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Department of Civil and Environmental EngineeringUniversity of Illinois at Urbana-Champaign
Alex Apeagyei
Prof Bill Buttlar
Prof Barry Dempsey
Development of Antioxidant Treatments for Asphalt Binders and Mixtures
November 9, 2005
Outline of Presentation
IntroductionResearch Approach
Experimental Design
Analysis of Results
Summary and Conclusions
Recommendations
Introduction: – Purpose of Study
The goal was to develop Antioxidant (AOX)
treatments …
… to reduce oxidative aging in asphalt binders and mixtures
Problem Statement
The problem of asphalt aging still exists despite
the extensive use of antioxidants:
Issues:
Sacrificial AOX, get consumed with time
Extensive degradation after 2-6 years
Possible environmental concerns
Experimental Plan
Selection of AOXs:- Eight additives
Binder testing
RTFO, PAV Dynamic Shear Rheometer (DSR) Test Bending Beam Rheometer (BBR) Test
Mixture testing Tests performed on most promising AOX system Creep Compliance, Dynamic modulus, Tensile
strength, DC(T) Fracture Energy, Moisture damage
List of AOXs evaluated
1. Irganox 1010
2. Vitamin E (Irganox E201)
3. Irgafos P-EPQ
4. Dilaurylthiodipropionate (DLTDP)
5. Furfural
6. Acryloid B-48N
7. Carbon Black (Raven 790)
8. Hydrated Lime
Evaluation of Aging
Aging Index (AI) used for evaluating aging
AI of binders based on SUPERPAVE Parameters
G*/Sin at 64 ºC
G*Sin at 25 ºC
AI of mixtures based on Creep Compliance, E*, Tensile Strength, Fracture
Energy
unaged
RTFOaged
SinG
SinGAI
/*
/*
Evaluation of Binder Results
Comparison of binder AI after RTFO
1.0
1.2
1.4
1.6
1.8
2.0
2.2
2.4
Specimen
Ag
ing
Ind
ex
AOX-Modified
Control
Aging Index: G*Sin at 25 ºC after PAV
S13
S14
S16
1.0
3.0
5.0
7.0
Sample
Ag
ing
Ind
ex
S13 – DLTDP + Furfural + Catalyst
S14 – Vitamin E + Furfural + catalyst
S16 - Control
Effect of AOXs on G*Sin after PAV
S13
S16 S14
0.0
2.0
4.0
6.0
Sample
Sti
ffn
ess
at 2
5 C
(M
Pa)
Control
Effect of AOXs on Creep Stiffness after PAV
Control
S13
S16S14
0
40
80
120
160
Sample
Sti
ffn
ess
at -
12 C
(M
Pa)
Effect of AOXs on m-value at after PAV
Control
S13
S16S14
0.35
0.40
0.45
0.50
Sample
m-v
alu
e
Effects of AOX on long-term binder aging
0.0
2.0
4.0
6.0
8.0
10.0
25 ºC 64 ºC
Ag
ing
In
dex
Control AOX-Mod
Improvement 40%
Improvement 20%
Selection of most promising AOX
S13 contains DLTDP/Furfural + catalyst
S13 is most preferred AOX treatment
Sample S13 will be labeled AOX-Modified
Asphalt concrete mixtures limited to S13
Asphalt Mixture Fabrication
Materials:
Limestone aggregates (9.5 mm Nom. Max)
PG 64-22 binder (Control)
AOX-Modified PG 64-22 binder
Mixture Aging
Short-term oven aging (135 ºC for 2 hours, STOA-2h)
Long-term oven aging (135 ºC for 8 hours, LTOA-8h)
Mixture Tests Performed
1. Creep Compliance
2. Dynamic Modulus E*
3. Indirect Tensile Strength
4. DC(T) Fracture Test (Wagoner et al. 2004)
5. Moisture Susceptibility
Creep Compliance master curve (Tref = -20 C)
0
0.05
0.1
0.15
0.2
0.25
0.3
0.35
0.4
0.45
1 100 10000 1000000
Reduced Time (sec)
Cre
ep C
om
plia
nce
(1/
GP
a)
Control-STOA-2h: m=0.47 Modified-STOA-2h: m=0.4021Modified-LTOA-8h: m=0.3813 Control-LTOA-8h: m=0.3597
Effect of aging on creep compliance
0.0
0.2
0.4
0.6
0.8
1.0
1 1000 1000000
Reduced Time (sec)
Ret
ain
ed
Cre
ep C
om
plia
nce
AOX-ModifiedControl
E* master curve (Tref = 20 ºC)
0
5000
10000
15000
20000
25000
0.001 0.1 10 1000 100000 1E+07
Reduced Frequency (Hz)
Dyn
am
ic M
od
ulu
s E
* (M
Pa)
Mod-LTOA-8hMod-STOA-2hContr_LTOA-8hContr-STOA-2h
Tref = 20 0C
Effect of aging on dynamic modulus E*
1.0
1.4
1.8
2.2
0.001 0.1 10 1000 100000 1E+07
Reduced Frequency (Hz)
Ag
ing
Ind
ex
AOX-ModifiedControl
DC(T) Fracture Testing
Test Setup
DC(T) Specimen
Effect of Aging on Fracture Energy
0.0
0.4
0.8
1.2
1.6
0 ºC -10 ºC
Ret
ain
ed F
ract
ure
En
erg
y
Control
AOX-Mod
Moisture Susceptibility
To investigate the moisture damage
potential of AOX-Modified Asphalt Mix
Tests performedAASHTO T283 [Tensile Strength Ratio, TSR]DC(T ) [Fracture Energy Ratio, FER]
Aggregates used: Limestone
Limestone Results Summary
0.0
0.4
0.8
1.2
1.6
TSR FER
Mo
istu
re D
amag
e ra
tio
Control
AOX-Mod
Limestone mixtures: Visual rating
74.0TSR 43.0TSR
Conclusion
The AOX treatments evaluated during this
study appear to cause significant reduction in
age-hardening of the PG 64-22 asphalt used
Recommendations
Evaluate AOXs using different asphalt sources
Full-scale production of the AOX-Modified
Construction of Full-scale pavement sections
Accelerated testing
Long-term performance evaluation
Acknowledgements
Research conducted at ATREL and was
supported by the Center of Excellence for
Airport Technology funded by the FAA
Special thanks to:
Prof Barry Dempsey – Director of Research
Prof Bill Buttlar – Advisor
End of Presentation
Thank You!