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National Concrete Consortium April 2018– [email protected] © Slide 1 of 40
Jason Weiss, Edwards Distinguished Professor, Oregon State University
Focusing on Long-TermDurability and Performance
For Concrete Pavement
National Concrete Consortium April 2018– [email protected] © Slide 2 of 40
Concrete Pavements of the Future
• Many concrete pavements are long-lasting; however some come out of service early due to concerns of durability
• PEM/PBS/PRS – Emphasize Performance• Can we test materials early to determine
if they will be durable for decades• Can we re-envision mixture proportioning for durability• Working on a long-term road map to get us there… several
steps in the process but we are already on the way
National Concrete Consortium April 2018– [email protected] © Slide 3 of 40
Focus on Durability
TARGET: ImproveLong-Term Durability
• Freeze-Thaw• Salt Damage• Chloride Ingress• ASR
• Shrinkage & Cracking
Today we will discuss the Formation Factor (a.k.a. F Factor)
Very simple, Very powerful, Very practice ready
This is work done prior to the current pooled fund and led to a large portion of AASHTO PP-84 Weiss et al. 2015
National Concrete Consortium April 2018– [email protected] © Slide 4 of 40
Four Step ApproachToward Performance
Assess Performance w/ Standard
Tests
Tests should be:• Easy to
perform• Economical• Repeatable
Convert Test Results to
Fundamental Properties
Relate Properties w/
ExposureConditions
EstablishPerformanceGrade and Measure
Example:• Measure ρ• Account for
Pore Solution• Determine
F- Factor
Set Performance Limits and Use Tests to Measure to Insure That You Received What you Specified
Use Exposure, Material Factors (e.g., Binding), and Models to Estimate Service Life Af
ter B
arde
et a
l. 20
07
National Concrete Consortium April 2018– [email protected] © Slide 5 of 40
We need to Test Correctly• Working on several
videos that folks here may find of use
• They will be directly linked from the NCC web page to here
National Concrete Consortium April 2018– [email protected] © Slide 6 of 40
Typical Videos
National Concrete Consortium April 2018– [email protected] © Slide 7 of 40
Jason Weiss, Edwards Distinguished Professor, Oregon State University
Determining the Formation Factor Using the Bucket Test
National Concrete Consortium April 2018– [email protected] © Slide 8 of 40
Four Step ApproachToward Performance
Assess Performance w/ Standard
Tests
Tests should be:• Easy to
perform• Economical• Repeatable
Convert Test Results to
Fundamental Properties
Relate Properties w/
ExposureConditions
EstablishPerformanceGrade and Measure
Example:• Measure ρ• Account for
Pore Solution• Determine
F- Factor
Set Performance Limits and Use Tests to Measure to Insure That You Received What you Specified
Use Exposure, Material Factors (e.g., Binding), and Models to Estimate Service Life Af
ter B
arde
et a
l. 20
07
• Need a test that is simple to perform in the field
• Resistivity is a great field test; however there are factors of geometry, temperature, saturation, and pore solution (leaching, chemistry) that need to be ‘standardized’
• Need a test that ‘can be transformed ‘to a property
National Concrete Consortium April 2018– [email protected] © Slide 9 of 40
R2D2
National Concrete Consortium April 2018– [email protected] © Slide 10 of 40
R2S2
• 5 Gal Bucket• Reliable • Robust • Simple • Safe
National Concrete Consortium April 2018– [email protected] © Slide 11 of 40
Current State • There are ‘three geometries’ frequently used• With proper geometry conditioning, all are similar
• There are two AASHTO test standards; while good a large issue in repeatability is related to conditioning
• Temperature, Moisture, Leaching, Degree of Saturation
National Concrete Consortium April 2018– [email protected] © Slide 12 of 40
Recommended Tests
• Option 1 - “The Bucket Test”• Option 2 - Sealed Samples • Option 3 – Vacuum Saturation• Option 4 – Moist Curing Room
• We will start by describing how to perform the tests using simplified procedures
National Concrete Consortium April 2018– [email protected] © Slide 13 of 40
Option 1 “Bucket Test”
• Begin with a 5 gallon bucket
National Concrete Consortium April 2018– [email protected] © Slide 14 of 40
Option 1 “Bucket Test”
• Begin with a 5 gallon bucket • Place a specific volume of fluid into the bucket (the
solution to sample ratio is important, placea line on the bucket)
National Concrete Consortium April 2018– [email protected] © Slide 15 of 40
Option 1 “Bucket Test”
• Begin with a 5 gallon bucket • Place a specific volume of fluid into the bucket (the
solution to sample ratio is important, placea line on the bucket)
• Place a specified “CH-salt” into the solution(some adjust to the mixture, we suggestselecting a standard value)
National Concrete Consortium April 2018– [email protected] © Slide 16 of 40
Option 1 “Bucket Test”
• Begin with a 5 gallon bucket • Place a specific volume of fluid into the bucket (the
solution to sample ratio is important, placea line on the bucket)
• Place a specified “CH-salt” into the solution(some adjust to the mixture, we suggestselecting a standard value)
• Place samples into the solution to allowthe solution to reach the entire sample
National Concrete Consortium April 2018– [email protected] © Slide 17 of 40
Option 1 “Bucket Test”
• Mass change and resistivity are shown
• Similar to absorption (like in ASTM C1585); however the time scale varies due to:– 1-sided vs immersion– sample geometry
• Approx. 5 vs. 1 days0 500 1000 1500 2000 2500 3000
0
10
20
30
40
50
60
Mas
s cha
nge
(g)
Square root of time (s0.5)
w/c=0.50, M4
Nick Point
0
30
60
90
120
150
Elec
trica
l res
istiv
ity (Ω
⋅m)
National Concrete Consortium April 2018– [email protected] © Slide 18 of 40
Option 1 “Bucket Test”
• At select ages remove sample from the bucket, towel/ wash off the surface and perform either the surface resistivity test or the uniaxial bulk resistivity test
• After 5 days in solutionthe sample is assumed tobe in matrix saturation
• This can provide a measureof ρmeasured or Fmatrix
• Conditioning solution ρsolution is known
National Concrete Consortium April 2018– [email protected] © Slide 19 of 40
Option 2 - Sealed
• Maintain a sealed sample (this can be done in a sealed sample or by placing the sample in double bags)
• The advantages of this approach:– Provides continual measure– Provides an “easy” test condition
• The disadvantages of this approach:– Will require a moisture correction– Requires some sort of ability to make it
clear as to whether the sample has dried
National Concrete Consortium April 2018– [email protected] © Slide 20 of 40
Option 3 – Vacuum Sat.
• This is not being recommended QC/QA use:• The advantages of this approach are:
– This will match most closely to ASTM C1202• The disadvantages of this approach are:
– time consuming– difficult to do on 4x8 in samples– It does not correlate to a field condition
National Concrete Consortium April 2018– [email protected] © Slide 21 of 40
Option 4 – Moist Room
• This is not being recommended.
• The advantages of this approach are:
• The disadvantages of this approach are:– Leaching – Not being saturated– Not a ‘easily achieved’ robust state
National Concrete Consortium April 2018– [email protected] © Slide 22 of 40
Scientific Principles
Historically the RCPT has been based on a vacuum saturated sample but is this the right way
Pro’s• State that many people can
get to repeatedly
Con’s• Requires Vacuum• Is this a “state in practice”?
National Concrete Consortium April 2018– [email protected] © Slide 23 of 40
Saturated, S
Saturated Matrix, SM
Saturation: S vs SMatrix• This will seem very academic and not very
important however it is a crucial issue • This applies both to testing and application• Vacuum saturation
fills all voids: gel, capillary, and air
• “Bucket Test” or Absorption fill in matrix voids: gel andcapillary (i.e., not air) 0 2 4 6 8
5
10
15
20
Aggregate pores
Air voids
Chemical shrinkage
Capillary pores
Gel pores
Poro
sity
Air content (%)
(b) w/c=0.45 w/c=0.45 (575)
National Concrete Consortium April 2018– [email protected] © Slide 24 of 40
Porosity: Measured versus Theoretical• We have compared numerous mixtures (32 shown
here) but many more have been tested• Theory matches practice well
0 2 4 6 8
5
10
15
20
Aggregate pores
Air voids
Chemical shrinkage
Capillary pores
Poro
sity
Air content (%)
(a) w/c=0.40 w/c=0.40 (575)
Gel pores
0 2 4 6 8
5
10
15
20
Aggregate pores
Air voids
Chemical shrinkage
Capillary pores
Gel pores
Poro
sity
Air content (%)
(b) w/c=0.45 w/c=0.45 (575)
0 2 4 6 8
5
10
15
20Aggregate pores
Poro
sity
Air content (%)
(c) w/c=0.50 w/c=0.50 (575)
Gel pores
Capillary pores
Chemical shrinkage
Air voids
National Concrete Consortium April 2018– [email protected] © Slide 25 of 40
0 2 4 6 80
100
200
300
400
R2=0.93 R2=0.94
w/c=0.40 w/c=0.45 w/c=0.50
Form
atio
n fa
ctor
Air content (%)
R2=0.96
(a)
Saturated F Factor(Air is Varied – OK PFS)
0 2 4 6 80
100
200
300
400
R2=0.83
R2=0.79
w/c=0.40 (575) w/c=0.45 (575) w/c=0.50 (575)
Form
atio
n fa
ctor
Air content (%)
R2=0.94
(b)
Qiao et al. submitted
National Concrete Consortium April 2018– [email protected] © Slide 26 of 40
Resistivity (F Factor) For Matrix Saturation (Bucket)
0 2 4 6 80
20
40
60
80
100
w/c=0.40 w/c=0.45 w/c=0.50
Resis
tivity
at N
ick
Poin
t (Ω⋅m
)
Air content (%)
(a)
0 2 4 6 80
20
40
60
80
100
w/c=0.40 (575) w/c=0.45 (575) w/c=0.50 (575)
Res
istiv
ity a
t Nic
k Po
int (Ω⋅m
)Air content (%)
(b)
National Concrete Consortium April 2018– [email protected] © Slide 27 of 40
F Factor For Matrix Saturation (Bucket)
National Concrete Consortium April 2018– [email protected] © Slide 28 of 40
National Concrete Consortium April 2018– [email protected] © Slide 29 of 40
What happens in the Bucket
Ionic solution in thebucket matches the pores
National Concrete Consortium April 2018– [email protected] © Slide 30 of 40
Sorption Based Model
Luce
ro e
t al.
2015
National Concrete Consortium April 2018– [email protected] © Slide 31 of 40
Sorption Based Model
Luce
ro e
t al.
2015
National Concrete Consortium April 2018– [email protected] © Slide 32 of 40
Saturation vs. Air
National Concrete Consortium April 2018– [email protected] © Slide 33 of 40
Confirming the Pores that Fill in the Bucket
0.0 0.2 0.4 0.6 0.8 1.00.0
0.2
0.4
0.6
0.8
1.0
w/c=0.40 w/c=0.45 w/c=0.50 w/c=0.40 (575) w/c=0.45 (575) w/c=0.50 (575)
Mea
sure
SN
K (b
ucke
t tes
ts)
Theoretical SNK (mixture proportion)
(a)
0.0 0.2 0.4 0.6 0.8 1.00.0
0.2
0.4
0.6
0.8
1.0
-20% variation
w/c=0.40 w/c=0.45 w/c=0.50 w/c=0.40 (575) w/c=0.45 (575) w/c=0.50 (575)
ρ SA
T/ρ N
K
SNK
+20% variation
National Concrete Consortium April 2018– [email protected] © Slide 34 of 40
F Factor Defined• Inverse of the product of porosity and connectivity.
𝐹𝐹 =1∅𝛽𝛽
∅ = porosity
𝛽𝛽 = connectivity
• The porosity in the matrix is the same if the w/cm is the
same, (gel, capillary and CS pores same; air varies)
𝐹𝐹 =𝜌𝜌
𝜌𝜌𝑜𝑜
National Concrete Consortium April 2018– [email protected] © Slide 35 of 40
Connectivity
National Concrete Consortium April 2018– [email protected] © Slide 36 of 40
Computation of the Pore Solution
• Assume a value (0.04-0.12 Ω-m) (Spragg 2017)• Estimate value from mill cert (NIST) (Bentz 2007)• Estimate value from GEMS (Azad et al. 2018) • Use of Sensors (Rajabiopour et al. 2007)• Pore solution expression (Barneyback/Diamond 1981)Direct measurements: resistance meterChemical analysis:
o Inductively coupled plasma (ICP)oAtomic absorption (AA)o Ion chromatography (IC)oX-ray Fluorescence (XRF)
Slag
𝐹𝐹 =𝜌𝜌𝑏𝑏𝜌𝜌𝑜𝑜
Are estimates perfect no, are thebetter than nothing (RCPT) yes
National Concrete Consortium April 2018– [email protected] © Slide 37 of 40
F Factor Defined• Inverse of the product of porosity and connectivity.
𝐹𝐹 =1∅𝛽𝛽
∅ = porosity
𝛽𝛽 = connectivity
• The porosity in the matrix is the same if the w/cm is the
same, (gel, capillary and CS pores same; air varies)
• The bucket helps define the pore solution
𝐹𝐹 =𝜌𝜌
𝜌𝜌𝑜𝑜
National Concrete Consortium April 2018– [email protected] © Slide 38 of 40
Theory of Everything
National Concrete Consortium April 2018– [email protected] © Slide 39 of 40
Theory of Everything
Use the F Factor to Obtain Other Transport
Properties
National Concrete Consortium April 2018– [email protected] © Slide 40 of 40
F Factor and RCPT
• More fundamentally however the F-Factor can be related with the pore solution conductivity and RCPT
𝑄𝑄 = 𝑉𝑉𝐴𝐴𝐿𝐿𝑡𝑡
1𝜌𝜌0
1𝐹𝐹
Q= 60𝑉𝑉 8107𝑚𝑚𝑚𝑚2
50.8𝑚𝑚𝑚𝑚21,600 𝑠𝑠 1
𝜌𝜌𝑜𝑜
1𝐹𝐹
Q= 206,830 𝑉𝑉 𝑚𝑚 𝑠𝑠𝜌𝜌𝑜𝑜
1𝐹𝐹 W
eiss
et a
l. 20
16
National Concrete Consortium April 2018– [email protected] © Slide 41 of 40
F Factor and DApparent
• Frequent criticism of F-Factor - it doesn’t include binding
• While this is true (neither does any electrical measure), it can be shown that F Factor can easily be combined with a binding isotherm to predict performance.
• Nernst Plank equation:
• Freundlich binding: 𝑐𝑐𝑐𝑐𝑐𝑐𝑏𝑏 = 𝛼𝛼 𝑐𝑐𝑐𝑐𝑐𝑐𝛽𝛽
(Qiao et al. submitted)
𝜕𝜕𝜕𝜕𝑡𝑡
𝑝𝑝𝐶𝐶𝑖𝑖 + 𝐶𝐶𝑖𝑖𝑏𝑏 = −div −𝐷𝐷𝑖𝑖0
𝐹𝐹 grad𝐶𝐶𝑖𝑖 + 𝐶𝐶𝑖𝑖grad ln 𝛾𝛾𝑖𝑖 +𝑧𝑧𝑖𝑖𝐹𝐹𝑅𝑅𝑅𝑅 𝐶𝐶𝑖𝑖
grad𝜓𝜓
National Concrete Consortium April 2018– [email protected] © Slide 42 of 40
Chloride Diffusion
• Here we see that combining the F-Factor and binding is very powerful .
• This does a good job at predicting chloride ingress.
• This is much faster than ASTM 1556.
• Further binding is a qualification test and F is a QC/QA test. (Qiao et al. submitted)
An example where datafrom 10 or so other states have also been collected, we wouldwelcome sharing method with others who want to try
National Concrete Consortium April 2018– [email protected] © Slide 43 of 40
F Factor and Absorption• Related to other transport properties directly.• Mass of absorbed water (M) is related to (F-0.5)• Derived from first principles
𝑀𝑀 𝑡𝑡 = 𝐴𝐴𝜌𝜌𝐴𝐴𝑖𝑖2
𝜀𝜀𝑃𝑃𝑐𝑐𝑐𝑐𝑐𝑐𝜇𝜇
1𝐹𝐹
𝑡𝑡
Mor
adllo
et a
l. su
bmitt
ed
National Concrete Consortium April 2018– [email protected] © Slide 44 of 40
Conclusions
Why was this a good idea, I don’t know
National Concrete Consortium April 2018– [email protected] © Slide 45 of 40
Conclusions
• Don’t Duck It – Get a Bucket
• Pores of the Matrix Are Great – They Saturate
• Air Voids are Vast – But Remain Full of Gas
• Bucket Solution is Great – The Ions Equilibrate
• F Factor is the Best – It can Replace Other Tests
National Concrete Consortium April 2018– [email protected] © Slide 46 of 40
Criticism may not be agreeable, but it is necessary. It fulfils the same function as pain in the human body.
Winston Churchill