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Reservoir Engineering
PETR3511 PETR8503: Course Reader2013
JISHAN LIU
SCHOOL OF MECHANICAL ENGINEERINGTHE UNIVERSITY OF WESTERN AUSTRALIA
Email: [email protected]: 6488 7205
F, Production
E,SystemE
xpansion
EFFull Balance
EFPartial Balance
F, Production
E,SystemE
xpansion
EFFull Balance
EFPartial Balance
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CHAPTER 1 RESERVOIR & RESERVOIR ENGINEERING
Petroleum Reservoir: A petroleum reservoir is a continuous body of oil and/or gas that
occurs within a single geological trap. A reservoir may be small (a few acres) or it may extend
over many square miles. A field consists of one or more reservoirs.
Tp,
Overburden Weight
e p
0 pe
Grain Stress orEffective Stress
LiquidPressure
Figure 1.1 Schematic diagram of a petroleum reservoir and its surroundings
External Geometry: Defined by seals or flow barriers that inhibit the migration of
hydrocarbons, forming a hydrocarbon trap.
Internal Architecture: Vertical stacking defined by stratigraphy.
Reservoir A box with its bottom removed.
Reservoir pressure, p, can be calculated as
ep (1)
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ep
e ep MPastress,EffectiveMPastress,Overburden
MPapressure,pore
e
p
Fig.1.2 Relation between overburden stress, pore pressure, and grain stress (effective stress).
Terzaghi equation
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QUESTION 1: How to calculate pore pressures at points B, C and D? Assuming the pore
pressure at Point A is equal to zero
.
Overlying rocks
Gas
Oil
Water
50 m
100 m
50 m
2,000 m
B
A
C
D
Rock density=2,200 kg/m3
Pressure gradient= 0.022 MPa/m
Density of Gas= 200 kg/m3
Pressure gradient= 0.002 MPa/m
Density of Oil= 600 kg/m3
Pressure gradient= 0.006 MPa/m
Density of Water= 1,000 kg/m3
Pressure gradient= 0.01 MPa/m
e ep0 pe
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QUESTION 2: How to calculate pore pressures at points B, C and D? Assuming the pore
pressure at Point A is equal to the effective stress: ep
.
Overlying rocks
Gas
Oil
Water
50 m
100 m
50 m
2,000 m
B
A
C
D
Rock density=2,200 kg/m3
Pressure gradient= 0.022 MPa/m
Density of Gas= 200 kg/m3
Pressure gradient= 0.002 MPa/m
Density of Oil= 600 kg/m3
Pressure gradient= 0.006 MPa/m
Density of Water= 1,000 kg/m3
Pressure gradient= 0.01 MPa/m
e ep ep
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QUESTION 3: The distribution of pore pressure is shown in the following figure. Please
determine the heights for oil zone, gas zone and water zone.
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RESERVOIR ENGINEERING
In this unit, Reservoir Engineering is defined as the underground science of evaluating the
original hydrocarbons in place, the performance of the full range of reservoirs from dry gases
to heavy oils, including gas condensates and volatile oils, and the ultimate recovery. These
evaluations will be conducted based on a single variable, i.e., pore pressure, only.
QUESTION 4: The distribution of pore pressure within a reservoir is shown in the following
figure. How do you determine what pressure to use for these evaluations?
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DEVELOPMENT HISTOTRY OF RESERVOIR ENGINEERING
FLUID & ROCK PROPERTIES
Shithuis, 1935; Fancher, 1933
FIRST MATERIAL BALANCE
EQUATION
Shithuis, 1936
FLOW PRINCIPLES
Muskat 1937
DISPLACEMENT THEORY
Buckley & Leverret 1942
FLUID & ROCK PROPERTIES
Shithuis, 1935; Fancher, 1933
FIRST MATERIAL BALANCE
EQUATION
Shithuis, 1936
FLOW PRINCIPLES
Muskat 1937
DISPLACEMENT THEORY
Buckley & Leverret 1942
AQUIFER INFLUX
Everdingen & Hurst 1949
REVIEW OF RESERVOIR
ENGINEERING
Moore 1955
MBE GRAPHICAL SOLUTION
Havlena &Oldel, 1963
MBE - VOLATILE RESERVOIRS
Walsh 1994
AQUIFER INFLUX
Everdingen & Hurst 1949
REVIEW OF RESERVOIR
ENGINEERING
Moore 1955
MBE GRAPHICAL SOLUTION
Havlena &Oldel, 1963
MBE - VOLATILE RESERVOIRS
Walsh 1994
Engineering Subject
Theory for Secondary
Recovery
TankModel
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CHAPTER 2 RESERVOIR CLASSIFICATIONS
pRP In this unit, we evaluate the performance of a reservoir based on its response to pore pressure
only. Therefore, we can design the classification schemes accordingly.
Pore pressure is related to the number of phases. We can classify reservoirs as single-phase
reservoir; two-phase reservoir; multi-phase reservoir.
Overlying rocks
Gas
Oil
Water
50 m
100 m
50 m
2,000 m
B
A
C
D
Reservoir pressure (MPa)
22 MPa
22.1 MPa
22.7 MPa
0.01MPa50
wwCD hp
MPa23.2 CDCD ppp23.2 MPa
Pore pressure is also related to the reservoir internal structure. Based on the internal structure,
we can classify reservoirs as un-fractured reservoir and fractured reservoir.
IN THIS UNIT, WE CLASSIFY RESERVOIRS BASED ON THE INITIAL
RESERVOIR PRESSURE.
From a technical point of view, the various types of reservoirs can be defined by the location
of the initial temperature and pressure with respect to the two-phase (gas and oil) region as
commonly shown on pressure temperature (PT) phase diagrams. This figure is the PT diagram
of a particular reservoir fluid. The area enclosed by the bubble-point and dew-point lines to
the lower left is the region of pressure-temperature combinations in which both gas and liquid
phases will exist.
Point A:initially at 300oF and 3700psi. Since this point lies outside the two-phase region, it
is originally in a one-phase state.
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Reservoir Fluid: If the reservoir pressure declines along path (1), it will remain in the
single-phase or gaseous state.
Production Fluid: Although the fluid left in the reservoir remains in one phase, the fluid
produced through the wellbore and into surface separators, may enter the two-phase region
owning to temperature decline, as along line (2).
Figure 1.2: P-T Diagram for a Typical Reservoir Fluid
Point B:initially at 180oF and 3300psi. Since this point lies outside the two-phase region, it
is originally in a one-phase state.
Reservoir Fluid:As pressure declines along path (1) because of production, the composition
of the reservoir fluid will remain constant until the dew-point pressure is reached at 2700psi.
Production Fluid:Because the condensed liquid adheres to the walls of the pore walls of the
rock, the gas produced at the surface will have a lower liquid content. This process of
retrograde continues until B2 is reached.
Point C:initially at 75oF and 2900psi. Since this point lies outside the two-phase region, it is
0 50 100 150 200 250 300350
Reservoir Temperature, oF
4000
3500
3000
2500
2000
1500
1000
ReservoirPressure,psi
A
A2
B2
B1
B
B3
A1
C1
C
D
0%
20%
10%
5%
80%40%
Bubb
lePo
int
Critical
Point
Dew
Point
Bubble Point or
Dissolved Gas
Reservoir
Dew Point or
Retrograde Gas
CondensateReservoir
Single-phase Gas
Reservoir
Path
ofReservoirFluid
Cricon
dentherm
Path
ofP
rod
ucti
on
0 50 100 150 200 250 300350
Reservoir Temperature, oF
4000
3500
3000
2500
2000
1500
1000
ReservoirPressure,psi
A
A2
B2
B1
B
B3
A1
C1
C
D
0%
20%
10%
5%
80%40%
Bubb
lePo
int
Critical
Point
Dew
Point
Bubble Point or
Dissolved Gas
Reservoir
Dew Point or
Retrograde Gas
CondensateReservoir
Single-phase Gas
Reservoir
Path
ofReservoirFluid
Cricon
dentherm
Path
ofP
rod
ucti
on
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originally in a one-phase state.
Reservoir Fluid:As pressure declines along path (1) because of production, the composition
of the reservoir fluid will remain constant until the bubble-point pressure is reached at
2550psi.
Production Fluid:Below this point, bubbles or a free gas will appear. Eventually, the free
gas evolved begins to flow to the wellbore, and in ever increasing quantities.
According to the initial conditions, reservoirs can be classified as
Single Phase Gas Reservoir Gas-Condensate Reservoir Undersaturated Oil Reservoir Saturated Oil Reservoir
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QUESTION 1: Assuming an ideal gas reservoir, the original gas pressure is 8MPa. During
production, the total pore volume, 0V , remains unchanged. When the reservoir pressure
becomes 4MPa, calculate the total gas volume in the reservoir. Comparing this volume with
the total pore volume, what can you conclude based on this comparison?
Ground Surface
Gas
Reservoir
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CHAPTER 3 PRODUCING MECHANISMS
pRP In this unit, we evaluate the performance of a reservoir based on its response to pore pressure
only. Therefore, all of the producing mechanisms can be related to the reservoir pressure.
1p 2p
21 pp
Balloon: The balloon size is proportional to the pressure. When air flows out from inside, the
balloon pressure becomes smaller.
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QUESTION 1: Use the balloon phenomenon to analyze the gas production process. When
the reservoir pressure deceases, what would happen to both the pore volume and the gas
volume?
PORE
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Types of Reservoir Energy
The major types of energy available for primary petroleum production are
The energy of compression of the water and rock within a reservoir; The energy of compression of oil within a reservoir; The energy of compression of gas within a reservoir; The energy of waters that are contiguous to and in communication with the petroleum
reservoir;
The gravitational energy that causes oil and gas to segregate within the reservoir.In the thermodynamic sense, the energy in the first four items of the list refers to the
potential energy stored in the compressed fluids. It is equivalent to the potential energy stored
in a compressed spring. Through the first law of thermodynamics, such energy can be
converted to the pressure-volume work (force through a distance) needed for fluids to be
produced. The energy in the fifth term is the potential energy caused by the differences
between different distances (elevations) from the Earths center of gravity.
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Producing Mechanisms
We need to know and understand by what mechanism the oil is being produced. These are the
fundamental drive mechanisms. The main drive mechanisms include water drive, oil and gas
expansion drive, compaction drive.
The performance characteristics of hydrocarbon producing reservoirs depend largely on thetypes of energy available to move the hydrocarbon fluids to the wellbore.
A water drive reservoir is an unsealed petroleum reservoir that is in communication with
water-bearing reservoirs (aquifers). There is appreciable movement of water from the aquifer
into the petroleum reservoir.
If the volumetric rate of water intrusion into the reservoir approaches the volumetric rate of
fluid withdrawal from the reservoir, then the reservoir is a complete-water drive reservoir. A
complete water drive reservoir experiences a very little pressure decline; however, some
pressure decline must exist else no potential (pressure) difference between the reservoir and
aquifer would exist and no water influx would occur. If the volumetric rate of water intrusioninto the reservoir is substantial but substantially less than the volumetric rate of fluid
withdrawal from the reservoir, then the reservoir is a partial water drive reservoir. When a
water drive exists, the reservoir pressure will always be sensitive to the producing rate. If the
producing rate is too large relative to the water influx rate, the water drive will lose its
effectiveness and the reservoir pressure will decline.
Oil Recovery Processes
PRODUCING MECHANISMS
EXPANSION
DRIVE
WATER
DRIVE
COMPACTION
DRIVE
OIL DRIVE GAS DRIVE
SOLUTION GAS
DRIVE
GAS
DRIVE
GAS CAP
DRIVE
PRODUCING MECHANISMS
EXPANSION
DRIVE
WATER
DRIVE
COMPACTION
DRIVE
OIL DRIVE GAS DRIVE
SOLUTION GAS
DRIVE
GAS
DRIVE
GAS CAP
DRIVE
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The simplest case is that of a single-phase oil field. Such fields can be found among fields in
their very early stage of development, when the gas or oil is produced by simple natural
decompression. This stage ends rapidly, when the pressure equilibrium between the oil field
and the atmosphere is attained: the natural production of oil or gas stops, though only a small
percentage of the total amount of oil or gas has been produced. This first stage is called
primary recovery.
In order to recover part of the remaining oil, we could pump off at the wells, creating a
pressure drop which would draw the oil to these wells. This would have two draw backs: first,
the pressure around the wells could fall below the bubble pressure of the oil so that the wells
would produce almost only gas, and the heavier components would mainly remain trapped in
the field. Second, diminishing the pressure in the fluid phase could lead the rock to collapse,
resulting in a field with lower permeability and hence more difficult to produce. This is why
we use an alternative method called secondary recovery: we divide the available wells into
two sets: one set of injection wells, and one set of production wells. The injection wells are
used to inject an inexpensive fluid (usually water) into the porous medium, in order to push
the oil toward the production wells. During this process, the pressure inside the field ismaintained above its initial level, so that the two above mentioned draw backs may be more
easily avoided.
For secondary recovery process, two cases are to be considered: Either the pressure can be
maintained always above the bubble pressure of the oil. The flow in the reservoir is then of
the two-phase immiscible type, one phase being water and the other being oil, with no mass
transfer between the phases. Or the pressure may drop, at some points, below the bubble
pressure of the oil: then the oil may split into one liquid phase and one gaseous phase atthermodynamical equilibrium. This is the so-called black-oil reservoir, with one water phase,
which does not exchange mass with the other phases, and two hydrocarbon phases (one liquid
Control Ps & Vs & T & Cs
Why the Recovery Fraction is Small?
Control Ps & Vs & T & Cs
Why the Recovery Fraction is Small?
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phase and one gaseous phase), which exchange mass when the pressure and the temperature
change.
The above waterflooding technique makes it possible to recover a certain percent (up to 40%)
of the oil. Three reasons for low recovery:
There exists regions which are never flooded by the water, and hence whose oil is notgoing to be produced; Even in the flooded regions, a significant part of oil (up to 20% to 30%) remains
trapped in the pores by the action of the capillary forces;
When the oil is heavy and viscous, the water is extremely mobile in comparison to theoil. Then instead of pushing the oil towards the production well, the water finds very
quickly its own way to the production well, getting the oil moving very slowly toward
the production well.
The oil industry developed a set of different techniques known under the generic name of
tertiary recovery techniques or enhanced oil recovery (EOR) techniques or improved oil
recovery (IOR) techniques. One of the main goals of those techniques is to achievemiscibility of fluids, thus eliminating the residual oil saturation, which was one cause of low
recovery with the water flooding technique. This miscibility is sought using temperature
increase or the introduction of other components such as polymers.
20%
35%
50%
Primary Recovery
Water Flooding
EOR
Recovery Processes
Without Stimulation
faster oil
Incremental
Oil
Same Process with
Well Stimulation
TIME
CumulativeOil
Recovery
Oil Recovery Summary
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QUESTION 2: Can you thinks five ways to get the oil droplets out?
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CHAPTER 4 ROCK PROPERTIES
pRP
In this unit, we evaluate the performance of a reservoir based on its response to pore pressureonly. Therefore, we can relate rock properties changes to the reservoir pressure.
A Four-Component Reservoir Model:To understand and predict the volumetric behavior of
oil and gas reservoirs as a function of pressure, knowledge of the physical properties of
reservoir rocks and fluids must be obtained. These properties are usually determined by lab
experiments on samples of actual reservoir rocks and fluids. In the absence of experimentally
measured properties, it is necessary for the petroleum engineer to determine the properties
from empirically derived correlations. In this unit, we assume that a reservoir consists of four
components:
Gas Oil Water RockWith the following assumptions:
At most, there are four components, gas, oil, water and rock; At most, there are four phases: gas, oil, water, and solid; The gas component is defined by the composition of the reservoir gas at the reservoir
conditions;
The oil component is defined by the composition of the reservoir oil at the reservoirconditions;
Thermodynamic equilibrium exists.In the following chapters, we will define the fundamental properties of each component and
interactions between components. These properties are absolutely essential for the
determination ofthe volumetric behavior of oil and gas reservoirs as a function of pressure.
In this chapter, we will cover five major properties of reservoir rocks: Porosity; Saturation; Permeability; Relative permeability; Compressibility.Two things are required to remember:
Definitions of all concepts; Evolution of each property during the production process.POROSITY
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We will start with what is porosity and then how does the porosity change as a function of
pore pressure.
Definition: Although a reservoir rock looks a solid to the naked eye, a microscopic
examination reveals the existence of voids in the rock. These pores are the ones where
petroleum reservoir fluids are present. This particular storage capacity is called porosity. The
more porous a reservoir rock material is, the greater the amount of voids it contains, hencegreater the capacity to store petroleum reservoir fluids. From a reservoir engineering
perspective, porosity is probably one of the most important reservoir rock properties.
Porosity, is a volumetric fraction defined as the ratio of the pore volume,poreV in a
reservoir rock to the total volume (bulk volume),bulkV :
bulk
pore
V
V (2.1)
The porosity of a rock is a measure of the storage capacity (pore volume) that is capable of
holding fluids. It may by occupied by a single-phase fluid or mixtures. As the sediments were
deposited and the rocks were being formed during past geological times, some void spaces
that developed became isolated from the other void spaces by excessive cementation. Thus,
many of the void spaces are interconnected while some of the pore spaces are completely
isolated. This leads to two distinct types of porosity, namely:
Absolute porosity Effective porosity.
bulk
totalpore
aV
V (2.2)
bulk
dporeerconnecte
eV
Vint (2.3)
The effective porosity is the value that is used in all reservoir engineering calculations
because it represents the interconnected pore space that contains the recoverable hydrocarbon
fluids.
QUESTION 1: Assuming the rock porosity is, use the mass conservation law to work out
the relation between the bulk density and rock & pore densities.
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Figure 1: Relation between porosity and density.
QUESTION 2: Assuming the pores in the rock as shown in Figure 1 are occupied by water,what is the total mass in the rock?
bulk
rock
pore
V
V
V
bulk
rock
pore
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Original Porosity & Induced Porosity: Porosity may be classified according to the mode of
origin as original induced. The original porosity is that developed in the deposition of the
material, while induced porosity is that developed by some geologic process subsequent to
deposition of the rock. The intergranular porosity of sandstones and the intercrystalline and
porosity of some limestones typify original porosity. Induced porosity is typified by fracture
development as found in shales and limestones and by the slugs or solution cavities
commonly found in limestones. Rocks having original porosity are more uniform in theircharacteristics than those rocks in which a large part of the porosity is included. For direct
quantitative measurement of porosity, reliance must be placed on formation samples obtained
by coring. Since effective porosity is the porosity value of interest to the petroleum engineer,
particular attention should be paid to the methods used to determine porosity. For example, if
the porosity of a rock sample was determined by saturating the rock sample 100 percent with
a fluid of known density and then determining, by weighing, the increased weight due to the
saturating fluid, this would yield an effective porosity measurement because the saturating
fluid could enter only the interconnected pore spaces. On the other hand, if the rock sample
were crushed with a mortar and pestle to determine the actual volume of the solids in the core
sample, then an absolute porosity measurement would result because the identity of any
isolated pores would be lost in the crushing process.
One important application of the porosity is its use in determining the original hydrocarbon
volume in place.
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Question 3As shown in Figure 2, think about how to use the porosity for the determination
of the original hydrocarbon volume in place (OHIP) and answer the following questions:
If the pore is occupied by oil only, the calculated PV is the original oil in place (OOIP); If the pore is occupied by gas only, the calculated PV is the original gas in place (OGIP). If the pore is occupied by oil and gas, what would happen? If the pore is occupied by oil, gas and water, what would happen?
Figure 2: Illustration of a reservoir volume determination
Question 4As shown in Figure 2, assuming the pores are occupied by water only, calculatethe original water in place (OWIP) and discuss what factors will change OWIP?
Question 5If pores are occupied by a mixture of oil, gas and water, discuss how to calculate
the original water, oil, or gas in place (OWIP, OOIP and OGIP)?
RESERVOIR
bulk
rock
pore
V
V
V
bulk
rock
pore
bulkVPV
RESERVOIR
bulk
rock
pore
V
V
V
bulk
rock
pore
bulkVPV
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COAL POROSITY
s
b
Coal Matrix
Fracture
Fig.3 Fractured Coal
Fractured coals are made up of two porosity systems; one matrix formed by void spaces
between the grains of the coal, and a second formed by void spaces of fractures as shown in
Fig.1. In a fractured coal reservoir the total porosity ( t ) is the result of the simple addition of
the matrix and fracture porosities:
fracturematrixt (1)
Where
VolumeBulkCoal
VolumeVoidMatrixCoalmatrix
VolumeBulkCoal
VolumeVoidFractureCoalfracture
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QUESTION 5: Assuming cmsmmb 10.0 , calculate the fracture porosity and discuss
the result.
s
b
Coal Matrix
Fracture
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FLUID SATURATION
While porosity represents the maximum capacity of a reservoir rock to store fluids, how can
we know how much of this available capacity, pore volume, or pore space distributed or
partitioned among the typical reservoir fluid phases: gas, oil and water? In order to achieve
this, we need to introduce the concept of fluid saturation.
Saturation is defined as that fraction, or percent, of the pore volume occupied by a particular
fluid (oil, gas, or water). This property is expressed mathematically by the following
relationship:
VolumePoreTotal
FluidtheofVolumeTotalSaturationFluid
Assumingwgo SSS ,, represent the oil saturation, gas saturation and water saturation,
respectively, andwgo VVV ,, for the oil volume, gas volume, and water volume, respectively,
and pV the total pore volume, applying the above mathematical concept to each to each
reservoir fluid gives
p
w
w
p
g
g
p
o
o
V
VS
V
VS
V
VS
(2.7)
Thus, all saturation values are based on pore volume and not on the gross reservoir volume.
The saturation of each individual phase ranges between zero to 100 percent. By definition, the
sum of the saturations is 100%, therefore
1 wgo
SSS (2.8)
Equation (2.8) is probably the simplest, yet the most fundamental equation in reservoir
engineering, and is used everywhere in reservoir engineering calculations. Moreover, many
important reservoir rock properties, such as capillary pressure and relative permeability, areactually related or linked with individual fluid-phase saturations.
The fluids in most reservoirs are believed to have reached a state of equilibrium and, therefore,
will have become separated according to their density, i.e., oil overlain by gas and underlain
by water. In addition to the bottom (or edge) water, there will be connate water distributed
throughout the oil and gas zones. The water in these zones will have been reduced to some
irreducible minimum. The forces retaining the water in the oil and gas zones are referred to as
capillary forces because they are important only in pore spaces of capillary size. Connate
(interstitial) water saturation Swc is important primarily because it reduces the amount of
space available between oil and gas. It is generally not uniformly distributed throughout the
reservoir but varies with permeability, lithology, and height above the free water table.
Another particular phase saturation of interest is called the critical saturation and it is
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associated with each reservoir fluid. The definition and the significance of the critical
saturation for each phase is described below.
Critical oil saturation,ocS : For the oil phase to flow, the saturation of the oil must exceed a
certain value which is termed critical oil saturation. At this particular saturation, the oil
remains in the pores and, for all practical purposes, will not flow.
Residual oil saturation,or
S : During the displacing process of the crude oil system from the
porous media by water or gas injection (or encroachment) there will be some remaining oil
left that is quantitatively characterized by a saturation value that is larger than the critical oil
saturation. This saturation value is called the residual oil saturation,orS . The term residual
saturation is usually associated with the nonwetting phase when it is being displaced by a
wetting phase.
Movable oil saturation,omS : Movable oil saturation is another saturation of interest and is
defined as the fraction of pore volume occupied by movable oil as expressed by the followingequation:
ocwcom SSS 1 (2.9)
wherewcS and
ocS are connate water saturation and critical oil saturation, respectively.
Critical gas saturation,gc
S : As the reservoir pressure declines below the bubble-point
pressure, gas evolves from the oil phase and consequently the saturation of the gas increases
as the reservoir pressure declines. The gas phase remains immobile until its saturation exceeds
a certain saturation, called critical gas saturation, above which gas begins to move.
Critical water saturation,gc
S : The critical water saturation, connate water saturation, and
irreducible water saturation are extensively used interchangeably to define the maximum
water saturation at which the water phase will remain immobile.
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QUESTION 4: The following is a summary of saturation definitions. Discuss their changes
during production processes.
1poreV
wiS
orS
wmS
omS1
omwmorwr SSSS
Irreduciblewatersaturation
Residualoilwatersaturation
Movablewatersaturation
Movableoilsaturation
1
1
1
1
**
*
*
ow
orwr
orw
o
orwr
wrw
w
SS
SS
SSS
SS
SSS
1
wo
oromo
wrwmw
SS
SSSSSS
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ABSOLUTE PERMEABILITY
In above sections, we address the porosity and saturation both of which are used to define the
storage capacity of reservoir rock for reservoir fluids. However, merely having a large enough
porosity of reservoir rock is not sufficient because the petroleum reservoir fluids contained inthe pore spaces of reservoir rock have to flow, so that they can be produced or brought to the
surface from the reservoir. This particular property of a reservoir rock is called permeability.
Permeability is one of the most influential parameters in determining the production
capabilities of a producing formation.
Unlike porosity, permeability is a flow property (dynamic) and therefore can be characterized
only by flow experiments in a reservoir rock. Permeability is a property of the porous medium
that measures the capacity and ability of the formation to transmit fluids. The rock
permeability, k, is a very important rock property because it controls the directional
movement and the flow rate of the reservoir fluids in the formation. Absolute permeability is
the rock permeability when a reservoir rock is 100% saturated with a given fluid. It should be
noted that the absolute permeability is a property of the rock alone and not the fluid that flowsthrough it, provided no chemical reaction takes place between the rock and the flowing fluid.
All the equations used to describe fluid flow in reservoirs are based on Darcys law. Darcy
(1856), investigated the flow of water through sand filters. He observed the following
relationship between velocity and pressure gradient as
x
pk
A
Qux
(2.10)
Where
direction-xtheinCoordinate
Pressure
flowtoopenareasectional-Cross
ViscosityFluid
tyPermeabili
RateFlow
direction-xtheinvelocityDarcy
x
p
A
k
Q
ux
Basic assumptions:
It is assumed that the porous medium is saturated with a single fluid. The flowing fluid is incompressible. The linear dependence of flow velocity on the pressure gradient implies laminar. The flow takes place under the viscous regime (i.e., the rate of flow is sufficiently low
so that it is directly proportional to the pressure differential or the hydraulic gradient).
The flowing fluid does not react with the porous medium.
The negative sign in the above equations indicates that pressure decreases in the direction of
flow. The sign convention is therefore that distance is measured positive in the direction of
flow.
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QUESTION: Assuming 1-D flow, determine the pressure distribution.
Figure 2.4 One-dimensional horizontal flow.
Flow-InFlow-Out
A
1p
2p?
Flow-InFlow-Out
A
Flow-InFlow-Out
A
1p
2p?
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Dimensional Analysis for Permeability Unit:
2
2
23
222
2
3
1
Lk
LM
LT
LT
MkL
T
L
LT
Mtime
area
force
LTM
LTML
areaforcep
LA
T
LQ
21 m-12101Darcy
One Darcy is a relatively high permeability as permeabilities of most reservoir rocks are
below one Darcy. In order to avoid the use fractions in describing permeabilities, the term
millidarcy is used. As the term indicates, one millidarcy, i.e., 1 md, is equal to one-thousand
of one Darcy or, 1 Darcy = 1000 md.
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QUESTION: A fluid of viscosity of 1.2cp flows through a cylindrical core at a rate of
scm /25.0 3 with a pressure drop of 2.5 atm. Core dimensions are length of 12cm and a 5-cm2
flow area. Determine the core permeability.
2
3
5
5.2
/25.0
2.1
???
cmA
atmp
scmq
cp
k
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2.4 Relative Permeability
Darcys law was considered to apply when the porous medium was 100% saturated with a
homogeneous single-phase fluid. However, petroleum reservoirs having much simple
single-phase fluid systems seldom exist; usually reservoir rock systems are saturated with atleast two or more fluids such as water, oil and gas. These multiphase fluid systems play a very
important role in the reservoir flow processes when petroleum reservoirs are produced by
primary recovery mechanism or immiscible displacement methods involving the injection of
water or gas. It is under these circumstances that more than one fluid phase is flowing or is
mobile through a porous medium; thus the flow of one fluid phase interferes with the other.
This interference is a competition for the flow paths.
Numerous laboratory studies have concluded that the effective permeability of any reservoir
fluid is a function of the reservoir fluid saturation and the wetting characteristics of the
formation. It becomes necessary, therefore, to specify the fluid saturation when stating the
effective permeability of any particular fluid in a given porous medium. Just as k is theaccepted universal symbol for the absolute permeability, ko, kg, and kw are the accepted
symbols for the effective permeability to oil, gas, and water, respectively. The saturations, i.e.,
So, Sg, and Sw, must be specified to completely define the conditions at which a given
effective permeability exists.
Effective permeabilities are normally measured directly in the laboratory on small core plugs.
Owing to many possible combinations of saturation for a single medium, however, laboratory
data are usually summarized and reported as relative permeability. The absolute permeability
is a property of the porous medium and is a
measure of the capacity of the medium to transmit fluids. When two or more fluids flow at the
same time, the relative permeability of each phase at a specific saturation is the ratio of theeffective permeability of the phase to the absolute permeability, or:
k
kk
k
kk
k
kk
wrw
g
rg
oro
(2.11)
For example, if the absolute permeability k of a rock is 200 md and the effective permeability
ko of the rock at an oil saturation of 80 percent is 60 md, the relative permeability kro is 0.30
at So = 0.80. Since the effective permeabilities may range from zero to k, the relative
permeabilities may have any value between zero and one, or:
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0.1,,0 rorgrw kkk (2.12)
It should be pointed out that when three phases are present the sum of the relative
permeabilitiesrwrgro
kkk is both variable and always less than or equal to unity.
Initially, it might appear that the sum of the phase permeabilities equals the total or absolute
permeability, which would mean that the relative permeabilities should sum to unity. However,
this is not true. When two or more phases are present, capillary forces exist that reduce the
flow rate of each individual phase in a non-linear fashion. This means that the sum of the
phase permeabilities is always less than the total or absolute permeability and the sum of
relative permeabilities is always less than one. Indeed, at irreducible water saturation, the
relative permeability to water becomes zero while the relative permeability to oil or gas is less
than one because the immobile water is occupying some of the flow volume. Similarly, at
residual oil saturation, the relative permeability to water or gas is less than one.
Question 2.7Relative Permeability Calculations from Steady-State TestsA set of steady state oil/water relative flow rates at different saturations is given below. Core
dimensions are a length of 12 cm and a 5-cm2 flow area (i.e. the area perpendicular to the
direction of flow). Oil viscosity is 5 cp and water viscosity is 1.2 cp.
Determine the oil and water relative permeabilities; Determine the oil- and water-phase permeabilities.Solution:
1. Relative Permeabilities2.
Sw qo(cm3/s) qw(cm3/s)
0 0.06 0
0.2 0.042 0
0.3 0.03 0.01
0.4 0.02 0.02
0.5 0.013 0.035
0.6 0.0075 0.051
0.7 0.004 0.068
0.8 0.001 0.085
0.85 0 0.0961 0 0.25
00
///
///
w
w
w
w
So
So
Soo
Sooo
roq
q
dpdxAq
dpdxAq
k
kk
Similarly,
11
///
///
w
w
w
w
So
So
Sww
Swww
rwq
q
dpdxAq
dpdxAq
k
kk
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kro krw
1 0
0.7 0
0.5 0.04
0.333333 0.08
0.216667 0.14
0.125 0.2040.066667 0.272
0.016667 0.34
0 0.384
0 1
0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1
0 0.2 0.4 0.6 0.8 1
Sw
Kro
,
krw
2. Phase Permeability
mddarcy
dx
dp
A
qk ooo
4.62624.0
5.2
12
5
5013.0/
ko kw
0.288 0
0.2016 0
0.144 0.01152
0.096 0.02304
0.0624 0.04032
0.036 0.058752
0.0192 0.078336
0.0048 0.097920 0.110592
0 0.288
2.5 Compressibility
A reservoir thousands of feet underground is subjected to an overburden pressure caused by
the weight of the overlying formations. Overburden pressures vary from area to area
depending on factors such as depth, nature of the structure, consolidation of the formation,
and possibly the geologic age and history of the rocks. Depth of the formation is the most
important consideration, and a typical value of overburden pressure is approximately one psiper foot of depth. The weight of the overburden simply applies a compressive force to the
reservoir. The pressure in the rock pore spaces does not normally approach the overburden
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pressure. A typical pore pressure, commonly referred to as the reservoir pressure, is
approximately 0.5 psi per foot of depth, assuming that the reservoir is sufficiently
consolidated so the overburden pressure is not transmitted to the fluids in the pore spaces.
The pressure difference between overburden and internal pore pressure is referred to as the
effective overburdenpressure. During pressure depletion operations, the internal pore pressure
decreases and, therefore, the effective overburden pressure increases. This increase causes thefollowing effects:
The bulk volume of the reservoir rock is reduced.
Sand grains within the pore spaces expand.
These two volume changes tend to reduce the pore space and, therefore, the porosity of the
rock. Often these data exhibit relationships with both porosity and the effective overburden
pressure.
Compressibility typically decreases with increasing porosity and effective overburden
pressure. Geertsma (1957) points out that there are three different types of compressibilitythat must be distinguished in rocks:
Rock-matrix compressibility,r
c : The rock matrix compressibility is defined as the
fractional change in volume of the solid rock material (grains) with a unit change in pressure.
Mathematically, the rock compressibility coefficient is given by
dp
dV
Vc rock
rock
r
1 (2.13)
Rock-bulk compressibility,Bc : The rock-bulk compressibility is defined as the fractional
change in volume of the bulk volume of the rock with a unit change in pressure. The
rock-bulk compressibility is defined mathematically by:
eff
B
B
Bd
dV
Vc
1 (2.14)
WhereB
V is the bulk volume and eff is effective pressure.
Pore compressibility,pc : The pore compressibility coefficient is defined as the fractional
change in pore volume of the rock with a unit change in pressure and given by the following
relationship:
dp
dV
Vc
p
p
p
1 (2.15)
Wherep
V is the pore volume.
Equation 2-15 can be expressed in terms of the porosity by noting that porosity increases
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with the increase in the pore pressure; or:
dp
dcp
1 (2.16)
For most petroleum reservoirs, the rock and bulk compressibility are considered small in
comparison with the pore compressibilityp
c . Theformation compressibilityf
c is the term
commonly used to describe the total compressibility of the formation and is set equal top
c ,
i.e.:
dp
d
dp
dV
Vcc
p
p
pf
11 (2.17)
Typical values for the formation compressibility range from16103 psi to 161025 psi .
It should be pointed out that the total reservoir compressibility ct is extensively used in the
transient flow equation and the material balance equation as defined by the following
expression:
fggwwoot ccScScSc (2.18)
Question 2.8: Measured volumes and pressures are listed below:
p(psi) Vp(cm3) Vb(cm3)
9800 3.42 20.53
9000 3.379 20.498
8000 3.337 20.447
7000 3.303 20.413
6000 3.276 20.3825000 3.257 20.367
4000 3.243 20.353
3000 3.23 20.34
2000 3.213 20.332
1000 3.177 20.329
500 3.144 20.254
Calculate porosity, rock compressibility, bulk compressibility and pore compressibility.
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porosity cp cb
16.65855 1.49854E-05 1.94837E-06
16.48454 1.24297E-05 2.48805E-06
16.32024 1.01888E-05 1.66284E-06
16.18087 8.17439E-06 1.51864E-06
16.07301 5.79976E-06 7.35943E-07
15.99155 4.29843E-06 6.87386E-0715.93377 4.00863E-06 6.38726E-07
15.88004 5.26316E-06 3.93314E-07
15.80268 1.12045E-05 1.47551E-07
15.62792 2.07743E-05 7.37862E-06
15.52286
0.00E+00
5.00E-06
1.00E-05
1.50E-05
2.00E-05
2.50E-05
0 2000 4000 6000 8000 10000
Pressure, psi
Compress
ibility,1
/ps
i
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DecreasingPermeability
Figure 2.5 Resource Triangle.
QUESTIONHow to relate the resource triangle to the rock properties?
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CHAPTER 3 FLUID PROPERTIES
To understand and predict the volumetric behavior of oil and gas reservoirs as a function of
pressure, knowledge of the physical properties of reservoir fluids must be obtained. These
fluid properties are usually determined by lab experiments on samples of actual reservoir
fluids. In the absence of experimentally measured properties, it is necessary for the petroleum
engineer to determine the properties from empirically derived correlations. The objective of
this chapter is to define fundamental PVT properties for the following reservoir fluids:
Natural Gases Crude Oil Water
3.1 Gas Properties
3.1.1 Gas Law
A gas is defined as a homogeneous fluid of low viscosity and density that has no definite
volume but expands to completely fill the vessel in which it is placed. Generally, the natural
gas is a mixture of hydrocarbon and nonhydrocarbon gases. The hydrocarbon gases that are
normally found in a natural gas are methanes, ethanes, propanes, butanes, pentanes, and small
amounts of hexanes and heavier. The nonhydrocarbon gases (i.e., impurities) include carbon
dioxide, hydrogen sulfide, and nitrogen.
Behavior of Ideal Gases:The kinetic theory of gases postulates that gases are composed of a
very large number of particles called molecules. For an ideal gas, the volume of these
molecules is insignificant compared with the total volume occupied by the gas. It is also
assumed that these molecules have no attractive or repulsive forces between them, and that all
collisions of molecules are perfectly elastic. Based on the above kinetic theory of gases, a
mathematical equation called equation-of-state can be derived to express the relationship
existing between pressure p, volume V, and temperature T for a given quantity of moles of
gas n. This relationship for perfect gases is called the ideal gas law and is expressedmathematically by the following equation:
nRTPV (3.1)
Where is the absolute pressure, psi; V is the volume, cft; T is the temperature, oR; n is the
number of moles of gas, lb-mole; R is the universal gas constant which, for the above units,
has the value of 10.730psi cft/lb-mole oR.
Behavior of Real Gases: Basically, the magnitude of deviations of real gases from theconditions of the ideal gas law increases with increasing pressure and temperature and varies
widely with the composition of the gas. Real gases behave differently than ideal gases. The
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reason for this is that the perfect gas law was derived under the assumption that the volume of
molecules is insignificant and that no molecular attraction or repulsion exists between them.
This is not the case for real gases. Numerous equations-of-state have been developed in the
attempt to correlate the pressure-volume-temperature variables for real gases with
experimental data. In order to express a more exact relationship between the variables p, V,
and T, a correction factor called thegas compressibility factor, gas deviation factor, or simply
thez-factor, must be introduced into Equation 3-1 to account for the departure of gases fromideality. The equation has the following form:
znRTPV (3.2)
where the gas deviation factor z is a dimensionless quantity and is defined as the ratio of the
actual volume of n-moles of gas at T and p to the ideal volume of the same number of moles
at the same T and p:
pnRT
V
V
Vz
ideal
actual
/
(3.3)
Figure 3.1: Effect of Pressure on the Gas Deviation Factor.
Many gases near atmospheric PT conditions approach ideal behavior (Z=1). All molecules
have two tendencies: 1. to fly apart from each other because of their constant kinetic motion,
and 2. to come together because of electrical attractive forces between molecules. Because the
molecules are quite far apart, the attractive forces are negligible, and the gas behaves close to
ideal. Also at high temperatures the kinetic motion, being greater, makes the attractive forces
comparatively negligible, and, again, the gas approaches ideal behavior. When the gas is
highly compressed, the gas appears to be more difficult to compress.
Question 3.1 For an ideal gas under the isothermal condition, prove the following relation
PRESSURE, PSI
1000 2000 6000
Z
1.0
PRESSURE, PSI
1000 2000 6000
Z
1.0
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between two P-V states:
1
2
2
1
V
V
p
p (3.4)
Assuming psipcfVpsip 5001010002
6
11
, calculate ?2
V
Question 3.2 For an ideal gas reservoir under the isothermal condition as shown in Figure
3.2, use equation (3.40 to calculate the surface volume if we move all of the gas in the
reservoir to the surface.
Figure 3.2 Volumetric Relations
3.1.2 Gas Formation Volume Factor
The gas formation volume factor is used to relate the volume of gas, as measured at reservoir
conditions, to the volume of the gas as measured at standard conditions, i.e., 60F and 14.7
psia. This gas property is then defined as the actual volume occupied by a certain amount of
gas at a specified pressure and temperature, divided by the volume occupied by the same
amount of gas at standard conditions. In an equation form, the relationship is expressed as
Ground Surface
cfV
psip
610
1000
?
7.14
V
psip
Ground Surface
cfV
psip
610
1000
?
7.14
V
psip
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SCg
Tpg
gV
VB
, (3.5)
Applying the real gas equation-of-state gives
p
zT
T
p
p
nRTz
p
nzRT
BSC
SC
SC
SCSC
g (3.6)
Assuming that the standard conditions are represented by psc =14.7psia and Tsc = 520, the
above expression can be reduced to the following relationship:
p
zTBg
02827.0 (3.7)
For an ideal gas, equation (3.7) becomes
p
TBg 02827.0 (3.8)
Under the isothermal condition, the gas formation volume factor is inversely proportional to
pressure as shown in Figure 3.3.
gBgB
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Figure 3.3 Relation between gas formation volume factor and pressure.
3.1.3 Gas Compressibility
Knowledge of the variability of fluid compressibility with pressure and temperature is
essential in performing many reservoir engineering calculations. For a liquid phase, the
compressibility is small and usually assumed to be constant. For a gas phase, the
compressibility is neither small nor constant.
By definition, the isothermal gas compressibility is the change in volume per unit volume for
a unit change in pressure or, in equation form:
p
V
Vc
g
g
g
1 (3.9)
From the real gas equation-of-state:
p
nRTzVp
(3.10)
Differentiating the above equation with respect to pressure gives
2
1
p
z
p
z
pnRT
p
Vp
(3.11)
Substituting (3.6) into (3.4) gives
p
z
zpcg
11 (3.12)
For an ideal gas, z=1 and 0/ pz , therefore,
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pcg
1 (3.13)
3.1.4 Dissolved Gas-Oil Ratio
Dissolved gas-oil ratio is defined as the ratio of surface gas to stock-tank oil in a reservoir
liquid phase at reservoir conditions. The volumes of surface gas and stock-tank oil are those
measured at standard conditions. The dissolved gas-oil ratio, vR is defined as
SCo
SCg
sV
VR (3.14)
For a particular gas and crude oil to exist at a constant temperature, the solubility increases
with pressure until the saturation pressure is reached. At the saturation pressure (bubble-point
pressure) all the available gases are dissolved in the oil and the gas solubility reaches its
maximum value. Rather than measuring the amount of gas that will dissolve in a given
stock-tank crude oil as the pressure is increased, it is customary to determine the amount of
gas that will come out of a sample of reservoir crude oil as pressure decreases.
A typical gas solubility curve, as a function of pressure for an undersaturated crude oil, is
shown in Figure 3.4. As the pressure is reduced from the initial reservoir pressure pi, to the
bubble-point pressure pb, no gas evolves from the oil and consequently the gas solubility
remains constant at its maximum value of Rsb. Below the bubble-point pressure, the solutiongas is liberated and the value of Rs decreases with pressure.
Figure 3.4 Dissolved Gas-Oil Ratio and Pressure Diagram
3.1.5 Volatilized Oil-Gas Ratio
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At pressures below the bubble-point pressure, the oil compressibility is defined as
p
R
B
B
p
B
Bc s
o
go
o
o
1 (3.20)
Note that the first term in Eq (3.20) is negative. The second term is necessary because FVFs
contain the effect of solution gas on the change in liquid volume caused by gas going into
solution as the pressure is increased.
3.3 Water
Similarly, we can define the water formation volume factor as
SCw
Tpw
wV
VB
, (3.21)
3.4 Summary of Single-Phase PVT Properties
Two-Component Model
1. At most, there are two hydrocarbon pseudo-components: surface gas and stock-tank-oil;2. At most, there are two hydrocarbon phases: gas and oil;3. The surface gas pseudo-component is defined by the composition of the gas at standard
conditions;
4. The stock-tank-oil pseudo-component is defined by the composition of the stock-tank oilat standard conditions;
5. The surface gas can partition between the oil and gas phases;6. The stock-tank oil can partition between the oil and the gas phases;7. Thermodynamic equilibrium exists.Assumption 5: The partitioning of surface gas into the oil phase allows for dissolved gas;
Assumption 6: The partitioning of stock-tank oil into gas phase allows for volatilized oil;
Partitioning implicitly exists at all conditions except standard conditions. Standard conditionsto measure a standard cubic food are defined as 14.7psi and 60oF.
The summary of PVT properties definitions is shown in Figure 3.5.
2 5
3
1
gB
3
4vR
3
Gas
Oil
Expanded
gas
5
6
4
Gas
Oil
Expanded
oil
OIL
MoveablePiston
BPpp
1
2
Gas
Oil
BPpp
Reservoir temperature
Surface conditions
22 55
3
1
gB
3
1
gB
3
4vR
3
4vR
3
Gas
Oil
Expanded
gas
3
Gas
Oil
Expanded
gas
5
6
4
Gas
Oil
Expanded
oil
5
6
4
Gas
Oil
Expanded
oil
Expanded
oil
OIL
MoveablePiston
BPpp
OIL
MoveablePiston
BPpp
1
2
Gas
Oil
BPpp
1
2
Gas
Oil
BPpp
Reservoir temperature
Surface conditions
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Figure 3.5: Summary of Gas PVT Properties
3.5 Two-Phase Formation Volume Factors
Two-phase or total formation volume factors are secondary PVT properties. They are strictly a
function of the standard PVT relations ( vsgo RandRBB ,,, ); consequently, they can always be
calculated from the standard PVT.
Two-Phase Oil Formation Volume Factor ( toB ): the total (liquid-phase plus gas-phase)
volume at reservoir conditions divided by its resulting oil-phase volume at standard
conditions.
SCo
Tpgo
toV
VVB
, (3.22)
Figure 3.6: Schematic interpretation of two phase oil formation volume factor.
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Two-Phase Gas Formation Volume Factor ( tgB ): the total (liquid-phase plus gas-phase)
volume at reservoir conditions divided by its resulting gas-phase volume at standard
conditions.
SCo
Tpgo
tg
V
VVB
,
(3.23)
Figure 3.6: Schematic interpretation of two phase gas formation volume factor.
3.6 Relations between Two-Phase and Single-Phase PVT Properties
Consider a reservoir oil sample composed of N surface volumes (e.g. STB) of oil and G
surface volumes (scf) of gas. The two-phase oil FVF is defined as
N
VB totalto (3.24)
Where Vtotal is the total volume (liquid+gas) of the hydrocarbon systems, and is defined as
fgfototal VVV (3.25)
Where Vfo and Vfg are defined as the total volume of the free-oil phase and the total volume
of the free-gas phase, respectively. They are given by
gfgfg
ofofo
BGV
BNV
(3.26)
Where Nfo and Gfg are the surface volume of oil in the free-oil phase and the surface volume
of gas in the free-gas phase.
The total surface volumes of the stock-tank oil and surface gas are
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NNN fgfo (3.27)
GGG fgfo (3.28)
Where
phaseoil-freein thegasof(SCF)volumesurface
phasegas-freein theoilof(STB)volumesurface
fo
fg
G
N
fgN and foG are given by
vfgfg RGN (3.29)
sfofo RNG (3.30)
Solving equations (3.8) through (3.11) gives
GGRRGNR fgsvfgs (3.31)
Solving for Gfg gives
vs
s
fgRR
NRGG
1 (3.32)
Similarly, we can obtain
vs
v
foRR
GRNN
1 (3.33)
We know
fgfo
gfgofofgfototal
toNN
BGBN
N
VV
N
VB
(3.34)
Substituting above equations into (3.34) gives
sv
ssigvsio
toRR
RRBRRBB
1
1 (3.35)
Similarly, we can obtain
G
VB Ttg (3.36)
sv
vviosvig
tg
RR
RRBRRBB
1
1 (3.37)
Equations (3.35) and (3.37) apply to any fluid whose overall composition is defined by a
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gas-oil ratio, siR , or by a oil-gas ratio, viR .
For the special case of a black oil, 0vR , they become
gtg
ssigoto
BB
RRBBB
(3.38)
3.5 Expansivities
The oil-phase expansivity is defined as the total expansion of a unit mass of oil phase between
two pressures at the reservoir temperature, expressed in units of reservoir volume per unit
volume of oil at standard conditions. The two subject pressures are a reference pressure and a
terminal pressure. The terminal pressure is invariably less than the reference pressure, hence
the term expansivity. The reference pressure is usually the initial reservoir pressure. The
expansion volume includes a gas-phase volume if one should emerge from the expanding oil
phase.
The gas expansivity is defined analogously: the total expansion of a unit mass of gas phase
between two pressures at the reservoir temperature, expressed in units of reservoir volume per
unit volume of gas at standard conditions. The expansion volume includes liquid dropout if
such condensation occurs.
itgitgig
itoitoio
pBpBppE
pBpBppE
,
, (3.39)
Example:How to calculate the two-phase formation volume factors.
p (psi) Bg (RB/Mscf) Bo (RB/STB) Rs (scf/STB) Rv (STB/MMscf)
4320 0.83 1.3647 710 23.9
4225 0.845 1.3578 693.5 23
4130 0.86 1.3509 677 22
4030 0.875 1.344 660 21
3930 0.89 1.337 643 20
3830 0.91 1.3301 626 19.1
3730 0.93 1.3232 609 18.2
3630 0.95 1.3164 592 17.3
3530 0.97 1.3095 576 16.4
3800.1
10235.6931
5.69371010845.0102371013578.1
)4225(
3647.1)4320()4320(
1
1
6
36
pB
pBpB
RR
RRBRRBB
to
oto
sv
ssigvsio
to
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3.6 Immaterial Concept
As illustrated in Figure 3.7, we force the two-phase fluid PVT properties to be equal to the
single-phase PVT properties for the single-phase (oil or gas) reservoirs. Assuming an oilreservoir, we define
o
SCo
RCo
SCo
RCtotal
to BV
V
V
VB (3.40)
vgogv
oso
SCg
SCo
SCo
RCo
SCg
RCtotal
tg RBBorBR
BRB
V
V
V
V
V
VB (3.41)
v
sR
R1
(3.42)
Assuming a gas reservoir, we define
g
SCg
RCg
SCg
RCtotal
tg BV
V
V
VB (3.43)
ovgSCoSCg
SCg
RCg
SCo
RCtotal
to BRBV
V
V
V
V
V
B
(3.44)
Figure 3.7 Illustration of immaterial concept
v
sgso
g
SCg
RCtotal
tg
o
SCo
RCtotal
to
RRBRB
BV
VB
BV
VB
1
Above the Bubblepoint:
GAS.asorOILaseithertreatedbecouldRCtotal
VReservoir Oil
Surface Oil
Surface
Gas
v
sgso
g
SCg
RCtotal
tg
o
SCo
RCtotal
to
RRBRB
BV
VB
BV
VB
1
Above the Bubblepoint:
GAS.asorOILaseithertreatedbecouldRCtotal
VReservoir Oil
Surface Oil
Surface
Gas
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CHAPTER 4 GENERALIZED MATERIAL BALANCE EQUATION
LIST OF SYMBOLS
4.1 Generalized Material Balance Equation
Injected
MassOverall
Initially
MassOverall
Produced
MassOverall
Finally
MassOverall
Ground Surface
Total Mass
PressureInitial
productionbefore0
0pp
t
Produced
Mass
Residual
Mass
PressureReservoir
productionDuring
p
t
PressureStandard7.14
productionDuring
psip
t
a
+=
Figure 4.1 Illustration of Mass Balance for a Petroleum Liquid
ratiooilgasSolution
factorvolumeformationOil
ratioproductionoil
-productiongasveAccumulati
factorcompactionformationandWater
factorvolumeformationgasInitial
factorvolumeformationoilInitial
influxNet water
factorexpansionGas
factorexpansionOil
PlaceInGasOriginal
placeingasphase-freeOriginal
PlaceInOilOriginal
placeinphase-freeOriginal
expansionfluidsNet
withdrawndundergrounfluidsNet
so
o
p
fw
gi
oi
g
o
fgi
foi
R
B
N
E
B
B
W
E
E
G
G
N
N
E
F
factorvolumeformationWater
productionWater
InfluxWater
intervalstimeobetween twdifferencepressure
saturationwaterconnateInitialilitycompressibwater
ilitycompressibrockFormation
factorvolumeformationgasphasetwoInital
factorvolumeformationgasphasetwo
factorvolumeformationoilphasetwoInital
factorvolumeformationoilpahseTwo
ratiogasoilvolatileInitial
ratiogasoilVolatile
factorvolumeformationGas
ratiooilgassolutioninitial
w
p
e
wi
w
f
tgi
tg
toi
to
vi
v
g
so i
B
W
W
p
Sc
c
B
B
B
B
R
R
B
R
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Apply this principle to oil, gas and water respectively:
NNRB
SV
B
SVpv
g
gb
o
ob
(4.1)
Ips
o
ob
g
gbGGGR
B
SV
B
SV
(4.2)
Ip
w
wb WWWB
SV
(4.3)
Constraint:
1 wgo SSS (4.4)
Solving equations (4.1) through (4.4) gives
gogo
sv
b
gogo
sv
pI
go
s
p
og
v
pI
BBBB
RRV
BBBB
RRWWW
BB
RNN
BB
RGGG
1
111
(4.5)
We note that the initial pore volume is
oifoigifgiwifoifgifwiib BNBGWBVVVV (4.6)
Where Vfwi, Vfgi and Vfoi are free water- gas- and oil-phase volumes. The pore volume at
any time is defined as
pi
p
oifoigifgiwibV
VBNBGWBV (4.7)
The original surface gas in place is the sum of the resident gas in the free gas and oil phases
sifoifgifoifgi RNGGGG (4.8)
Analogously, the original stock-tank oil in place is
vifgifoifgifoi RGNNNN (4.9)
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wIp
sv
sgo
p
sv
vog
Ip
pi
p
wiw
sv
vog
si
pi
p
oi
sv
sgo
foi
sv
sgo
vi
pi
p
gi
sv
vog
fgi
BWWRR
RBBN
RR
RBBGG
V
VBBW
RR
RBBR
V
VB
RR
RBBN
RR
RBBR
V
VB
RR
RBBG
11
11
11
(4.10)
The next step is to eliminate the pore volume and replace certain terms with their
expansivities. The rock expansivity is defined as
f
pi
p
pi
ppif E
V
V
V
VVE
1 (4.11)
The gas, oil and water expansivities are defined by
tgitgg BBE (4.12)
toitoo BBE (4.13)
wiww BBE (4.14)
Solving equations (10) to (14) gives
WIpsv
sgo
p
sv
vog
Ip
efpiwofoigfgi
BWWRR
RBBN
RR
RBBGG
WEVWEENEG
11
(4.15)
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Figure 4.2: Volumetric Interpretation of General Material Balance Equation
Equation (4.15) applies to the full range of reservoir fluids. Substituting the following
relations
wwipi BSVW / (4.16)
oifoigifgiwipi BNBGWBV (4.17)
Into equation (4.15) gives
WIpsv
sgo
p
sv
vog
Ipeowffoigwffgi BWWRR
RBBN
RR
RBBGGWENEG
11 (4.18)
Where
f
wi
wwi
wi
oi
oowf EB
ES
S
BEE
1 (4.19)
f
wi
wwi
wi
gi
ggwf EB
ES
S
BEE
1 (4.20)
The water and rock expansivities can be replaced by compressibilities. Water and rock
compressibilities are defined as
pB
BpVV
VVc w
w
scww
scww
w
1//1 (4.21)
INITIAL PRESSURE LOWER PRESSURE
InitialVolume
Produced
Volume
Expanded
Volume
INITIAL PRESSURE LOWER PRESSURE
InitialVolume
Produced
Volume
Expanded
Volume
INITIAL PRESSURE LOWER PRESSURE
InitialVolume
Produced
Volume
Expanded
Volume
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p
E
pV
VV
p
V
Vc
f
f
ffif
f
f
11 (4.22)
pcE ff (4.23)
pcBE wwiw (4.24)
Substituting equations (4.23) and (4.24) into (4.19) and (4.20) gives
fwoioToioowf EBEpcBEE (4.25)
fwgigTgiggwf EBEpcBEE (4.26)
Where
pS
Scc
pcEwi
wiwf
Tfw
1 (4.27)
The generalized MBE can be further simplified as
EF (4.28)
Where
eowffoigwffgi WENEGE (4.29)
WIp
sv
sgo
p
sv
vog
ps BWWRR
RBBN
RR
RBBGF
11
(4.30)
And
Ipps GGG (4.31)
4.2 MBE APPLICATIONS
The MBE can be used to
Estimate the original oil and gas in place (OOIP and OGIP); Estimate the gas-cap size; Estimate water influx; Estimate water influx model parameters; Estimate geophysical parameters;
Confirm producing mechanisms.
The application forms may be different for different reservoir types. In the following, we
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present some general principles.
Definitive Tool or Diagnostic Tool: The simplest form of MBE can be written as
EF (4.32)
where, F and E are the hydrocarbon production and the reservoir expansion in volume. If thematerial is fully balanced, F vs. E is a straight line; if the material is NOT fully balanced, F vs.
E is a curve, as illustrated in Figure 4.2.
Figure 4.3: Illustration of Material Balance and Imbalance.
We write the material balance equation as
eowffoigwffgiWIp
sv
sgo
p
sv
vog
ps WENEGBWWRR
RBBN
RR
RBBGEF
11(4.33)
When the material is balanced,
0EF (4.33)
Equation (4.34) can be used to solve only for one unknown. If eW or fwE are not known
and are dropped off from the equation, equation (4.33) becomes
0EF (4.34)
If the water production data are not available and are dropped off from the MBE, equation
(4.34) becomes
0EF (4.35)
F
E
BALANCE
IMBALANCE
F
E
BALANCE
IMBALANCE
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Figure 4.4: MBE can be used either as a definitive tool or as a diagnostic tool.
Recovery Ratios:Oil and gas recoveries as a fraction of the original amount in place can be
solved from the material balance equation. Dividing equation (18) byfoiN gives
sv
spsgpsvo
foi
gwffgi
owf
foi
ewpI
foi
p
RR
RRBRRB
N
EGE
N
WBWW
N
N
1
1 (4.36)
Where, psR , is defined as the cumulative produced sales gas-oil ratio,
p
Ip
p
ps
ps
N
GG
N
GR
(4.37)
When 0IG , equation (4.37) becomes
p
p
p
p
pN
G
N
GR (4.38)
In practice, we calculate the fraction of the total OOIP recovered. The oil recovery fraction
and gas recovery fraction are defined as
N
NF
p
o (4.49)
F
E
0
11
eowffoigwffgi
WIp
sv
sgo
p
sv
vog
ps
WENEG
BWWRR
RBB
NRR
RBB
GEF
0
11
eowffoigwffgi
sv
sgo
p
sv
vog
ps
WENEG
RR
RBBN
RR
RBBGEF
0
11
ofoigfgi
WIp
sv
sgo
p
sv
vog
ps
ENEG
BWWRR
RBBN
RR
RBBGEF
F
E
F
E
0
11
eowffoigwffgi
WIp
sv
sgo
p
sv
vog
ps
WENEG
BWWRR
RBB
NRR
RBB
GEF
0
11
eowffoigwffgi
sv
sgo
p
sv
vog
ps
WENEG
RR
RBBN
RR
RBBGEF
0
11
ofoigfgi
WIp
sv
sgo
p
sv
vog
ps
ENEG
BWWRR
RBBN
RR
RBBGEF
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G
GF
p
g (4.50)
respectively.
Drive Indices: We write the general material balance equation as
sv
sgo
p
sv
vog
Ip
WIpefwoifoigifgiofoigfgi
RR
RBBN
RR
RBBGG
BWWWEBNBGENEG
11
(4.51)
We define
WIpefwoifoigifgiofoigfgit BWWWEBNBGENEGE
Dividing each term in Equation (4.51) by tE gives
1 wdcdodgd IIII (4.52)
IndexDriveWater
IndexDriveCompaction
IndexDriveExpansionOil
IndexDriveExpansionGas
t
wIpe
wd
t
fwoifoigifgi
cd
t
ofoi
od
t
gfgi
gd
E
BWWWI
E
EBNBGI
E
ENI
E
EGI
(4.53)
These drive indices provide a convenient means to rank the different producing mechanisms.
They change with time. For example, the gas drive may dominate early in the life of a
reservoir while the water drive dominates later after water influx commences.
Calculation of Saturations:The oil saturation at any time can be obtained
sgo
pp
vog
vpp
ow
o
RBBN
N
G
GBBB
N
G
RPG
G
G
N
NBS
S
11
111
(4.54)
At the initial condition: 0 pp GN , equation (4.54) becomes
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sigioivioigi
voiwi
oi
RBBBBBN
G
RP
GBS
S
11
(4.55)
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CHAPTER 5 DRY-GAS RESERVOIRS
A reservoir that produces only gas and no appreciable hydrocarbon liquids is called a dry-gasreservoir. Dry-gas reservoir is the simplest type to evaluate. Gas reservoirs often have high
recovery factors irrespective of the drive mechanism. Recovery factors of more than 80% are
not uncommon, and can even be found in volumetric reservoirs. Natural gas is very
compressible and has a very low viscosity, and both factors contribute to the high recovery
factor.
The recovery factor is lower in waterdrive gas reservoirs primarily because waterdrive leaves
behind a residual gas saturation that is unrecoverable. This residual gas saturation is usually at
high pressure. The residual gas saturation at high pressure has a large volume of gas
compressed into a small space. In heterogeneous waterdrive reservoirs, water tends to flow
along the high permeability streaks, bypassing gas that gets trapped in low permeability areas.This becomes a severe problem if the reservoir is highly fractured and has a strong waterdrive.
The waterdrive flushes the gas out of the fractures and bypasses the great majority of the gas
contained in the matrix.
Figure 5.1: P-T Diagram of A Typical Reservoir Fluid
5.1 Volumetrics and Recovery Factors
0 50 100 150 200 250 300 350
Reservoir Temperature, oF
4000
3500
3000
2500
2000
1500
1000
ReservoirPressure,
psi
A
A2
B2
B1
B
B3
A1
C1
C
D
0%
20%
10%5%
80%40%
Bubb
lePo
int
Critical
PointDewPoint
Bubble Point or
Dissolved Gas
Reservoir
Dew Point or Retrograde
GasCondensate
Reservoir
Single-phase Gas
Reservoir
PathofReservoirFluid
Cricondentherm
Path
ofPr
od
ucti
on
Wet-andDry-GasReservoirs
0 50 100 150 200 250 300 350
Reservoir Temperature, oF
4000
3500
3000
2500
2000
1500
1000
ReservoirPressure,
psi
A
A2
B2
B1
B
B3
A1
C1
C
D
0%
20%
10%5%
80%40%
Bubb
lePo
int
Critical
PointDewPoint
Bubble Point or
Dissolved Gas
Reservoir
Dew Point or Retrograde
GasCondensate
Reservoir
Single-phase Gas
Reservoir
PathofReservoirFluid
Cricondentherm
Path
ofPr
od
ucti
on
0 50 100 150 200 250 300 350
Reservoir Temperature, oF
4000
3500
3000
2500
2000
1500
1000
ReservoirPressure,
psi
A
A2
B2
B1
B
B3
A1
C1
C
D
0%
20%
10%5%
80%40%
Bubb
lePo
int
Critical
PointDewPoint
Bubble Point or
Dissolved Gas
Reservoir
Dew Point or Retrograde
GasCondensate
Reservoir
Single-phase Gas
Reservoir
PathofReservoirFluid
Cricondentherm
Path
ofPr
od
ucti
on
Wet-andDry-GasReservoirs
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The OGIP (original gas in place) can be determined by
gi
wi
B
SAhG
1 (5.1)
Where
SaturationWaterInitial
FactorVolumeFormationGasInitial
HeightReservoir
AreaReservoir
PlaceInGasOriginal
wi
gi
S
B
h
A
G
At the abandonment pressure, the remaining gas is calculated as
ga
gr
aB
SAhG
(5.2)
PressuretAbandonmenat theSaturationGas
PressuretAbandonmenat theFactorVolumeFormationGas
PressuretAbandonmenat thePlaceInGas
gr
ga
a
S
B
G
Recovery factor is defined as
wiga
grgia
RSB
SB
G
GGF
11 (5.3)
If the reservoir is homogeneous and volumetric (no waterdrive), 0wiS and 1grS ,
equation (5.3) can be simplified as
ga
gia
RB
B
G
GGF
1 (5.4)
5.2 MBE Analysis
Two conditions:
0
0
vvi
foi
RR
N (5.5)
General Material Balance Equation
eowffoigwffgi WENEGE (5.6)
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WIp
sv
sgo
p
sv
vog
ps BWWRR
RBBN
RR
RBBGF
11
(5.7)
pS
SccpcE
NW
wi
wiwf
Tfw
foi
e
1
00
fwoioToioowf EBEpcBEE (5.8)
fwgigTgiggwf EBEpcBEE
Substituting equation (5.8) into (5.6) and (5.7) gives
fwgifgigfgi EBGEGE (5.9)
gpBGF (5.10)
If 0fwE , substituting gigg BBE into (5.9) gives
gigfgigp BBGBG (5.11)
Equation (5.11) is the equation most commonly used to analyze the normal volumetric gas
reservoirs.
5.3 P-Z Plot
We note
sc
sc
gpT
zTpB (5.12)
Substituting (5.12) into (5.11) gives
sci
sci
sc
sc
fgi
sc
scp
TpTpz
pTzTpG
pTzTpG (5.13)
fgi
p
i
i
i
i
G
G
z
p
z
p
z
p (5.14)
Use MBE as a Diagnostic Tool
efwgigfgi WEBEGF (5.15)
fwgig
e
fgi
fwgig EBEWG
EBEF
(5.16)
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Overpressured Gas Reservoir: 0fwE
Example 1:A volumetric dry-gas reservoir with an initial pressure of 3000 psi (zi=0.912) and
formation temperature 190F has produced 384MMscf of gas, and the pressure has dropped to
2,876 psi (z=0.907). Determine the original gas in place (OGIP) by material balance.
Solution:The material balance equation for this problem is
p
fgii
i
i
i GGz
p
z
p
z
p
Wherep
G is the accumulative gas production. Rearranging Equation above gives
Bscf
scfzppz
GG
ii
p
fgi
7.10
10652.10907.03000/912.028761
10384
/19
6
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Example 2
A volumetric dry-gas reservoir has the measured production and pressures given below
P(psi) Gp(MMscf) z
3000 0 0.912
2876 384 0.9072824 550 0.905
2755 788 0.903
2688 1002 0.902
2570 1445 0.901
2435 1899 0.900
2226 2670 0.901
2122 3113 0.903
1866 3982 0.905
Determine the OGIP from appropriate material balance plots.
Solution:
The material balance equation can be written as
gigfgigp BBGBG (E2.1)
Alternatively,
p
fgii
i
i
i GGz
p
z
p
z
p (E2.2)
We can use both equations to solve for Gfgi.
Method 1: p/z plot
y = -0.3063x + 3290.1
R2= 0.9998
0
500
1000
1500
2000
2500
3000
3500
0 1000 2000 3000 4000
Accumulative Gas Production, Gp
p/z,psi
y = -0.3063x + 3290.1
R2= 0.9998
0
500
1000
1500
2000
2500
3000
3500
0 1000 2000 3000 4000
Accumulative Gas Production, Gp
p/z,psi
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From the plot, Gfgi=10.74MMscf.
Method 2: GpBg versus Eg plot.
005586.0460603000
7.14460190912.0
sc
sc
gpT
zTpB
Example 3:
If we do not know if there is a waterdrive, we can use the material balance equation as a
diagnostic tool. The material balance equation for a waterdrive gas reservoir can be written as
g
fgi
g
gp
g
gfgigp
E
WGE
BG
E
F
WEGBGF
The graph verifies the volumetric nature of the gas reservoir.
Bg-Bgi=Eg
GpBg
y = 10740x
R2= 0.9998
0
5
10
15
20
25
30
35
40
0 0.001 0.002 0.003 0.004
9000
9500
10000
10500
11000
11500
12000
0 1000 2000 3000 4000 5000
gE
F
pG
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CHAPTER 6 GAS/CONDENSATE RESERVOIRS
When a gas reservoir produces significant quantities of liquids along with the gas, it is called
a wet-gas or retrograde condensate reservoir. A wet-gas reservoir can be produced
volumetrically, like a dry-gas reservoir, but the liquids are an added valuable product. In
analyzing and managing such reservoirs, h