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SafetyDataSheet
CrystalDishwasherPowderMountainCleaningProducts
IssueDate:May2016Validto:May2021
Page1of9
SECTION1:IDENTIFICATIONOFPRODUCTANDCOMPANY
TradeName: CrystalDishwasherPowderSynonyms: NA
ChemicalFormula: NACASNumber: NAProductUses: Machinedishwashing.Hasbuiltinrinseaid.
Supplier/Manufacturer: MountainCleaningProducts
Address: 7/7/SnowSt,SouthLismore,NSW2480Telephone: 0266228733
Fax: 0266228744Email: [email protected]
Website: www.mountaincleaning.com.auEmergencyTelephone: 131126(PoisonsInformationCentre)
SECTION2:HAZARD(S)IDENTIFICATION
GHSClassification: Skincorrosion(Category1B)Singletargetorgantoxicity(Category3)
LABELLINGELEMENTS:
SignalWord: DangerPictogram(s):
CorrosiveHealthhazards
HazardStatements(s): H314Causessevereskinburnsandeyedamage.H335Maycauserespiratoryirritation.
PrecautionaryStatement(s):
PreventionP260Donotbreathedusts.P264Washhandsthoroughlyafterhandling.P271Useonlyinawellventilatedarea.P273Avoidreleasetotheenvironment(ifnotintendeduse).P280Wearprotectivegloves.
SafetyDataSheet
CrystalDishwasherPowderMountainCleaningProducts
IssueDate:May2016Validto:May2021
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ResponseP301+P330+P331IFSWALLOWED:Rinsemouth.DoNOTinducevomiting.P303+P361+P353IFONSKIN(orhair):Immediatelytakeoffallcontaminatedclothing.Rinseskinwithwater/shower.P363Washcontaminatedclothingbeforereuse.P304+P340IFINHALED:Removevictimtofreshairandkeepatrestinapositioncomfortableforbreathing.P305+P351+P338IFINEYES:Rinsecautiouslywithwaterforseveralminutes.Removecontactlenses,ifpresentandeasytodo.Continuerinsing.P310ImmediatelycallaPOISONCENTRE(131126)ordoctor.P321Specifictreatment,seeFirstAidMeasuresonthisSafetyDataSheet.
Storage: P403+P233Storeinawell-ventilatedplace.Keepcontainertightlyclosed.P405Storelockedup.
Disposal: P501Disposeofcontents/containertoanapprovedwastedisposalplant.
SECTION3:COMPOSITIONANDINFORMATIONONINGREDIENTSIngredients CASNo.s Percentage(w/w) ClassificationSodiummetasilicatepentahydrate
10213-79-3 20-40% H314+H335
Sodiumcarbonate 497-19-8 20-40% H319Sodiumpercarbonate 16630-89-4 <10% H272+H302+H318Otheringredientsdeterminedtobenonhazardousorbelowconcentrationcutoffs
<30%
SECTION4:FIRSTAIDMEASURES
FirstAidFacilities: Normalwashroomfacilities.EyeContact: Immediatelyirrigatewithcopiousquantitiesofwaterforat
least30minutes.Eyelidstobeheldopen.Avoidrinsewater
SafetyDataSheet
CrystalDishwasherPowderMountainCleaningProducts
IssueDate:May2016Validto:May2021
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enteringuncontaminatedeye.Seekmedicaladvice(e.g.ophthalmologist)ifthereareongoingsymptoms.
SkinContact: Removecontaminatedclothing.Washaffectedskinwithplentyofwater.Seekmedicaladviceifirritation,burningorrednessdevelops.
Inhalation: Removevictimtofreshairawayfromexposure-avoidbecomingacasualty.Removecontaminatedclothingandloosenremainingclothing.Allowpatienttoassumemostcomfortableposition,keepwarmandatrest.Ifbreathinglabouredandpatientcyanotic(blue),ensureairwaysareclearandhavequalifiedpersongiveoxygenthroughafacemask.Seekmedicalattention.
Ingestion: DoNOTinducevomiting.DoNOTattempttogiveanythingbymouthtoanunconsciousperson.Ifconscious,rinsemouththoroughlywithwaterandgivewatertodrink.Ifvomitingoccurs,givefurtherwatertoachieveeffectivedilution.Seekmedicaladvice.
AdvicetoDoctor: Nospecificantidote.Treatsymptomaticallyforchemicalburns.Alltreatmentsshouldbebasedonobservedsignsandsymptomsofdistressofthepatient.PoisonsInformationCentreineachAustralianStatecapitalcityorinChristchurch,NewZealandcanprovideadditionalassistanceforscheduledpoisons.
ScheduledPoisons: PoisonsInformationCentreineachAustralianStatecapitalcitycanprovideadditionalassistanceforscheduledpoisons.PhoneAustralia131126.
SECTION5:FIREFIGHTINGMEASURESFireandExplosionHazard: Non-combustible.However,ifinvolvedinafire,willemittoxic
fumes.ExtinguishingMedia: Usefinewaterspray,normalfoamordryagentextinguisher
(carbondioxideordrychemicalpowder).FireFighting: Keepcontainersexposedtoextremeheatcoolwithwater
spray.Firefighterstowearself-containedbreathingapparatusifriskofexposuretoproductsofcombustionordecomposition.Evacuatearea-moveupwindoffire.
FlashPoint: None.
SafetyDataSheet
CrystalDishwasherPowderMountainCleaningProducts
IssueDate:May2016Validto:May2021
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HazchemCode: 2X.SECTION6:ACCIDENTALRELEASEMEASURES
MinorSpills: Collectspills,avoidinggenerationofdust.Rinseareawithwater.
MajorSpills: Forexampletransportaccidentorbulkspill.Clearareaofunprotectedpersonnel.Workupwindorincreaseventilation.Preventspillagefromenteringdrainsorwatercourses.Wearappropriateprotectiveequipment(seesection8)topreventskinandeyecontamination.Spiltmaterialshouldbeshovelledupandandplacedintosuitablecontainers,appropriatelylabeled,fordisposalbyanapprovedagentaccordingtolocalconditions.Spillageareamayremainslippery.Flushspillareawithexcesswater.Considerneutralisationwithacidifrequired.Ifcontaminationofsewersorwaterwayshasoccurredadvisethelocalemergencyservices.Intheeventofalargespillagenotifythelocalenvironmentprotectionauthorityoremergencyservices.
PPE: PersonalprotectiveequipmentadviceiscontainedinSection8ofthisdocument.
SECTION7:HANDLINGANDSTORAGE
Handling: Avoidskinandeyecontact.Donoteat,drinkorsmokewhenhandlingproduct.Keepoutofreachofchildren.Alwayswashhandswithwaterafterhandling.
Storage: Storeinacool,dry,placewithgoodventilation.Avoidstoringinaluminiumandlightalloycontainers.Storeawayfromincompatiblematerials(seeSection10).Keepcontainersclosedatalltimeswhennotinuse.Checkregularlyforleaksordamage.
SECTION8:EXPOSURECONTROLSANDPERSONALPROTECTION
SafetyDataSheet
CrystalDishwasherPowderMountainCleaningProducts
IssueDate:May2016Validto:May2021
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OCCUPATIONALEXPOSURELIMITS:Noneestablishedforthisproduct.Howevertheexposurestandardfordust,nototherwisespecifiedis10mg/m3(inspirabledust)and3mg/m3(respirabledust).Ingredient TWA STEL DNEL
PersonalProtection: Rubberglovesundernormalconditionsofuse.Chemicalgogglesorsafetyglasses,gloves,longsleevedcoverallsandsafetyfootwearwherecontaminationislikely.
EngineeringControls: Ensureventilationisadequate.Avoidgeneratingdust.Ensureairflowisdirectedawayfromoperators.
EyeandFaceProtection: Chemicalgogglesorsafetyglassestohandleinquantity.HandandSkinProtection: WearimperviousPVCorrubberglovestodispense.
Whenusinglargequantitiesorwhereheavycontaminationislikely,wearcoverallsandfootwearthatprovidesprotectionagainstacids/alkalis.
InhalationProtection: Notnormallyrequiredundernormaluseconditions.Whereadustinhalationriskexistswearafilter/apparatusthatmeetsAS/NZS1715andAS/NZS1716.Foremergencies,includinginstanceswhereexposurelevelsarenotknown,usefull-facepositivepressureair-suppliedrespirator.
SECTION9:PHYSICALANDCHEMICALPROPERTIES
Appearance: Whitecrystallinepowder
Odour: Faint VapourPressure: NotavailableOdourThreshold: Notavailable RelativeVapour
Density:Notavailable
pH: 12.0-13.0at1%solution
RelativeDensity(Water=1):
Notavailable
MeltingPoint: Notavailable WaterSolubility: Miscibleinallportions
BoilingPoint: Notavailable PartitionCoefficientn-Octanol/Water
Notavailable
FlashPoint: Notavailable Auto-ignition Notavailable
SafetyDataSheet
CrystalDishwasherPowderMountainCleaningProducts
IssueDate:May2016Validto:May2021
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TemperatureEvaporationRate: Notavailable Decomposition
TemperatureNotavailable
Flammability: Notflammable Viscosity NotavailableUpper/LowerFlammability:
Notavailable
SECTION10:STABILITYANDREACTIVITY
Reactivity: Reactsviolentlywithacidsyieldingheatandpressurethatcanburstaclosedcontainer.Reactsslowlywithair,absorbingcarbondioxide,whichmaycauseinsolublesaltstoforminsolutionsoftheproduct.
ChemicalStability: Stableundernormalconditionsofstorageandhandling.Contaminationofproductandexposuretoheatandlightwillacceleratedecomposition.
PossibilityofHazardousReactions:
Noneknown.
ConditionstoAvoid: Avoidcontactwithincompatiblematerialsandstorageinmetalcontainers.
IncompatibleMaterials: Acids,amines,ammoniumsalts,aziridine,methanolandphenylacetonitrile.Reactswithmetalsaltsandreducingagents.
SECTION11:TOXICOLOGICALINFORMATION
Inhaled: Corrosive.Breathingindustsmayresultinsorethroat,cough,shortnessofbreathandirritationintherespiratorytract.Inhalationofgranuleswillresultinrespiratoryirritationandpossiblyharmfulcorrosiveeffectsincludingpulmonaryoedema,lesionsofthenasalseptum,pneumonitisandemphysema.
SkinContact: Corrosivetoskin.Maycauseskinburns.EyeContact: Corrosivetoeyes.Contactcancausecornealburnswith
possibleriskofseriousdamagetoeyes.Ingestion: Corrosive.Swallowingcanresultinnausea,vomiting,diarrhoea,
abdominalpain,convulsions,chemicalburns,lostconsciousnessandpossibledeath.Ingestionofdryorliquidformulationscontaining10%orhigherconcentrationofthe
SafetyDataSheet
CrystalDishwasherPowderMountainCleaningProducts
IssueDate:May2016Validto:May2021
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productcanresultinserioushealthproblems.AcuteToxicity: NoLD50dataavailableforthisproduct.
Foractiveconstituent,sodiumcarbonate(at100%):OralLD50(rat)-4090mg/kg Foractiveconstituent,sodiummetasilicatepentahydrate(at100%):OralLD50(rat)-847mg/kg Foractiveconstituent,sodiumpercarbonate(at88%):OralLD50(rat)-1034mg/kg
Chronic: Noinformationavailable.SECTION12:ECOLOGICALINFORMATION
Ecotoxicity: Acuteaquatictoxicity(Category3).Chronicaquatictoxicity(Category3).Harmfultoaquaticlifewithlonglastingeffects.Nodataavailableforthisproduct.Foractiveconstituent,sodiumcarbonate(at100%):LC50(Pimephalespromelas(fatheadminnow))–400mg/litre.Foractiveconstituent,sodiummetasilicatepentahydrate(at100%):LC50(Gambusiaaffnis)–2320mg/litre-96h.Foractiveconstituent,sodiumtripolyphosphate(at>94%):EC50(bacteria)>1000mg/litre–48h. Foractiveconstituent,sodiumpercarbonate(at88%):LC50(Pimephalespromelas(fatheadminnow))–70.7mg/litre-96h.Forminorconstituent,alkoxylatedalcohol(at>60%):LC50(fish)–0.65-1.05mg/litre–96h.Longtermeffect:Nodataavailable.Avoidcontaminatingwaterways.Acuteandchronictoxicityduetoalkoxylatedalcohol,whichisaminorconstituentoftheproduct,pluspHriseeffect.
PersistenceandDegradability:
Individualcomponentsstatedtobebiodegradable.
Bioaccumulative Bioaccumulationisnotexpected.
SafetyDataSheet
CrystalDishwasherPowderMountainCleaningProducts
IssueDate:May2016Validto:May2021
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Potential:MobilityinSoil: Notknown.
OtherAdverseAffects: Noneknown.SECTION13:DISPOSALCONSIDERATIONS
DisposalMethods: RefertoWasteManagementAuthority.Disposeofmaterialthroughalicensedwastecontractor.Decontaminationanddestructionofcontainersshouldbeconsidered.
SECTION14:TRANSPORTINFORMATIONADGCodeClassification: DangerousGoods.
UNNo.: 1759ProperShippingName: CORROSIVESOLIDS,N.O.S.TransportHazardClass: 8–Corrosive
PackingGroup: IIIHazchemCode: 2X
EnvironmentalHazardsforTransport:
Aquatoxicity.
SECTION15:REGULATORYINFORMATIONSUSMP(PoisonSchedule): S6PoisonSECTION16:OTHERINFORMATION
Abbreviations: ADG–AustralianCodefortheTransportofDangerousGoodsbyRoadandRail.CASNo.-ChemicalAbstractServiceNumberusedtouniquelyidentifychemicalcompounds.
SafetyDataSheet
CrystalDishwasherPowderMountainCleaningProducts
IssueDate:May2016Validto:May2021
Page9of9
GHS-GloballyHarmonisedSystem.IARC-InternationalAgencyforResearchonCancer.LD50-LethalDose,50%/medianLethalDose.Mg/m3-Milligramspercubicmetre.PPM–Partspermillion.STEL–ShortTermExposureLimit.STOT-RE–SpecificTargetOrganToxicity(repeatedexposure).STOT–SE-SpecificTargetOrganToxicity(singleexposure).SUSMP–StandardfortheUniformSchedulingofMedicinesandPoisons.TWA/OEL–TimeWeightedAverageorOccupationalExposurelimit.
RevisionHistory: Rev1.0InitialSDSforGHScompliance.PreparedBy: MountainCleaningProductsRegulatoryService.
ENDOFSDS