FORM 1 ANNEXURES · M/S ARBUDA INDUSTRIES F-95, RIICO , PHASE-II, MAVAL,ABU ROAD, DIST: SIROHI, RAJASTHAN-307026. 1 FORM 1 ANNEXURES ANNEXURE NAME OF THE ANNEXURE PAGE NO. ANNEXURE

M/S ARBUDA INDUSTRIES F-95, RIICO , PHASE-II, MAVAL,ABU ROAD, DIST: SIROHI, RAJASTHAN-307026.

1

FORM 1

ANNEXURES

ANNEXURE NAME OF THE ANNEXURE PAGE NO.

ANNEXURE I Detail of product 2

ANNEXURE II Detail of Raw Materials 3

ANNEXURE III Manufacturing process of

proposed product

4

ANNEXURE IV Water consumption

Wastewater generation

12

ANNEXURE V Details of flue gas emission 13

ANNEXURE VI Hazardous waste management

and disposal facility

14

ANNEXURE VII Power requirement of the plant 15

ANNEXURE VIII Effluent treatment plant 16

ANNEXURE IX Plan layout 18

ANNEXURE X Land Possession

Document

20

ANNEXURE XI TSDF site Membership

Letter


2

ANNEXURE-I

PRODUCTION DETAILS

Sr.

No.

Name Of

Product/Nature

M.W

(g/mol)/

Nature

CAS NO. Use

Of Product

Quantity

MT/Mont

h

1 Sulpho VS

Dyestuff &

Dyestuff

Intermediate

4

2 2, Naphthol, 6,8 Dia

Sulphonic Acid

(G. Salt)

304.287

118-32-1 Dyestuff &

Dyestuff

Intermediate

6

3 4 Sulpho Ortho Amino

Benzoic Acid

217 98-43-1 Dyestuff

Intermediate

5

4 4,4 Dinitro Stilbene, 2,2 Disulphonic Acid

430.358

3709-43-1 Dyestuff Intermediate

for Direct Dyes,

Manufacturing of DSD Acid

5

5 Metanilic Acid 173.19

121-47-1 Dyestuff &

Dyestuff

Intermediate

5

6 MPDSA (Meta Phenyl Di

Amine Sulphonic Acid)

188 88-63-1 Dyestuff

Intermediate

5

Total 30


3

ANNEXURE-II

PRODUCT WISE RAW MATERIALS DETAIL

Sr.

No.

Product Name Raw Material CAS NO. Proposed

MT/Month

1 Sulpho VS

Venyl Sulphne 2.516

Oleum (65 %) 2.516

Sulfuric Acid 3.240

KCl 1.844

2 2, Naphthol, 6,8

Dia Sulphonic Acid

(G. Salt)

B-Naphthol 135-19-3 7.1

Olium 23% 8014-95-7 13

Sulphuric acid 76-64-93-9 8.276

Caustic Soda Flakes 1310-73-2 0.166

Potassium chloride 7447-40-7 7.713 3 4 Sulpho Ortho

Amino Benzoic

Acid

Olium 23% 8014-95-7 40.0

Sulphuric Acid 76-64-93-9 4.0

Ortho Nitro Toluene 88-72-2 20.0

Caustic Soda 1310-73-2 16.0

HCl 30% 7647-01-0 80.0 4 4,4 Dinitro

Stilbene, 2,2 Disulphonic Acid

Pantosa 121-03-09 9.6

Caustic Flaks 1310-73-2 36

Soda Ash 497-19-8 4.52

O2 gas (AIR oxidation) 7782-50-5 10.2

5 MPDSA (Meta

Phenyl Di Amine

Sulphonic Acid)

MPD 108-45-2 7.4

Sulphuric Acid 7664-93-9 5.92

Oleum 8014-95-7 14.81

6 Metanilic Acid

Metanilic Acid

Nitro benzene 98-95-3 3.36

Oleum 8014-95-7 6.72

Calcium Hydroxide 1305-62-0 4.8

HCl 7647-01-0 1.2

Iron Powder 7439-89-6 3.36

Soda Ash 497-19-8 1.8

H2So4 7664-93-9 2.8


4

ANNEXURE-III

MANUFACTURING PROCESS

1. Sulpho VS


5

2. 2, Naphthol, 6-8 Di-Sulphonic Acid

(G. Salt)

OLIUM23% 1300 KGS

SULPHURIC ACID 98% 1000 KG

B-NAPHTHOL 1000 KG SULPHO MASS 2500

KG

WATER 100 KG

ICE 1100 KG

SULPHO MASS 2500 KG

PHOTASSIUM CLORIDE

900 KG

10% SULPHURIC SPENT

2700 KG

G-SALT 1400 KG TO

1450 KG

STAGE-1

REACTOR-1

STAIR

ADD SULFONATION MASS -

READY (HEAT 90C)

STAGE-2

OPEN REACTOR-2

ADD & STAIR

STAIR

DUMP

STAIR

ADD

READY G-SALT

THEN NUTCH & CENTRIFUSE


6

3. 4 Sulpho Ortho Amino Benzoic Acid

SULPHURIC ACID 98% 200 KG

ORTHO NITRO TOLUENE

1000 KG

OLIUM 23% 2000 KG

CAUSTIK SODA

(800 KG + 2000 LT WATER)

5800 LITERS AMINO

SLUDGE 58 KG

5800 LITERS AMINO

HIDRO CLORIC ACID (HCL)

200 KG

HCL 3800 KG

4,SULPHO ORTHO

AMINO BENZOIC ACID

(500 KG)

6 % HCL WATER

8900 KGS

STAGE-1

REACTOR-1

ADD

CHARGING

ADD

STAGE-2

OPEN REACTOR-2

2000 WATER + CAUSTIK SODA

STAIR IT

THAN FILTER

STAGE-3

OPEN REACTOR-3

STAIR

UP TO PH 6,8 TO7

ISOLATION

THAN NUTCH


7

4. 4,4DinitroStilbene, 2,2Disulphonic Acid

5. Metanilic Acid

1. Metanilic Acid

Manufacturing Process:

Stage-I

In a reactor Oleum (23%) is taken and Nitrobenzene is charged in it at a controlled

rate andtemperature. After that drawn the sulfo mass in water. Add lime slurry to

neutralize the reaction mass. Filter the solution to remove gypsum.

Stage-II

In a reactor, a mixture of Iron &HCl (30%) is made. In that sulfo mass is slowly

added. Filterthe ML & add H2SO4 (98%) to bring the pH 1.5. cool the reaction mass,

filter, centrifuge &getthe final product.

Chemical reaction:


8


9

Mass balance:

6. MPDSA (Meta Phenyl Di Amine Sulphonic Acid)

Manufacturing Process:

Reactor-1:

Take Sulphuric Acid, Oleum 65% Charged. Then take MPD and heat at 130 0 C

(Maintain).

Reactor-2:

Add Water, Ice and Sulpho mass Real. Then Nutch and Centrifuge.

Chemical Reaction:

Input Kg KG Output

Nitro benzene 840

Oleum 1680

Water 2800

Clacium Hydroxide 1200

2400 Gypsum

HCl 300

Iron Powder 840

Soda Ash 450

2000 Iron Sludge

H2SO4 700 1000 Metanilic Acid

200 Drying Loss

3210 Effluent to ETP

TOTAL 8810 8810 TOTAL

Metanilic Acid

ISOLATION & FILTERTION &

DRYING

REACTOR -1

FILTRATION

REACTOR-2

FILTER PRESS


10

+H2SO4+H2S2O7

Mass balance:

Input Kg KG Output

H2SO4 800

OLEUM 2000

MPD 1000

WATER 650

ICE 400

3500 SPENT

1350 MPDSA

TOTAL 4850 4850 TOTAL

MPDSA

REACTOR-1

REACTOR-2

NUTCH

CENTRIFUGE

PRODUCT


11

ANNEXURE-IV

WATER CONSUMPTION

Sr.

No.

Water required for Proposed

(KLD)

(1) Domestic 1.00

(2) Gardening 0.50

Industrial

(3) Process 4.73

(4) Cooling 1.00

(5) Boiler 2.50

(6) Washing & Scrubber 2.27

Total (Industrial) 10.50

Total (Industrial + Domestic + Gardening)

12.00

WASTEWATER GENERATION

Sr. No.

Water required for Proposed (KLD)

(1) Domestic 0.80

(2) Gardening 0.00

Industrial

(3) Process 4.00

(4) Cooling 0.50

(5) Boiler 0.50

(6) Washing & Scrubber 2.27

Total (Industrial) 7.27

Total (Industrial + Domestic +

Gardening)

8.07

NOTE:-

0.8 KLD Domestic waste water will be discharged to the soak pit.

7.27 KLD will be treated in ETP and evaporated by MEE in premises.


12

ANNEXURE-V

DETAILS OF FLUE GAS EMISSION

Flue Gas Emission

Process Gas Emission

Sr.

No.

Stack

Attache

d to

Stack Height

(m)

Fuel

Used

Quantity of Fuel

APCM

Pollutants

1.

Thermic

Fluid

Heater 6 Lac K

Cal

13

Agro

Waste

1.0 MT/Day

Multi Cyclone PM< 150 mg/Nm3

SO2< 100 ppm

NOx<50 ppm

2 Boiler

1 Ton

13 Agro Waste

1.0 MT/Day Multi Cyclone PM< 150 mg/Nm3

SO2< 100 ppm

NOx<50 ppm

Sr.

No.

Stack

Attached to

Pollutant Stack

Height

(m)

APCM Pollutants

1.

Scrubber SO2 13 Scrubber

SO2<40 ppm

2 Scrubber HCl 13 Scrubber HCl<20 ppm


13

ANNEXURE VI

HAZARDOUS WASTER MANAGEMENT AND DISPOSAL FACILITY

Sr.

No.

Types of

Waste Category

Total

MT/Annum Mode of Disposal

1.

Waste ETP

Sludge

34.3

15

Collection, Storage, Transportation and disposal to TSDF site.

2. Used Oil/

Spent Oil 5.1

0.10

Collection, Storage, Transportation and

Sold to Recycler, Re processor or used as Lubricants for Machineries.

3.

Discarded

Container / Drum Bags

33.3 6

Collection, Storage, Transportation and Sold to Registered Recycler

Or Send back to Raw Material supplier Or

Use for ETP sludge packing

4. Gypsum 26.1 52 Collection, Storage, Transportation and disposal to active incinerator site or actual register user.

5. Spent Acid 26.1 444 Collection, Storage, Transportation and sold to actual users having rule 9

permission.

5. Carbon

Waste 36.2 1.7

Collection, Storage, Transportation and

disposal to Incineration Site.

6. Salt from

MEE 35.3 30

Collection, Storage, Transportation and disposal to TSDF site.


14

ANNEXURE VII

POWER& FUEL REQUIREMENT OF THE PLANT

Detail of Power

Sr. No.

Electricity (KVA)

Source of Supply

Existing Proposed Total 1 125.00 - 125 Jodhpur Vidyut Vitran

Nigam Ltd.

Fuel Requirement

Sr.

No.

Stack

Attached to

Stack

Height

(m)

Fuel

Used

Quantity of

Fuel

APCM Pollutants

1.

Thermic Fluid Heater 6 Lac K Cal

13

Agro

Waste

0.5 MT/Day

Multi Cyclone

PM< 150 mg/Nm3 SO2< 100 ppm NOx<50 ppm

2 Boiler 800 KG

13 Agro Waste

0.5 MT/Day Multi Cyclone PM< 150 mg/Nm3 SO2< 100 ppm NOx<50 ppm

3 DG Set 125 KVA

13 Diesel 0.1 MT/Hr. 5.0 m Stack Height

PM< 150 mg/Nm3 SO2< 100 ppm NOx<50 ppm


15

ANNEXURE VII

EFFLUENT TREATMENT PLANT ETP PLANT

32 M

10.2

M

ME PLANT

STORAGE-3

EFLLUENT

STORAGE-2

EFLLUENT

STORAGE-1

ETP PLANT


16

ANNEXURE IX

Site plan


17

FACTORY LAYOUT PLAN

30.42 M

65 M 65 M

61.06 M

6 M

14 M

ETP AREA

GATE ELECTRIC

ROOM

OFFICE &

LAB ROOM

MANUFACTURING

AREA

UTILITY

S

T

O

R

A

G

E

T

A

N

K

A

R

E

A

WO

RK ER

RO

OM

C

T


18

ANNEXURE IX

Land Ownership Details


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21


22


23


24


25


26


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Documents

FORM 1 ANNEXURES · M/S ARBUDA INDUSTRIES F-95, RIICO , PHASE-II, MAVAL,ABU ROAD, DIST: SIROHI, RAJASTHAN-307026. 1 FORM 1 ANNEXURES ANNEXURE NAME OF THE ANNEXURE PAGE NO. ANNEXURE