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Foam formation in glass furnaces Postdoc: John van der Schaaf Phone : +31 (0) 40 247 4712 Supervision: Ruud Beerkens Fax: +31 (0) 40 244 6653 Cooperation: TNO-TPD, Rexam, EET E-mail: [email protected] Introduction In a glass-melting furnace, fining of the glass- melt may cause foam formation. If the gas- bubble flux to the glass-melt surface is high enough, a layer of foam is formed. This foam layer insulates the glass-melt from heat radiation generated in the combustion space above the glass-melt. Effectively, heat transfer is severely restricted towards the glass-melt and a large amount of heat is reflected, thus increasing crown temperatures (increased refractory attack hazard) and reducing glass- melt temperatures. Consequently, maintaining glass-melt temperatures at specified values by burner- control becomes increasingly difficult with increasing foam-layer thickness. Thus, in order to be able to predict and prevent foam formation, a foam-model, based on first principles, is developed in this project. Model Description The transient foam-layer height, H F , is given by: ) t ( j ) t ( j H b in in F τ - - = with τ b the average lifetime of a gas bubble in the foam-layer and j in the gas bubble to the glass-melt surface. The average lifetime of a gas-bubble at the glass-melt surface can be derived from the momentum balances and the equation of continuity, using partially immobile gas-bubble walls. The degree of immobilization depends on the surface activity, represented by parameter ψ. The relationship derived for τ b is: δ ψ δ δ τ = τ c c 0 2 b 2 ln R 1 3 R The lifetime of a gas-bubble in a foam-layer will increase because of down-flowing liquid from the top of the foam. This effect is described by: = - τ τ - τ τ - τ τ - τ = δ δ N 1 i 1 i f N 0 c f N e ) 1 i ( e The lifetime of a gas bubble in a N-layer foam τ N , is thus determined implicitly. Results Experiments In the figure below, the transient foam height is shown for different constant gas fluxes in a glass-melt at 1400 o C. At low gas fluxes a finite foam-height is rapidly attained (slope equals gas flux), which increases only slowly in time. At higher fluxes, a steady, unbounded, increase in foam height is observed. When the gas flow is stopped, the foam height rapidly decreases. Model In the figure below, the simulated transient foam height is displayed. The same behavior is observed as in the experiments. At low gas fluxes a bounded foam height is obtained, at higher gas fluxes the foam height increases indefinitely. 0 20 40 60 80 100 0 500 1000 H f (mm) time(s)

Foam Formation in Glass Furnace

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Page 1: Foam Formation in Glass Furnace

Foam formation in glass furnaces

Postdoc: John van der Schaaf Phone: +31 (0) 40 247 4712Supervision: Ruud Beerkens Fax: +31 (0) 40 244 6653Cooperation: TNO-TPD, Rexam, EET E-mail: [email protected]

IntroductionIn a glass-melting furnace, fining of the glass-melt may cause foam formation. If the gas-bubble flux to the glass-melt surface is highenough, a layer of foam is formed. This foamlayer insulates the glass-melt from heatradiation generated in the combustion spaceabove the glass-melt. Effectively, heat transferis severely restricted towards the glass-meltand a large amount of heat is reflected, thusincreasing crown temperatures (increasedrefractory attack hazard) and reducing glass-melt temperatures.Consequently, maintaining glass-melttemperatures at specified values by burner-control becomes increasingly difficult withincreasing foam-layer thickness. Thus, in orderto be able to predict and prevent foamformation, a foam-model, based on firstprinciples, is developed in this project.

Model DescriptionThe transient foam-layer height, HF, is givenby: )t(j)t(jH bininF τ−−=with τb the average lifetime of a gas bubble inthe foam-layer and j in the gas bubble to theglass-melt surface. The average lifetime of agas-bubble at the glass-melt surface can bederived from the momentum balances and theequation of continuity, using partially immobilegas-bubble walls. The degree of immobilizationdepends on the surface activity, represented byparameter ψ. The relationship derived for τb is:

δψ

+

δδτ

=τcc

02b 2

lnR1

3R

The lifetime of a gas-bubble in a foam-layer willincrease because of down-flowing liquid fromthe top of the foam. This effect is described by:

∑=

ττ

−τ

τ−

ττ−+τ

=δδ N

1i

1i

fN

0

cfN

e)1i(

e

The lifetime of a gas bubble in a N-layer foam τN,is thus determined implicitly.

ResultsExperiments In the figure below, the transientfoam height is shown for different constant gasfluxes in a glass-melt at 1400oC. At low gasfluxes a finite foam-height is rapidly attained(slope equals gas flux), which increases onlyslowly in time. At higher fluxes, a steady,unbounded, increase in foam height is observed.When the gas flow is stopped, the foam heightrapidly decreases.

Model In the figure below, the simulatedtransient foam height is displayed. The samebehavior is observed as in the experiments. Atlow gas fluxes a bounded foam height isobtained, at higher gas fluxes the foam heightincreases indefinitely.

020406080

100

0 500 1000

Hf(mm)

time(s)