EPOXY PRODUCTS FOR EMEA Civil EnginEERing APPliCATiOnS · Olin Epoxy Products for EMEA Civil Engineering Applications 6 Modified Polyamide Curing Agents D.E.H.™ 1450 • • D.E.H

Epoxy

EPOXY PRODUCTS FOR EMEA Civil EnginEERing APPliCATiOnS

1 Olin Epoxy Products for EMEA Civil Engineering Applications

Set New Standards for Civil Engineering with Olin Epoxy ProductsCivil engineering projects worth doing right are worth protecting right. With a robust portfolio of resins, diluents and curing agents developed with the building and construction industry in mind, Olin Epoxy can help formulators meet evolving specific civil engineering application requirements across Europe and beyond.

Olin Epoxy products enable formulators to provide a complete binder system: high performance along with value-added features like exceptional sustainability, broad application parameters and economical lifetime costs.

Olin leadership in epoxy technology spans more than 60 years. Our legacy of innovative technology, high quality products and attention to customer service is evident in today’s portfolio. Low emission curing agents, products developed for curing under challenging conditions and products with improved UV stability for enhanced aesthetics are examples of the pioneering technology resulting from Olin’s continued investment in research and development.

And, as always, our commitment to providing exceptional epoxy solutions to the building and construction industry is based on adherence to the highest standards for safety in the manufacture, storage, transport, use and disposal of epoxy products.

Olin Epoxy Products for EMEA Civil Engineering Applications 2

Building a Better World, Side by SideBeyond technology development, Olin Epoxy is your technical support partner. Our experts are dedicated to helping you apply our solutions effectively so your customers achieve their desired results.

Our comprehensive European service model combines sales and technical service with our technical center in Baltringen, Germany. This collaboration provides access to local know-how and support backed by world-class technical resources.

Sustainable Performance Across the Board Olin epoxy solutions help formulators develop solutions that provide:

• Excellent resistance to acids, organic solvents and other chemicals for long-term durable performance and easy maintenance

• High mechanical strength and toughness properties to stand up to heavy loads and to resist impact damage and other abuse

• High flexural strength to withstand elongation, compressive and bending forces

• Low temperature and rapid curing capabilities along with good pot life to extend the floor application season and speed project completion

• Exceptional environmental performance with low emission products to improve air quality

• Long-lasting, appealing aesthetics with enhanced UV stability and excellent long-term resistance to wear

The high mechanical strength and toughness properties of flooring systems formulated using epoxy products from Olin provide the high load-bearing properties necessary in many industrial environments. Flexural strength properties can be enhanced to increase toughness, protecting flooring surfaces from impact damage, abrasive wear and other abuse.

For more information about any of the products listed in this brochure, or to learn more about how Olin Epoxy can provide the products and support you need to strengthen your system differentiation and competitive position, contact your Olin Epoxy representative.

REACH Compliance In accordance with Regulation (EC) No. 1907/2006 concerning the Registration, Evaluation, Authorisation, and Restriction of Chemicals (REACH), all REACH-relevant substances manufactured or imported into the European Union by Olin and contained in our Epoxy products have been registered or will be registered within the current deadlines. In Olin’s opinion, REACH represents an extraordinary opportunity for the chemical industry, its suppliers and customers to work together to protect the environment and to ensure a future for the chemical industry in Europe.


Olin Curing Agent InnovationsLow Emissions Olin’s commitment to responsible stewardship of the environment, human health and safety extends to the products we offer. Our innovative product line of emission-minimized D.E.H.™ hardeners can be used to formulate primer and top-coat floorings while meeting the most stringent emission regulations.

Following are the latest generation of emission-minimized hardeners. We also offer products that do not contain alkyl phenols, benzyl alcohol or VOCs.

Product Characteristics

• no vOC

• no benzyl alcohol

• no alkyl phenols

• Passed AgBB evaluation scheme when cured with epoxy resins

• label A+ according to French legislation when cured with epoxy resins

Technologies Used

• non-vOC, non-reactive diluent

• 100% reactive hardeners

• Waterborne hardeners

• non-vOC containing hardeners

GradeD.E.H.™ 1911 low emission curing agent particularly suited for the development of primers whenever the

substrateiswetordifficulttoadhereto. •D.E.H. 2920 low emission curing agent. Offers a long working time (long pot life) and a quick Shore D

hardness development •D.E.H. 2955 Offers very rapid curing and is highly suitable for anchoring systems or as accelerator.

Suitable for primers if curing is required at temperatures down to -5 °C. •D.E.H. 4911 Fully reactive curing agent containing no vOC and no alkyl phenol. good mechanical

properties. • •D.E.H. 4912 Fully reactive curing agent containing no vOC and no alkyl phenol. Shows low exothermic

reaction. • •D.E.H. 804 Aqueouspolyamineadductsolutionwithemulsificationcapability.Offersvisibleendofpot

life, fast drying, low odor. Suitable for thick layer self-leveling applications. •D.E.H. 805 Aqueouspolyamineadductsolutionwithemulsificationcapability.Offersvisibleendofpot

life, low odor, fast drying and through hardening. • •pr

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Low Viscosity Epoxy and Novolacs Heavy-duty coating and flooring performance requirements call for high-performance epoxy solutions. Solvent-free, low-viscosity resins from Olin Epoxy can be used to achieve both high volume solids and high pigment concentration (PVC), while maintaining good application and metal protection properties.

Olin Epoxy’s low viscosity epoxies and novolacs are suited for applications in challenging environmental conditions such as low temperatures and high humidity. They can be used to formulate coatings for marine use, as well as for linings in chemical tanks. All of these are low viscosity liquid epoxy resins modified with a cycloaliphatic polyglycidyl ether (free of any organic solvent) that facilitate high solids coating formulations with low volatile organic compound (VOC) emissions, while minimizing compromises in performance. They can be cured with multiple types of curing agents (hardeners).

Olin Epoxy low-viscosity technologies can overcome many of the disadvantages inherent in current high-solids systems. In particular, Olin Epoxy technologies can combine ease of application using conventional spray equipment and demonstrate similar performance compared to traditional epoxy systems.

LowViscosityEpoxyandNovolacsBenefits

• Solvent-free formulation capability

• Enables primers with excellent balance of:

- Application properties

- Corrosion resistance

- Chemical resistance

• High achievable volume solids and PvC

• High sprayability

• long pot life

• Exceptional cured coating properties

• DlvnE products have higher chemical and thermal resistance


Low Temperature / Fast Cure The Olin Epoxy curing agent portfolio includes several products that allow cure at temperatures around 5 °C (D.E.H. 622 to 0 ºC), in addition to those offering rapid cure at and below room temperature. As shown in the following tables, these products enable an extended season for flooring installation and use, providing a short back-to-service time.

Low Temperature Curing Data1

Curing Agent AHEW (gr/eg) Viscosity @25 °C (mPa•s)

Mixing Ratio (gr/100g Resin) Resin pot Life (min) Tg1 (ºC) Shore D

7 ºC/65%r.H/24h

D.E.H.™ 614 85 600 50 D.E.R. 3581 14.0 62 73

D.E.H. 615 75 500 40 D.E.R. 3531 20.0 59 76

D.E.H. 622 60 590 35 D.E.R. 3571 6.0 91 67

D.E.H. 622 60 590 33 D.E.R. 331 6.0 101 73

D.E.H. 630 73 800 38 D.E.R. 3531 14.0 nA 741Typicalproperties,nottobeconstruedasspecifications

Typical Properties1

Grade EEW (gr/eq)

Viscosity @25 ºC (mPa•s)

Description

DlvE™ 18 160-175 400-1,000 Lowviscosityliquidepoxyresinmodifiedwithacycloaliphaticpolyglycidyletherforhighsolids coating formulations with ultra low volatile organic compound (vOC) emissions and ease of application. Excellent corrosion protection and chemical resistance. Can be cured with multiple types of curing agents (hardeners).

DlvE 19 185-200 2,600-4,200 Lowviscosityepoxyresinmodifiedwithacycloaliphaticpolyglycidyletherforhighsolidscoating formulations with low volatile organic compound (vOC) emissions, excellent application, corrosion and chemical resistance. Can be cured with multiple types of curing agents (hardeners).

DlvE 52 165-180 350-550 Ultralowviscosityepoxyresinmodifiedwithacycloaliphaticpolyglycidylether(freeofanyorganic solvent) for high solids coating formulations with low volatile organic compound (vOC) emissions, excellent application, corrosion and chemical resistance. This resin is more hydrophobic and can provide better surface wetting. Can be cured with multiple types of curing agents (hardeners).

DlvnE 59 160-175 2,000-4,000 Lowviscositynovolacresinmodifiedwithacycloaliphaticpolyglycidylether(freeofanyorganic solvent) for high solids coating formulations with low volatile organic compound (vOC) emissions. Balance of properties similar to solvent-borne novolac.

DlvnE 60 166-176 1,100-1,9002 Lowviscositynovolacresinmodifiedwithacycloaliphaticpolyglycidylether(freeofanyorganicsolvent) that facilitates high solids coating formulations with low volatile organic compound (vOC) emissions, improved application, and strong chemical and thermal resistance.

DlvnE 61 155-170 4,500-6,500 Mediumlowviscositynovolacresinmodifiedwithacycloaliphaticpolyglycidylether(freeof any organic solvent) that facilitates high solids coating formulations with low volatile organic compound (vOC) emissions, improved application, and strong chemical and thermal resistance.

1All grades are 100% solids 2cSt @ 51.7 ºC


Temperature Recommendation Ranking Shore D Hardness Development of D.E.H.™ 622 at -5 ºC with Different D.E.R.™ Epoxy Resins

0

20

40

60

80

Curing Time [h]

Shor

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Har

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s

0 12 24 36 48

D.E.R.™ 3581

D.E.R.™ 3412D.E.R.™ 3531

Best-fit CurveBest-fit CurveBest-fit Curve

Shore D hardness development of D.E.H.™ 622) @ -5 °C with different D.E.R.™ EP-resins

15 ºC

10 ºC

5 ºC

0 ºC

D.E.H. 630

D.E.H.™ 487

D.E.H. 488

D.E.H. 489

D.E.H. 619

D.E.H. 614

D.E.H. 2955

D.E.H. 4060

D.E.H. 615

D.E.H. 622

Industrial Hygiene Many fast curing agents are based on condensation products of amine, formaldehyde and some alkyl phenol compound, so-called Mannich base curing agents. Most of the alkyl phenol compounds are to be labeled with Risk-phrase R-62: “Possible Risk of Impaired Fertility.”

In order to overcome exposure risk for employees working with such types of Mannich base curing agents, Olin Epoxy offers D.E.H.™ 630 curing agent. D.E.H. 630 curing agent is a special grade of low temperature curing agent that is also completely VOC- and alkyl phenol-free while meeting low emission standards.

As Mannich base hardeners are based on phenolic raw material, color and color stability upon UV exposure is often a problem. D.E.H. 630 curing agent offers not only low emission, favorable labeling and fast cure but also improved chemical resistance and UV resistance as shown below.

On the left is a typical clear casting based on liquid epoxy resin and cured with D.E.H. 614 curing agent partially exposed to UV radiation (lower portion). On the right, similar testing is shown using D.E.H. 630 curing agent resulting in almost no discoloration.

ImprovedEH&Sprofile

D.E.H.™ 630Curing Agent

Rapid curing

Greater UVresistance

Higherchemicalresistance


Modified Polyamide Curing AgentsD.E.H.™ 1450 • •D.E.H. 1501 •D.E.H. 1911 • •Modified-Amine Curing AgentsD.E.H. 2102 •D.E.H. 2112 •D.E.H. 2122 •D.E.H. 2132 •D.E.H. 2450 • • •D.E.H. 2497 • • •D.E.H. 262 • •D.E.H. 2920 • •D.E.H. 2955 • •Modified Epoxy - Amine AdductsD.E.H. 4043 • • •D.E.H. 4060 •D.E.H. 4147 •D.E.H. 4353 • • • •D.E.H. 4354 • • • •D.E.H. 444 • • •D.E.H. 445 • • •D.E.H. 4702 • • •D.E.H. 4712 • •D.E.H. 4723 •D.E.H. 487 • • • •D.E.H. 488 • • •D.E.H. 489 • • • •D.E.H. 4911 • • •D.E.H. 4912 • • •Low Temperature Curing AgentsD.E.H. 614 •D.E.H. 615 • • •D.E.H. 619 • • •D.E.H. 622 • • •D.E.H. 630 • • •Waterborne Epoxy Curing AgentsD.E.H. 800 • •D.E.H. 804 •D.E.H. 805 • •D.E.H. 806 •D.E.H. 813 • •D.E.H. 860 • •

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Setting Projects Up for Success Curing Agents for Your Building & Construction Applications Olin’s epoxy products are available for a wide range of civil engineering, infrastructure and other building and construction applications. Selection of the proper epoxy curing agents is the starting point for development of formulations with the viscosity, reactivity, pot life, cure rate, chemical resistance, wear resistance, adhesion, flexibility and other properties required to meet your specific formulating, application and end-use requirements. Use this chart to identify curing agents best suited for your application needs.

EMEA Curing Agents Selection Guide


Olin Curing Agent Portfolio For Civil Engineering Applications Available in EMEA

Grade AHEW (gr/eq)

Viscosity @25 °C (mPa•s)

pot Life min. (with

Reference Resin)

Reference Resin Description

Modified Amine Curing Agents

D.E.H.™ 2102 41 8-18 125 D.E.R.™ 3272 Recommendedformineralcastingsorheavy-filledmortars.Offers low exothermic reaction and high heat resistance.

D.E.H. 2112 45 8-18 26 D.E.R. 3271Recommended system, with D.E.R. 3271 epoxy resin, for mineralcastingsorheavy-filledmortars.Offerslowexothermand high heat resistance.

D.E.H. 2122 45 15-35 110 D.E.R. 3271 Recommendedformineralcastingsorheavy-filledmortars.Offers low exothermic reaction and high heat resistance.

D.E.H. 2132 45 5-25 >120 D.E.R. 331 very slow, low exotherm curing agent for mineral castings, compositesandhighlyfilledmortars.

D.E.H. 2450 58 13-23 30 D.E.R. 3113 Fast curing for crack-injection systems D.E.R. 3113 epoxy resin.

D.E.H. 2497 76 30-100 100 D.E.R. 331 low viscosity; offers long pot life. it is used as a blending/curing agent.

D.E.H. 262 87 30-70 25 D.E.R. 331 Lowviscosity,alkylphenol-freecuringagentforhighlyfilledmortars, coatings and screeds.

Modified Epoxy Amine Adducts

D.E.H. 4043 115 290-450 40 D.E.R. 331Offers good color and light stability, as well as tack-free surfaces and excellent early water resistance. D.E.H. 4702 has similar performance properties but is nonyl-phenol-free.

D.E.H. 4060 122 5,000-7,000 30 D.E.R. 331 Offers best-in-class chemical resistance in combination with food contact compliance.

D.E.H. 4147 75 150-300 30 D.E.R. 331 Offers very good Uv-stability with only a low tendency to yellowing. Especially suitable for color quartz and paints.

D.E.H. 4353 93 80-180 50 D.E.R. 331Universal curing agent offering a long pot life. Suitable for adhesives,highlyfilledcoatingsystems,mortarsandscreeds.D.E.H. 487 is a nonyl-phenol-free version.

D.E.H. 4354 95 150-350 25 D.E.R. 331 Universal curing agent offering a faster reactivity. D.E.H. 488 and D.E.H. 489 are equivalent nonyl-phenol-free versions.

D.E.H. 444 93 160-220 105 D.E.R. 331 longer pot life curing agent with good Uv stability.

D.E.H. 445 105 370-570 45 D.E.R. 331 low viscosity curing agent with good Uv stability and overall mechanical and chemical resistance properties.

D.E.H. 4702 115 370-470 40 D.E.R. 331 Excellent early water-spot resistance combined with high acid and solvent resistance.

D.E.H. 4712 87 1,600-2,400 20 D.E.R. 3581 Offers systems with good Uv stability for paints and coatings, aswellasfloorings.

D.E.H. 4723 120 750-1,150 55 D.E.R 3911Recommended for elastic intermediate layers, especially when used in combination with D.E.R. 3911. Provides very high flexibilitywithelongationatbreakaround200%.

D.E.H. 487 93 170-270 41 D.E.R. 331 longer pot life version of D.E.H. 488 curing agent.

D.E.H. 488 93 280-380 25 D.E.R. 331 low viscosity curing agent for liquid epoxy resins. good blush resistance and general chemical resistance.

D.E.H. 489 93 210-290 20 D.E.R. 331 Accelerated version of D.E.H. 488 curing agent.


Grade AHEW (gr/eq)


pot Life min. (with

Reference Resin)

Reference Resin Description

Modified Polyamide Curing Agents

D.E.H. ™ 1450 115 600-1,400 60 D.E.R.™ 331 Excellent adhesion on critical (badly prepared or wet/humid) substrates. Contains alkyl phenol.

D.E.H. 1501 63 70-170 70 D.E.R. 331 Formulated polyamide for washable tile-grouts.

Low Emission Curing Agents

D.E.H. 1911 115 1,100-1,700 70 D.E.R. 3531 low emission curing agent particularly suited for the development of primerswheneverthesubstrateiswetordifficulttoadhereto.

D.E.H. 2920 76 40-120 50 D.E.R. 3531 low emission curing agent. Offers a long working time (long pot-life) and a quick Shore D hardness development.

D.E.H. 2955 82 1,400-1,700 6 D.E.R. 3581Offers very rapid curing and is highly suitable for anchoring systems or as accelerator. Suitable for primers if curing is required at temperatures down to -5 °C.

D.E.H. 4911 82 360-460 50 D.E.R. 3531 Fully reactive curing agent containing no vOC and no alkyl phenol. good mechanical properties.

D.E.H. 4912 84 280-480 40 D.E.R. 3531 Fully reactive curing agent containing no vOC and no alkyl phenol. Shows low exothermic reaction.

Low Temperature Curing Agents

D.E.H. 614 85 450-750 15 D.E.R. 331 Solvent-free, Mannich base curing agent curing down to about 0 °C. High water and chemical resistance.

D.E.H. 615 75 400-500 15 D.E.R. 331 low viscosity version of D.E.H. 614 curing agent. Over-coatable after 4 hours (industrial coatings).

D.E.H. 619 92 820-1,200 52 D.E.R. 3261 VOC-free,modifiedMannichbasecuringagentforimprovedchemical resistance.

D.E.H. 622 60 490-690 6 D.E.R. 331 Modifiedaminecuringagentwithextremehighreactivity.Curesdown to -5 °C.

D.E.H. 630 73 700-900 14 D.E.R. 3531Highly reactive (non-Mannich base) curing agent with an improved EH&Sprofile,betterchemicalresistanceandUVstabilityovertraditional Mannich base curing agents.


Experience the Benefits of Waterborne Epoxy Technology Olin Epoxy is pushing waterborne technology to new levels. The solvent-free nature of these products can help formulators meet stringent VOC regulations, including ultra-low-VOC formulations, in the development of high-performance coatings.

Olin waterborne epoxies perform almost as well as solvent-borne technologies, providing formulators with the opportunity to approach solvent-level performance while also meeting environmental goals.

Waterborne epoxy product benefits include:• Solvent-free formulation capability

• Easy mixing with other waterborne components

• Manufactured without the use of APEO1 surfactants

• Low odor

• Shear stable

• Easy water clean-up

• High gloss

• Early hardness

• Good abrasion

• Chemical resistance

• Freeze stable (curing agents)

Typical Properties – Waterborne Epoxy Resin Emulsions and Dispersions Available in EMEA Olin offers various epoxy resin dispersions and emulsions that are available as 100% VOC-free waterborne product with very low particle size and very narrow distribution. The standard shelf-life of Olin’s epoxy resin emulsions and dispersions is 12 months when stored appropriately (see SDS).

Typical Properties – Waterborne Epoxy Curing Agents Available in EMEA All Olin waterborne epoxy curing agents are solutions in water and subsequently freeze stable when stored under appropriate conditions (see SDS).

Grade EEW (gr/eq)on Solids


Solids (wt%) Description

D.E.R.™ 913 167-193 100-400 67 liquid epoxy resin emulsion with improved reactivity, designed for 2-component coating systems.

D.E.R. 915 475-500 3,000-9,000 47Waterborne dispersion of “1-type” solid epoxy resins for 2-component coating systems. Offers good corrosion protection on steel as well as fast-drying on mineral substrates.

D.E.R. 917 193-204 3,000-9,000 64liquid epoxy emulsion designed for use in waterborne 2-pack coating systems. Also used as cross-linking agent for other aqueous (acrylic) systems.

Grade AHEW (gr/eq) on Solids


Solids (wt%) Description

D.E.H.™ 800 150 5,000-10,000 50Aqueouspolyamineadductsolutionwithemulsificationcapability.Offersvisible end of pot life, excellent chemical, corrosion resistance and excellent gloss potential.

D.E.H. 804 123 5,000-11,000 70Aqueouspolyamineadductsolutionwithemulsificationcapability.Offersvisible end of pot life, fast drying, low odor. Suitable for thick layer self- leveling applications.

D.E.H. 805 143 10,000-18,500 65 Aqueouspolyamineadductsolutionwithemulsificationcapability.Offersvisible end of pot life, low odor, fast drying and through hardening.

D.E.H. 806 160 9,500-15,500 80Aqueouspolyamineadductsolutionwithemulsificationcapability.Designed for anti-corrosion applications in combination with epoxy dispersions. Compatible with zinc-phosphate anti-corrosion pigments.

D.E.H. 813 140 5,000-10,000 70

Aqueouspolyamineadductsolutionwithemulsificationcapability.Designed for fast drying anti-corrosion applications in combination with epoxy dispersions. Compatible with zinc-phosphate anti-corrosion pigments.

D.E.H. 860 105 25,000-50,000 50 Aqueouspolyamidesolutionwithemulsificationcapability.Suitableforimpregnation and sealing of concrete substrates.


Olin Epoxy Resins for Building and Construction Available in EMEA Mechanical Strength and Increased Flexibility Olin offers a full range of liquid epoxy resins for room temperature curing applications on mineral substrates.

Below is an overview of the liquid epoxy resins used in the building and construction industry and available in EMEA. Corresponding technical and Safety Datasheets will be provided upon request.

Grade EEW (gr/eq)

Viscosity @25 °C (mPa•s) Description

Bisphenol A Epoxy Resins

D.E.R.™ 330 176-185 7,000-10,000LowerviscositybisphenolAepoxyresinallowingtheuseoffewerdiluentsormorefillersintheformulation. Offers longer pot life versus the standard resin and slightly improved resistance properties when used in heat curing (composite) applications.

D.E.R. 330-El 176-185 7,000-10,000 lower viscosity bisphenol A epoxy resin with very low hydrolysable chloride content (<100 ppm). Specificallysuitableforelectrical,electronicandencapsulationapplications.

D.E.R. 331 182-192 11,000-14,000industry standard bisphenol-A-based liquid epoxy resin. Offers excellent mechanical, thermal and chemical resistance properties in multiple applications. Shows improved reactivity and wetting properties versus competitive alternatives.

D.E.R. 331-El 182-192 11,000-14,000 Standard bisphenol-A epoxy resin with very low hydrolysable chloride content (<150 ppm). Specificallysuitableforelectrical,electronicandencapsulationapplications.

D.E.R. 336 181-185 9,400-11,000 Standard liquid bisphenol A epoxy resin of intermediate viscosity and equivalent weight with narrowspecificationlimits.

D.E.R. 336-El 181-185 9,400-11,000 intermediate viscosity epoxy resin with very low hydrolysable chloride content (<150 ppm). Specificallysuitableforelectrical,electronicandencapsulationapplications.

Modified Bisphenol A Epoxy Resins

D.E.R. 3113 178-197 250-350 Extreme low viscosity resin for crack injection and sealing.

D.E.R. 321 180-188 500-700Verylowviscosityresinallowinglargeamountsoffillers.Cureratesimilartoundilutedresins.Improvedacidresistancecanbeobserved.Forfloorings,grouting,concretereinforcement,structural adhesives, crack injection and castings.

D.E.R. 3221 187-208 700-1,000 liquid epoxy resin especially suitable for use in waterborne epoxy binder systems.

D.E.R. 324 195-204 600-800

Offers low viscosity and low surface tension to wet the surface better, giving better adhesionandslightlylowerviscosityatanygivenfillerloading.Thediluentincreasespotlife,flexibility(impactresistance)andacidresistance,butlimitsthesolventresistance.Pronetocrystallization.

D.E.R. 3271 156-170 250-450Offers low viscosity and low surface tension to wet the surface better, giving better adhesion andslightlylowerviscosityatanygivenfillerloading.Thediluentincreasespotlife,flexibility(impact resistance) and acid resistance, but limits the solvent resistance.

D.E.R. 3274 160-180 1,300-1,500 very low viscosity epoxy resin designed for mineral castings in combination with, e.g., D.E.H. 2112 epoxy curing agent.

D.E.R. 3282 173-183 900-1,100 Reactive diluent containing epoxy resin offering low viscosity, good mechanical properties as well as solvent resistance.

D.E.R. 3284 173-185 2,400-2,900Medium viscosity liquid epoxy resin with di-functional reactive diluent. Especially suited for lamination purposes where it shows excellent wetting of the fabric and gives outstanding mechanical properties.

Bisphenol A/F Epoxy Resins

D.E.R. 351 169-181 4,500-6,500Bisphenol A/F resin with very low tendency to crystallize. Applications include solvent-free coating,tank-andpipe-linings,concretereinforcementsandalsofloorings,adhesives,electricalinsulationandfilamentwinding.

D.E.R. 352 172-181 5,700-7,700 Higher viscosity and more economical bisphenol A/F liquid epoxy resin. Recommended base formanymodifiedbisphenolA/Fepoxyresins.

D.E.R. 356 176-183 6,500-8,000 Economical bisphenol A/F epoxy resin with enhanced reactivity.

NOTICE: No freedom from infringement of any patent or other intellectual property rights owned by Olin or others is to be inferred. Because use conditions and applicable laws may differ from one location to another and may change with time, Customer is responsible for determining whether products and the information in this document are appropriate for the Customer’s use and for ensuring that the Customer’s workplace and disposal practices are in compliance with applicable laws and other governmental enactments. Olin assumes no obligation or liability for the information in this document. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED.

© Olin Corporation 2015. All rights reserved.

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Grade EEW (gr/eq)

Viscosity @25 °C (mPa•s) Description

Modified Bisphenol A/F Epoxy Resins

D.E.R.™ 3531 183-199 750-1,150 low crystallization resin with low vapor pressure; hydrophobic in nature. Offers low viscosity and good wetting properties and is suitable for casting resin coatings and adhesives.

D.E.R. 3532 181-200 500-900 low crystallization resin with low vapor pressure; hydrophobic in nature. Offers very low viscosity and good wetting properties. Similar to D.E.R. 3531 in nature.

D.E.R. 3533 187-200 450-550 low crystallization resin with low vapor pressure; hydrophobic in nature. Offers extremely low viscosity and good wetting properties. Similar to D.E.R. 3531/3532 in nature.

D.E.R. 3551 184-193 700-1,100 Lowcrystallizationtendencymodifiedbisphenol-A/Fliquidepoxyresin.Offersexcellentwettingandisrecommendedforfloorings,mortars,groutsandadhesives.

D.E.R. 3552 167-178 400-600 Verylowviscosityepoxymodifiedepoxyresinwithfastcureandgoodmechanicalproperties.Forhighlyfillerssystems,crackinjectionsystemsorlowviscousprimers.

D.E.R. 3572 164-176 600-900 Liquidepoxyresin,modifiedwithadi-funtionalreactivediluent.Offersimprovedreactivity,bettermechanical properties as well as solvent resistance versus mono-functional aliphatic diluents.

D.E.R. 3581 169-180 900-1,400Liquidepoxyresin,modifiedwithalowervaporpressuredi-functionalreactivediluent.Offersimproved reactivity, better mechanical properties as well as solvent resistance versus mono-functional aliphatic diluents.

Accelerated Epoxy Resins

D.E.R. 3411 185-205 4,500-5,500 Accelerated, crystallization-stable liquid epoxy resin.

D.E.R. 3412 187-207 850-1,150 AcceleratedmodifiedbisphenolA/Fepoxyresinoflowviscosity.

Flexible Epoxy Resins

D.E.R. 3911 374-416 6,500-9,500 Flexible hybrid epoxy resin with elongation around 200% in combination with D.E.H.™ 4723. Recommended for elastic intermediate layers.

D.E.R. 3912 550-650 21,000-29,000 Aliphaticliquidepoxyresinflexibilizerforhighsolidsorsolvent-freecoatings.

D.E.R. 3913 345-365 7,500-9,500Flexible epoxy resin that offers high elongations at break at room temperature as well asat-20°C.Canbeusedwithstandardepoxyamineadductcuringagentsforflooringformulations in (freezing) cold areas.

D.E.R. 732 (P) 310-330 60-70 longer chain length polyglycol diepoxide liquid resin. Applications include coatings and adhesivesforimprovedflexibility,elongationandimpactresistance.

D.E.R. 736 (P) 175-205 30-60 Shorterchainpolyglycoldiepoxideliquidresinforimprovedflexibility,elongationandimpactresistance in coatings and adhesives.

Epoxy Resin Solutions

D.E.R. 671-X75 430-4802 7,500-11,500 Solution of D.E.R. 671 in xylene. industry standard for heavy duty anti-corrosion paints.

D.E.R. 684-EK40 2,800 min.2 600-2,5001

Solution of an ultra-high molecular weight epoxy resin. it has essentially no epoxy functionality and provides coatings with outstanding physical and chemical resistance properties by solvent evaporationalone.Mainapplicationsincludemaintenance-andflash-primers,shopcoats,wireenamels, road markers and clear coatings for brass, chrome and aluminum.

1 cSt 2On solids

Proven Protection Taken to New Heights

Dow Epoxy Industrial Coating Materials

pg 2

Dow Epoxy Industrial Coating Materials | April 2015

Coatings Innovation Derived from Experience and ExpertiseEpoxy technology is the fundamental building block for durable, high-performance coating technology used in diverse industries around the world.

Dow is an experienced innovator in epoxy technology, helping formulators develop robust solutions to meet society’s energy, transportation and infrastructure needs.

It has been that way for more than 50 years, and our longevity and dedication have yielded an impressive and broad portfolio of epoxy solutions. Looking ahead to the next 50 years, we’re closely following industry trends and are constantly reevaluating our product line to meet changing emissions and sustainability targets.

We’re proud of our past and excited about our future as we continue to provide a reliable global supply of innovative epoxy products and solutions for a changing world.

pg 3


Intense Focus on Industrial CoatingsFrom oil platforms to pipelines, from chemical processing plants to marine vessels and containers, each approach to protective coatings is unique. But no matter the asset, no matter the location, Dow Epoxy is at your side to help protect your investment.

Supported by a broad portfolio comprising the traditional as well as the innovative, Dow Epoxy enables formulators to provide a complete package: better performance with value-added features such as improved sustainability, broader application parameters and economical lifetime costs.

Dow Epoxy experts understand end-use applications and global markets. Our in-region experts appreciate the nuances of each situation and environment.

Dedicated to Continued InnovationNew challenges in the energy, infrastructure, petrochemical, manufacturing, industrial architecture, transportation and marine markets are driving the need for innovation.

And Dow Epoxy is delivering higher-performing technologies that respect the environment, perform in increasingly demanding conditions and provide value.

Dow Epoxy continues to boost our portfolio to meet these needs. Our research and development efforts are founded on three guiding principles: • Reduce environmental impact• Enhance durability• Lower system costs

Of course, we also understand that innovation sometimes means taking a new approach. Fortunately, innovation is not confined to the laboratory. We view collaboration as the key to optimizing technology and processes. It’s the best way we know to help formulators focus on creating the right solution for their customers – the first time and every time.

Industry Leading InnovationsDow Epoxy is rethinking the traditional approach to industrial epoxy coating with game-changing systems enabled by our low viscosity epoxies and novolacs, waterborne technologies, and high-performance powder coatings and hardeners.

In addition, Dow Epoxy possesses the global resources to develop specialty products to address specific local challenges.

pg 4


Waterborne Epoxies Dow Epoxy is pushing waterborne technology to new levels. The solvent-free nature of these products can help formulators meet stringent VOC regulations, including ultra-low VOC formulations, in the development of high-performance coatings.

Our waterborne epoxies have been shown to perform as well as solvent-borne technologies, giving formulators the opportunity to gain solvent-level performance while also meeting environmental and performance goals.

Waterborne Epoxy Benefits• Solvent-free formulation capability• Easy mixing with other waterborne components• Manufactured without the use of APEO1 surfactants• Low odor• Shear stable• Easy water clean-up• High gloss• Early hardness• Good abrasion• Chemical resistance• Freeze stable (curing agents)

Low Viscosity Epoxy and NovolacsHeavy-duty coating performance requirements call for high-performance epoxy solutions. Solvent-free, low-viscosity resins from Dow Epoxy can be used to achieve both high volume solids and high pigment concentration (PVC), while maintaining good application and metal protection properties.

Dow Epoxy’s low viscosity epoxies and novolacs are suited for applications in challenging environmental conditions such as low temperatures and high humidity. They can be used to formulate coatings for marine use, as well as for linings in chemical tanks. All of these are low viscosity liquid epoxy resins modified with a cycloaliphatic polyglycidyl ether (free of any organic solvent) that facilitate high solids coating formulations with low volatile organic compound (VOC) emissions, while minimizing compromises in performance. They can be cured with multiple types of curing agents (hardeners).

Dow Epoxy low-viscosity technologies can overcome many of the disadvantages inherent in current high-solids systems. In particular, Dow Epoxy technologies can combine ease of application using conventional spray equipment and demonstrate similar performance compared to traditional epoxy systems.

Typical Properties1

Low Viscosity Epoxy and Novolacs Benefits• Solvent-free formulation capability• Enables primers with excellent balance of:

- Application properties - Corrosion resistance - Chemical resistance

• High achievable volume solids and PVC• High sprayability• Long pot life• Exceptional cured coating properties• DLVNE™ products have higher chemical

and thermal resistance

Grade EEW (gr/eq)

Viscosity @25º C (mPa•s)

Description Availability by Region

DLVE™ 18 160-175 400-1,000 Low viscosity liquid epoxy resin modified with a cycloaliphatic polyglycidyl ether for high solids coating formulations with ultra low volatile organic compound (VOC) emissions and ease of application. Excellent corrosion protection and chemical resistance. Can be cured with multiple types of curing agents (hardeners).

EMEAI, NAA, LAA

DLVE 19 185-200 2,600-4,200 Low viscosity epoxy resin modified with a cycloaliphatic polyglycidyl ether for high solids coating formulations with low volatile organic compound (VOC) emissions, excellent application, corrosion and chemical resistance. Can be cured with multiple types of curing agents (hardeners).

EMEAI, NAA, LAA

DLVE 52 165-180 350-550 Ultra low viscosity epoxy resin modified with a cycloaliphatic polyglycidyl ether (free of any organic solvent) for high solids coating formulations with low volatile organic compound (VOC) emissions, excellent application, corrosion and chemical resistance. This resin is more hydrophobic and can provide better surface wetting. Can be cured with multiple types of curing agents (hardeners).

EMEAI, NAA, LAA

DLVNE 59 160-175 2,000-4,000 Low viscosity novolac resin modified with a cycloaliphatic polyglycidyl ether (free of any organic solvent) for high solids coating formulations with low volatile organic compound (VOC) emissions. Balance of properties similar to solvent-borne novolac.

EMEAI, NAA, LAA

DLVNE 60 166-176 1,100-1,9002 Low viscosity novolac resin modified with a cycloaliphatic polyglycidyl ether (free of any organic solvent) that facilitates high solids coating formulations with low volatile organic compound (VOC) emissions, improved application, and strong chemical and thermal resistance.

EMEAI, NAA, LAA

DLVNE 61 155-170 4,500-6,500 Medium low viscosity novolac resin modified with a cycloaliphatic polyglycidyl ether (free of any organic solvent) that facilitates high solids coating formulations with low volatile organic compound (VOC) emissions, improved application, and strong chemical and thermal resistance.

EMEAI, NAA, LAA

1All grades are 100% solids 2cSt @ 51.7ºC

1Alkyl phenol ethoxylates

pg 5


Typical Properties – Waterborne Epoxy Resins


Viscosity @25°C (mPa•s)

Solids (wt%)


D.E.R.™ 900 193-204 NA 64 Liquid epoxy emulsion designed for use in waterborne 2-pack coating systems. Is also used as cross-linking agent for other aqueous (acrylic-) systems.

APAC

D.E.R. 913 167-193 100-400 67 Liquid epoxy resin emulsion with improved reactivity, designed for 2-component coating systems.

EMEAI

D.E.R. 915 475-500 3,000-9,000 47 Waterborne dispersion of “1-type” solid epoxy resins for 2-component coating systems. Offers good corrosion protection on steel as well as fast-drying on mineral substrates.

EMEAI, NAA, LAA

D.E.R. 916 184-204 5,000-10,000 58 Semi-solid epoxy novolac resin dispersion designed for 2-component coating systems. Can produce highly cross-linked matrices, providing excellent heat and chemical resistance similar to solvent-borne novolac systems.

EMEAI, APAC, LAA

D.E.R. 917 193-204 3,000-9,000 64 Liquid epoxy emulsion designed for use in waterborne 2-pack coating systems. Is also used as cross-linking agent for other aqueous (acrylic-) systems.

EMEAI, NAA, LAA

D.E.R. 925 455-480 1,300-3,000 55 Waterborne dispersion of “1-type” solid epoxy resins with increased solids content. Offers good corrosion protection on steel as well as fast-drying on mineral substrates.

NAA, LAA

Typical Properties – Waterborne Curing Agents

Grade AHEW on Solids (gr/eq)


Solids (wt%)


D.E.H.™ 805 143 10,000-18,500 65 Aqueous polyamine adduct solution with emulsification capability. Offers visible end of pot life, low odor, fast drying and through hardening.

EMEAI, NAA

D.E.H.806 160 9,500-15,500 80 Aqueous polyamine adduct solution with emulsification capability. Designed for anti-corrosion applications in combination with epoxy dispersions. Compatible with zinc-phosphate anti-corrosion pigments.

EMEAI, APAC

D.E.H. 810 150 2,000-4,000 50 Aqueous polyamine adduct solution with emulsification capability. Offers low viscosity, long pot life and excellent coatings properties.

EMEAI, NAA

D.E.H. 813 140 5,000-10,000 70 Aqueous polyamine adduct solution with emulsification capability. Designed for fast drying anti-corrosion applications in combination with epoxy dispersions. Compatible with zinc-phosphate anti-corrosion pigments.

EMEAI, APAC

pg 6


Typical Properties – High-Performance Powder Curing Agents

Grade OHEW (gr/eq) Softening Point (°C)


D.E.H.™ 90 240-270 76-84 Phenolic curing agent for fast cure combined with superior adhesion under humid conditions. Suitable also for low application temperature applications in combination with D.E.R. 6615 solid epoxy resin.

Globally

Typical Properties – High-Performance Powder Coatings Resins

Grade EEW (gr/eq)

Softening Point (°C)


FORTEGRA™ 104 960-1,060 – Specialty “4-type solid” epoxy resin with improved toughness and impact resistance designed for fusion bonded epoxy abrasion resistant overcoats.

APAC, LAA, NAA

FORTEGRA 304 920-1,090 105-115 Specialty solid resin designed to improve flexibility and impact resistance of fusion bonded epoxy coatings.

APAC, LAA, NAA

FORTEGRA 310 400-450 105-117 Specialty resin designed to improve flexibility and impact resistance of fusion bonded epoxy coatings with high glass transition temperature (up to 170 °C).

APAC, LAA, NAA

D.E.R.™ 664HA 750-850 105-115 Chemically modified medium molecular weight solid epoxy resin offering significantly improved hot/wet adhesion and cathodic disbondment.

EMEAI, NAA

D.E.R. 6615 500-550 78-86 Low application temperature cure, down to approximately 110 °C, solid epoxy resin. Based on Dow patented process technology that allows combination of low melt viscosity whilst retaining sufficiently high softening point.

Globally

D.E.R. 6508 380-420 95-105 Specialty resin designed for high glass transition temperature fusion bonded epoxy coatings (up to 150 °C).

Globally

D.E.R. 6510 HT 410-440 105-114 Specialty resin designed for high glass transition temperature fusion bonded epoxy coatings (up to 170 °C).

Globally

High-Performance Powder Coatings

Dow’s high-performance coating products are strong enough to address the toughest coating challenges while also meeting stringent environmental requirements. Ideal for high-temperature and high-stress applications, these inherently VOC-free products offer increased adhesion and increased durability to help resist corrosion.

High-Performance Powder Coatings Benefits

• Inherently VOC-free

• Enable increased adhesion

• Increased durability

• High corrosion resistance

pg 7


Other Regional SolutionsWhatever the challenge, wherever you are located, Dow Epoxy can help develop solutions that meet specific temperature and flexibility requirements and faster return to service, among other demands.

Typical Properties – Regionally Specific Resins

Typical Properties – Regionally Specific Curing Agents

Grade EEW (gr/eq) Viscosity @25°C (mPa•s)


D.E.R.™ 301 245-265 10,000-14,000Modified liquid epoxy resin; compared with standard bisphenol A based liquid epoxy resin, similar viscosity, improved flexibility, longer pot life and anti-corrosion performance; suitable for high solids (80% volume solid above) formulation.

APAC

D.E.R. 3401 175-215 1,500-3,500 Low viscosity rapidly reacting bisphenol A/F epoxy resin designed for fast-curing coatings, adhesives and mortars. It can be used as the sole epoxy or in combination with other epoxy resins. Benefits include rapid cure, return to service, low emissions or substance of concern content, low viscosity and good chemical resistance.

NAA

Grade AHEW (gr/eq)


Pot Life, min (with Reference Resin)

Reference Resin


D.E.H.™ 125 120 8,000-12,0001 NA NAStandard polyamide. Excellent adhesion to various substrates. Recommended for anti-corrosion coatings, concrete primer and adhesives.

APAC

D.E.H.140 95 10,000-20,000 NA NA

Standard polyamide. Lower viscosity, higher chemical resistance, excellent adhesion to various substrates, good balance in performances. Recommended for adhesives and anti-corrosion coatings.

APAC

D.E.H. 5902 83 1,600-1,800 38 D.E.R. 354 Excellent resistance to sulfuric acid (50% to 98%). Epoxy novolacs resins (D.E.R. 354, D.E.N. 425 or D.E.N. 431) need to be used for 98% sulfuric acid resistance application. Good chemical resistance to concentrated hydrochloric acid.

NAA, APAC

D.E.H.™ 5912 65 60-80 33 D.E.R. 354 Excellent acid resistance properties similar to D.E.H. 590 but with improved blush resistance and coating appearance.

NAA

140ºC 2Includes NAA exempt solvents

pg 8


Liquid Epoxy Resins

Our Complete PortfolioDow is committed to the successful development of protective coatings that stand up to the harshest conditions. We’re here to assist you during each stage of the formulation process. The following overview of our complete portfolio of resin products and hardeners can be used to compare options and determine which combination provides the required performance for your application.

These are the same products that have been trusted by formulators for decades, and can be reliably supplied nearly anywhere in the world.

For more information about any of these products, or to learn more about how Dow Epoxy can provide the products and support you need to strengthen your system differentiation and competitive position, contact your Dow Epoxy representative.



Bisphenol A Epoxy Resins

D.E.R.™ 330 176-185 7,000-10,000 Lower viscosity bisphenol-A epoxy resin allowing the use of less diluents or more fillers in the formulation. Offers longer pot life versus the standard resin and slightly improved resistance properties when used in heat curing (composite) applications.

EMEAI, NAA

D.E.R. 331™ 182-192 11,000-14,000 Industry standard bisphenol-A based liquid epoxy resin. Offers excellent mechanical, thermal and chemical resistance properties in multiple applications. Shows improved reactivity and wetting properties versus competitive alternatives.

Globally

D.E.R. 336 181-185 9,400-11,000 Standard liquid bisphenol-A epoxy resin of intermediate viscosity and equivalent weight with narrow specification limits.

EMEAI

D.E.R. 337 230-250 400-8001 Intermediate epoxy equivalent weight semi-solid epoxy resin, mainly used in adhesives and protective coatings, or as a modifier for other epoxy resins to improve impact strength, extensibility and adhesion.

EMEAI

D.E.R. 383 176-183 9,000-10,500 Lower viscosity bisphenol-A epoxy resin allowing the use of fewer diluents or more fillers in the formulation. Offers longer pot life versus the standard resin and slightly improved resistance properties when used in heat curing (composite) applications.

NAA, APAC, LAA

Modified Bisphenol A Epoxy Resins

D.E.R. 317 192-203 16,000-25,000 High viscosity, fast reacting (20% faster than D.E.R. 331) liquid epoxy resin designed for adhesive applications requiring quick gelling with amine curing agents.

NAA

D.E.R. 321 180-188 500-700 Very low viscosity resin allowing large amounts of fillers. Cure rate similar to undiluted resins. Improved acid resistance can be observed. For floorings, grouting, concrete reinforcement, structural adhesives, crack injection and castings.

EMEAI, NAA, LAA

D.E.R. 3212 179-193 750-1,400 Similar to D.E.R. 321 epoxy resin but of higher viscosity, maintaining more mechanical strength.

NAA, LAA

D.E.R. 322 183-193 5,500-8,500 Low diluent content resin combining significant viscosity reduction whilst maintaining mechanical strength properties.

NAA

D.E.R. 323 190-204 1,000-1,200 Low viscosity liquid epoxy resin with reduced surface tension. Offers excellent wetting and flow. The low diluent content is the cause of the improved mechanical properties over D.E.R. 324 epoxy resin.

NAA

170 wt% in diethylene glycol monobutyl ether

pg 9


Grade EEW (gr/eq)



Modified Bisphenol A Epoxy Resins , cont.

D.E.R.™ 324 195-204 600-800 Offers low viscosity and low surface tension to wet the surface better, giving better adhesion and slightly lower viscosity at any given filler loading. The diluent increases pot life, flexibility (impact resistance) and acid resistance, but limits the solvent resistance. Prone to crystallization.

Globally

D.E.R. 325 185-206 850-2,800 Low viscosity liquid epoxy resin with reduced surface tension. Offers excellent wetting and flow. The low diluent content is the cause of the improved mechanical properties over D.E.R. 323 and D.E.R. 324 epoxy resin.

NAA

D.E.R. 3274 160-180 1,300-1,500 Bi-functional reactive diluent containing resin offering reduced viscosity while only affecting the mechanical and thermal properties moderately.

EMEAI, NAA, LAA

D.E.R. 362 185-205 4,500-6,500 Chemically modified liquid epoxy resin without diluent. Offers excellent flow and high gloss coatings/floorings. This resin is used in building applications above and below ground, on road and bridge construction, as well as in underwater applications.

NAA

Bisphenol A/F Epoxy Resins

D.E.R. 351 169-181 4,500-6,500 Bisphenol A/F resin with very low tendency to crystallize. Applications include solvent-free coating, tank- and pipe-linings, concrete reinforcements and also floorings, adhesives, electrical insulation and filament winding.

EMEAI, APAC

D.E.R. 352 172-181 5,700-7,700 Higher viscosity and more economical bisphenol A/F liquid epoxy resin. Recommended base for many modified bisphenol A/F epoxy resins.

EMEAI

D.E.R. 356 176-183 6,500-8,000 Economical bisphenol A/F epoxy resin with enhanced reactivity. EMEAI

Modified Bisphenol A/F Epoxy Resins

D.E.R. 353 190-200 800-1,000 Low viscosity epoxy resin with very low crystallization tendency. Offers low surface tension to wet the surface better, giving better adhesion. The diluent increases pot life, flexibility (impact resistance) and acid resistance.

NAA, APAC, LAA

D.E.R. 3531 183-199 750-1,150 Low crystallization resin with low vapor pressure and hydrophobic in nature. Offers low viscosity and good wetting properties and is suitable for casting resin, coatings and adhesives.

EMEAI

D.E.R. 3581 169-180 900-1,400 Liquid epoxy resin, modified with a lower vapor pressure di-functional reactive diluent. Offers improved reactivity, better mechanical properties as well as solvent resistance versus mono functional aliphatic diluents.

EMEAI

Bisphenol F Epoxy Resins

D.E.R. 354 167-174 3,400-4,200 Unmodified bisphenol F-based epoxy resin of low viscosity. Improves crystallization resistance of other epoxy resins and gives improvement in solvent resistance. Frequently used in solvent-free coatings, floor coverings, adhesives or composite applications.

NAA, LAA, APAC

Flexible Epoxy Resins

D.E.R. 3912 550-650 21,000-29,000 Aliphatic liquid epoxy resin flexibilizer for high solids or solvent-free coatings. EMEAI, APAC

D.E.R. 732 (P) 310-330 60-70 Longer chain length polyglycol diepoxide liquid resin. Applications include coatings and adhesives for improved flexibility, elongation and impact resistance.

Globally

D.E.R. 736 (P) 175-205 30-60 Shorter chain polyglycol diepoxide liquid resin for improved flexibility, elongation and impact resistance in coatings and adhesives.

Globally

D.E.R. 750 176-186 2,500-4,500 Flexibilized epoxy resin suitable for civil engineering compounds (crack bridging), adhesives or for improvement of the toughness of fiber reinforced composites.

NAA

D.E.R. 791 255-275 28,000-34,000 Toughened epoxy resin with good cold elasticity and good curing rate. APAC

pg 10


Epoxy Toughening Agents and Toughened Epoxy Resins

Epoxy Novolac Resins



FORTEGRA™ 100 NA 3,000-4,000 Low-viscosity toughening agent designed for use in amine-cured epoxy systems. NAA, APAC, LAA

FORTEGRA 102 345-374 4,000-8,000 Toughened bisphenol A liquid epoxy resin master-batch (50 wt%). Allows easy formulation into other liquid epoxy binder systems for composite as well as coating applications.

NAA, LAA

FORTEGRA 201 325-360 26,000-46,000 Elastomer-modified epoxy functional adduct designed to improve toughness of epoxy systems with minimal impact on thermo-mechanical properties. Offers improved fatigue resistance, thermal shock resistance, impact resistance, and peel and shear strength.

NAA, LAA

FORTEGRA 202 NA 4,500-8,000 Low-viscosity toughener based on innovative technology. Imparts adhesion, impact resistance and anti-corrosion resistance via nanometer size phase separation in curing matrix.

APAC

FORTEGRA 301 200-225 2,700-3,5001 Toughened liquid epoxy resin with core shell rubber particles. Offers improved toughness in coating and composite applications.

NAA, LAA

1at 50º

Grade EEW (gr/eq) on Solids



D.E.N.™ 425 169-175 9,500-12,500 Approximately 2.5 functional liquid epoxy novolac resin bridging between standard liquid epoxy resin and semi-solid epoxy novolac resins. When used in combination with a fast curing agent no post-cure is required and binder systems are obtained with excellent mechanical and especially solvent resistance properties.

Globally

D.E.N. 431 172-179 1,100-1,7001 Multi-functional (±2.8) epoxy novolac resin of lower molecular weight for application where solvents cannot be tolerated and application viscosity (temperature) needs to remain relatively low. Used in adhesives, electrical and structural laminates and castings for elevated temperature service and excellent chemical resistance.

Globally

D.E.N. 438™ 176-181 31,000-40,0001 Highly functional (±3.6) epoxy novolac resin offering best mechanical, temperature and chemical resistance performance with acceptable viscosity. Recognized as a standard for high-temperature applications.

Globally

D.E.N. 438L 176-181 27,500-32,5001 Low(er) viscosity version of D.E.N. 438 epoxy novolac resin to allow higher solids and/or lower viscosity formulations.

NAA

D.E.N. 438-A85 176-181 500-1,200 Solution of D.E.N. 438 in acetone mainly for laminating or prepreg applications. NAA, APAC

D.E.N. 438-EK85 176-181 600-1,600 Solution of D.E.N. 438 in methyl-ethyl ketone mainly for laminating or prepreg applications.

EMEAI, NAA, APAC

D.E.N. 438-MAK80 176-181 600-1,200 Solution of D.E.N. 438 in methyl n-amyl ketone mainly for laminating or prepreg applications.

NAA

D.E.N. 438-MK75 176-181 200-600 Solution of D.E.N. 438 in methyl iso-butyl ketone mainly for laminating or prepreg applications.

NAA

D.E.N. 438-X80 176-181 1,200-2,000 Solution of D.E.N. 438 in xylene. Main use in wet-paint systems with high temperature or chemical resistance requirements.

EMEAI, NAA, APAC

D.E.N. 439 191-210 15,000-35,0002 Highly functional (±3.8) epoxy novolac resin with improved reactivity. The higher viscosity offers a means of obtaining good drape and limited tack in prepreg formulations.

EMEAI, NAA, APAC

D.E.N. 439-EK85 191-210 4,000-10,000 Solution of D.E.N. 439 in methyl-ethyl ketone mainly for laminating or prepreg applications.

EMEAI, NAA, APAC

D.E.N. 440 187-192 50,000-90,0002 Extremely high functional (± 4.4) epoxy novolac resin. Offers highest performance in this product group with regards to mechanical, temperature and chemical resistance properties.

NAA

1at 51.7°C 2 at 71°C

pg 11


Brominated Resins

Solid Epoxy Resins




D.E.R.™ 530-A80 425-440 1,500-2,500 Standard brominated epoxy resin in acetone with about 20.5% bromine on solids. EMEAI, NAA

D.E.R. 538-A80 465-495 800-1,800 Brominated epoxy resin in acetone with about 20% bromine on solids. Offers less flow during lamination versus D.E.R. 530-A80 epoxy resin.

EMEAI, NAA

D.E.R. 539-EK80 430-470 NA Brominated epoxy resin in methyl ethyl ketone with about 20% bromine on solids. Offers enhanced UV-blocking and fluorescence.

EMEAI

D.E.R. 592-A80 350-370 1,000-2,400 Brominated epoxy resin in acetone with about 17% bromine on solids. Offers best dimensional stability and better chemical resistance that standard resins.

EMEAI, NAA

D.E.R. 593 350-370 400-1,100 Brominated epoxy resin in DOWANOL™ PM glycol ether with about 17 wt% bromine on solids. Allows quicker cure and higher Tg due to the large amount of catalyst that can be added.

EMEAI, NAA

Grade EEW (gr/eq)

Softening Point (ºC)


Low Molecular Weight Solids

D.E.R. 6116 520-560 80-90 Low molecular weight “1.5-type” epoxy resin offers excellent flow in standard and low temperature cure powder coating systems. Suggested in cases where D.E.R. 662E resin does not provide adequate flow.

NAA, APAC, LAA

D.E.R. 6224 675-725 88-98 Low molecular weight “2.5-type” epoxy resin specifically designed for decorative powders coatings requiring excellent gloss and flow.

NAA, APAC

D.E.R. 661 500-560 75-85 Unmodified standard “1-type” solid epoxy resin. Excellent base for many high quality chemical-resistant coatings withstanding exposure to corrosive atmospheres.

NAA, APAC, LAA

D.E.R. 662E 590-630 87-93 Standard “2-type” epoxy resin for excellent flow in standard as well as in low application temperature cure applications.

Globally

D.E.R. 662UH 675-750 90-98 Low molecular weight “2.5-type” epoxy resin for decorative powders coatings requiring excellent gloss and flow.

NAA, LAA

D.E.R. 671 475-550 75-85 Low molecular weight “1-type” solid epoxy resin designed for room temperature curing wet paints. Industry standard for heave duty anti-corrosion paints for which many solutions exists.

Globally

D.E.R. 692 660-720 87-97 Low molecular weight “2.5-type” epoxy resin for decorative powders coatings requiring excellent gloss and flow.

Globally

D.E.R. 692H 660-720 89-97 Low molecular weight “2.5-type” epoxy resin containing 2 wt% of a polyacrylate flow modifier. The flow modifier is different than in D.E.R. 692HB epoxy resin.

EMEAI, APAC

D.E.R. 692HB 660-720 89-97 Low molecular weight “2.5-type” epoxy resin containing 2 wt% of a polyacrylate flow modifier. The flow modifier is different than in D.E.R. 692HB epoxy resin.

EMEAI

Medium Molecular Weight Solids

D.E.R. 6155 1,250-1,400 105-125 Medium molecular weight “5 type” solid epoxy resin designed for powder coatings which require greater flexibility.

NAA, APAC, LAA

D.E.R. 663U 730-820 92-102 Medium molecular weight “3-type” epoxy resin for both pure epoxy and epoxy/polyester hybrid powder coatings requiring good gloss, smoothness and excellent flexibility.

NAA, APAC, LAA

D.E.R. 663UE 740-800 98-104 Medium molecular weight “3-type” epoxy resin for both pure epoxy and epoxy/polyester hybrid powder coatings requiring good gloss, smoothness and excellent flexibility.

Globally

D.E.R. 664 875-955 100-110 Medium molecular weight “4-type” epoxy resin containing an esterification catalyst. Esters prepared by reacting this resin with fatty acids have very consistent viscosities and acid values.

NAA, LAA

D.E.R. 664U 875-955 100-110 Medium molecular weight “4-type” epoxy resin for both decorative and functional coatings to provide improved viscosity characteristics and greater flexibility.

NAA, APAC, LAA

D.E.R. 664U-20 875-955 103-111 Medium molecular weight “4-type” epoxy resin for both decorative and functional coatings to provide improved viscosity characteristics and greater flexibility.

EMEAI

D.E.R. 664UE 860-930 104-110 Medium molecular weight “4-type” epoxy resin for both decorative and functional coatings to provide improved viscosity characteristics and greater flexibility.

Globally

pg 12


Solid Epoxy Resins, cont.

Grade EEW (gr/eq)

Softening Point (ºC)


Specialty Solids

D.E.R.™ 6225 650-725 87-95 Chemically modified bisphenol A solid epoxy resin for very high flow and gloss powder coating applications. Specifically suitable for thin film applications.

NAA, LAA

D.E.R. 6330-A10 780-900 98-106 Solid epoxy resin master-batch resin containing 10% wt of a silicone-free flow agent.

EMEAI, NAA, LAA

D.E.R. 640 840-940 93-103 Chemically modified epoxy resin with low surface tension offering excellent flow and pigment / substrate wetting.

EMEAI

D.E.R. 642U 520-560 92-98 Novolac modified solid resin for functional powder coatings. In combination with other resins provides excellent corrosion and chemical resistance combined with good mechanical properties. Typical applications include pipe coatings and internal drum linings.

NAA, APAC, LAA

D.E.R. 642U-20 500-560 89-97 Novolac modified solid resin for functional powder coatings. In combination with other resins provides excellent corrosion and chemical resistance combined with good mechanical properties. Typical applications include pipe coatings and internal drum linings.

EMEAI, APAC

D.E.R. 6670 1,600-1,900 115-125 Internally flexibilized solid epoxy resin designed for powder coatings for low diameter pipes.

EMEAI

D.E.R. 672U 750-850 110-120 Novolac modified, higher molecular weight solid epoxy resin for more flexible, corrosion resistant epoxy powder coating. Extra edge-coverage can be obtained by the addition of 10-50% of this resin grade to the pipe or internal drum lining formulation.

NAA, APAC, LAA

D.E.R. 672U-20 740-830 110-120 Novolac modified, higher molecular weight solid epoxy resin for more flexible, corrosion resistant epoxy powder coating. Extra edge-coverage can be obtained by the addition of 10-50% of this resin grade to the pipe or internal drum lining formulation.

EMEAI, APAC

D.E.R. 8230WS 770-860 82-92 Master batch resin for powder coatings. The siloxane flow modifier provides maximum transparency in clear powder coatings. Also the flow modifier provides good slip and mar resistance.

APAC

Grade EEW (gr/eq)

Viscosity @25°C in cSt1


High Molecular Weight Solids

D.E.R.™ 666E 1,350-1,650 1,500-2,200 Solid epoxy resin of the “6-type” particularly suited for higher solids can coatings.

EMEAI

D.E.R. 667-20 1,600-1,950 1,300-4,000 Higher reactivity, high molecular weight “7-type” solid epoxy resin. Suitable for metal decoration, interior and exterior can coatings, tube and drum linings, coil primers and many other industrial applications.

EMEAI, APAC

D.E.R. 667E 1,600-1,950 2,000-2,900 High molecular weight “7-type” solid epoxy resin with improved solution stability. Suitable for metal decoration, interior and exterior can coatings, tube and drum linings, coil primers and many other industrial applications.

Globally

D.E.R. 668-20 2,000-3,500 2,700-5,000 High molecular weight “8-type” epoxy resin designed for can and coil coatings. Offers improved flexibility versus equivalent 7-type epoxy resins.

Globally

D.E.R. 669-20 3,500-5,500 4,400-10,000 Highest molecular weight solid epoxy resin, of the “9-type,” for can and coil coatings. Offers enhanced reactivity versus the E-version.

Globally

D.E.R. 669E 2,500-4,000 4,500-10,000 Highest molecular weight solid epoxy resin, of the “9-type,” for can and coil coatings. Shows improved solution storage stability.

Globally

140 wt% in diethylene glycol monobutyl ether

pg 13


Epoxy Resin Solutions

Grade EEW on Solids (gr/eq)



D.E.R.™ 337-DA97 230-278 NA Solution of D.E.R. 337 with diacetone alcohol. NAA

D.E.R. 337-X80 230-260 500-1,200 Solution of D.E.R. 337 in xylene. The excellent resistance and physical properties for epoxy coal tar combinations and higher solids content marine coatings.

EMEAI, NAA

D.E.R. 337-X90 230-250 5,000-15,000 Solution of D.E.R. 337 in xylene. Higher solids content than D.E.R. 337-X80 epoxy resin solution. NAA

D.E.R. 338-X90 230-280 5,000-50,000 Solution of a semi-solid epoxy resin in xylene. NAA

D.E.R. 3680-X90(K) 230-270 1,200-3,200 Chemically modified low molecular weight epoxy resin in xylene. Offers lower viscosity allowing higher solids contents at similar corrosion protection properties. Improves lower temperature curing.

Globally

D.E.R. 660-B80 300-350 2,300-7,500 Semi-solid epoxy resin solution of D.E.R. 660 in butanol. NAA

D.E.R. 660-MAK80 300-350 1,000-1,500 Semi-solid epoxy resin solution of D.E.R. 660 in methyl n-amyl ketone. NAA

D.E.R. 660-PA80 300-350 1,500-4,500 Solution of D.E.R. 660 epoxy resin in propyl acetate. The solvent choice makes it possible to formulate coatings without solvents listed as Hazardous Air Pollutants.

NAA

D.E.R. 660-X80 300-335 3,500-7,000 Intermediate molecular weight epoxy resin in a xylene solution for high solids / build coatings. Combines the high solids and chemical resistance of liquid epoxy resins with the outstanding adhesion, flexibility and fast cure of higher molecular weight solid epoxy resin.

EMEAI, NAA, APAC

D.E.R. 661-A75 500-550 800-2,500 Low viscosity solution of D.E.R. 661 solid epoxy resin in acetone. NAA

D.E.R. 661-A80 475-575 3,500-8,500 Intermediate viscosity solution of D.E.R. 661 solid epoxy resin in acetone. NAA

D.E.R. 671-MAK75 425-550 3,000-15,000 Solution of D.E.R. 671 in methyl n-amyl ketone, for industrial protective coatings. NAA

D.E.R. 671-PM75 425-500 9,500-15,000 Solution of D.E.R. 671 in DOWANOL PM glycol ether, for industrial protective coatings. NAA

D.E.R. 671-T75 425-550 2,200-10,000 Solution of D.E.R. 671 in toluene, for industrial protective coatings. NAA

D.E.R. 671-X70 445-500 2,000-4,000 Solution of D.E.R. 671 in xylene. Industry standard for heavy duty anti-corrosion paint. NAA, APAC

D.E.R. 671-X75 430-480 7,500-11,500 Solution of D.E.R. 671 in xylene. Industry standard for heavy duty anti-corrosion paint. EMEAI, NAA, APAC

D.E.R. 671-XM75 425-550 2,500-9,000 Solution of D.E.R. 671 in xylene/methyl isobutyl ketone, for industrial protective coatings. NAA

D.E.R. 684-EK40 2,800 min. 600-2,5001 Solution of an ultra-high molecular weight epoxy resin. It has essentially no epoxy functionality and provides coatings with outstanding physical and chemical resistance properties by solvent evaporation alone. Main applications include maintenance- and flash-primers, shop coats, wire enamels, road markers and clear coatings for brass, chrome and aluminum.

EMEAI, NAA, APAC

1cSt

Solid Epoxy Curing Agents

Grade OHEW (gr/eq)

Softening Point (°C)


D.E.H.™ 80 245-275 83-90 Phenolic hardener containing curing catalyst and polyacrylate flow modifier of moderate reactivity. Phenolic curing agents offer excellent chemical and moisture/water resistance and improved flexibility compared to e.g., dicyandiamide curing agents.

Globally

D.E.H. 81 240-270 83-90 Phenolic curing agent of intermediate reactivity containing curing catalyst as well as a polyacrylate flow modifier. The intermediate reactivity makes D.E.H. 81 particularly suitable as starting base for product development.

Globally

D.E.H. 82 235-265 83-90 High reactivity phenolic curing agent containing curing catalyst as well as a polyacrylate flow modifier. Can be formulated in low temperature applications in combination with D.E.R. ™ 6615 solid epoxy resin.

Globally

D.E.H. 84 240-270 83-90 Phenolic curing agent of intermediate reactivity containing only curing catalyst. The lack of flow modifier allows formulation with alternative additives that could potentially cause compatibility problems.

Globally

D.E.H. 85 250-280 83-90Unmodified phenolic curing agent particularly suitable for optimizing the reactivity of hardeners such as D.E.H. 81, D.E.H. 82 or D.E.H. 84 phenolic curing agent.

Globally

D.E.H. 87 370-400 96-102 Unmodified, high molecular weight phenolic hardener for increased flexibility and good storage stability. Globally

pg 14


Epoxy Curing Agents

Typical Properties – Epoxy Curing Agents

Grade AHEW (gr/eq)

Viscosity @25°C

(mPa•s)

Pot Life min. (with Reference Resin)

Reference Resin


Modified Amine Curing Agents

D.E.H. ™ 20 21 4-8 25 D.E.R. ™ 331™ Short pot life curing agent on basis of diethylenetriamine (DETA).

NAA, APAC, LAA

D.E.H. 24 24 19.5-22.5 25 D.E.R. 331 Short pot life curing agent on basis of triethylenetetramine (TETA).

NAA, APAC, LAA

D.E.H. 26 27 50-60 27 D.E.R. 331 Similar to D.E.H. 24 Epoxy Curing Agent in application, it provides lower vapor hazard to workers due to its higher boiling point.

NAA, LAA

D.E.H. 29 29 200-300 24 D.E.R. 331 Economical mixture of linear, branched, and cyclic ethylene amines that offers higher flexibility and peel strength in applications where color is not a limitation.

NAA, APAC, LAA

D.E.H. 39 43 10-15 27 D.E.R. 331 Fast curing amine hardener based on amino-ethyl piperazine. Mostly used as accelerator for other curing agent.

NAA, LAA

D.E.H. 508 34 100-300 12 D.E.R. 331 Reactive low viscous curing agent with good chemical resistance and high strength.

LAA

D.E.H. 512 86 150-350 9 D.E.R. 331 Fast low viscosity curing agent with good flexibility and blush resistance.

LAA

D.E.H. 55 40-42 1,000-1,700 11 D.E.R. 331 Medium viscosity, room-temperature, accelerated curing agent that is good for systems requiring low color.

NAA, LAA

D.E.H. 58 28-32 85-130 15 D.E.R. 331 Room-temperature, low viscosity curing agent that is extremely reactive with liquid epoxy resins.

NAA, LAA

Modified Epoxy Amine Adducts

D.E.H. 4060 122 5,000-7,000 30 D.E.R. 331 Offers best in class chemical resistance in combination with food contact compliance.

Globally

D.E.H. 4129 108 700-1,000 20 D.E.R. 331 For high quality coatings and flooring with good UV stability, mechanical properties and increased impact resistance.

NAA, APAC, LAA

D.E.H. 444 93 160-220 105 D.E.R. 331 Longer pot life curing agent with good UV stability. EMEAI, NAA, LAA

D.E.H. 445 105 370-570 45 D.E.R. 331 Low viscosity curing agent with good UV stability and overall mechanical & chemical resistance properties.

EMEAI, NAA, LAA

D.E.H. 4702 115 370-470 40 D.E.R. 331 Excellent early water-spot resistance combined with high acid and solvent resistance.

Globally

D.E.H. 4712 87 1,600-2,400 20 D.E.R. 3581 Offers systems with good UV stability and is therefore suitable for paints and coatings as well as floorings.

Globally

D.E.H. 487 93 170-270 41 D.E.R. 331 Longer pot life version of D.E.H. 488 curing agent. EMEAI, NAA, LAA

D.E.H. 488 93 280-380 25 D.E.R. 331 Low viscosity curing agent for liquid epoxy resins. Good blush resistance and general chemical resistance.

EMEAI, NAA, LAA

D.E.H. 489 93 210-290 20 D.E.R. 331 Accelerated version of D.E.H. 488 curing agent. EMEAI, NAA, LAA

D.E.H. 52 42-47 5,000-7,500 18 D.E.R. 331 Viscous, room temperature curing agent that has a short pot life and convenient handling and mixing rates with liquid epoxy resins.

NAA, LAA

D.E.H. 530 112 300-400 43 D.E.R. 331 Rapid set, low temperature curing agent for high gloss, blush-free products with good mechanical, chemical and water spot resistance.

NAA,LAA

pg 15


Product AHEW (gr/eq)


Pot Life min. (with Reference

Resin)

Reference Resin


Modified Epoxy Amine Adducts, cont.

D.E.H.™ 534 120 500-1,000 18 D.E.R. ™ 331™ Rapid set, low temperature curing agent offering good corrosion protection and water spot resistance.

NAA, LAA

D.E.H. 536 116 750-1,250 14 D.E.R. 331 Low viscosity, low temperature curing agent for applications requiring high gloss and good color stability.

NAA, LAA

D.E.H. 554 86 60-80 38 D.E.R. 331 Low viscosity curing agent for applications requiring self-leveling with chemical, blushing and water spot resistance.

NAA, LAA

D.E.H. 581 95 250-600 9 D.E.R. 331 Low viscosity, low temperature curing agent for products with good color and light stability.

NAA, LAA

D.E.H. 595 75 1,000-1,500 16 D.E.R. 331 Very fast ambient and low temperature curing agent for non-blushing products with good water spot resistance, excellent chemical resistance, high gloss and high strength.

NAA, LAA

Modified Polyamide Curing Agents

D.E.H. 1450 115 600-1,400 60 D.E.R. 331 Excellent adhesion on critical (badly prepared or wet/humid) substrates. Contains alkyl phenol.

EMEAI, APAC, LAA

D.E.H. 545 115 400-650 39 D.E.R. 331 Polyamide curing agent offering excellent adhesion onto highly humid or wet substrates. Good corrosion protection and low viscosity.

NAA, LAA

Low Temperature Curing Agents

D.E.H. 613 90 900-1,300 10 D.E.R. 331 Shorter pot life version of D.E.H. 614 curing agent. NAA, APAC

D.E.H. 614 85 450-750 15 D.E.R. 331 Solvent-free, Mannich base curing agent curing down to about 0°C. High water and chemical resistance.

EMEAI, NAA

D.E.H. 615 75 400-500 15 D.E.R. 331 Low viscosity version of D.E.H. 614 curing agent. Over-coatable after 4 hours (industrial coatings).

EMEAI, NAA, APAC

D.E.H. 616 75 400-600 15 D.E.R. 331 Good cure rate above 0°C and high water resistance. NAA

D.E.H. 619 92 820-1,200 52 D.E.R. 3261 VOC-free, modified Mannich base curing agent for improved chemical resistance

EMEAI

D.E.H. 622 60 490-690 6 D.E.R. 331 Modified amine curing agent with extreme high reactivity. Cures down to -5°C.

Globally

D.E.H. 630 73 700-900 14 D.E.R. 3531 Highly reactive (non-Mannich base) curing agent with an improved EH&S profile, better chemical resistance and UV stability over traditional Mannich base curing agents.

EMEAI

Low Emission Curing Agents

D.E.H. 1911 115 1,100-1,700 70 D.E.R. 3531 Low emission curing agent particularly suited for the development of primers whenever the substrate is wet or difficult to adhere to.

EMEAI, LAA

D.E.H. 2955 82 1,400-1,700 6 D.E.R. 3581 Offers very rapid curing and is highly suitable for anchoring systems or as accelerator. Suitable for primers if curing is required at temperatures down to -5°C.

EMEAI

D.E.H. 4909 83 180-280 60 D.E.R. 3531 Free of benzyl alcohol, nonyl phenol, bisphenol A and any inert volatile compounds for low-emission flooring systems. Excellent wetting, long pot life and quick tack-free time.

NAA

D.E.H. 4911 82 360-460 50 D.E.R. 3531 Fully reactive curing agent containing no VOC and no alkyl phenol. Good mechanical properties.

EMEAI

D.E.H. 4912 84 280-480 40 D.E.R. 3531 Fully reactive curing agent containing no VOC and no alkyl phenol. Shows low exothermic reaction.

EMEAI, NAA

D.E.H. 4914 108 8,000-10,000 45 D.E.R. 331 Excellent corrosion resistance and impact resistance for wet paints on metallic substrates.

EMEAI

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EPOXY PRODUCTS FOR EMEA Civil EnginEERing APPliCATiOnS · Olin Epoxy Products for EMEA Civil Engineering Applications 6 Modified Polyamide Curing Agents D.E.H.™ 1450 • • D.E.H