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MATERIAL PRODUCTION AND CHARACTERIZATION
Multifunctional materials for 3D printed
customizable footwearD. Rigotti, G. Barp, A. Dorigato, L. Fambri, A. Pegoretti
Università di Trento, Dip. Ingegneria Industriale
via Sommarive, 9 - 38123 Trento, Italy
Nowadays the research on performance in sport is becoming more and more significant, athletes are constantly searching for new challenges
pushing further their own limits and the ones of their equipment. Materials and sport gears tailored on the single athlete are key points to express all
the potential of the sportsman during the achievement of his goals. In winter sport footwear applications, like skiing, snowboarding, running and so
on, cold temperature, vibration absorption and comfort are crucial aspects. 3D printable soft material able to absorb heat and then release it later,
when needed, seems an innovative solution in this field.
The aim of this study was to develop a novel rubbery material to produce customizable insoles for winter sports application with enhanced thermal
properties given by the introduction of phase change material (PCM) through a Fused Deposition Modeling (FDM) 3D printer machine.
4032D
4032D+30%M6D
4032D+40%M6D
4032D+50%M6D
4032D+60%M6D
FilaFlex
Sharebot
0
5
10
15
20
25
30
35
40
Mod
ulu
s C
ho
rd (
MP
a)
30 40 50 60
0
20
40
60
80
Sp
ecific
Hea
t (J
/g)
Percentage of M6D (wt%)
Bulk Sample
Filament
Printed
30 40 50 60
0
10
20
30
40
50
60
70
80
90
100
Norm
aliz
ed H
eat of C
rysta
llization (
%)
MPCM6D
OPEN SOURCE INSOLE DESIGN AND PRODUCTION
Infill density 10% 25% 50% 75%
Hexagonal infill
Rectangular infill
In order to understand how fill density and fill
pattern affect the compression modulus,
compression tests were carried out on 3D
printed cylinders.
Different commercial TPU filament were tested
and used to produce samples with different
densities and fill pattern. The measurements
are carried out according to the ASTM D1621,
standard test method for compressive
properties of rigid cellular plastics.
Cylinders of 3cm in diameter and 1cm in height,
with infill densities of 10%, 25%, 50% and 75%
and with rectilinear and hexagonal filling were
printed and tested by using a Instron 5969 test
machine.
The first part was devoted to the
acquisition of an image of the foot. A 3D
reconstruction is possible by using 3D
scanner that is a very useful tool but not
easy to be found. The consequence is
that possible scan of parts of the body can
be very expensive that collides with the
open-source intention of this work. A
possible solution of this problem is to use
a normal 2D scanner.
The image of the foot was collected by the
scanner and processed by using the
GIMP, an open software for image
manipulation. The image was vertically
flipped, translated into a black and white
picture and posterized. The posterization
is used for the conversion of a continuous
gradation of tone to several regions of
fewer tones with abrupt changes from onetone to another.
The next step was to reconstruct the 3D
shape of the foot. This is possible by
using OpenSCAD software with the
command “surface” that assigns a height
for each color gradation of the 2D picture.
The 3D model needed to be smoothed
before printing and it was done by using
an Meshmixer a freeware software from
Autodesk, the model was saved in a STL
format and loaded to the slicing software.
Slic3r is an open-source software develop
by the RepRap community.This software
is a non-profit project, is widespread and
it is being used by tens thousands of
people all over the world.
Slic3r has an innovative tool that permits
to create 3D printed objects with different
densities and it was possible to print an
insole with different mechanical
properties.
The insole was printed with a desktop 3D
printer provided by Sharebot with our
innovative filament.
Main printing parameters were:
• Nozzle temperature of 240°C
• Nozzle diameter 0.35mm
• Deposition rate of 40 mm/s
The aim of this part of the work was to design a tailor-made insole for 3D printing with innovative and open-source devices. The idea was to create an insole that can
compensate postural defects by distributing the weight of the body uniformly in each point of the foot.
Neat TPU 30wt% M6D
40wt% M6D 50wt% M6D
0 10 20 30 40 50
60
65
70
75
Sp
eci
fic H
ea
t (J
/g)
Cycle number (#)
Heat of Fusion
Heat of Crystallization
0 10 20 30 40 50 60 70 80 90 100
0
1
2
3
4
5
6
Com
pre
ssio
n M
od
ulu
s (
MP
a)
Fill Density (%)
Filaflex Hexagonal
FilaFlex Rectangular
Different kinds of phase change materials (PCM) and processing techniques were
taken in account to produce a material suitable to produce advanced insoles with
additive manufacturing (AM) techniques. Good results were found in terms of
processability and heat production by using a combination of thermoplastic
polyurethane (TPU), already use in footwear applications, and microencapsulated
paraffin with a crystallization peak temperature of 6°C (MPCM6D). TPU powder
was mixed together with MPCM6D and with the aid of a single screw extruder, we
could obtain filaments to feed our 3D printer machine.
Dumbbell specimens were printed with a 3D printer provided by Sharebot. SEM
observation shows a good adhesion between layers for all the different
composition regardless the increasing amount of PCM inside the matrix.
The shell of the PCMs microcapsules increase the stiffness of TPU as confirmed
by tensile test and dynamic mechanical analysis (DMA). At room temperature the
melted paraffin increase the damping effect of the material as proved by the
shoulder in tan delta graph. Differential scanning calorimeter (DSC) shows an
increase of the crystallization enthalpy with the increase of PCM and just a slightly
decrease after each working step. Heating effect remains constant cycle after
cycle as confirmed by DSC.
-60 -40 -20 0 20 40 60 80
1
10
100
1000
10000
Sto
rag
e M
od
ulu
s (
MP
a)
Temperature (°C)
TPU_3D
TPU+30%M6D_3D
TPU+40%M6D_3D
TPU+50%M6D_3D
-60 -40 -20 0 20 40 60 80
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
Tan D
elta
Temperature (°C)
TPU_3D
TPU+30%M6D_3D
TPU+40%M6D_3D
TPU+50%M6D_3D
Filaflex filament was choosen as a preliminary experimental material due to
similar values in stiffness compared to our filaments filled with PCM.
Compression test on cylinder specimen was the starting point to design the infill
of our insole.
Not only the infill density plays a role in the mechanical properties of the printed
materials but also the design of the infill. Rectangular infill was found to be softer
than the hexagonal one due to the less contact point between the layers walls.
0 30 40 50 60
0
2
4
6
8
10
12
14
16
18
20
22
24
Mod
ulus
Cho
rd (M
Pa)
M6D content (wt%)
Compression Molded
Filament
3D printed
FILAFLEX SAMPLES