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    Types of Crystals

    Shapes and Structures

    By Anne Marie Helmenstine, Ph.D., About.com Guide

    See More About:

    crystallography

    crystal lattices

    physical properties

    chemical properties

    crystals

    Copper sulfate has a triclinic crystal structure.

    Stephanb, wikipedia.org

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    Crystal Grouped by Lattices (Shape)

    8here are se;en crystal lattice systems. only one lattice point per unit cell? or nonprimiti;e >more than one lattice

    point per unit cell?. Combining the crystal systems !ith the lattice types yields the *4Bra;ais attices >named after Auguste Bra;ais, !ho !or#ed out lattice structures in

    *-)?. 8he structure of real crystals is pretty complicated: 1aCl?is an e%ample of this type of crystal.

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    A specified motif !hich is translated linearly and repeated many times !ill

    produce a lattice. A lattice is an array of points !hich define a repeated spatial

    entity called a unit cell. 8he unit cell of a lattice is the smallest unit !hich can

    be repeated in three dimensions in order to construct the lattice. 8he corners of

    the unit cell ser;e as points !hich are repeated to form the lattice arrayE these

    points are termed lattice points.

    8he number of possible lattices is limited. 'n the plane only fi;e different

    lattices may be produced by translation. 8he 6rench crystallographer Auguste

    Bra;ais >*-***-3@? established that in threedimensional space only fourteen

    different lattices may be constructed. 8hese fourteen different lattice structures

    are thus termed the ra%ais lattices.

    8he reflection, rotation, in;ersion, and rotoin;ersion symmetry operations

    may be combined in a ;ariety of different !ays. 8here are thirtyt!o possible

    uniue combinations of symmetry operations. Minerals possessing the different

    combinations are therefore categori0ed as members of thirtyt!o crystal

    classesE each crystal class corresponds to a uniue set of symmetry operations.

    $ach of the crystal classes is named according to the ;ariant of a crystal form

    !hich it displays. $ach crystal class is grouped as one of the si% different

    crystal systemsaccording to !hich characteristic symmetry operation it

    possesses.

    A crystal formis a set of planar faces !hich are geometrically eui;alent

    and !hose spatial positions are related to one another by a specified set of

    symmetry operations. 'f one face of a crystal form is defined, the specified set

    of point symmetry operations !ill determine all of the other faces of the crystalform.

    A simple crystal may consist of only a single crystal form. A more

    complicated crystal may be a combination of se;eral different forms. 8he

    crystal forms of the fi;e nonisometric crystal systems are the monohedron or

    pedion, parallelohedron or pinacoid, dihedron, or dome and sphenoid,

    disphenoid, prism, pyramid, dipyramid, trape0ohedron, scalenohedron,

    rhombohedron and tetrahedron. 6ifteen different forms are possible !ithin the

    isometric system.

    $ach crystal class is a member of one of si% crystal systems. 8hese systems

    include the isometric, he%agonal, tetragonal, orthorhombic, monoclinic, andtriclinic systems. 8he he%agonal crystal system is further bro#en do!n into the

    he%agonal and rhombohedral di;isions. $;ery crystal of a certain crystal

    system !ill share a characteristic symmetry element !ith the other members of

    its system. 8he crystal system of a mineral species may sometimes be

    determined ;isually by e%amining a particularly !ellformed crystal of the

    species.

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    *' Symmetry and Lattices

    8op

    Symmetry

    Crystals possess a regular, repetiti;e internal structure. 8he concept of

    symmetrydescribes the repetition of structural features. Crystals therefore

    possess symmetry, and much of the discipline of crystallography is concerned

    !ith describing and cataloging different types of symmetry.

    8!o general types of symmetry e%ist. 8hese consist of translational

    symmetryand point symmetry. 8ranslational symmetry describes the periodic

    repetition of a structural feature across a length or through an area or ;olume.

    Point symmetry, on the other hand, describes the periodic repetition of astructural feature around a point. 5eflection, rotation, and in;ersion are all

    point symmetries.

    Lattices

    8he concept of a latticeis directly related to the idea of translational

    symmetry. A lattice is a net!or# or array composed of single motif !hich has

    been translated and repeated at fi%ed inter;als throughout space. 6or e%ample, a

    suare !hich is translated and repeated many times across the plane !ill

    produce a planar suare lattice.8he unit cellof a lattice is the smallest unit !hich can be repeated in three

    dimensions in order to construct the lattice. 'n a crystal, the unit cell consists of

    a specific group of atoms !hich are bonded to one another in a set geometrical

    arrangement. 8his unit and its constituent atoms are then repeated o;er and

    o;er in order to construct the crystal lattice. 8he surroundings in any gi;en

    direction of one corner of a unit cell must be identical to the surroundings in the

    same direction of all the other corners. 8he corners of the unit cell therefore

    ser;e as points !hich are repeated to form a lattice arrayE these points are

    termed lattice points. 8he ;ectors !hich connect a straight line of eui;alent

    lattice points and delineate the edges of the unit cell are #no!n as thecrystalloraphic a#es.

    8he number of possible lattices is limited. 'n the plane only fi;e different

    lattices may be produced by translation. ne of these lattices possesses a suare

    unit cell !hile another possesses a rectangular unit cell. 8he third possible

    planar lattice possesses a centered rectangular unit cell, !hich contains a lattice

    point in the center as !ell as lattice points on the corners. 8he unit cell of the

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    fourth possible planar lattice is a parallelogram, and that of the final planar

    lattice is a he%agonal unit cell !hich may alternately be considered a rhombus.

    Bravais Lattices

    8op

    8he 6rench crystallographer Auguste Bra;ais >*-***-3@? established that

    in threedimensional space only fourteen different lattices may be constructed.

    8he fourteen ra%ais latticesmay be di;ided among si% crystal systems. 8hese

    are the isometric or cubic, tetragonal, orthorhombic, monoclinic, triclinic, and

    he%agonal systems. >8he si% crystal systemsare discussed belo!.? 8he Bra;ais

    lattices are furthermore of three different types. A primiti%e latticehas only a

    lattice point at each corner of the threedimensional unit cell. A body+centered

    latticecontains not only lattice points at each corner of the unit cell but also

    contains a lattice point at the center of the threedimensional unit cell. A face+

    centered latticepossesses not only lattice points at the corners of the unit cell

    but also at either the centers of "ust one pair of faces or else at the centers of all

    three pairs of faces. 8he fourteen Bra;ais lattices are therefore the primiti;e

    cubic, bodycentered cubic, facecentered cubic, primiti;e tetragonal, body

    centered tetragonal, primiti;e orthorhombic, bodycentered orthorhombic,

    single facecentered orthorhombic, multiple facecentered orthorhombic,

    primiti;e monoclinic, single facecentered monoclinic, primiti;e triclinic,

    single facecentered he%agonal, and rhombohedral lattices. >8he rhombohedral

    lattice is a subset of the he%agonal crystal system.?

    Point Symmetry Operations

    $oint symmetrydescribes the repetition of a motif or structural feature

    around a single reference point, commonly the center of a unit cell or a crystal.

    8he different pointsymmetry operations are reflection, rotation, in;ersion, and

    the combined operation rotoin;ersion.

    A reflectionoccurs !hen the structure features on one side of a plane

    passing through the center of a crystal are the mirror image of the structural

    features on the other side. 8he plane across !hich the reflection occurs is then

    termed a mirror plane.

    otational symmetryarises !hen a structural element is rotated a fi%ed

    number of degrees about a central point and then repeated. A suare, for

    e%ample, possesses 4fold rotational symmetry because it may be rotated four

    times by ()F about its central point before it is returned to its original position.

    $ach time it is rotated by ()F the resultant suare !ill be identical in

    appearance to the original suare.

    'f a crystal possesses in%ersion symmetry, then any line !hich is dra!n

    http://dave.ucsc.edu/myrtreia/crystal.htmlhttp://dave.ucsc.edu/myrtreia/crystal.html#SYSTEMShttp://dave.ucsc.edu/myrtreia/crystal.htmlhttp://dave.ucsc.edu/myrtreia/crystal.html#SYSTEMS
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    through the origin at the center of the crystal !ill connect t!o identical features

    on opposite sides of the crystal.

    otoin%ersionis a compound symmetry operation !hich is produced by

    performing a rotation follo!ed by an in;ersion. *fold, fold, @fold, 4fold,

    and 3fold rotoin;ersion operations e%ist. Most of these rotoin;ersions may

    alternately be described by a specified set of rotation, reflection and in;ersion

    operations. A *fold rotoin;ersion is eui;alent to rotation by @3)F follo!ed by

    in;ersion. 8his procedure is ultimately eui;alent to a single in;ersion. A

    fold rotoin;ersion a%is is eui;alent to reflection through a mirror plane

    perpendicular to the rotoin;ersion a%is. A crystal !hich possesses a @fold

    rotoin;ersion a%is is eui;alent to one !hich possesses both @fold rotational

    symmetry and in;ersion symmetry. A 3fold rotoin;ersion is eui;alent to @

    fold rotation and reflection across a mirror plane !hich lies at right angles to

    the rotation a%is. 8he only rotoin;ersion operation !hich cannot be replaced by

    a combination of rotations, reflections and in;ersions is 4fold rotoin;ersion.

    8he reflection, rotation, in;ersion, and rotoin;ersion symmetry operations

    may be combined in a ;ariety of different !ays. 8here are thirtyt!o different

    possible combinations of these symmetry elements. Minerals possessing the

    different combinations are therefore categori0ed as members of @ possible

    crystal classes. According to this schema, each crystal class corresponds to a

    uniue set of symmetry operations. $ach crystal class is then placed into one of

    the si% different crystal systems so that se;eral different classes are members of

    each system.

    ,' Crystal Systems

    8op

    $;ery crystal class is a member of one of the si% crystal systems. 8hese

    systems include the isometric, he%agonal, tetragonal, orthorhombic,

    monoclinic, and triclinic crystal systems. 8he he%agonal crystal system is

    further bro#en do!n into he%agonal and rhombohedral di;isions.

    $;ery crystal class !hich belongs to a certain crystal system !ill share a

    characteristic symmetry element !ith the other members of its system. 6ore%ample, all crystals of the isometric system possess four @fold a%es of

    symmetry !hich proceed diagonally from corner to corner through the center

    of the cubic unit cell. 'n contrast, all crystals of the he%agonal di;ision of the

    he%agonal system possess a single si%fold a%is of rotation.

    'n addition to the characteristic symmetry element, a crystal class may

    possess other symmetry elements !hich are not necessarily present in all

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    members of the same system. 8he crystal class !hich possesses the highest

    possible symmetry or the highest number of symmetry elements !ithin each

    system is termed the holomorphic classof the system. 6or e%ample, crystals of

    the holomorphic class of the isometric system possess in;ersion symmetry,

    three 4fold a%es of rotational symmetry, the characteristic set of four @fold

    a%es of rotational symmetry !hich is indicati;e of the isometric crystal system,

    si% fold a%es of rotational symmetry, and nine different mirror planes. 'n

    contrast, a crystal !hich is not a member of the holomorphic class yet still

    belongs to the isometric system may possess only three fold a%es of rotational

    symmetry and the characteristic four @fold a%es of rotational symmetry.

    8he crystal system of a mineral species may sometimes be determined in

    the field by ;isually e%amining a particularly !ellformed crystal of the

    species.

    Isometric

    8he isometriccrystal system is also #no!n as the cubicsystem. 8he

    crystallographic a%es used in this system are of eual length and are

    mutually perpendicular, occurring at right angles to one another.

    All crystals of the isometric system possess four @fold a%es of

    symmetry, each of !hich proceeds diagonally from corner to corner

    through the center of the cubic unit cell. Crystals of the isometric system

    may also demonstrate up to three separate 4fold a%es of rotational

    symmetry. 8hese a%es, if present, proceed from the center of each face

    through the origin to the center of the opposite face and correspond to

    the crystallographic a%es. 6urthermore crystals of the isometric systemmay possess si% fold a%es of symmetry !hich e%tend from the center

    of each edge of the crystal through the origin to the center of the

    opposite edge. Minerals of this system may demonstrate up to nine

    different mirror planes.

    $%amples of minerals !hich crystalli0e in the isometric system are

    halite, magnetite, and garnet. Minerals of this system tend to produce

    crystals of euidimensional or euant habit. >Please refer to ection for

    more information on crystal habit.?

    "e#aonal

    Minerals of the he#aonalcrystal system are referred to threecrystallographic a%es !hich intersect at *)F and a fourth !hich is

    perpendicular to the other three. 8his fourth a%is is usually depicted

    ;ertically.

    8he he%agonal crystal system is di;ided into the he#aonaland

    rhombohedralor trionaldi;isions. All crystals of the he%agonal

    di;ision possess a single 3fold a%is of rotation. 'n addition to the single

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    3fold a%is of rotation, crystals of the he%agonal di;ision may possess up

    to si% fold a%es of rotation. 8hey may demonstrate a center of

    in;ersion symmetry and up to se;en mirror planes. Crystals of the

    trigonal di;ision all possess a single @fold a%is of rotation rather than

    the 3fold a%is of the he%agonal di;ision. Crystals of this di;ision may

    possess up to three fold a%es of rotation and may demonstrate a center

    of in;ersion and up to three mirror planes.

    Minerals species !hich crystalli0e in the he%agonal di;ision are

    apatite, beryl, and high uart0. Minerals of this di;ision tend to produce

    he%agonal prisms and pyramids. $%ample species !hich crystalli0e in

    the rhombohedral di;ision are calcite, dolomite, lo! uart0, and

    tourmaline. uch minerals tend to produce rhombohedra and triangular

    prisms.

    Tetraonal

    Minerals of the tetraonalcrystal system are referred to three

    mutually perpendicular a%es. 8he t!o hori0ontal a%es are of eual

    length, !hile the ;ertical a%is is of different length and may be either

    shorter or longer than the other t!o. Minerals of this system all possess a

    single 4fold symmetry a%is. 8hey may possess up to four fold a%es of

    rotation, a center of in;ersion, and up to fi;e mirror planes.

    Mineral species !hich crystalli0e in the tetragonal crystal system are

    0ircon and cassiterite. 8hese minerals tend to produce short crystals of

    prismatic habit.

    !rthorhombic

    Minerals of the orthorhombiccrystal system are referred to threemutually perpendicular a%es, each of !hich is of a different length than

    the others.

    Crystals of this system uniformly possess three fold rotation a%es

    and/or three mirror planes. 8he holomorphic class demonstrates three

    fold symmetry a%es and three mirror planes as !ell as a center of

    in;ersion. ther classes may demonstrate three fold a%es of rotation or

    one fold rotation a%is and t!o mirror planes.

    pecies !hich belong to the orthorhombic system are oli;ine and

    barite. Crystals of this system tend to be of prismatic, tabular, or acicular

    habit.Monoclinic

    Crystals of the monoclinicsystem are referred to three uneual a%es.

    8!o of these a%es are inclined to!ard each other at an obliue angleE

    these are usually depicted ;ertically. 8he third a%is is perpendicular to

    the other t!o. 8he t!o ;ertical a%es therefore do not intersect one

    another at right angles, although both are perpendicular to the hori0ontal

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    a%is.

    Monoclinic crystals demonstrate a single fold rotation a%is and/or a

    single mirror plane. 8he holomorphic class possesses the single fold

    rotation a%is, a mirror plane, and a center of symmetry. ther classes

    display "ust the fold rotation a%is or "ust the mirror plane.

    Mineral species !hich adhere to the monoclinic crystal system

    include pyro%ene, amphibole, orthoclase, a0urite, and malachite, among

    many others. 8he minerals of the monoclinic system tend to produce

    long prisms.

    Triclinic

    Crystals of the triclinicsystem are referred to three uneual a%es, all

    of !hich intersect at obliue angles. 1one of the a%es are perpendicular

    to any other a%is.

    Crystals of the triclinic system may be said to possess only a *fold

    symmetry a%is, !hich is eui;alent to possessing no symmetry at all.

    Crystals of this system possess no mirror planes. 8he holomorphic class

    demonstrates a center of in;ersion symmetry.

    Mineral species of the triclinic class include plagioclase and a%initeE

    these species tend to be of tabular habit.

    -' Crystal .orms

    8op

    A crystal formis a set of faces !hich are geometrically eui;alent and

    !hose spatial positions are related to one another according to the symmetry of

    the crystal. 'f one face of a crystal form is defined, the point symmetry

    operations !hich specify the class to !hich the crystal belongs also determine

    the other faces of the crystal form.

    6ifteen different forms are possible !ithin the isometric or cubic system.

    8hese include the he%octahedron, gyroid, he%tetrahedron, diploid, and tetartoid,

    among others. 8he crystal forms of the remaining fi;e crystal systems are the

    monohedron or pedion, parallelohedron or pinacoid, dihedron, or dome andsphenoid, disphenoid, prism, pyramid, dipyramid, trape0ohedron,

    scalenohedron, rhombohedron, and tetrahedron.

    8he crystal forms !hich occur in each crystal class and system must

    possess a symmetry complementary to that of the associated crystal class and

    system. 6or e%ample, a monohedron, !hich possesses only one face, !ill ne;er

    occur in a crystal !ith in;ersion symmetry because the in;ersion operation

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    reuires that an eui;alent face be present on the opposite side of the crystal.

    A simple crystal may consist of only a single crystal form. A more

    complicated crystal may be a combination of se;eral different forms. All forms

    !hich occur in a crystal of a particular system must be compatible !ith that

    crystal system.

    Monohedron

    8he monohedralcrystal form is also called a pedion. 't consists of a

    single face !hich is geometrically uniue for the crystal and is not

    repeated by any set of symmetry operations. Members of the triclinic

    crystal system produce monohedral crystal forms.

    $arallelohedron

    8he parallelohedralcrystal form is also called a pinacoid. 't consists of

    t!o and only t!o geometrically eui;alent faces !hich occupy opposite

    sides of a crystal. 8he t!o faces are parallel and are related to one

    another only by a reflection or an in;ersion. Members of the triclinic

    crystal system produce parallelohedral crystal forms.

    /ihedron

    8he dihedronconsists of t!o and only t!o nonparallel geometrically

    eui;alent faces. 8he t!o faces may be related by a reflection or by a

    rotation. 8he dihedron is termed a domeif the t!o faces are related only

    by reflection across a mirror plane. 'f the t!o faces are related instead by

    a fold rotation a%is then the dihedron is termed a sphenoid. Members

    of the monoclinic crystal system produce dihedral crystal forms.

    /isphenoidMembers of the orthorhombic and tetragonal crystal systems produce

    rhombic and tetragonal disphenoids, !hich possess t!o sets of

    nonparallel geometrically eui;alent faces, each of !hich is related by a

    fold rotation. 8he faces of the upper sphenoid alternate !ith the faces

    of the lo!er sphenoid in such forms.

    $rism

    A prismis composed of a set of @, 4, 3, -, or * geometrically

    eui;alent faces !hich are all parallel to the same a%is. $ach of these

    faces intersects !ith the t!o faces ad"acent to it to produce a set of

    parallel edges. 8he mutually parallel edges of all intersections of theprism sides then form a tube. Prisms are gi;en names based on the shape

    of their cross section. ariants of the prism form include the rhombic

    prism, tetragonal prism, trigonal prism, and he%agonal prism. A prism in

    !hich the large faces are di;ided into t!o mirrorimage faces !hich

    intersect !ith one another at an obliue angle is called a ditetragonal

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    prism, a ditrigonal prism, or a dihe%agonal prism. Prisms are associated

    !ith the members of the monoclinic crystal system.

    $yramid

    A pyramidis composed of a set of @, 4, 3, -, or * faces !hich are not

    parallel but instead intersect at a point. 8he orthorhombic, tetragonal and

    he%agonal crystal systems all produce pyramids. 8hese pyramids are

    named according to the shape of their crosssection in the same !ay that

    prisms are. 8hus are produced the rhombic pyramid, tetragonal pyramid,

    trigonal pyramid, and he%agonal pyramid. $ach large face of the

    ditetragonal pyramid, ditrigonal pyramid, and dihe%agonal pyramids is

    di;ided into t!o mirrorimage faces !hich occupy an obliue angle !ith

    respect to one another.

    /ipyramid

    8he dipyramidalcrystal form is composed of t!o pyramids placed

    basetobase and related by reflection across a mirror plane !hich runs

    parallel to and ad"acent to the pyramid bases. 8he upper and lo!er

    pyramids may each ha;e @, 4, 3, -, or * facesE the dipyramidal form

    therefore possesses a total of 3, -, *, *3, or 4 faces. 8he orthorhombic,

    tetragonal and he%agonal crystal systems all produce dipyramids. 8hese

    dipyramids are named for the shape of their crosssection "ust as prisms

    and pyramids are, resulting in the rhombic dipyramid, trigonal

    dipyramid, tetragonal dipyramid, and he%agonal dipyramid. 8he large

    faces of the ditetragonal, ditrigonal and dihe%agonal dipyramids are

    di;ided into t!o mirrorimage faces !hich intersect one another at an

    obliue angle.Trape0ohedron

    A trape0ohedronis a crystal form possessing 3, -, or * trape0oidal

    faces. 8he tetragonal crystal system and both the trigonal and he%agonal

    di;isions of the he%agonal crystal system produce trape0ohedral crystal

    forms. 8rigonal trape0ohedra possess three trape0oidal faces on the top

    and three on the bottom for a total of si% facesE tetragonal trape0ohedra

    ha;e four faces on top and four on the bottom for a total of eight facesE

    and he%agonal trape0ohedra ha;e si% faces on top and si% on the bottom,

    resulting in t!el;e faces total.

    ScalenohedronA scalenohedronconsists of - or * faces, each of !hich is a scalene

    triangle. 8he faces appear to be grouped into symmetric pairs. 8he

    tetragonal and he%agonal crystal systems produce the scalenohedral

    crystal form, of !hich e%amples may be further described as trigonal,

    tetragonal and he%agonal scalenohedra.

    hombohedron

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    8he rhombohedralcrystal form possesses si% rhombusshaped faces. A

    rhombohedron resembles in appearance a cube !hich is poised upright

    upon one corner and has been either flattened or elongated along an a%is

    !hich runs diagonally from corner to corner through the center. 8he

    rhombohedral crystal form is produced only by members of the trigonal

    and rhombohedral di;isions of the he%agonal crystal system.

    Tetrahedron

    A tetrahedronis composed of four triangular faces. 'n crystals of the

    isometric system each face is an identical euilateral triangle. 'n crystals

    of the tetragonal system each face is an identical isoceles triangleE this

    ;ariant of the tetrahedron is called a tetragonal tetrahedron. 'n crystals of

    the orthorhombic system the faces consist of t!o pairs of different

    isoceles trianglesE the crystal is then termed a rhombic tetrahedron.

    1' Crystal Classes

    8he reflection, rotation, in;ersion, and rotoin;ersion symmetry operations

    may be combined in thirtyt!o different !ays. 8hirtyt!o different crystal

    classesare therefore defined so that each crystal class corresponds to a uniue

    set of symmetry operations. $ach of the crystal classes is named according to

    the ;ariant of a crystal form!hich it displays. 6or e%ample, the isometric

    he%octahedral class belongs to the isometric crystal system and demonstrates

    the he%octahedral crystal form. 8he rhombic pyramidal, tetragonal pyramidal,trigonal pyramidal and he%agonal pyramidal classes each display a ;ariant of

    the crystal form !hich is called a pyramid.

    $ach crystal class is a member of one of the si% different crystal systems

    according to !hich characteristic symmetry operation it possesses. 6or

    e%ample, all crystals of the isometric system possess four @fold a%es of

    symmetry, !hile minerals of the tetragonal system possess a single 4fold

    symmetry a%is and crystals of the triclinic class sho! no symmetry at all. 8he

    rhombic pyramidal crystal class is thus a member of the orthorhombic crystal

    system, the tetragonal pyramidal class is a member of the tetragonal crystal

    system, and the trigonal and he%agonal pyramidal classes are members of the

    rhombohedral >trigonal? and he%agonal di;isions of the he%agonal crystal

    system respecti;ely.

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    Table of the 32 Crystal Classes

    8he follo!ing table lists in bold type the si% crystal systems. 'ncluded are

    the isometric, he%agonal, tetragonal, orthorhombic, monoclinic, and triclinic

    systems. 8he tetragonal crystal system is further separated into the he%agonal

    and trigonal or rhombohedral di;isions. nder each crystal system the tablelists by name the crystal classes !hich occur !ithin that system. 6or e%ample,

    the crystal classes !hich occur !ithin the trigonal crystal system are the

    trigonal monohedral and trigonal parallelohedral crystal classes. Ad"acent to the

    listing of each crystal class is the symmetry of the class.

    =hen listing the symmetry of each crystal class an a%is of rotational

    symmetry is represented by the capital letter A. =hether this a%is is a fold, @

    fold, or 4fold a%is is indicated by a subscript follo!ing the letter A. 8he

    number of such a%es present is indicated by a numeral preceding the capital A.

    *A, A@, and @A4thus represent one fold a%is of rotation, t!o @fold a%es, and

    three 4fold a%es respecti;ely. A center of in;ersion is noted by the lo!ercase

    letter 9i9 !hile a mirror plane is denoted by 9m9. 8he numeral preceding the m

    indicates ho! many mirror planes are present. A%es of rotary in;ersion are

    usually replaced by the eui;alent rotations and reflections. 6or e%ample, a

    fold rotoin;ersion a%is is eui;alent to reflection through a mirror plane

    perpendicular to the rotoin;ersion a%is. A crystal !hich possesses a @fold

    rotoin;ersion a%is is eui;alent to one !hich possesses both @fold rotational

    symmetry and in;ersion symmetry. A 3fold rotoin;ersion is eui;alent to @

    fold rotation and reflection across a mirror plane at right angles to the rotation

    a%is. 8he only rotoin;ersion operation !hich cannot be thus replaced is 4foldrotoin;ersion, !hich is indicated by 54.

    8he class !hich possesses the highest possible symmetry !ithin each

    crystal system is termed the holomorphic class of that system. 8he holomorphic

    class of each crystal system is indicated in the table by bold type. 6or e%ample,

    the triclinic parallelohedron is the holomorphic class of the triclinic crystal

    system !hile the isometric he%octahedron is the holomorphic class of the

    isomorphic or cubic crystal system. 8he characteristic symmetry element of

    each crystal system is listed in bold type. 't is thus apparent that the

    characteristic symmetry element of the isometric crystal system is the

    possession of four @fold a%es of rotational symmetry, !hile the characteristicsymmetry element of the rhombohedral di;ision of the he%agonal crystal

    system is the possession of a single @fold a%is of rotational symmetry.

    Crystal System Crystal Class 2 Symmetry of

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    Crystal .orm Class

    Isometric System

    he#octahedron

    gyroid

    he%tetrahedron

    diploidtetartoid

    i, @A4, -A,, 3A,

    (m

    @A4, -A,, 3A@A, -A,, 3m

    i, @A, -A,, @m@A, -A,

    "e#aonal SystemHe%agonal

    Di;ision

    dihe#aonal

    dipyramid

    he%agonal

    trape0ohedron

    dihe%agonal pyramid

    ditrigonal dipyramid

    he%agonal dipyramid

    he%agonal pyramidtrigonal dipyramid

    i, &A3, 3A, m

    &A3, 3A

    &A3, 3m

    &3, @A, @m

    i, &A3, *m

    &A3

    &3

    5hombohedral

    Di;ision

    he#aonal

    scalenohedron

    trigonal trape0ohedron

    ditrigonal pyramid

    rhombohedron

    trigonal pyramid

    i, &A,, @A, @m

    &A,, @A

    &A,, @m

    i, &A,

    &A,

    Tetraonal

    System

    ditetraonal

    dipyramidtetragonal

    trap0ohedron

    ditetragonal pyramid

    tetragonal

    scalenohedron

    tetragonal dipyramid

    tetragonal pyramid

    tetragonal disphenoid

    i, &A-, 4A, m

    &A-, 4A

    &A-, 4m

    &-, A, m

    i, &A-, *m

    &A-

    &-

    !rthorhombicSystem

    rhombic dipyramid

    rhombic disphenoid

    rhombic pyramid

    i, @A, @m@A

    *A, m

    Monoclinic

    System

    prism

    sphenoid

    dome

    i, *A, *m

    *A*m

    Triclinic System parallellohedron i

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