De Broglie Waves

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    LOUIS DE BROGLIE'S CONCEPT OFMATTER WAVES

    Louis de Broglie asked himself "doesnature respect symmetry?" He wasconvinced that it does. He postulated thatjust as light has dual character, so doesmatter. So for a photon,

    E = h.(1)also E = p c .(2)

    (for a particle of zero rest like Photon)Equating (1) and (2)

    p c = h or p = h/c =h/p = h/ ..(3)

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    The above equation was interpreted byde Broglie as the correlation betweenparticle (momentum p) and wave (wave

    length ) characteristics. He simply invertedthe equation and wrote it as

    = h/ p ..(4)and declared that particle of matter ofmomentum p must have its dual wavecharacter of wave length . The wavesassociated with matter are called matter-waves. Matter-waves cannot be consideredas oscillations of some field (s) like electro-magnetic waves. They are also calledprobability waves.

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    A beam of electrons acceleratedthrough the potential V were allowed to

    strike a nickle crystal. Measurements weremade to count the number of electronsscattered by the crystal.

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    Davisson and Germer further investigatedwith properly oriented crystals thatelectron behave as waves of all wave

    lengths () as given by De-Broglie'shypothesis. They calculated the wavelength of electron from the knownaccelerating potential V by applying the

    relation:=12.24/V1/2 Ao

    OBSERVATIONS

    Davisson and Germerreported unexpected

    results that the electronsreflected very strongly atcertain angles only andnot at other directions.

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    vm

    h

    m

    eVv

    or

    vmeV

    2

    2

    1 2Kinetic energygained by theelectron when

    acclerated through Vvolts

    De-Broglie

    wavelength is givenby

    Substituting for v

    e-charge on electronh-Plancks constant

    mo-rest mass of

    electronA

    VeVm

    h

    or

    m

    eVm

    h

    vm

    h

    24.12

    2

    2

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    PHASE VELOCITY AND GROUP VELOCITY

    The de Broglie wave velocity/phase velocity isgiven by

    vp=..(1)

    where is the frequency is the de Broglie

    wavelength=h/mv.

    Equating the quantum expression E=h with therelativistic total energy E=mc2 to obtain h = mc2or = mc2 /h.

    The de Broglie wave velocity is therefore

    vp = = (mc2 /h)(h/mv)

    vp =c2/v..(2)

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    As vc! violating special relativity;de Broglie introduced the concept of groupvelocity vg and showed that a group of waves

    need not have the same velocity as the wavesthemselves to avoid the violation.

    To begin with consider a group of waves

    formed by combining the two waves differingslightly in frequency and wave number as

    Y1=Acos(t-kx) .(1)

    and

    Y2=Acos[(+)t-(k+ k)x] .(2)

    The resultant displacement Y at any time t andany position x is the sum of Y1 and Y2

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    With the help of trigonometric identity

    cosA + cosB = 2 cos[(A+B)/2] cos[(A-B)/2] and

    cos(-A) = cos(A) .(3)

    We find

    Y=Y1 + Y2

    =2Acos[(2+)t/2 + (2k+k)x/2]*cos[(t- kx)/2] ..(4)

    Since and k are small compared with andk respectively,

    2+ 2 and 2k+k 2k and so

    Y= 2Acos(t-kx) cos[(t- kx)/2] ..(5)

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    Equation (5) represents a wave of angularfrequency aand wave number k that has

    superimposed upon it a modulation of angularfrequency /2 and of wave number k/2.

    The effect of modulation is thus to producesuccessive wave groups as shown

    +

    =

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