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POPs Pesticides and Priority PollutantStandard Mixtures• POPs Pesticides “Dirty Dozen” Standard Mixtures• Priority Pollutant Standard Mixtures• HCH Standard Mixtures• Toxaphene Standard Mixtures

Cambridge Isotope Laboratories, Inc. (CIL) has long been the leader in development of isotopically labeled standards for use in trace and ultra-trace analysis of environmental pollutants. CIL continues this leading role by introducing the first ever comprehensive POPs pesticides standard mixtures for use in isotope dilution mass spectrometry analysis.

On May 17, 2004, the Stockholm Convention on Persistent Organic Pollutants entered into force with the objective to eliminate and/or restrict production and use of POPs of interest to the global community. The convention has defined 12 POPs of highest concern, called “The Dirty Dozen.” This list currently includes:

• Dioxins and furans• PCBs and hexachlorobenzene• Pesticides: aldrin, dieldrin, endrin, chlordane,

heptachlor, mirex, DDT and toxaphene.

While CIL has offered individual dioxin, furan, and PCB standards and standard mixtures for many years, as well as individual pesticide standards, our new POPs pesticides standard mixtures are designed to allow laboratories to use consistent, high quality, pre-formulated mixtures for analysis of these highest priority pollutants. CIL also offers extended priority pollutants standard mixtures, incorporating all thePOPs pesticides plus several other major pollutants ofconcern. For specific testing purposes, CIL also offersHCH-only and toxaphene-only standard mixes.

ENVIRONMENTAL CONTAMINANT STANDARDS

To place an order please contact CIL: t: 978.749.8000 1.800.322.1174 (North America) envsales@isotope.com

For international inquiries, please contact our International Customer Service Department at intlsales@isotope.com.

Cambridge Isotope Laboratories, Inc.

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POPs Pesticides and Priority Pollutant Standard Mixtures

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POPs Pesticides Standard Mixtures

ES-5348 POPs Pesticides Calibration Solutions CS1-CS6 (unlabeled/13C, 99%) 6 x 0.2 mL nonane

(all concentrations in ng/mL)

Unlabeled analyte CS1 CS2 CS3 CS4 CS5 CS6

Hexachlorobenzene 0.4 2 10 40 200 800

Aldrin 0.4 2 10 40 200 800

Dieldrin 0.4 2 10 40 200 800

Endrin 0.4 2 10 40 200 800

4,4’-DDT 0.4 2 10 40 200 800

4,4’-DDE 0.4 2 10 40 200 800

4,4’-DDD 0.4 2 10 40 200 800

2,4’-DDT 0.4 2 10 40 200 800

2,4’-DDE 0.4 2 10 40 200 800

2,4’-DDD 0.4 2 10 40 200 800

trans-Chlordane (gamma) 0.4 2 10 40 200 800

cis-Chlordane (alpha) 0.4 2 10 40 200 800

trans-Nonachlor 0.4 2 10 40 200 800

cis-Nonachlor 0.4 2 10 40 200 800

Oxychlordane 0.4 2 10 40 200 800

Heptachlor 0.4 2 10 40 200 800

trans-Heptachlor Epoxide 0.4 2 10 40 200 800

cis-Heptachlor Epoxide 0.4 2 10 40 200 800

Mirex 0.4 2 10 40 200 800

alpha-BHC 0.4 2 10 40 200 800

beta-BHC 0.4 2 10 40 200 800

Lindane 0.4 2 10 40 200 800

delta-BHC 0.4 2 10 40 200 800

Cleanup Spike

Hexachlorobenzene-13C620 20 20 20 20 20

Aldrin-13C1220 20 20 20 20 20

Dieldrin-13C1220 20 20 20 20 20

Endrin-13C1220 20 20 20 20 20

4,4’-DDT-13C1220 20 20 20 20 20

4,4’-DDE-13C1220 20 20 20 20 20

4,4’-DDD-13C1220 20 20 20 20 20

2,4’-DDT-13C1220 20 20 20 20 20

2,4’-DDE-13C1220 20 20 20 20 20

2,4’-DDD-13C1220 20 20 20 20 20

trans-Chlordane (gamma)-13C10 20 20 20 20 20 20

trans-Nonachlor-13C10 20 20 20 20 20 20

cis-Nonachlor-13C1020 20 20 20 20 20

Oxychlordane-13C1020 20 20 20 20 20

Heptachlor-13C1020 20 20 20 20 20

cis-Heptachlor Epoxide-13C10 20 20 20 20 20 20

Mirex-13C1020 20 20 20 20 20

alpha-BHC-13C620 20 20 20 20 20

beta-BHC-13C620 20 20 20 20 20

Lindane-13C620 20 20 20 20 20

delta-BHC-13C620 20 20 20 20 20

Syringe Spike

4,4’-DiCB-13C12 (PCB-15) 20 20 20 20 20 20

2,3’,4’,5-TetraCB-13C12 (PCB-70) 20 20 20 20 20 20

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03

POPs Pesticides Standard Mixtures Cont... ES-5399 POPs PAR Solution (unlabeled) 1.2 mL nonane

ES-5399-10X-0.5 POPs PAR Solution (unlabeled) 0.5 mL nonane

(all concentrations in ng/mL)

ES-5399 ES-5399-10X-0.5

Hexachlorobenzene 200 2000

Aldrin 200 2000

Dieldrin 200 2000

Endrin 200 2000

4,4’-DDT 200 2000

4,4’-DDE 200 2000

4,4’-DDD 200 2000

2,4’-DDT 200 2000

2,4’-DDE 200 2000

2,4’-DDD 200 2000

trans-Chlordane (gamma) 200 2000

cis-Chlordane (alpha) 200 2000

trans-Nonachlor 200 2000

cis-Nonachlor 200 2000

Oxychlordane 200 2000

Heptachlor 200 2000

trans-Heptachlor Epoxide 200 2000

cis-Heptachlor Epoxide 200 2000

Mirex 200 2000

alpha-BHC 200 2000

beta-BHC 200 2000

Lindane (gamma-BHC) 200 2000

delta-BHC 200 2000

ES-5349 POPs Pesticides HRMS Clean-Up Spike (13C,99%) 1.2 mL nonane

ES-5400 POPs Pesticides Clean-Up Spike (13C,99%) 1.2 mL nonane

ES-5349-L POPs Pesticides LRMS Clean-Up Spike (13C,99%) 0.5 mL nonane

(all concentrations in ng/mL)

ES-5349 ES-5400 ES-5349-L

Hexachlorobenzene-13C6 100 200 1000

Aldrin-13C12 100 200 1000

Dieldrin-13C12 100 200 1000

Endrin-13C12 100 200 1000

4,4’-DDT-13C12 100 200 1000

4,4’-DDE-13C12 100 200 1000

4,4’-DDD-13C12 100 200 1000

2,4’-DDT-13C12 100 200 1000

2,4’-DDE-13C12 100 200 1000

2,4’-DDD-13C12 100 200 1000

trans-Chlordane (gamma)-13C10 100 200 1000

trans-Nonachlor-13C10 100 200 1000

cis-Nonachlor-13C10 100 200 1000

Oxychlordane-13C10 100 200 1000

Heptachlor-13C10 100 200 1000

cis-Heptachlor Epoxide-13C10 100 200 1000

Mirex-13C10 100 200 1000

alpha-HCH-13C6 100 200 1000

beta-HCH-13C6 100 200 1000

gamma-HCH (Lindane)-13C6 100 200 1000

delta-HCH-13C6 100 200 1000

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POPs Pesticides and Priority Pollutant Standard Mixtures

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POPs Pesticides Standard Mixtures Cont...EC-5350 POPs Pesticides HRMS (PCB) Syringe Spike (13C, 99%) 1.2 mL nonane

EC-5350-L POPs Pesticides LRMS (PCB) Syringe Spike (13C, 99%) 1.2 mL nonane

(all concentrations in ng/mL)

EC-5350 EC-5350-L

4,4’-DiCB-13C12 (PCB-15) 100 1000

2,3’,4’,5-TetraCB-13C12 (PCB-70) 100 1000

POPs Pesticides Alternative Spiking MixturesES-5021 Persistent Pesticide Spiking Solution (13C, 99%) 2.5 mL nonane

ES-5177-500X-N-0.5 Persistent Pesticide Spiking Solution (13C, 99%) 0.5 mL nonane

(all concentrations in ng/mL)

ES-5021 ES-5177-500X-N-0.5

Hexachlorobenzene-13C6 100 5000

Dieldrin-13C12 100 5000

beta-HCH-13C6 100 5000

gamma-HCH (Lindane)-13C6 100 5000

cis-Heptachlor Epoxide-13C10 100 5000

Oxychlordane-13C10 100 5000

trans-Nonachlor-13C10 100 5000

Mirex-13C10 100 5000

2,4’-DDT-13C12 100 5000

4,4’-DDT-13C12 100 5000

4,4’-DDE-13C12 250 12,500

ES-5261-1.2 Persistent Organic Pollutants Clean-Up Spike (13C, 99%) 1.2 mL nonane

(all concentrations in ng/mL)

13C6-Hexachlorobenzene 100013C6-α-HCH 100013C6-β-HCH 100013C6-Lindane (γ-HCCH) 100013C12-Aldrin 100013C12-Dieldrin 100013C12-Endrin 100013C10-trans-Chlordane 100013C10-Oxychlordane 100013C10-trans-Nonachlor 100013C10-Heptachlor 100013C10-cis-Heptachlor Epoxide 100013C12-2,4’-DDT 100013C12-4,4’-DDT 100013C12-4,4’-DDE 1000

03

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05

ES-5364CDC Priority Pollutant Calibration Solutions CS1 - CS10

(unlabeled/13C, 99%)10 x 0.5 mL nonane

(all concentrations in ng/mL)

Unlabeled Analyte CS1 CS2 CS3 CS4 CS5 CS6 CS7 CS8 CS9 CS10

Parlar 26 0.2 0.5 1 2.5 10 75 100 500

Parlar 50 0.2 0.5 1 2.5 10 75 100 500

Parlar 62 0.2 0.5 1 2.5 10 75 100 500

Hexachlorobenzene 0.2 0.5 1 2.5 10 75 100 500

beta-BHC 0.2 0.5 1 2.5 10 75 100 500

Lindane 0.2 0.5 1 2.5 10 75 100 500

Aldrin 0.2 0.5 1 2.5 10 75 100 500

cis-Heptachlor Epoxide 0.2 0.5 1 2.5 10 75 100 500

Oxychlordane 0.2 0.5 1 2.5 10 75 100 500

trans-Nonachlor 0.2 0.5 1 2.5 10 75 100 500

4,4’-DDE 0.2 0.5 1 2.5 10 75 100 500 3000 7500

Dieldrin 0.2 0.5 1 2.5 10 75 100 500

Endrin 0.2 0.5 1 2.5 10 75 100 500

Isodrin 0.2 0.5 1 2.5 10 75 100 500

2,4’-DDT 0.2 0.5 1 2.5 10 75 100 500

4,4’-DDT 0.2 0.5 1 2.5 10 75 100 500

Mirex 0.2 0.5 1 2.5 10 75 100 500

alpha-BHC 0.2 0.5 1 2.5 10 75 100 500

cis-Chlordane (alpha) 0.2 0.5 1 2.5 10 75 100 500

trans-Chlordane (gamma) 0.2 0.5 1 2.5 10 75 100 500

2,4’-DDE 0.2 0.5 1 2.5 10 75 100 500

cis-Nonachlor 0.2 0.5 1 2.5 10 75 100 500

Methoxychlor 0.2 0.5 1 2.5 10 75 100 500

Pentachloroanisole 0.2 0.5 1 2.5 10 75 100 500

Octachlorostyrene 0.2 0.5 1 2.5 10 75 100 500

Labeled Compound

1,2,3,4-TCDD-13C6 25 25 25 25 25 25 25 25 25 25

2,2’,3,3’,4,5,5’,6,6’-NonaCB-13C12 100 100 100 100 100 100 100 100 100 100

3,3’,4,4’-TetraBDE-13C12 75 75 75 75 75 75 75 75 75 75

2,2’,3,4,4’,6-HexaBDE-13C12 75 75 75 75 75 75 75 75 75 75

Hexachlorobenzene-13C6 75 75 75 75 75 75 75 75 75 75

beta-BHC-13C6 75 75 75 75 75 75 75 75 75 75

Lindane-13C6 75 75 75 75 75 75 75 75 75 75

Aldrin-13C12 75 75 75 75 75 75 75 75 75 75

cis-Heptachlor Epoxide 75 75 75 75 75 75 75 75 75 75

Oxychlordane-13C10 75 75 75 75 75 75 75 75 75 75

trans-Nonachlor-13C10 75 75 75 75 75 75 75 75 75 75

4,4’-DDE-13C12 150 150 150 150 150 150 150 150 150 150

Dieldrin-13C12 75 75 75 75 75 75 75 75 75 75

Endrin-13C12 75 75 75 75 75 75 75 75 75 75

Isodrin-13C12 75 75 75 75 75 75 75 75 75 75

2,4’-DDT-13C12 75 75 75 75 75 75 75 75 75 75

4,4’-DDT-13C12 75 75 75 75 75 75 75 75 75 75

Mirex-13C10 75 75 75 75 75 75 75 75 75 75

alpha-BHC-13C6 75 75 75 75 75 75 75 75 75 75

trans-Chlordane (gamma)- 13C10 75 75 75 75 75 75 75 75 75 75

2,4’-DDE-13C12 75 75 75 75 75 75 75 75 75 75

cis-Nonachlor-13C10 75 75 75 75 75 75 75 75 75 75

Methoxychlor-13C12 75 75 75 75 75 75 75 75 75 75

Pentachloroanisole-13C6 75 75 75 75 75 75 75 75 75 75

Octachlorostyrene-13C8 75 75 75 75 75 75 75 75 75 75

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Priority Pollutant Standard Mixtures

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POPs Pesticides and Priority Pollutant Standard Mixtures

06

ES-5365 CDC Priority Pollutant Spiking Standard (13C, 99%) 10 mL methanol (all concentrations in ng/mL)

Hexachlorobenzene-13C6 7.5

beta-BHC-13C6 7.5

Lindane-13C6 7.5

Aldrin-13C12 7.5

cis-Heptachlor Epoxide 7.5

Oxychlordane-13C10 7.5

trans-Nonachlor-13C10 7.5

4,4’-DDE-13C12 15

Dieldrin-13C12 7.5

Endrin-13C12 7.5

Isodrin-13C12 7.5

2,4’-DDT-13C12 7.5

4,4’-DDT-13C12 7.5

Mirex-13C10 7.5

alpha-BHC-13C6 7.5

trans-Chlordane (gamma)- 13C10 7.5

2,4’-DDE-13C12 7.5

cis-Nonachlor-13C10 7.5

Methoxychlor-13C12 7.5

Pentachloroanisole-13C6 7.5

Octachlorostyrene-13C8 7.5

Hexachlorocyclohexanes (HCH) Standard MixturesWhile Lindane (γ-Hexachlorocyclohexane, γ-HCH, or γ-BHC) is the predominant HCH isomer, α-, β-, and δ-HCH are also produced during synthesis of Lindane, and demonstrate bioaccumulative tendencies. The following mixes allow independent analysis of this class of compounds.

ES-5343 POPs HRMS HCH Calibration Solutions CS1-CS5 5 x 0.2 mL nonane (all concentrations in ng/mL)

Unlabeled Analytes CS1 CS2 CS3 CS4 CS5

alpha-BHC 0.1 0.3 1 3 10

beta-BHC 0.1 0.3 1 3 10

Lindane 0.1 0.3 1 3 10

delta-BHC 0.1 0.3 1 3 10

Surrogate Standards

alpha-BHC-13C6 2 2 2 2 2

beta-BHC-13C6 2 2 2 2 2

Lindane-13C6 2 2 2 2 2

delta-BHC-13C6 2 2 2 2 2

ES-5344 POPs HRMS HCH Clean-Up Spike 1.2 mL nonaneES-5344-50X-0.5 POPs HRMS HCH Clean-Up Spike (50x Stock) * 0.5 mL nonane (all concentrations in ng/mL)

ES-5344 ES-5344-50X-0.5

alpha-BHC-13C6 20 1000

beta-BHC-13C6 20 1000

Lindane-13C6 20 1000

delta-BHC-13C6 20 1000

05

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07 06

Toxaphene Standard Mixtures Toxaphene, a technical mixture of polychlorinated Camphenes, is an inexpensive and potent insecticide.The following mixtures allow analysis of the three commonly analyzed congeners of Toxaphene.

ES-5351 POPs Toxaphene Calibration Solutions CS1-CS6 6 x 0.2 mL nonane (all concentrations in ng/mL)

Unlabeled Analytes CS1 CS2 CS3 CS4 CS5 CS6

Parlar-26 0.4 2 10 40 200 800

Parlar-50 0.4 2 10 40 200 800

Parlar-62 0.4 2 10 40 200 800

Surrogate Standard

trans-Chlordane (gamma)-13C10 20 20 20 20 20 20

ES-5345 POPs Toxaphene Calibration Solutions CS1-CS5 5 x 0.2 mL nonane (all concentrations in ng/mL)

Unlabeled Analytes CS1 CS2 CS3 CS4 CS5

Parlar-26 10 30 100 300 1000

Parlar-50 10 30 100 300 1000

Parlar-62 10 30 100 300 1000

Surrogate Standard

trans-Chlordane-13C10 1 1 1 1 1

ES-5353 Predominant Bioaccumulative Toxaphene Congeners 1.2 mL nonane (all concentrations in ng/mL)

Parlar-26 2,000

Parlar-50 2,000

Parlar-62 2,000

ES-5346 POPs Toxaphene HRMS Surrogate Solution 1.2 mL nonane

ES-5352-L POPs Toxaphene LRMS Surrogate Solution 1.2 mL nonane (all concentrations in ng/mL)

ES-5346 ES-5352-L

trans-Chlordane (gamma)-13C10 100 1000

The mixtures listed in the preceding pages represent only part of the wide range of CIL Standards related to

Pesticides testing. For more information, or to request alternative mixtures, please contact CIL’s Environmental

Contaminant Standards division at envsales@ isotope.com.

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For accounts where a CIL distributor is not listed, our terms are:DELIVERY: FOB point Andover, MA USA Shipping charges are additional (air mail or courier) for non-hazardous

goods; air freight for hazardous chemicals as defined by IATA/ICAO.PAYMENT: Prepayment in US dollars by wire transfer or check drawn on US bank

(unless credit terms established). MasterCard / Visa/American Express are also accepted.

PRICES: Please contact our International Customer Service Department for pricing information at intlsales@isotope.com.

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ENV _STD_POP2/14 Supersedes all previously published literature