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8/3/2019 Fire and Prevention
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Fire ExtinguishingFire Extinguishing
Dr.Kowit Nambunmee
School of Health Science
Mae Fah Luang University
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Fire, Fire ExtinguishingFire, Fire Extinguishing
SmokeSmoke
BurnBurn
InjuryInjury
CatastropicCatastropic
Animal deathAnimal death
Destroyed estateDestroyed estateClimate changeClimate change
Ecology changeEcology change
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Kader Toy IndustryKader Toy Industry
http://www.thaiengineering.com/column/lesson_disaster/World_trade_center/World_Trade_Center.asp
http://www.oknation.net/blog/print.php?id=595510
CatastropicCatastropic
DisabilityDisability
BurnBurnCompensationCompensation
Business imageBusiness image
Business chanceBusiness chance
ProfitProfit
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Definition of Fire
Definition of Fire
Fire is the heat and light energy released
during a chemical reaction, in particular a
combustion reaction.
Depending on the substances alight and any
impurities within, the color of the flameand the fire intensity might vary.
Fire, Fire Extinguishing
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http://www.tpfire.co.uk/Fire%20Triangle.JPG
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Heat/Ignition SourceHeat/Ignition Source
Direct heatCurrent electricity
Static electricity
Electric stormsImpact sparks and friction
Spontaneous combustion
Auto ignitionPyrophoric ignition
http://www.towage-salvage.com/Marine-other/2317.html
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Types of Ignition Sources Identified in WebsiteTypes of Ignition Sources Identified in Website
Case StudiesCase Studies
http://www.firesandexplosions.ca/hazards/ignition_sources.php
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Ignition SourceIgnition Source
Potassium chloratePotassium chlorate
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http://www.mycarefreepc.com/images/static_monkey.gif
Insulator
Charge imbalance
Catch electric current easily
https://reader009.{domain}/reader009/html5/0506/5aee74794d686/5aee747fcd79e.jpg
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Ignition SourceIgnition Source
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FuelFuel
Fuel classification;Solid
:wood, paper, plastic, rubber, fiber,some types of plastics
Liquid:petrol/gasoline, solvents, alcohol, oil,
paintGas
:ethylene, propylene, natural gas
Fire, Fire Extinguishing
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Combustible and FlammableCombustible and Flammable
FlammableFlammable is a material that can easily catch fireunder normal circumstances and with the help ofminimal ignition source. Just a spark is sufficientenough.
CombustibleCombustible materials can include anything thatwill burn. A simple spark is definitely not enough.
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FuelFuel
Temperature to generate fire
Flash point: lowest temperature at which a
liquid fuel will form an ignitable vapor Fire point: lowest temperature at which vapor
will be formed rapidly enough to sustain a fire
Boiling point: Lowest temperature at somegiven pressure at which a liquid begins to
evaporate or boil
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FuelFuel
Fuel properties;
1. Flash point
Fuel Flash point (C)Gasoline - 43
Acetone - 19
Heptane - 4
Toluene 6
Methyl alcohol 11
Fire, Fire Extinguishing
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FuelFuel
Mix with optimum concentration to the air
Upper flammability limit
Lower flammability limit
Specific gravity:
Water = 1
Water =1
Specific gravity>1
Specific gravity
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Flammable LiquidsFlammable Liquids
Flammable Limits Example
LEL lower explosive limit
UEL upper explosive limit
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BoilingP
ointBoilingP
ointD
efinitionD
efinition Boiling pointBoiling point is the temperature at which ais the temperature at which a
liquid changes to a gas (liquid changes to a gas (vaporvapor) at) at normalnormal
atmospheric pressureatmospheric pressure. A more specific. A more specific
definition of boiling point is the temperaturedefinition of boiling point is the temperature
at which theat which the vapor pressurevapor pressure of a liquid isof a liquid is
equal to the external pressure.equal to the external pressure.
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Example of Boiling PointExample of Boiling Point Water freezes atWater freezes at 3232 F.F.
((00 C)C)
Turns to liquid at aboveTurns to liquid at above
3232 F.F.
Boils & changes to GasBoils & changes to Gas
atat 212212
F (F (100100 C).C). ExpandsExpands 1717,,000000 times ittimes it
normal size when heated.normal size when heated.
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Boiling PointBoiling Point
MSDS relevanceMSDS relevance
Knowing the boiling point of a substance is anKnowing the boiling point of a substance is animportant consideration for storage.important consideration for storage.
3030 C: room temperature, almost evaporated,C: room temperature, almost evaporated,protect from sunlightprotect from sunlight
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FuelFuel
Fuel properties;1. Flash point
2. Ignition temperature
3. Auto-Ignition temperature
4. Percentage mixture
5. Water solubility6. Specific gravity
7. Vapor density
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OxygenOxygen
Oxidizing agent
Oxidation: give heat
Fluorine and chlorine
Exothermic reaction
-H: release energy
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Type of FireType of Fire
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Extinguishment TheoryExtinguishment Theory
Remove HeatRemove Heat
Remove FuelRemove Fuel
ReduceOxygenReduceOxygen WILLWILL
Inhibit ChemicalInhibit Chemical
Chain ReactionChain Reaction
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Cut-out
Air
Fuel
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Fire extinguisherFire extinguisher
Is an active fire protection device used to
extinguish or control small fires, often in
emergency situations.
It should never be used on an out-of-control
fire, such as one which reaches the ceiling,
endangers the user, or otherwise requires
the expertise of a fire department.
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Fire extinguisherFire extinguisher
Typically, a fire extinguisher consists of a
handheld cylindrical pressure vessel
containing an agent which can bedischarged to extinguish a fire.
Fire, Fire Extinguishing
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Fire extinguisherFire extinguisher
The typical steps for operating a stored pressure fire
extinguisher: described by the acronym PASS
P: Pull the safety pin.A: Aim the nozzle at the base of the fire, from a safe
distance. (about 1-3 meters)
S: Squeeze the handle.
S: Sweep the extinguisher from side to side while
aiming at the base of the fire.
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Types of extinguishing agentsTypes of extinguishing agents
Dry Chemical:
Powder based agent that extinguishes by
separating the four parts of the fire
tetrahegon.
It prevents the chemical reaction betweenheat, fuel and oxygen. Thus extinguishing
the fire.
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Dry Chemical:
Contrary to some beliefs dry chemical agents do not
cool or smother a fire.
Examples:
- Ammoniun phosphate- Sodium bicarbonate
- potassium bicarbonatex
- Potassium bicarbonatex & Urea complex
Fire, Fire Extinguishing
Types of extinguishing agents
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Foams:
AFFF: Aqueous Film Forming Foam
AR-AFFF: Alcohol Resistant-Aqueous Ailm
Forming Foams
FFFP: Film Forming Fluoro-Protein
CAFS: Compressed Air Foam SystemArctic Fire
Fire Ade
Fire, Fire Extinguishing
Types of extinguishing agents
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Water:
APW: Air Pressurized Water
Water Mist
Water Additives:
Wet Chemical (potassium acetate)
Wetting agent: detergent based additives
used to break the surface
tension of water
Fire, Fire Extinguishing
Types of extinguishing agents
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Clean Agents:
Agent does not extinguish by smothering but displaces
oxygen, or inhibits chemical chain reaction.
They are labeled clean agents because they do not
leave any residue after discharge which is ideal for
sensitive electronics and documents.
Fire, Fire Extinguishing
Types of extinguishing agents
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Clean Agents:
Halon ( Halon 1221 and Halon 1301), a gaseous
agent that inhibits the chemical reaction of the
fire.
CO2, a clean gaseous agent which displaces
oxygen.
Mixtures of inert gases (inergen and argonite)
Fire, Fire Extinguishing
Types of extinguishing agents
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Fire extinguisherFire extinguisher
Fire, Fire Extinguishing
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Fire extinguisherFire extinguisher
Fire, Fire Extinguishing
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Proactive Fire SafetyProactive Fire Safety
Fire Risk AnalysisFire Risk Analysis Identify the fuel source & eliminate it ifIdentify the fuel source & eliminate it if
possible.possible.
Identify the heat source and eliminate it ifIdentify the heat source and eliminate it ifpossible.possible.
Terminate behaviors that lead to hazardousTerminate behaviors that lead to hazardous
conditions & replace with appropriate behaviorsconditions & replace with appropriate behaviors
conducive to good fire safety.conducive to good fire safety.
1.1. Storing flammable and combustible inStoring flammable and combustible in
appropriate areas.appropriate areas.
2.2. On equipment, in fire cabinets, in work areas.On equipment, in fire cabinets, in work areas.
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Identifying Fire Hazards In YourIdentifying Fire Hazards In Your
Work AreaWork Area What chemical are present in your work area?What chemical are present in your work area?
What are there flash points?What are there flash points?
In stationary equipment areasIn stationary equipment areasOn mobile equipmentOn mobile equipment
At shopsAt shops
What heat source are present?What heat source are present?
Thermal (heat)Thermal (heat)
ElectricalElectrical
RadiantRadiant