FOR THE PROPOSED NEW PROJECT FOR MANUFACTURING …environmentclearance.nic.in/writereaddata/Online/TOR/07_Jan_2017... · THE PROPOSED NEW PROJECT FOR MANUFACTURING OF Trimethyl Phosphite

FOR

THE PROPOSED NEW PROJECT

FOR MANUFACTURING OF

Trimethyl Phosphite (TMP) and Triethyl Phosphite (TEP) @ 300.00 MT/Month,

TMP derivatives @ 200 MT/Month, Dichlorvos-Technical @100 MT/Month,

Dichlorvos-Formulation @100 MT/Month, Plastic and Paint Additives (Organic

Phosphite) – 300 MT/ Month, Organic Phosphates @ 150 MT/ Month

Under Activity: 5(b), Category- A

[Pesticides industry and pesticide specific intermediates (excluding formulation)]

OF

Located at:

Plot No. 1249 & 1250, GIDC Notified Industrial Area, Sarigam, Dist-Valsad (Gujarat).

PROJECT PRE-FEASIBILITY REPORT

M/s. Sandhya Organic Chemicals Pvt. Ltd., Sarigam II

INDEX

1. Executive Summary……………………………………………………………………………………….………………. 01

2. Introduction……………………………………………………………………………………..………….………………… 06

I. Identification of Project and proponent…………………………………………………..…..………… 06 II. Brief description of nature of the Project……………………………………………………..………… 06 III. Need for the project and its importance to the country and or region…………..……….. 06 IV. Demand –Supply Gap…………………………………………………………………………………….………. 07 V. Imports vs. Indigenous production……………………………………………………………..………….. 07 VI. Export Possibility / Domestic / export Markets…………………………………………..…………. 07 VII. Employment Generation (Direct and Indirect) due to the project……………….……….... 07

3. Project Description…………………………………………………………………………………………………………. 08

I. Type of Project including interlinked and interdependent projects, If any……………… 08 II. Location (map showing general location, Specific location, and project boundary &

project site layout) with coordinates………………………………………………………………………

08

III. Profile of Project Site……………………………………………………………………………………………… 09 IV. Site Layout Plan……………………………………………………………………………….…………………….. 10 V. Details of alternate sites considered and the basis of selecting the proposed site,

particularly the environmental considerations gone into should be highlighted……………………………………………………………………………………….…………………….

11

VI. Size or magnitude of operation………………………………………………………………………………. 11

VII. Project description with process details (a schematic diagram/ flow chart showing the

project layout components of the project etc. should be given)……………………..

12

VIII. Raw material required along with estimated quantity, likely source, marketing area of

final products/s, mode of transport of raw Material and finished product

26

IX. Resource optimization/ recycling and reuse envisaged in the project, if any, should briefly

outlined……………………………………………………………………………………………………….

27

X. Availability of water its source, Energy/power requirement and source should be given……………………………………………………………………………………………………………………….

28

XI. Quantity of waste to be generated (liquid and solid) and scheme for their Management/disposal……………………………………………………………………………………………

29

XII. Schematic representations of the feasibility drawing which give information of EIA purpose…………………………………………………………………………………………………………..........

34

4. Site Analyses………………………………………………………………………………………………………………..… 35

I. Connectivity…………………………………………………………………………………………………………… 35 II. Land Form, Land use and Land ownership……………………………………………………………… 35 III. Topography (along with map)………………………………………………………………………………… 36 IV. Existing land use pattern (agriculture, non-agriculture, forest , water bodied ( including

area under CRZ)), shortest distances from the periphery of the project to periphery of the forest, national park, wild life sanctuary , eco sensitive areas, water bodies (distance from the HFL of the river), CRZ . In case of notified industrial area, a copy of Gazette notification should be given………………………………

36

V. ExistingInfrastructure…………………………………………………………………………………………….. 36 VI. Soil classification……………………………………………………………………………………………………. 36 VII. Climate data from secondary sources…………………………………………………………………….. 36 VIII. Social Infrastructure available………………………………………………………………………………… 36

5. Planning Description………………………………………………………………………………………………………. 38

I. Planning Concept (Type of industries, facilities, transportation etc) Town and Country Planning /Development authority Classification………………………………………..

38

II. Population Projection…………………………………………………………………………………………….. 38


M/s. Sandhya Organic Chemicals Pvt. Ltd., Sarigam III

III. Land use planning (breakup along with green belt etc……………………………………………. 38

6. Infrastructure Details……………………………………………………………………………………………………… 39

I. Industrial Area (Processing Area)………………………..…………………………………………………. 39 II. Residential Area (Non Processing Area)……….………………………………………………………... 39

III. Green Belt…………………………………………………………………………………………………….……….. 39 IV. Social Infrastructure……………………………………………………………………………………..……….. 39 V. Connectivity (Traffic and Transportation Road/ Rail/ Metro/ Water ways etc….……. 39 VI. Drinking Water management (Source & Supply of water)……………………….……………... 39 VII. Sewerage System…………………………………………………………………………………………………... 39 VIII. Industrial Waste Management………………………………………………………………..…………….. 39 IX. Solid Waste Management………………………………………………………………………..……………. 39 X. Power Requirement & Supply / Source………………………………………………………………….. 39

7. Rehabilitation and Resettlement (R&R) Plan………………………………………………………………….. 40

I. Policy to be adopted (Central/ State) in respect of the project affected persons including home oustees, land oustees and landless laborers (a brief outline to be given)……………………………………………………………………………………………………..……………..

40

8. Project Schedule & Cost Estimates………………………………………………………………………………... 40

I. Likely date of start of construction and likely date of completion (Time schedule for the project to be given…………………………………………………………………………………………...

40

II. Estimated project cost along with analysis in terms of economic viability of the project…………………………………………………………………………………………………..……………….

40

9. Analysis of Proposal (Final Recommendations………………………………………………………………… 41

I. Financial and social benefits with special emphasis on the befit to the local people including tribal population, if any, in the area…………………………….……………………….….

41


M/s. Sandhya Organic Chemicals Pvt. Ltd., Sarigam 1

1. EXECUTIVE SUMMARY

Name of Project: M/s. Sandhya Organic Chemicals Pvt. Ltd.

Location: Plot No. 1249 & 1250, GIDC, Sarigam- 396155.

Tal. Umbergaon, Dist. Valsad (Gujarat) INDIA.

Project

SANDHYA GROUP is one of the leading names in the speciality chemicals field in India, ever since its

inception in 1984. Sandhya has state of art manufacturing plants with large storage capacity and

sophisticated testing equipment for analysis. M/s. Sandhya Organic Chemicals Pvt. Ltd. is a

proposed manufacturing unit of Sandhya group located at Plot No. 1249 & 1250, GIDC, Sarigam-

396155. Tal.- Umbergaon, Dist.- Valsad (Gujarat) INDIA.

The unit proposes for manufacture pesticide intermediate products falling under the activity

“Pesticides industry and pesticide specific intermediates (including formulations)”

Trimethyl Phosphite (TMP) and Triethyl Phosphite (TEP) @ 300.00 MT/Month, TMP derivatives @

200 MT/Month, Dichlorvos-Technical @100 MT/Month, Dichlorvos-Formulation @100 MT/Month,

Plastic , Paint Additives (Organic Phosphite) – 300 MT/ Month, Organic Phosphates @ 150 MT/

Month and Co -products (Ammonium Chloride Solution or Crystal ,Methanol, HCL, Phenol)@2667.94

MT/month

The Proposed Project Cost: Rs. 1590.00 Lacs.

Applicability of EIA notification – 2006

Project activity as per schedule is 5(b), Category-A “Pesticides industry and pesticide specific

intermediates (including formulations)” (Trimethyl Phosphite (TMP) and Triethyl Phosphite (TEP) @

300.00 MT/Month, TMP derivatives @ 200 MT/Month, Dichlorvos-Technical @100 MT/Month,

Dichlorvos-Formulation @100 MT/Month, Plastic and Paint Additives (Organic Phosphite) – 300 MT/

Month, Organic Phosphates @ 150 MT/ Month)

Submission for obtaining EC under provision of EIA notification 14 September 2006, as amended.

Project Proponent

Indian Private Limited Company incorporated by the four Directors.

Medium Scale Unit



List of Finished Product

Sr.

No.

Product Name Quantity (MT/Month)

1. Trimethyl Phosphite (TMP)and Triethyl Phosphite (TEP) 300.00

2. TMP derivatives ([Tri Decyl Phosphite (TDP), Tris Tridecyl Phosphite (TTDP), Tri Lauryl Phosphite (TLP), Tri-Iso Octyl Phosphite (TIOP) etc]

200.00

3. Dichlorvos - Technical 100.00

4. DiChlorvos Formulation 100.00

5. Plastic and Paint Additives (Organic Phosphite)

(Tri Phenyl Phosphite, Diphenyl Isodecyl phoshite,

2-Hexyl Diphenylphosphite, Phenyl Di-IsodecylPhosphite,

Tri –Decyl Phosphite, Tri Trisdecyl Phosphite,

TrisNonyl Phenyl Phosphite, DiphenuulTridecylPhosphite (DPTDP), Tetra Phenyl

Dipropylene Glycol Phosphite (THOP),Poly (Dipropylene Glycol) Phenyl Phosphite

(DHOP),4-4-Isoproplidene bis (disodecyl Phenyl Phosphite),

DistearylpentaerythritolDiphosphite (DPEDP), TRIS (2,4 ditertbutylphenyl)

Phosphite,

TRIS (2,4 ditertamylphenylphosphite etc.)

300.00

6 Organic Phosphates

Tri aryl and Alkyl Phosphate Triphenyl Phosphate, Tricrisyl Phosphate, Tributyl Phosphate, Cresyl Diphenyl Phosphate, etc.)

150.00

7 Ammonium Chloride Solution or Crystal (Co-product) 2176.50

8 Methanol(Co-product) 30.54

9 HCL(Co-product) 414.90

10 Phenol (Co-product) 46.00

Total Product 3817.94



Resource Requirement

Raw Material Consumption

Sr. No.

Product Name Raw Materials Raw Material Consumption

Kg/MT MT/Month

1 Trimethyl Phosphite(TMP) / Triethyl Phosphite (TEP)

Phosphorus Trichloride 1108.000 332.400

Ammonia 411.000 123.300

Methanol / Ethanol 831.600 249.480

Catalyst [like Heavy Normal Parafine(HNP) and Diethyl Anilene(DEA)]

740.000 222.000

2 TMP derivatives ([Tri Decyl Phosphite (TDP), Tris Tridecyl Phosphite (TTDP), Tri Lauryl Phosphite (TLP), Tri-Iso Octyl Phosphite (TIOP) etc]

TMP 197.20 39.94

Alcohol (isodecyl alcohol) Tri Decyl Alcohol (TDA), Lauryl Alcohol (LA), 2-Octanol

955.50 191.10

3 Dichlorvos - Technical Chloral 667.00 66.70

Tri methyl phospite (TMP) 561.00 56.10

4

DiChlorvos Formulation Dichlorvos (DDVP) 760.00 76.00

Solvant C-9 230.00 23.00

Emulsifier 10.00 1.00

5 Plastic and Paint Additives

A. Tri Phenyl Phosphite Phenol 951.00 124.00

PCl3 450.00 58.00

B. Organic Phosphites

Tri Phenyl Phosphite 829.00 99.50

Alcohol (IsoDecyl alcohol, 2-Ethyl Hexanol, TriDecyl Alcohol, Di propylene Glycol, Bisphenol , Stearyl alcohol , Pentaerythritol etc.)

423.00 51.00

C. TrisNonyl Phenyl Phosphite, Tris ( 2,4 ditertbutylphenyl) Phosphite , Tris ( 2,4 ditertamylphenyl ) phosphite

Nonyl Phenol, 2,4 di-tert-butyl phenol, 2,4 di-tert-amyl phenol

959.00 48.00

PCl3 200.00 10.00


Alcohols (Phenol or Cresolor Butanol, etc.)

995.00 148.25

POCl3 470.00 70.50

Utility Requirement

Components Proposed Resources availability

Power 500 KVA Dakshin Gujarat Vij Co. Ltd.

Standby Power Source

D.G. Set (1 No.) Capacity: 320 KVA

Local Supplier

Fresh Water 133 KL/day GIDC water supply dept., Sarigam

Steam Requirement Steam Boiler - 2 No.

Capacity: 2000 Kg/Hr Local Supplier



Capacity: 1000 Kg/Hr

Heat Requirement Thermopack (1 No)

Capacity : 6 Lac kcal/hr Local Supplier

Fuel Requirement

HSD (for D.G. Set) @ 50 L/Hr. Bagasse briquettes (for Boiler) @2.00 MT/day

Bagasse briquettes (for TFH) @1.00 MT/day

Will be sourced from local dealer.

Water and Waste Water Management

Total Fresh Water requirement will be 133 KL/day & Water supply will be met from GIDC water supply dept.

Total industrial Waste Water Generation will be 30 KL/Day.

Domestic waste water (4 KL/day) will be disposed off through Septic Tank.

We will produce the product simultaneously therefore we have considered accordingly.

Air Emission and its Control Measures

Company shall install Thermic fluid heater having capacity of 6000 kcal/hr. Bagasse briquettes will be used as

a fuel for Thermic fluid heater.

Company shall install 2 nos. of Boiler having capacity of 2000 kg/hr. & 1000 kg/hr. Bagasse briquettes will be

used as a fuel for the boiler.

Company shall install a D.G. Set having capacity of 320 KVA, as stand by. It will be used during the power

failures. Diesel will be used as a fuel for the D.G. Set.

Adequate stack height and stack monitoring facilities will be provided as per rule. Also we will install the bag

filter as APCD for reduction of Air emission.

Adequate capacity of Scrubbing system will be installed for Ammonium Chloride recovery and to control the

process gas emission within the prescribed norms.

Hazardous Wastes and its Management

Types of Waste Quantity/annum Storage Method Method of Disposal

ETP Waste (Schedule-1, 35.3)

10.00 MT Will be stored at a separate storage area

Will be sent to TSDF, Vapi

Process residue (Schedule-1, 20.3)

27.00 MT Will be stored at a separate storage area in a closed container

Will be sent to co incineration or common incinerations.

Discarded containers (Schedule-I, 33.1)

400 Nos. Stored at a specified storage area as per rule.

After decontamination will be sold to re-conditioners

HDPE bags (Schedule-I, 33.1)

3000 Nos. Stored at a specified storage area as per rule.

After decontamination will be sold to re-conditioners

Used oil (Schedule-1, 5.1)

100 Lit Stored into the closed container. Disposal by selling to registered refiners



Hazardous Raw Materials Identification as per MSIHC Rules (2000)

Name Chemical Classification MSIHC Applicability

Phosphorus trichloride Toxic, Flammable, Corrosive (Class 6.1) Sh-I, Part-II,506

Ammonia Toxic , Flammable Sh-I, Part-II, 31

Methanol Flammable, Toxic Sh-I,Part-II,277

Ethanol Flammable Sh-I,Part-II,248

Butanol flammable Sh-I,Part-I

Solvent C-9 Flammable -

Chloral Toxic -

Phenol Toxic (Class 6.1) Sh-I,Part-II,481

POCl3 Toxic, Flammable, Corrosive (Class 8) Sh-I,Part-II,504

2-Ethyl Hexanol Flammble,Irritant(Class 3)) Sh-I,Part-II,254

Cresol Flammble Sh-I,Part-I

High Speed Diesel Flamable Sh-I, Part-I



2. INTRODUCTION

(i) Identification of Project and proponent

Name of the project Proponent: M/s. Sandhya Organic Chemicals Pvt. Ltd. located at Plot No. 1249 & 1250,

GIDC, Sarigam – 396155. Tal. Umbergaon, Dist. Valsad.

The unit is promoted by four Directors. Details related to them are given below:

Sr. No. Name of Directors Residential Address

1. Mr. Kantilal M. Koli

Plot No. 203 & 204, Residential Bunglow Area,

Sauravh Society, GIDC, Vapi – 396195.Dist.

Valsad (Gujarat).

2. Mrs. Sandhya K. Koli



Valsad (Gujarat).

3. Mr. Snehal K. Patel



Valsad (Gujarat).

4. Mr. Smit K. Patel



Valsad (Gujarat).

(ii) Brief description of nature of the Project

M/s. Sandhya Organic Chemicals Pvt. Ltd. proposes to establish their product manufacturing unit at Plot No.

1249 & 1250, GIDC, Sarigam – 396155. Tal. Umbergaon, Dist. Valsad (Gujarat) India.

The proposed project involves the production of “TMP & TEP, Dichlorvos, Paints & Plastic Additive Phosphites

and Organic Phosphates” which are Pesticide intermediates. For the proposed new project, the company

intends to procure the available latest technology for manufacturing the proposed products.

The industrial sector in the past years has seen a drastic boom and also the keeping in mind the globalization

trend, we have identified the demand for the proposed products and with continuous R&D found that it can

be developed in-house and produce commercially for domestic market as well as an eye more on export

markets.

As per the EIA notification‐ 2006 as amended the proposed new project involves the production of “TMP &

TEP, Dichlorvos, Paints & Plastic Additive Phosphites and Organic Phosphates” which falls under Item No. 5(b)

– Pesticides industry and pesticide specific intermediates (excluding formulations) as per the EIA

notification- 2006, hence required Prior Environmental Clearance.

(iii) Need for the project and its importance to the country and or region

The proposed project will provide a potential growth opportunity for the already running business of the

company. The industrial sector in the past years has seen a drastic boom and also the keeping in mind the

globalization trend, we have identified the demand for the proposed products and it can be developed in-

house and produce commercially for domestic market as well as an eye more on export markets. Its export

and also increase the foreign revenue. The products are now well established and acceptable in the

international markets.



(iv) Demand –Supply Gap

These products (TMP & TEP, Dichlorvos, Paints & Plastic Additive Phosphites and Organic Phosphates) have

very high demand these are the key intermediate in the manufacture of several organophosphatic pesticides

like Monocrotophos, DDVP, Phosphomidon etc , as a reagent in organic synthesis, as plasticizer for nylon and

as a raw material in the production of fire resistant and fire retardant materials.

(v) Imports vs. Indigenous production

Proposed products manufacturing in the country will be very much economical compare to Imports of the

same and also the export of the same will earn extra revenue generation for our county.

(vi) Export Possibility / Domestic / export Markets

There is a huge demand of the proposed products in the export market. Our products are widely used

and are in demand in the domestic Chemical industry.

(vii) Employment Generation (Direct and Indirect) due to the project

There will be very good opportunity of employment generation directly and indirectly due to proposed

expansion project. The company will provide employment to 62 people in different categories for

operation and maintenance of the proposed project. The details of the direct employment structure are

presented below in tabular form.

Sr. No. Particular No. of Employment

1 Managerial 04

2 Skilled 10

3 Semi-Skilled 13

4 Unskilled 35

TOTAL 62



3. PROJECT DESCRIPTION

(I) Type of Project including interlinked and interdependent projects, If any :

The proposed project is not interlinked and interdependent project of the company.

(II) Location (map showing general location, Specific location, and project boundary & project site layout) with

coordinates:

The map showing general location, specific location and project boundary and project site layout of M/s.

Sandhya Organic Chemicals Pvt. Ltd. located at Plot No. 1249 & 1250, GIDC, Sarigam – 396155 Tal.

Umbergaon, Dist. Valsad. Gujarat (INDIA). The coordinates of the project site is latitude 20.304967°N and

longitude 72.852815°E.

Fig. 3.1: Location map showing the Project site and inter-state boundary with 10 kms radius



(III) Profile of Project Site

Sr. No. Nearest Infrastructure Feature Distance from Project Site

1 Geographical Position Lat.: 20.304967°N Long.: 72.852815°E.

2 Elevation above Sea Level 36 Meters (Approx.)

3 Nearest Village Sarigam : 2.0 km SE

4 Nearest Town Sarigam residential town – 2.43 km SE

5 Nearest National Highway NH:8:5.5km E

6 Nearest State Highway SH: 0.45 km SW

8 Nearer RW Station Bhilad – 4.3 Km NE

9 Nearest Airport Public : Surat 85 Km NW

Non – Public: Daman – 12 km NW

10 Nearest Surface water

Resource/Reservoir

Darotha River 3.50 km E

Damanganga River 6 Km NNE

GIDC Water Supply Dam 25 km SE

Arabian Sea 11.75 km W

11 Nearest Forest Patches 1.67 KmN

12 Location of Archaeologically

/Historically important places N. A.

13 National Park/Sanctuary or Ecologically

sensitive Area D & NH Wild Life Sactuary Apptox. 14 km E

14 National or State Boundary Dadra & Nagar Haveli – 8.43 Km E

Daman – 7.71km N

15 Tourist Places Dadra & Nagar Haveli – 14.00 Km E

Daman – 13.47 km N



Project site Area Statement:

Area Statement Area

(in m2)

Total Area 8640.00

Construction Area 5014.00

Open Land Area 1826.00

Greenbelt Area 1800.00

(IV) Site layout Plan:



Location of Project Site in GIDC Sarigam:

(V) Details of alternate sites considered and the basis of selecting the proposed site, particularly the

environmental considerations gone into should be highlighted:

The plot of the proposed project is located within the GIDC Notified Industrial area of Sarigam having proper

industrial infrastructure hence alternate site consideration is not envisaged.

(VI) Size or magnitude of operation:

As per the proposed project cost the project is covered under Small Scale category of manufacturing

industries, it comes under MSI.



(VII) Project description with process details (a schematic diagram/ flow chart showing the project layout

components of the project etc. should be given):

Detailed project description with process details –

LIST OF FINISHED PRODUCTS

Sr. No.

Product Name Quantity (MT/Month)

6. Trimethyl Phosphite (TMP)and Triethyl Phosphite (TEP) 300.00

7. TMP derivatives ([Tri Decyl Phosphite (TDP), Tris Tridecyl Phosphite (TTDP), Tri Lauryl Phosphite (TLP), Tri-Iso Octyl Phosphite (TIOP) etc]

200.00

8. Dichlorvos - Technical 100.00

9. DiChlorvos Formulation 100.00

10. Plastic and Paint Additives (Organic Phosphite) (Tri Phenyl Phosphite, Diphenyl Isodecyl phoshite, 2-Hexyl Diphenylphosphite, Phenyl Di-IsodecylPhosphite, Tri –Decyl Phosphite, Tri Trisdecyl Phosphite, TrisNonyl Phenyl Phosphite, DiphenuulTridecylPhosphite (DPTDP), Tetra Phenyl Dipropylene Glycol Phosphite (THOP),Poly (Dipropylene Glycol) Phenyl Phosphite (DHOP),4-4-Isoproplidene bis (disodecyl Phenyl Phosphite), DistearylpentaerythritolDiphosphite (DPEDP), TRIS (2,4 ditertbutylphenyl) Phosphite, TRIS (2,4 ditertamylphenylphosphite etc.)

300.00

6 Organic Phosphates Tri aryl and Alkyl Phosphate Triphenyl Phosphate, Tricrisyl Phosphate, Tributyl Phosphate, Cresyl Diphenyl Phosphate, etc.)

150.00

7 Ammonium Chloride Solution or Crystal (Co-product) 2176.50

8 Methanol(Co-product) 30.54

9 HCL(Co-product) 414.90

10 Phenol (Co-product) 46.00

Total Product 3817.94

INFRASTRUCTURE, MACHINERIES, EQUIPMENT & TECHNOLOGIES

Civil construction work, Installation of the plants and machineries and latest technology will be required to

manufacturing the products.

To get the best results in terms of quality and quantity, the company will invests in the latest available plant

and machinery and leverages state-of-the-art technologies to get excellent results.



MANUFACTURING PROCESS

The company shall use the latest available process technology for the production. This section includes the

manufacturing process of the product, chemical reactions, and mass balance of each proposed products.

1 Product: Trimethyl Phosphite & Triethyl Phosphite (@300 MT/Month)

A Trimethyl Phosphite (TMP)

Manufacturing Process:

Tri Methyl Phosphite [TMP ] is obtained by the Reaction of PCl3 (Phosphorous Trichloride) and Anhydrous

Methanol in the presence of a Solvent having a Catalyst. Since HCl is produced in the Reaction, in order to

neutralize it, Ammonia Gas in sparged into the Reactor simultaneously to fix the HCl as soon as it is formed.

This produces a by-product Ammonium Chloride, which is separated from the Reaction Stream and sold to

actual users.

The Reaction is carried out in a continuous manner and the Raw Materials, PCl3, Methanol, Solvent and

Ammonia are admitted to a Stirred Reactor, where the Reaction takes place instantaneously. The reaction

is highly exothermic and the Temperature of the reaction is controlled by circulation of Chilled Water to the

Jacket and Coil of the Reactor.

The Reaction Mixture containing Solvent, Tri Methyl Phosphite and Ammonium Chloride overflows from

the Reactor continuously to a continuous contacting Extractor, where the Reaction Mixture is contacted

with Water continuously to dissolve the Ammonium Chloride in Water and separate the Solvent containing

TMP [Organic layer ] from the Ammonium Chloride Layer and collected in separate tanks and processed

further as follows.

The Organic Layer- Solvent +TMP is first feed to a Dehydration Column, where the Reaction Mixture

containing traces of Water and Methanol are removed under Vacuum and recycled back to the Extractor.

This is obtained as the overhead product from the column. The bottoms from the Column, containing the

Solvent and product (TMP) are feed to the next Column where TMP is distilled under Vacuum and obtained

as a top product, with high purity.

Bottoms from this column, which is essentially the Solvent, but at a high Temperature, is cooled

continuously and recycled and feed to the Reactor along with the Fresh Methanol , PCl3 (Phosphorous

Trichloride) and Ammonia Gas .

Ammonium Chloride obtained as a Solution from the Extractor, is concentrated in an Evaporation System

M.E.E. (Multi Effect Evaporation System), Crystallized, Centrifuged or belt filter, dried and bagged for sale

to actual users.

Water obtained from the Evaporator system is treated and recycled to the Process to the Extractor again

for dissolution of the Ammonium Chloride obtained in the Reaction.

Tri Methyl Phosphite is a Liquid with a high Boiling Point and is stored in Storage Tanks and sold in Tankers

and Drums as required by the user.



Process Flow Chart:



Chemical Reaction:

3 (CH3OH) + PCL3 + 3NH3 C3H9O3P + 3 (NH 4Cl)

0.774 1.108 0.411 1 1.293

Methanol Phosphorus

Trichloride Ammonia Trimethyl Phosphite

Ammonium

Chloride

3 (NH 4Cl) + H2O NH 4Cl Solution

1.293 6.315 7.608

Ammonium Chloride Water Ammonium Chloride Solution (17%)

B Triethyl Phosphite (TEP)


Tri Ethyl Phosphite is obtained by the Reaction of PCl3 (Phosphorous Trichloride) and Anhydrous Ethyl

Alcohol in the presence of a Solvent having a Catalyst. Since HCl is produced in the Reaction, in order to

neutralize it, Ammonia Gas in sparged into the Reactor simultaneously to fix the HCl as soon as it is formed.

This produces a by-product Ammonium Chloride which is separated from the Reaction Stream and sold to

actual users.

The Reaction is carried out in a continuous manner and the Raw Materials, PCl3, Ethyl Alcohol, Solvent and

Ammonia are admitted to a Stirred Reactor, where the Reaction takes place instantaneously. The reaction

is highly exothermic and the Temperature of the reaction is controlled by circulation of Chilled Water to the

Jacket and Coil of the Reactor.

The Reaction Mixture containing Solvent, Tri Ethyl Phosphite and Ammonium Chloride overflows from the

Reactor continuously to a continuous contacting Extractor, where the Reaction Mixture is contacted with

Water continuously to dissolve the Ammonium Chloride in Water and separate the Solvent containing TEP

from the Ammonium Chloride Layer and collected in separate tanks and processed further as follows.

The Organic Layer- Solvent and TEP is first feed to a Dehydration Column, where the Reaction Mixture

containing traces of Water and Ethyl Alcohol are removed under Vacuum and recycled back to the

Extractor after collection. This is obtained as the overhead product from the column. The bottoms from the

Column containing the Solvent and product (TEP) are fed to the next Column where TEP is distilled under

Vacuum and obtained as a top product, with high purity.

Bottoms from this column, which is essentially the Solvent, but at a high Temperature, is cooled

continuously and recycled and feed to the Reactor along with the Fresh Ethyl Alcohol ,PCl3 (Phosphorous

Trichloride) and ammonia.

Ammonium Chloride obtained as a Solution from the Extractor, is concentrated in an Evaporation System

M.E.E. (Multi Effect Evaporator), Crystallized, Centrifuged or belt filtered, drying and bagged for sale to

actual users.

Water obtained from the Evaporator system is treated and recycled to the Process to the Extractor again

for dissolution of the Ammonium Chloride obtained in the Reaction.

Tri Ethyl Phosphite is a Liquid with a high Boiling Point and is stored in Storage Tanks and sold in Tankers

and Drums as required by the user.



The Two Products are Produced on a campaign basis and manufactured as per the Market demand.

Process Flow Chart:



Chemical Reaction:

3 (C2H5OH) + PCL3 + 3NH3 C6H15O3P + 3 (NH 4Cl)

0.8316 0.8275 0.307 1 0.9661

Ethanol Phosphorus

Trichloride Ammonia Triethyl Phosphite Ammonium Chloride

3 (NH 4Cl) + H2O NH 4Cl Solution

0.9661 5.935 6.9011

Ammonium Chloride Water Ammonium Chloride Solution (14%)

2 A. Product: Tri decyl Phosphite (TDP)


Tri Methyl Phosphite (TMP) is reacted with isodecyl alcohol ( IDA) at elevated temperature. After the

reaction, Methanol will be distilled out. TDP will be packed as per customer requirement. Recovered

Methanol will be reuse as a Raw material into our Product.

Process Flow Chart:

TMP

IDA

Methanol (Reused)

Chemical Reaction:

C3H9O3P + 3R1 – OH (R1 – O)3P +3CH3OH (Where R1 is C10H21)

0.246 + 0.945 1 + 0.191

Molecular Formula – (C10H21O)3P

Molecular weight - 502.79 gms / mole

Reaction

Packing

Distillation



2 B. Product: Tris Tridecyl Phosphite (TTDP)


Tri Methyl Phosphite (TMP) is reacted with Tri Decyl Alcohol (TDA) at elevated temperature. After the

reaction, Methanol will be distilled out. TTDP will be packed as per customer requirement. Recovered

Methanol will be reuse as a Raw material into our Product.

Process Flow Chart:

TMP

TDA

Methanol (Reused)

Chemical Reaction:

C3H9O3P + 3R1 – CH2 -OH (R1CH2 – O)3P +3CH3OH

(Where R1 is CH3 (CH2)11

0.1972 + 0.9555 1 + 0.1527

Molecular Formula – C39H81O3P

Molecular weight - 629.03 gms/mole

Reaction

Packing

Distillation



2 C. Product: Tri Lauryl Phosphite (TLP)


Tri Methyl Phosphite (TMP) is reacted with Lauryl Alcohol (LA) at elevated temperature. After the reaction,

Methanol will be distilled out. TLP will be packed as per customer requirement. Recovered Methanol will be

reuse as a Raw material into our Product.

Process Flow Chart:

TMP

LA

Methanol (Reused)

Chemical Reaction:

C3H9O3P + 3(C12H26 O) (C36H75O)3P +3CH3OH

0.2113 + 0.9523 1 + 0.1636



Reaction

Packing

Distillation



2 D. Product: Tri Iso Octyl Phosphite (TIOP)


Tri Methyl Phosphite (TMP) is reacted with 2- Octanol at elevated temperature. After the reaction,

Methanol will be distilled out. TIOP will be packed as per customer requirement. Recovered Methanol will

be reuse as a Raw material into our Product.

Process Flow Chart:

TMP

2-Octanol

Methanol (Reused)

Chemical Reaction:

C3H9O3P + 3(C8H18 O) C24H51O3P +3CH3OH

0.296 + 0.9333 1 + 0.2293



Reaction

Packing

Distillation



3 Product: Dichlorvos- Technical (@100 MT/Month)


Take Chloro acetaldehyde (Chloral)in reactor. Add Tri methyl phospite (TMP)slowly to controlled temp.

after reaction over pack DDVP in suitable container as per costumer requirement. During reaction methyl

chloride as by - product. This by-product will be incineration.

Process Flow Chart:

TMP 561

CHLORAL 667

Chemical Reaction:

CCl3CHO + (CH3O)3 P O II (CH3O)2POCH=CCl3

+ CH3Cl

0.667 0.561 1 0.228

Choral TMP DDVP Methyl Chloride

(Reactor)

DDVP

Reaction

METHYL

CHLORIDE 228

To

Incinerator

Packing

DDVP

1000



4 Product: Dichlorvos Formulation (@100 MT/Month)


Take Solvent C-9 & Dichlorvos in to reactor. Stir for 2 hrs. Charge Emulsifier. Again Stir for 1 hour. After

that Pack the material as per the customer requirement

Process Flow Chart:

Dichlorvos

C-9 Solvant

Emulsifier

Chemical Reaction:

No Chemical Reaction is involved. The product is prepared by mixing of raw materials.

(Reactor)

DDVP Formulation

Reaction

Packing

DDVP

76%



5. PRODUCT: PLASTIC AND PAINT ADDITIVES (ORGANIC PHOSPHITES)(300 MT/M)

A. TRI PHENYL PHOSPHITE:

Production Process:

Phenol and PCI3are reacted at elevated Temperature. During the course of reaction HCl gas is generated,

which is scrubbed in water and dispatched as HCl solution. Unreacted mass is recovered by distillation at

elevated temperature and under reduced pressure. After complete removal of phenol from the reaction

mass finally pure TriphenylPhosphite is collected and packed in suitable containers as per customer’s

requirements and used for captive purpose to manufacture other products.

Chemical Reaction:

3C6H5OH +PCl3 → (C6H5O)3P + 3HClgas (Reactor)

HClgas +H2O → HClSoln. (Scrubbing)

Process Flow Diagram:

B. ORGANIC PHOSPHITES: (Diphenyl Isodecylphoshite/ Diphenyl 2-ehtyl hexyl phosphate/ Phenyl Di-IsodecylPhosphite/ Tri –DecylPhosphite/ Tri TrisdecylPhosphite/Diphenyl TridecylPhosphite (DPTDP)/Tetra Phenyl Dipropylene Glycol Phosphite (THOP)/ Poly (Dipropylene Glycol) Phenyl Phosphite (DHOP)/Isopropylidenebis (diisodecyl Phenyl Phosphite)/DistearylpentaerythritolDiphosphite (DPEDP)/ TRIS ( 2,4 ditertbutylphenyl) Phosphite/ TRIS ( 2,4 ditertamylphenyl phosphate, etc.))

Production Process:

TPP (Tri Phenyl Phosphite) and Alcohol (IsoDecanol, 2-Ethyl Hexanol, IsoDecanol, TrisDecyl Alcohol ect.) are

reacted at elevated temperature. During the course of reaction (n) mole phenol is generated. Phenol is

distilled out and OrganicPhosphite is collected and packed in suitable containers as per customer’s

requirement.

REACTOR

DISTILLATION

PRODUCT: Tri Phenyl Phosphite Packaging & Dispatch

RAW MATERIALS Phenol PCl3

SCRUBBER HCl Recovery

Phenol Recovery



Chemical Reaction:

(C6H5O)3P + (R1)-OH → (C6H5O)2-P-O-(R1) + C6H5OH

Where, R1 can be Isodecanol OR 2-Ethyl Hexanol OR TrisDecyl Alcohol etc.

Process Flow Diagram

C. TRISNONYL PHENYL PHOSPHITE:

Production Process:

PCl3and Nonyl Phenol are reacted at elevated temperature. During the course of reaction 3 mole HCl is

generated as gas. Gaseous HCl is scrubbed in water scrubber attached to the reactor and TrisNonyl Phenyl

Phosphite is collected after complete removal of HCl from reactor. The product TrisNonyl Phenyl Phosphite

is then packed in suitable containers as per customer’s requirement.

Chemical Reaction:

3C9H19-C6H4OH + PCl3 → (C9H19-O-C6H4)3P + 3HClgas (Reactor)

HClgas + H2O → HClSoln (Scrubber)

Process Flow Diagram:

REACTOR SCRUBBER HCl Recovery

PRODUCT: Tri NonylPhenylPhosphite

Packaging & Dispatch

RAW MATERIALS Nonyl Phenol PCl3

REACTOR

DISTILLATION

PRODUCT: Organic Phosphite


RAW MATERIALS Tri Phenyl Phosphite Alcohol

Phenol Recovery Reuse in TPP



6. ORGANIC PHOSPHATES(Triphenyl Phosphate OR Tricresyl Phosphate OR Tributyl Phosphate OR Cresyl

Diphenyl Phosphate etc.) (150 MT/M)

Production Process:

3 mole alcohol (Phenol OR Cresol OR Butanol OR Isoproponol etc.) reacted with 1 mole of POCl3 at

elevated temperature in presence of catalyst during the course of reaction HCl is generated which

is trapped in water and will be dispatched as HCl solution. 5 % excess alcohol (Phenol OR cresol

etc.) used is distilled out under reduced pressure after the reaction.

Finished product distilled at elevated temperature and at reduced pressure and collected in to the receiver.

From receiver the material is flaked, collected and packed in bags.

Chemical Reaction:

3R1-OH + POCl3 → (R1-O)3OP + 3HClgas (Reactor)

HClgas + H2O → HClSoln (Scrubber)

Where, R1 can be Phenol OR Cresol OR Butanol OR Isopropanol etc.

Process Flow Diagram

REACTOR

SCRUBBER HCl Recovery

PRODUCT: Organic Phosphate


RAW MATERIALS Alcohol POCl3

DISTILLATION

FLAKING

AlcoholRecovery and Reused



(viii) Raw material required along with estimated quantity, likely source, marketing area of final

products/s, mode of transport of raw Material and finished product :

Detailed raw material requirement along with estimated quantity, likely source, marketing are of final

products mode of transport of raw material and finish product.

Raw material requirements: Product-wise list of Raw-materials

Sr. No.

Product Name Raw Materials Raw Material Consumption

Kg/MT MT/Month

1 Trimethyl Phosphite(TMP) / Triethyl Phosphite (TEP)

Phosphorus Trichloride 1108.000 332.400

Ammonia 411.000 123.300

Methanol / Ethanol 831.600 249.480

Catalyst [like Heavy Normal Parafine(HNP) and Diethyl Anilene(DEA)]

740.000 222.000

2 TMP derivatives

([Tri Decyl Phosphite (TDP), Tris Tridecyl Phosphite (TTDP), Tri Lauryl Phosphite (TLP), Tri-Iso Octyl Phosphite (TIOP) etc]

TMP 197.20 39.94

Alcohol (isodecyl alcohol) Tri Decyl Alcohol (TDA), Lauryl Alcohol (LA), 2-Octanol 955.50 191.10

3 Dichlorvos - Technical Chloral 667.00 66.70

Tri methyl phospite (TMP) 561.00 56.10

4

DiChlorvos Formulation Dichlorvos (DDVP) 760.00 76.00

Solvant C-9 230.00 23.00

Emulsifier 10.00 1.00

5 Plastic and Paint Additives

D. Tri Phenyl Phosphite Phenol 951.00 124.00

PCl3 450.00 58.00

E. Organic Phosphites

Tri Phenyl Phosphite 829.00 99.50

Alcohol (IsoDecyl alcohol, 2-Ethyl Hexanol, TriDecyl Alcohol, Di propylene Glycol, Bisphenol , Stearyl alcohol , Pentaerythritol etc.)

423.00 51.00

F. TrisNonyl Phenyl Phosphite, Tris ( 2,4 ditertbutylphenyl) Phosphite , Tris ( 2,4 ditertamylphenyl ) phosphite

Nonyl Phenol, 2,4 di-tert-butyl phenol, 2,4 di-tert-amyl phenol

959.00 48.00

PCl3 200.00 10.00


Alcohols (Phenol or Cresolor Butanol, etc.)

995.00 148.25

POCl3 470.00 70.50

Marketing area of final products:

“Trimethyl Phosphite (TMP) and Triethyl Phosphite (TEP)” have very high demand as the key intermediate in the manufacture of several organophosphatic pesticides like Monocrotophos, DDVP, Phosphomidon etc , as a reagent in organic synthesis, as plasticizer for nylon and as a raw material in the production of fire



resistant and fire retardant materials. The company has a wider customer base and to cater to the increased market demand.

Transport of Raw material and Finish products:

Sr. No.

Name of Chemical Physical

state Max. Storage Quantity (MT)

Mode of storage

Source of Supply

Mode of Transport

1. Tri methyl Phosphite Liquid 30.00 Tank Indigenous By road

2. Tri ethyl phosphite Liquid 15.0 Tank Indigenous By road

3. Ammonia Liquid 15.00 Tank Indigenous By road

4. Methanol Liquid 20.00 + 20.00 Tank Indigenous By road

5. Ethanol Liquid 20.00 Tank Indigenous By road

6. Catalysts Liquid 10.00 Tank Indigenous By road

7. Choral Liquid 10.00 HDPE drums Indigenous By road

8. Dichlovos Liquid 10.0 HDPE drums Indigenous By road

9. Solvent C-9 Liquid 10.0 Tank Indigenous By road

10. Emulsifier Liquid 0.4 HDPE drums Indigenous By road

11. Phenol Liquid 70.00 Tank Indigenous By road

12. PCl3 Liquid 16.00 Tank Indigenous By road

13. POCl3 Liquid 16.00 Tank Indigenous By road

14. 2-Ethyl Hexanol Liquid 20.00 Drum/Tank Indigenous By road

15. Butanol Liquid 5.00 Drum/Barrel Indigenous By road

16. Cresol Liquid 16.00 Drum/Tank Indigenous By road

17. Tri Phenyl Phosphite Liquid 30.00 Tank Indigenous By road

18. Stearyl alcohol Solid 5.00 HDPE Bag Indigenous By road

19. Di propylene Glycol Liquid 5.00 Drum/Barrel Indigenous By road

20. Bisphenol Solid 5.00 HDPE Bag Indigenous By road

21. Nonyl Phenol Liquid 20.00 Tank Indigenous By road

22. Pentaerythritol Solid 5.00 HDPE Bag Indigenous By road

23. 2,4 di-tert-butyl phenol

Solid 5.00 Drum Indigenous By road

24. 2,4 di-tert-amyl phenol

Liquid 5.00 Drum/Barrel Indigenous By road

25. Isodecyl alcohol Liquid 20.00 Drum/ tank Indigenous By road

(ix) Resource optimization/ recycling and reuse envisaged in the project , if any , should briefly outlined :

By adoption continuous improvement in technology and process the reduction in process waste

generation will be achieved.

Efficient handling of raw materials the wastages of raw materials will be reduced.

The raw materials will be stored in closed containers and will be handled through closed system to

avoid the handling losses.



(x) Availability of water its source, Energy/power requirement and source:

Fresh Water Requirement

Sr. No. Particulars Quantity (KL/Day)

1. Domestic 5.00

Sub Total Domestic 5.00

2. Industrial

Processing 10.00

Boiler 4.00

Cooling 60.00

Washing 10.0

Scrubber 11.00

Sub Total Industrial 95.00

3. Other (Gardening) 7.00

Total 107.00

Source: Water will be meet from GIDC Water supply , Sarigam

Energy Requirements and its source:

Sr.

No. Particulars Proposed Source

1 Steam 2000 & 1000

Kg/Hr

Will be obtained by installation of Two nos.

Boiler having steam generation capacity of

2000 kg./Hr & 1000 Kg/ Hr.

2 Heat 6 Lac KCal/Hr.

Will be obtained by installation of one nos.

Thermic fluid heater having heat generation

capacity of 6 Lacs Kcal/Hr each.

Power & Fuel Requirements and its source:

Sr. No. Particulars Proposed Source

1 Power –Electricity requirement 500 KVA Dakshin Gujarat Vij Co. Ltd.

2 D.G. Set (1 No.) Capacity: 320 KVA From Local supplier. (as a

Stand by source)

3 HSD (for D.G. Set) 60 L/Hr. From local supplier

4 Bagasse Brickets (for Boiler & TFH) 3 MT/day From local supplier



(xi) Quantity of waste to be generated (liquid and solid) and scheme for their Management/disposal:

Quantity of Waste Water (liquid waste) generation and its management :

Sr. No. Particulars Quantity (KL/Day)

1. Domestic 4.00

Sub Total Domestic 4.00

2. Industrial

I. Processing 9.00

II. Boiler 2.00

III. Cooling 9.00

IV. Washing 10.00

V. Scrubber 0.00

Sub Total Industrial 30.00

3. Total 34.00

The generated domestic waste water will be disposed off through adequate soak pit.

The generated industrial waste water will be treated in adequate effluent treatment plant (ETP). The treated

effluent meeting the discharge norms is discharged through GIDC underground drainage system to CETP. The

details of the same is as given below :

Scrubber Water will be consumed in the by-product HCl.



EFFLUENT TREATMENT SCHEME Design Criteria: Product : Pesticide intermediates & Synthetic Organic Chemicals Source of Effluent : Boiler, Cooling & Washing

Design Flow of Effluent : 35 KL/day Max. Design Parameters : As under

Effluent Characteristics:

Sr. No. Parameter Unit Untreated Treated

1. pH -- 7.0 to 10.0 5.5to8.5

2. Colour Pt-CoScale 200 <100

3. Suspended Solids mg/lit 550(max) <100

4. BiochemicalOxygenDemand mg/lit 1800(max) <300

5. ChemicalOxygenDemand mg/lit 4000(max) <1000

6. Oil&Grease mg/lit 25(max) <10

7. TotalDissolvedSolids mg/lit 3200(max) <2100

EFFLUENT TREATMENT SCHEME

1. PRIMARY TREATMENT:

UNITS: Oil & Grease removal Tank

Collection cum Neutralization Tank

Primary settling and sludge removal

The effluent coming from the plant is initially passed through the Oil & Grease removal system. The oil free

effluent is then collected into the collection cum reaction tank. In the collection cum reaction tank various

chemicals like None Ferric Alum, Caustic soda/acid and polyelectrolyte (coagulant) are added to ensure

proper settling which reduces the suspended solid concentration, color and COD in the effluent. The treated

effluent is then fed into the primary clarifier. Clear effluent from primary settling tank is charged into the

secondary treatment tank (Aeration tank) and settled sludge is discharged into the sludge drying beds and

leached of the sludge drying beds is going back to collection tank.

2. SECONDARY TREATMENT (BIOLOGICAL TREATMENT):

UNITS: Aeration Tank

Secondary settling

The primary treated clear effluent is passed through the aeration tank where the biodegradation of the

organic matter is taken place in presence of active microorganism and required Dissolved Oxygen level.

During the biological treatment BOD Value and COD Value are reduced. After the biological treatment

(aeration tank) the effluent with the biomass is passed through secondary settling tank where biomass is

settled and settled biomass is recycle back to aeration tank or if excess is discharged into the sludge drying

beds. And clear effluent is collected into the holding tank.



3. TERTIARY TREATMENT:

UNIT: Sand and Carbon Filter (Mixed bed)

After secondary treatment the effluent is passed through the mixed bed filter for further reduction of COD

Value, BOD Value and Color. Treated water is collected into the treated water tank above the roof. Finally the

treated effluent confirming the treated water discharge norms laid down by board will be discharged for

plantation or into the closed drainage line.

4. In Dichlorvos, Production, Methyl Chloride produced as a by-product. This by-product will be evaporated

through inclinator.



5. WATER BALANCE DIAGRAM

Utility Emission & Control Measures (Proposed):

Sr.

No. Particulars

Fuel / Power & its

Qty

Probable Pollutants &

Limits

Air Pollution Control

Measures

1.

Steam Boiler – 2 No.

Capacity : 2000 kgs/Hr &

1000 kgs/ Hr

Bagasse briquettes -

2.00 MT/Day

PM <150 mg/Nm3

SO2 < 100 ppm

NOx< 50 ppm Bag filter with

Common Chimney

(Chimney ht: 15 m)

Diameter: 200 mm 2.

Thermic Fluid Heater- 1

Capacity:6000 kcal/hr

Bagasse briquettes -

1.00 MT/Day

PM <150 mg/Nm3

SO2 < 100 ppm

NOx< 50 ppm

3.

D.G. Set – 1 Nos

Capacity: 320 KVA with

Acoustic enclosure

HSD: 50 Lts/Hr.

PM <150 mg/Nm3

SO2 < 100 ppm

NOx< 50 ppm

Chimney ht: 15 m

Diameter: 200 mm

Process stack emission :

Stack attached

to

Details Air Pollution Control

Device

Parameter Permissible Limit

Reaction Vessel Chimney ht: 11 mtr.

Diameter: 150 mm

Water Scrubbing System

Ammonia 175 mg/m3

Total water requirement: 133.00 KL/day (107.00 (fresh) +26 .00(recycled)) from

Steam Condensate

5.00 KL/Day 4.00KL/Day 60.00 KL/Day 10.00 KL/Day 11.00 KL/Day 7.00 KL/Day

Effluent Treatment Plant (35 KL/day) Discharged through GIDC

Underground drainage to

Arebian Sea.

Septic Tank /

Soak Pit

Waste Water (effluent) 30.0 KL/day

Recover as by product

& reuse in process

Gardening Scrubbing Washing Boiler Domestic Cooling

2.00 KL/Day 9.00 KL/Day

10.00 KL/Day

4.00 KL/Day

2.00 KL/Day Evp.loss

51.00 KL/Day Evp.loss

Process

9.00 KL/Day

10.00 KL/Day

Process ejector

Condensate



Quantity of Solid Waste generation and its management :

Types of Waste Quantity/annum Storage Method Method of Disposal

ETP Waste

(Schedule-1, 35.3) 10.00 MT

Will be stored at a separate

storage area Will be sent to TSDF, Vapi

Process residue

(Schedule-1, 20.3) 50.00 MT

Will be stored at a separate

storage area in a closed container

Will be sent to co

incineration or common

incinerations.

Discarded containers

(Schedule-I, 33.1) 400 Nos.

Stored at a specified storage area

as per rule.

After decontamination will

be sold to re-conditioners

HDPE bags

(Schedule-I, 33.1) 3000 Nos.

Stored at a specified storage area

as per rule.

After decontamination will

be sold to re-conditioners

Used oil

(Schedule-1, 5.1) 100 Lit Stored into the closed container.

Disposal by selling to

registered refiners

Details of Hazardous Raw Materials Identification as per MSIHC Rules (2000):

The company has provided proper facilities within the premises to store the above raw material as per rule.

Name Chemical Classification MSIHC Applicability

Phosphorus trichloride Toxic, Flammable, Corrosive (Class 6.1) Sh-I, Part-II,506

Ammonia Toxic , Flammable Sh-I, Part-II, 31

Methanol Flammable, Toxic Sh-I,Part-II,277

Ethanol Flammable Sh-I,Part-II,248

Butanol flammable Sh-I,Part-I

Solvent C-9 Flammable -

Chloral Toxic -

Phenol Toxic (Class 6.1) Sh-I,Part-II,481

POCl3 Toxic, Flammable, Corrosive (Class 8) Sh-I,Part-II,504

2-Ethyl Hexanol Flammble,Irritant(Class 3)) Sh-I,Part-II,254

Cresol Flammble Sh-I,Part-I

High Speed Diesel Flamable Sh-I, Part-I



(XII) Schematic representations of the feasibility drawing which give information of EIA purpose:

A schematic representation of the feasibility drawing

Resource requirements • Raw Material: Sourced from Manufacturer / Traders of the same. • Land: Plot within GIDC, Sarigam. • Water: will be sourced GIDC Water Supply. • Power: power will be sourced through Dakshin Gujarat Vij Co. Ltd • Fuel : Local dealer.

Environment Management Plan (EMP)

Air Pollution Control Measures: Air Pollution control system will be provided

Water Pollution : ETP

Greenbelt Area: ~25% of the Total Area will be developed.

Health & Safety measures will be followed properly

Soak pit/ Septic Tank

Industrial waste water in the form of washing, boiler & cooling tower blow down will be treated in the propose ETP and treated effluent is recycled back to process/ gardening

Flue Gas emissions: Adequate chimney height will be provided.

Type of Industry: Proposed Mfg. unit of “TMP & TEP, Dichlorvos, Paints & Plastic

Additive Phosphites and Organic Phosphates”

Project Site Location: The company located at Plot No. 1249 & 1250,

GIDC, Sarigam, Tal. Umargam, Dist. Valsad,, (Gujarat)

Public consultation: Not applicable as the project site is located in

notified Industrial Area of GIDC Sarigam

Submission of TOR Application: Form-1 and Project Pre-Feasibility Report & Draft TOR

Proposed Activity: The proposed project involves the production of “TMP & TEP, Dichlorvos, Paints & Plastic Additive

Phosphites and Organic Phosphates”

Type of category as per EIA notification: “Pesticides industry and pesticide specific intermediates (excluding formulations)”

Activity -5(b), Category- A

Presentation before the EAC for obtaining TOR



4. SITE ANALYSES

4.0 Site Analysis

(i) Connectivity:

The project site is located in notified Industrial Estate of Sarigam which is very well connected to National

Highway no.8 and Western Railways. And the nearest air port (Mumbai) and port are 150 KM away from the

project site by road.

(ii) Land Form, Land use and Land ownership:

The land is in the form of industrial shed owned by Gujarat Industrial Development Corporation.

(iii) Topography (along with map):

Topography map showing the elevation of the study area below.



(iv) Existing land use pattern (agriculture, non-agriculture, forest , water bodied ( including area under CRZ)),

shortest distances from the periphery of the project to periphery of the forest, national park, wild life

sanctuary , eco sensitive areas, water bodies (distance from the HFL of the river), CRZ . In case of notified

industrial area, a copy of Gazette notification should be given:

The land is located in the notified industrial area and a copy of gazette notification. Copy of notification and

letter of Notified area from GIDC are enclosed as Annexure- II.

(v) Existing Infrastructure:

GIDC notified industrial area of Sarigam has the entire available infrastructure like water, electricity, roads,

rail, transportation, availability of raw material and drainage system.

(vi) Soil classification:

General soil classification of the area is as under:

The area, being of basaltic formation, falls under the broad soil group of red loams and black clay soils. The

transmission of water through similar parent material seems to have influenced the development of different

physiographic characteristics of the soils in the area.

The area in between the hills with sloping lands contains dark yellowish brown to very dark grayish brown

gravelly clay loam to clayey soils of shallow to moderate thickness. The dissected hill and steep slopes suffer

from severe erosion hazards. The steep hill slopes are almost devoid of soil.

(vii) Climate data from secondary sources:

Rainfall Data:

The project site location receives annual rainfall of> 1500mmin 35 to 50 rainy days.

Temperature Data:

The project site is located in the southern part of Gujarat. The project site temperature regime is medium to

high level temperature (30-35°C) during the summer seasonal months.

(viii) Social Infrastructure available:

Social Infrastructure in Valsad district is as under:

Education:

There are 990 primary and 161 secondary and higher secondary schools. List of Educational Institutes schools

in the district Educational Totals With over 1,250 seats, there are 6 ITIs offering several industrial training

Institutes programs which includes, fitting, armature & motor rewinding, Primary School 990 electrician,

information technology and electronic system maintenance Secondary School etc. One Government

polytechnic College is present in the district offering courses in civil, chemical, electrical, mechanical and

plastic engineering, ITI’s 6 with an intake capacity of 360 Polytechnic 1 College With 120 seats, there is one

Degree Engineering College present in Pharmacy College 2 Valsad offering engineering courses in mechanical

and chemical Engineering 1 branches Colleges Located in Vapi, G. M. Bilakhia Pharmacy College has an intake

Management 1 College capacity of 60 students per year. Other Colleges* 8 Rofel Institute of Management

studies in Valsad offers full time MBA. *Other Colleges: Arts, Commerce, Science, B.Ed and Law College

course and takes 120 students per annum Source: Department of Education, 2007 28



Health:

There are 43 primary healthcare centres, 10 community healthcare centres, 10 Government and 1 Municipal

hospital present in the district. Valsad has several private specialised hospitals to provide a comprehensive

range of tertiary and secondary care services backed by state-of- the- art technology and trained medicos§ A

multi-specialty 21st Century Hospital, (branch of Nadkarni Group of Hospitals) is present in Vapi, giving

services in general and laparoscopic surgery, trauma, orthopedic and urology etc. the hospital is one of the

few centers in India offering Uterine Thermochoice thermal Balloon Therapy for Days functioning Uterine

Bleeding (DUB) patients.§ Beside this, several private hospitals such as, Kasturba Hospital, Bhatia General

Hospital, and Adarsh Hospital are also present in Valsad 29.

Tourism:

Tourism Built in 1742, the Fire Temple at Udawada, which is also known Fire Temple as Mecca for the Parsi

community in India, makes the city a famous pilgrimage center throughout the world.Dharampur is

surrounded on three sides by the Sahyadri Mountains which grace the town with pleasant climate

throughout the year. The collection at the Lady Wilson Museum in Dharampur includes tribal art and art

crafts that highlights the local culture. Besides this, District Science Centre is also present in Valsad Proximity

of Valsad with Daman & Diu, has increased the graph of tourist flow in the district.



5. Planning Description

5.0 Planning Brief.

(i) Planning Concept (Type of industries, facilities, transportation etc) Town and Country Planning

/Development authority Classification:

There is a cluster of numerous large-scale, medium-scale and small-scale industries, engaged in

manufacture of variety of products, for example pharmaceuticals, dyes and chemicals, paper mills, paints,

plastics, packaging, textiles, speciality chemicals and others in the Gujarat Industrial Development

Corporation (GIDC) notified area of Sarigam.

(ii) Population Projection:

Not applicable

(iii) Land use planning (breakup along with green belt etc):

Area Statement

Area Statement Area

(in m2)

Total Area 8640.00

Construction Area 5014.00

Open Land Area 1826.00

Greenbelt Area 1800.00



6. Infrastructure Details

6.0 Proposed Infrastructure:

(i) Industrial Area (Processing Area).

The proposed infrastructure to manufacture products will be built with standard engineering design

considering all the relevant parameters related to environment, health and safety.

(ii) Residential Area (Non Processing Area):

No residential area is involved in the proposed expansion project.

(iii) Green Belt:

Green belt area will be provided and maintain at the tune of 21% of the total land area.

(iv) Social Infrastructure:

Not applicable

(v) Connectivity (Traffic and Transportation Road/ Rail/ Metro/ Water ways etc) :

The project site is very well connected by road through National Highway no. 8, western railways.

(vi) Drinking Water management (Source & Supply of water):

Source of water is from GIDC water supply services.

(vii) Sewerage System:

GIDC has provided sewage system to dispose the sewage effluent.

(viii) Industrial Waste Management:

Industrial liquid effluent regeneration during the manufacturing of proposed products will be treated and

discharge in to drainage provided by GIDC to CETP for final treatment and disposal.

Generated domestic liquid waste is being disposed off through soak pit system to drainage.

(ix) Solid Waste Management:

All the generated hazardous solid wastes during the proposed industrial activities will be managed as per

Hazardous Waste (MH&TM) Rules-2016 as amended.

(x) Power Requirement & Supply / Source:

Power requirement for proposed project will be taken from DGVCL and D.G. set will be installed to use in

case of power failure only.



7. Rehabilitation and Resettlement (R&R) Plan:

(i) Policy to be adopted (Central/ State) in respect of the project affected persons including home oustees,

land oustees and landless laborers (a brief outline to be given):

There will be no rehabilitation and resettlement undertaken as labors and workers from local & nearby areas

for the proposed construction activity as the project site is within the notified industrial area only.

8. Project Schedule & Cost Estimates:

(i) Likely date of start of construction and likely date of completion (Time schedule for the project to be

given):

After obtaining Environmental clearance and Consent to Establish from GPCB, the company shall start the

proposed construction and commissioning of the project.

(ii) Estimated project cost along with analysis in terms of economic viability of the project:

Estimated project cost along with the analysis in terms of economic viability of the project

Plant & Machinery, Pipeline & Fittings, Electrical Installation, Safety systems, etc. are the major heads

considered in the Capital Cost Projection for the proposed project. Environment Protection has also been

considered in planning the Cost Projection, which will include Green belt development, safety systems, etc.

Capital Cost Projection

Sr.

No. Purpose

Proposed

(Rs. In lakhs)

1. Land and Building 325.00

2. Plant & Machinery and other fittings 1165.00

3. Environmental protection measures 100.00

TOTAL : 1590.00

The proposed investment will be made by company only.

The company will provide budgetary provision for the recurring expenses for environmental issues while

planning the allocation of funds during the annual budgetary planning.

Recurring Cost per annum

Sr. No. Component Proposed

(Rs. in Lacs/annum)

1. Environment & Safety Management System 15.00

2. Greenbelt Maintenance 1.00

3. Solid waste Disposal 5.00

4. Enterprise Social Contribution 15.00

Total 36.00



9. Analysis of Proposal (Final Recommendations):

(i) Financial and social benefits with special emphasis on the befit to the local people including tribal

population, if any, in the area:

The Proposed project activity will provide benefits to the local people in terms of financial and social welfare.

Local people will get direct financial benefit by way of employment.

Local people will get some contracts of supply and services to get indirect income.

Company will contribute in improving education and health facilities in nearby area.

Documents

FOR THE PROPOSED NEW PROJECT FOR MANUFACTURING …environmentclearance.nic.in/writereaddata/Online/TOR/07_Jan_2017... · THE PROPOSED NEW PROJECT FOR MANUFACTURING OF Trimethyl Phosphite