exposure systems, consisting of components like liquid aerosol or dust generators,

d regulation software,

In recent years, great hopes have been pinned on properties and economics of nanomaterials, which are now in use in fields as diverse as pharmacology, materials science, insulators and onductors, and many more. On the other hand, safety risks upon exposure have been postulated,

but as yet only limited data on health hazards are available. This is in part due to the unavailability

ped modular instrumentation to reliably generate nanoparticle aerosols Spray NanoGen Advanced.

Spray NanoGen embeds nanoparticles in individual aerosol droplets with reduced subsequent aggregation. Nanoparticles can be generated reproducibly for risk assessment and health hazard investigations. The nanoparticle generator core

ay NanoGen is accompanied by our advanced nanomaterial analysis instrument, the radioactive neutralizer, and a

toxic working fluid. These developments extend our

16

Curriculum Vitae Dr.-Ing. Peter Grambow Dr. Peter Grambow studied electrical engineering in Darmstadt (Germany), focusing on high-frequency technology and telecommunications. Thereafter he worked as a research associate at the Max Planck Institute for Solid State Research in Stuttgart (Germany), where he helped plan and set up the microstructure laboratory. While at the Max Planck Institute, Peter Grambow also completed his doctoral thesis “Technology and Analysis of Nanostructured Semiconductor Systems”. This was followed by industrial positions at Siemens, Infineon, 3D Connexion, Logitech, and Infineon Austria. Dr. Grambow was most recently responsible for project engineering in the Sense & Control division at Infineon. Since 2009, Dr. Grambow is working as a project manager, coach, lecturer, and project leader in a freelance capacity. Since April 2010 Dr. Grambow is responsible for the management of the Bavarian Cluster Nanotechnology.

The responsible development of nanosilver throughout the entire product life cycle.

The NanoSilber network was founded in June 2011. It consists largely of small and medium-sized partner enterprises (SMEs) that are supported by partner institutions. The network's management lies with the Cluster Nanotechnology.

Nanosilver holds great technical potential, because of its antimicrobial activity, electrical and thermal conductivity and unique optical properties. It brings improvements to many innovative products. The network aims to further develop nanosilver in terms of manufacturing, processing, application, production and disposal. In doing so, the network considers nanosilver materials across their entire life cycle.

Like many advancing technologies, there are still questions to be answered. These concern both technological issues and risk assessment. Therefore, the network is planning and executing market-oriented R&D projects.

One of this projects will be evaluating the release of nanosilver from consumer products by standardized ageing-tribology, simulation of alterations in the material by ageing and use. Subsequently the amount of airborne particles is measured.

The network's services: - Targeted development of nanosilver - Responsible realisation of the technical potential - Careful risk analysis - Execution of market-oriented, innovative R&D projects - Cooperation of SMEs with research facilities, leading to more effective technology transfer - Use of synergies in the partners' knowhow in all areas of the nanosilver product life cycle - Clear communications with the public - Public relations, exhibition appearances and events The network project is supported within the framework of the ZIM-NEMO support programme of the German Federal Ministry of Economics and Technology (BMWi).

17

Dr.-Ing. Uwe Reichel

Education:

1981 Dipl.-Ing. of “Materials and Technologies of Silicates” (Technologies

of Glass and Ceramic) at TU Bergakademie Freiberg;

1990 Dr.-Ing. at TU Bergakademie Freiberg

in the area of materials science / ceramic material;

Career:

1981 – 2006 different leading works in industrial companies of

Technical Ceramic / Advanced Ceramic:

Professional experience over 20 years in the fields of

- Silicate materials (Glass / Ceramic)

- Advanced Ceramic (Structural ceramic)

- Nano structured materials (Ceramic)

- Technique for joining parts (ceramic / glass – metal)

- Application of ceramic parts in industry and

medicine

from 2007 Scientist at Hermsdorfer Institut for Technical Ceramic

(HITK) / since 2010 Fraunhofer IKTS, Division Oxide

Ceramic Components and Systems; project manager

Main topics: nanostructured ceramic materials for high strength,

biocompatibility and transparency

POSTER TITLE

Ceramic nanomaterials – research & Development

18

Dr. Kristina Riehemann

POSTER TITLE

Inflammation induced surface alteration of endothelial cell

Nicolas Schierbaum+*, Jonas Franz++, Christoph Riethmüller#, Kristina Riehemann+*, Harald Fuchs+* +Institute of Physics, University of Münster, *Institute of Physiology II, University of Münster #Nanostic Institute, +Center for Nanotechnology, Münster During development of inflammation leukocytes are recruited to the site of disease. The control of interaction of endothelial cells and leukocytes play a crucial role during this process. The extravasation of inflammatory active cells is regulated by surface proteins on this type of cells as well as on the surface of the endothelium. But not only biochemical mechanisms but also morphological changes may occur during this process. Here we report the detection of such morphologic surface changes on inflammatory activated endothelial cells by Atomic Force Microscopy (AFM). Whether these structures are involved in the regulation of inflammation has to be shown in further studies.

19

Dr. Kristina Riehemann Curriculum Vitae STUDIES 1982-1988 Study of Physics and Biology, University Münster Main subject: Industrial Microbiology 1989 Diploma degree with Prof. Dr. F. Meinhard

Thesis: "Isolation and Characterization of Promoters from Bacillus megaterium"

Profession 1989- Oct. 1993 Preparation of a Ph.D. thesis at the Institute of Experimental

Dermatology, University of Münster with Prof. Dr. C. Sorg. Thesis: "Structure, Function and Distribution of Restin, a cytoskeleton- associated Protein"

1994-1995 Postdoctoral position at the "Gerhard-Domagk"-Institute of Pathology 1995-2000 Junior group leader at the Institute of Medical Biochemistry at the

ZMBE (Centre for Molecular Biology of Inflammation). Centre of research: "Anti-inflammatory mechanisms"

2000-2004 Scientific Coordinator and manager of the “Integrated functional Genomics (IFG)”, a service unit of the “Interdisciplinary centre of clinical research (IZKF), Münster.

Since 2004 Delegation from the Medical Department to the Department of Natural Sciences, here: group leader at the Center for Nanotechnology (CeNTech)

Since 2005 SRP leader cell biology in the N2L network Since 2006 Coordinator of the BMBF Project “Biocompatibility of nanoparticles for

medical engineering, diagnostics and therapy (NanoBiocomp)” a joint project between China and Germany

Since 2011 Coordinator of the BMBF Project “Mechanisms of the Interaction of Nanoparticles with Cells _ MINAC)” the Sino-German follow-on project of Nano-Biocomp

Selected publications

1: Riehemann K. Nanotoxicity: How the Body Develops A Way to Reduce the Toxicity of Carbon Nanotubes. Small. 2012 Apr 4. doi: 10.1002/smll.201200400. [Epub ahead of print] 2: Riehemann K, Schneider SW, Luger TA, Godin B, Ferrari M, Fuchs H. Nanomedicine--challenge and perspectives. Angew Chem Int Ed Engl. 2009;48(5):872-97. Review. 3: Sun T, Han D, Riehemann K, Chi L, Fuchs H. Stereospecific interaction between immune cells and chiral surfaces. J Am Chem Soc. 2007 Feb 14;129(6):1496-7. Erratum in: J Am Chem Soc. 2007 Apr 18;129(15):4853. Rhemann, Kristina [corrected to Riehemann, Kristina]. 4: Walther A, Riehemann K, Gerke V. A novel ligand of the formyl peptide receptor: annexin I regulates neutrophil extravasation by interacting with the FPR. Mol Cell. 2000 May;5(5):831-40.

20

Nina Sergeeva Mefodievna Researcher of the theoretical foundations of Materials Technology Institute (St. Petersburg), candidate of technical sciences. Works at the Institute since 2006. Deals with the synthesis of colloidally dispersed phosphors and studied their optical and luminescent properties. Efforts aimed at establishing the relationship of initial conditions for the synthesis of structurally. Interest in the study initiated by employees of the Physico-Technical Institute, Ioffe, (St. Petersburg), which help to meaningfully understand the variety of experimental data. [email protected]

Orange luminescence of colloidal zinc sulfide in the presence of sodium chloride

Sergeeva N.M., Tsvetkova M.N., Osokina N.A, and Abyzov A.M. Federal State budget institution of higher education "Saint-Petersburg State Technological Institute

(Technical University)" (SPbSTI (TU)), St. Petersburg, Moskovsky prospect 26, 190013, Russia Tel: (812) 494-92 – 86, [email protected]

Abstract The possibility of obtaining colloidal dispersion of zinc sulfide with a high content of manganese. This is achieved by adding sodium chloride, triggering increased spatial symmetry, as one of the phases of manganese, as well as the main phase of zinc sulfide. The observed effect strengthens the lattice of zinc sulfide. In the photoluminescence spectra present a band of manganese luminescence at a wavelength of 605 nm. Keywords: phosphors, ZnS, Manganese, NaCl, photoluminescence 1. Introduction Colloidal phosphors based on zinc sulphide nanocrystals with typical sizes smaller than 10 nm have attracted the attention of researchers because of the possibility of their use in optoelectronics. Phosphors have high photoluminescence yield and the opportunity to adjust the shades of orange and red colors to produce beautiful color combinations [1, 2]. However, one can increase the concentration of manganese, only 2% in the standard technology of doping ZnS phosphors. This paper shows a way of increasing the concentration of manganese by changing the spatial symmetry of the co-precipitated colloidal phase method with the addition of sodium chloride. 2. Experimental and results Colloidal synthesis method for the double-exchange reactions have been synthesized undoped zinc sulfide, zinc sulfide, containing 0 - 8% Mn with the addition of sodium chloride. Deposition of colloidal sulfides was carried out from acetate solutions of sodium sulfide with continuous stirring under normal conditions. Luminescent-optical properties of colloidal phosphor characterized the spectra of photoluminescence (PL), the relative values of the brightness of the photoluminescence and absorption spectra obtained by special treatment of electronic spectra of diffuse reflection on the Kubelka-Munk equation. The phase composition of solid phase sulfides was studied by X-ray diffraction analysis indicate. X-ray diffraction patterns were obtained on minidifraktometre "diffracted" at a wavelength of λ (CuKα-radiation). Qualitative analysis of the diffraction of the solid phases were carried out according to the filing ASTM (JCPDS). All phases of the cubic system and are presented face-centered lattice, but differ in the symmetry class. By symmetry class is one of the two phases of manganese sulphide belongs to the structural type of sodium chloride with space group Fm3m, and the other - to the type of zinc sulfide with the space group F43m. Phase F43m manganese sulfide and sodium chloride had similar values of lattice parameters. 3. Conclusion Adding sodium chloride in the process of co-deposition of a mixture of sulfides possible to eliminate the defect luminescence of solid solutions and get the orange luminescence with chromaticity coordinates X = 0,443 and Y = 0,42. Acknowledgements The authors thank N. Schmidt for critical comments and valuable continuous support in carrying out the work. 4. References 1. Lu X., Chen.C., Husurianto S., and Koretsky M.D. Journal of Applied Physics 1999, v.85, № 8, p. 4154-4159. 2. Wang L., Xu X., Yuan X. Journal of Luminescence 2010, v. 130,p. 137-140.

21

Curriculum Vitae - Jürgen Spielvogel Juergen Spielvogel studied Physics at the University of Stuttgart (1989-1993). As fellow of the Rose-Hulman International Fellowship (Indiana, USA) he completed his Master in Applied Optics (1995) with the thesis titled: Study of the photorefractive phase shift in a BaTiO3 crystal using an interferometric technique. He worked at the Institute for Lasertechnologies in Medicine and Metrology (Ulm, Germany) on infrared spectroscopy with Silverhalide fibers and at the University of Ulm where he used Raman spectroscopy and AFM for adhesion experiments. He participated in exchanges with the Kanazawa Institute of Technology (Japan) and Tel Aviv University (Israel) and spent seven years in the industry in USA where he worked in the R & D departments of three major particle counting companies. At his former employer in Germany he was responsible for the nano instrumentation division. He joined Palas in 2010 and is now responsible for the development and distribution in the fields of environmental monitoring and nano instrumentation.

POSTER TITLE „A NEW NANOPARTICLE COUNTER (UF-CPC)“

22

Anton Starovoytov Anton Starovoytov is a associate professor at the St. Petersburg National Research University of Information Technologies, Mechanics and Optics, where he recieved his specialist degree in laser technologies (2008) and Ph.D. in optics (2011). His interests include the optical properties of organic dye molecules deposited at the substrate or embedded in mesoporous materials, spectroscopy of these molecules in the presence of the plasmon resonance of metal particles. He has published 15 papers an has presented at over 30 conferences.

Influence of Electron Density Distribution in a Molecule on Equilibrium Component Composition of Cyanine Thin Films by Starovoytov A., Kaliteevskaya E., Krutyakova V., Razumova T. A stacking multilayer organic thin film is a great interest in connection with biological membrane such as a photoantenna system, where different chromophores are stacked in higher order and excitation energy obtained by light absorption transfers very efficiently to the reaction center of photosynthesis. Thin films and molecular layers of cyanine dyes are also widely used in optoelectronics. Therefore, it is urgent to study the properties of such layers and heterostructures based on them. A stacking multilayer organics thin film is a great interest in connection with biological membrane such as a photoantenna systen, where different chromophores are stacked in higher orderand excitation energe obtaine by light absorption transfers very efficiently to the reaction center of photosynthesis. It was found that the absorption spectra of layers of symmetric cyanine molecules (SCM) are considerably broadened in comparison with the spectrum of their solutions. This is because in the equilibrium solutions symmetrical molecules are mainly present in the form of all-trans isomers, whereas in layers several molecular components differing in the structures exist. The above components are identified as monomeric all-trans and cis isomers and associates (dimers and J aggregates). The presence of cis isomers is due to the break in the electron molecular symmetry owing to the interaction between the cationic dye and the negative charge at the surface of a substrate. The component composition of a layer depends on its thickness. This means that in cyanine dyes the interaction with the substrate and surrounding molecules affects intramolecular electron asymmetry. Increasing the electron-donor ability (Ф0) of end groups, which characterizes the shift of electrons from an end group toward a conjugated chain in SCM, leads to an increase in the number of the absorption bands of different cis isomers. In solutions of asymmetric cianine molecules (ACM), whose end groups have different structures and are characterized by different electron-donor abilites, i.e, by the difference ∆Ф0, in addition to all-trans isomers, cis isomers are also present, which is accounted for by the asymmetry of intramolecular electron density distribution along the conjugated chain. The relative concentration of cis isomers increases with increasing ∆Ф0. The ACM adsorbed on the surface changes the asymmetry in the electron density distribution along conjugated chain, which affects the equilibrium concentration of cis isomers in a molecular layer. At low ∆Ф0 values the component composition of ACM layer is close to that of SCM layer. At large values the relative concentration of cis isomers decreases, which shows that the asymmetry degree decreases.

23

Medical plants decontamination by low temperature plasma Bogma M.1), Potekhina T.2), Eruzhin A.3), Manoilova L.M.1) Gavrilenko I.3) Sychov M.M.3)

1) Medical Academy of Postgraduate Studies, Saint-Petersburg, Russia 2) Saint-Petersburg State Chemical Pharmaceutical Academy, Saint-Petersburg, Russia 3) St. Petersburg State Institute of technology (Technical University) Herbal remedies take up about 40% of total amount of all medicines used for treating different kinds of diseases. It is due to their multiple biological activity and soft therapeutic effects in comparison to synthetic drugs]. One of the major tasks for pharmaceutical producers is to provide high quality and safety of ready drugs. Analysis of Russian medicines quality shows that the amount of herbal drugs (tinctures, extracts, infusion and decoction) spoilages is constantly growing. The criteria, which brings the quality of herbal drugs down is inconsistency of microbiological purity. Herbs might contain high quantities of different microorganisms since medicinal herbs, as well as other plants, are native habitat for lots of bacteria. Besides, microbiological pollution can take place during processing steps, such as: collection, drying, weighing, packing, transporting and storage. Thus, providing a certain level of microbiological purity is very important for herbal drugs producers. There are different methods to decrease a number of vitalized microorganisms: UV-, IR- , γ- radiation. Each of these methods has advantages and disadvantages. Preserving the whole complex of plants biologically active substances is the main restricting factor for using listed techniques. In this work the action of non-equilibrium plasma on medical plants was investigated. It was found out that fungi are more sensitive to low temperature plasma treatment that bacteria. Efficiency of antimicrobial treatment depends on plasma forming gas composition. In artificially contaminated samples of herbal drugs the amount of colony-forming units (genera Aspergillus and Mucor) is 1000 times less than in samples of untreated control group.

Dr. Maxim Maximovich Sychov

24

Nikita Toropov. PhD student (since 2010), Dept. of Optical Physics and Modern Natural Science. Engineer (since 2012). Center "Information Optical Technologies" (National Research University of IT, Mechanics, and Optics, St. Petersburg). R&D interests: nanoplasmonics, photonics of cyanine dyes thin films, thermal imaging systems. Skills: creation of the nanoparticles coated by organic molecules, study the optical properties Contact email: [email protected]

Optical absorption and fluorescence of cyanine dye thin films in the near field of silver nanoparticles. (poster presentation) Recent years have witnessed an increased interest in “nanoplasmonics” relevant to sensor applications. In this paper, we focus upon the modification optical absorption and flourescence that results when molecules are placed near metal nanoparticles for such applications. This modification is part of the general study of optical properties modification obtained in the vicinity of nanostructured metallic objects whose characteristic features are much smaller than the optical wavelength. It has been well understood that the enhancement of optical field is associated with excitation of localized surface plasmon modes, and it has been established that diverse optical effects can be enhanced near the resonantly excited metal nanoparticles. However, the actual numerical values of enhancement reported in different experiments differ by orders of magnitude and are often inconsistent with the theoretical or numerical results. At this work optical properties of supported silver nanoparticles coated by mono- and dicarbocyanine dyes molecular overlayers were investigated. Silver nanoparticles were prepared by vacuum evaporation on a sapphire substrate. Cyanine dye molecules were spread over the silver nanoparticle arrays by spin-coating technique. The samples were characterized by scanning electron microscopy and optical spectroscopy. Significant enhancements of the dye absorption, fluorescence as well as the shifts of the resonance positions of plasmon resonances were observed. The extinction spectrum of the hybrid material was rationalized as a result of mutual interactions between the surface plasmon oscillations localized in the Ag nanoparticles and resonance absorption and refraction of dye molecules. Plasmon resonances are shifted due to the anomalous refraction of dye molecules. Depending on the spectral position of the dye absorption band relative to the inhomogeneously broadened plasmon band this shift may lead to considerable clarification of the sample at particular wavelengths that was observed experimentally. On the other hand, the absorption of dye molecules is enhanced due to the incident field amplification in the near field of metal nanoparticles. Even when the dye absorption band overlaps with the tail of the plasmon band of silver nanoparticles, 3 to 5 times enhancement of the dye absorption was obtained. Besides that a nearly 4-fold increase of monocarbocyanine dyes fluorescence intensity in the presence of metal nanoparticles was observed.

25

ABSTRACTS

PLENARY SESSION

PRESENTATIONS

Nano-Education

Scientific Topics

Application and development topics

26

Чистякова Тамара Балабековна проректор по учебной работе СПбГТИ(ТУ), заведующая кафедрой систем автоматизированного проектирования и управления, доктор технических наук, профессор, заслуженный работник высшей школы РФ, руководитель ведущей научно-педагогической школы Санкт-Петербурга и международных научных проектов

Нанообразовательная программа в СПбГТИ(ТУ), Профессор Т.Чистякова, СПбГТИ В Технологическом институте реализуются 3 образовательные программы,

направленные на повышение квалификации управленческо-производственного персонала, работающего на автоматизированных производствах наноиндустрии химического и биотехнологического профиля:

1. Образовательная программа повышения квалификации для специалистов предприятий наноиндустрии химического и биотехнологического профиля в области автоматизированных производственных технологий (прикладная НИР по договору с Фондом инфраструктурных и образовательных программ ОАО «РОСНАНО», руководитель – проф. Чистякова Т.Б.). Руководители профильных предприятий, руководители кадровых агентств, заинтересованные в участии в программе повышения квалификации, а также каждый конкретный специалист (работник предприятия-заказчика) имеют возможность самостоятельно сформировать образовательную траекторию для повышения квалификации, выбрав для освоения все предлагаемые компетенции или некоторые из них в соответствии с имеющимся квалификационным дефицитом.

В разработке и реализации ОП принимают участие представители ведущих зарубежных образовательных, академических учреждений и предприятий наноиндустрии: Кристиан Колерт (Christian Kohlert), д-р, академик МАН ВШ, директор подразделения технологий и процессов «Klöckner Pentaplast Europe», специалист в области наноструктурированных полимерных материалов и автоматизированных систем; Гунтер Райниг (Gunter Reinig), д-р техн. наук, профессор кафедры автоматического управления и теории систем Рурского университета – Ruhr-Universität Bochum (Бохум, Германия), специалист в области моделирования и автоматизированного управления наукоемкими технологическими процессами.

2. Программа профессиональной подготовки (уровень – магистратура) в области материаловедения и высокотемпературных наноструктурированных конструкционных материалов и изделий (прикладная НИР по договору с Фондом инфраструктурных и образовательных программ ОАО «РОСНАНО» с целью подготовки молодых специалистов для ООО «Вириал», руководитель – проф. Чистякова Т.Б.)

Компетенции магистров, прошедших обучение по программе профессиональной подготовки в области материаловедения и высокотемпературных наноструктурированных конструкционных материалов и изделий соответствуют ФГОС высшего профессионального образования по направлению подготовки 150100 «Материаловедение и технологии материалов» (квалификация (степень) магистр). В разработке и реализации ОП принимают участие представители ведущих зарубежных образовательных, академических учреждений и предприятий наноиндустрии: д-р хим. наук, доцент Д.Н. Акбаева (Казахский национальный университет им. Аль-Фараби, Казахстан), д-р техн. наук профессор А.В. Рагуля (Институт проблем материаловедения им. И.М. Францевича НАН Украины), доктор М. Херрманн (Фраунгоферовский институт керамических технологий и систем, Германия), доктор-инженер М. Шубауэр (компания по производству строительных материалов и керамики «B + M NOTTENKÄMPER», Германия), доктор Ю. Гринь (Институт химической физики Общества Макса Планка, Германия).

3. Программа профессиональной подготовки «Автоматизированная обработка информации и управление производством наноструктурированных керамических материалов и покрытий» разрабатывается в режиме e-learning (с использованием видеолекций, мультимедийных учебных пособий, виртуальных практикумов и лабораторных занятий, реальных установок в удаленном доступе, тренажеров, презентаций с голосовым сопровождением, видеозаписей реальных экспериментов, вебинаров и т.д.). Данная программа проходит апробацию для инженеров-технологов ООО «Вириал».

27

Tamara Chistyakova Vice-Rector, Education SPbSIT (TU), Chairwoman of The Computer-Aided Design and Control Systems Department, Professor, Dr. Sc. (Engineering), Honored worker of higher school of the Russian Federation, Head of the leading scientific and educational schools of St. Petersburg and international research projects

Nano-educational program in Saint-Petersburg State Institute of Technology,

Prof. Tamara Chistyakova, SPSIT Three educational programs in automated manufacturing technology for professionals

enterprises of chemical and nano bio-technology are realized in the Institute of Technology: 1. The educational training program for professionals enterprises of chemical

and nano bio-technology in automated manufacturing technology (applied research under contract with the Fund for Infrastructure and Educational Programs RUSNANO, supervisor - Prof. Tamara Chistyakova).

The leaders of profiled companies, and the heads of Human Resource Management who are interested in participating in the program of improving qualifications, as well as employees of the corporate companies, have the opportunity to build an educational portfolio by selecting either all of the proposed competencies or some of them according to the current lack of qualification.

In developing and implementing educational programs, there partici-pate the following representatives of leading foreign educational, academic institutions and enterprises of nanotechnology: Christian Kohlert, Dr., director of technology and processes «Klöckner Pentaplast Europe», an expert in the field of nanostructured polymeric materials, and automated systems; Gunter Reinig, Dr. Sc. Sciences, Department of Automatic Control and Systems Theory Ruhr-Universität Bochum (Bochum, Germany), a specialist in the field of simulation and knowledge-based automated control of technological processes.

2. The training program (level - Master's degree) in the field of nanostructured materials and high-temperature structural materials and products (applied R&D contract with the Fund for Infrastructure and Educational Programs RUSNANO to professional training young specialists for the company, «VIRIAL», supervisor - prof. Tamara Chistyakova)

The competence of Masters graduates, trained in the field of nanostructured materials and high-temperature structural materials and products, conforms to Federal State Education Standards of Higher Education of direction of training 150100 «Materials Science and Technology of Material» (qualification (degree) Master).

In developing and implementing educational programs attended by representatives of leading foreign educational, academic institutions and enterprises of nanotechnology: Dr., Associate Professor D. Akbaeva (Kazakh National University. Al-Farabi Kazakh National University, Kazakhstan), Doctor of Technical Sciences, Professor A. Ragulya (Frantsevich Institute for Problems of Materials Science), Dr. M. Herrmann (Fraunhofer Institute for Ceramic Technologies and Systems, Germany), Dr. M. Shubauer engineer (company producing building materials and ceramics «BM NOTTENKÄMPER», Germany), Dr. Yuri Grin (Institute of Chemical Physics, the Max Planck Society, Germany).

3. The training program «Computer-based information processing and production control of nanostructured ceramic materials and coatings is developed in the mode of e-learning (with video lectures, multimedia tutorials, workshops, and virtual labs, real installations in remote access, simulator, and presentations with voice, video, real experimentation, webinars, etc.). This training program is being tested for process engineers (VIRIAL Limited Liability Company).

Presentation Abstract Development of an Integrated, Comprehensive Micro and Nanomaterial Inhalation Exposure Setup TSE Systems specializes in modular, comprehensive, automated highinhalation toxicology, behavioral and metabolic phyears of experience in developing and manufacturing highstudies. TSE Systems is one of the leading suppliers of complete inhalation exposure system solutions. Thesystems consist of multiple components, such as aerosol or dust generators, whole body, nose only, or cell culture exposure units, Daco control and regulation software, analysis tools and integrated safety devices. Our inhalation systems have been valiWith the introduction of the E-Spray NanoGen, atechnology, and the NanAeroSpec nanoparticle aerosol spectrometer, we have opened the door tuse nanomaterials with our inhalation exposure systems. The Eadapted for nose-only exposure systems. We are now able to offer complete systems out of one hand, globally supported by our trademark 2-Year ALL-IN Warranty and Service Package and a dedicated group of highly qualified service engineers. Further extensions of the system and novel applications are in the planning stages.

28

Curriculum Vitae Jürgen Fehmer – Sales Director TSE Systems GmbH, Bad HomburgSince: 01/2011 Position: Sales Director Eastern Europe & Middle East PJA Genomika, Moscow 05/2010 – 12/2010 Position: Business Development Director Parallabs, Moscow 10/2005 – 04/2010 Position: Business Development Director

Geneworx AG, Oberhaching 09/2004 – 09/2005 Position: Chief Executive Officer Protedyne Europe GmbH, Martinsried03/2002 – 09/2004 Position: Managing Director a1-Biotech GmbH, Planegg 10/1998 – 03/2002 Position: General Manager UniEquip Laborgerätebau und- vertriebs GmbH, Planegg09/1982 – 10/1998 Position: Trainee sales and marketing Siemensstr.21 / 61352 Bad HomburgT: +49-6172-789-0 F: +49-6172-789E-Mail: [email protected]

Presentation Abstract

Development of an Integrated, Comprehensive Micro and Nanomaterial Inhalation Exposure Setup

TSE Systems specializes in modular, comprehensive, automated high-throughput systems for inhalation toxicology, behavioral and metabolic phenotyping, and other applications years of experience in developing and manufacturing high-quality laboratory supplies for research

TSE Systems is one of the leading suppliers of complete inhalation exposure system solutions. Thesystems consist of multiple components, such as aerosol or dust generators, whole body, nose only, or cell culture exposure units, Daco control and regulation software, analysis tools and integrated

Our inhalation systems have been validated for controlled exposure conditions with microparticles. Spray NanoGen, a nanoparticle aerosol generator utilizing

and the NanAeroSpec nanoparticle aerosol spectrometer, we have opened the door tuse nanomaterials with our inhalation exposure systems. The E-Spray NanoGen has already been

only exposure systems.

We are now able to offer complete systems out of one hand, globally supported by our trademark and Service Package and a dedicated group of highly qualified service

engineers. Further extensions of the system and novel applications are in the planning stages.

Sales Director

Bad Homburg

Position: Sales Director Eastern Europe & Middle East



Protedyne Europe GmbH, Martinsried

vertriebs GmbH, Planegg

Position: Trainee sales and marketing

Siemensstr.21 / 61352 Bad Homburg 789-500

Development of an Integrated, Comprehensive Micro and

throughput systems for enotyping, and other applications - with over 125

quality laboratory supplies for research

TSE Systems is one of the leading suppliers of complete inhalation exposure system solutions. These systems consist of multiple components, such as aerosol or dust generators, whole body, nose only, or cell culture exposure units, Daco control and regulation software, analysis tools and integrated

dated for controlled exposure conditions with microparticles. utilizing electrospray

and the NanAeroSpec nanoparticle aerosol spectrometer, we have opened the door to Spray NanoGen has already been

We are now able to offer complete systems out of one hand, globally supported by our trademark and Service Package and a dedicated group of highly qualified service

engineers. Further extensions of the system and novel applications are in the planning stages.

29

Curriculum Vitae Prof. Dr. Harald Fuchs Harald Fuchs is a Full-Professor of Experimental Physics at the University of Muenster, Germany, and Founder and Scientific Director of the Center of Nanotechnology (CeNTech). He received his PhD degree in 1982 at the University des Saarlandes, Saarbrücken and spent from 1984 –1985 a post doctoral year with IBM Research Laboratory Zurich in the group of G. Binnig & H. Rohrer. From 1985-1993 he was heading the ‚Ultrathin Organic Films’ project with BASF AG, Germany, before he became 1993 Full Professor and Director at the Physical Institute of the University of Münster. His research focuses on nanoscale science and nanotechnology, ranging from scanning probe microscopy to self organized nanostructure fabrication, and nano-bio systems. He has published more than 400 scientific articles, and has filed more than 30 patents. He was awarded with several research prizes. He holds several guest professorships in Asia. He is a cofounder of nanotechnology companies and a member of the Editorial Boards in several international journals. He is elected member of the German National Academy of Science ‘Leopoldina’, the German National Academy of Science and Engineering 'acatech', and the TWAS.

30

PRESENTATION ABSTRACT

Self-organized functional molecular systems

- Generation and Characterization -

Harald Fuchs Physikalisches Institut

Westfälische Wilhelms-Universität Münster & Center for Nanotechnology (CeNTech)

D-48149 Münster, Germany Functional nanoscale materials are of high interest for the generation of novel diagnostics and targeting techniques in nanoBiomedicine. Besides self-organization the generation of local nanostructures on surfaces can be done using scanning probe microscopy techniques. In particular, Dip-Pen Nano-Lithography (DPN), which originated from conventional AFM has proven in the recent years as a very valuable tool for the generation of chemical patterns of virtually any level of structural and chemical complexity. Depending on the molecular ink applied, biomimetic nanostructures can be easily generated as mono- and multilayers. Using parallel tip arrays this process can be significantly accelerated and allows the generation of nanopatterns covering areas as large as several square centimeters per minute. Examples for the generation of biomimetic nanostructures by DPN-Lithography and novel self-organization techniques using nanostructured surfaces for the promotion of unusual chemical reactions and the generation of well-defined and oriented graphene nanoribbons will be presented. References: S. Linden, D. Zhong, A. Timmer, N. Aghdassi, J.-H. Franke, H. Zhang, X. Feng, K. Müllen, H. Fuchs, L. F. Chi, H. Zacharias Electronic structure of spatially aligned graphene nanoribbons on Au(788) Phys. Rev. Lett. 108, 216801-(5pp) (2012) S. Sekula-Neuner, J. Maier, E. Oppong, A. Cato, M. Hirtz, H. Fuchs Allergen arrays for antibody screening and immune cell activation profiling generated by parallel lipid dip-pen nanolithography Small 8, 585-591 (2012) D. Zhong, J.-H. Franke, S. Kumar Podiyanachari, T. Blömker, H. Zhang, G. Kehr, G. Erker, H. Fuchs, L. F. Chi Linear alkane polymerization on a gold surface Science 334, 213-216 (2011) S. Lenhert, F. Brinkmann, T. Laue, S. Walheim, C. Vannahme, S. Klinkhammer, M. Xu, S. Sekula, T. Mappes, T. Schimmel, H. Fuchs Lipid multilayer gratings, Nature Nanotechnology 5, 275-279 (2010) E-mail: [email protected] Web: http://www.uni-muenster.de/Physik/PI/Fuchs http://www.centech.de

31

German-Russian Network NanoBRIDGE (www.nanobridge.owwz.de) The consortium NanoBRIDGE is focused on the intensification of the German-Russian collaboration in technology and science fields for biomedical and bioanalytical nanotechnology to increase the international competitiveness of both countries. Following the mission „Bridging Nano for Sustainable Competitiveness“ new partners will be integrated, bilateral workshops realized, as well as research and development projects and cooperation initiated. These activities and the exchange of young scientists create synergies in the nanobiotechnology to benefit joint advance in the biomedical research and application. The conceptual study on bilateral education and coaching in nanobioanalytics, nanotechnology and cooperation of innovative enterprises enable the sustainability of the bilateral collaborations. Major competences: - Nanobioanalytics - Nanostructured biosensors - Nanostructure, nanophotonics and -optics for diagnostics and therapeutic techniques - Nanotechnology for medical and gene technology.

Dr. Gabriele Gorzka

Graduated in East European studies (1975), Ph.D. degree (1979), Research Assistant at the Centre of Research on Higher Education and Work at the University of Kassel, Germany (1978 – 1990), Lecturer for East-European History at the University of Kassel, research on Soviet Cultural History (since 1983), First Vice-President of the University of Kassel (1990 – 1994), Managing Director of the East West Science Centre at University of Kassel (since 1994), Part-time Professorship for East European History at the University of Basel, Switzerland (1995 – 1996)

32

Ignatov G. Sergei – Dr Sci in Microbiology Head of Nanobiotechnology laboratory State Research Center for Applied Microbiology and Biotechnology, Obolensk, Moscow Region 142279 RUSSIA Major fields of training and research experience: Nanobiotechnology, nanotoxicology, , biosensors, antioxidants detectionmicrobiology, biochemical study of bacterial membranes

Specific Identification of Bacterial Cell Fragments with Using Atomic Force Microscopy.

Sergei G. Ignatov1, E. V. Dubrovin2, E.N. Baranova1 , S.F. Biketov1

1- State Research Center for Applied Microbiology and Biotechnology, Obolensk, 142279, Russia

2- M.V. Lomonosov Moscow State University, 1/2 Leninskie gory, Moscow, 119991, Russia

33

Prof. Dr. Christian Kohlert 1975 Dipl.-Ing. of Chemical Engineering at TH Merseburg 1978 Dr.-Ing. Technological Institute in Leningrad,Russia Topic: Increasing the calendering of polymers 1978 - 1991 Scientific Assistant Professor TH Merseburg 1991 to date Kloeckner Pentaplast GmbH & Co.KG Director of Process Technology Kloeckner Pentaplast Europe Project Manager, Russia 1998 Honorary Professor at University of St. Petersburg 2008 Member of the International Academy of Sciences of higher education (IHEAS) based in Moscow 2011 Member of the Leibniz Society of Sciences in Berlin

Nanotechnology to improve properties of polymer films

Klöckner Pentaplast as a manufacturer of packaging films for pharmaceutical and food packaging represents over 500 000 tons of PVC rigid films, PET, PA and other materials after calendering or extrusion. For several years, Pentaplast employs the use of nanoparticles in the formulation or as a coating for the achievement of surface effects. This special coating methods have been developed that allow flexible thin films applied to surfaces. This can be done by spraying, dye felt coating or by aerosol corona surface treatment. Many properties are desired, but only on the surface of a polymer film, because they only work there either should or can be taken for reasons of cost-effective to use. Here we differentiate between active surfaces that protect the packaged product and extend shelf-life, in intelligent interfaces that provide information about the condition of the packaging material and special features, such as better or worse printability and scratch resistance. Klöckner Pentaplast operates at its plant in St. Petersburg a common "center of polymer films" with the St. Petersburg Technological Institute, where scientific knowledge of nanotechnology laboratory and production equipment to be connected to film production and produced first applicable films with special properties based on nanotechnology.

Major competences:

- Calendering and extrusion of polymer films - Measurement of film characteristics - Using nanoparticles for packaging materials

34

Нанотехнологические исследования в России А.А. Малыгин

В сообщении рассмотрены некоторые результаты по научным исследованиям и путям их

коммерциализации в Росси в области нанотехнологий.

Разделяют нанотехнологии, действующие по принципу «снизу вверх», «сверху вниз» или их

сочетанием. Первые имеют предпочтительное развитие.

Характерной особенностью разрабатываемых процессов «снизу вверх» является высокий

удельный вес химических подходов при их реализации. В значительной степени чисто физические

технологии достигли предела с точки зрения свойств используемых в них материалов и оборудования.

Существующая в настоящее время ситуация свидетельствует о том, что проекты в области

разработки нанотехнологии и наноматериалов могут быть успешно реализованы междисциплинарными

коллективами, обладающими необходимым научным и кадровым потенциалами и, безусловно,

материальными ресурсами. Поэтому представляется целесообразным создание учебно-научно-

производственных комплексов, объединяющих университеты, академические институты и

промышленные предприятия, для осуществления совместных комплексных научно-исследовательских

проектов, обеспечения подготовки высококвалифицированных кадров и ускоренного внедрения

результатов научно-технических разработок в промышленность.

Серьезный импульс к практической реализации работ по нанотехнологии, безусловно, дало

создание в 2007 г. Роснанокорпорации, а также проведение исследований в рамках программ

Минобрнауки, отраслевых министерств.

Санкт-Петербург является крупным промышленным центром, который ориентирован на развитие

таких отраслей промышленности как машиностроение, судостроение, электроника, пищевая,

фармацевтическая промышленность, топливно-энергетический комплекс и др. Из мировой практики

известно, что в большинстве из вышеперечисленных отраслей уже находят широкое применение

материалы и процессы нанотехнологии. К сожалению, в связи с отсутствием на многих отечественных

промышленных предприятиях собственной научно-исследовательской базы, активная деятельность по

внедрению нанотехнологий, реализуется, очень медленно.

Одними из приоритетных направлений в России являются исследования в области разработки

базовой технологии для решения проблем создания элементной базы наноэлектроники. В то же время

все более активно принципы нанотехнологии затрагивают практически все области твердофазного

материаловедения. Об этом свидетельствуют приоритетное направление «Индустрия наносистем и

материалы», затрагивающие такие материалы, как кристаллические, полимерные, керамические,

композиционные, мембранные, биосовместимые и др.

На примере разработок СПбГТИ(ТУ) рассмотрены некоторые результаты как научных, так и

прикладных разработок по созданию наноматериалов различного функционального

назначения, а также пути их коммерциализации.

Представлены результаты сотрудничества СПбГТИ(ТУ) и немецкой фирмы Клекнер

Пентаплас по применению нанотехнологий в производстве полимерных пленок.

Отмечено, что исследования, проводимые в СПбГТИ(ТУ) в области создания

наноматериалов поддерживаются грантами РФФИ (гранты 11-03-12040, 10-03-00658),

выполняются в рамках программ Минобрнауки, а также финансируются промышленными

предприятиями и бизнесс-структурами.

35

36

37

Dr.-Ing. Uwe Reichel

Education:

1981 Dipl.-Ing. of “Materials and Technologies of Silicates” (Technologies of Glass and Ceramic) at TU Bergakademie Freiberg; 1990 Dr.-Ing. at TU Bergakademie Freiberg in the area of materials science / ceramic material; Career:

1981 – 2006 different leading works in industrial companies of Technical Ceramic / Advanced Ceramic: Professional experience over 20 years in the fields of

- Silicate materials (Glass / Ceramic) - Advanced Ceramic (Structural ceramic) - Nano structured materials (Ceramic) - Technique for joining parts (ceramic / glass –

metal) - Application of ceramic parts in industry and

medicine

from 2007 Scientist at Hermsdorfer Institut for Technical Ceramic (HITK) / since 2010 Fraunhofer IKTS, Division Oxide Ceramic Components and Systems; project manager

Main topics: nanostructured ceramic materials for high strength, biocompatibility and transparency

Ceramic materials based on nanopowders Ceramic parts or systems are almost at all times parts of a solution with important and unique attributes. An essential quality standard for advanced ceramic is the structure design of the material: Submicron Grain size and defect free structure, that means without pores, cracks and inhomogeneous parts or pollutes. To manufacture advanced materials and products especially optimized processing is necessary. Two most difficult steps for nano-structured ceramics are the powder compacting to homogeneous green parts and the sintering technology to avoid giant grain growth. One main emphasis is the development of powder processing for submicron and nanodisperse powders to get new ceramic bulk materials with submicron (or nanodisperse) structure. The development is directed at better mechanical, chemical and optical functions, for instance in Electrical Engineering and Optics, Medicine and Microengineering. Important areas for our work are the preparation, characterisation and handling of nanoparticles and suspensions including the health and environmental aspects. Different results of powder processing, shaping and sintering are shown and various ceramic materials are examined. Possible applications are nanostructured ceramic materials for Medical implants, Surgical instruments, Nanostructured Optoceramics (Transparent ceramic material) for diagnostics and therapeutic techniques / antibacteria photodynamic Therapie (aPDT), sensors, cutting tools, bearings, wear parts etc.

We are looking for R&D-projects / participants for: -Development / Production of Ceramic nanopowders -Compacting technologies for Ceramic nanopowders -User / Application for nanostructured ceramic materials / optoceramic materials

38

Dr. Nina Sergeeva Researcher of the theoretical foundations of Materials Technology Institute (St. Petersburg), candidate of technical sciences. Works at the Institute since 2006. Deals with the synthesis of colloidally dispersed phosphors and studied their optical and luminescent properties. Efforts aimed at establishing the relationship of initial conditions for the synthesis of structurally. Interest in the study initiated by employees of the Physico-Technical Institute, Ioffe, (St. Petersburg), which help to meaningfully understand the variety of experimental data. [email protected]

Orange luminescence of colloidal zinc sulfide in the presence of

sodium chloride

Sergeeva N.M., Tsvetkova M.N., Osokina N.A, and Abyzov A.M. «Saint-Petersburg State Technological Institute (Technical University)» (SPbSTI (TU))

St. Petersburg, Moskovsky prospect 26, 190013, Russia Tel: (812) 494-92 – 86

Abstract. The possibility of obtaining colloidal dispersion of zinc sulfide with a high content of manganese. This is achieved by adding sodium chloride, triggering increased spatial symmetry, as one of the phases of manganese, as well as the main phase of zinc sulfide. The observed effect strengthens the lattice of zinc sulfide. In the photoluminescence spectra present a band of manganese luminescence at a wavelength of 605 nm. 1. Introduction. Colloidal phosphors based on ZnS nanocrystals with typical sizes smaller than 10 nm have attracted the attention of researchers because of the possibility of their use in optoelectronics. Phosphors have high photoluminescence yield and the opportunity to adjust the shades of orange and red colors to produce beautiful color combinations. However, one can in-crease the concentration of manganese, only 2% in the standard technology of doping ZnS pho-sphors. This paper shows a way of increasing the concentration of manganese by changing the spatial symmetry of the co-precipitated colloidal phase method with the addition of NaCl. 2. Experimental and results. Colloidal synthesis method for the double-exchange reactions have been synthesized, zinc sulfide, containing 0 - 8% Mn with the addition of sodium chlori-de. Deposition of colloidal sulfides was carried out from acetate solutions of sodium sulfide with continuous stirring under normal conditions. Luminescent-optical properties of colloidal phosphor characterized the spectra of photoluminescence (PL), the relative values of the brigh-tness of the photoluminescence and absorption spectra obtained by special treatment of electronic spectra of diffuse reflection on the Kubelka-Munk equation. The phase composition of solid phase sulfides was studied by X-ray diffraction analysis indicate. X-ray diffraction patterns were obtained on minidifraktometre "diffracted" of λ (CuKα-radiation). All phases of the cubic system and are presented face-centered lattice, but differ in the symmetry class (data JCPDS). By symmetry class is one of the two phases of manganese sulphide belongs to the structural type of sodium chloride with space group Fm3m, and the other - to the type of zinc sulfide with the space group F43m. Phase F43m manganese sulfide and sodium chloride had similar values of lattice parameters. 3. Conclusion. Adding sodium chloride in the process of co-deposition of a mixture of sulfides possible to eliminate the defect luminescence of solid solutions and get the orange luminescence with chromaticity coordinates X = 0,443 and Y = 0,42.

39

Curriculum Vitae - Jürgen Spielvogel Juergen Spielvogel studied Physics at the University of Stuttgart (1989-1993). As fellow of the Rose-Hulman International Fellowship (Indiana, USA) he completed his Master in Applied Optics (1995) with the thesis titled: Study of the photorefractive phase shift in a BaTiO3 crystal using an interferometric technique. He worked at the Institute for Lasertechnologies in Medicine and Metrology (Ulm, Germany) on infrared spectroscopy with Silverhalide fibers and at the University of Ulm where he used Raman spectroscopy and AFM for adhesion experiments. He participated in exchanges with the Kanazawa Institute of Technology (Japan) and Tel Aviv University (Israel) and spent seven years in the industry in USA where he worked in the R & D departments of three major particle counting companies. At his former employer in Germany he was responsible for the nano instrumentation division. He joined Palas in 2010 and is now responsible for the development and distribution in the fields of environmental monitoring and nano instrumentation.

A new versatile condensation particle counter for research and environmental monitoring Presented will be a recently developed condensation particle counter in which the unique, patented way of providing the working fluid for condensation allows the user to change the working fluid from e.g. butanol to isopropanol or water. Within the saturator the working fluid is moved helically around the flow area of the aerosol leading to a homogeneous contact area. By changing the working fluid but with the same hardware it is for example possible to conclude on hydrophilic and hydrophobic particles or to study how these properties change during aging of the aerosol. Measurements using this feature were made at a mail distribution center and will be presented. Since butanol can cause skin irritation and other adverse health effects it is desirable to use other working fluids when possible. This condensation particle counter provides a platform to analyze suitable replacements, e. g. less hazardous, more environmentally friendly. The modular design of this instrument further allows adapting the sensor to different concentration levels up to single particle counting of concentrations of 1,000,000 particles/cm3. This eliminates the need to dilute the aerosol in many cases. The counting is performed by an optical aerosol spectrometer (sensor) that also measures the size of the droplets that result from the internal condensation process. A researcher can easily monitor changes in this droplet distribution due to different temperature settings, different working fluid or different particle composition in the analyzed aerosol. Selected measurements will be shown.

40

Plasma coatings on plastic films, glass, ceramics and powders

A.A. Eruzin, K.A. Ogurtsov, I.B. Gavrilenko, M.M. Sychov St. Petersburg State Institute of technology (Technical University)

Fabrication of metal and ceramics coatings on plastics, fabric, glass substrates and powders using “frozen plasma” technology which allows one to maintain low substrate temperature. Advantages: Low cost, High throughput, Low substrate, temperature, High adhesion to substrate, Increased hardness, Improved aesthetics properties of material, Magic mirror effect. Applications:

• Tranparent conductive ZnO coatings for displays, sensors, solar cells and heating elements.

• Good-looking, metal-looking and antiscratch coatings on plastics and glass for mobile electronics;

• Control of hydrophilic-hydrophobic properties; • Identification of goods and documents. • Capsulation of powders in order to protect from moisture, improve processibility.

Possible substrates: PMMA, ABS, polycarbonate and other plastics, plastics with galvanic coatings (Cu, Ni,Cr). Coating material – metal, oxides, nitrides, polymers. Magic mirror effect is a high-tech article with modified surface. Due to that hidden image may be revealed in certain physical process like vapor condensation (e.g. from breathing), wetting by liquids, deformation. Effect is reversible. For plastics it is possible to achieve revealing of hidden image by one-time process of mechanical deformation. Effect may be used for decoration as well as for identification purposes of documents, goods and package.


41

Luminescent Nanoparticles for Photodynamic Cancer Therapy

V.V. Bakhmetyev, L.P. Mezentseva, A.V. Osipov, A.I. Orlova, N.V. Malanina, A.E. Sovestnov, V.A. Trunov, A.E. Sokolov, M.M. Sychov

St. Petersburg State Institute of technology (Technical University)

One of the methods of cancer treatment is photodynamic therapy. Its essence is the injection of a photosensitizer in the body - a drug that can selectively accumulate in tumors and to produce under the influence of light active oxygen, which destroys the tumor. The main problem is the lead-in light, that stimulated photosensitizer directly into the tumor tissue. The resolution to this problem may lie in the injection into the body of the nanosized phosphor, emitting light with a required wavelength under the influence of X-ray or gamma radiation easily penetrates through the body.

The aim of this study was to obtain of nanosized phosphor having a particle size not exceeding 70 nm, capable of efficiently luminesce under the action of X-ray or gamma-radiation with a peak in the luminescence spectrum near 662 nm, which corresponds to the maximum in the absorption spectrum of Photoditazin - known photosensitizer.

It is known that the effective X-ray and radioluminescence have phosphors based on phosphates. In this paper, for the synthesis of phosphate nanosized phosphors used sol-gel method, which consists in the precipitation of phosphate from aqueous solutions of metal salts. Deposition was carried out in acidic, neutral and alkaline solution. As precipitants used phosphoric acid and ammonium dihydrogen phosphate. The resulting gels were separated from the solutions, dried and annealed at temperatures from 600 to 1000 °C. Was synthesized a many samples of phosphate nanosized phosphors with different chemical structure.

X-ray study of the synthesized samples was excited by radiation from X-ray tube with a wavelength of 0.4...1.7 Å showed that the highest intensity of luminescence wavelength near 662 nm have a nanosized phosphor Zn3(PO4)2:0.05Mn. The average particle size of the synthesized samples according to atomic-force microscopy was 54.8 ± 12 nm, that allows preparing from them a colloidal solution with Photoditazin suitable for injection into the body.


42

Olga Timak Sales Manager EXAKT Advanced Technologies GmbH since 2006, Business Unit Mixing and Dispersion, Focus Eastern Europe, Russia and Ukraine

Directed dispersion of nano particles for defined material characteristics with EXAKT Three-Roll Mills Realizing functional properties of materials is key. Within suspensions this depends not just on particles and formulation, but also on the processing. The crucial parameters for defined characteristics are

• Preservation of the primary particles‘ properties • Defined particle size • Defined, homogenous particle distribution • Optimized wetting of the particle • Defined rheological properties • Reproducibility

This is valid for all applications, whether bio or industrial material. To realize those parameters, the process needs controllable application of energy and a directable dispersion mechanism. Shear is the main dispersion mechanism of the EXAKT Three Roll Mill. Using the example of Carbon Nanotubes, a very challenging particle, we show the advantages of this process.

43

Curriculum Vitae Usoltseva Nadezhda Vasil’yevna 1973: Defended Thesis of Candidate of Science - Ph.D

1976

-

1983:

Senior Researcher at the Liquid Crystals Laboratory in

Ivanovo State University

1990: Defended Thesis for a Doctors Degree in Leningrad

University (Doctor of Sciences – Habilitation; Physical

Chemistry, Colloid Chemistry)

since

1992:

Professor of Chemistry

1983

-

2008:

Head of the Laboratory

2004: Awarded the Freedericsz Medal of the Russian Liquid

Crystal Society "Commonwealth"

2006: Honored Expert in Higher Professional Education of

the Russian Federation

Since

2008

Head of Nanomaterials Research Institute of Ivanovo

State University

Head of a large number of projects awarded with

grants of DAAD, DFG, DFG – RFBR, INTAS, Ministry of

Education of Russian Federation

Languages

German, English

Publications

Author of more than 250 articles, among them 6

monographies and 12 patents. Editor-in-chief of 4

monographies, 4 Interuniversity collected articles:

"Liquid Crystals" (Ivanovo, 1986 and 1987),

"Structure and Properties of Liquid Crystals" (1989,

Ivanovo), "Liquid Crystals and their Application"

(Ivanovo, 1990). Editor in Chief of journal

International LC Community "Commonwealth"

"Liquid Crystals and Their

Application".(http://nano.ivanovo.ac.ru/journal.php).

44

Tigran Vartanyan. Ph.D. from Vavilov State Optical Institute in 1980, Dr. Sc. from the Supreme Certifying Commission of Russian Federation in 2004. Since 2006 he is a professor at the St. Petersburg National Research University of Information Technologies, Mechanics and Optics (NRU ITMO) and headed a Laboratory of Surface Photophysics at this University. He held also visiting positions in the Universities of Germany (Kassel, Bonn), France (Paris) and USA (SUNY Buffalo, NMSU Las Cruses). His current research interests are in the field of photoinduced surface processes and nanoplasmonics.

Developing of laser-based techniques for creation and shaping of metal nanostructures

Among different approaches to manufacture ordered metallic, semiconductor, or organic

nanostructures the so called “top-down” technologies are leading1,2. They include molecular beam epitaxy, electroplating, mask and interference photolithography as well as electron beam lithography followed by the chemical or electrochemical etching. Although these technologies are mature and almost universally applicable they are not free of shortcomings. The main drawback is the excessive number of steps needed to fabricate a single pattern. Large amount of material waste and substantial energy consumption are the consequences of the processes complexity. In this respect the “top-down” counterpart, the so called “bottom-up” technologies look favorable3,4. These technologies are based on the self-organized and photoinduced formation of nanostructures. They attract a lot of attention due to the promises of scalability, reduced energy consumption and reduced production of waste that they offer. Basically, under proper conditions, a new material is deposited at those places of the substrate surface where it is needed. Hence, the number of steps to produce the required structure is reduced.

On the other hand, it is obvious that “bottom-up” technologies are not going to be universally applicable as it is the case with the “top-down” technologies. Every “bottom-up” technology relies on a specific process. Nevertheless, after a successful debut some of the “top-down” technologies may find very promising niche application. A lot of attention was devoted to the laser-induced processes that lead to the formation of metal nanostructures at the illuminated sites of the substrate. A new method to deposit silver nanoparticles from a solution exclusively at the spots of intense laser irradiation is reported in5. An array of microspheres was employed in6 to focus the laser light and produce metal nanostructures. In the first case metal nanoparticles were produced in advance via a chemical process while in the second case the diameter of the produced gold particles was about one micron. Another attractive possibility to produce metal nanostructures relies on the dipole forces exerted on the atoms by resonant standing waves. This technology named atom lithography is very complicated in realization due to the weakness of dipole forces. For this reason the atoms are to be cooled before entering the region where they interact with the standing waves. As a result the throughput tends to be rather low.

In this contribution we describe one specific process, which can be employed to develop a one-step technology of nanostructure production with lager throughput. We are going to show that light-induced atomic desorption is a reliable tool to control the surface number density of the adsorbed atoms in the course of physical vapor deposition process. In short, strong enough illumination diminishes the number density of the adsorbed atoms below the threshold value needed for the beginning of the nucleation process. Hence, the deposition pattern reproduces the distribution of the illumination intensity over the surface. [1]. Lin S. Y., Fleming J. G., Hetherington D. C., et al., Nature, 394, 251 (1998); [2] Su Y.W., Wu C.S., Chen C.C., Chen C.D., Adv. Mater., 15, 49 (2003). [3] Arsenault A., Fournier-Bidoz S., Hatton B., et al., J. Mater. Chem. 14, 781 (2004). [4] Wang X., Neff C., Graugnard E., et al., Adv. Mater. 17, 2103 (2005) [5] Henleya S. J., Silva S. R. P. “Laser direct write of silver nanoparticles from solution onto glass substrates for surface-enhanced Raman spectroscopy”. Appl. Phys. Lett. V. 91. P. 023107 (2007). [6] Othona C. M., Laracuentea A., Ladouceura H.D., Ringeisen B. R. “Sub-micron parallel laser direct-write”. Appl. Surf. Sci. V. 255 (5), Part 2, P. 3407-3413 (2008).

56

Documents

Foto Frontpage: Lab-on-chip system, PD Dr. Stefan ...€¦ · 2 Foto Frontpage: Lab-on-chip system, PD Dr. Stefan Thalhammer, Helmholtz Research Centre Munich. Foto page 2: view on