.

( )

, . , . ( ) ( ). . , , .

-

- , . 2 , , I S. I S , I H, H0, Hloc, S. Hloc :

Hloc 20 , . , , IS , , ..

. , . , - - : -- -- , , , :

1. T1 T2

- . ,

2.

, T1 T2 , :

T1 T2 , 1989 1, 8 .., .., .., .. .. T1 T2 - SXP-4-100 Bruker 90 180-t-90 90-t-180, ( T2 ~1). Li+ Nafion 20,5.

3. T1 T2 Nafion 20,5. T2 250K 2 T1 T2, T1 T2 . , , , . (< 260 K > 260 K) , :< 260 K> 260 K

, C, , . , , , T1 T2

PI PII . : 4. PII , :

5. T1 T2 ( , ) , T1 , T2 . :

d 0,3 , . 300 14*10-10 2/ (6,0*10-10), 250 4,5*10-12 (6*10-12), .

Nafion -

270 300

270

1000/T1000/Tlg(T2_ [c])lg(T1_ [c])

Row 53-1.182568807339451.#NAN

Row 63.11320754716981-1.26513761467891.#NAN

Row 73.20754716981132-1.329357798165141.#NAN

Row 83.34905660377358-1.43944954128441.#NAN

Row 93.44339622641509-1.411926605504591.#NAN

Row 103.56603773584906-1.329357798165141.#NAN

Row 113.69811320754717-1.283486238532111.#NAN

Row 123.74528301886792-1.311009174311931.#NAN

Row 133.78301886792453-1.347706422018351.#NAN

Row 143.83962264150943-1.411926605504591.#NAN

Row 153.91509433962264-1.714678899082571.#NAN

Row 164-1.888990825688071.#NAN

Row 174.00943396226415-1.971559633027521.#NAN

Row 184.04716981132076-2.008256880733941.#NAN

Row 194.11320754716981-2.173394495412841.#NAN

Row 204.16037735849057-2.219266055045871.#NAN

Row 214.25471698113208-2.59541284403671.#NAN

Row 224.33962264150943-2.797247706422021.#NAN

Row 234.44339622641509-2.916513761467891.#NAN

Row 244.4811320754717-3.063302752293581.#NAN

Row 254.5377358490566-3.173394495412841.#NAN

Row 264.65094339622642-3.503669724770641.#NAN

Row 274.70754716981132-3.815596330275231.#NAN

Row 284.75471698113208-4.136697247706421.#NAN

Row 294.79245283018868-4.329357798165141.#NAN

Row 304.85849056603774-4.522018348623851.#NAN

Row 314.88679245283019-4.60458715596331.#NAN

Row 3231.#NAN-0.907339449541284

Row 333.122641509433961.#NAN-1.03577981651376

Row 343.226415094339621.#NAN-1.13669724770642

Row 353.349056603773581.#NAN-1.24678899082569

Row 363.452830188679251.#NAN-1.2651376146789

Row 373.575471698113211.#NAN-1.21009174311927

Row 383.707547169811321.#NAN-1.15504587155963

Row 393.745283018867921.#NAN-1.18256880733945

Row 403.792452830188681.#NAN-1.20091743119266

Row 413.849056603773581.#NAN-1.2651376146789

Row 423.924528301886791.#NAN-1.48532110091743

Row 4341.#NAN-1.57706422018349

Row 444.01886792452831.#NAN-1.62293577981651

Row 454.047169811320761.#NAN-1.63211009174312

Row 464.113207547169811.#NAN-1.66880733944954

Row 474.169811320754721.#NAN-1.67798165137615

Row 484.254716981132081.#NAN-1.67798165137615

Row 494.339622641509431.#NAN-1.68715596330275

Row 504.443396226415091.#NAN-1.61376146788991

Row 514.490566037735851.#NAN-1.57706422018349

Row 524.547169811320761.#NAN-1.51284403669725

Row 534.660377358490571.#NAN-1.36605504587156

Row 544.716981132075471.#NAN-1.20091743119266

Row 554.811320754716981.#NAN-0.907339449541284

Row 564.915094339622641.#NAN-0.503669724770641

Column W

Row 91

Row 100.97

Row 110.8

Row 120.6

Row 130.4

Row 140.2

Row 150.1

Row 160

1000/T1000/Tlg(T2)lg(T1)lg(T2_ [c])lg(T1_ [c])

Row 53-0.7554124292455111.#NAN-1.182568807339451.#NAN

Row 63.11320754716981-0.8673508263217971.#NAN-1.26513761467891.#NAN

Row 73.20754716981132-0.9603973454868551.#NAN-1.329357798165141.#NAN

Row 83.34905660377358-1.09928641166411.#NAN-1.43944954128441.#NAN

Row 93.44339622641509-1.191140156515021.#NAN-1.411926605504591.#NAN

Row 103.56603773584906-1.179138462178291.#NAN-1.329357798165141.#NAN

Row 113.69811320754717-1.141178926151491.#NAN-1.283486238532111.#NAN

Row 123.74528301886792-1.105298798318081.#NAN-1.311009174311931.#NAN

Row 133.78301886792453-1.113474189827631.#NAN-1.347706422018351.#NAN

Row 143.83962264150943-1.220965837312891.#NAN-1.411926605504591.#NAN

Row 153.91509433962264-1.445979467689721.#NAN-1.714678899082571.#NAN

Row 164-1.727374094603311.#NAN-1.888990825688071.#NAN

Row 174.00943396226415-1.760407414639991.#NAN-1.971559633027521.#NAN

Row 184.04716981132076-1.892540694786751.#NAN-2.008256880733941.#NAN

Row 194.11320754716981-2.123773935043581.#NAN-2.173394495412841.#NAN

Row 204.16037735849057-2.288940535227021.#NAN-2.219266055045871.#NAN

Row 214.25471698113208-2.619273735593911.#NAN-2.59541284403671.#NAN

Row 224.33962264150943-2.916573615924111.#NAN-2.797247706422021.#NAN

Row 234.44339622641509-3.279940136327691.#NAN-2.916513761467891.#NAN

Row 244.4811320754717-3.412073416474451.#NAN-3.063302752293581.#NAN

Row 254.5377358490566-3.610273336694581.#NAN-3.173394495412841.#NAN

Row 264.65094339622642-4.006673177134851.#NAN-3.503669724770641.#NAN

Row 274.70754716981132-4.204873097354981.#NAN-3.815596330275231.#NAN

Row 284.75471698113208-4.370039697538431.#NAN-4.136697247706421.#NAN

Row 294.79245283018868-4.502172977685191.#NAN-4.329357798165141.#NAN

Row 304.85849056603774-4.7334062179421.#NAN-4.522018348623851.#NAN

Row 314.88679245283019-4.832506178052081.#NAN-4.60458715596331.#NAN

Row 3231.#NAN-0.9097327347608851.#NAN-0.907339449541284

Row 333.122641509433961.#NAN-1.030551782715191.#NAN-1.03577981651376

Row 343.226415094339621.#NAN-1.13224282219661.#NAN-1.13669724770642

Row 353.349056603773581.#NAN-1.251348065148321.#NAN-1.24678899082569

Row 363.452830188679251.#NAN-1.350652074717191.#NAN-1.2651376146789

Row 373.575471698113211.#NAN-1.2958074365331.#NAN-1.21009174311927

Row 383.707547169811321.#NAN-1.213181363869391.#NAN-1.15504587155963

Row 393.745283018867921.#NAN-1.127574402110861.#NAN-1.18256880733945

Row 403.792452830188681.#NAN-1.144529099160181.#NAN-1.20091743119266

Row 413.849056603773581.#NAN-1.222312768735181.#NAN-1.2651376146789

Row 423.924528301886791.#NAN-1.379599460571981.#NAN-1.48532110091743

Row 4341.#NAN-1.49232585168791.#NAN-1.57706422018349

Row 444.01886792452831.#NAN-1.518185898720921.#NAN-1.62293577981651

Row 454.047169811320761.#NAN-1.550947644127431.#NAN-1.63211009174312

Row 464.113207547169811.#NAN-1.603921406152371.#NAN-1.66880733944954

Row 474.169811320754721.#NAN-1.629956248174721.#NAN-1.67798165137615

Row 484.254716981132081.#NAN-1.647453684532071.#NAN-1.67798165137615

Row 494.339622641509431.#NAN-1.646454711299691.#NAN-1.68715596330275

Row 504.443396226415091.#NAN-1.618442403120421.#NAN-1.61376146788991

Row 514.490566037735851.#NAN-1.591030810098881.#NAN-1.57706422018349

Row 524.547169811320761.#NAN-1.539117290846081.#NAN-1.51284403669725

Row 534.660377358490571.#NAN-1.347480767618761.#NAN-1.36605504587156

Row 544.716981132075471.#NAN-1.204464022876071.#NAN-1.20091743119266

Row 554.811320754716981.#NAN-0.9157818194948751.#NAN-0.907339449541284

Row 564.915094339622641.#NAN-0.5642736494764191.#NAN-0.503669724770641

1000/T1000/Tlg(T2)lg(T1)

Row 531.040057347750451.#NAN

Row 63.113207547169810.6850724467824211.#NAN

Row 73.207547169811320.389251781379031.#NAN

Row 83.34905660377358-0.05447838063097571.#NAN

Row 93.44339622641509-0.350295810570021.#NAN

Row 103.56603773584906-0.7348408846433691.#NAN

Row 113.69811320754717-1.148838495153051.#NAN

Row 123.74528301886792-1.296575452684681.#NAN

Row 133.78301886792453-1.414649824165711.#NAN

Row 143.83962264150943-1.591380927942671.#NAN

Row 153.91509433962264-1.825381847923161.#NAN

Row 164-2.082418120008841.#NAN

Row 174.00943396226415-2.110177378809461.#NAN

Row 184.04716981132076-2.218588077115111.#NAN

Row 194.11320754716981-2.393466525520691.#NAN

Row 204.16037735849057-2.501648101503881.#NAN

Row 214.25471698113208-2.668010969190271.#NAN

Row 224.33962264150943-2.793620488898711.#NAN

Row 234.44339622641509-3.010760484491371.#NAN

Row 244.4811320754717-3.11039789863351.#NAN

Row 254.5377358490566-3.272219141613381.#NAN

Row 264.65094339622642-3.616582040528171.#NAN

Row 274.70754716981132-3.792596218967271.#NAN

Row 284.75471698113208-3.939926382298651.#NAN

Row 294.79245283018868-4.058004495633261.#NAN

Row 304.85849056603774-4.264866539961471.#NAN

Row 314.88679245283019-4.353568052605091.#NAN

Row 3231.#NAN1.04005735979054

Row 333.122641509433961.#NAN0.655490445472219

Row 343.226415094339621.#NAN0.330087989481489

Row 353.349056603773581.#NAN-0.0544765198214544

Row 363.452830188679251.#NAN-0.379868904456078

Row 373.575471698113211.#NAN-0.764370172607716

Row 383.707547169811321.#NAN-1.17806530995377

Row 393.745283018867921.#NAN-1.2960078606651

Row 403.792452830188681.#NAN-1.44302356545386

Row 413.849056603773581.#NAN-1.61823605863224

Row 423.924528301886791.#NAN-1.84695150575847

Row 4341.#NAN-2.06101124551693

Row 444.01886792452831.#NAN-2.11000242561274

Row 454.047169811320761.#NAN-2.17814959228721

Row 464.113207547169811.#NAN-2.30114687696146

Row 474.169811320754721.#NAN-2.35102067567311

Row 484.254716981132081.#NAN-2.3165266086905

Row 494.339622641509431.#NAN-2.16986849635084

Row 504.443396226415091.#NAN-1.8977090927836

Row 514.490566037735851.#NAN-1.75834445999215

Row 524.547169811320761.#NAN-1.58587312028677

Row 534.660377358490571.#NAN-1.23413722700012

Row 544.716981132075471.#NAN-1.0570874711404

Row 554.811320754716981.#NAN-0.761527499153203

Row 564.915094339622641.#NAN-0.436194402574405

t_cF

Row 810

Row 920

Row 1040

Row 1140.25

Row 1250.2

Row 1360.166666666666667

Row 1470.142857142857143

Row 1580.125

Row 1690.111111111111111

Row 17100.1

Row 18110.0909090909090909

Row 19120.0833333333333333

Row 20130.0769230769230769

Row 21130

Row 22150

Row 23160

Row 24170

Row 25180

Row 26190

Row 27200

Row 28210