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8/13/2019 Crystal Form
1/16
Types of Crystals
Shapes and Structures
By Anne Marie Helmenstine, Ph.D., About.com Guide
See More About:
crystallography
crystal lattices
physical properties
chemical properties
crystals
Copper sulfate has a triclinic crystal structure.
Stephanb, wikipedia.org
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Crystal Form
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Crystal Grouped by Lattices (Shape)
8here are se;en crystal lattice systems. only one lattice point per unit cell? or nonprimiti;e >more than one lattice
point per unit cell?. Combining the crystal systems !ith the lattice types yields the *4Bra;ais attices >named after Auguste Bra;ais, !ho !or#ed out lattice structures in
*-)?. 8he structure of real crystals is pretty complicated: 1aCl?is an e%ample of this type of crystal.
http://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Simple-Cubic-Lattice.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Simple-Tetragonal-Lattice.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Simple-Orthorhombic.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Hexagonal-Crystal-Lattice.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Rhombohedral-Crystal-Lattice.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Triclinic-Crystal-Lattice.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Simple-Monoclinic-Lattice.htmhttp://dave.ucsc.edu/myrtreia/crystal.htmlhttp://www.rockhounds.com/rockshop/xtal/part2.htmlhttp://chemistry.about.com/library/glossary/bldef528.htmhttp://chemistry.about.com/library/glossary/bldef528.htmhttp://chemistry.about.com/library/glossary/bldef540.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Simple-Cubic-Lattice.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Simple-Tetragonal-Lattice.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Simple-Orthorhombic.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Hexagonal-Crystal-Lattice.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Rhombohedral-Crystal-Lattice.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Triclinic-Crystal-Lattice.htmhttp://chemistry.about.com/od/crystallography/ig/Bravais-Crystal-Lattices/Simple-Monoclinic-Lattice.htmhttp://dave.ucsc.edu/myrtreia/crystal.htmlhttp://www.rockhounds.com/rockshop/xtal/part2.htmlhttp://chemistry.about.com/library/glossary/bldef528.htmhttp://chemistry.about.com/library/glossary/bldef540.htm8/13/2019 Crystal Form
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8/13/2019 Crystal Form
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A specified motif !hich is translated linearly and repeated many times !ill
produce a lattice. A lattice is an array of points !hich define a repeated spatial
entity called a unit cell. 8he unit cell of a lattice is the smallest unit !hich can
be repeated in three dimensions in order to construct the lattice. 8he corners of
the unit cell ser;e as points !hich are repeated to form the lattice arrayE these
points are termed lattice points.
8he number of possible lattices is limited. 'n the plane only fi;e different
lattices may be produced by translation. 8he 6rench crystallographer Auguste
Bra;ais >*-***-3@? established that in threedimensional space only fourteen
different lattices may be constructed. 8hese fourteen different lattice structures
are thus termed the ra%ais lattices.
8he reflection, rotation, in;ersion, and rotoin;ersion symmetry operations
may be combined in a ;ariety of different !ays. 8here are thirtyt!o possible
uniue combinations of symmetry operations. Minerals possessing the different
combinations are therefore categori0ed as members of thirtyt!o crystal
classesE each crystal class corresponds to a uniue set of symmetry operations.
$ach of the crystal classes is named according to the ;ariant of a crystal form
!hich it displays. $ach crystal class is grouped as one of the si% different
crystal systemsaccording to !hich characteristic symmetry operation it
possesses.
A crystal formis a set of planar faces !hich are geometrically eui;alent
and !hose spatial positions are related to one another by a specified set of
symmetry operations. 'f one face of a crystal form is defined, the specified set
of point symmetry operations !ill determine all of the other faces of the crystalform.
A simple crystal may consist of only a single crystal form. A more
complicated crystal may be a combination of se;eral different forms. 8he
crystal forms of the fi;e nonisometric crystal systems are the monohedron or
pedion, parallelohedron or pinacoid, dihedron, or dome and sphenoid,
disphenoid, prism, pyramid, dipyramid, trape0ohedron, scalenohedron,
rhombohedron and tetrahedron. 6ifteen different forms are possible !ithin the
isometric system.
$ach crystal class is a member of one of si% crystal systems. 8hese systems
include the isometric, he%agonal, tetragonal, orthorhombic, monoclinic, andtriclinic systems. 8he he%agonal crystal system is further bro#en do!n into the
he%agonal and rhombohedral di;isions. $;ery crystal of a certain crystal
system !ill share a characteristic symmetry element !ith the other members of
its system. 8he crystal system of a mineral species may sometimes be
determined ;isually by e%amining a particularly !ellformed crystal of the
species.
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*' Symmetry and Lattices
8op
Symmetry
Crystals possess a regular, repetiti;e internal structure. 8he concept of
symmetrydescribes the repetition of structural features. Crystals therefore
possess symmetry, and much of the discipline of crystallography is concerned
!ith describing and cataloging different types of symmetry.
8!o general types of symmetry e%ist. 8hese consist of translational
symmetryand point symmetry. 8ranslational symmetry describes the periodic
repetition of a structural feature across a length or through an area or ;olume.
Point symmetry, on the other hand, describes the periodic repetition of astructural feature around a point. 5eflection, rotation, and in;ersion are all
point symmetries.
Lattices
8he concept of a latticeis directly related to the idea of translational
symmetry. A lattice is a net!or# or array composed of single motif !hich has
been translated and repeated at fi%ed inter;als throughout space. 6or e%ample, a
suare !hich is translated and repeated many times across the plane !ill
produce a planar suare lattice.8he unit cellof a lattice is the smallest unit !hich can be repeated in three
dimensions in order to construct the lattice. 'n a crystal, the unit cell consists of
a specific group of atoms !hich are bonded to one another in a set geometrical
arrangement. 8his unit and its constituent atoms are then repeated o;er and
o;er in order to construct the crystal lattice. 8he surroundings in any gi;en
direction of one corner of a unit cell must be identical to the surroundings in the
same direction of all the other corners. 8he corners of the unit cell therefore
ser;e as points !hich are repeated to form a lattice arrayE these points are
termed lattice points. 8he ;ectors !hich connect a straight line of eui;alent
lattice points and delineate the edges of the unit cell are #no!n as thecrystalloraphic a#es.
8he number of possible lattices is limited. 'n the plane only fi;e different
lattices may be produced by translation. ne of these lattices possesses a suare
unit cell !hile another possesses a rectangular unit cell. 8he third possible
planar lattice possesses a centered rectangular unit cell, !hich contains a lattice
point in the center as !ell as lattice points on the corners. 8he unit cell of the
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fourth possible planar lattice is a parallelogram, and that of the final planar
lattice is a he%agonal unit cell !hich may alternately be considered a rhombus.
Bravais Lattices
8op
8he 6rench crystallographer Auguste Bra;ais >*-***-3@? established that
in threedimensional space only fourteen different lattices may be constructed.
8he fourteen ra%ais latticesmay be di;ided among si% crystal systems. 8hese
are the isometric or cubic, tetragonal, orthorhombic, monoclinic, triclinic, and
he%agonal systems. >8he si% crystal systemsare discussed belo!.? 8he Bra;ais
lattices are furthermore of three different types. A primiti%e latticehas only a
lattice point at each corner of the threedimensional unit cell. A body+centered
latticecontains not only lattice points at each corner of the unit cell but also
contains a lattice point at the center of the threedimensional unit cell. A face+
centered latticepossesses not only lattice points at the corners of the unit cell
but also at either the centers of "ust one pair of faces or else at the centers of all
three pairs of faces. 8he fourteen Bra;ais lattices are therefore the primiti;e
cubic, bodycentered cubic, facecentered cubic, primiti;e tetragonal, body
centered tetragonal, primiti;e orthorhombic, bodycentered orthorhombic,
single facecentered orthorhombic, multiple facecentered orthorhombic,
primiti;e monoclinic, single facecentered monoclinic, primiti;e triclinic,
single facecentered he%agonal, and rhombohedral lattices. >8he rhombohedral
lattice is a subset of the he%agonal crystal system.?
Point Symmetry Operations
$oint symmetrydescribes the repetition of a motif or structural feature
around a single reference point, commonly the center of a unit cell or a crystal.
8he different pointsymmetry operations are reflection, rotation, in;ersion, and
the combined operation rotoin;ersion.
A reflectionoccurs !hen the structure features on one side of a plane
passing through the center of a crystal are the mirror image of the structural
features on the other side. 8he plane across !hich the reflection occurs is then
termed a mirror plane.
otational symmetryarises !hen a structural element is rotated a fi%ed
number of degrees about a central point and then repeated. A suare, for
e%ample, possesses 4fold rotational symmetry because it may be rotated four
times by ()F about its central point before it is returned to its original position.
$ach time it is rotated by ()F the resultant suare !ill be identical in
appearance to the original suare.
'f a crystal possesses in%ersion symmetry, then any line !hich is dra!n
http://dave.ucsc.edu/myrtreia/crystal.htmlhttp://dave.ucsc.edu/myrtreia/crystal.html#SYSTEMShttp://dave.ucsc.edu/myrtreia/crystal.htmlhttp://dave.ucsc.edu/myrtreia/crystal.html#SYSTEMS8/13/2019 Crystal Form
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through the origin at the center of the crystal !ill connect t!o identical features
on opposite sides of the crystal.
otoin%ersionis a compound symmetry operation !hich is produced by
performing a rotation follo!ed by an in;ersion. *fold, fold, @fold, 4fold,
and 3fold rotoin;ersion operations e%ist. Most of these rotoin;ersions may
alternately be described by a specified set of rotation, reflection and in;ersion
operations. A *fold rotoin;ersion is eui;alent to rotation by @3)F follo!ed by
in;ersion. 8his procedure is ultimately eui;alent to a single in;ersion. A
fold rotoin;ersion a%is is eui;alent to reflection through a mirror plane
perpendicular to the rotoin;ersion a%is. A crystal !hich possesses a @fold
rotoin;ersion a%is is eui;alent to one !hich possesses both @fold rotational
symmetry and in;ersion symmetry. A 3fold rotoin;ersion is eui;alent to @
fold rotation and reflection across a mirror plane !hich lies at right angles to
the rotation a%is. 8he only rotoin;ersion operation !hich cannot be replaced by
a combination of rotations, reflections and in;ersions is 4fold rotoin;ersion.
8he reflection, rotation, in;ersion, and rotoin;ersion symmetry operations
may be combined in a ;ariety of different !ays. 8here are thirtyt!o different
possible combinations of these symmetry elements. Minerals possessing the
different combinations are therefore categori0ed as members of @ possible
crystal classes. According to this schema, each crystal class corresponds to a
uniue set of symmetry operations. $ach crystal class is then placed into one of
the si% different crystal systems so that se;eral different classes are members of
each system.
,' Crystal Systems
8op
$;ery crystal class is a member of one of the si% crystal systems. 8hese
systems include the isometric, he%agonal, tetragonal, orthorhombic,
monoclinic, and triclinic crystal systems. 8he he%agonal crystal system is
further bro#en do!n into he%agonal and rhombohedral di;isions.
$;ery crystal class !hich belongs to a certain crystal system !ill share a
characteristic symmetry element !ith the other members of its system. 6ore%ample, all crystals of the isometric system possess four @fold a%es of
symmetry !hich proceed diagonally from corner to corner through the center
of the cubic unit cell. 'n contrast, all crystals of the he%agonal di;ision of the
he%agonal system possess a single si%fold a%is of rotation.
'n addition to the characteristic symmetry element, a crystal class may
possess other symmetry elements !hich are not necessarily present in all
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members of the same system. 8he crystal class !hich possesses the highest
possible symmetry or the highest number of symmetry elements !ithin each
system is termed the holomorphic classof the system. 6or e%ample, crystals of
the holomorphic class of the isometric system possess in;ersion symmetry,
three 4fold a%es of rotational symmetry, the characteristic set of four @fold
a%es of rotational symmetry !hich is indicati;e of the isometric crystal system,
si% fold a%es of rotational symmetry, and nine different mirror planes. 'n
contrast, a crystal !hich is not a member of the holomorphic class yet still
belongs to the isometric system may possess only three fold a%es of rotational
symmetry and the characteristic four @fold a%es of rotational symmetry.
8he crystal system of a mineral species may sometimes be determined in
the field by ;isually e%amining a particularly !ellformed crystal of the
species.
Isometric
8he isometriccrystal system is also #no!n as the cubicsystem. 8he
crystallographic a%es used in this system are of eual length and are
mutually perpendicular, occurring at right angles to one another.
All crystals of the isometric system possess four @fold a%es of
symmetry, each of !hich proceeds diagonally from corner to corner
through the center of the cubic unit cell. Crystals of the isometric system
may also demonstrate up to three separate 4fold a%es of rotational
symmetry. 8hese a%es, if present, proceed from the center of each face
through the origin to the center of the opposite face and correspond to
the crystallographic a%es. 6urthermore crystals of the isometric systemmay possess si% fold a%es of symmetry !hich e%tend from the center
of each edge of the crystal through the origin to the center of the
opposite edge. Minerals of this system may demonstrate up to nine
different mirror planes.
$%amples of minerals !hich crystalli0e in the isometric system are
halite, magnetite, and garnet. Minerals of this system tend to produce
crystals of euidimensional or euant habit. >Please refer to ection for
more information on crystal habit.?
"e#aonal
Minerals of the he#aonalcrystal system are referred to threecrystallographic a%es !hich intersect at *)F and a fourth !hich is
perpendicular to the other three. 8his fourth a%is is usually depicted
;ertically.
8he he%agonal crystal system is di;ided into the he#aonaland
rhombohedralor trionaldi;isions. All crystals of the he%agonal
di;ision possess a single 3fold a%is of rotation. 'n addition to the single
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3fold a%is of rotation, crystals of the he%agonal di;ision may possess up
to si% fold a%es of rotation. 8hey may demonstrate a center of
in;ersion symmetry and up to se;en mirror planes. Crystals of the
trigonal di;ision all possess a single @fold a%is of rotation rather than
the 3fold a%is of the he%agonal di;ision. Crystals of this di;ision may
possess up to three fold a%es of rotation and may demonstrate a center
of in;ersion and up to three mirror planes.
Minerals species !hich crystalli0e in the he%agonal di;ision are
apatite, beryl, and high uart0. Minerals of this di;ision tend to produce
he%agonal prisms and pyramids. $%ample species !hich crystalli0e in
the rhombohedral di;ision are calcite, dolomite, lo! uart0, and
tourmaline. uch minerals tend to produce rhombohedra and triangular
prisms.
Tetraonal
Minerals of the tetraonalcrystal system are referred to three
mutually perpendicular a%es. 8he t!o hori0ontal a%es are of eual
length, !hile the ;ertical a%is is of different length and may be either
shorter or longer than the other t!o. Minerals of this system all possess a
single 4fold symmetry a%is. 8hey may possess up to four fold a%es of
rotation, a center of in;ersion, and up to fi;e mirror planes.
Mineral species !hich crystalli0e in the tetragonal crystal system are
0ircon and cassiterite. 8hese minerals tend to produce short crystals of
prismatic habit.
!rthorhombic
Minerals of the orthorhombiccrystal system are referred to threemutually perpendicular a%es, each of !hich is of a different length than
the others.
Crystals of this system uniformly possess three fold rotation a%es
and/or three mirror planes. 8he holomorphic class demonstrates three
fold symmetry a%es and three mirror planes as !ell as a center of
in;ersion. ther classes may demonstrate three fold a%es of rotation or
one fold rotation a%is and t!o mirror planes.
pecies !hich belong to the orthorhombic system are oli;ine and
barite. Crystals of this system tend to be of prismatic, tabular, or acicular
habit.Monoclinic
Crystals of the monoclinicsystem are referred to three uneual a%es.
8!o of these a%es are inclined to!ard each other at an obliue angleE
these are usually depicted ;ertically. 8he third a%is is perpendicular to
the other t!o. 8he t!o ;ertical a%es therefore do not intersect one
another at right angles, although both are perpendicular to the hori0ontal
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a%is.
Monoclinic crystals demonstrate a single fold rotation a%is and/or a
single mirror plane. 8he holomorphic class possesses the single fold
rotation a%is, a mirror plane, and a center of symmetry. ther classes
display "ust the fold rotation a%is or "ust the mirror plane.
Mineral species !hich adhere to the monoclinic crystal system
include pyro%ene, amphibole, orthoclase, a0urite, and malachite, among
many others. 8he minerals of the monoclinic system tend to produce
long prisms.
Triclinic
Crystals of the triclinicsystem are referred to three uneual a%es, all
of !hich intersect at obliue angles. 1one of the a%es are perpendicular
to any other a%is.
Crystals of the triclinic system may be said to possess only a *fold
symmetry a%is, !hich is eui;alent to possessing no symmetry at all.
Crystals of this system possess no mirror planes. 8he holomorphic class
demonstrates a center of in;ersion symmetry.
Mineral species of the triclinic class include plagioclase and a%initeE
these species tend to be of tabular habit.
-' Crystal .orms
8op
A crystal formis a set of faces !hich are geometrically eui;alent and
!hose spatial positions are related to one another according to the symmetry of
the crystal. 'f one face of a crystal form is defined, the point symmetry
operations !hich specify the class to !hich the crystal belongs also determine
the other faces of the crystal form.
6ifteen different forms are possible !ithin the isometric or cubic system.
8hese include the he%octahedron, gyroid, he%tetrahedron, diploid, and tetartoid,
among others. 8he crystal forms of the remaining fi;e crystal systems are the
monohedron or pedion, parallelohedron or pinacoid, dihedron, or dome andsphenoid, disphenoid, prism, pyramid, dipyramid, trape0ohedron,
scalenohedron, rhombohedron, and tetrahedron.
8he crystal forms !hich occur in each crystal class and system must
possess a symmetry complementary to that of the associated crystal class and
system. 6or e%ample, a monohedron, !hich possesses only one face, !ill ne;er
occur in a crystal !ith in;ersion symmetry because the in;ersion operation
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reuires that an eui;alent face be present on the opposite side of the crystal.
A simple crystal may consist of only a single crystal form. A more
complicated crystal may be a combination of se;eral different forms. All forms
!hich occur in a crystal of a particular system must be compatible !ith that
crystal system.
Monohedron
8he monohedralcrystal form is also called a pedion. 't consists of a
single face !hich is geometrically uniue for the crystal and is not
repeated by any set of symmetry operations. Members of the triclinic
crystal system produce monohedral crystal forms.
$arallelohedron
8he parallelohedralcrystal form is also called a pinacoid. 't consists of
t!o and only t!o geometrically eui;alent faces !hich occupy opposite
sides of a crystal. 8he t!o faces are parallel and are related to one
another only by a reflection or an in;ersion. Members of the triclinic
crystal system produce parallelohedral crystal forms.
/ihedron
8he dihedronconsists of t!o and only t!o nonparallel geometrically
eui;alent faces. 8he t!o faces may be related by a reflection or by a
rotation. 8he dihedron is termed a domeif the t!o faces are related only
by reflection across a mirror plane. 'f the t!o faces are related instead by
a fold rotation a%is then the dihedron is termed a sphenoid. Members
of the monoclinic crystal system produce dihedral crystal forms.
/isphenoidMembers of the orthorhombic and tetragonal crystal systems produce
rhombic and tetragonal disphenoids, !hich possess t!o sets of
nonparallel geometrically eui;alent faces, each of !hich is related by a
fold rotation. 8he faces of the upper sphenoid alternate !ith the faces
of the lo!er sphenoid in such forms.
$rism
A prismis composed of a set of @, 4, 3, -, or * geometrically
eui;alent faces !hich are all parallel to the same a%is. $ach of these
faces intersects !ith the t!o faces ad"acent to it to produce a set of
parallel edges. 8he mutually parallel edges of all intersections of theprism sides then form a tube. Prisms are gi;en names based on the shape
of their cross section. ariants of the prism form include the rhombic
prism, tetragonal prism, trigonal prism, and he%agonal prism. A prism in
!hich the large faces are di;ided into t!o mirrorimage faces !hich
intersect !ith one another at an obliue angle is called a ditetragonal
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prism, a ditrigonal prism, or a dihe%agonal prism. Prisms are associated
!ith the members of the monoclinic crystal system.
$yramid
A pyramidis composed of a set of @, 4, 3, -, or * faces !hich are not
parallel but instead intersect at a point. 8he orthorhombic, tetragonal and
he%agonal crystal systems all produce pyramids. 8hese pyramids are
named according to the shape of their crosssection in the same !ay that
prisms are. 8hus are produced the rhombic pyramid, tetragonal pyramid,
trigonal pyramid, and he%agonal pyramid. $ach large face of the
ditetragonal pyramid, ditrigonal pyramid, and dihe%agonal pyramids is
di;ided into t!o mirrorimage faces !hich occupy an obliue angle !ith
respect to one another.
/ipyramid
8he dipyramidalcrystal form is composed of t!o pyramids placed
basetobase and related by reflection across a mirror plane !hich runs
parallel to and ad"acent to the pyramid bases. 8he upper and lo!er
pyramids may each ha;e @, 4, 3, -, or * facesE the dipyramidal form
therefore possesses a total of 3, -, *, *3, or 4 faces. 8he orthorhombic,
tetragonal and he%agonal crystal systems all produce dipyramids. 8hese
dipyramids are named for the shape of their crosssection "ust as prisms
and pyramids are, resulting in the rhombic dipyramid, trigonal
dipyramid, tetragonal dipyramid, and he%agonal dipyramid. 8he large
faces of the ditetragonal, ditrigonal and dihe%agonal dipyramids are
di;ided into t!o mirrorimage faces !hich intersect one another at an
obliue angle.Trape0ohedron
A trape0ohedronis a crystal form possessing 3, -, or * trape0oidal
faces. 8he tetragonal crystal system and both the trigonal and he%agonal
di;isions of the he%agonal crystal system produce trape0ohedral crystal
forms. 8rigonal trape0ohedra possess three trape0oidal faces on the top
and three on the bottom for a total of si% facesE tetragonal trape0ohedra
ha;e four faces on top and four on the bottom for a total of eight facesE
and he%agonal trape0ohedra ha;e si% faces on top and si% on the bottom,
resulting in t!el;e faces total.
ScalenohedronA scalenohedronconsists of - or * faces, each of !hich is a scalene
triangle. 8he faces appear to be grouped into symmetric pairs. 8he
tetragonal and he%agonal crystal systems produce the scalenohedral
crystal form, of !hich e%amples may be further described as trigonal,
tetragonal and he%agonal scalenohedra.
hombohedron
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8he rhombohedralcrystal form possesses si% rhombusshaped faces. A
rhombohedron resembles in appearance a cube !hich is poised upright
upon one corner and has been either flattened or elongated along an a%is
!hich runs diagonally from corner to corner through the center. 8he
rhombohedral crystal form is produced only by members of the trigonal
and rhombohedral di;isions of the he%agonal crystal system.
Tetrahedron
A tetrahedronis composed of four triangular faces. 'n crystals of the
isometric system each face is an identical euilateral triangle. 'n crystals
of the tetragonal system each face is an identical isoceles triangleE this
;ariant of the tetrahedron is called a tetragonal tetrahedron. 'n crystals of
the orthorhombic system the faces consist of t!o pairs of different
isoceles trianglesE the crystal is then termed a rhombic tetrahedron.
1' Crystal Classes
8he reflection, rotation, in;ersion, and rotoin;ersion symmetry operations
may be combined in thirtyt!o different !ays. 8hirtyt!o different crystal
classesare therefore defined so that each crystal class corresponds to a uniue
set of symmetry operations. $ach of the crystal classes is named according to
the ;ariant of a crystal form!hich it displays. 6or e%ample, the isometric
he%octahedral class belongs to the isometric crystal system and demonstrates
the he%octahedral crystal form. 8he rhombic pyramidal, tetragonal pyramidal,trigonal pyramidal and he%agonal pyramidal classes each display a ;ariant of
the crystal form !hich is called a pyramid.
$ach crystal class is a member of one of the si% different crystal systems
according to !hich characteristic symmetry operation it possesses. 6or
e%ample, all crystals of the isometric system possess four @fold a%es of
symmetry, !hile minerals of the tetragonal system possess a single 4fold
symmetry a%is and crystals of the triclinic class sho! no symmetry at all. 8he
rhombic pyramidal crystal class is thus a member of the orthorhombic crystal
system, the tetragonal pyramidal class is a member of the tetragonal crystal
system, and the trigonal and he%agonal pyramidal classes are members of the
rhombohedral >trigonal? and he%agonal di;isions of the he%agonal crystal
system respecti;ely.
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Table of the 32 Crystal Classes
8he follo!ing table lists in bold type the si% crystal systems. 'ncluded are
the isometric, he%agonal, tetragonal, orthorhombic, monoclinic, and triclinic
systems. 8he tetragonal crystal system is further separated into the he%agonal
and trigonal or rhombohedral di;isions. nder each crystal system the tablelists by name the crystal classes !hich occur !ithin that system. 6or e%ample,
the crystal classes !hich occur !ithin the trigonal crystal system are the
trigonal monohedral and trigonal parallelohedral crystal classes. Ad"acent to the
listing of each crystal class is the symmetry of the class.
=hen listing the symmetry of each crystal class an a%is of rotational
symmetry is represented by the capital letter A. =hether this a%is is a fold, @
fold, or 4fold a%is is indicated by a subscript follo!ing the letter A. 8he
number of such a%es present is indicated by a numeral preceding the capital A.
*A, A@, and @A4thus represent one fold a%is of rotation, t!o @fold a%es, and
three 4fold a%es respecti;ely. A center of in;ersion is noted by the lo!ercase
letter 9i9 !hile a mirror plane is denoted by 9m9. 8he numeral preceding the m
indicates ho! many mirror planes are present. A%es of rotary in;ersion are
usually replaced by the eui;alent rotations and reflections. 6or e%ample, a
fold rotoin;ersion a%is is eui;alent to reflection through a mirror plane
perpendicular to the rotoin;ersion a%is. A crystal !hich possesses a @fold
rotoin;ersion a%is is eui;alent to one !hich possesses both @fold rotational
symmetry and in;ersion symmetry. A 3fold rotoin;ersion is eui;alent to @
fold rotation and reflection across a mirror plane at right angles to the rotation
a%is. 8he only rotoin;ersion operation !hich cannot be thus replaced is 4foldrotoin;ersion, !hich is indicated by 54.
8he class !hich possesses the highest possible symmetry !ithin each
crystal system is termed the holomorphic class of that system. 8he holomorphic
class of each crystal system is indicated in the table by bold type. 6or e%ample,
the triclinic parallelohedron is the holomorphic class of the triclinic crystal
system !hile the isometric he%octahedron is the holomorphic class of the
isomorphic or cubic crystal system. 8he characteristic symmetry element of
each crystal system is listed in bold type. 't is thus apparent that the
characteristic symmetry element of the isometric crystal system is the
possession of four @fold a%es of rotational symmetry, !hile the characteristicsymmetry element of the rhombohedral di;ision of the he%agonal crystal
system is the possession of a single @fold a%is of rotational symmetry.
Crystal System Crystal Class 2 Symmetry of
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Crystal .orm Class
Isometric System
he#octahedron
gyroid
he%tetrahedron
diploidtetartoid
i, @A4, -A,, 3A,
(m
@A4, -A,, 3A@A, -A,, 3m
i, @A, -A,, @m@A, -A,
"e#aonal SystemHe%agonal
Di;ision
dihe#aonal
dipyramid
he%agonal
trape0ohedron
dihe%agonal pyramid
ditrigonal dipyramid
he%agonal dipyramid
he%agonal pyramidtrigonal dipyramid
i, &A3, 3A, m
&A3, 3A
&A3, 3m
&3, @A, @m
i, &A3, *m
&A3
&3
5hombohedral
Di;ision
he#aonal
scalenohedron
trigonal trape0ohedron
ditrigonal pyramid
rhombohedron
trigonal pyramid
i, &A,, @A, @m
&A,, @A
&A,, @m
i, &A,
&A,
Tetraonal
System
ditetraonal
dipyramidtetragonal
trap0ohedron
ditetragonal pyramid
tetragonal
scalenohedron
tetragonal dipyramid
tetragonal pyramid
tetragonal disphenoid
i, &A-, 4A, m
&A-, 4A
&A-, 4m
&-, A, m
i, &A-, *m
&A-
&-
!rthorhombicSystem
rhombic dipyramid
rhombic disphenoid
rhombic pyramid
i, @A, @m@A
*A, m
Monoclinic
System
prism
sphenoid
dome
i, *A, *m
*A*m
Triclinic System parallellohedron i
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