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Norma ISO 43
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La Acreditacin e ISO 17025 Validacin y incertidumbre
Manfred Kindler
ValidacinRequisitos de ISO 17025: ValidacinPreciso, pero no correctoNi preciso, ni correcto
Manfred Kindler
ValidacinRequisitos de ISO 17025: ValidacinPreciso y correctoCorrecto, pero no preciso
Manfred Kindler
Manfred Kindler
Chart1
7.810.1810.180.119.35-0.772.150.68.440.32
Cd
Pb PE
Cu
Ni
Cr
Ni PE
Cu PE
Cr PE
Zn PE
Cd PE
Ni
Ni PE
Cd
Cd PE
Cu
Cu PE
Cr
Cr PE
Pb PE
Zn PE
Extended Uncertainty %
Difference % to Reference
Summary
ICIM Lab #1 AAS
ParameterExt. UncDiff%
Ni1980.0 %781.00 %
Ni PE1200.0 %18.00 %
Cd3030.0 %1018.00 %
Cd PE790.0 %11.00 %
Cu2220.0 %935.00 %
Cu PE650.0 %-77.00 %
Cr1750.0 %215.00 %
Cr PE680.0 %60.00 %
Pb
Pb PE2410.0 %844.00 %
Zn
Zn PE564.0 %32.00 %
Summary
0000000000
Cd
Pb PE
Cu
Ni
Cr
Ni PE
Cu PE
Cr PE
Zn PE
Cd PE
Ni
Ni PE
Cd
Cd PE
Cu
Cu PE
Cr
Cr PE
Pb PE
Zn PE
Extended Uncertainty %
Difference % to Reference
All CuSums
NiCdCuCrNi PECd PECu PECr PEPb PEZn PE
1-4.2%15.2%8.0%-0.5%14.4%5.5%2.1%1.6%12.6%2.7%
21.6%39.0%11.8%-7.6%23.9%3.9%2.3%-1.5%3.0%0.8%
3-0.7%71.1%23.1%-15.9%33.4%5.8%2.9%4.6%23.9%0.1%
415.0%79.2%30.7%-12.6%40.6%3.1%0.4%2.5%25.8%-3.4%
517.7%75.4%35.9%-5.7%51.3%-6.4%4.8%31.8%-2.9%
642.4%93.7%40.2%-12.9%6-1.1%-5.8%5.7%32.6%-6.8%
756.1%122.3%49.6%2.4%7-7.3%5.2%30.6%-6.9%
865.4%133.2%73.6%13.2%8-9.6%5.8%29.2%-4.6%
974.8%147.0%91.0%7.4%9-9.9%6.2%49.8%-2.1%
1072.5%148.9%11.6%10-8.9%6.2%-4.2%
11146.8%15.7%11-10.7%-5.7%
128.1%12-6.9%
1313-7.0%
1414-6.0%
1515-5.1%
16160.5%
17173.0%
18182.3%
19194.8%
2020
All CuSums
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
0000
Ni
Cd
Cu
Cr
Cumulative Sum %
Ni
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000
000000
Ni PE
Cd PE
Cu PE
Cr PE
Pb PE
Zn PE
Cumulative Sum %
Ni PE
Cod laboratorW.M.L.
G.C.-5.10-1
Parametru:NiMean=10.781SD=1.07Extended Uncertainty=19.8%n=23
Aparat de masura:S.A.A. tip Unicam 939 +GF
Ref. Value:10.000Difference:7.81%
Inregistrari pentru graficul de control
Nr.DataValoare de referinta (mg/l)Statistics
crt.Masuratorii12345678910MeanSDDiff%CuSum
12/5/009.589.58-4.2%-4.2%
22/23/0010.5810.585.8%1.6%
35/8/009.969.579.770.28-2.3%-0.7%
44/4/0110.3211.9212.4811.571.1215.7%15.0%
55/28/0110.3210.0312.318.4110.271.602.7%17.7%
65/31/0112.4712.4724.7%42.4%
76/5/0111.8510.8911.370.6813.7%56.1%
86/6/0111.389.7910.7211.8510.940.899.4%65.4%
97/17/0110.4910.6211.2111.4410.940.469.4%74.8%
107/18/019.779.77-2.3%72.5%
117/18/010.000.000.0%0.0%
127/18/010.000.000.0%0.0%
137/18/010.000.000.0%0.0%
147/18/010.000.000.0%0.0%
157/18/010.000.000.0%0.0%
167/18/010.000.000.0%0.0%
177/18/010.000.000.0%0.0%
187/18/010.000.000.0%0.0%
197/18/010.000.000.0%0.0%
207/18/010.000.000.0%0.0%
217/18/010.000.000.0%0.0%
227/18/010.000.000.0%0.0%
237/18/010.000.000.0%0.0%
247/18/010.000.000.0%0.0%
257/18/010.000.000.0%0.0%
267/18/010.000.000.0%0.0%
277/18/010.000.000.0%0.0%
287/18/010.000.000.0%0.0%
297/18/010.000.000.0%0.0%
307/18/010.000.000.0%0.0%
317/18/010.000.000.0%0.0%
327/18/010.000.000.0%0.0%
337/18/010.000.000.0%0.0%
347/18/010.000.000.0%0.0%
357/18/010.000.000.0%0.0%
367/18/010.000.000.0%0.0%
Ni PE
0
0
00.27930717860.2793071786
01.12095197641.1209519764
01.6001328071.600132807
0
00.67882250990.6788225099
00.8930285550.893028555
00.45745673750.4574567375
0
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
Cd
0
0
0
0
0
0
0
0
0
0
0
0
Cd PE
Cod laboratorW.M.L.
G.C.-5.10-1
Parametru:NiMean=0.5009SD=0.030Extended Uncertainty=12.0%n=26
Aparat de masura:S.A.A. tip Perkni Elmer 2380
Ref. Value:0.500Difference:0.18%
Inregistrari pentru graficul de control
Nr.DataValoare de referinta (mg/l)Statistics
crt.Masuratorii12345678910MeanSDDiff%CuSum
17/12/010.5420.5440.6140.4990.4630.4690.5220.0574.4%4.4%
27/23/010.5020.4930.5090.4960.4890.4980.008-0.4%3.9%
38/10/010.4850.4750.5150.5240.5030.4930.4890.4980.4950.4960.4970.014-0.5%3.4%
48/13/010.4830.4740.4920.4850.4960.4860.009-2.8%0.6%
58/13/010.0000.0000.0%0.0%
68/13/010.0000.0000.0%0.0%
78/13/010.0000.0000.0%0.0%
88/13/010.0000.0000.0%0.0%
98/13/010.0000.0000.0%0.0%
108/13/010.0000.0000.0%0.0%
118/13/010.0000.0000.0%0.0%
128/13/010.0000.0000.0%0.0%
138/13/010.0000.0000.0%0.0%
148/13/010.0000.0000.0%0.0%
158/13/010.0000.0000.0%0.0%
168/13/010.0000.0000.0%0.0%
178/13/010.0000.0000.0%0.0%
188/13/010.0000.0000.0%0.0%
198/13/010.0000.0000.0%0.0%
208/13/010.0000.0000.0%0.0%
218/13/010.0000.0000.0%0.0%
228/13/010.0000.0000.0%0.0%
238/13/010.0000.0000.0%0.0%
248/13/010.0000.0000.0%0.0%
258/13/010.0000.0000.0%0.0%
268/13/010.0000.0000.0%0.0%
278/13/010.0000.0000.0%0.0%
288/13/010.0000.0000.0%0.0%
298/13/010.0000.0000.0%0.0%
308/13/010.0000.0000.0%0.0%
318/13/010.0000.0000.0%0.0%
328/13/010.0000.0000.0%0.0%
338/13/010.0000.0000.0%0.0%
348/13/010.0000.0000.0%0.0%
358/13/010.0000.0000.0%0.0%
368/13/010.0000.0000.0%0.0%
Cd PE
00.05686270010.0568627001
00.00785493480.0078549348
00.01415038280.0141503828
00.00851469320.0085146932
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
Cu
0
0
0
0
0
0
Cu PE
Cod laboratorW.M.L.
G.C.-5.10-1
Parametru:CdMean=5.5092SD=0.836Extended Uncertainty=30.3%n=23
Aparat de masura:S.A.A. tip Unicam 939 +GF
Ref. Value:5.000Difference:10.18%
Inregistrari pentru graficul de control
Nr.DataValoare de referinta (mg/l)Statistics
crt.Masuratorii12345678910MeanSDDiff%CuSum
18/10/005.0215.4046.8515.7590.96515.2%15.2%
28/17/006.1936.19323.9%39.0%
32/12/016.6046.60432.1%71.1%
44/6/015.3086.464.2265.9485.4215.0615.4040.7658.1%79.2%
55/9/014.7654.8554.8100.064-3.8%75.4%
66/23/015.9175.91718.3%93.7%
76/27/016.4276.42728.5%122.3%
87/9/016.7364.3585.5471.68110.9%133.2%
97/10/014.8016.5815.6911.25913.8%147.0%
107/13/015.0925.0921.8%148.9%
118/16/015.6614.4634.5584.8940.666-2.1%146.8%
128/16/010.0000.0000.0%0.0%
138/16/010.0000.0000.0%0.0%
148/16/010.0000.0000.0%0.0%
158/16/010.0000.0000.0%0.0%
168/16/010.0000.0000.0%0.0%
178/16/010.0000.0000.0%0.0%
188/16/010.0000.0000.0%0.0%
198/16/010.0000.0000.0%0.0%
208/16/010.0000.0000.0%0.0%
218/16/010.0000.0000.0%0.0%
228/16/010.0000.0000.0%0.0%
238/16/010.0000.0000.0%0.0%
248/16/010.0000.0000.0%0.0%
258/16/010.0000.0000.0%0.0%
268/16/010.0000.0000.0%0.0%
278/16/010.0000.0000.0%0.0%
288/16/010.0000.0000.0%0.0%
298/16/010.0000.0000.0%0.0%
308/16/010.0000.0000.0%0.0%
318/16/010.0000.0000.0%0.0%
328/16/010.0000.0000.0%0.0%
338/16/010.0000.0000.0%0.0%
348/16/010.0000.0000.0%0.0%
358/16/010.0000.0000.0%0.0%
368/16/010.0000.0000.0%0.0%
Cu PE
00.96517684040.9651768404
0
0
00.76497189490.7649718949
00.06363961030.0636396103
0
0
01.68149992571.6814999257
01.25865007051.2586500705
0
00.66593768480.6659376848
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
Cr
0
0
0
0
0
0
0
0
0
0
0
0
0
Cr PE
Cod laboratorW.M.L.
G.C.-5.10-1
Parametru:CdMean=0.5005SD=0.020Extended Uncertainty=7.9%n=39
Aparat de masura:S.A.A. tip Perkni Elmer 2380
Ref. Value:0.500Difference:0.11%
Inregistrari pentru graficul de control
Nr.DataValoare de referinta (mg/l)Statistics
crt.Masuratorii12345678910MeanSDDiff%CuSum
16/21/010.50800.50600.53300.52300.55600.53900.5280.0195.5%5.5%
27/20/010.49400.48400.48100.49200.50200.48800.49700.49600.4920.007-1.7%3.9%
37/20/010.54700.51900.52700.50530.49860.49250.49610.50040.50350.50740.5100.0171.9%5.8%
47/23/010.49800.48200.49700.49100.48900.50300.44700.4870.019-2.7%3.1%
58/8/010.49200.48700.49500.49200.48900.4910.003-1.8%1.3%
68/16/010.49200.48900.48200.4880.005-2.5%-1.1%
78/16/010.0000.0000.0%0.0%
88/16/010.0000.0000.0%0.0%
98/16/010.0000.0000.0%0.0%
108/16/010.0000.0000.0%0.0%
118/16/010.0000.0000.0%0.0%
128/16/010.0000.0000.0%0.0%
138/16/010.0000.0000.0%0.0%
148/16/010.0000.0000.0%0.0%
158/16/010.0000.0000.0%0.0%
168/16/010.0000.0000.0%0.0%
178/16/010.0000.0000.0%0.0%
188/16/010.0000.0000.0%0.0%
198/16/010.0000.0000.0%0.0%
208/16/010.0000.0000.0%0.0%
218/16/010.0000.0000.0%0.0%
228/16/010.0000.0000.0%0.0%
238/16/010.0000.0000.0%0.0%
248/16/010.0000.0000.0%0.0%
258/16/010.0000.0000.0%0.0%
268/16/010.0000.0000.0%0.0%
278/16/010.0000.0000.0%0.0%
288/16/010.0000.0000.0%0.0%
298/16/010.0000.0000.0%0.0%
308/16/010.0000.0000.0%0.0%
318/16/010.0000.0000.0%0.0%
328/16/010.0000.0000.0%0.0%
338/16/010.0000.0000.0%0.0%
348/16/010.0000.0000.0%0.0%
358/16/010.0000.0000.0%0.0%
368/16/010.0000.0000.0%0.0%
Cr PE
00.01917028950.0191702895
00.00702546390.0070254639
00.0167685420.016768542
00.01880349510.0188034951
00.0030822070.003082207
00.00513160140.0051316014
000
000
Pb PE
0
0
0
0
0
0
0
0
Zn PE
Cod laboratorW.M.L.
G.C.-5.10-1
Parametru:CuMean=10.935SD=1.212Extended Uncertainty=22.2%n=18
Aparat de masura:S.A.A. tip Unicam 939 +GF
Ref. Value:10.000Difference:9.35%
Inregistrari pentru graficul de control
Nr.DataValoare de referinta (mg/l)Statistics
crt.Masuratorii12345678910MeanSDDiff%CuSum
111/15/0010.8010.8008.0%8.0%
211/16/0010.3810.3803.8%11.8%
312/17/0011.1311.13011.3%23.1%
43/21/0110.7610.7607.6%30.7%
55/7/0110.7310.3110.5200.2975.2%35.9%
65/23/0112.589.2212.0910.089.289.3110.4271.5194.3%40.2%
77/5/019.3012.5810.9422.3169.4%49.6%
87/19/0112.6412.1612.4000.33924.0%73.6%
98/17/0111.7511.7311.7400.01417.4%91.0%
108/17/010.0000.0000.0%0.0%
118/17/010.0000.0000.0%0.0%
128/17/010.0000.0000.0%0.0%
138/17/010.0000.0000.0%0.0%
148/17/010.0000.0000.0%0.0%
158/17/010.0000.0000.0%0.0%
168/17/010.0000.0000.0%0.0%
178/17/010.0000.0000.0%0.0%
188/17/010.0000.0000.0%0.0%
198/17/010.0000.0000.0%0.0%
208/17/010.0000.0000.0%0.0%
218/17/010.0000.0000.0%0.0%
228/17/010.0000.0000.0%0.0%
238/17/010.0000.0000.0%0.0%
248/17/010.0000.0000.0%0.0%
258/17/010.0000.0000.0%0.0%
268/17/010.0000.0000.0%0.0%
278/17/010.0000.0000.0%0.0%
288/17/010.0000.0000.0%0.0%
298/17/010.0000.0000.0%0.0%
308/17/010.0000.0000.0%0.0%
318/17/010.0000.0000.0%0.0%
328/17/010.0000.0000.0%0.0%
338/17/010.0000.0000.0%0.0%
348/17/010.0000.0000.0%0.0%
358/17/010.0000.0000.0%0.0%
368/17/010.0000.0000.0%0.0%
Zn PE
0
0
0
0
00.29698484810.2969848481
01.51917693721.5191769372
02.31648181522.3164818152
00.3394112550.339411255
00.01414213560.0141421356
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
0
0
0
0
0
0
0
0
0
0
Cod laboratorW.M.L.
G.C.-5.10-1
Parametru:CuMean=0.4961SD=0.016Extended Uncertainty=6.5%n=45
Aparat de masura:S.A.A. tip Perkni Elmer 2380
Ref. Value:0.500Difference:-0.77%
Inregistrari pentru graficul de control
Nr.DataValoare de referinta (mg/l)Statistics
crt.Masuratorii12345678910MeanSDDiff%CuSum
12/18/000.5140.5090.5080.5100.0032.1%2.1%
23/1/000.5030.4920.5090.5010.0090.3%2.3%
34/13/000.4970.5020.5090.5030.0060.5%2.9%
47/19/000.4900.4970.5020.5060.4890.4430.4880.023-2.4%0.4%
57/23/000.4640.4680.4660.003-6.8%-6.4%
610/11/000.4960.5090.5030.5030.0070.5%-5.8%
711/6/000.4920.4870.4950.5020.4960.4840.4930.007-1.5%-7.3%
87/19/010.4820.4950.4890.009-2.3%-9.6%
97/20/010.5050.5130.5240.4440.5060.4980.031-0.3%-9.9%
107/23/010.5090.5120.5030.4970.5010.5080.5060.5050.0051.0%-8.9%
118/8/010.4920.4870.4950.4920.4890.4910.003-1.8%-10.7%
128/8/010.0000.0000.0%0.0%
138/8/010.0000.0000.0%0.0%
148/8/010.0000.0000.0%0.0%
158/8/010.0000.0000.0%0.0%
168/8/010.0000.0000.0%0.0%
178/8/010.0000.0000.0%0.0%
188/8/010.0000.0000.0%0.0%
198/8/010.0000.0000.0%0.0%
208/8/010.0000.0000.0%0.0%
218/8/010.0000.0000.0%0.0%
228/8/010.0000.0000.0%0.0%
238/8/010.0000.0000.0%0.0%
248/8/010.0000.0000.0%0.0%
258/8/010.0000.0000.0%0.0%
268/8/010.0000.0000.0%0.0%
278/8/010.0000.0000.0%0.0%
288/8/010.0000.0000.0%0.0%
298/8/010.0000.0000.0%0.0%
308/8/010.0000.0000.0%0.0%
318/8/010.0000.0000.0%0.0%
328/8/010.0000.0000.0%0.0%
338/8/010.0000.0000.0%0.0%
348/8/010.0000.0000.0%0.0%
358/8/010.0000.0000.0%0.0%
368/8/010.0000.0000.0%0.0%
00.00321455030.0032145503
00.00862167810.0086216781
00.00602771380.0060277138
00.02293832310.0229383231
00.00282842710.0028284271
00.00650640710.0065064071
00.00650128190.0065012819
00.00919238820.0091923882
00.03134166560.0313416656
00.0051455020.005145502
00.0030822070.003082207
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
0
0
0
0
0
0
0
0
0
0
0
0
0
Cod laboratorW.M.L.
G.C.-5.10-1
Parametru:CrMean=10.215SD=0.896Extended Uncertainty=17.5%n=21
Aparat de masura:S.A.A. tip Unicam 939 +GF
Ref. Value:10.000Difference:2.15%
Inregistrari pentru graficul de control
Nr.DataValoare de referinta (mg/l)Statistics
crt.Masuratorii12345678910MeanSDDiff%CuSum
14/28/009.9479.947-0.5%-0.5%
22/8/019.2899.289-7.1%-7.6%
32/9/019.1709.170-8.3%-15.9%
44/3/0110.47010.19010.3300.1983.3%-12.6%
55/8/0110.73010.65010.6900.0576.9%-5.7%
65/24/019.2829.282-7.2%-12.9%
75/31/0112.21010.85011.5300.96215.3%2.4%
86/4/0111.69010.93010.51011.19011.0800.49410.8%13.2%
96/7/019.7229.1199.4210.426-5.8%7.4%
107/6/0110.42010.4204.2%11.6%
117/24/0110.41010.4104.1%15.7%
128/17/019.6109.0059.1249.2460.321-7.5%8.1%
138/17/010.0000.0000.0%0.0%
148/17/010.0000.0000.0%0.0%
158/17/010.0000.0000.0%0.0%
168/17/010.0000.0000.0%0.0%
178/17/010.0000.0000.0%0.0%
188/17/010.0000.0000.0%0.0%
198/17/010.0000.0000.0%0.0%
208/17/010.0000.0000.0%0.0%
218/17/010.0000.0000.0%0.0%
228/17/010.0000.0000.0%0.0%
238/17/010.0000.0000.0%0.0%
248/17/010.0000.0000.0%0.0%
258/17/010.0000.0000.0%0.0%
268/17/010.0000.0000.0%0.0%
278/17/010.0000.0000.0%0.0%
288/17/010.0000.0000.0%0.0%
298/17/010.0000.0000.0%0.0%
308/17/010.0000.0000.0%0.0%
318/17/010.0000.0000.0%0.0%
328/17/010.0000.0000.0%0.0%
338/17/010.0000.0000.0%0.0%
348/17/010.0000.0000.0%0.0%
358/17/010.0000.0000.0%0.0%
368/17/010.0000.0000.0%0.0%
0
0
0
00.19798989870.1979898987
00.05656854250.0565685425
0
00.96166522240.9616652224
00.49382858020.4938285802
00.42638538910.4263853891
0
0
00.32051573020.3205157302
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Cod laboratorW.M.L.
G.C.-5.10-1
Parametru:CrMean=0.5030SD=0.017Extended Uncertainty=6.8%n=58
Aparat de masura:S.A.A. tip Perkni Elmer 2380
Ref. Value:0.500Difference:0.60%
Inregistrari pentru graficul de control
Nr.DataValoare de referinta (mg/l)Statistics
crt.Masuratorii12345678910MeanSDDiff%CuSum
18/10/000.5440.5370.5200.5220.5280.4450.4800.4980.5040.5010.5080.0291.6%1.6%
28/16/000.4780.4800.4960.4850.010-3.1%-1.5%
311/2/000.5340.5330.5250.5310.0056.1%4.6%
411/7/000.4970.4760.4890.4920.4960.4870.4900.008-2.1%2.5%
57/11/010.5120.5090.5150.5120.5060.5130.5110.0032.2%4.8%
67/20/010.5170.4980.4980.4950.5140.5040.0100.9%5.7%
77/23/010.5020.4890.4930.5090.4960.4980.008-0.4%5.2%
87/23/010.5070.5100.5000.5120.4860.5030.0110.6%5.8%
98/8/010.4870.5030.5170.5210.5220.4910.5050.4960.4870.4910.5020.0140.4%6.2%
1010/10/010.4880.5120.5000.4980.5020.5000.0090.0%6.2%
1110/10/010.0000.0000.0%0.0%
1210/10/010.0000.0000.0%0.0%
1310/10/010.0000.0000.0%0.0%
1410/10/010.0000.0000.0%0.0%
1510/10/010.0000.0000.0%0.0%
1610/10/010.0000.0000.0%0.0%
1710/10/010.0000.0000.0%0.0%
1810/10/010.0000.0000.0%0.0%
1910/10/010.0000.0000.0%0.0%
2010/10/010.0000.0000.0%0.0%
2110/10/010.0000.0000.0%0.0%
2210/10/010.0000.0000.0%0.0%
2310/10/010.0000.0000.0%0.0%
2410/10/010.0000.0000.0%0.0%
2510/10/010.0000.0000.0%0.0%
2610/10/010.0000.0000.0%0.0%
2710/10/010.0000.0000.0%0.0%
2810/10/010.0000.0000.0%0.0%
2910/10/010.0000.0000.0%0.0%
3010/10/010.0000.0000.0%0.0%
3110/10/010.0000.0000.0%0.0%
3210/10/010.0000.0000.0%0.0%
3310/10/010.0000.0000.0%0.0%
3410/10/010.0000.0000.0%0.0%
3510/10/010.0000.0000.0%0.0%
3610/10/010.0000.0000.0%0.0%
00.02940583650.0294058365
00.00986576570.0098657657
00.00493288290.0049328829
00.00766159250.0076615925
00.00318852110.0031885211
00.01026157880.0102615788
00.00785493480.0078549348
00.01053565380.0105356538
00.01384035970.0138403597
00.00860232530.0086023253
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
0
0
0
0
0
0
0
0
0
0
0
Cod laboratorW.M.L.
G.C.-5.10-1
Parametru:PbMean=0.5422SD=0.065Extended Uncertainty=24.1%n=45
Aparat de masura:S.A.A. tip Perkni Elmer 2380
Ref. Value:0.500Difference:8.44%
Inregistrari pentru graficul de control
Nr.DataValoare de referinta (mg/l)Statistics
crt.Masuratorii12345678910MeanSDDiff%CuSum
110/4/990.4100.5810.6200.5400.5610.5600.5800.6500.5630.07112.6%12.6%
28/16/000.4600.4800.4300.4400.4530.022-9.5%3.0%
38/29/000.6400.5200.6800.6100.5700.6040.06220.8%23.9%
41/29/010.5080.5110.5100.0021.9%25.8%
52/15/010.5810.5040.5060.5300.0446.1%31.8%
67/10/010.5150.4960.5010.5040.0100.8%32.6%
77/20/010.4820.4930.4870.4950.4920.4900.005-2.0%30.6%
87/23/010.4890.5020.4870.4920.4950.4930.006-1.4%29.2%
98/10/010.6100.5400.6100.6400.6000.6300.5900.6200.5900.6000.6030.02820.6%49.8%
108/10/010.0000.0000.0%0.0%
118/10/010.0000.0000.0%0.0%
128/10/010.0000.0000.0%0.0%
138/10/010.0000.0000.0%0.0%
148/10/010.0000.0000.0%0.0%
158/10/010.0000.0000.0%0.0%
168/10/010.0000.0000.0%0.0%
178/10/010.0000.0000.0%0.0%
188/10/010.0000.0000.0%0.0%
198/10/010.0000.0000.0%0.0%
208/10/010.0000.0000.0%0.0%
218/10/010.0000.0000.0%0.0%
228/10/010.0000.0000.0%0.0%
238/10/010.0000.0000.0%0.0%
248/10/010.0000.0000.0%0.0%
258/10/010.0000.0000.0%0.0%
268/10/010.0000.0000.0%0.0%
278/10/010.0000.0000.0%0.0%
288/10/010.0000.0000.0%0.0%
298/10/010.0000.0000.0%0.0%
308/10/010.0000.0000.0%0.0%
318/10/010.0000.0000.0%0.0%
328/10/010.0000.0000.0%0.0%
338/10/010.0000.0000.0%0.0%
348/10/010.0000.0000.0%0.0%
358/10/010.0000.0000.0%0.0%
368/10/010.0000.0000.0%0.0%
00.07109500690.0710950069
00.02217355780.0221735578
00.06188699380.0618869938
00.00212132030.0021213203
00.04389001410.0438900141
00.00984885780.0098488578
00.00526307890.0052630789
00.00587367010.0058736701
00.02750757470.0275075747
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
0
0
0
0
0
0
0
0
0
0
0
Cod laboratorW.M.L.
G.C.-5.10-1
Parametru:ZnMean=0.5016SD=0.014Extended Uncertainty=5.64%n=72
Aparat de masura:S.A.A. tip Perkni Elmer 2380
Ref. Value:0.500Difference:0.32%
Inregistrari pentru graficul de control
Nr.DataValoare de referinta (mg/l)Statistics
crt.Masuratorii12345678910MeanSDDiff%CuSum
18/24/000.51300.51400.5140.0012.7%2.7%
29/7/000.49700.48100.49300.4900.008-1.9%0.8%
39/19/000.49200.49500.50300.4970.006-0.7%0.1%
410/10/000.44200.48900.50200.49700.4830.028-3.5%-3.4%
510/25/000.50400.50100.5030.0020.5%-2.9%
610/31/000.47600.48200.48400.4810.004-3.9%-6.8%
72/8/010.49900.50200.49700.4990.003-0.1%-6.9%
85/16/010.51200.50400.51900.5120.0082.3%-4.6%
95/28/010.50630.51240.51900.5130.0062.5%-2.1%
106/7/010.48750.48810.49160.48950.4890.002-2.2%-4.2%
116/22/010.49560.48980.49250.4930.003-1.5%-5.7%
126/25/010.49640.49280.49320.4940.002-1.2%-6.9%
137/5/010.50400.51200.50700.49280.48760.49580.49760.5000.009-0.1%-7.0%
147/11/010.50100.50400.50900.5050.0040.9%-6.0%
157/19/010.49700.50800.50900.5050.0070.9%-5.1%
167/23/010.54920.52140.51290.5280.0195.6%0.5%
178/8/010.50910.51390.51050.50420.52460.49470.52410.51920.51330.5130.0102.5%3.0%
188/15/010.50440.49140.49900.50110.49320.48990.4970.006-0.7%2.3%
198/17/010.51550.51210.50960.50840.51770.5130.0042.5%4.8%
208/17/010.0000.0000.0%0.0%
218/17/010.0000.0000.0%0.0%
228/17/010.0000.0000.0%0.0%
238/17/010.0000.0000.0%0.0%
248/17/010.0000.0000.0%0.0%
258/17/010.0000.0000.0%0.0%
268/17/010.0000.0000.0%0.0%
278/17/010.0000.0000.0%0.0%
288/17/010.0000.0000.0%0.0%
298/17/010.0000.0000.0%0.0%
308/17/010.0000.0000.0%0.0%
318/17/010.0000.0000.0%0.0%
328/17/010.0000.0000.0%0.0%
338/17/010.0000.0000.0%0.0%
348/17/010.0000.0000.0%0.0%
358/17/010.0000.0000.0%0.0%
368/17/010.0000.0000.0%0.0%
00.00070710680.0007071068
00.0083266640.008326664
00.00568624070.0056862407
00.02752574550.0275257455
00.00212132030.0021213203
00.0041633320.004163332
00.00251661150.0025166115
00.00750555350.0075055535
00.00635164020.0063516402
00.0018209430.001820943
00.00290229790.0029022979
00.00197315310.0019731531
00.00852972390.0085297239
00.00404145190.0040414519
00.00665832810.0066583281
00.01898587190.0189858719
00.00954997090.0095499709
00.00583575190.0058357519
00.00391446040.0039144604
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
000
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ValidacinOut of ControlOut of Control
Manfred Kindler
Control Data
Performance of method out of Control Status, if
Case 1Case 2Case 3Case 4
1-2.35-1.710.83-2.51
2-1.930.141.24-1.59
32.560.74-0.87-0.59
42.142.160.171.74
50.132.82-1.032.35
6-0.11-0.08-0.78-0.69
7-0.461.32-0.14-1.95
8-1.47-0.280.71-0.20
9-2.01-0.02-0.99-2.33
100.19-1.910.791.24
11-1.93-2.13-0.41-0.02
122.55-0.840.85-1.19
13-0.000.851.330.28
14-2.950.820.930.26
15-0.61-0.04-0.850.11
160.50-2.191.220.62
17-3.23-2.421.370.28
18-3.40-2.311.550.18
19-1.40-0.141.220.46
202.721.041.10-1.80
Case 1
-2.3528253262
-1.93
2.5558643493
2.1448062943
0.1332318745
-0.1055820663
-0.4590117282
-1.4696280443
-2.0137942067
0.1939116671
-1.9293378118
2.5486928799
-0.0010914641
-2.9478942117
-0.6064775335
0.4977217758
-3.23
-3.4
-1.4
2.7213574971
Tarjetas de Control
Case 1
Case 2
-1.7145943458
0.1369962425
0.7428257497
2.16
2.82
-0.082682734
1.3248215059
-0.2801670386
-0.0212937048
-1.9115025559
-2.13
-0.8447931602
0.8482140209
0.8170250388
-0.0427683823
-2.19
-2.42
-2.31
-0.1355802791
1.0433783843
3 consecutive points outside of 2 SD
!
!
!
Case 2
Performance of method out of Control Status
Case 3
0.8255879274
1.24
-0.8661217701
0.1705234929
-1.03
-0.78
-0.1362024608
0.7104613729
-0.9921303526
0.7908140938
-0.4070493677
0.8542073411
1.33
0.9332660938
-0.8493523458
1.22
1.37
1.5547864276
1.22
1.1
5 consecutive points outside of 1 SD
Case 3
Performance of method out of Control Status
Case 4
-2.509481803
-1.5882636888
-0.5894218611
1.7382014911
2.3464886743
-0.686220705
-1.9490608873
-0.2049422248
-2.3255556212
1.2413120812
-0.0192645657
-1.19
0.2781988187
0.2591247324
0.1086496078
0.618256524
0.2766935067
0.1758543291
0.45779091
-1.8
7 consecutive points over / under the central line
!
!
!
Case 4
Performance of method out of Control Status
Tabelle2
Tabelle3
ValidacinTarjetas de Control1 SD: Lnea de atencin 2 SD: Lmite de advertencia3 SD: Lmite de control
El desempeo est fuera de control si:7 puntos encima/debajo de la lnea central5 puntos fuera de 1 SD3 puntos fuera de 2 SD2 puntos fuera de 3 SD
Manfred Kindler
Out of ControlOut of Control
Manfred Kindler
Control Data
Performance of method out of Control Status, if
Case 1Case 2Case 3Case 4
1-2.35-1.710.83-2.51
2-1.930.141.24-1.59
32.560.74-0.87-0.59
42.142.160.171.74
50.132.82-1.032.35
6-0.11-0.08-0.78-0.69
7-0.461.32-0.14-1.95
8-1.47-0.280.71-0.20
9-2.01-0.02-0.99-2.33
100.19-1.910.791.24
11-1.93-2.13-0.41-0.02
122.55-0.840.85-1.19
13-0.000.851.330.28
14-2.950.820.930.26
15-0.61-0.04-0.850.11
160.50-2.191.220.62
17-3.23-2.421.370.28
18-3.40-2.311.550.18
19-1.40-0.141.220.46
202.721.041.10-1.80
Case 1
-2.3528253262
-1.93
2.5558643493
2.1448062943
0.1332318745
-0.1055820663
-0.4590117282
-1.4696280443
-2.0137942067
0.1939116671
-1.9293378118
2.5486928799
-0.0010914641
-2.9478942117
-0.6064775335
0.4977217758
-3.23
-3.4
-1.4
2.7213574971
2 consecutive points outside of 3 SD
!
!
!
!
!
!
Case 1
Performance of method out of Control Status
Case 2
-1.7145943458
0.1369962425
0.7428257497
2.16
2.82
-0.082682734
1.3248215059
-0.2801670386
-0.0212937048
-1.9115025559
-2.13
-0.8447931602
0.8482140209
0.8170250388
-0.0427683823
-2.19
-2.42
-2.31
-0.1355802791
1.0433783843
3 consecutive points outside of 2 SD
!
!
!
Case 2
Performance of method out of Control Status
Case 3
0.8255879274
1.24
-0.8661217701
0.1705234929
-1.03
-0.78
-0.1362024608
0.7104613729
-0.9921303526
0.7908140938
-0.4070493677
0.8542073411
1.33
0.9332660938
-0.8493523458
1.22
1.37
1.5547864276
1.22
1.1
5 consecutive points outside of 1 SD
Case 3
Performance of method out of Control Status
Case 4
-2.509481803
-1.5882636888
-0.5894218611
1.7382014911
2.3464886743
-0.686220705
-1.9490608873
-0.2049422248
-2.3255556212
1.2413120812
-0.0192645657
-1.19
0.2781988187
0.2591247324
0.1086496078
0.618256524
0.2766935067
0.1758543291
0.45779091
-1.8
7 consecutive points over / under the central line
!
!
!
Case 4
Performance of method out of Control Status
Tabelle2
Tabelle3
Out of ControlOut of Control
Manfred Kindler
Control Data
Performance of method out of Control Status, if
Case 1Case 2Case 3Case 4
1-2.35-1.710.83-2.51
2-1.930.141.24-1.59
32.560.74-0.87-0.59
42.142.160.171.74
50.132.82-1.032.35
6-0.11-0.08-0.78-0.69
7-0.461.32-0.14-1.95
8-1.47-0.280.71-0.20
9-2.01-0.02-0.99-2.33
100.19-1.910.791.24
11-1.93-2.13-0.41-0.02
122.55-0.840.85-1.19
13-0.000.851.330.28
14-2.950.820.930.26
15-0.61-0.04-0.850.11
160.50-2.191.220.62
17-3.23-2.421.370.28
18-3.40-2.311.550.18
19-1.40-0.141.220.46
202.721.041.10-1.80
Case 1
-2.3528253262
-1.93
2.5558643493
2.1448062943
0.1332318745
-0.1055820663
-0.4590117282
-1.4696280443
-2.0137942067
0.1939116671
-1.9293378118
2.5486928799
-0.0010914641
-2.9478942117
-0.6064775335
0.4977217758
-3.23
-3.4
-1.4
2.7213574971
2 consecutive points outside of 3 SD
!
!
!
!
!
!
Case 1
Performance of method out of Control Status
Case 2
-1.7145943458
0.1369962425
0.7428257497
2.16
2.82
-0.082682734
1.3248215059
-0.2801670386
-0.0212937048
-1.9115025559
-2.13
-0.8447931602
0.8482140209
0.8170250388
-0.0427683823
-2.19
-2.42
-2.31
-0.1355802791
1.0433783843
3 consecutive points outside of 2 SD
!
!
!
Case 2
Performance of method out of Control Status
Case 3
0.8255879274
1.24
-0.8661217701
0.1705234929
-1.03
-0.78
-0.1362024608
0.7104613729
-0.9921303526
0.7908140938
-0.4070493677
0.8542073411
1.33
0.9332660938
-0.8493523458
1.22
1.37
1.5547864276
1.22
1.1
5 consecutive points outside of 1 SD
Case 3
Performance of method out of Control Status
Case 4
-2.509481803
-1.5882636888
-0.5894218611
1.7382014911
2.3464886743
-0.686220705
-1.9490608873
-0.2049422248
-2.3255556212
1.2413120812
-0.0192645657
-1.19
0.2781988187
0.2591247324
0.1086496078
0.618256524
0.2766935067
0.1758543291
0.45779091
-1.8
7 consecutive points over / under the central line
!
!
!
Case 4
Performance of method out of Control Status
Tabelle2
Tabelle3
Out of ControlOut of Control
Manfred Kindler
Control Data
Performance of method out of Control Status, if
Case 1Case 2Case 3Case 4
1-2.35-1.710.83-2.51
2-1.930.141.24-1.59
32.560.74-0.87-0.59
42.142.160.171.74
50.132.82-1.032.35
6-0.11-0.08-0.78-0.69
7-0.461.32-0.14-1.95
8-1.47-0.280.71-0.20
9-2.01-0.02-0.99-2.33
100.19-1.910.791.24
11-1.93-2.13-0.41-0.02
122.55-0.840.85-1.19
13-0.000.851.330.28
14-2.950.820.930.26
15-0.61-0.04-0.850.11
160.50-2.191.220.62
17-3.23-2.421.370.28
18-3.40-2.311.550.18
19-1.40-0.141.220.46
202.721.041.10-1.80
Case 1
-2.3528253262
-1.93
2.5558643493
2.1448062943
0.1332318745
-0.1055820663
-0.4590117282
-1.4696280443
-2.0137942067
0.1939116671
-1.9293378118
2.5486928799
-0.0010914641
-2.9478942117
-0.6064775335
0.4977217758
-3.23
-3.4
-1.4
2.7213574971
2 consecutive points outside of 3 SD
!
!
!
!
!
!
Case 1
Performance of method out of Control Status
Case 2
-1.7145943458
0.1369962425
0.7428257497
2.16
2.82
-0.082682734
1.3248215059
-0.2801670386
-0.0212937048
-1.9115025559
-2.13
-0.8447931602
0.8482140209
0.8170250388
-0.0427683823
-2.19
-2.42
-2.31
-0.1355802791
1.0433783843
3 consecutive points outside of 2 SD
!
!
!
Case 2
Performance of method out of Control Status
Case 3
0.8255879274
1.24
-0.8661217701
0.1705234929
-1.03
-0.78
-0.1362024608
0.7104613729
-0.9921303526
0.7908140938
-0.4070493677
0.8542073411
1.33
0.9332660938
-0.8493523458
1.22
1.37
1.5547864276
1.22
1.1
5 consecutive points outside of 1 SD
Case 3
Performance of method out of Control Status
Case 4
-2.509481803
-1.5882636888
-0.5894218611
1.7382014911
2.3464886743
-0.686220705
-1.9490608873
-0.2049422248
-2.3255556212
1.2413120812
-0.0192645657
-1.19
0.2781988187
0.2591247324
0.1086496078
0.618256524
0.2766935067
0.1758543291
0.45779091
-1.8
7 consecutive points over / under the central line
!
!
!
Case 4
Performance of method out of Control Status
Tabelle2
Tabelle3
La Acreditacin e ISO 17025 Ejemplo 1
Manfred Kindler
Manfred Kindler
Control Data
Performance of method out of Control Status, if
Case 1Case 2Case 3Case 4
1-2.35-1.710.83-2.51
2-1.930.141.24-1.59
32.560.74-0.87-0.59
42.142.160.171.74
50.132.82-1.032.35
6-0.11-0.08-0.78-0.69
7-0.461.32-0.14-1.95
8-1.47-0.280.71-0.20
9-2.01-0.02-0.99-2.33
100.19-1.910.791.24
11-1.93-2.13-0.41-0.02
122.55-0.840.85-1.19
13-0.000.851.330.28
14-2.950.820.930.26
15-0.61-0.04-0.850.11
160.50-2.191.220.62
17-3.23-2.421.370.28
18-3.40-2.311.550.18
19-1.40-0.141.220.46
202.721.041.10-1.80
Cr data
Valori determinate pentru trasarea diagramei de control
pentru CCO-Cr utilizand ca substanta de referinta C8H5KO4
Nr. Det.teoreticmasuratdiffcusumdiff%cusum %
1500.00491.96-8.04-8.04-1.6%-1.6%
2500.00491.96-8.04-16.08-1.6%-3.2%
3500.00489.88-10.12-26.20-2.0%-5.2%
4500.00502.052.05-24.150.4%-4.8%
5500.00492.95-7.05-31.20-1.4%-6.2%
6500.00505.955.95-25.251.2%-5.1%
7500.00499.02-0.98-26.23-0.2%-5.2%
8500.00499.00-1.00-27.23-0.2%-5.4%
9500.00499.20-0.80-28.03-0.2%-5.6%
10500.00502.072.07-25.960.4%-5.2%
11500.00506.006.00-19.961.2%-4.0%
12500.00499.00-1.00-20.96-0.2%-4.2%
13500.00495.76-4.24-25.20-0.8%-5.0%
14500.00499.00-1.00-26.20-0.2%-5.2%
15500.00504.754.75-21.451.0%-4.3%
16500.00505.925.92-15.531.2%-3.1%
17500.00505.845.84-9.691.2%-1.9%
18500.00502.002.00-7.690.4%-1.5%
19500.00499.00-1.00-8.69-0.2%-1.7%
20500.00499.00-1.00-9.69-0.2%-1.9%
Mean =499.52
Std.Dev.=5.01
STD %=1.00%
Cr Graph
491.96
491.96
489.88
502.05
492.95
505.95
499.02
499
499.2
502.07
506
499
495.76
499
504.75
505.92
505.84
502
499
499
Out of Control
Out of Control
+ 2 SD
+ 1 SD
+ 3 SD
- 1 SD
- 2 SD
- 3 SD
masurat
Cr CuSum
-0.01608
-0.03216
-0.0524
-0.0483
-0.0624
-0.0505
-0.05246
-0.05446
-0.05606
-0.05192
-0.03992
-0.04192
-0.0504
-0.0524
-0.0429
-0.03106
-0.01938
-0.01538
-0.01738
-0.01938
cusum %
Control Chart: Cusum-Analysis
Manfred Kindler
Control Data
Performance of method out of Control Status, if
Case 1Case 2Case 3Case 4
1-2.35-1.710.83-2.51
2-1.930.141.24-1.59
32.560.74-0.87-0.59
42.142.160.171.74
50.132.82-1.032.35
6-0.11-0.08-0.78-0.69
7-0.461.32-0.14-1.95
8-1.47-0.280.71-0.20
9-2.01-0.02-0.99-2.33
100.19-1.910.791.24
11-1.93-2.13-0.41-0.02
122.55-0.840.85-1.19
13-0.000.851.330.28
14-2.950.820.930.26
15-0.61-0.04-0.850.11
160.50-2.191.220.62
17-3.23-2.421.370.28
18-3.40-2.311.550.18
19-1.40-0.141.220.46
202.721.041.10-1.80
Cr data
Valori determinate pentru trasarea diagramei de control
pentru CCO-Cr utilizand ca substanta de referinta C8H5KO4
Nr. Det.teoreticmasuratdiffcusumdiff%cusum %
1500.00491.96-8.04-8.04-1.6%-1.6%
2500.00491.96-8.04-16.08-1.6%-3.2%
3500.00489.88-10.12-26.20-2.0%-5.2%
4500.00502.052.05-24.150.4%-4.8%
5500.00492.95-7.05-31.20-1.4%-6.2%
6500.00505.955.95-25.251.2%-5.1%
7500.00499.02-0.98-26.23-0.2%-5.2%
8500.00499.00-1.00-27.23-0.2%-5.4%
9500.00499.20-0.80-28.03-0.2%-5.6%
10500.00502.072.07-25.960.4%-5.2%
11500.00506.006.00-19.961.2%-4.0%
12500.00499.00-1.00-20.96-0.2%-4.2%
13500.00495.76-4.24-25.20-0.8%-5.0%
14500.00499.00-1.00-26.20-0.2%-5.2%
15500.00504.754.75-21.451.0%-4.3%
16500.00505.925.92-15.531.2%-3.1%
17500.00505.845.84-9.691.2%-1.9%
18500.00502.002.00-7.690.4%-1.5%
19500.00499.00-1.00-8.69-0.2%-1.7%
20500.00499.00-1.00-9.69-0.2%-1.9%
Mean =499.52
Std.Dev.=5.01
STD %=1.00%
Cr Graph
491.96
491.96
489.88
502.05
492.95
505.95
499.02
499
499.2
502.07
506
499
495.76
499
504.75
505.92
505.84
502
499
499
Out of Control
Out of Control
+ 2 SD
+ 1 SD
+ 3 SD
- 1 SD
- 2 SD
- 3 SD
masurat
Cr CuSum
-0.01608
-0.03216
-0.0524
-0.0483
-0.0624
-0.0505
-0.05246
-0.05446
-0.05606
-0.05192
-0.03992
-0.04192
-0.0504
-0.0524
-0.0429
-0.03106
-0.01938
-0.01538
-0.01738
-0.01938
cusum %
Control Chart: Cusum-Analysis
Manfred Kindler
Control Data
Performance of method out of Control Status, if
Case 1Case 2Case 3Case 4
1-2.35-1.710.83-2.51
2-1.930.141.24-1.59
32.560.74-0.87-0.59
42.142.160.171.74
50.132.82-1.032.35
6-0.11-0.08-0.78-0.69
7-0.461.32-0.14-1.95
8-1.47-0.280.71-0.20
9-2.01-0.02-0.99-2.33
100.19-1.910.791.24
11-1.93-2.13-0.41-0.02
122.55-0.840.85-1.19
13-0.000.851.330.28
14-2.950.820.930.26
15-0.61-0.04-0.850.11
160.50-2.191.220.62
17-3.23-2.421.370.28
18-3.40-2.311.550.18
19-1.40-0.141.220.46
202.721.041.10-1.80
Cr data
Valori determinate pentru trasarea diagramei de control
pentru CCO-Cr utilizand ca substanta de referinta C8H5KO4
Nr. Det.teoreticmasuratdiffcusumdiff%cusum %
1500.00491.96-8.04-8.04-1.6%-1.6%
2500.00491.96-8.04-16.08-1.6%-3.2%
3500.00489.88-10.12-26.20-2.0%-5.2%
4500.00502.052.05-24.150.4%-4.8%
5500.00492.95-7.05-31.20-1.4%-6.2%
6500.00505.955.95-25.251.2%-5.1%
7500.00499.02-0.98-26.23-0.2%-5.2%
8500.00499.00-1.00-27.23-0.2%-5.4%
9500.00499.20-0.80-28.03-0.2%-5.6%
10500.00502.072.07-25.960.4%-5.2%
11500.00506.006.00-19.961.2%-4.0%
12500.00499.00-1.00-20.96-0.2%-4.2%
13500.00495.76-4.24-25.20-0.8%-5.0%
14500.00499.00-1.00-26.20-0.2%-5.2%
15500.00504.754.75-21.451.0%-4.3%
16500.00505.925.92-15.531.2%-3.1%
17500.00505.845.84-9.691.2%-1.9%
18500.00502.002.00-7.690.4%-1.5%
19500.00499.00-1.00-8.69-0.2%-1.7%
20500.00499.00-1.00-9.69-0.2%-1.9%
Mean =499.52
Std.Dev.=5.01
STD %=1.00%
Cr Graph
491.96
491.96
489.88
502.05
492.95
505.95
499.02
499
499.2
502.07
506
499
495.76
499
504.75
505.92
505.84
502
499
499
Out of Control
Out of Control
+ 2 SD
+ 1 SD
+ 3 SD
- 1 SD
- 2 SD
- 3 SD
masurat
Cr CuSum
-0.01608
-0.03216
-0.0524
-0.0483
-0.0624
-0.0505
-0.05246
-0.05446
-0.05606
-0.05192
-0.03992
-0.04192
-0.0504
-0.0524
-0.0429
-0.03106
-0.01938
-0.01538
-0.01738
-0.01938
cusum %
Control Chart: Cusum-Analysis
La Acreditacin e ISO 17025 Ejemplo 2
Manfred Kindler
Manfred Kindler
Summary
ICIM Lab #2 AAS
ParameterExt. UncDiff%
Ni 0,5472.00 %177.00 %
Ni 1,0333.00 %82.00 %
Ni 5,0210.00 %37.00 %
Zn 0,5305.00 %65.00 %
Zn 1,0197.00 %-14.00 %
Zn 5,0196.00 %-37.00 %
Mn 0,5439.00 %-143.00 %
Mn 1,0377.00 %-135.00 %
Mn 5,0230.00 %-44.00 %
Cu 0,5415.00 %123.00 %
Cu 1,0178.00 %-95.00 %
Cu 5,0127.00 %-18.00 %
Cr 0,51313.00 %578.00 %
Cr 1,0518.00 %505.00 %
Cr 5,0420.00 %570.00 %
Pb 0,52203.00 %-473.00 %
Pb 1,01973.00 %-365.00 %
Pb 2,0685.00 %-377.00 %
Cd 0,5268.00 %110.00 %
Cd 1,0359.00 %92.00 %
Cd 5,0161.00 %33.00 %
Summary
Pb 2,0
Pb 1,0
Pb 0,5
Cr 1,0
Cr 0,5
Cr 5,0
Ni 0,5
Cu 0,5
Mn 0,5
Mn 1,0
Ni 0,5 Ni 1,0 Ni 5,0
Zn 0,5 Zn 1,0 Zn 5,0
Mn 0,5 Mn 1,0 Mn 5,0
Cu 0,5 Cu 1,0 Cu 5,0
Cr 0,5 Cr 1,0 Cr 5,0
Pb 0,5 Pb 1,0 Pb 2,0
Cd 0,5 Cd 1,0 Cd 5,0
Extended Uncertainty %
Difference % to Reference
All CuSums
low Concentrationhigh Concentration
NiZnMnCuCrPbCdNiZnMnCuCrPbCd
8/14/01-2.4%-1.4%-4.8%3.0%-1.4%6.8%-0.6%8/14/01-0.6%-0.6%0.0%-0.7%5.0%-5.2%-0.1%
8/15/01-1.0%-1.2%-6.6%-17.2%-2.6%-4.0%1.6%8/15/01-1.2%-0.3%0.1%-1.6%8.5%-3.4%0.6%
8/16/010.6%-0.4%-9.0%-16.0%-3.0%-19.4%1.6%8/16/01-0.0%-1.2%1.3%-1.2%11.8%-10.1%0.1%
8/17/010.0%-0.2%-12.4%-16.6%-3.2%-7.6%2.0%8/17/010.1%0.2%0.6%-1.7%20.6%-11.8%0.9%
8/20/013.6%-1.0%-12.8%-15.0%-4.2%-11.0%4.6%8/20/012.4%-1.1%-0.1%-1.7%24.3%-13.9%0.2%
8/21/018.6%2.6%-13.0%-15.4%-1.6%-30.2%7.4%8/21/012.4%-1.1%-2.3%-2.5%32.7%-22.9%2.0%
8/22/0110.6%4.2%-13.6%-15.8%2.6%-33.2%7.2%8/22/011.8%-1.4%-1.7%-1.8%38.1%-27.3%2.6%
8/23/0114.2%5.2%-11.4%-10.4%7.8%-37.8%8.8%8/23/012.9%-2.9%-3.5%-1.5%45.6%-30.2%2.6%
All CuSums
Ni
Zn
Mn
Cu
Cr
Pb
Cd
Cumulative Sum %
Low Concentration
Nichel
Ni
Zn
Mn
Cu
Cr
Pb
Cd
Cumulative Sum %
High Concentration
Zinc
Nichel
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4880.9824.968-2.4%-1.8%-0.6%-2.4%-1.8%-0.6%
8/15/010.5071.0314.9731.4%3.1%-0.5%-1.0%1.3%-1.2%
8/16/010.5081.0265.0571.6%2.6%1.1%0.6%3.9%-0.0%
8/17/010.4971.0025.006-0.6%0.2%0.1%0.0%4.1%0.1%
8/20/010.5181.0075.1163.6%0.7%2.3%3.6%4.8%2.4%
8/21/010.5251.0164.9985.0%1.6%-0.0%8.6%6.4%2.4%
8/22/010.5101.0124.9742.0%1.2%-0.5%10.6%7.6%1.8%
8/23/010.5180.9905.0543.6%-1.0%1.1%14.2%6.6%2.9%
Mean:0.50891.00835.0183Mean:0.50891.00835.0183
Std. Dev.0.01200.01680.0527Ext. Uncertainty4.72%3.33%2.10%
SD %:2.36%1.66%1.05%Diff-% to Reference1.77%0.82%0.37%
Zinc
Mangan
Cupru
Zinc
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4931.0054.969-1.4%0.5%-0.6%-1.4%0.5%-0.6%
8/15/010.5011.0075.0160.2%0.7%0.3%-1.2%1.2%-0.3%
8/16/010.5040.9914.9540.8%-0.9%-0.9%-0.4%0.3%-1.2%
8/17/010.5010.9955.0730.2%-0.5%1.5%-0.2%-0.2%0.2%
8/20/010.4960.9834.933-0.8%-1.7%-1.3%-1.0%-1.9%-1.1%
8/21/010.5181.0025.0023.6%0.2%0.0%2.6%-1.7%-1.1%
8/22/010.5081.0134.9831.6%1.3%-0.3%4.2%-0.4%-1.4%
8/23/010.5050.9934.9231.0%-0.7%-1.5%5.2%-1.1%-2.9%
Mean:0.50330.99864.9816Mean:0.50330.99864.9816
Std. Dev.0.00770.00980.0488Ext. Uncertainty3.05%1.97%1.96%
SD %:1.52%0.98%0.98%Diff-% to Reference0.65%-0.14%-0.37%
Cupru
Crom
Plumb
Mangan
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4760.9865.001-4.8%-1.4%0.0%-4.8%-1.4%0.0%
8/15/010.4911.0005.003-1.8%0.0%0.1%-6.6%-1.4%0.1%
8/16/010.4880.9625.060-2.4%-3.8%1.2%-9.0%-5.2%1.3%
8/17/010.4831.0004.964-3.4%0.0%-0.7%-12.4%-5.2%0.6%
8/20/010.4980.9874.967-0.4%-1.3%-0.7%-12.8%-6.5%-0.1%
8/21/010.4990.9594.891-0.2%-4.1%-2.2%-13.0%-10.6%-2.3%
8/22/010.4971.0135.029-0.6%1.3%0.6%-13.6%-9.3%-1.7%
8/23/010.5110.9854.9102.2%-1.5%-1.8%-11.4%-10.8%-3.5%
Mean:0.49290.98654.9781Mean:0.49290.98654.9781
Std. Dev.0.01080.01860.0573Ext. Uncertainty4.39%3.77%2.30%
SD %:2.19%1.89%1.15%Diff-% to Reference-1.43%-1.35%-0.44%
Plumb
Cadmiu
Cupru
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5150.9964.9633.0%-0.4%-0.7%3.0%-0.4%-0.7%
8/15/010.3990.9944.955-20.2%-0.6%-0.9%-17.2%-1.0%-1.6%
8/16/010.5061.0055.0241.2%0.5%0.5%-16.0%-0.5%-1.2%
8/17/010.4970.9854.973-0.6%-1.5%-0.5%-16.6%-2.0%-1.7%
8/20/010.5080.9865.0001.6%-1.4%0.0%-15.0%-3.4%-1.7%
8/21/010.4980.9814.961-0.4%-1.9%-0.8%-15.4%-5.3%-2.5%
8/22/010.4980.9975.036-0.4%-0.3%0.7%-15.8%-5.6%-1.8%
8/23/010.5270.9805.0155.4%-2.0%0.3%-10.4%-7.6%-1.5%
Mean:0.49350.99054.9909Mean:0.49350.99054.9909
Std. Dev.0.03950.00880.0318Ext. Uncertainty16.02%1.78%1.27%
SD %:8.01%0.89%0.64%Diff-% to Reference-1.30%-0.95%-0.18%
Crom
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5211.0565.2484.2%5.6%5.0%4.2%5.6%5.0%
8/15/010.4951.0745.176-1.0%7.4%3.5%3.2%13.0%8.5%
8/16/010.4931.0585.167-1.4%5.8%3.3%1.8%18.8%11.8%
8/17/010.5501.0585.43710.0%5.8%8.7%11.8%24.6%20.6%
8/20/010.5211.0255.1884.2%2.5%3.8%16.0%27.1%24.3%
8/21/010.5961.0945.42119.2%9.4%8.4%35.2%36.5%32.7%
8/22/010.5061.0235.2691.2%2.3%5.4%36.4%38.8%38.1%
8/23/010.5491.0165.3749.8%1.6%7.5%46.2%40.4%45.6%
Mean:0.52891.05055.2850Mean:0.52891.05055.2850
Std. Dev.0.03470.02720.1111Ext. Uncertainty13.13%5.18%4.20%
SD %:6.57%2.59%2.10%Diff-% to Reference5.78%5.05%5.70%
Plumb
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0002.0000.5001.0002.000
Concentratii standard00.5001.0002.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5341.0801.8976.8%8.0%-5.2%6.8%8.0%-5.2%
8/15/010.4460.9532.035-10.8%-4.7%1.8%-4.0%3.3%-3.4%
8/16/010.4230.7941.866-15.4%-20.6%-6.7%-19.4%-17.3%-10.1%
8/17/010.5591.0811.96711.8%8.1%-1.7%-7.6%-9.2%-11.8%
8/20/010.4831.0061.957-3.4%0.6%-2.2%-11.0%-8.6%-13.9%
8/21/010.4040.8941.821-19.2%-10.6%-9.0%-30.2%-19.2%-22.9%
8/22/010.4850.9511.912-3.0%-4.9%-4.4%-33.2%-24.1%-27.3%
8/23/010.4770.9491.941-4.6%-5.1%-3.0%-37.8%-29.2%-30.2%
Mean:0.47640.96351.9245Mean:0.47640.96351.9245
Std. Dev.0.05250.09500.0659Ext. Uncertainty22.03%19.73%6.85%
SD %:11.02%9.86%3.42%Diff-% to Reference-4.73%-3.65%-3.77%
Cadmiu
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4971.0094.996-0.6%0.9%-0.1%-0.6%0.9%-0.1%
8/15/010.5111.0165.0352.2%1.6%0.7%1.6%2.5%0.6%
8/16/010.5000.9764.9720.0%-2.4%-0.6%1.6%0.1%0.1%
8/17/010.5021.0115.0410.4%1.1%0.8%2.0%1.2%0.9%
8/20/010.5131.0114.9672.6%1.1%-0.7%4.6%2.3%0.2%
8/21/010.5141.0425.0892.8%4.2%1.8%7.4%6.5%2.0%
8/22/010.4991.0085.030-0.2%0.8%0.6%7.2%7.3%2.6%
8/23/010.5081.0015.0011.6%0.1%0.0%8.8%7.4%2.6%
Mean:0.50551.00935.0164Mean:0.50551.00935.0164
Std. Dev.0.00680.01810.0405Ext. Uncertainty2.68%3.59%1.61%
SD %:1.34%1.80%0.81%Diff-% to Reference1.10%0.92%0.33%
Manfred Kindler
Summary
ICIM Lab #2 AAS
ParameterExt. UncDiff%
Ni 0,5472.00 %177.00 %
Ni 1,0333.00 %82.00 %
Ni 5,0210.00 %37.00 %
Zn 0,5305.00 %65.00 %
Zn 1,0197.00 %-14.00 %
Zn 5,0196.00 %-37.00 %
Mn 0,5439.00 %-143.00 %
Mn 1,0377.00 %-135.00 %
Mn 5,0230.00 %-44.00 %
Cu 0,5415.00 %123.00 %
Cu 1,0178.00 %-95.00 %
Cu 5,0127.00 %-18.00 %
Cr 0,51313.00 %578.00 %
Cr 1,0518.00 %505.00 %
Cr 5,0420.00 %570.00 %
Pb 0,52203.00 %-473.00 %
Pb 1,01973.00 %-365.00 %
Pb 2,0685.00 %-377.00 %
Cd 0,5268.00 %110.00 %
Cd 1,0359.00 %92.00 %
Cd 5,0161.00 %33.00 %
Summary
Pb 2,0
Pb 1,0
Pb 0,5
Cr 1,0
Cr 0,5
Cr 5,0
Ni 0,5
Cu 0,5
Mn 0,5
Mn 1,0
Ni 0,5 Ni 1,0 Ni 5,0
Zn 0,5 Zn 1,0 Zn 5,0
Mn 0,5 Mn 1,0 Mn 5,0
Cu 0,5 Cu 1,0 Cu 5,0
Cr 0,5 Cr 1,0 Cr 5,0
Pb 0,5 Pb 1,0 Pb 2,0
Cd 0,5 Cd 1,0 Cd 5,0
Extended Uncertainty %
Difference % to Reference
All CuSums
low Concentrationhigh Concentration
NiZnMnCuCrPbCdNiZnMnCuCrPbCd
8/14/01-2.4%-1.4%-4.8%3.0%-1.4%6.8%-0.6%8/14/01-0.6%-0.6%0.0%-0.7%5.0%-5.2%-0.1%
8/15/01-1.0%-1.2%-6.6%-17.2%-2.6%-4.0%1.6%8/15/01-1.2%-0.3%0.1%-1.6%8.5%-3.4%0.6%
8/16/010.6%-0.4%-9.0%-16.0%-3.0%-19.4%1.6%8/16/01-0.0%-1.2%1.3%-1.2%11.8%-10.1%0.1%
8/17/010.0%-0.2%-12.4%-16.6%-3.2%-7.6%2.0%8/17/010.1%0.2%0.6%-1.7%20.6%-11.8%0.9%
8/20/013.6%-1.0%-12.8%-15.0%-4.2%-11.0%4.6%8/20/012.4%-1.1%-0.1%-1.7%24.3%-13.9%0.2%
8/21/018.6%2.6%-13.0%-15.4%-1.6%-30.2%7.4%8/21/012.4%-1.1%-2.3%-2.5%32.7%-22.9%2.0%
8/22/0110.6%4.2%-13.6%-15.8%2.6%-33.2%7.2%8/22/011.8%-1.4%-1.7%-1.8%38.1%-27.3%2.6%
8/23/0114.2%5.2%-11.4%-10.4%7.8%-37.8%8.8%8/23/012.9%-2.9%-3.5%-1.5%45.6%-30.2%2.6%
All CuSums
Ni
Zn
Mn
Cu
Cr
Pb
Cd
Cumulative Sum %
Low Concentration
Nichel
Ni
Zn
Mn
Cu
Cr
Pb
Cd
Cumulative Sum %
High Concentration
Zinc
Nichel
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4880.9824.968-2.4%-1.8%-0.6%-2.4%-1.8%-0.6%
8/15/010.5071.0314.9731.4%3.1%-0.5%-1.0%1.3%-1.2%
8/16/010.5081.0265.0571.6%2.6%1.1%0.6%3.9%-0.0%
8/17/010.4971.0025.006-0.6%0.2%0.1%0.0%4.1%0.1%
8/20/010.5181.0075.1163.6%0.7%2.3%3.6%4.8%2.4%
8/21/010.5251.0164.9985.0%1.6%-0.0%8.6%6.4%2.4%
8/22/010.5101.0124.9742.0%1.2%-0.5%10.6%7.6%1.8%
8/23/010.5180.9905.0543.6%-1.0%1.1%14.2%6.6%2.9%
Mean:0.50891.00835.0183Mean:0.50891.00835.0183
Std. Dev.0.01200.01680.0527Ext. Uncertainty4.72%3.33%2.10%
SD %:2.36%1.66%1.05%Diff-% to Reference1.77%0.82%0.37%
Zinc
Mangan
Cupru
Zinc
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4931.0054.969-1.4%0.5%-0.6%-1.4%0.5%-0.6%
8/15/010.5011.0075.0160.2%0.7%0.3%-1.2%1.2%-0.3%
8/16/010.5040.9914.9540.8%-0.9%-0.9%-0.4%0.3%-1.2%
8/17/010.5010.9955.0730.2%-0.5%1.5%-0.2%-0.2%0.2%
8/20/010.4960.9834.933-0.8%-1.7%-1.3%-1.0%-1.9%-1.1%
8/21/010.5181.0025.0023.6%0.2%0.0%2.6%-1.7%-1.1%
8/22/010.5081.0134.9831.6%1.3%-0.3%4.2%-0.4%-1.4%
8/23/010.5050.9934.9231.0%-0.7%-1.5%5.2%-1.1%-2.9%
Mean:0.50330.99864.9816Mean:0.50330.99864.9816
Std. Dev.0.00770.00980.0488Ext. Uncertainty3.05%1.97%1.96%
SD %:1.52%0.98%0.98%Diff-% to Reference0.65%-0.14%-0.37%
Cupru
Crom
Plumb
Mangan
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4760.9865.001-4.8%-1.4%0.0%-4.8%-1.4%0.0%
8/15/010.4911.0005.003-1.8%0.0%0.1%-6.6%-1.4%0.1%
8/16/010.4880.9625.060-2.4%-3.8%1.2%-9.0%-5.2%1.3%
8/17/010.4831.0004.964-3.4%0.0%-0.7%-12.4%-5.2%0.6%
8/20/010.4980.9874.967-0.4%-1.3%-0.7%-12.8%-6.5%-0.1%
8/21/010.4990.9594.891-0.2%-4.1%-2.2%-13.0%-10.6%-2.3%
8/22/010.4971.0135.029-0.6%1.3%0.6%-13.6%-9.3%-1.7%
8/23/010.5110.9854.9102.2%-1.5%-1.8%-11.4%-10.8%-3.5%
Mean:0.49290.98654.9781Mean:0.49290.98654.9781
Std. Dev.0.01080.01860.0573Ext. Uncertainty4.39%3.77%2.30%
SD %:2.19%1.89%1.15%Diff-% to Reference-1.43%-1.35%-0.44%
Plumb
Cadmiu
Cupru
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5150.9964.9633.0%-0.4%-0.7%3.0%-0.4%-0.7%
8/15/010.3990.9944.955-20.2%-0.6%-0.9%-17.2%-1.0%-1.6%
8/16/010.5061.0055.0241.2%0.5%0.5%-16.0%-0.5%-1.2%
8/17/010.4970.9854.973-0.6%-1.5%-0.5%-16.6%-2.0%-1.7%
8/20/010.5080.9865.0001.6%-1.4%0.0%-15.0%-3.4%-1.7%
8/21/010.4980.9814.961-0.4%-1.9%-0.8%-15.4%-5.3%-2.5%
8/22/010.4980.9975.036-0.4%-0.3%0.7%-15.8%-5.6%-1.8%
8/23/010.5270.9805.0155.4%-2.0%0.3%-10.4%-7.6%-1.5%
Mean:0.49350.99054.9909Mean:0.49350.99054.9909
Std. Dev.0.03950.00880.0318Ext. Uncertainty16.02%1.78%1.27%
SD %:8.01%0.89%0.64%Diff-% to Reference-1.30%-0.95%-0.18%
Crom
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5211.0565.2484.2%5.6%5.0%4.2%5.6%5.0%
8/15/010.4951.0745.176-1.0%7.4%3.5%3.2%13.0%8.5%
8/16/010.4931.0585.167-1.4%5.8%3.3%1.8%18.8%11.8%
8/17/010.5501.0585.43710.0%5.8%8.7%11.8%24.6%20.6%
8/20/010.5211.0255.1884.2%2.5%3.8%16.0%27.1%24.3%
8/21/010.5961.0945.42119.2%9.4%8.4%35.2%36.5%32.7%
8/22/010.5061.0235.2691.2%2.3%5.4%36.4%38.8%38.1%
8/23/010.5491.0165.3749.8%1.6%7.5%46.2%40.4%45.6%
Mean:0.52891.05055.2850Mean:0.52891.05055.2850
Std. Dev.0.03470.02720.1111Ext. Uncertainty13.13%5.18%4.20%
SD %:6.57%2.59%2.10%Diff-% to Reference5.78%5.05%5.70%
Plumb
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0002.0000.5001.0002.000
Concentratii standard00.5001.0002.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5341.0801.8976.8%8.0%-5.2%6.8%8.0%-5.2%
8/15/010.4460.9532.035-10.8%-4.7%1.8%-4.0%3.3%-3.4%
8/16/010.4230.7941.866-15.4%-20.6%-6.7%-19.4%-17.3%-10.1%
8/17/010.5591.0811.96711.8%8.1%-1.7%-7.6%-9.2%-11.8%
8/20/010.4831.0061.957-3.4%0.6%-2.2%-11.0%-8.6%-13.9%
8/21/010.4040.8941.821-19.2%-10.6%-9.0%-30.2%-19.2%-22.9%
8/22/010.4850.9511.912-3.0%-4.9%-4.4%-33.2%-24.1%-27.3%
8/23/010.4770.9491.941-4.6%-5.1%-3.0%-37.8%-29.2%-30.2%
Mean:0.47640.96351.9245Mean:0.47640.96351.9245
Std. Dev.0.05250.09500.0659Ext. Uncertainty22.03%19.73%6.85%
SD %:11.02%9.86%3.42%Diff-% to Reference-4.73%-3.65%-3.77%
Cadmiu
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4971.0094.996-0.6%0.9%-0.1%-0.6%0.9%-0.1%
8/15/010.5111.0165.0352.2%1.6%0.7%1.6%2.5%0.6%
8/16/010.5000.9764.9720.0%-2.4%-0.6%1.6%0.1%0.1%
8/17/010.5021.0115.0410.4%1.1%0.8%2.0%1.2%0.9%
8/20/010.5131.0114.9672.6%1.1%-0.7%4.6%2.3%0.2%
8/21/010.5141.0425.0892.8%4.2%1.8%7.4%6.5%2.0%
8/22/010.4991.0085.030-0.2%0.8%0.6%7.2%7.3%2.6%
8/23/010.5081.0015.0011.6%0.1%0.0%8.8%7.4%2.6%
Mean:0.50551.00935.0164Mean:0.50551.00935.0164
Std. Dev.0.00680.01810.0405Ext. Uncertainty2.68%3.59%1.61%
SD %:1.34%1.80%0.81%Diff-% to Reference1.10%0.92%0.33%
Manfred Kindler
Summary
ICIM Lab #2 AAS
ParameterExt. UncDiff%
Ni 0,5472.00 %177.00 %
Ni 1,0333.00 %82.00 %
Ni 5,0210.00 %37.00 %
Zn 0,5305.00 %65.00 %
Zn 1,0197.00 %-14.00 %
Zn 5,0196.00 %-37.00 %
Mn 0,5439.00 %-143.00 %
Mn 1,0377.00 %-135.00 %
Mn 5,0230.00 %-44.00 %
Cu 0,5415.00 %123.00 %
Cu 1,0178.00 %-95.00 %
Cu 5,0127.00 %-18.00 %
Cr 0,51313.00 %578.00 %
Cr 1,0518.00 %505.00 %
Cr 5,0420.00 %570.00 %
Pb 0,52203.00 %-473.00 %
Pb 1,01973.00 %-365.00 %
Pb 2,0685.00 %-377.00 %
Cd 0,5268.00 %110.00 %
Cd 1,0359.00 %92.00 %
Cd 5,0161.00 %33.00 %
Summary
Pb 2,0
Pb 1,0
Pb 0,5
Cr 1,0
Cr 0,5
Cr 5,0
Ni 0,5
Cu 0,5
Mn 0,5
Mn 1,0
Ni 0,5 Ni 1,0 Ni 5,0
Zn 0,5 Zn 1,0 Zn 5,0
Mn 0,5 Mn 1,0 Mn 5,0
Cu 0,5 Cu 1,0 Cu 5,0
Cr 0,5 Cr 1,0 Cr 5,0
Pb 0,5 Pb 1,0 Pb 2,0
Cd 0,5 Cd 1,0 Cd 5,0
Extended Uncertainty %
Difference % to Reference
All CuSums
low Concentrationhigh Concentration
NiZnMnCuCrPbCdNiZnMnCuCrPbCd
8/14/01-2.4%-1.4%-4.8%3.0%-1.4%6.8%-0.6%8/14/01-0.6%-0.6%0.0%-0.7%5.0%-5.2%-0.1%
8/15/01-1.0%-1.2%-6.6%-17.2%-2.6%-4.0%1.6%8/15/01-1.2%-0.3%0.1%-1.6%8.5%-3.4%0.6%
8/16/010.6%-0.4%-9.0%-16.0%-3.0%-19.4%1.6%8/16/01-0.0%-1.2%1.3%-1.2%11.8%-10.1%0.1%
8/17/010.0%-0.2%-12.4%-16.6%-3.2%-7.6%2.0%8/17/010.1%0.2%0.6%-1.7%20.6%-11.8%0.9%
8/20/013.6%-1.0%-12.8%-15.0%-4.2%-11.0%4.6%8/20/012.4%-1.1%-0.1%-1.7%24.3%-13.9%0.2%
8/21/018.6%2.6%-13.0%-15.4%-1.6%-30.2%7.4%8/21/012.4%-1.1%-2.3%-2.5%32.7%-22.9%2.0%
8/22/0110.6%4.2%-13.6%-15.8%2.6%-33.2%7.2%8/22/011.8%-1.4%-1.7%-1.8%38.1%-27.3%2.6%
8/23/0114.2%5.2%-11.4%-10.4%7.8%-37.8%8.8%8/23/012.9%-2.9%-3.5%-1.5%45.6%-30.2%2.6%
All CuSums
Ni
Zn
Mn
Cu
Cr
Pb
Cd
Cumulative Sum %
Low Concentration
Nichel
Ni
Zn
Mn
Cu
Cr
Pb
Cd
Cumulative Sum %
High Concentration
Zinc
Nichel
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4880.9824.968-2.4%-1.8%-0.6%-2.4%-1.8%-0.6%
8/15/010.5071.0314.9731.4%3.1%-0.5%-1.0%1.3%-1.2%
8/16/010.5081.0265.0571.6%2.6%1.1%0.6%3.9%-0.0%
8/17/010.4971.0025.006-0.6%0.2%0.1%0.0%4.1%0.1%
8/20/010.5181.0075.1163.6%0.7%2.3%3.6%4.8%2.4%
8/21/010.5251.0164.9985.0%1.6%-0.0%8.6%6.4%2.4%
8/22/010.5101.0124.9742.0%1.2%-0.5%10.6%7.6%1.8%
8/23/010.5180.9905.0543.6%-1.0%1.1%14.2%6.6%2.9%
Mean:0.50891.00835.0183Mean:0.50891.00835.0183
Std. Dev.0.01200.01680.0527Ext. Uncertainty4.72%3.33%2.10%
SD %:2.36%1.66%1.05%Diff-% to Reference1.77%0.82%0.37%
Zinc
Mangan
Cupru
Zinc
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4931.0054.969-1.4%0.5%-0.6%-1.4%0.5%-0.6%
8/15/010.5011.0075.0160.2%0.7%0.3%-1.2%1.2%-0.3%
8/16/010.5040.9914.9540.8%-0.9%-0.9%-0.4%0.3%-1.2%
8/17/010.5010.9955.0730.2%-0.5%1.5%-0.2%-0.2%0.2%
8/20/010.4960.9834.933-0.8%-1.7%-1.3%-1.0%-1.9%-1.1%
8/21/010.5181.0025.0023.6%0.2%0.0%2.6%-1.7%-1.1%
8/22/010.5081.0134.9831.6%1.3%-0.3%4.2%-0.4%-1.4%
8/23/010.5050.9934.9231.0%-0.7%-1.5%5.2%-1.1%-2.9%
Mean:0.50330.99864.9816Mean:0.50330.99864.9816
Std. Dev.0.00770.00980.0488Ext. Uncertainty3.05%1.97%1.96%
SD %:1.52%0.98%0.98%Diff-% to Reference0.65%-0.14%-0.37%
Cupru
Crom
Plumb
Mangan
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4760.9865.001-4.8%-1.4%0.0%-4.8%-1.4%0.0%
8/15/010.4911.0005.003-1.8%0.0%0.1%-6.6%-1.4%0.1%
8/16/010.4880.9625.060-2.4%-3.8%1.2%-9.0%-5.2%1.3%
8/17/010.4831.0004.964-3.4%0.0%-0.7%-12.4%-5.2%0.6%
8/20/010.4980.9874.967-0.4%-1.3%-0.7%-12.8%-6.5%-0.1%
8/21/010.4990.9594.891-0.2%-4.1%-2.2%-13.0%-10.6%-2.3%
8/22/010.4971.0135.029-0.6%1.3%0.6%-13.6%-9.3%-1.7%
8/23/010.5110.9854.9102.2%-1.5%-1.8%-11.4%-10.8%-3.5%
Mean:0.49290.98654.9781Mean:0.49290.98654.9781
Std. Dev.0.01080.01860.0573Ext. Uncertainty4.39%3.77%2.30%
SD %:2.19%1.89%1.15%Diff-% to Reference-1.43%-1.35%-0.44%
Plumb
Cadmiu
Cupru
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5150.9964.9633.0%-0.4%-0.7%3.0%-0.4%-0.7%
8/15/010.3990.9944.955-20.2%-0.6%-0.9%-17.2%-1.0%-1.6%
8/16/010.5061.0055.0241.2%0.5%0.5%-16.0%-0.5%-1.2%
8/17/010.4970.9854.973-0.6%-1.5%-0.5%-16.6%-2.0%-1.7%
8/20/010.5080.9865.0001.6%-1.4%0.0%-15.0%-3.4%-1.7%
8/21/010.4980.9814.961-0.4%-1.9%-0.8%-15.4%-5.3%-2.5%
8/22/010.4980.9975.036-0.4%-0.3%0.7%-15.8%-5.6%-1.8%
8/23/010.5270.9805.0155.4%-2.0%0.3%-10.4%-7.6%-1.5%
Mean:0.49350.99054.9909Mean:0.49350.99054.9909
Std. Dev.0.03950.00880.0318Ext. Uncertainty16.02%1.78%1.27%
SD %:8.01%0.89%0.64%Diff-% to Reference-1.30%-0.95%-0.18%
Crom
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5211.0565.2484.2%5.6%5.0%4.2%5.6%5.0%
8/15/010.4951.0745.176-1.0%7.4%3.5%3.2%13.0%8.5%
8/16/010.4931.0585.167-1.4%5.8%3.3%1.8%18.8%11.8%
8/17/010.5501.0585.43710.0%5.8%8.7%11.8%24.6%20.6%
8/20/010.5211.0255.1884.2%2.5%3.8%16.0%27.1%24.3%
8/21/010.5961.0945.42119.2%9.4%8.4%35.2%36.5%32.7%
8/22/010.5061.0235.2691.2%2.3%5.4%36.4%38.8%38.1%
8/23/010.5491.0165.3749.8%1.6%7.5%46.2%40.4%45.6%
Mean:0.52891.05055.2850Mean:0.52891.05055.2850
Std. Dev.0.03470.02720.1111Ext. Uncertainty13.13%5.18%4.20%
SD %:6.57%2.59%2.10%Diff-% to Reference5.78%5.05%5.70%
Plumb
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0002.0000.5001.0002.000
Concentratii standard00.5001.0002.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5341.0801.8976.8%8.0%-5.2%6.8%8.0%-5.2%
8/15/010.4460.9532.035-10.8%-4.7%1.8%-4.0%3.3%-3.4%
8/16/010.4230.7941.866-15.4%-20.6%-6.7%-19.4%-17.3%-10.1%
8/17/010.5591.0811.96711.8%8.1%-1.7%-7.6%-9.2%-11.8%
8/20/010.4831.0061.957-3.4%0.6%-2.2%-11.0%-8.6%-13.9%
8/21/010.4040.8941.821-19.2%-10.6%-9.0%-30.2%-19.2%-22.9%
8/22/010.4850.9511.912-3.0%-4.9%-4.4%-33.2%-24.1%-27.3%
8/23/010.4770.9491.941-4.6%-5.1%-3.0%-37.8%-29.2%-30.2%
Mean:0.47640.96351.9245Mean:0.47640.96351.9245
Std. Dev.0.05250.09500.0659Ext. Uncertainty22.03%19.73%6.85%
SD %:11.02%9.86%3.42%Diff-% to Reference-4.73%-3.65%-3.77%
Cadmiu
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4971.0094.996-0.6%0.9%-0.1%-0.6%0.9%-0.1%
8/15/010.5111.0165.0352.2%1.6%0.7%1.6%2.5%0.6%
8/16/010.5000.9764.9720.0%-2.4%-0.6%1.6%0.1%0.1%
8/17/010.5021.0115.0410.4%1.1%0.8%2.0%1.2%0.9%
8/20/010.5131.0114.9672.6%1.1%-0.7%4.6%2.3%0.2%
8/21/010.5141.0425.0892.8%4.2%1.8%7.4%6.5%2.0%
8/22/010.4991.0085.030-0.2%0.8%0.6%7.2%7.3%2.6%
8/23/010.5081.0015.0011.6%0.1%0.0%8.8%7.4%2.6%
Mean:0.50551.00935.0164Mean:0.50551.00935.0164
Std. Dev.0.00680.01810.0405Ext. Uncertainty2.68%3.59%1.61%
SD %:1.34%1.80%0.81%Diff-% to Reference1.10%0.92%0.33%
Manfred Kindler
Summary
ICIM Lab #2 AAS
ParameterExt. UncDiff%
Ni 0,5472.00 %177.00 %
Ni 1,0333.00 %82.00 %
Ni 5,0210.00 %37.00 %
Zn 0,5305.00 %65.00 %
Zn 1,0197.00 %-14.00 %
Zn 5,0196.00 %-37.00 %
Mn 0,5439.00 %-143.00 %
Mn 1,0377.00 %-135.00 %
Mn 5,0230.00 %-44.00 %
Cu 0,5415.00 %123.00 %
Cu 1,0178.00 %-95.00 %
Cu 5,0127.00 %-18.00 %
Cr 0,51313.00 %578.00 %
Cr 1,0518.00 %505.00 %
Cr 5,0420.00 %570.00 %
Pb 0,52203.00 %-473.00 %
Pb 1,01973.00 %-365.00 %
Pb 2,0685.00 %-377.00 %
Cd 0,5268.00 %110.00 %
Cd 1,0359.00 %92.00 %
Cd 5,0161.00 %33.00 %
Summary
Pb 2,0
Pb 1,0
Pb 0,5
Cr 1,0
Cr 0,5
Cr 5,0
Ni 0,5
Cu 0,5
Mn 0,5
Mn 1,0
Ni 0,5 Ni 1,0 Ni 5,0
Zn 0,5 Zn 1,0 Zn 5,0
Mn 0,5 Mn 1,0 Mn 5,0
Cu 0,5 Cu 1,0 Cu 5,0
Cr 0,5 Cr 1,0 Cr 5,0
Pb 0,5 Pb 1,0 Pb 2,0
Cd 0,5 Cd 1,0 Cd 5,0
Extended Uncertainty %
Difference % to Reference
All CuSums
low Concentrationhigh Concentration
NiZnMnCuCrPbCdNiZnMnCuCrPbCd
8/14/01-2.4%-1.4%-4.8%3.0%-1.4%6.8%-0.6%8/14/01-0.6%-0.6%0.0%-0.7%5.0%-5.2%-0.1%
8/15/01-1.0%-1.2%-6.6%-17.2%-2.6%-4.0%1.6%8/15/01-1.2%-0.3%0.1%-1.6%8.5%-3.4%0.6%
8/16/010.6%-0.4%-9.0%-16.0%-3.0%-19.4%1.6%8/16/01-0.0%-1.2%1.3%-1.2%11.8%-10.1%0.1%
8/17/010.0%-0.2%-12.4%-16.6%-3.2%-7.6%2.0%8/17/010.1%0.2%0.6%-1.7%20.6%-11.8%0.9%
8/20/013.6%-1.0%-12.8%-15.0%-4.2%-11.0%4.6%8/20/012.4%-1.1%-0.1%-1.7%24.3%-13.9%0.2%
8/21/018.6%2.6%-13.0%-15.4%-1.6%-30.2%7.4%8/21/012.4%-1.1%-2.3%-2.5%32.7%-22.9%2.0%
8/22/0110.6%4.2%-13.6%-15.8%2.6%-33.2%7.2%8/22/011.8%-1.4%-1.7%-1.8%38.1%-27.3%2.6%
8/23/0114.2%5.2%-11.4%-10.4%7.8%-37.8%8.8%8/23/012.9%-2.9%-3.5%-1.5%45.6%-30.2%2.6%
All CuSums
Ni
Zn
Mn
Cu
Cr
Pb
Cd
Cumulative Sum %
Low Concentration
Nichel
Ni
Zn
Mn
Cu
Cr
Pb
Cd
Cumulative Sum %
High Concentration
Zinc
Nichel
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4880.9824.968-2.4%-1.8%-0.6%-2.4%-1.8%-0.6%
8/15/010.5071.0314.9731.4%3.1%-0.5%-1.0%1.3%-1.2%
8/16/010.5081.0265.0571.6%2.6%1.1%0.6%3.9%-0.0%
8/17/010.4971.0025.006-0.6%0.2%0.1%0.0%4.1%0.1%
8/20/010.5181.0075.1163.6%0.7%2.3%3.6%4.8%2.4%
8/21/010.5251.0164.9985.0%1.6%-0.0%8.6%6.4%2.4%
8/22/010.5101.0124.9742.0%1.2%-0.5%10.6%7.6%1.8%
8/23/010.5180.9905.0543.6%-1.0%1.1%14.2%6.6%2.9%
Mean:0.50891.00835.0183Mean:0.50891.00835.0183
Std. Dev.0.01200.01680.0527Ext. Uncertainty4.72%3.33%2.10%
SD %:2.36%1.66%1.05%Diff-% to Reference1.77%0.82%0.37%
Zinc
Mangan
Cupru
Zinc
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4931.0054.969-1.4%0.5%-0.6%-1.4%0.5%-0.6%
8/15/010.5011.0075.0160.2%0.7%0.3%-1.2%1.2%-0.3%
8/16/010.5040.9914.9540.8%-0.9%-0.9%-0.4%0.3%-1.2%
8/17/010.5010.9955.0730.2%-0.5%1.5%-0.2%-0.2%0.2%
8/20/010.4960.9834.933-0.8%-1.7%-1.3%-1.0%-1.9%-1.1%
8/21/010.5181.0025.0023.6%0.2%0.0%2.6%-1.7%-1.1%
8/22/010.5081.0134.9831.6%1.3%-0.3%4.2%-0.4%-1.4%
8/23/010.5050.9934.9231.0%-0.7%-1.5%5.2%-1.1%-2.9%
Mean:0.50330.99864.9816Mean:0.50330.99864.9816
Std. Dev.0.00770.00980.0488Ext. Uncertainty3.05%1.97%1.96%
SD %:1.52%0.98%0.98%Diff-% to Reference0.65%-0.14%-0.37%
Cupru
Crom
Plumb
Mangan
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4760.9865.001-4.8%-1.4%0.0%-4.8%-1.4%0.0%
8/15/010.4911.0005.003-1.8%0.0%0.1%-6.6%-1.4%0.1%
8/16/010.4880.9625.060-2.4%-3.8%1.2%-9.0%-5.2%1.3%
8/17/010.4831.0004.964-3.4%0.0%-0.7%-12.4%-5.2%0.6%
8/20/010.4980.9874.967-0.4%-1.3%-0.7%-12.8%-6.5%-0.1%
8/21/010.4990.9594.891-0.2%-4.1%-2.2%-13.0%-10.6%-2.3%
8/22/010.4971.0135.029-0.6%1.3%0.6%-13.6%-9.3%-1.7%
8/23/010.5110.9854.9102.2%-1.5%-1.8%-11.4%-10.8%-3.5%
Mean:0.49290.98654.9781Mean:0.49290.98654.9781
Std. Dev.0.01080.01860.0573Ext. Uncertainty4.39%3.77%2.30%
SD %:2.19%1.89%1.15%Diff-% to Reference-1.43%-1.35%-0.44%
Plumb
Cadmiu
Cupru
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5150.9964.9633.0%-0.4%-0.7%3.0%-0.4%-0.7%
8/15/010.3990.9944.955-20.2%-0.6%-0.9%-17.2%-1.0%-1.6%
8/16/010.5061.0055.0241.2%0.5%0.5%-16.0%-0.5%-1.2%
8/17/010.4970.9854.973-0.6%-1.5%-0.5%-16.6%-2.0%-1.7%
8/20/010.5080.9865.0001.6%-1.4%0.0%-15.0%-3.4%-1.7%
8/21/010.4980.9814.961-0.4%-1.9%-0.8%-15.4%-5.3%-2.5%
8/22/010.4980.9975.036-0.4%-0.3%0.7%-15.8%-5.6%-1.8%
8/23/010.5270.9805.0155.4%-2.0%0.3%-10.4%-7.6%-1.5%
Mean:0.49350.99054.9909Mean:0.49350.99054.9909
Std. Dev.0.03950.00880.0318Ext. Uncertainty16.02%1.78%1.27%
SD %:8.01%0.89%0.64%Diff-% to Reference-1.30%-0.95%-0.18%
Crom
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5211.0565.2484.2%5.6%5.0%4.2%5.6%5.0%
8/15/010.4951.0745.176-1.0%7.4%3.5%3.2%13.0%8.5%
8/16/010.4931.0585.167-1.4%5.8%3.3%1.8%18.8%11.8%
8/17/010.5501.0585.43710.0%5.8%8.7%11.8%24.6%20.6%
8/20/010.5211.0255.1884.2%2.5%3.8%16.0%27.1%24.3%
8/21/010.5961.0945.42119.2%9.4%8.4%35.2%36.5%32.7%
8/22/010.5061.0235.2691.2%2.3%5.4%36.4%38.8%38.1%
8/23/010.5491.0165.3749.8%1.6%7.5%46.2%40.4%45.6%
Mean:0.52891.05055.2850Mean:0.52891.05055.2850
Std. Dev.0.03470.02720.1111Ext. Uncertainty13.13%5.18%4.20%
SD %:6.57%2.59%2.10%Diff-% to Reference5.78%5.05%5.70%
Plumb
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0002.0000.5001.0002.000
Concentratii standard00.5001.0002.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5341.0801.8976.8%8.0%-5.2%6.8%8.0%-5.2%
8/15/010.4460.9532.035-10.8%-4.7%1.8%-4.0%3.3%-3.4%
8/16/010.4230.7941.866-15.4%-20.6%-6.7%-19.4%-17.3%-10.1%
8/17/010.5591.0811.96711.8%8.1%-1.7%-7.6%-9.2%-11.8%
8/20/010.4831.0061.957-3.4%0.6%-2.2%-11.0%-8.6%-13.9%
8/21/010.4040.8941.821-19.2%-10.6%-9.0%-30.2%-19.2%-22.9%
8/22/010.4850.9511.912-3.0%-4.9%-4.4%-33.2%-24.1%-27.3%
8/23/010.4770.9491.941-4.6%-5.1%-3.0%-37.8%-29.2%-30.2%
Mean:0.47640.96351.9245Mean:0.47640.96351.9245
Std. Dev.0.05250.09500.0659Ext. Uncertainty22.03%19.73%6.85%
SD %:11.02%9.86%3.42%Diff-% to Reference-4.73%-3.65%-3.77%
Cadmiu
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4971.0094.996-0.6%0.9%-0.1%-0.6%0.9%-0.1%
8/15/010.5111.0165.0352.2%1.6%0.7%1.6%2.5%0.6%
8/16/010.5000.9764.9720.0%-2.4%-0.6%1.6%0.1%0.1%
8/17/010.5021.0115.0410.4%1.1%0.8%2.0%1.2%0.9%
8/20/010.5131.0114.9672.6%1.1%-0.7%4.6%2.3%0.2%
8/21/010.5141.0425.0892.8%4.2%1.8%7.4%6.5%2.0%
8/22/010.4991.0085.030-0.2%0.8%0.6%7.2%7.3%2.6%
8/23/010.5081.0015.0011.6%0.1%0.0%8.8%7.4%2.6%
Mean:0.50551.00935.0164Mean:0.50551.00935.0164
Std. Dev.0.00680.01810.0405Ext. Uncertainty2.68%3.59%1.61%
SD %:1.34%1.80%0.81%Diff-% to Reference1.10%0.92%0.33%
Manfred Kindler
Summary
ICIM Lab #2 AAS
ParameterExt. UncDiff%
Ni 0,5472.00 %177.00 %
Ni 1,0333.00 %82.00 %
Ni 5,0210.00 %37.00 %
Zn 0,5305.00 %65.00 %
Zn 1,0197.00 %-14.00 %
Zn 5,0196.00 %-37.00 %
Mn 0,5439.00 %-143.00 %
Mn 1,0377.00 %-135.00 %
Mn 5,0230.00 %-44.00 %
Cu 0,5415.00 %123.00 %
Cu 1,0178.00 %-95.00 %
Cu 5,0127.00 %-18.00 %
Cr 0,51313.00 %578.00 %
Cr 1,0518.00 %505.00 %
Cr 5,0420.00 %570.00 %
Pb 0,52203.00 %-473.00 %
Pb 1,01973.00 %-365.00 %
Pb 2,0685.00 %-377.00 %
Cd 0,5268.00 %110.00 %
Cd 1,0359.00 %92.00 %
Cd 5,0161.00 %33.00 %
Summary
Pb 2,0
Pb 1,0
Pb 0,5
Cr 1,0
Cr 0,5
Cr 5,0
Ni 0,5
Cu 0,5
Mn 0,5
Mn 1,0
Ni 0,5 Ni 1,0 Ni 5,0
Zn 0,5 Zn 1,0 Zn 5,0
Mn 0,5 Mn 1,0 Mn 5,0
Cu 0,5 Cu 1,0 Cu 5,0
Cr 0,5 Cr 1,0 Cr 5,0
Pb 0,5 Pb 1,0 Pb 2,0
Cd 0,5 Cd 1,0 Cd 5,0
Extended Uncertainty %
Difference % to Reference
All CuSums
low Concentrationhigh Concentration
NiZnMnCuCrPbCdNiZnMnCuCrPbCd
8/14/01-2.4%-1.4%-4.8%3.0%-1.4%6.8%-0.6%8/14/01-0.6%-0.6%0.0%-0.7%5.0%-5.2%-0.1%
8/15/01-1.0%-1.2%-6.6%-17.2%-2.6%-4.0%1.6%8/15/01-1.2%-0.3%0.1%-1.6%8.5%-3.4%0.6%
8/16/010.6%-0.4%-9.0%-16.0%-3.0%-19.4%1.6%8/16/01-0.0%-1.2%1.3%-1.2%11.8%-10.1%0.1%
8/17/010.0%-0.2%-12.4%-16.6%-3.2%-7.6%2.0%8/17/010.1%0.2%0.6%-1.7%20.6%-11.8%0.9%
8/20/013.6%-1.0%-12.8%-15.0%-4.2%-11.0%4.6%8/20/012.4%-1.1%-0.1%-1.7%24.3%-13.9%0.2%
8/21/018.6%2.6%-13.0%-15.4%-1.6%-30.2%7.4%8/21/012.4%-1.1%-2.3%-2.5%32.7%-22.9%2.0%
8/22/0110.6%4.2%-13.6%-15.8%2.6%-33.2%7.2%8/22/011.8%-1.4%-1.7%-1.8%38.1%-27.3%2.6%
8/23/0114.2%5.2%-11.4%-10.4%7.8%-37.8%8.8%8/23/012.9%-2.9%-3.5%-1.5%45.6%-30.2%2.6%
All CuSums
Ni
Zn
Mn
Cu
Cr
Pb
Cd
Cumulative Sum %
Low Concentration
Nichel
Ni
Zn
Mn
Cu
Cr
Pb
Cd
Cumulative Sum %
High Concentration
Zinc
Nichel
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4880.9824.968-2.4%-1.8%-0.6%-2.4%-1.8%-0.6%
8/15/010.5071.0314.9731.4%3.1%-0.5%-1.0%1.3%-1.2%
8/16/010.5081.0265.0571.6%2.6%1.1%0.6%3.9%-0.0%
8/17/010.4971.0025.006-0.6%0.2%0.1%0.0%4.1%0.1%
8/20/010.5181.0075.1163.6%0.7%2.3%3.6%4.8%2.4%
8/21/010.5251.0164.9985.0%1.6%-0.0%8.6%6.4%2.4%
8/22/010.5101.0124.9742.0%1.2%-0.5%10.6%7.6%1.8%
8/23/010.5180.9905.0543.6%-1.0%1.1%14.2%6.6%2.9%
Mean:0.50891.00835.0183Mean:0.50891.00835.0183
Std. Dev.0.01200.01680.0527Ext. Uncertainty4.72%3.33%2.10%
SD %:2.36%1.66%1.05%Diff-% to Reference1.77%0.82%0.37%
Zinc
Mangan
Cupru
Zinc
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4931.0054.969-1.4%0.5%-0.6%-1.4%0.5%-0.6%
8/15/010.5011.0075.0160.2%0.7%0.3%-1.2%1.2%-0.3%
8/16/010.5040.9914.9540.8%-0.9%-0.9%-0.4%0.3%-1.2%
8/17/010.5010.9955.0730.2%-0.5%1.5%-0.2%-0.2%0.2%
8/20/010.4960.9834.933-0.8%-1.7%-1.3%-1.0%-1.9%-1.1%
8/21/010.5181.0025.0023.6%0.2%0.0%2.6%-1.7%-1.1%
8/22/010.5081.0134.9831.6%1.3%-0.3%4.2%-0.4%-1.4%
8/23/010.5050.9934.9231.0%-0.7%-1.5%5.2%-1.1%-2.9%
Mean:0.50330.99864.9816Mean:0.50330.99864.9816
Std. Dev.0.00770.00980.0488Ext. Uncertainty3.05%1.97%1.96%
SD %:1.52%0.98%0.98%Diff-% to Reference0.65%-0.14%-0.37%
Cupru
Crom
Plumb
Mangan
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4760.9865.001-4.8%-1.4%0.0%-4.8%-1.4%0.0%
8/15/010.4911.0005.003-1.8%0.0%0.1%-6.6%-1.4%0.1%
8/16/010.4880.9625.060-2.4%-3.8%1.2%-9.0%-5.2%1.3%
8/17/010.4831.0004.964-3.4%0.0%-0.7%-12.4%-5.2%0.6%
8/20/010.4980.9874.967-0.4%-1.3%-0.7%-12.8%-6.5%-0.1%
8/21/010.4990.9594.891-0.2%-4.1%-2.2%-13.0%-10.6%-2.3%
8/22/010.4971.0135.029-0.6%1.3%0.6%-13.6%-9.3%-1.7%
8/23/010.5110.9854.9102.2%-1.5%-1.8%-11.4%-10.8%-3.5%
Mean:0.49290.98654.9781Mean:0.49290.98654.9781
Std. Dev.0.01080.01860.0573Ext. Uncertainty4.39%3.77%2.30%
SD %:2.19%1.89%1.15%Diff-% to Reference-1.43%-1.35%-0.44%
Plumb
Cadmiu
Cupru
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5150.9964.9633.0%-0.4%-0.7%3.0%-0.4%-0.7%
8/15/010.3990.9944.955-20.2%-0.6%-0.9%-17.2%-1.0%-1.6%
8/16/010.5061.0055.0241.2%0.5%0.5%-16.0%-0.5%-1.2%
8/17/010.4970.9854.973-0.6%-1.5%-0.5%-16.6%-2.0%-1.7%
8/20/010.5080.9865.0001.6%-1.4%0.0%-15.0%-3.4%-1.7%
8/21/010.4980.9814.961-0.4%-1.9%-0.8%-15.4%-5.3%-2.5%
8/22/010.4980.9975.036-0.4%-0.3%0.7%-15.8%-5.6%-1.8%
8/23/010.5270.9805.0155.4%-2.0%0.3%-10.4%-7.6%-1.5%
Mean:0.49350.99054.9909Mean:0.49350.99054.9909
Std. Dev.0.03950.00880.0318Ext. Uncertainty16.02%1.78%1.27%
SD %:8.01%0.89%0.64%Diff-% to Reference-1.30%-0.95%-0.18%
Crom
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5211.0565.2484.2%5.6%5.0%4.2%5.6%5.0%
8/15/010.4951.0745.176-1.0%7.4%3.5%3.2%13.0%8.5%
8/16/010.4931.0585.167-1.4%5.8%3.3%1.8%18.8%11.8%
8/17/010.5501.0585.43710.0%5.8%8.7%11.8%24.6%20.6%
8/20/010.5211.0255.1884.2%2.5%3.8%16.0%27.1%24.3%
8/21/010.5961.0945.42119.2%9.4%8.4%35.2%36.5%32.7%
8/22/010.5061.0235.2691.2%2.3%5.4%36.4%38.8%38.1%
8/23/010.5491.0165.3749.8%1.6%7.5%46.2%40.4%45.6%
Mean:0.52891.05055.2850Mean:0.52891.05055.2850
Std. Dev.0.03470.02720.1111Ext. Uncertainty13.13%5.18%4.20%
SD %:6.57%2.59%2.10%Diff-% to Reference5.78%5.05%5.70%
Plumb
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0002.0000.5001.0002.000
Concentratii standard00.5001.0002.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.5341.0801.8976.8%8.0%-5.2%6.8%8.0%-5.2%
8/15/010.4460.9532.035-10.8%-4.7%1.8%-4.0%3.3%-3.4%
8/16/010.4230.7941.866-15.4%-20.6%-6.7%-19.4%-17.3%-10.1%
8/17/010.5591.0811.96711.8%8.1%-1.7%-7.6%-9.2%-11.8%
8/20/010.4831.0061.957-3.4%0.6%-2.2%-11.0%-8.6%-13.9%
8/21/010.4040.8941.821-19.2%-10.6%-9.0%-30.2%-19.2%-22.9%
8/22/010.4850.9511.912-3.0%-4.9%-4.4%-33.2%-24.1%-27.3%
8/23/010.4770.9491.941-4.6%-5.1%-3.0%-37.8%-29.2%-30.2%
Mean:0.47640.96351.9245Mean:0.47640.96351.9245
Std. Dev.0.05250.09500.0659Ext. Uncertainty22.03%19.73%6.85%
SD %:11.02%9.86%3.42%Diff-% to Reference-4.73%-3.65%-3.77%
Cadmiu
DataConcentratii determinateDifferencesCumulated sums
(mg/l)0.5001.0005.0000.5001.0005.000
Concentratii standard00.5001.0005.000Serie 1Serie 2Serie 3Serie 1Serie 2Serie 3
8/14/010.4971.0094.996-0.6%0.9%-0.1%-0.6%0.9%-0.1%
8/15/010.5111.0165.0352.2%1.6%0.7%1.6%2.5%0.6%
8/16/010.5000.9764.9720.0%-2.4%-0.6%1.6%0.1%0.1%
8/17/010.5021.0115.0410.4%1.1%0.8%2.0%1.2%0.9%
8/20/010.5131.0114.9672.6%1.1%-0.7%4.6%2.3%0.2%
8/21/010.5141.0425.0892.8%4.2%1.8%7.4%6.5%2.0%
8/22/010.4991.0085.030-0.2%0.8%0.6%7.2%7.3%2.6%
8/23/010.5081.0015.0011.6%0.1%0.0%8.8%7.4%2.6%
Mean:0.50551.00935.0164Mean:0.50551.00935.0164
Std. Dev.0.00680.01810.0405Ext. Uncertainty2.68%3.59%1.61%
SD %:1.34%1.80%0.81%Diff-% to Reference1.10%0.92%0.33%
La Acreditacin e ISO 17025 Ejemplo 3
Manfred Kindler
Manfred Kindler
Summary
ICIM Lab #1 AAS
ParameterExt. UncDiff%
Ni1980.0 %781.00 %
Ni PE1200.0 %18.00 %
Cd3030.0 %1018.00 %
Cd PE790.0 %11.00 %
Cu2220.0 %935.00 %
Cu PE650.0 %-77.00 %
Cr1750.0 %215.00 %
Cr PE680.0 %60.00 %
Pb
Pb PE2410.0 %844.00 %
Zn
Zn PE564.0 %32.00 %
Summary
Cd
Pb PE
Cu
Ni
Cr
Ni PE
Cu PE
Cr PE
Zn PE
Cd PE
Ni
Ni PE
Cd
Cd PE
Cu
Cu PE
Cr
Cr PE
Pb PE
Zn PE
Extended Uncertainty %
Difference % to Reference
All CuSums
NiCdCuCrNi PECd PECu PECr PEPb PEZn PE
1-4.2%15.2%8.0%-0.5%14.4%5.5%2.1%1.6%12.6%2.7%
21.6%39.0%11.8%-7.6%23.9%3.9%2.3%-1.5%3.0%0.8%
3-0.7%71.1%23.1%-15.9%33.4%5.8%2.9%4.6%23.9%0.1%
415.0%79.2%30.7%-12.6%40.6%3.1%0.4%2.5%25.8%-3.4%
517.7%75.4%35.9%-5.7%51.3%-6.4%4.8%31.8%-2.9%
642.4%93.7%40.2%-12.9%6-1.1%-5.8%5.7%32.6%-6.8%
756.1%122.3%49.6%2.4%7-7.3%5.2%30.6%-6.9%
865.4%133.2%73.6%13.2%8-9.6%5.8%29.2%-4.6%
974.8%147.0%91.0%7.4%9-9.9%6.2%49.8%-2.1%
1072.5%148.9%11.6%10-8.9%6.2%-4.2%
11146.8%15.7%11-10.7%-5.7%
128.1%12-6.9%
1313-7.0%
1414-6.0%
1515-5.1%
16160.5%
17173.0%
18182.3%
19194.8%
2020
All CuSums
Ni
Cd
Cu
Cr
Cumulative Sum %
Ni
Ni PE
Cd PE
Cu PE
Cr PE
Pb PE
Zn PE
Cumulative Sum %
Ni PE
Cod laboratorW.M.L.
G.C.-5.10-1
Parametru:NiMean=10.781SD=1.07Extended Uncertainty=19.8%n=23
Aparat de masura:S.A.A. tip Unicam 939 +GF
Ref. Value:10.000Difference:7.81%
Inregistrari pentru graficul de control
Nr.DataStatistics
crt.Masuratorii12345678910MeanSDDiff%CuSum
12/5/009.589.58-4.2%-4.2%
22/23/0010.5810.585.8%1.6%
35/8/009.969.579.770.28-2.3%-0.7%
44/4/0110.3211.9212.4811.571.1215.7%15.0%
55/28/0110.3210.0312.318.4110.271.602.7%17.7%
65/31/0112.4712.4724.7%42.4%
76/5/0111.8510.8911.370.6813.7%56.1%
86/6/0111.389.7910.7211.8510.940.899.4%65.4%
97/17/0110.4910.6211.2111.4410.940.469.4%74.8%
107/18/019.779.77-2.3%72.5%
117/18/010.000.000.0%0.0%
127/18/010.000.000.0%0.0%
137/18/010.000.000.0%0.0%
147/18/010.000.000.0%0.0%
157/18/010.000.000.0%0.0%
167/18/010.000.000.0%0.0%
177/18/010.000.000.0%0.0%
187/18/010.000.000.0%0.0%
197/18/010.000.000.0%0.0%
207/18/010.000.000.0%0.0%
217/18/010.000.000.0%0.0%
227/18/010.000.000.0%0.0%
237/18/010.000.000.0%0.0%
247/18/010.000.000.0%0.0%
257/18/010.000.000.0%0.0%
267/18/010.000.000.0%0.0%
277/18/010.000.000.0%0.0%
287/18/010.000.000.0%0.0%
297/18/010.000.000.0%0.0%
307/18/010.000.000.0%0.0%
317/18/010.000.000.0%0.0%
327/18/010.000.000.0%0.0%
337/18/010.000.000.0%0.0%
347/18/010.000.000.0%0.0%
357/18/010.000.000.0%0.0%
367/18/010.000.000.0%0.0%
Ni PE
0.27930717860.2793071786
1.12095197641.1209519764
1.6001328071.600132807
0.67882250990.6788225099
0.8930285550.893028555
0.45745673750.4574567375
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
00
Cd
Cd PE
Cod laboratorW.M.L.
G.C.-5.10-1
Parametru:NiMean=0.5009SD=0.030Extended Uncertainty=12.0%n=26
Aparat de masura:S.A.A. tip Perkni Elmer 2380
Ref. Value:0.500Difference:0.18%
Inregistrari pentru graficul de control
Nr.DataStatistics
crt.Masuratorii12345678910MeanSDDiff%CuSum
17/12/010.5420.5440.6140.4990.4630.4690.5220.0574.4%4.4%
27/23/010.5020.4930.5090.4960.4890.4980.008-0.4%3.9%
38/10/010.4850.4750.5150.5240.5030.4930.4890.4980.4950.4960.4970.014-0