Upload
others
View
17
Download
0
Embed Size (px)
Citation preview
Depositional environments and facies of the Late Triassic
Abu Ruweis Formation, Jordan
Issa M. Makhlouf a,*, Abdel Aziz El-Haddad b
a Department of Earth and Environmental Sciences, Hashemite University, P.O. Box 330028, Zarqa 13133, Jordanb Department of Geology, South Valley University, Sohag, Egypt
Received 25 May 2005; received in revised form 27 September 2005; accepted 12 October 2005
Abstract
The Abu Ruweis Formation is composed of carbonates, evaporites, and mudstones, with some locally developed pelletic, oolitic and
stromatolitic limestones. The lateral persistence of bedding, the purity of the evaporite rocks, the alternating arrangement of marine carbonates
and evaporites indicates periodic deposition in subaqueous conditions (salina). Petrographic investigations, X-ray diffraction analysis as well as
chemical analysis have shown that the outcropping evaporite beds are mainly composed of secondary gypsum, with rare anhydrite relics. Five
microfacies of gypsum were recognized according to their fabrics: porphyroblastic and granoblastic gypsum showing polarization texture,
gypsum pseudomorph after anhydrite laths, and satin spar gypsum. The textures they display indicate a hydration origin of precursor anhydrite,
which is in turn rehydrated from primary gypsum. Some of these anhydrites were formed as a result of replacement processes of the carbonate
sediments associated with the evaporites, as evidenced from the textural relationships of the carbonate and sulfate minerals. The O18 content
ranges from 1.45 to 8.38% PDB and the C13 content ranges from K1.52 to 4.73% PDB. Trace elements analysis has shown that the Abu Ruweis
dolomites are rich in strontium (up to 600 ppm), and sodium (up to 835 ppm). The isotope composition and trace elements content, as well as the
petrographic characteristics point to a penecontemporaneous hypersaline dolomitization origin for the Abu Ruweis dolomites. The evaporites
were deposited during a regressive lowstand systems tract, whereas the carbonates were deposited under shallow water marine conditions during a
highstand systems tract. The Abu Ruweis succession represents a relatively stable arid climate within a rapidly subsiding basin. Restricted
conditions were provided by the development of beach barriers.
q 2005 Elsevier Ltd. All rights reserved.
Keywords: Abu Ruweis; Jordan; Evaporites; Triassic; Cyclicity; Salina
1. Introduction
The Triassic strata of Jordan were developed along the
southern margins of the Tethyan seaway. During the late
Triassic, a unique sequence of evaporites, the Carnian Abu
Ruweis Formation, accumulated in northwest Jordan (Fig. 1). It
is the uppermost formation of the marine and fluvial Triassic
succession in Jordan. This formation is considered as the major
evaporite deposit in Jordan. Evaporite depositional environ-
ments of the Abu Ruweis and their vertical succession provide
clues to the depositional history of the basin.
The Triassic succession consists of eight formations. The
Abu Ruweis is the uppermost formation and underlies the
1367-9120/$ - see front matter q 2005 Elsevier Ltd. All rights reserved.
doi:10.1016/j.jseaes.2005.10.017
* Corresponding author. Tel.: C962 492 5 390 3333; fax: C962 492 5 382
6613.
E-mail address: [email protected] (I.M. Makhlouf).
fluvial Jurassic Hihi Formation (Table 1). The Abu Ruweis
Formation is composed of evaporites, carbonates and shales
(Fig. 2). It is exposed in one locality at the confluence of Wadi
Huni and Wadi Abu Ruweis in Zarqa River, about 35 km
north of Amman and 22 km north of Salt in northwest Jordan
(Fig. 1). The succession was given different names by
different authors, for example, the Formation Gypsifere of
Zarqa (Ionides and Blake, 1939), the Zarqa gypsums
Formation (Basha, 1982), and the Abu Ruweis Formation
(Bandel and Khoury, 1981). Only the uppermost part of the
formation is exposed in the Subayhi area, where the gypsum
deposits are quarried for cement.
The lithostratigraphy of the Abu Ruweis Formation (e.g.
Wetzel and Morton, 1959; Bender, 1974; Ionides and Blake,
1939; Bandel and Khoury, 1981; Basha, 1982; FEJ, 1989;
Bandel and Waksmundzki, 1985; Ahmad, 1989) is well
known. Muneizel and Khalil (1993) prepared a geologic map
.
Journal of Asian Earth Sciences 28 (2006) 372–384
www.elsevier.com/locate/jaes
Fig. 1. Location map showing the outcrops of the Abu Ruweis Formation (modified from Muneizel and Khalil, 1993).
I.M. Makhlouf, A.A. El-Haddad / Journal of Asian Earth Sciences 28 (2006) 372–384 373
(scale 1:50,000) of the Salt area included the study area.
Amireh (1993) described the paleosol horizon at the boundary
between Abu Ruweis Formation and the Jurassic Hihi
Formation. Arikat (2000) studied the geology, sedimentology
and industrial potential of the Abu Ruweis evaporites in the
Subayhi area. The suitability of Abu Ruweis gypsum for
production of gypsum plaster was studied by Saqqa and
Arikat (2003).
Table 1
Rock formations and lithostratigraphy of the Triassic succession in Jordan
Era Period Epoch Lithology Formation Depositional environments
Mesozoic Jurassic Bathonian Sandstone, claystone and Fe-paleosol Hihi Fluvial
Carnian Gypsum, anhydrite, and claystone Abu Ruweis Marine (supratidal)
Ladinian Limestone and dolomite Umm Tina Marine (subtidal)
Limestone and dolomite Iraq el Amir Marine (subtidal)
Triassic Anisian Sandstone, shale, marlstone and limestone Mukheiris Fluvial and marine
Limestone and shale Hisban Marine (subtidal)
Scythian Sandstone, shale and marlstone Ain Musa Marine (intertidal–subtidal)
Sandstone and marlstone Dardur Marine (intertidal–subtidal)
Sandstone, shale and marlstone Ma’in Marine (intertidal–subtidal)
Paleozoic Permian Conglomerate, sandstone and shale Umm Irna Fluviatile
I.M. Makhlouf, A.A. El-Haddad / Journal of Asian Earth Sciences 28 (2006) 372–384374
The present work aims to shed some light on the origin of
Abu Ruweis evaporite deposition and their diagenetic
evolution. The depositional model evolved for the Abu Ruweis
evaporites may help interpreting related sedimentary basins in
the Middle East.
1.1. Geological and stratigraphical setting
The uppermost part of the Abu Ruweis Formation is
exposed in the Subayhi area, at the confluence of Wadi el Huni
andWadi al Azab with the Zarqa River (N 32810 0 and E 35843 0)
(Figs. 1 and 2). A combination of domal uplift, denudation and
incision by the Rivers Zarqa and Huna has created local
exposures of the Abu Ruweis Formation. The quarry excavated
by the Jordanian Cement Factory during the last 60 years
produced excellent exposures. The Abu Ruweis Formation
overlies the carbonates of the Triassic Umm Tina Formation.
The base of the formation is not exposed and has only been
reported from the subsurface, where it is defined by the first
appearance of a thick anhydrite bed. It is unconformably
overlain by the Jurassic limestones of Azab Group (Bandel and
Khoury, 1981).
At outcrop, the top of the formation is defined by the first
appearance of the paleosol horizon that marks the base of the
Jurassic Hihi Formation (Khalil and Muneizel, 1992). The Abu
Ruweis Formation has been dated as Carnian in age on the
basis of diverse palynomorph-assemblages identified by
Keegan et al. (1987a,b) including Taeniaesporites noviavlen-
sis, Pseudenzonalasporites summus, T. acutus, Camerosporites
secatus, Enzonalasporites subgranulatus and Duplicicsporites
granulatus.
All the evaporite units in the Zarqa River basin are
horizontal (Fig. 3(A)), although locally they exhibit some
deformation, such as gentle flexures, folds and faults. Although
the basal part is unexposed, complete stratigraphic sections
occur in the subsurface, where they reach a maximum
thickness of about 500 m (Andrews, 1992). Dalqamuni
(1995), Sadooni and Dalqamouni (1998) studied the sequence
stratigraphy and oil prospects of the Abu Ruweis Formation in
the subsurface in three wells, Ajlun-1 (AJ-1), Northern
Highland-2 (NH-2), and Risha-2 (RH-2). The measured
thicknesses were 230, 287, and 492 m, respectively.
1.2. Methodology
Detailed field investigations of the succession were carried
out and representative samples collected for further laboratory
investigations (Fig. 2). Thin sections were prepared from the
evaporites and carbonates for petrographic analysis. Miner-
alogical composition was determined by X-ray diffraction
(XRD), and dolomite samples were analyzed for dO18
and dC13.
1.3. Regional setting
Jordan as a part of northern Arabian Plate witnessed an
evaporitic stage during the Late Triassic. Therefore, the Abu
Ruweis Formation is considered to be the equivalent of the
Mohilla Formation (Druckman, 1974; Bandel and Khoury,
1981), and was equated with the upper member of the
Saharonim and the Mohilla Formations of southern Palestine
(Ahmad, 1989). Northwards, the Abu Ruweis Formation is
equivalent to the Kurra China Formation in Iraq (Sadooni,
1995), and to the Kurra Chine Anhydrite Formation in Syria
(Beydoun and Habib, 1995).
2. Lithofacies
The exposed thickness of Abu Ruweis Formation gypsum in
the quarry area (Subayhi) is about 90 m (Figs. 2 and 3(A)). It is
composed mainly of three lithofacies; evaporites, carbonates
and shales. The evaporites comprise gypsum are laminated,
banded, massive, enterolithic and nodular types. Carbonate
lithofacies includes dolomite (most prominent), oolitic, pelletic
and stromatolitic rocks, and shale lithofacies includes
carbonaceous shales and mudstones (Figs. 2 and 3(B)–(D)).
2.1. Laminated gypsum facies
This facies occurs as thick to very thick-bedded pale
white to gray gypsum. Beds range in thickness from 80 to
160 cm. Very thin evaporite beds and laminae are inter-
bedded/interlaminated with thinner dark lime mud laminae
(organic material possible algal mats) and thin-bedded
dolomites (Fig. 4(A)). Evaporite laminae display enterolithic
Thi
ckne
ss(m
)
For
mat
ion
Epo
ch
Per
iod
Age
10
20
30
40
50
60
70
80
90
100
0
(cm)
AB
U R
UW
EIS
CA
RN
IAN
TR
IAS
SIC
Sha
le
Gyp
sum
Dol
omite
Stro
mat
olite
Ool
ite
Lithology
Laminated gypsum
Nodular gypsum
Dolomite
Stromatolite
Oolite
Shale
Mudcracks
LEGEND
0
Fig. 2. Measured vertical section of the Abu Ruweis Formation exposed in the
Subayhi area, North Jordan.
I.M. Makhlouf, A.A. El-Haddad / Journal of Asian Earth Sciences 28 (2006) 372–384 375
features. The laminated structure of this facies shows local
deformation and overturning.
2.2. Nodular gypsum facies
Nodular gypsum commonly overlies the laminated gypsum
facies, and both are separated by sharp and conspicuous
contacts (Fig. 4(A)). The nodules are elliptical in shape and
aligned almost parallel to the laminated gypsum below with a
preferred orientation (Fig. 4(B) and (C)). They consist of
closely packed, pale white nodules set in a faint gray–black
organic lime mud, forming the chicken-wire (Fig. 4(B) and
(C)) or mosaic structure (Fig. 4(D)) of Maiklem et al. (1969).
The individual beds range in thickness from a few
centimetres to 1 m.
The change of gypsum fabrics from laminated to nodular
suggests that the latter results from the mobility of sulfate
during diagenesis (Hussain and Warren, 1989; Aref et al.,
1997). The formation of nodular structures is probably the
result of fluctuations in salina water level, and periodic
precipitation of gypsum during seasonal concentration of
marine water (Ogniben, 1955).
3. Description of gypsum microfacies
Microscopic investigation as well as X-ray diffraction has
shown that the evaporites of the Abu Ruweis Formation are
composed primarily of microcrystalline gypsum (Fig. 5), The
microcrystalline gypsum displays a variety of textures ranging
from xenotopic to idiotopic. Five microfacies were recognized;
(1) gypsum pseudomorphs after anhydrite, including gypsum
pseudomorphs after felted anhydrite and gypsum pseudo-
morphs after radiated anhydrite, (2) porphyroblastic gypsum,
(3) granoblastic gypsum, (4) amiboid gypsum, and (5) fibrous
satin spar gypsum. Of these, the fibrous (satin spar) gypsum
variety is the only type which formed from sulfate-rich
solutions, developed as a result of the rehydration of anhydrite,
whereas, the other microfacies were formed by rehydration of
precursor anhydrite.
3.1. Gypsum pseudomorph after anhydrite
This is the most common type in the Abu Ruweis gypsum.
Two varieties were recorded. The first is composed of
elongated, randomly arranged thin laths showing a felted
appearance (Fig. 6(A) and (B)). The second variety is
composed of prismatic crystals arranged in a fibro-radiated
texture (Fig. 6(C)). It is believed that these two varieties
formed by the rehydration process of precursor anhydrite. This
is supported by the presence of satin spar gypsum veins which
are the bi-products of the rehydration process of anhydrite
(Holliday, 1970; Testa and Lugli, 2000).
3.2. Porphyroblastic gypsum
This is composed of large euhedral to subhedral crystals which
showing sharp extinction (Fig. 6(D)). These large crystals occur as
individual crystals or in groups of two or three crystals (Fig. 6(D)).
The large crystals are surrounded by fine gypsum crystals and are
characterised by abundant anhydrite relics (Fig. 6(D)). The
porphyroblastic gypsum was formed by the rehydration of
anhydrite as indicated by anhydrite relics (Holliday, 1970).
Fig. 3. (A) General view showing the gypsum quarry face in the Subayhi area. Note the lateral persistence of strata and regularity of the bedding. The arrow shows
contact with Jurassic strata. (B) Thick bedded evaporites alternating with carbonates and shales. (C) Thin bedded evaporites alternating with carbonates and shales.
Note the distortion of bedding (upper right). Hammer is 28 cm long. (D) Carbonaceous shale sandwiched between two gypsum beds. Gypsum nodules are developed
within the shale (Hammer is 28 cm long).
Fig. 4. (A) Regular alternation of laminated gypsum (white) and dolomites (gray) rich in organic matter, passing upward into nodular gypsum. (B) Alternating
laminated and nodular gypsum displaying chicken-wire pattern of the aligned nodules. (C) Banded nodular gypsum displaying chicken-wire pattern. (D) Aggregate
of gypsum nodules forming a botryoidal pattern (Hammer is 28 cm long).
I.M. Makhlouf, A.A. El-Haddad / Journal of Asian Earth Sciences 28 (2006) 372–384376
10 20 30 40 500
2000
4000G-GypsumA-Anhydrate
G
G
G
G
AA
G
Fig. 5. X-ray diffraction pattern of the Abu Ruweis gypsum, Subayhi area,
North Jordan.
I.M. Makhlouf, A.A. El-Haddad / Journal of Asian Earth Sciences 28 (2006) 372–384 377
3.3. Granoblastic gypsum
The granoblastic gypsum is of limited distribution in the
Abu Ruweis succession. It exhibits well defined euhedral to
subhedral crystals with sharp and homogenous extinction
(Fig. 7(A)). The crystals being almost equigranular in size (10–
50 mm) are interlocking and form a mosaic texture (Fig. 7(A)).
This gypsum microfacies is characterized by the absence of
anhydrite relics. It is believed that the granoblastic gypsum
represents an advanced stage of anhydrite rehydration (West,
1964, 1965; Holliday, 1970; Warren, 1999).
Fig. 6. Photomicrographs showing the different microfacies of the Abu Ruweis gyps
anhydrite. (C) Gypsum pseudomorph after fibro-radiated anhydrite. (D) Porphyrob
3.4. Amiboid gypsum
The distribution of this microfacies in the Abu Ruweis
gypsum is limited, and is similar to the granoblastic gypsum.
It is composed of gypsum crystals which display cloudy
amiboid texture (Fig. 7(B)), similar to the supra individual
amiboid texture of Ogniben (1957), and amiboid texture of
Holliday (1970). The crystals have very irregular boundaries
and undulose extinction. No anhydrite relics were observed
associated with this type of gypsum. The cloudy amiboid
microfacies of gypsum has been interpreted by many authors
as an early stage of anhydrite rehydration (Ogniben, 1957;
Holliday, 1970; Lugli and Testa, 1993; Testa and Lugli,
2000).
3.5. Fibrous (satin spar) gypsum
The fibrous satin spar gypsum occurs as gypsum veins
interbedded within the evaporites as well as the carbonates of
the Abu Ruweis Formation. The veins are composed of
elongated crystals arranged perpendicular to the walls of the
veins (Fig. 7(C) and (D)). Occasionally, the gypsum crystals
are arranged randomly (Fig. 7(C)). Many authors consider satin
spar gypsum as a bi-product of the rehydration process of
anhydrite (Shearman et al., 1972; Testa and Lugli, 2000). It is
believed that the gypsum veins, which are composed of
randomly oriented crystals, were originally formed as
anhydrite at depth and at high temperature and pressure,
prior to their later rehydration to gypsum.
um. (A) Gypsum pseudomorph after anhydrite laths. (B) Gypsum pseudofelted
lastic gypsum (C.N.100!), scale is 250 mm.
Fig. 7. Photomicrographs showing the different microfacies of the Abu Ruweis gypsum. (A) Granoblastic gypsum. (B) Ameboid gypsum. (C and D) Satin spar
gypsum veins within the Abu Ruweis dolomites (C.N.100!), scale is 250 mm.
D-Dolomite
G-GypsumC-Calcite
Q-Quartz
5040302010
D
DD
D
DDG+
Q
CCC
C
G0
400
600
800
200
Fig. 8. X-ray diffraction pattern of the Abu Ruweis dolomites, Subayhi area,
North Jordan.
I.M. Makhlouf, A.A. El-Haddad / Journal of Asian Earth Sciences 28 (2006) 372–384378
4. Interpretation of gypsum microfacies
The microscopic investigations indicate that most gypsum
microfacies of the Abu Ruweis Formation resulted from
hydration of precursor anhydrite. Experimental studies and
modern sedimentary analogies indicate that primary gypsum is
more commonly precipitated under normal surface conditions
(Haridie, 1967; Shearman, 1985; Testa and Lugli, 2000). The
precursor anhydrite could be interpreted as a diagenetic
product derived from rehydration process of primary gypsum
(Murray, 1964; Holliday, 1970).
It is believed that the Abu Ruweis evaporites were deposited
originally as gypsum under restricted shallow marine salina
conditions. This is evidenced by their regular bedding and
interbedding with marine carbonates. These conditions may
have changed, for some time, into a desiccated basin, as
evidenced from the presence of a thick succession (up to 50 m)
of rock salt in the subsurface (Andrews, 1992; Kendall, 1989).
The primary gypsum was transformed diagenetically into
anhydrite during burial (Murray, 1964; Holliday, 1970; Testa
and Lugli, 2000; Kirkland, 2003), or by solar heating similar to
the Miocene evaporites of the northwestern Red Sea (Aref et
al., 2003).
During uplift, the exposed part of the Abu Ruweis
anhydrites changed to gypsum. These evaporites are still in
the form of anhydrite in the subsurface as mentioned by
Andrews (1992), Dalqamuni (1995). All gypsum microfacies
of Abu Ruweis Formation in the Subayhi area (e.g. gypsum
pseudomorphs after anhydrite, porphyroblastic gypsum, gran-
ular gypsum and amiboid gypsum) are of secondary origin.
This is confirmed by the widespread satin spar gypsum veins
scattered within the Abu Ruweis Formation (Fig. 7(C) and
(D)), which are considered by many authors to be the result of
the hydration process of anhydrite (Holliday, 1970; Kendall,
1989; Testa and Lugli, 2000).
5. Carbonate lithofacies
The carbonates are composed primarily of dolomites with
subordinate oolitic and stromatolitic limestones.
5.1. Dolomite facies
The microscopic investigations, X-ray analysis and staining
technique have revealed that the carbonate beds interbedded
with the Abu Ruweis evaporites are mainly composed of the
mineral dolomite (Fig. 8). The Abu Ruweis dolomites are
characterised by their fine crystallinity, thin laminated
dolomicrite (Fig. 9(A)), and the abundance of organic matter.
Some bioclastic dolomites are composed of pelecypod
Fig. 9. Photomicrographs showing the different microfacies of the Abu Ruweis dolomites. (A) Laminated dolomicrite. (B and C) Bioclastic dolomites. (D) Peletal
dolomites (C.N.100!), scale is 250 mm.
Table 2
Stable isotope content and Sr and Na content of some samples taken from the Abu Ruweis dolomites at Subayhi area (ppm)
Sample No. 1 2 3 4 5 6 7 8 9 10 11 12
dO18 5.36 6.11 3.71 4.78 7.23 8.21 6.32 5.45 8.38 7.41 4.49 1.45
dC13 3.27 K0.57 2.45 K1.52 K1.21 4.73 2.72 3.17 4.22 K1.16 4.16 K0.72
Sr 515 421 600 412 482 588 621 600 342 561 322 411
Na 425 672 351 785 835 812 734 611 575 442 566 779
10 8 6 4 2 0
2
7
δC13
I.M. Makhlouf, A.A. El-Haddad / Journal of Asian Earth Sciences 28 (2006) 372–384 379
fragments and crushed shells of arenite size (Fig. 9(B) and (C)),
and other dolomites are pelletal (Fig. 9(D)).
Oxygen and carbon isotope analysis of the dolomites
associated with the Abu Ruweis gypsum show that these
dolomites are isotopically heavy. The O18 content ranges from
1.45 to 8.38‰ which is higher than the Standard Mean Ocean
Water (SMOW) value which is 0‰. The C13 content range
fromK1.52 to 4.73‰ PDB (Table 2, Fig. 10). The Oxygen
isotope values are too high to have formed from normal sea
water. Therefore, these isotopically heavy dolomites must have
been precipitated from fluids enriched in O18, probably as a
result of evaporation (Gill et al., 1995). Trace elements analysis
has shown that the Abu Ruweis dolomites are rich in
strontium (up to 600 ppm) and sodium (up to 835 ppm)
(Table 2). The isotope composition and trace elements content
as well as the petrographic characteristics, all point to
penecontemporaneous hypersaline dolomitization for the
Abu Ruweis dolomites.
––3δO18
Fig. 10. dO18 and dC13 of the Abu Ruweis dolomites at Subayhi area, North
Jordan.
5.2. Stromatolite facies
These rocks are composed of closely spaced, thin algal
laminations. Some of these rocks are thick bedded reaching
up to one metre thick. The stromatolite structure is composed
of interlaminated light coloured clastic-rich and dark-
coloured organic-rich laminae that are highly contorted
(Fig. 11(A)). During hot conditions, brine is saturated, and
gypsum is deposited. During the next wet season, water
influx dilutes salina waters promoting algal mats, to develop
on top of the preceded precipitated gypsum (Arkal, 1980;
Aref et al., 1997).
The laminated mats formed in a shallow marginal marine
salina along a supratidal flat. The interlamination with
gypsum indicates that the growth of algal mats took place
Fig. 11. (A) Regular interlaminations of slightly undulating, dark coloured stromatolitic laminae and light coloured gypsum laminae. (B) Mudcracks infilled by
gypsum (Hammer is 28 cm long). (C) Laminated gypsum passing upward into claystones (note the brecciation at the boundary between both facies and the
associated embedded gypsum layer which is completely broken into pieces) (Hammer is 28 cm long). (D) Gypsum and claystones showing contortion of the strata
(the ruler top left is 20 cm long).
I.M. Makhlouf, A.A. El-Haddad / Journal of Asian Earth Sciences 28 (2006) 372–384380
on the bottom during phases of dilution of salina water and
low salinity rates, when gypsum precipitation ceased
(Schreiber et al., 1982; Aref et al., 1997). Some workers
restrict the term ‘stromatolite’ to structures, such as domes
and columns, with primary relief, but stromatolites may be
originally flat deposits (Riding, 2000).
6. Shales lithofacies
This facies displays sharp contact with the evaporite beds
throughout the study area (Fig. 3(C) and (D)). Individual beds
range in thickness from a few centimetres up to 150 cm. This
facies shows vertical to oblique cracks that are partially or
completely infilled with clear white transparent gypsum from
the overlying subaqueous gypsum layer (Fig. 11(B)), similar
to those described by Aref et al. (1997) from the Gulf of
Suez, Egypt. The mudstone layers also enclose white
lenticular gypsum nodules up to 25 cm long and 10 cm
thick, showing local deformation structures (Fig. 11(C) and
(D)). Organic-rich shales are common in the Abu Ruweis
succession, especially as part of the evaporite–carbonate
cycles.
Black shale samples from RH-1 well (well depth at 850–
1380 m) were analyzed by the Amoco Oil Company (1987).
They indicated that the samples were slightly carbonaceous,
non to slightly calcareous. The kerogen content consists mainly
of amorphous organic matter, associated with small amounts of
miospores and plant tissues. Therefore, the Abu Ruweis
Formation may be considered as a potential source rock
(Dalqamuni, 1995).
7. Gypsum–dolomite relationship
The microscopic investigations of the dolomites inter-
bedded within the Abu Ruweis evaporites have revealed that
they contain gypsum as veins and scattered crystals amongst
their constituents. The gypsum occurs either as elongate thin
laths, scattered randomly within the dolomite crystals, or as
small irregular areas composed of fine aggregates of gypsum
(Fig. 12(A)–(C)). These gypsified areas usually occur very
close to the previously described gypsum veins. Occasionally,
the walls of the veins are eroded and became irregular and pass
laterally to the gypsified areas.
It is believed that this type of gypsum was formed by the
replacement of carbonate minerals (calcite or dolomite) by
sulfate-rich solutions (Fig. 13). The textural characteristics of
this gypsum indicate that the carbonate minerals (calcite or
dolomite) were replaced originally by anhydrite, which in turn
was replaced by secondary gypsum (Fig. 13). If this is the case,
which is more likely, the replacement of carbonate minerals
took place at depth under high temperature and pressure,
thereby favouring the formation of anhydrite rather than
gypsum (Murray, 1964; Holliday, 1970; Kendall, 1989; Testa
and Lugli, 2000). Locally, the gypsum occurs as lenticular
crystals scattered within the dolomite crystals (Fig. 5(F)) which
probably indicates a direct replacement of carbonate minerals
by gypsum under near surface conditions (Warren, 1999).
Fig. 12. Photomicrographs showing: (A and B) sulfatization of the Abu Ruweis
dolomites (the gypsum occurres as separated areas as in A or as lenticular crystals
as in B), (C) sulfatized dolomites in the form of gypsum vein and irregular areas.
Note that the gypsum laths are arranged randomly (C.N.100!), scale is 250 mm.
Satin spar gypsum
Pseudomor-ph Gypsum
PorphyroblasticGypsum
GanoblasticGypsum
AmeboidGypsum
Epigenetic felted Anhydrite
Primary Gypsum
Fig. 13. The diagenetic stages of the Abu Ruw
I.M. Makhlouf, A.A. El-Haddad / Journal of Asian Earth Sciences 28 (2006) 372–384 381
8. Gypsum–dolomite cyclicity
The alternation of gypsum and dolomite as couplets
continues upward, and displays a ‘dolomite–gypsum rhythmic
pattern’ at different levels of the outcropping succession. Each
couplet consists of a dark-gray, thin to thick-bedded dolomite
overlain by a thick-bedded white gypsum. Rhythmic couplets
are distinct, but are irregularly spaced, and occur in multiple
sequences commonly capped with carbonaceous shales. When
the three components are together the term ‘dolomite–gypsum–
shale tripartite’ is used. This tripartite style of composition also
occurs in the subsurface, where it is composed of an alternation
of laminated dolomite and anhydrite with rare shale intercala-
tions (Andrews, 1992). In the subsurface, a thick salt bed (22–
57 m) was recorded (Andrews, 1992). It is noted that the
dolomite interbeds increase in thickness and frequency at the
lower and upper parts of the section, and decrease in the middle
part of the section.
9. Environment of deposition
Evaporite sequences have been generated in a variety of
geographic settings: (1) coastal intertidal and supratidal
environments (marine sabkhas), (2) along coasts, (3) large
basins with marine inflow (subaqueous marine/salina), and
(4) non-marine interior basins (continental sabkha-playa)
(Kendall, 1984). No single facies model can be applied to
such heterogeneous rocks as the evaporites, and their
identification may depend more upon associated facies than
upon internal characteristics (Kendall, 1984).
The Abu Ruweis evaporites formed in shallow seawater,
and occasionally in desiccated environments subject to floods.
The lateral persistence of beds over large areas with only minor
changes in thickness and facies indicates that they formed on
broad, very low relief areas that were affected by rapid
transgressions that led to major changes in brine chemistry
(Peryt, 2001).
Satin spar gypsum
Secondary gypsum
Anhydrite Anhydrite Anhydrite
Dolomite Gypsum
Calcite Stage I
Stage II
Stage III
Stage IV
eis evaporites at Subayhi, North Jordan.
Subtid
al (o
pen m
arin
e she
lf)
Beach
barsIn
tertid
al
Supert
idal (
Sabkh
a)
(peri
odic
expo
sure)Allu
vial p
lain
Arabian
Nubian
Shield
DolomiteDolomite
LimestoneLimestone
GypsumGypsum
HaliteHalite
SandstoneSandstone
Shale
SStromatolite
OoidsOoids
Pelloids
Mudcracks
FossilsN
Influx
Open m
arine s
ource
Fig. 14. Schematic block diagram of the coastal salina setting showing generalized subenvironments and their respective lithofacies of the Abu Ruweis Formation.
I.M. Makhlouf, A.A. El-Haddad / Journal of Asian Earth Sciences 28 (2006) 372–384382
The marine origin of Abu Ruweis evaporites–carbonates
cyclic pattern is explained by Braitsch’s model (1962). As
water evaporates, salinity progressively increases, calcium
carbonate and calcium sulfate precipitate in the order of their
solubility, and an evaporative couplet results. Another influx of
seawater begins a new cycle.
During deposition of the Abu Ruweis Formation, beach bars
may have developed toward the sea and shoals further landward
(Fig. 14). This setting shows considerable variation in facies
characteristics and represents the transition from subtidal shelf
conditions through intertidal to supratidal, as evidenced by the
presence of pelletic, oolitic and stromatolitic facies. Based on
our studies, this formation is believed to have been deposited in
three types of setting (Fig. 14): (1) shallow marine shelves, (2)
intertidal flats, and (3) supratidal sabkhas. The supratidal
environment was dominated by sabkhas during an arid climate.
As a result algal mats were developed along the tidal flats and
stromatolites were formed. Carbonate stromatolites vary
considerably in origin and components, and also in the quality
of lamination. Episodic, even accretion promotes layering,
including lamination, and may be related to seasonal growth,
periodic sedimentation or both (Braga et al., 1995). Modern
marine stromatolites are well known in tidal flat settings, and
the most famous examples are restricted to hypersaline
embayments of Shark Bay in Western Australia (Logan, 1961).
Carbonaceous shales also formed in the supratidal zone and
are interbedded between the stromatolites and evaporites.
Water agitation in the intertidal zone was responsible for the
formation of oolitic beds. Pellets were also accumulated along
the intertidal and subtidal zones. This setting is also suitable for
the deposition of mudstones and stromatolites (Fig. 13).
Shallow-water evaporative environments are associated with
strong microbial activity promoting dolomite formation and
early dolomitization of other carbonate sediments at low
temperature (Schreiber and El Tabakh, 2000). Primary
dolomite deposits may have formed in supratidal and upper
intertidal environments, such as those reported from the
modern coastal lagoon environment in Brazil (Vasconcelos
and McKenzie, 1997).
The dolomite beds containing marine fauna in the form of
bioclasts (Fig. 9(B) and (C)) indicate an open-marine setting
for the original limestones (dolomitised grainstones). The
dolomite beds are finely laminated and rich in organic material,
indicative of restricted conditions. The dolomite–gypsum
cyclicity is the result of periodic deepening (transgressive
shoal) and shallowing (regressive supratidal) conditions.
During deepening carbonates developed. Periodical inundation
of the supratidal sabkha surface during high tides was also
common. This situation is similar to that described by
Alsharhan and Whittle (1995) in the Arabian Gulf. A shallow
carbonate shelf was proposed by Dalqamuni (1995), starting
with a subtidal foraminiferal bioclastic limestone grading into
oolitic shoals, passing into lagoonal pelletal and peloidal
limestone, followed by intertidal stromatolitic limestone that
shifted at the top to nodular anhydrite. The succession
represents a shallowing upward carbonate sabkha sequence,
whereas, a salina was developed in the subsurface where thick
halites were precipitated (Dalqamuni, 1995).
I.M. Makhlouf, A.A. El-Haddad / Journal of Asian Earth Sciences 28 (2006) 372–384 383
It seems that the Abu Ruweis Formation experienced a
remarkable periodicity; a dry season during which more water
left the basin when the evaporation rate is high and
consequently gypsum was deposited; and a humid season
when water is available and the evaporation rate is low. During
the humid season, carbonates (calcite and dolomite) precipi-
tated resulting in distinct lamina of carbonates and admixed
organic matter.
The regularity and lateral persistence of evaporite bedding
(Fig. 3(B)), as well as the alternation of marine carbonates
containing bioclasts, oolites and pellets indicate deposition
under subaqueous marine conditions similar to those happen-
ing today at the Ras Mohamed pool at the northern end of the
Red sea (Friedman, 1982). It is believed that the depositional
conditions changed periodically from a normal marine phase
during when the carbonates were deposited, to an evaporative
phase when the evaporites were deposited. The persistent
stratification was developed due to high seasonal evaporation
rate (Kirkland, 2003).
Mudstone layers were deposited periodically when muddy
flood water inundates the marginal marine salina setting, where
it ponds and settles (Aref et al., 1997) during major flooding
stages and high tides (Lowenstein and Hardie, 1985). The
presence of desiccation cracks (Fig. 11(B)) suggests that
periods of desiccation and exposure may have occurred in the
hypersaline basin, regardless of its initial depth (Schreiber and
El Tabakh, 2000). The presence of vertical cracks filled with
gypsum is most probably related to the formation of
subaqueous shrinkage cracks in an environment subjected to
large salinity fluctuations (Astin and Rogers, 1991; Plummer
and Gostin, 1981). The absence of detrital materials to fill
cracks and their filling by subaqueous gypsum from the
overlying laminated gypsum layer confirm a subaqueous
shrinkage of the cracks (Aref et al., 1997). The thick halite
precipitation encountered in the subsurface reflects greater
evaporation and greater brine concentration (Kendall, 2000).
The frequent occurrence of the organic matter (OM) indicates
the euxinic conditions prevailed throughout the deposition of
Abu Ruweis Formation. The source of some of the organic
debris in such a barred and restricted basin is probably marine
plankton swept in by influx currents (Peterson and Hite, 1969).
It seems that the Abu Ruweis Formation is one of the few
marine evaporite settings where the amount of organic matter
accumulating in the evaporitic facies has been established.
10. Sequence stratigraphy
A proposed sequence stratigraphic framework for the Abu
Ruweis Formation may indicate that the bulk volume of
evaporites formed during lowstand conditions, whereas the
carbonates represent the transgressive and highstand con-
ditions. During evaporative phases, the basin subsided in order
to accommodate the thick evaporite succession. Areas of
sufficient evaporation and low water influx are developed
during periods of low sea level, mainly during a low stand
systems tract. High rates of accumulation of organic matter
indicate that bottom waters were anoxic (Kirkland, 2003). The
development of a barrier caused restriction of the basin,
associated with relatively stable arid climatic conditions,
allowing deposition of a thick prograding succession, similar
to that described by Schroder et al. (2003) in the Early
Cambrian Ara Group in Oman. Kendall (1992) indicated that
low-lying basins with a flat basin floor are flooded rapidly
leading to rapid establishment of open-marine conditions.
Nevertheless, shallow water deposition persisted throughout
the deposition of the Abu Ruweis Formation (Fig. 14).
11. Conclusion
The Abu Ruweis Formation in the Subayhi area has a
tripartite arrangement: thick evaporite beds, thin dolomite beds
and a few shale beds. Several evaporite phases took place
during the deposition of the Abu Ruweis Formation. At the
beginning of each phase; progradation took place and a shallow
water carbonate ramp gradually evolved into a series of
shallow sulfate and halite salinas. Several carbonate–evaporite
sequences are recognized, each consisting of a lower,
carbonate part, containing minor amounts of evaporites,
representing transgressive and highstand systems tracts.
These are overlain by an evaporite part formed mainly during
a lowstand systems tract.
Most of the Abu Ruweis gypsum lithofacies are of
secondary origin as a result of a successive series of
rehydration and hydration processes. The satin spar gypsum
veins scattered within the Abu Ruweis evaporites and
carbonates are considered as a bi-product of the hydration
processes of the precursor anhydrite. The carbonates associated
with the evaporites of the Abu Ruweis Formation are mainly
composed of the mineral dolomite resulted from hypersaline
dolomitization.
Acknowledgements
The authors are greatly indebted to the following institutes
for facilitating analyses. X-ray diffraction analyses were
performed at the laboratories of Assut University, chemical
analyses were performed at the laboratories of the South Valley
University, and isotope analyses were performed at the English
Academic Laboratories through the industrial petroleum
consultancy (FJA) to whom we are most grateful. The
Deanship of Scientific Research at the Hashemite University
is also thanked for providing logistic support. The paper has
been substantially improved as a result of suggestions and
criticisms by Abdulkader Abed, Charlotte Schreiber and Khalil
Ibrahim. We thank them for their advice. Brian Turner and
Basim Moh’d are thanked for their critical reviewing of the
manuscript.
References
Ahmad, A.M., 1989. The Triassic stratigraphy zonation and hydro-carbon
potential of the subsurface sequence of north Jordan. Unpublished report of
Petroleum Geology Division, Petroleum Exploration Directorate, NRA,
Amman, 22pp.
I.M. Makhlouf, A.A. El-Haddad / Journal of Asian Earth Sciences 28 (2006) 372–384384
Alsharhan, A.S., Whittle, G.L., 1995. Carbonate–evaporite sequence of the
Late Jurassic, Southern and Southwestern Arabian Gulf. AAPG Bull. 79
(11), 1608–1630.
Amireh, B., 1993. Three Paleosols of the Nubian Series of Jordan:
Climatologic, tectonic and palaeogeographic implications. J. Dirasat 20B
(4), 33–62.
Amoco oil company, 1987. Source rock evaluation of sediments from
Jordanian well RH-1, WS-2, 3. Petroleum Geochemistry Report, Petra-
chem Ltd. Jordan, pp16.
Andrews, I., 1992. Permian, Triassic and Jurassic lithostratigraphy in the
subsurface of Jordan: natural resources authority of Jordan. Subsurface
Geol. Div., Bull. 4.
Aref, M., Attiia, O., Wali, A., 1997. Facies and depositional environment of the
Holocene evaporites in the Ras Shukeir area, gulf of Suez, Egypt. Sediment.
Geol. 110, 123–145.
Aref, M., Abu El-Enain, F., bdallah, G., 2003. Origin of secondary gypsum of
the Miocene Abu Dabbab Evaporites, NW Red Sea coast, Egypt. Fifth
International Conference on the Geology of the Middle East, pp. 321–330.
Arikat, M. 2000. Sedimentological characteristics and industrial evaluation of
evaporite sequence within the Zarqa Group, nearby Subayhi area, Northern
Jordan. Unpublished MSc thesis, Yarmouk University, Irbid, 113pp.
Arkal, A.V., 1980. Genesis and diagenesis of holocene evaporitic sediments in
Hutt and Leeman lagoons, western Australia. J. Sediment. Petrol. 50/4,
1305–1326.
Astin, T.R., Rogers, D.A., 1991. Subaqueous shrinkage cracks in the devonian
of Scotland reinterpreted. J. Sediment. Petrol. 61 (5), 850–859.
Bandel, K., Khoury, H., 1981. Lithostratigraphy of the Triassic in Jordan.
Erlangen, Facies 4, 1–26.
Bandel, K., Waksmundzki, B., 1985. Triassic conodonts from Jordan. Acta
Geol. Pol. 35, 289–304 (Warszawa).
Basha, S.H., 1982. Microfauna from the Triassic rocks of Jordan. Revue de
Micropaleontologic 25, 3–11.
Bender, F., 1974. Geology of Jordan. Gebruder Borntraeger, Berlin. 196 pp.
Beydoun, Z.R., Habib, J.G., 1995. Lebanon revisited: new insights into Triassic
hydrocarbon prospects. J. Petrol. Geol. 18, 75–90.
Braga, J.C., Martin, J.M., Riding, R., 1995. Controls on microbial dome fabric
development along a carbonate–siliciclastic shelf–basin transect, miocene,
SE Spain. Palaios 10, 347–361.
Dalqamuni, A., 1995. Sequence stratigraphy and petroleum prospects of
theUpper Triassic sediments (Abu Ruweis), North Jordan. Unpublished
MSc thesis, Yarmouk University, Jordan.
Druckman, Y., 1974. The stratigraphy of the Triassic squence in Southern
Israel. Geol. Surv. Bull. 64, 92.
Friedman, G.M., 1982. Evaporites as source rocks for petroleum. In Hanford,
C.R., Houcks, R.G., Davies, G.R. (eds.) Depositional and Diagenetic
Spectra of Evaporites. A Core Workshop, vol.3, SEPMCoreWorkshop, pp.
385–396.
Gill, I.P., Moore, C.H., Aharon, P., 1995. Evaporitic mixed water
dolomitization St Corix, USVI. J. Sediment. Res. 65 (4), 591–604.
Haridie, L.A., 1967. The gypsum–anhydrite equilibrium at one atmospheric
pressure. Am. Mineral. 52, 171–199.
Holliday, D.W., 1970. The petrology of secondary gypsum rocks. J. Sediment.
Petrol. 40, 734–744.
Hussain, M., Warren, J.K., 1989. Nodular and enterolithic gypsum: the
‘sabkhatization’ of salt flat playa,West Texas. J. Sediment. Petrol. 64, 13–24.
Ionides, M.G., Blake, G.S., 1939. Report on the water resources of Transjordan
and their development, local report, Government of Transjordan, 372 pp.
Keegan, J., Majed, H., Shaheen, Y., 1987. Palynological analysis of well Er
Ramtha 1A, interval 1340–2754 m, North Jordan, Report of Biostrati-
graphic and Petroleum Laboratory Division, NRA.
Keegan, J., Shaheen, Y., Majed, H., 1987. Palynological analysis of well Risha-
1 (RH-1), interval 403–3177 m. Report of Biostratigraphic and Petroleum
Geochemistry Section, Petroleum Laboratory Division, NRA.
Kendall, A.C., 1984. Evaporites. In: Walker, R.G., (Ed.), Facies Models,
Geoscience Canada, Reprint Series 1, second ed., pp. 259–296.
Kendall, A.C., 1989. Brine mixing in the devonian of western Canada and
its possible significance to regional dolomitization. Sediment. Geol. 64,
271–285.
Kendall, A.C., 1992. Evaporites. In: Walker, R.G., James, N.B. (Eds.), Facies
Models—Response to Sea Level Change. Geological Association of
Canada, St John’s, pp. 375–409.
Khalil, B., Muneizel, S., 1992. Lithostratigraphy of the Jurassic outcrops of
North Jordan (Azab Group). Natural resources authority of Jordan. Geol.
Mapping Div. Bull. 21.
Kirkland, D.W., 2003. An explanation for the varves of the castile evaporites
(upper Permian), Texas and NewMexico, USA. Sedimentology 50, 898–920.
Logan, B.W., 1961. Cryptozoon and associated stromatolites from the recent,
Shark Bay, western Australia. J. Geol. 69, 517–533.
Lowenstein, T.K., Hardie, L.A., 1985. Criteria for the recognition of salt-pan
evaporites. Sedimentology 32, 627–644.
Lugli, S., Testa, G., 1993. The origin of the gypsum and alabaster spheroids in
the messinian evaporites from castellina marttima (Pisa, Italy), preliminary
observations. Geology 55, 51–68.
Maiklem, W.R., Bebout, D.G., Glaister, R.P., 1969. Classification of anhydrite:
a practical approach. Can. Pet. Geol. Bull. 17, 194–233.
Muneizel, S., Khalil, B. 1993. As salt geological map, shee no. 3154 III (scale
1:50000), natural resources authority of Jordan.GeologicalMappingDivision.
Murray, R.C., 1964. Origin and diagenesis of gypsum and anhydrite. Sediment.
Petrol. 34, 512–523.
Ogniben, L., 1955. Inverse graded bedding in primary gypsum of chemical
deposition. J. Sediment. Petrol. 25, 273–281.
Ogniben, L., 1957. Secondary gypsum of the Sulpher series, sicily. Sediment.
Petrol. 27, 64–79.
Peryt, T.M., 2001.Gypsum facies transitions in basin-marginal evaporites:middle
miocene (Badenian) of west Ukranie. Sedimentology 48, 1103–1119.
Peterson, J.A., Hite, R.J., 1969. Pennsylvanian evaporite, carbonate cycles and
their relation to petroleum occurrences, southern Rocky mountains. Bull.
Am. Assoc. Pet. Geol. 53, 884–908.
Plummer, P.S., Gostin, V.A., 1981. Shrinkage cracks-desiccation or synaeresis.
J. Sediment. Petrol. 51, 1147–1156.
Riding, R., 2000. Microbial carbonates: the geological record of calcified
bacterial-algal mats and biofilms. Sedimentology 47 (Suppl. 1), 179–214.
Sadooni, F.N., 1995. Petroleum prospects of the upper Triassic carbonates in
northern Iraq. J. Petrol. Geol. 18, 171–190.
Sadooni, F.N., Dalqamouni, A., 1998. Geology and petroleum prospects of
upper Triassic sediments, Jordan. Mar. Petrol. Geol. 15, 783–801.
Saqqa, W., Arikat, M., 2003. Suitability of gypsum for the production of
gypsum plaster an example from the Abu Ruweis evaporites (upper
Triassic). Dirasat 2, 167–181.
Schreiber, B.C., El Tabakh, M., 2000. Deposition and early alteration of
evaporites. Sedimentology 47 (Suppl. 1), 215–238.
Schreiber, B.C., Roth, M.S., Helman, M.L., 1982. Recogintion of primary
facies characteristics of evaporites and the differentiation of these forms
from the diagenetic over-prints, In: Handford, C.R., Loucks, R.G., Davies,
G.R., (Eds.), Depositional and Diagenetic Spectra of Evaporites: a Core
Workshop, vol. 3, SEPM Core Workshop, pp. 1–32
Schroder, S., Schreiber, B.C., Amthor, J.E., Matter, A., 2003. A depositional
model for the terminal Neoproterozoic–early Cambrian ara group
evaporites in south Oman. Sedimentology 50, 879–898.
Shearman D.J., 1985. Syndepositional and later diagenetic alteration of primary
gypsum to anhydrite. The Sixth Symposium Salt, the Salt Institute, vol. 1,
pp. 44–55.
Shearman, D.J., Mossop, G., Dunsmone, H., Martine, H., 1972. Origin of
gypsum veins in hydraulic fracture. Trans. Inst. Min. Hetall. Appl. Earth
Sci. 81, 149–155.
Testa, G., Lugli, S., 2000. Gypsum anhydrite transformation in messinion
evaporites of central Tuscany (Italy). Sediment. Geol., 249–268.
Vasconcelos, C., McKenzie, J.A., 1997. Microbial mediation of modern
dolomite precipitation and diagenesis under anoxic conditions (Lagoa
Vermelha, Rio de Janeiro, Brazil). J. Sediment. Res. 67, 378–390.
Warren, J.K., 1999. Evaporites—Their Evolution and Economics. Blackwell,
Oxford. 438 pp.
West, I.M., 1964. Evaporite diagenesis in the lower Purbeck beds of Dorset.
Proc. York Geol. Soc. 34, 315–330.
Wetzel, R., Morton, D.M., 1959. Contribution a la geologie de la
Transjordanie. Notes et Memoires sur le Moyen-Orient 7, 95–191 (Paris).