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Electroplating of PA Lanxess HK Semi-Crystalline Product Asia Pacific

Electroplating of PA

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Page 1: Electroplating of PA

Elec

trop

latin

g of

PA

Lanx

ess

HK

Sem

i-Cry

stal

line

Prod

uct

Asi

a Pa

cific

Page 2: Electroplating of PA

Intr

oduc

tion

•E

lect

ropl

atin

g ca

n pr

ovid

e a

dura

ble,

hig

h qu

ality

fin

ishe

d fo

r va

riety

of a

pplic

atio

n.

•M

any

poly

mer

s ca

n be

ele

ctro

plat

ed,

but

only

few

can

pro

vide

go

od a

dhes

ion

and

appe

aran

ce r

equi

red

by h

igh

perfo

rman

ce

appl

icat

ion.

•S

peci

al p

latin

g A

BS

and

PA

gra

des

mee

ts th

e re

quire

men

t of

man

y de

man

ding

aut

omot

ive

and

appl

ianc

e ap

plic

atio

ns.

Page 3: Electroplating of PA

Elec

trop

latin

g Pr

oces

s

•P

rior t

o th

e el

ectro

plat

ing

proc

ess,

the

non-

cond

uctiv

e pl

astic

s su

rface

mus

t firs

t und

ergo

an

elec

trole

ss c

hem

ical

pro

cess

to

depo

site

a c

ondu

ctiv

e m

etal

laye

r.

•Th

e el

ectro

less

pro

cess

usu

ally

invo

lves

imm

ersi

ng th

e pa

rts in

se

ries

of s

peci

al fo

rmul

ated

, aqu

eous

bat

h an

d rin

ses

to c

lean

, et

ch a

nd a

ctiv

ate

the

part

surfa

ce.

•A

met

al la

yer,

such

as

copp

er is

che

mic

ally

dep

osite

d on

the

part

surfa

ce.

Afte

r thi

s tre

atm

ent,

mor

e co

nven

tiona

l met

al-p

latin

g m

etho

ds

appl

y ad

ditio

nal m

etal

to th

e no

w-c

ondu

ctiv

e la

yer,

like

nick

el.

Page 4: Electroplating of PA

Elec

trop

latin

g Pr

oces

s of

Pol

yam

ide

•Th

e el

ectro

plat

ing

prin

cipl

e fo

r PA

is s

imila

r to

plat

ing

AB

S.

•In

cas

e of

AB

S, t

he p

olyb

utad

ien

parti

cles

will

be

diss

olve

d or

rem

oved

by

ch

rom

ic

acid

, in

ca

se

of

PA

th

e pr

e-tre

atm

ent

rem

oves

th

e am

orph

ous

sect

ions

mai

nly

by g

lyco

l.

•Th

is r

equi

res

sem

icry

stal

line

surfa

ces

with

hig

h am

ount

of a

mor

phou

s se

ctio

ns.

•Th

e le

ss c

ryst

allin

e th

e su

rface

, the

bet

ter t

he p

latin

g re

sult.

•Fi

ller

cont

ent

(gla

ss f

iber

or

min

eral

) sh

ould

not

exc

eed

50%

(lo

wer

ad

hesi

on)

•B

lack

Pol

yam

ide

cann

ot b

e pl

ated

Page 5: Electroplating of PA

Met

alliz

atio

n

Act

ivat

ion

Che

mic

al

Pret

reat

men

t

Red

uctio

nR

educ

tion

Act

ivat

ion

Act

ivat

ion

Elec

trole

ss M

etal

Lay

erEl

ectro

less

Met

al L

ayer

Swel

ling

Swel

ling

Cle

anin

gC

lean

ing

Strik

e La

yer

Strik

e La

yer

elec

trole

ssel

ectro

less

galv

anic

galv

anic

Nic

kel

Nic

kel

Cop

per

Cop

per

Gol

dG

old

Cop

per

Cop

per

Nic

kel

Nic

kel

(esp

ecia

lly)

(esp

ecia

lly)

Bes

t met

alliz

atio

n re

sults

by

follo

win

g th

ese

rule

s:

Tool

ing

tem

pera

ture

s fro

m40

to 8

0 °C

N

oncr

ysta

lline

surfa

ce o

f the

pl

astic

par

t (no

mec

hnic

al

treat

men

t afte

r the

mol

ding

pr

oces

s)N

o us

e of

rele

asin

g ag

ent

Elec

trop

latin

g Pr

oces

s of

Pol

yam

ide

Chr

ome

Chr

ome

Page 6: Electroplating of PA

Elec

trop

latin

g Pr

oces

s of

Pol

yam

ide

•B

efor

e et

chin

g •

Afte

r etc

hing

Page 7: Electroplating of PA

Stan

dard

PA

Pla

ting

Sequ

ence

s -A

tote

ch

Page 8: Electroplating of PA

Mat

eria

l Sel

ectio

nG

lass

Fill

ed M

ater

ial

VS

. M

iner

al F

illed

Mat

eria

l•

The

min

eral

fill

er h

as n

o sp

ecia

l fun

ctio

n fo

r pl

atin

g. T

he m

echa

nica

l bo

nd b

etw

een

resi

n an

d m

etal

is p

rovi

ded

by d

isso

lvin

g/re

mov

ing

the

amor

phou

s ar

eas

at th

e P

A-s

urfa

ce o

f the

mol

ded

parts

. Thi

s cr

eate

s a

mic

ro-r

ough

sur

face

with

ver

y sm

all u

nder

cuts

, whi

ch a

llow

the

met

al to

fix

/bon

d to

the

resi

n.

•G

lass

fibe

rs p

rovi

de a

dditi

onal

mic

ro-r

ough

und

ercu

ts, a

llow

ing

the

met

al to

bon

d be

tter.

Ther

efor

e, g

lass

fibe

r rei

nfor

ced

grad

es te

nd to

sh

ow b

ette

r adh

esio

n th

an m

iner

al fi

lled

grad

es.

Impa

ct m

odifi

er•

Impa

ct m

odifi

ed g

rade

s pr

ovid

e be

tter a

dhes

ion

than

sta

ndar

d gr

ades

.•

It is

per

sum

ed th

at th

e im

pact

par

ticle

s ac

t lik

e P

olyb

utad

ien

in A

BS

.

Page 9: Electroplating of PA

Lanx

ess

Poly

amid

e G

rade

s fo

r Ele

ctro

plat

ing

•D

uret

han

BK

V11

5 (P

A6-

GF1

5, im

pact

mod

ified

)

•D

uret

han

BK

V13

0 (P

A6-

GF3

0, im

pact

mod

ified

)

•D

uret

han

BM

240

(PA

6-M

40)

Page 10: Electroplating of PA

Serv

ice

Prov

ider

for E

lect

ropl

atin

g Po

lyam

ide

•K

eim

Wer

dohl

/Ger

man

y (h

ttp://

ww

w.k

eim

-gm

bh.d

e)

•D

GM

(ht

tp://

ww

w.d

gm-g

mbh

.de/

wir.

htm

)

•S

axon

ia(h

ttp://

ww

w.s

axon

ia.d

e/U

nser

e_P

rodu

kte/

Gal

vano

te/g

alva

note

.htm

l )

•A

HC

•M

c D

erm

id H

ong

Kon

g (M

r. Je

ff B

rass

ard)

•P

AL

Hon

g K

ong

(con

stru

ctio

n of

pla

ting

lines

)

•S

hipl

ey

•S

chaa

l

•A

tote

ch

Page 11: Electroplating of PA

Com

posi

tion

of G

alva

nic

syst

em

Page 12: Electroplating of PA

Com

posi

tion

of G

alva

nic

syst

em

Page 13: Electroplating of PA

•C

hem

ical

Nic

kel

0.01

-0.1

µm

•N

icke

l Stri

keab

out 0

.1 µ

m

•G

loss

y C

oppe

rab

out 2

0-30

µm

•G

loss

y N

icke

lab

out 1

0-15

µm

•G

loss

y C

hrom

ium

up to

0.3

µm

A

bove

0.3

µm

Chr

omiu

m s

houl

d be

app

lied

with

mic

ro-c

rack

ed

surfa

ce

Typi

cal G

alva

nic

Syst

em in

Aut

omot

ive

Page 14: Electroplating of PA

Fact

ors

Affe

ctin

g El

ectr

opla

ting

Res

ult

•D

esig

n

•In

ject

ion

mol

ding

pro

cess

ing

•E

lect

ropl

atin

g pr

oces

sing

•M

ater

ial S

elec

tion

Page 15: Electroplating of PA

Des

ign

Con

side

ratio

ns

•E

lect

ric c

urre

nt d

ensi

ty d

istri

butio

n ov

er th

e pa

rt su

rface

de

term

ine

plat

ing

thic

knes

s.

•H

igh

curre

nt a

t edg

e, n

otch

and

out

side

cor

ner c

an le

ads

to

exce

ss p

latin

g bu

ildup

.

•R

eces

s ar

ea a

t low

er c

urre

nt d

ensi

tyie

s an

d te

nds

to p

late

th

inne

r tha

n ot

her a

reas

.

Page 16: Electroplating of PA

Des

ign

Con

side

ratio

n –

Plan

ting

Bui

ldup

Page 17: Electroplating of PA

Des

ign

Con

side

ratio

ns•

App

ly a

radi

us o

f at l

east

0.0

1 in

ch in

to p

late

d ed

ge.

•In

lcud

e a

min

imum

1/1

6 in

ch m

inim

um ra

dius

on

all o

utsi

de c

orne

rs.

•A

void

ext

rem

e re

cess

es th

at c

ould

lead

to in

adeq

uate

pla

ting

thic

knes

s.

•A

void

feat

ures

that

may

trap

air

durin

g im

mer

sion

in th

e ba

ths,

or h

inde

r rin

sing

afte

rwar

ds.

•D

esig

n cl

ampi

ng p

oint

s th

at s

ecur

e th

e pa

rt on

the

rack

with

out f

lexi

ng it

.

•Th

e w

all t

hick

ness

sho

uld

be b

etw

een

1.5

mm

and

3 m

m to

pre

vent

hig

h m

olde

d-in

stre

ss

•A

void

hol

es o

r rec

esse

s w

hich

can

car

ry li

quid

es fr

om o

ne c

hem

ical

bat

h to

th

e ot

her

•A

void

gat

ing

poin

ts in

or n

ear v

isib

le a

reas

with

cos

met

ic re

quire

men

ts

Page 18: Electroplating of PA

Mol

ding

Con

side

ratio

ns•

The

mol

ds m

ust b

e ab

solu

tely

cle

an. N

o de

mol

ding

age

nts,

gre

ases

or o

ils

are

allo

wed

.

•M

oldi

ng p

roce

ss a

ffect

s th

e pl

atin

g ad

hesi

on a

nd e

nd-u

se p

erfo

rman

ce

dire

ctly

.

•H

igh

mol

ded-

in-s

tress

es o

n th

e pa

rt su

rface

can

redu

ce a

dhes

ion

and

lead

s to

cra

ckin

g, b

liste

ring

and

war

ping

in th

e pl

ated

par

ts.

•P

rope

r dry

ing

prev

ent m

oist

ure-

rela

ted

surfa

ce d

efec

ts th

at c

ould

app

ears

w

orse

afte

r pla

ting.

•R

elat

ivel

y lo

w

mol

d te

mpe

ratu

res

are

reco

mm

ende

d.

If th

e m

old

tem

pera

ture

is h

igh,

ther

e w

ill b

e to

o le

ss a

mor

phou

s m

ater

ial a

t the

sur

face

w

hich

will

affe

ct th

e ad

hesi

on.

•R

ecyc

led

mat

eria

l can

not b

e us

ed.

Page 19: Electroplating of PA

Elec

trop

latin

g C

onsi

dera

tions

•S

wel

ling

time

shou

ld n

ot b

e to

o lo

ng,

othe

rwis

e, t

oo m

uch

mat

eria

l is

diss

olve

d an

d th

e ad

hens

ion

will

be

low

er.

PA

, afte

r 7 m

in s

wel

ling

PA

, afte

r 15

min

sw

ellin

g

Page 20: Electroplating of PA

Ano

ther

def

ect c

ause

d by

ove

r-sw

ellin

g pr

oces

s is

the

form

atio

n of

hol

es a

nd b

ubbl

es.

Elec

trop

latin

g C

onsi

dera

tions

Page 21: Electroplating of PA

Oth

er C

onsi

dera

tions

•A

ssur

ing

that

all

mol

ded

part

surfa

ces

are

free

from

oil,

gre

ase

and

cont

amin

atio

n.

•D

esig

ning

par

t and

mol

d to

faci

litat

e th

e pa

rt ej

ectio

n w

ithou

t m

old-

rele

ase

agen

ts, e

spec

ially

sili

cone

.

•U

sing

sel

f-lub

ricat

ing

ejec

tor p

in to

oil

cont

amin

atio

n.

•D

esig

ning

and

mai

ntai

ning

mol

d an

d pa

rting

line

car

eful

ly to

pr

even

t sha

rp a

nd ra

gged

edg

es th

at c

ould

exa

gger

ated

by

the

plat

ing

proc

ess.

•P

ositi

on th

e ga

te o

ut-o

f-sig

ht a

nd tr

imm

ing

gate

cle

anly

.

•A

pply

ing

a lig

ht s

atin

-fini

sh to

the

mol

d ca

vity

sur

face

to

enha

nce

plat

ing

adhe

sion

on

the

mol

ded

surfa

ces.

Page 22: Electroplating of PA

Segr

egat

ion

Failu

re

•P

reva

lent

afte

reffe

ct is

apo

or a

dhes

ion

ofth

e m

etal

laye

rto

the

poly

mer

surfa

ce

•R

easo

n m

ostly

“ove

r-ac

tivat

ion“

caus

ed b

y ca

rryi

ngof

fact

ivat

or s

ubst

rate

into

the

chem

ical

Ni-b

ath

Page 23: Electroplating of PA

Failu

re C

ause

d by

the

pollu

tion

of C

u B

ath

Page 24: Electroplating of PA

Cro

ss H

atch

Tes

t

Page 25: Electroplating of PA

Adh

esio

n Te

st

Page 26: Electroplating of PA

Adh

esio

n Te

st

Page 27: Electroplating of PA

Than

k Yo

u.