15
Time 1 5 10 Volume of titrating NaOH (ml) 6.3 21.3 24.1 2.52 8.52 9.64 7.48 1.48 0.36 Mole of HCl reacted with NaOH in Sample 0.00187 0.00037 0.00009 Mole of NaOH Unreacted in Sample 0.00187 0.00037 0.00009 0.00374 0.00074 0.00018 0.9626 0.9926 0.9982 0.04626 0.09926 0.09982 0.02313 0.04963 0.04991 0.04626 0.09926 0.09982 0.05374 0.00074 0.00018 Time 1 5 10 ln -2.923598 -7.20886 -8.622554 1/CA 18.60811 1351.351 5555.556 Volume of quenching HCl Unreacted with NaOH in Sample (ml) [C] Volume of HCl reacted with NaOH in Sample (ml) Concentration of NaOH Unreacted with Ethyl Acetate (mol/L) Steady state fraction of NaOH, XA Concentration of NaOH reacted with Ethyl Acetate (mol/L) Mole of NaOH reacted with Ethyl Acetate in Sample Concentration of Ethyl Acetate Reacted with NaOH (moles/L) Concentration of Ethyl Acetate Unreacted (moles/L) -1 -1 - - - - 0 5 10 15 20 25 3 -30000 -25000 -20000 -15000 -10000 -5000 0 5000 10000 15000 1/CA

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Page 1: cstr rate of reaction

Time 1 5 10Volume of titrating NaOH (ml) 6.3 21.3 24.1

2.52 8.52 9.64

7.48 1.48 0.36

Mole of HCl reacted with NaOH in Sample 0.00187 0.00037 0.00009Mole of NaOH Unreacted in Sample 0.00187 0.00037 0.00009

0.00374 0.00074 0.000180.9626 0.9926 0.9982

0.04626 0.09926 0.09982

0.02313 0.04963 0.04991

0.04626 0.09926 0.09982

0.05374 0.00074 0.00018Time 1 5 10

ln -2.923598 -7.20886 -8.6225541/CA 18.60811 1351.351 5555.556

Volume of quenching HCl Unreacted with NaOH in Sample (ml) [C]

Volume of HCl reacted with NaOH in Sample (ml)

Concentration of NaOH Unreacted with Ethyl Acetate (mol/L)

Steady state fraction of NaOH, XA

Concentration of NaOH reacted with Ethyl Acetate (mol/L)

Mole of NaOH reacted with Ethyl Acetate in Sample

Concentration of Ethyl Acetate Reacted with NaOH (moles/L)

Concentration of Ethyl Acetate Unreacted (moles/L)

0 5 10 15 20 25 30

-12

-10

-8

-6

-4

-2

0

f(x) = - 0.3397488057x - 4.1975875381R² = 0.8124008581

ln

0 5 10 15 20 25 30

-30000

-25000

-20000

-15000

-10000

-5000

0

5000

10000

15000

1/CA

Page 2: cstr rate of reaction

15 20 2524.6 25.2 25.0

9.84 10.08 10

0.16 -0.08 0

0.00004 -0.00002 00.00004 -0.00002 0

0.00008 -0.00004 00.9992 1.0004 1

0.09992 0.10004 0.1

0.04996 0.05002 0.05

0.09992 0.10004 0.1

0.00008 -0.00004 015 20 25

-9.433484 -10.12663 Err:50212500 -25000 #DIV/0!

0 5 10 15 20 25 30-0.01

0

0.01

0.02

0.03

0.04

0.05

0.06

f(x) = -0.0162257008 ln(x) + 0.0438252831R² = 0.7828551998

Concentration of Ethyl Acetate Unreacted (moles/L)

Axis Title

Axis Title

0 5 10 15 20 25 30

-12

-10

-8

-6

-4

-2

0

f(x) = - 0.3397488057x - 4.1975875381R² = 0.8124008581

ln

0 5 10 15 20 25 30

-30000

-25000

-20000

-15000

-10000

-5000

0

5000

10000

15000

1/CA

Page 3: cstr rate of reaction

0 5 10 15 20 25 30-0.01

0

0.01

0.02

0.03

0.04

0.05

0.06

f(x) = -0.0162257008 ln(x) + 0.0438252831R² = 0.7828551998

Concentration of Ethyl Acetate Unreacted (moles/L)

Axis Title

Axis Title

Page 4: cstr rate of reaction

0 5 10 15 20 25 30-0.01

0

0.01

0.02

0.03

0.04

0.05

0.06

f(x) = -0.0162257008 ln(x) + 0.0438252831R² = 0.7828551998

Concentration of Ethyl Acetate Unreacted (moles/L)

Axis Title

Axis Title

Page 5: cstr rate of reaction

Time 1 5 10

Volume of titrating NaOH (ml) 26.8 24.5 24.0

10.72 9.8 9.6

-0.72 0.2 0.4

-0.00018 0.00005 0.0001Mole of NaOH Unreacted in Sample -0.00018 0.00005 0.0001

-0.00036 0.0001 0.00021.0072 0.999 0.998

0.05036 0.0499 0.0498

0.02518 0.02495 0.0249

0.05036 0.0499 0.0498

0.04964 0.0501 0.0502

Time 1 5 10ln (CA) -3.002958 -2.9937342709 -2.991741/CA 20.14504 19.9600798403 19.92032

Volume of quenching HCl Unreacted with NaOH in Sample (ml) [C]

Volume of HCl reacted with NaOH in Sample (ml)

Mole of HCl reacted with NaOH in Sample

Concentration of NaOH Unreacted with Ethyl Acetate (mol/L)

Steady state fraction of NaOH, XA

Concentration of NaOH reacted with Ethyl Acetate (mol/L)

Mole of NaOH reacted with Ethyl Acetate in Sample

Concentration of Ethyl Acetate Reacted with NaOH (moles/L)

Concentration of Ethyl Acetate Unreacted (moles/L)

0 5 10 15 20 25 3019.8

19.85

19.9

19.95

20

20.05

20.1

20.15

20.2

f(x) = - 0.0038383803x + 20.046200224R² = 0.2045195593

1/CA

Page 6: cstr rate of reaction

0 5 10 15 20 25 3019.8

19.85

19.9

19.95

20

20.05

20.1

20.15

20.2

f(x) = - 0.0038383803x + 20.046200224R² = 0.2045195593

1/CA

Page 7: cstr rate of reaction

15 20 25

25.0 24.8 24.7

10 9.92 9.88

0 0.08 0.12

0 0.00002 0.000030 0.00002 0.00003

0 0.00004 0.000061 0.9996 0.9994

0.05 0.04996 0.04994

0.025 0.02498 0.02497

0.05 0.04996 0.04994

0.05 0.05004 0.05006

15 20 25-2.995732 -2.994933 -2.994533

20 19.98401 19.97603

0 5 10 15 20 25 30

-3.004

-3.002

-3

-2.998

-2.996

-2.994

-2.992

-2.99

-2.988

-2.986

f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669

ln (CA)

0 5 10 15 20 25 3019.8

19.85

19.9

19.95

20

20.05

20.1

20.15

20.2

f(x) = - 0.0038383803x + 20.046200224R² = 0.2045195593

1/CA

Page 8: cstr rate of reaction

0 5 10 15 20 25 30

-3.004

-3.002

-3

-2.998

-2.996

-2.994

-2.992

-2.99

-2.988

-2.986

f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669

ln (CA)

0 5 10 15 20 25 3019.8

19.85

19.9

19.95

20

20.05

20.1

20.15

20.2

f(x) = - 0.0038383803x + 20.046200224R² = 0.2045195593

1/CA

Page 9: cstr rate of reaction

0 5 10 15 20 25 30

-3.004

-3.002

-3

-2.998

-2.996

-2.994

-2.992

-2.99

-2.988

-2.986

f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669

ln (CA)

0 5 10 15 20 25 30

-3.004

-3.002

-3

-2.998

-2.996

-2.994

-2.992

-2.99

-2.988

-2.986

f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669

ln (CA)

Page 10: cstr rate of reaction

0 5 10 15 20 25 30

-3.004

-3.002

-3

-2.998

-2.996

-2.994

-2.992

-2.99

-2.988

-2.986

f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669

ln (CA)

0 5 10 15 20 25 30

-3.004

-3.002

-3

-2.998

-2.996

-2.994

-2.992

-2.99

-2.988

-2.986

f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669

ln (CA)

Page 11: cstr rate of reaction

0 5 10 15 20 25 30

-3.004

-3.002

-3

-2.998

-2.996

-2.994

-2.992

-2.99

-2.988

-2.986

f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669

ln (CA)

Page 12: cstr rate of reaction

0 5 10 15 20 25 30

-3.004

-3.002

-3

-2.998

-2.996

-2.994

-2.992

-2.99

-2.988

-2.986

f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669

ln (CA)

Page 13: cstr rate of reaction

Time 1 5 10 15Volume of titrating NaOH (ml) 26.7 25.2 25.6 25.6

10.68 10.08 10.24 10.24

-0.68 -0.08 -0.24 -0.24

-0.00017 -0.00002 -0.00006 -0.00006Mole of NaOH Unreacted in Sample -0.00017 -0.00002 -0.00006 -0.00006

-0.00034 -0.00004 -0.00012 -0.000121.0034 1.0004 1.0012 1.0012

0.05034 0.05004 0.05012 0.05012

0.02517 0.02502 0.02506 0.02506

0.05034 0.05004 0.05012 0.05012

0.04966 0.04996 0.04988 0.04988Time 1 5 10 15lnCa -3.002555 -2.996533 -2.998135 -2.9981351/ca 20.13693 20.01601 20.04812 20.04812

Volume of quenching HCl Unreacted with NaOH in Sample

(ml) [C]

Volume of HCl reacted with NaOH in Sample (ml)

Mole of HCl reacted with NaOH in Sample

Concentration of NaOH Unreacted with Ethyl Acetate (mol/L)

Steady state fraction of NaOH, XA

Concentration of NaOH reacted with Ethyl Acetate (mol/L)

Mole of NaOH reacted with Ethyl Acetate in Sample

Concentration of Ethyl Acetate Reacted with NaOH (moles/L)

Concentration of Ethyl Acetate Unreacted (moles/L)

Page 14: cstr rate of reaction

20 2525.8 25.0

10.32 10

-0.32 0

-0.00008 0-0.00008 0

-0.00016 01.0016 1

0.05016 0.05

0.02508 0.025

0.05016 0.05

0.04984 0.0520 25

-2.998937 -2.99573220.06421 20

0 5 10 15 20 25 30

-3.004

-3.002

-3

-2.998

-2.996

-2.994

-2.992

f(x) = 0.0001525083x - 3.0002697859R² = 0.3399662853

lnCa

0 5 10 15 20 25 3019.9

19.95

20

20.05

20.1

20.15

f(x) = - 0.0030616771x + 20.0910113028R² = 0.3401334708

1/ca

Page 15: cstr rate of reaction

0 5 10 15 20 25 300.0494

0.0495

0.0496

0.0497

0.0498

0.0499

0.05

0.0501

f(x) = 7.59677419354853E-006x + 0.0497737742R² = 0.3397987317

Concentration of Ethyl Acetate Unreacted (moles/L)

0 5 10 15 20 25 30

-3.004

-3.002

-3

-2.998

-2.996

-2.994

-2.992

f(x) = 0.0001525083x - 3.0002697859R² = 0.3399662853

lnCa

0 5 10 15 20 25 3019.9

19.95

20

20.05

20.1

20.15

f(x) = - 0.0030616771x + 20.0910113028R² = 0.3401334708

1/ca