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Cambridge Isotope Laboratories, Inc.www.isotope.com
POPs Pesticides and Priority PollutantStandard Mixtures• POPs Pesticides “Dirty Dozen” Standard Mixtures• Priority Pollutant Standard Mixtures• HCH Standard Mixtures• Toxaphene Standard Mixtures
Cambridge Isotope Laboratories, Inc. (CIL) has long been the leader in development of isotopically labeled standards for use in trace and ultra-trace analysis of environmental pollutants. CIL continues this leading role by introducing the first ever comprehensive POPs pesticides standard mixtures for use in isotope dilution mass spectrometry analysis.
On May 17, 2004, the Stockholm Convention on Persistent Organic Pollutants entered into force with the objective to eliminate and/or restrict production and use of POPs of interest to the global community. The convention has defined 12 POPs of highest concern, called “The Dirty Dozen.” This list currently includes:
• Dioxins and furans• PCBs and hexachlorobenzene• Pesticides: aldrin, dieldrin, endrin, chlordane,
heptachlor, mirex, DDT and toxaphene.
While CIL has offered individual dioxin, furan, and PCB standards and standard mixtures for many years, as well as individual pesticide standards, our new POPs pesticides standard mixtures are designed to allow laboratories to use consistent, high quality, pre-formulated mixtures for analysis of these highest priority pollutants. CIL also offers extended priority pollutants standard mixtures, incorporating all thePOPs pesticides plus several other major pollutants ofconcern. For specific testing purposes, CIL also offersHCH-only and toxaphene-only standard mixes.
ENVIRONMENTAL CONTAMINANT STANDARDS
To place an order please contact CIL: t: 978.749.8000 1.800.322.1174 (North America) [email protected]
For international inquiries, please contact our International Customer Service Department at [email protected].
Cambridge Isotope Laboratories, Inc.
ENVIRONMENTAL CONTAMINANT STANDARDS
Cambridge Isotope Laboratories, Inc.
POPs Pesticides and Priority Pollutant Standard Mixtures
02
POPs Pesticides Standard Mixtures
ES-5348 POPs Pesticides Calibration Solutions CS1-CS6 (unlabeled/13C, 99%) 6 x 0.2 mL nonane
(all concentrations in ng/mL)
Unlabeled analyte CS1 CS2 CS3 CS4 CS5 CS6
Hexachlorobenzene 0.4 2 10 40 200 800
Aldrin 0.4 2 10 40 200 800
Dieldrin 0.4 2 10 40 200 800
Endrin 0.4 2 10 40 200 800
4,4’-DDT 0.4 2 10 40 200 800
4,4’-DDE 0.4 2 10 40 200 800
4,4’-DDD 0.4 2 10 40 200 800
2,4’-DDT 0.4 2 10 40 200 800
2,4’-DDE 0.4 2 10 40 200 800
2,4’-DDD 0.4 2 10 40 200 800
trans-Chlordane (gamma) 0.4 2 10 40 200 800
cis-Chlordane (alpha) 0.4 2 10 40 200 800
trans-Nonachlor 0.4 2 10 40 200 800
cis-Nonachlor 0.4 2 10 40 200 800
Oxychlordane 0.4 2 10 40 200 800
Heptachlor 0.4 2 10 40 200 800
trans-Heptachlor Epoxide 0.4 2 10 40 200 800
cis-Heptachlor Epoxide 0.4 2 10 40 200 800
Mirex 0.4 2 10 40 200 800
alpha-BHC 0.4 2 10 40 200 800
beta-BHC 0.4 2 10 40 200 800
Lindane 0.4 2 10 40 200 800
delta-BHC 0.4 2 10 40 200 800
Cleanup Spike
Hexachlorobenzene-13C620 20 20 20 20 20
Aldrin-13C1220 20 20 20 20 20
Dieldrin-13C1220 20 20 20 20 20
Endrin-13C1220 20 20 20 20 20
4,4’-DDT-13C1220 20 20 20 20 20
4,4’-DDE-13C1220 20 20 20 20 20
4,4’-DDD-13C1220 20 20 20 20 20
2,4’-DDT-13C1220 20 20 20 20 20
2,4’-DDE-13C1220 20 20 20 20 20
2,4’-DDD-13C1220 20 20 20 20 20
trans-Chlordane (gamma)-13C10 20 20 20 20 20 20
trans-Nonachlor-13C10 20 20 20 20 20 20
cis-Nonachlor-13C1020 20 20 20 20 20
Oxychlordane-13C1020 20 20 20 20 20
Heptachlor-13C1020 20 20 20 20 20
cis-Heptachlor Epoxide-13C10 20 20 20 20 20 20
Mirex-13C1020 20 20 20 20 20
alpha-BHC-13C620 20 20 20 20 20
beta-BHC-13C620 20 20 20 20 20
Lindane-13C620 20 20 20 20 20
delta-BHC-13C620 20 20 20 20 20
Syringe Spike
4,4’-DiCB-13C12 (PCB-15) 20 20 20 20 20 20
2,3’,4’,5-TetraCB-13C12 (PCB-70) 20 20 20 20 20 20
01
www.isotope.com
ENVIRONMENTAL CONTAMINANT STANDARDS
www.isotope.com
To place an order please contact CIL at: [email protected] l 978-749-8000 l 800-322-1174 ( N.America)
03
POPs Pesticides Standard Mixtures Cont... ES-5399 POPs PAR Solution (unlabeled) 1.2 mL nonane
ES-5399-10X-0.5 POPs PAR Solution (unlabeled) 0.5 mL nonane
(all concentrations in ng/mL)
ES-5399 ES-5399-10X-0.5
Hexachlorobenzene 200 2000
Aldrin 200 2000
Dieldrin 200 2000
Endrin 200 2000
4,4’-DDT 200 2000
4,4’-DDE 200 2000
4,4’-DDD 200 2000
2,4’-DDT 200 2000
2,4’-DDE 200 2000
2,4’-DDD 200 2000
trans-Chlordane (gamma) 200 2000
cis-Chlordane (alpha) 200 2000
trans-Nonachlor 200 2000
cis-Nonachlor 200 2000
Oxychlordane 200 2000
Heptachlor 200 2000
trans-Heptachlor Epoxide 200 2000
cis-Heptachlor Epoxide 200 2000
Mirex 200 2000
alpha-BHC 200 2000
beta-BHC 200 2000
Lindane (gamma-BHC) 200 2000
delta-BHC 200 2000
ES-5349 POPs Pesticides HRMS Clean-Up Spike (13C,99%) 1.2 mL nonane
ES-5400 POPs Pesticides Clean-Up Spike (13C,99%) 1.2 mL nonane
ES-5349-L POPs Pesticides LRMS Clean-Up Spike (13C,99%) 0.5 mL nonane
(all concentrations in ng/mL)
ES-5349 ES-5400 ES-5349-L
Hexachlorobenzene-13C6 100 200 1000
Aldrin-13C12 100 200 1000
Dieldrin-13C12 100 200 1000
Endrin-13C12 100 200 1000
4,4’-DDT-13C12 100 200 1000
4,4’-DDE-13C12 100 200 1000
4,4’-DDD-13C12 100 200 1000
2,4’-DDT-13C12 100 200 1000
2,4’-DDE-13C12 100 200 1000
2,4’-DDD-13C12 100 200 1000
trans-Chlordane (gamma)-13C10 100 200 1000
trans-Nonachlor-13C10 100 200 1000
cis-Nonachlor-13C10 100 200 1000
Oxychlordane-13C10 100 200 1000
Heptachlor-13C10 100 200 1000
cis-Heptachlor Epoxide-13C10 100 200 1000
Mirex-13C10 100 200 1000
alpha-HCH-13C6 100 200 1000
beta-HCH-13C6 100 200 1000
gamma-HCH (Lindane)-13C6 100 200 1000
delta-HCH-13C6 100 200 1000
02
Cambridge Isotope Laboratories, Inc.
ENVIRONMENTAL CONTAMINANT STANDARDS
Cambridge Isotope Laboratories, Inc.
POPs Pesticides and Priority Pollutant Standard Mixtures
04
POPs Pesticides Standard Mixtures Cont...EC-5350 POPs Pesticides HRMS (PCB) Syringe Spike (13C, 99%) 1.2 mL nonane
EC-5350-L POPs Pesticides LRMS (PCB) Syringe Spike (13C, 99%) 1.2 mL nonane
(all concentrations in ng/mL)
EC-5350 EC-5350-L
4,4’-DiCB-13C12 (PCB-15) 100 1000
2,3’,4’,5-TetraCB-13C12 (PCB-70) 100 1000
POPs Pesticides Alternative Spiking MixturesES-5021 Persistent Pesticide Spiking Solution (13C, 99%) 2.5 mL nonane
ES-5177-500X-N-0.5 Persistent Pesticide Spiking Solution (13C, 99%) 0.5 mL nonane
(all concentrations in ng/mL)
ES-5021 ES-5177-500X-N-0.5
Hexachlorobenzene-13C6 100 5000
Dieldrin-13C12 100 5000
beta-HCH-13C6 100 5000
gamma-HCH (Lindane)-13C6 100 5000
cis-Heptachlor Epoxide-13C10 100 5000
Oxychlordane-13C10 100 5000
trans-Nonachlor-13C10 100 5000
Mirex-13C10 100 5000
2,4’-DDT-13C12 100 5000
4,4’-DDT-13C12 100 5000
4,4’-DDE-13C12 250 12,500
ES-5261-1.2 Persistent Organic Pollutants Clean-Up Spike (13C, 99%) 1.2 mL nonane
(all concentrations in ng/mL)
13C6-Hexachlorobenzene 100013C6-α-HCH 100013C6-β-HCH 100013C6-Lindane (γ-HCCH) 100013C12-Aldrin 100013C12-Dieldrin 100013C12-Endrin 100013C10-trans-Chlordane 100013C10-Oxychlordane 100013C10-trans-Nonachlor 100013C10-Heptachlor 100013C10-cis-Heptachlor Epoxide 100013C12-2,4’-DDT 100013C12-4,4’-DDT 100013C12-4,4’-DDE 1000
03
www.isotope.com
ENVIRONMENTAL CONTAMINANT STANDARDS
www.isotope.com
To place an order please contact CIL at: [email protected] l 978-749-8000 l 800-322-1174 ( N.America)
05
ES-5364CDC Priority Pollutant Calibration Solutions CS1 - CS10
(unlabeled/13C, 99%)10 x 0.5 mL nonane
(all concentrations in ng/mL)
Unlabeled Analyte CS1 CS2 CS3 CS4 CS5 CS6 CS7 CS8 CS9 CS10
Parlar 26 0.2 0.5 1 2.5 10 75 100 500
Parlar 50 0.2 0.5 1 2.5 10 75 100 500
Parlar 62 0.2 0.5 1 2.5 10 75 100 500
Hexachlorobenzene 0.2 0.5 1 2.5 10 75 100 500
beta-BHC 0.2 0.5 1 2.5 10 75 100 500
Lindane 0.2 0.5 1 2.5 10 75 100 500
Aldrin 0.2 0.5 1 2.5 10 75 100 500
cis-Heptachlor Epoxide 0.2 0.5 1 2.5 10 75 100 500
Oxychlordane 0.2 0.5 1 2.5 10 75 100 500
trans-Nonachlor 0.2 0.5 1 2.5 10 75 100 500
4,4’-DDE 0.2 0.5 1 2.5 10 75 100 500 3000 7500
Dieldrin 0.2 0.5 1 2.5 10 75 100 500
Endrin 0.2 0.5 1 2.5 10 75 100 500
Isodrin 0.2 0.5 1 2.5 10 75 100 500
2,4’-DDT 0.2 0.5 1 2.5 10 75 100 500
4,4’-DDT 0.2 0.5 1 2.5 10 75 100 500
Mirex 0.2 0.5 1 2.5 10 75 100 500
alpha-BHC 0.2 0.5 1 2.5 10 75 100 500
cis-Chlordane (alpha) 0.2 0.5 1 2.5 10 75 100 500
trans-Chlordane (gamma) 0.2 0.5 1 2.5 10 75 100 500
2,4’-DDE 0.2 0.5 1 2.5 10 75 100 500
cis-Nonachlor 0.2 0.5 1 2.5 10 75 100 500
Methoxychlor 0.2 0.5 1 2.5 10 75 100 500
Pentachloroanisole 0.2 0.5 1 2.5 10 75 100 500
Octachlorostyrene 0.2 0.5 1 2.5 10 75 100 500
Labeled Compound
1,2,3,4-TCDD-13C6 25 25 25 25 25 25 25 25 25 25
2,2’,3,3’,4,5,5’,6,6’-NonaCB-13C12 100 100 100 100 100 100 100 100 100 100
3,3’,4,4’-TetraBDE-13C12 75 75 75 75 75 75 75 75 75 75
2,2’,3,4,4’,6-HexaBDE-13C12 75 75 75 75 75 75 75 75 75 75
Hexachlorobenzene-13C6 75 75 75 75 75 75 75 75 75 75
beta-BHC-13C6 75 75 75 75 75 75 75 75 75 75
Lindane-13C6 75 75 75 75 75 75 75 75 75 75
Aldrin-13C12 75 75 75 75 75 75 75 75 75 75
cis-Heptachlor Epoxide 75 75 75 75 75 75 75 75 75 75
Oxychlordane-13C10 75 75 75 75 75 75 75 75 75 75
trans-Nonachlor-13C10 75 75 75 75 75 75 75 75 75 75
4,4’-DDE-13C12 150 150 150 150 150 150 150 150 150 150
Dieldrin-13C12 75 75 75 75 75 75 75 75 75 75
Endrin-13C12 75 75 75 75 75 75 75 75 75 75
Isodrin-13C12 75 75 75 75 75 75 75 75 75 75
2,4’-DDT-13C12 75 75 75 75 75 75 75 75 75 75
4,4’-DDT-13C12 75 75 75 75 75 75 75 75 75 75
Mirex-13C10 75 75 75 75 75 75 75 75 75 75
alpha-BHC-13C6 75 75 75 75 75 75 75 75 75 75
trans-Chlordane (gamma)- 13C10 75 75 75 75 75 75 75 75 75 75
2,4’-DDE-13C12 75 75 75 75 75 75 75 75 75 75
cis-Nonachlor-13C10 75 75 75 75 75 75 75 75 75 75
Methoxychlor-13C12 75 75 75 75 75 75 75 75 75 75
Pentachloroanisole-13C6 75 75 75 75 75 75 75 75 75 75
Octachlorostyrene-13C8 75 75 75 75 75 75 75 75 75 75
04
Priority Pollutant Standard Mixtures
Cambridge Isotope Laboratories, Inc.
ENVIRONMENTAL CONTAMINANT STANDARDS
Cambridge Isotope Laboratories, Inc.
POPs Pesticides and Priority Pollutant Standard Mixtures
06
ES-5365 CDC Priority Pollutant Spiking Standard (13C, 99%) 10 mL methanol (all concentrations in ng/mL)
Hexachlorobenzene-13C6 7.5
beta-BHC-13C6 7.5
Lindane-13C6 7.5
Aldrin-13C12 7.5
cis-Heptachlor Epoxide 7.5
Oxychlordane-13C10 7.5
trans-Nonachlor-13C10 7.5
4,4’-DDE-13C12 15
Dieldrin-13C12 7.5
Endrin-13C12 7.5
Isodrin-13C12 7.5
2,4’-DDT-13C12 7.5
4,4’-DDT-13C12 7.5
Mirex-13C10 7.5
alpha-BHC-13C6 7.5
trans-Chlordane (gamma)- 13C10 7.5
2,4’-DDE-13C12 7.5
cis-Nonachlor-13C10 7.5
Methoxychlor-13C12 7.5
Pentachloroanisole-13C6 7.5
Octachlorostyrene-13C8 7.5
Hexachlorocyclohexanes (HCH) Standard MixturesWhile Lindane (γ-Hexachlorocyclohexane, γ-HCH, or γ-BHC) is the predominant HCH isomer, α-, β-, and δ-HCH are also produced during synthesis of Lindane, and demonstrate bioaccumulative tendencies. The following mixes allow independent analysis of this class of compounds.
ES-5343 POPs HRMS HCH Calibration Solutions CS1-CS5 5 x 0.2 mL nonane (all concentrations in ng/mL)
Unlabeled Analytes CS1 CS2 CS3 CS4 CS5
alpha-BHC 0.1 0.3 1 3 10
beta-BHC 0.1 0.3 1 3 10
Lindane 0.1 0.3 1 3 10
delta-BHC 0.1 0.3 1 3 10
Surrogate Standards
alpha-BHC-13C6 2 2 2 2 2
beta-BHC-13C6 2 2 2 2 2
Lindane-13C6 2 2 2 2 2
delta-BHC-13C6 2 2 2 2 2
ES-5344 POPs HRMS HCH Clean-Up Spike 1.2 mL nonaneES-5344-50X-0.5 POPs HRMS HCH Clean-Up Spike (50x Stock) * 0.5 mL nonane (all concentrations in ng/mL)
ES-5344 ES-5344-50X-0.5
alpha-BHC-13C6 20 1000
beta-BHC-13C6 20 1000
Lindane-13C6 20 1000
delta-BHC-13C6 20 1000
05
www.isotope.com
ENVIRONMENTAL CONTAMINANT STANDARDS
www.isotope.com
To place an order please contact CIL at: [email protected] l 978-749-8000 l 800-322-1174 ( N.America)
07 06
Toxaphene Standard Mixtures Toxaphene, a technical mixture of polychlorinated Camphenes, is an inexpensive and potent insecticide.The following mixtures allow analysis of the three commonly analyzed congeners of Toxaphene.
ES-5351 POPs Toxaphene Calibration Solutions CS1-CS6 6 x 0.2 mL nonane (all concentrations in ng/mL)
Unlabeled Analytes CS1 CS2 CS3 CS4 CS5 CS6
Parlar-26 0.4 2 10 40 200 800
Parlar-50 0.4 2 10 40 200 800
Parlar-62 0.4 2 10 40 200 800
Surrogate Standard
trans-Chlordane (gamma)-13C10 20 20 20 20 20 20
ES-5345 POPs Toxaphene Calibration Solutions CS1-CS5 5 x 0.2 mL nonane (all concentrations in ng/mL)
Unlabeled Analytes CS1 CS2 CS3 CS4 CS5
Parlar-26 10 30 100 300 1000
Parlar-50 10 30 100 300 1000
Parlar-62 10 30 100 300 1000
Surrogate Standard
trans-Chlordane-13C10 1 1 1 1 1
ES-5353 Predominant Bioaccumulative Toxaphene Congeners 1.2 mL nonane (all concentrations in ng/mL)
Parlar-26 2,000
Parlar-50 2,000
Parlar-62 2,000
ES-5346 POPs Toxaphene HRMS Surrogate Solution 1.2 mL nonane
ES-5352-L POPs Toxaphene LRMS Surrogate Solution 1.2 mL nonane (all concentrations in ng/mL)
ES-5346 ES-5352-L
trans-Chlordane (gamma)-13C10 100 1000
The mixtures listed in the preceding pages represent only part of the wide range of CIL Standards related to
Pesticides testing. For more information, or to request alternative mixtures, please contact CIL’s Environmental
Contaminant Standards division at envsales@ isotope.com.
Cambridge Isotope Laboratories, Inc.
ENVIRONMENTAL CONTAMINANT STANDARDS
For accounts where a CIL distributor is not listed, our terms are:DELIVERY: FOB point Andover, MA USA Shipping charges are additional (air mail or courier) for non-hazardous
goods; air freight for hazardous chemicals as defined by IATA/ICAO.PAYMENT: Prepayment in US dollars by wire transfer or check drawn on US bank
(unless credit terms established). MasterCard / Visa/American Express are also accepted.
PRICES: Please contact our International Customer Service Department for pricing information at [email protected].
Cambridge Isotope Laboratories, Inc.3 Highwood Drive, Tewksbury, MA 01876 USA
direct: 1.978.749.8000toll-free: 1.800.322.1174 (North America)
fax: 1.978.749.2768e-mail: [email protected]: www.isotope.com
ENV _STD_POP2/14 Supersedes all previously published literature