Upload
queen
View
224
Download
10
Embed Size (px)
DESCRIPTION
format for calculation
Citation preview
Time 1 5 10Volume of titrating NaOH (ml) 6.3 21.3 24.1
2.52 8.52 9.64
7.48 1.48 0.36
Mole of HCl reacted with NaOH in Sample 0.00187 0.00037 0.00009Mole of NaOH Unreacted in Sample 0.00187 0.00037 0.00009
0.00374 0.00074 0.000180.9626 0.9926 0.9982
0.04626 0.09926 0.09982
0.02313 0.04963 0.04991
0.04626 0.09926 0.09982
0.05374 0.00074 0.00018Time 1 5 10
ln -2.923598 -7.20886 -8.6225541/CA 18.60811 1351.351 5555.556
Volume of quenching HCl Unreacted with NaOH in Sample (ml) [C]
Volume of HCl reacted with NaOH in Sample (ml)
Concentration of NaOH Unreacted with Ethyl Acetate (mol/L)
Steady state fraction of NaOH, XA
Concentration of NaOH reacted with Ethyl Acetate (mol/L)
Mole of NaOH reacted with Ethyl Acetate in Sample
Concentration of Ethyl Acetate Reacted with NaOH (moles/L)
Concentration of Ethyl Acetate Unreacted (moles/L)
0 5 10 15 20 25 30
-12
-10
-8
-6
-4
-2
0
f(x) = - 0.3397488057x - 4.1975875381R² = 0.8124008581
ln
0 5 10 15 20 25 30
-30000
-25000
-20000
-15000
-10000
-5000
0
5000
10000
15000
1/CA
15 20 2524.6 25.2 25.0
9.84 10.08 10
0.16 -0.08 0
0.00004 -0.00002 00.00004 -0.00002 0
0.00008 -0.00004 00.9992 1.0004 1
0.09992 0.10004 0.1
0.04996 0.05002 0.05
0.09992 0.10004 0.1
0.00008 -0.00004 015 20 25
-9.433484 -10.12663 Err:50212500 -25000 #DIV/0!
0 5 10 15 20 25 30-0.01
0
0.01
0.02
0.03
0.04
0.05
0.06
f(x) = -0.0162257008 ln(x) + 0.0438252831R² = 0.7828551998
Concentration of Ethyl Acetate Unreacted (moles/L)
Axis Title
Axis Title
0 5 10 15 20 25 30
-12
-10
-8
-6
-4
-2
0
f(x) = - 0.3397488057x - 4.1975875381R² = 0.8124008581
ln
0 5 10 15 20 25 30
-30000
-25000
-20000
-15000
-10000
-5000
0
5000
10000
15000
1/CA
0 5 10 15 20 25 30-0.01
0
0.01
0.02
0.03
0.04
0.05
0.06
f(x) = -0.0162257008 ln(x) + 0.0438252831R² = 0.7828551998
Concentration of Ethyl Acetate Unreacted (moles/L)
Axis Title
Axis Title
0 5 10 15 20 25 30-0.01
0
0.01
0.02
0.03
0.04
0.05
0.06
f(x) = -0.0162257008 ln(x) + 0.0438252831R² = 0.7828551998
Concentration of Ethyl Acetate Unreacted (moles/L)
Axis Title
Axis Title
Time 1 5 10
Volume of titrating NaOH (ml) 26.8 24.5 24.0
10.72 9.8 9.6
-0.72 0.2 0.4
-0.00018 0.00005 0.0001Mole of NaOH Unreacted in Sample -0.00018 0.00005 0.0001
-0.00036 0.0001 0.00021.0072 0.999 0.998
0.05036 0.0499 0.0498
0.02518 0.02495 0.0249
0.05036 0.0499 0.0498
0.04964 0.0501 0.0502
Time 1 5 10ln (CA) -3.002958 -2.9937342709 -2.991741/CA 20.14504 19.9600798403 19.92032
Volume of quenching HCl Unreacted with NaOH in Sample (ml) [C]
Volume of HCl reacted with NaOH in Sample (ml)
Mole of HCl reacted with NaOH in Sample
Concentration of NaOH Unreacted with Ethyl Acetate (mol/L)
Steady state fraction of NaOH, XA
Concentration of NaOH reacted with Ethyl Acetate (mol/L)
Mole of NaOH reacted with Ethyl Acetate in Sample
Concentration of Ethyl Acetate Reacted with NaOH (moles/L)
Concentration of Ethyl Acetate Unreacted (moles/L)
0 5 10 15 20 25 3019.8
19.85
19.9
19.95
20
20.05
20.1
20.15
20.2
f(x) = - 0.0038383803x + 20.046200224R² = 0.2045195593
1/CA
0 5 10 15 20 25 3019.8
19.85
19.9
19.95
20
20.05
20.1
20.15
20.2
f(x) = - 0.0038383803x + 20.046200224R² = 0.2045195593
1/CA
15 20 25
25.0 24.8 24.7
10 9.92 9.88
0 0.08 0.12
0 0.00002 0.000030 0.00002 0.00003
0 0.00004 0.000061 0.9996 0.9994
0.05 0.04996 0.04994
0.025 0.02498 0.02497
0.05 0.04996 0.04994
0.05 0.05004 0.05006
15 20 25-2.995732 -2.994933 -2.994533
20 19.98401 19.97603
0 5 10 15 20 25 30
-3.004
-3.002
-3
-2.998
-2.996
-2.994
-2.992
-2.99
-2.988
-2.986
f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669
ln (CA)
0 5 10 15 20 25 3019.8
19.85
19.9
19.95
20
20.05
20.1
20.15
20.2
f(x) = - 0.0038383803x + 20.046200224R² = 0.2045195593
1/CA
0 5 10 15 20 25 30
-3.004
-3.002
-3
-2.998
-2.996
-2.994
-2.992
-2.99
-2.988
-2.986
f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669
ln (CA)
0 5 10 15 20 25 3019.8
19.85
19.9
19.95
20
20.05
20.1
20.15
20.2
f(x) = - 0.0038383803x + 20.046200224R² = 0.2045195593
1/CA
0 5 10 15 20 25 30
-3.004
-3.002
-3
-2.998
-2.996
-2.994
-2.992
-2.99
-2.988
-2.986
f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669
ln (CA)
0 5 10 15 20 25 30
-3.004
-3.002
-3
-2.998
-2.996
-2.994
-2.992
-2.99
-2.988
-2.986
f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669
ln (CA)
0 5 10 15 20 25 30
-3.004
-3.002
-3
-2.998
-2.996
-2.994
-2.992
-2.99
-2.988
-2.986
f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669
ln (CA)
0 5 10 15 20 25 30
-3.004
-3.002
-3
-2.998
-2.996
-2.994
-2.992
-2.99
-2.988
-2.986
f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669
ln (CA)
0 5 10 15 20 25 30
-3.004
-3.002
-3
-2.998
-2.996
-2.994
-2.992
-2.99
-2.988
-2.986
f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669
ln (CA)
0 5 10 15 20 25 30
-3.004
-3.002
-3
-2.998
-2.996
-2.994
-2.992
-2.99
-2.988
-2.986
f(x) = 0.0001911191x - 2.998025959R² = 0.2036786669
ln (CA)
Time 1 5 10 15Volume of titrating NaOH (ml) 26.7 25.2 25.6 25.6
10.68 10.08 10.24 10.24
-0.68 -0.08 -0.24 -0.24
-0.00017 -0.00002 -0.00006 -0.00006Mole of NaOH Unreacted in Sample -0.00017 -0.00002 -0.00006 -0.00006
-0.00034 -0.00004 -0.00012 -0.000121.0034 1.0004 1.0012 1.0012
0.05034 0.05004 0.05012 0.05012
0.02517 0.02502 0.02506 0.02506
0.05034 0.05004 0.05012 0.05012
0.04966 0.04996 0.04988 0.04988Time 1 5 10 15lnCa -3.002555 -2.996533 -2.998135 -2.9981351/ca 20.13693 20.01601 20.04812 20.04812
Volume of quenching HCl Unreacted with NaOH in Sample
(ml) [C]
Volume of HCl reacted with NaOH in Sample (ml)
Mole of HCl reacted with NaOH in Sample
Concentration of NaOH Unreacted with Ethyl Acetate (mol/L)
Steady state fraction of NaOH, XA
Concentration of NaOH reacted with Ethyl Acetate (mol/L)
Mole of NaOH reacted with Ethyl Acetate in Sample
Concentration of Ethyl Acetate Reacted with NaOH (moles/L)
Concentration of Ethyl Acetate Unreacted (moles/L)
20 2525.8 25.0
10.32 10
-0.32 0
-0.00008 0-0.00008 0
-0.00016 01.0016 1
0.05016 0.05
0.02508 0.025
0.05016 0.05
0.04984 0.0520 25
-2.998937 -2.99573220.06421 20
0 5 10 15 20 25 30
-3.004
-3.002
-3
-2.998
-2.996
-2.994
-2.992
f(x) = 0.0001525083x - 3.0002697859R² = 0.3399662853
lnCa
0 5 10 15 20 25 3019.9
19.95
20
20.05
20.1
20.15
f(x) = - 0.0030616771x + 20.0910113028R² = 0.3401334708
1/ca
0 5 10 15 20 25 300.0494
0.0495
0.0496
0.0497
0.0498
0.0499
0.05
0.0501
f(x) = 7.59677419354853E-006x + 0.0497737742R² = 0.3397987317
Concentration of Ethyl Acetate Unreacted (moles/L)
0 5 10 15 20 25 30
-3.004
-3.002
-3
-2.998
-2.996
-2.994
-2.992
f(x) = 0.0001525083x - 3.0002697859R² = 0.3399662853
lnCa
0 5 10 15 20 25 3019.9
19.95
20
20.05
20.1
20.15
f(x) = - 0.0030616771x + 20.0910113028R² = 0.3401334708
1/ca