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is the three-way catalyst. For diesel engines operating under lean conditions, the tighter particulate matter limits are met by using a pgm- coated diesel particulate filter. Good progress has been made on the control of NOx from gasoline engines and developments are being made on lowering NOx emissions from diesels to meet upcoming emissions limits. A conference review of the Society of Automotive Engineers 2012 World Congress by Timothy Johnson from Corning Environmental Technologies, USA, focuses on the key developments related to the pgms for both diesel and gasoline engine emissions control. Also in the issue, a book review by Bruno Pollet of HySA Systems Competence Centre, University of the Western Cape, South Africa, covers topics such as pgm electrocatalysts, fuels and materials, durability tests, and the main (in situ) techniques and methods currently employed in characterising the membrane electrode assembly and its subcomponents. The conversion of biomass to fuels and chemicals as a way to mitigate global warming and diversify energy sources is also featured in the latest issue, with a conference review highlighting the progress of pgm catalysts. Shaped metal nanoparticles and their applications in catalysis are covered in a book review by Laura Ashfield of Johnson Matthey Technology Centre, Sonning Common, UK. Other topics in this issue include the role of platinum in superconductors and the crystallographic properties of ruthenium. Original Source: Johnson Matthey Platinum Today, website: http://www.platinum.matthey.com/ (1 May 2013) © Johnson Matthey plc 2013 Bacteria produce fuel identical with petrol John Love and his colleagues at the University of Exeter in the UK modified Escherichia coli to produce hydrocarbons that can be used as desirable biofuels. The researchers inserted the genes of camphor tree, soil bacteria, and blue-green algae into the DNA of E coli. The enzymes in the modified E coli turned fatty acids into hydrocarbons that are identical with those of commercial fuel. This process could produce biofuels that are suitable for, and would not corrode, vehicle engines. Original Source: New Scientist – UK Edition, 27 Apr 2013, 218 (2914), 18 (Website: http://www.newscientist.com) © Reed Business Information Ltd 2013 Akermin demonstrates CO 2 capture using Biocatalyst Delivery System Akermin announces the successful commissioning and testing of its proprietary Biocatalyst Delivery System at the National Carbon Capture Centre in Wilsonville, AL. The pilot unit has operated continuously for several weeks capturing close to 90% CO 2 from flue gas with significant rate enhancement and no degradation in performance. The pilot plant will continue operations for several months with no replenishment of enzyme. The operating data provide technical and economic validation for CO 2 removal from target markets such as biogas upgrading, LNG and ammonia production and support larger-scale field pilot testing for natural gas and coal-fired power plants. Original Source: Akermin, 2013. Found on PR Newswire, 3 Jun 2013, (Website: http://www.prnewswire.com) UK researchers devise PE decomposition additive London-based Advanced Enzyme Science has developed Enzymoplast, a polyethylene additive that can break down polyethylene “in a natural way”. Decomposition of plastic bags occurs when plastic bags with additive comes into contact with microorganisms. The polymer chain is broken when the microorganisms consumes the protein. The process is accelerated with activation of enzymes. The process leaves only water and CO 2 after a few months. Original Source: Plastics News, 8 May 2013, (Website: http://www.plasticsnews.com) © Crain Communications Inc 2013 PATENTS Microbiological production of metallic nanoparticles Nanoparticles of metals (Au, Ag, Zn, Hg, Pd, Pt, Bi) are made by contacting aqueous solutions of the metals with bacteria (eg lactobacillus) which incorporate the metals in their membranes. The bacteria are harvested in various ways, yielding suspensions of metals having bactericidal properties. US 8,455,226, Janssen Pharmaceutica NV, Beerse, Belgium, 4 Jun 2013 Acrylic acid from fumaric acid Fumaric acid is made from biomass by fermentation with a genetically- modified micro-organism. Then the fumaric acid is combined with ethylene by cross-metathesis, catalysed by known metathesis catalysts. These are mostly based on ruthenium with a complex ligand. US 8,455,683, Genomatica Inc, San Diego, C, USA, 4 Jun 2013 Ethanol made by hydrogenating acetic acid and ethyl acetate Ethanol is made from acetic acid or ethyl acetate by hydrogenating it over a supported catalyst containing cobalt and tin. US 8,455,702, Celanese International Corp, Irving, TX, USA, 4 Jun 2013 Conversion of oxygenates to liquid fuels This is an extension of the Bioforming Process invented in the University of Wisconsin. Mono-oxygenated hydrocarbons obtained by aqueous phase reforming of biomass are catalytically hydrogenated. US 8,455,705, Virent Inc, Madison, WI, USA, 4 Jun 2013 Structured F-T catalysts Fischer-Tropsch catalysts traditionally contain cobalt and iron on a solid support.In this example, the cobalt metal is obtained by reducing the supported oxide, and iron is deposited on its surface by the decomposition of iron carbonyl. US 8,455,556, Shell Oil Co, Houston, TX, USA, 4 Jun 2013 Preparation of granular mesoporous carbon Initially a composite is prepared containing a silica precursor, a carbon precursor, and a pore-forming additive. JULY 2013 7 FOCUS ON CATALYSTS

Ethanol made by hydrogenating acetic acid and ethyl acetate

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is the three-way catalyst. For dieselengines operating under leanconditions, the tighter particulatematter limits are met by using a pgm-coated diesel particulate filter. Goodprogress has been made on thecontrol of NOx from gasoline enginesand developments are being made onlowering NOx emissions from dieselsto meet upcoming emissions limits. Aconference review of the Society ofAutomotive Engineers 2012 WorldCongress by Timothy Johnson fromCorning Environmental Technologies,USA, focuses on the keydevelopments related to the pgms forboth diesel and gasoline engineemissions control. Also in the issue, abook review by Bruno Pollet of HySASystems Competence Centre,University of the Western Cape, SouthAfrica, covers topics such as pgmelectrocatalysts, fuels and materials,durability tests, and the main (in situ)techniques and methods currentlyemployed in characterising themembrane electrode assembly and itssubcomponents. The conversion ofbiomass to fuels and chemicals as away to mitigate global warming anddiversify energy sources is alsofeatured in the latest issue, with aconference review highlighting theprogress of pgm catalysts. Shapedmetal nanoparticles and theirapplications in catalysis are coveredin a book review by Laura Ashfield ofJohnson Matthey Technology Centre,Sonning Common, UK. Other topics inthis issue include the role of platinumin superconductors and thecrystallographic properties ofruthenium.

Original Source: Johnson Matthey Platinum Today,website: http://www.platinum.matthey.com/ (1 May2013) © Johnson Matthey plc 2013

Bacteria produce fuel identical withpetrol

John Love and his colleagues at theUniversity of Exeter in the UKmodified Escherichia coli to producehydrocarbons that can be used asdesirable biofuels. The researchersinserted the genes of camphor tree,soil bacteria, and blue-green algaeinto the DNA of E coli. The enzymesin the modified E coli turned fattyacids into hydrocarbons that areidentical with those of commercialfuel. This process could produce

biofuels that are suitable for, andwould not corrode, vehicle engines.

Original Source: New Scientist – UK Edition, 27 Apr2013, 218 (2914), 18 (Website:http://www.newscientist.com) © Reed BusinessInformation Ltd 2013

Akermin demonstrates CO2 captureusing Biocatalyst Delivery System

Akermin announces the successfulcommissioning and testing of itsproprietary Biocatalyst Delivery Systemat the National Carbon Capture Centrein Wilsonville, AL. The pilot unit hasoperated continuously for severalweeks capturing close to 90% CO2from flue gas with significant rateenhancement and no degradation inperformance. The pilot plant willcontinue operations for several monthswith no replenishment of enzyme. Theoperating data provide technical andeconomic validation for CO2 removalfrom target markets such as biogasupgrading, LNG and ammoniaproduction and support larger-scalefield pilot testing for natural gas andcoal-fired power plants.

Original Source: Akermin, 2013. Found on PRNewswire, 3 Jun 2013, (Website:http://www.prnewswire.com)

UK researchers devise PEdecomposition additive

London-based Advanced EnzymeScience has developed Enzymoplast,a polyethylene additive that can breakdown polyethylene “in a natural way”.Decomposition of plastic bags occurswhen plastic bags with additive comesinto contact with microorganisms. Thepolymer chain is broken when themicroorganisms consumes theprotein. The process is acceleratedwith activation of enzymes. Theprocess leaves only water and CO2after a few months.

Original Source: Plastics News, 8 May 2013, (Website:http://www.plasticsnews.com) © CrainCommunications Inc 2013

PATENTSMicrobiological production of metallicnanoparticles

Nanoparticles of metals (Au, Ag, Zn,Hg, Pd, Pt, Bi) are made bycontacting aqueous solutions of the

metals with bacteria (eg lactobacillus)which incorporate the metals in theirmembranes. The bacteria areharvested in various ways, yieldingsuspensions of metals havingbactericidal properties.

US 8,455,226, Janssen Pharmaceutica NV, Beerse,Belgium, 4 Jun 2013

Acrylic acid from fumaric acid

Fumaric acid is made from biomassby fermentation with a genetically-modified micro-organism. Then thefumaric acid is combined withethylene by cross-metathesis,catalysed by known metathesiscatalysts. These are mostly based onruthenium with a complex ligand.

US 8,455,683, Genomatica Inc, San Diego, C, USA, 4Jun 2013

Ethanol made by hydrogenating aceticacid and ethyl acetate

Ethanol is made from acetic acid orethyl acetate by hydrogenating it overa supported catalyst containing cobaltand tin.

US 8,455,702, Celanese International Corp, Irving, TX,USA, 4 Jun 2013

Conversion of oxygenates to liquid fuels

This is an extension of the BioformingProcess invented in the University ofWisconsin. Mono-oxygenatedhydrocarbons obtained by aqueousphase reforming of biomass arecatalytically hydrogenated.

US 8,455,705, Virent Inc, Madison, WI, USA, 4 Jun2013

Structured F-T catalysts

Fischer-Tropsch catalysts traditionallycontain cobalt and iron on a solidsupport.In this example, the cobaltmetal is obtained by reducing thesupported oxide, and iron is depositedon its surface by the decomposition ofiron carbonyl.

US 8,455,556, Shell Oil Co, Houston, TX, USA, 4 Jun2013

Preparation of granular mesoporouscarbon

Initially a composite is preparedcontaining a silica precursor, a carbonprecursor, and a pore-forming additive.

JULY 2013 7

F O C U S O N C A T A LY S T S