SECTION 24(C) REGISTRATION FOR

• •

EMULSIFIABLE CONCENTRATEFOR USE ON GINKGO TREES

FOR DISTRIBUTION AND USE ONLY WITHIN DISTRICT OF COLUMBIA.

ALL APPLICABLE DIRECTIONS, RESTRICTIONS, AND PRECAUTIONS ON THE EPALABEL ARE TO BE FOLLOWED. THIS LABEL MUST BE IN POSSESSION OF USER ATTHE TIME OF APPLICATION.

DIRECTIONS FOR USEIt is a violation of Federal Law to use this product in a manner inconsistent with its labeling.

FOR USE ONLY BY FEDERAL OR DISTRICT AGENCIES

GINKGO (GINKGO BILOBA) TREES: To control fruiting, apply within 3 weeks followingpollination when the young fruit is responsive. Pollination in the District of Columbia usuallyoccurs the third week of April. Mix as shown below and apply with a mist blower to nearly thepoint of runoff.

Amount of This Product Amount of Water

4.25 fluid ounces 5 gallons

84.5 fluid ounces(5 pints + 4.5 fluid ounces) . 100 gallons

1 gallon 151.5 gallons

Notices: To avoid foliage burn, do not apply when temperature is above 80T Avoid directapplication or drift to non target species, as leaf spotting may occur. Do not apply this productthrough any type of irrigation system. Do not use on ginkgo trees which produce ginkgo nutsdestined for human consumption.

EPA REG. NO. 2749·70 EPA SLN NO. DC-120001Registration Expires December 31,2018

24(c) Registrant:Aceto Agricultural Chemicals Corp.

4 Tri Harbor CourtPort Washington, NY 11050-4661

Phone: 516-627-6000

REV:09202012

Aif10-;"~

flR8

TA

ID

=~~Ot........,...,'IfI!I*I.....

poMI"lC

ICd'al:alW

W..~~~kr

IIIan

ufa

cttnd

Far:A

.-A

grladlurUC

hotnIcUI~

an._~

lJIbsu

.:c..;NV

110Q"'-1

11

1-8

%1

""

~,

AC

ET

O"""=

CM

,1W

ClJ~OPSAU!

~~

~rnePlla)\;Cl'~TO",oec.AL~NCtai

_Y

m_

nE

"-"',O

'l1Y

)O

Il_t-

._

_.~

W""DIlIl~lHI!R_

_Ofu.."",~_-.v_

_G

'nCl<

..-T

Y'"""""'*'""""

OIl

I'II'IGO

I"'"

...........eu.NI"-­

_""_

_TO-_Ol'~_~rou,en

~CI!l

_-.

QlO

IllltlON

Ia

ll_

CC

IQllC

JIIM

OT~'r~1l)~NiQ)'\MIR"""""'"

-.cfO

l'.Nl't

au

ckQR

.

DIL

UnO

l'CO

I'T1IIIC

Ol\'C

EI01lA

l'E

AM

1J.-:D

WI£

C..u

~_

U.

....................41I1DW

"'(L~.,~.~

d,....a

l0

._.............

-"'.......

~:M

__

_,.,..........

1'io

na

~Alilltl:K"...-:w..a-

_~.,

'---_iIIC

1:la1

11

,.:b:_

.-.....---.

~....,_~

APP1.JCA

TlOM

~1HIIII:1!C"""'

••'''''''''~''''''CII''''''IIIlI"",,~n.

.....~.......-

~~~

...,__,...'IIIIItt...

..................JIIUIIIld

..".~~

.,....~

~_

.__.00

""""...__

-_

_O

'IIOl...

·OIIII~CIIQ.01Ot

...f{I/~MI'tollD..-~

......"

..,............_--------­•..,_

w_

_.........._

_.._

_...

...ec:a..-..r:.....2IIP.

STO

RA

GE

AlID

IlISI'OSA

L'PIIIOtIIJIftDIlfa:Oo.'ICII~

hbd'lll"bJ~"~

ao.t~'-

r.=1EDISPOML.:w.e.'41~

,....

alI....~IM

f"N-'-

da

n...

..~...

~....,.

CQtfT_~

T_l<o~l

...._...........

_..

=...~.,.,..CII

..-,.~Of'~"""'"proc~~t.r......

.mlo

cll

~oo-oo_

_....-_

............_--

U••r

3rifly

R.com~onl::

l""'_.

t..=-~~·::t::.::=..

=....~=I'.=~~~1

----.

~=..~_:..."';'"'9':_:t:;..~-=~...-"':i..-

~

~=::...==z=,~===-~~--~

UIn

Ey

!HI.=

.........-.............,1tlf

1s.a

~CIriId_

_..~..,

5.....

---O

Ildl:IcB

'....DMl!mW4~

rrrin6ldn'orI'

T_

_C

1<llhlrlg•

__

...._ot_""..·,._•

c..a.IdIoIt~"""lIIdadar*"

PH

Y9

ICA

I.HA

ZA

RD

,tolIIOCHEt'llC~1."~ARD

OO...

_b

IlM...........

_..

k..

.....,•...,......,~01'~

I'sw.n_

I,...._

-_

.._._~~'

.....--

..........-~.~flI

J.....u~

Da

....~........~

laillr·f"C*O":~Ql'-Ct

_.

1,3­~

rEllSO

HA

LI'R

OT

EC

TIV

SE

Cllllrlrem

("FE

)~"""""'~1a_~WllI""~

llpiwwi.........'*'-1IIt~tar~AOfI

~~~iIINIJG'I....,.~

................-;d-*

::II~

............,.,..

..............~

.........,....~

.....~~~

~DIUd......-:'

•~

~bIg~

__....

~..-..n:

(JIIWB~

aft.m

.......tM"~

.....,..rtItlM

t.:w

rq

nn

IM

lMr,

~1IIIhIDftl:liII0I"'~

a.c...~_.cdIIf..-....~...~ItelII'~ar~~

......~.~L'IOrw:lIt_

_mr.n..

DlR

Ecn

01

l1lF

OR

US

S.......u

.-JI;'-.~fJlF........~

......~iIrl.~~WIIb

..

- OO

m.,.,.......

~Ia

•.,.i1d..~~IllIt"..~....,.,diI:~ar~li1Il

lll1r...-

..

ElIV

IRO

NM

El'llA

LII.~

-......."-10

""""----

.............._--

...........

01

')t

.,.,..,.,...,....wl..~~

...-..1_-,.......----........

""".._0.""'_-__...--_--~

hta

ll.....

-..rmm

t~~

Fer~

'CII::lfU

(I.,..$

l1liw

.-ea.m

tit

~CWar#-""'"

.

..

·,··~w•

EP

AR

eg.No.27-4&-70

EP

A&

t.No.37Ii07-M

T-1

EM

UL

SIF

IAB

LE

CO

NC

EN

TR

AT

E

ACTlYElN

GRED

IENT

II)'W

IIlght

~~.

3e.o%

0T

HflR

ING

RED

IEImI

-Il!Jm

TOTA

L.100.0%

ca.c.nS

poonIa....1rv1NIonIJl'II'gIIIan.

FOR

AG

RIC

ULTU

RA

LU

SE

ON

LY

CA

UT

ION

KE

EP

OU

TO

FT

HE

RE

AC

HO

FC

HILD

RE

N

EJlE

RO

&IC

YIIFO

RIIA

TJOtI

Fo

rop

ll.-.

...._

_o

r8lld

den

lcd

CH

EM

TR

EC

1_

N.tCG

nlBnbo:0

5G

IIana0

30

lHIIa

N

PR

EC

AU

T10NA

RY

ST

AT

EM

EN

TS

HA

ZARD

STO

HliM

AH

sN

«J

DO

IoIESTlCA

Nlw

.LS

Hto

riJl.............,II'

_1hrougIl1lw

oJdn.e

a.-

rnodwno

IIYl'

~AIIOiO

__

..."_

_ordclh/ro.

u..o

nly

"'"~

..........~-"'**--_...-

MATERIAL SAFETY DATA SHEET SPROUT NIP® EC

FOR CHEMICAL EMERGENCY, SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT, CALL CHEMTREC. DAY OR NIGHT 1.80D-424-9300

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION .

FORMULATED FOR:

Loveland Products, Inc.P.O. Box 1288 • Greeley, CO 60632-1286

24-Hour Emergency Phone: 1-800-424·9300MedlCIII Emergenc,": 1-800-301-7976

U.S. Coest GuarQ Natlonal Rnponse center: 1-800-424-8802PRODUCT NAME: SPROUT NI~ EMULSIFIABLE CONCENTRATECHEMICAL NAME: 1s000opyi N- (3-chloropheoyQ carbamate; laopropyl3-chlorobanilate; ChlorprophamCHEMICAL FAMILY: CarbamateEPA REG. NO.: 34704-613MSOS Number: 000613-04b·LPI MSOS Revisions: See section 16 Dite Of Inue: 07/12104

2. HAZARDS IDENTIFICATION SUMMARY

Supe~ed8ll: 05124104

KEEP OUT OF REACH OF CHILDREN - CAUTION - Harmful if swallowed or absorbed through skin. Causas moderate eye Imlstlon. Do not taka intemally.Avoid contact with skin, eyes, or clothIng. Avoid breathing of vapor or spray mist.

This product is 8 dear, pale yellow liqUid with slight com oil odor.

3. COMPOSIT1ON, INFORMATION ON INGREDIENTS

Chem!callngrtdlents:

ChlorprophamIsopropyl AlcoholInert Ingredients

Pen;eDtaqe by Weight

36.0012.7551.25

~

101·21-367-63-0

TLy IUnlts.

none established492mg1m'

This product is hazardous according to the OSHA Hazard Communication Standard (29 CFR 1910.1200)

4. FIRST AtD MEASURES

If swallowed: Call a polson control center or doclor immediately for Ireatment advice. Have a person sip a glass of water if ablew toswallow. Do not Induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth toan unconscious person.

If in eyes: Hold eye open and rinse slowly and genUy with water 15-20 minutes. Remove contact lenses, if present. after the first 5minutes. then conUnue rfnslng eye, CaU a polson control cenlB( or doctor for treatment advlce.

If on akin or clothing: Take off contaminated clothing. Rinse skin with plenty or water for 15-20 minutes. Call a poison control centB( or doctor fortreatment advice.

If Inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artifidal respiration, prafel8bly bymoutjh-to-mouth If possible. Call a polson control center ordoctor for further treatment advice.

FOR A MEDICAL EMERGENCV INVOLVING THIS PRODUCT CALL: 1-800-301.71176. Have the prodUct container or label with you When calling a poison controlcenter or doctor.

6. FIRE FIGHTING MEASURES

FlASH POINT (OFITast Methodl:FlAMMABLE UMITS (LFL & UFL):EXTINGUISHING MEDIA:HAZARDOUS COMBUSTION PRODUCTS:

SPECIAL FIRE FIGHTING PROCEDURES:

UNUSUAL FIRE AND EXPLOSION HAZARDS:

6. ACCIDENTAL RELEASE MEASURES

76°FI24.4°C (TCC)LFL: 2.6; UFL: 12.6Considered tlammable; dry chemical, carbon dioxide, alcohol roam, foam, water spl8y or fog.ChloroaniDne, Isocyanates, oxides of nitrogen, chlorine-<:onlaining compounds and other unknownhazardous rnatalieJ may be formed. Incomplete combustion may lead to fonnaUon of carbon monoxideandlor other asphyxiants.Use water spray to cool containers exposed to fire. Remain upwind. Avoid breathing smoke. Wear self­contained breathing apparatus and fuJi protective gear. Avoid using heavy streams of water.Containers In fire may burst from exoesslva heal. Vapors may travel along floor and flash back. Maypresent an explosion hazard II the lower IIm~ of flammability Is exceeded.

STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:Release or Spill; \Near chemical safety glasses with side shIelds or chemical gogglas. rubber gloves, rubber boots, IClI1g·sleeved shirt, long pants,head covering, and a NIOSH-approved pesticide respirator or air-supplied respirator.

For spills: Spills may be collected with absorbent material and placed in a container for proper disposal in accordance with Federal, State and LocalRegulations. Prevent runoff from entering sewer drains and waterweys.

PAGE 1 OF 3

MATERIAL SAFETY DATA SHEET

7. HANDUNG AND STORAGE

SPROUT NIP® EC

STORAGE:

HANDUNG: Wash hands before eating. drinking. chewing gum, using tobacco or using \he toilet. Remove clothIng Immediately if pesticidegels Inside. The wash thoroughly and put on clean dolh/ng. Remove PPE Immediately after handling this product. Wash theoutside of 9!oves before removing. As soon as possible, wash thoroughly and change Into dean clothing.Keep container dosed. Avoid storage below freezing temperalures. Prolonged storage may cause ~tal formation. Warmingcontents and agitation will restore material to useable condillon, but do not warm above 250oF/121.1 C. Flammable. Keepaway from heat and open flame. Do not contaminate water. food or feed by storage or disposal.'

Pe~onal ProtecUve Equipment (P~E): MIK.~, load.~,appllcatol'll and all other handlsl'll muat wear: 10l1g sleeved shIrt and long pants, chemicalresIstant gloves such as barrier laminate, butyl rubber, nitrile rubber. neoprene rubber or Vito~and shoes piUS socks. Discard clothing and otherabsorbent materials that have been drenched or healllly contaminated with thlll product's concentrate. Do not reuse them. Follow manufacturer'sInstructions for cleaning and maintaining PPE. If no Instructions for washables, use detergent and hot water. Keep and wash PPE separalely from otherlaundry.

8. EXPOSURE CONTROLS I PERSONAL PROTECTION

ENGINEERING CONTROLS: Local ventilation recommended. Work In well-ventilated areas. Follow Jabel dlrectlons.RESPIRATORY PROTECTION: Wear a NIOSH approved pesticide respirator with organic vapor cartridge and pesticide prefilter. Follow lebel

directions..EYE PROTECTION: Chemical goggles or shielded safety glasses.SKIN PROTECTION: Wear protective clothing: long-sleeved shirts and pants, shoes plus socks. Wear chemical-resistant gloves.

OSHAPEL8hr1WA ACGIHTLV·1WAIsopropyl Alcohol 980 mglm) 492 mglmJ

9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE AND ODOR: Clear, pale yellow liquid with slight corn 011 odor.SPECIFIC GRAVITY (Water" 1): 0.99 glml BULK DENSITY: 8.26 Ibsl8allonVAPOR PRESSURE: 35mm Hg @250C BOILING POINT: 185·195 F/85.Q-90.50CPERCENT VOLATILE (by volume): 1.84 x 104 torr @ 25°(: EVAPORATION RATE: not establishedNote: These physical data are typical values based on matenal tesled but may very from sample to sample.

Typical values should not be construed as a guaranteed analysis of any specfflc lot or as specificalion items.

10. STABILITY AND REACTIVITY

SOLUBILITY: EmulsifiespH: 6.7

STABIUTY: Stable CONDmoNS TO AVOID: Excessive heat; ignition sources.INCOMPATlBlUTY: Strong olddlzers. acids, alkalis (bases).

HAZARDOUS oeCOMPOSfnON PRODUCTS: Chloroaniline, isocyanates, oxides of nitrogen, and chlorine-GOntaining compounds may form in a firesituation.

HAZARDOUS POLYMERIZATION: Will not occur.

11. TOXICOLOGICAL INFORMATION

Acute OrlillD.. (rat): 4977 mglkg Acute Dennal LO.. (rabbit): >2000 mglkgEye Irritation (rlIbblt): Not an irritant Skin IrritaUon (rabbit): Not an IlT1tantInhalatJon lC.. (rat): > 5.06 mglL (4 hr) Skin S8nl1ltlzatlon (gulne. pig): Not a .sensi~~r. .CarcinogenIc PotentIal: Nothing listed in NTP or OSHA. IARC lists Isopropanol as 3 (Unclassifiable as to Human CarClnogemClty); ACGIH trillsIsopropanol as TLV-M (Not Classifiable as a Human Carcinogen).

12. ECOLOGICAL INFORMAllON

For terrestrial uses, do not apply direct1y to water, or to areas where surfaca water Is present or to Interudal areas below the mean high water mark. Donot contaminate water by cleaning of equipment or disposal of wastes.

13. DISPOSAL CONSIDERATIONS

Do not reuse containers. Plutlc:: Triple rinse (or equivalellt). then offer for recycling at an ACRe site (go to hUo'/lwww aaecycle oruJ for locetions) or byreconditioning, or puncture and di6pose of in a sanitary landfill, or incineration, or If allowed by slate and local authorities, by buming. If bumed. slay outof smoke. 1IetlI1: Triple rll1$8 (or eqUivalent), then offer for recycling or reconditioning, or puncture and dispose of In e sanitary landfill, or by otherprocedures allowed by state and local authoJitles. PUlicide W8$tes are toxic. Improper disposal of excess pesticide, spray miKlUre, or rlnsale Is aviolation of Federal law. Do not contaminate water, food or feed by storage or di5posal.

14. TRANSPORT INFORMATION

DOT Shipping o..crfptlon: FLAMMABLE LIQUID, N.O.S., 3, UN1993, I( (ISOPROPANOL, CHLORPROPHAM) ERG GUIDE 128

U.S. Surface Freight Claulflcatlon: INHIBITORS, NOI, POTATO SPROUTING (NMFC 101690; CLASS: 60)ConGult appropriate ICAO/IATA and IMDG regUlations for 8hlpment requirements In the Air and Marllime shIpping modea.

Page 2 of 3

MATERIAL SAFETY DATA SHEET

1S. REGULATORY INFORMATION

SPROUT NIP® EC

NFPA & HMIS Haurd RatIngs: NFPA

1 Health3 Flammabilityo Instability

o Least1 Slight2 Moderate3 High4 Severe

HMIS

1 Health3 Flammabilityo ReactivityG PPE

SARA Hazard NolltlcatlonlReportlngSARA TIUe III Hazard category: Immediate

Delayed

Repo.ubkl Quantity (RQ) under U.s. CERCLA: NolllstedSARA, TItle III, SectIon 313: Not listedRCRA Waste Code: Not listedCA Proposition 65: Not listed.

16. OTHER INFORMATION

Fire J.­ReaclJve -tL..

Sudden Release ofPressure -L

MSDS STATUS: Fonnat modified to address change-s In ANSI Standard Z400.1-2004

PREPARED BY: Registrations and Regulatory Affairs

@Sprout Nip Is a registered trademark of Platte Chemical Company

REVIEWED BY: Environmental! Regulatory Services

Although \he infonnation and recommendations set forth herein (hereinafter "Infonnation") are presented in good faith and befl6ved to be correct, LovelandProdUcts, Inc.. the manufacturer or the seller makes no representations 8S to the completene-ss or accuracy \hereof. Information is $lJpplied upon \hecondition that the persons receiving it will make their own determination as to its sultebllity for their purposes priorto use.

The product covered by this infonnaUon sheet is fumlshed "as is' by Loveland Products, Inc.• \he manufacturer Dr the seller, and Is subject only to thewarrantie-s, If ilOy, lhat appear on the product's label or are otherwise expressly provided harein.

Except as expressly provided on the product's label Dr otherwise provided herein. no warranties. guarantees. or representations of any kind, either expressor Implied, or by usage of trade, statutory or otherwise, are made by Loveland ProdUcts, Inc.. \he manufacturer or the seller with regard to the product oruse of the prodUct. Including, but not lim~ed to, merchantability, fitness for a particular purpose, use or eligibility of the prodUct for any particular tradeusage.

Except as expressly stated herein, Loveland Products, Inc" \he manufacturer or \he seller makes no warranty of resuKs to be obtained by use of theproduct covered by this InformaUon. Buyefs or usefs exclusive remedy, and the tolallJabllity of Loveland Products. Inc.. the manufacturer or the seller,shall be limited 10 damages not exceeding the cost of the product. No agent Dr employee of Loveland Products, Inc., the manufacturer or the seller isauthorized to amend the lenns of th s warranty dlsdalmer or the product's lebel or to make a representation or recommendation different from orInconsistent with \he label of this product

IN NO EVENT SHALL LOVELAND PRODUCTS, INC., THE MANUFACTURER OR THE SELLER BE LIABLE FOR CONSEQUENTIAL, SPECIAL ORINDIRECT DAMAGES RESULTING FROM THE USE, HANDliNG, APPLICATION, STORAGE OR DISPOSAL OF THIS PRODUCT OR FORDAMAGES IN THE NATURE OF PENALTIES AND THE BUYER AND USER WAIVE ANY RIGHT THEY MAY HAVE TO SUCH DAMAGES.

Page 30'3