Alkali-Chlorine / Sulfur Balance

BalanceP R O G R A M for A L K A L I - S U L F U R - B A L A N C EThis program shall serve the CONSULTANT and the GROUP PLANTS to assess the situation regarding Alkali, Sulfur and Chlorine.Throughout the program the following conventions have been used for data input and illustration:Input data fieldInput field for data which are not directly required for the Alkali - Cl - Sulfur - BalanceA cell containing a red point in it's upper right corner contains a short note giving a hint, remark or explanation to the user.The note becomes visible by selecting "Tools / Options / View / Comment & Indicator"Cell containing a resultLanguage Option:only english availableFor description, instructions and application of the program see report TPT 01/21130/EDatabase for this program template:PT Procedures\.\Alk-SO3-Cl Balance v2.02.xlsDatabase for the description and instruction:PT Procedures\.\Manual Alk-SO3-Cl Balance 21-12-2001.docResponsible for any program updates:Christian EngmannUpdate history:Sheet "Update"This version is dated:Version 2.1, January 2003HGRS/CEN-03ALKALI - CHLORINE - SULFUR - BALANCEExamplePlantDateTimePlantSP/PC Kiln ExampleDateTimeKilnType, makeHeat consumptionkJ/kg cliKilnType, makeHeat consumption3500kJ/kg cliLengthmThermal load (BZ)0.0MW/m2Clinker productiont/dKiln SystemA/Smax SO3max relevant ClLength80mThermal load (BZ)6.3MW/m2Clinker production2126t/dDiameter (BZ)mLength of fix coatingm0.0t/hPreheater / PC kiln0.8 - 1.2< 1.5< 300 (no Cl valve)Diameter (BZ)4.6mLength of fix coatingm88.6t/hHolcim Group SupportCoolerType, makeL coating / kiln diam.:0-grate preheater> 0.8< 1.2< 300 (no Cl valve)CoolerType, makeL coating / kiln diam.:0-Cleaning methodObser-O2 kiln inlet%long dry kiln> 0.8< 1.2< 300 (no Cl valve)Cleaning methodObser-O2 kiln inlet%frequencyvationsO2 PH outlet%wet kiln> 0.8< 1.2< 300 (no Cl valve)frequencyvationsO2 PH outlet%1HGRS criteria for Preheater / PC kiln :0.8 - 1.2< 1.5< 300 (no Cl valve)Fuels (sulfur input)Emission at main stack (including bypass stack)0Fuels (sulfur input)Emission at main stack (including bypass stack)Fuel typeCVSFinenessRateHeatSO2-Emission (sulfur output)HCl-Emission (chlorine output)FuelFuel typeFuel typeCVSFinenessRateHeatSO2-Emission (sulfur output)HCl-Emission (chlorine output)[kJ/kg][ % ][% 90mm][t/h][ % ]O2, at SO2 measurement%O2O2, at HCl measurement%O2GJ/h[kJ/kg][ % ][% 90mm][t/h][ % ]O2, at SO2 measurement10%O2O2, at HCl measurement10%O2Main firing0Dry exh.gas at 0.0%O20.280Nm3/kg cliDry exh.gas at 0.0%O20.280Nm3/kg cli0.000.00Main firingCoal/Petcoke305291.510.26Dry exh.gas at 10.0%O20.280Nm3/kg cliDry exh.gas at 10.0%O20.280Nm3/kg cli0SO2 dryppmHCl dryppm0.000.000000SO2 dry20ppmHCl dry2ppm0SO20mg /Nm3HCl0mg /Nm30.000.000000SO257mg /Nm3HCl3mg /Nm300mg/kg cli0mg/kg cli0.000.00000016mg/kg cli1mg/kg cliSec. Firing or PC00.0kg SO2/h0.0kg HCl/h0.000.00Sec. Firing or PC00001.4kg SO2/h0.1kg HCl/h0SO30mg/kg cliCl0mg/kg cli0.000.00SO320mg/kg cliCl1mg/kg cli0SO3cli basis0.000%Clcli basis0.000%0.000.00SO3cli basis0.002%Clcli basis0.000%00.000.00Calculated specific fuel cons. (from above data)0kJ/kg0.00TotalCalculated specific fuel cons. (from above data)00.0000.0kJ/kgBalanceMassflowSO3K2ONa2ONa2OequivClA/SMass BalanceBalanceMassflowSO3K2ONa2ONa2OequivClA/SMass Balanceratecli basisconc.cli basisconc.cli basisconc.cli basiscli basisconc.cli basisLOIcli basisratecli basisconc.cli basisconc.cli basisconc.cli basiscli basisconc.cli basisLOIcli basis[t/h][t/t cli][ % ][ % ][ % ][ % ][ % ][ % ][ % ][ % ][ % ][ - ][%][t/h][t/h][t/t cli][ % ][ % ][ % ][ % ][ % ][ % ][ % ][ % ][ % ][ - ][%][t/h]INPUT1Kiln Feed (dry) as fed00000000INPUT1Kiln Feed (dry) as fed152.7500.0400.4500.12000.0230035.898.12000000000200000000000000030.0000000000003Coal/Petcoke10.2603.75000.000.0000.050092.20.80.0000000000000.00000000000000000.0000000000000.00000000000000000.0000000000000.00000000000000000.0000000000000.00000000000000000.0000000000000.0000000000000.0000000000000.0000000000000.0000000000000.000000000000TOTAL INPUT0000000TOTAL INPUT00000098.9OUTPUT4Clinker000000000OUTPUT4Clinker88.5800.4300.6400.2000.01000.488.25Bypass dust removed from kiln000000005Bypass dust removed from kiln000000000000006aDust (main filter) returned via kiln feed000000006Dust (main filter) retured via kiln feed14.9800.4500.8400.16000.190036.99.57Dust (main filter) removed from kiln000000007Dust (main filter) removed from kiln1.4200.4500.8400.16000.190036.90.98Emission--0------0---8Emission--0.002------0.0001---TOTAL OUTPUT0000000TOTAL OUTPUT0.0020000.0001-0.04998.6Diff.Input - output0.0000.0000.0000.0000.0000.00Diff.Input - output-0.0020.0000.0000.000-0.0000.29in % of input0.00.00.00.00.00.0in % of input0.00.00.00.00.00.30(red values: estimated figures)0(red values: estimated figures)Hot mealMassflowSO3K2ONa2ONa2OequivClA/SMass BalanceHot mealMassflowSO3K2ONa2ONa2OequivClA/SMass Balanceconc.Limitsconc.conc.conc.Limitsconc.LimitsLOICalcinationconc.Limitsconc.conc.conc.Limitsconc.LimitsLOICalcination[%][%][%][%][%][%][%][%][%][%][%][%][%][%][%][%][%][%][%][%]Mix right + left-0---Mix right + left2.21-4.860.533.729-1.24-25.3--0.000----0.000---Average0000000Average2.214.860.533.7291.240100.0Applicable Balance Boundary for all Kiln Types:

&L&8&F&C&8HGRS/CTS/TPT&R&8&DExample of a noteMenu: Format --> Sheet --> Unhide to view the latest changes

EvaluationEVALUATION of ALKALI - CHLORINE - SULFUR - BALANCE- The following section is only applicable if the balance boundary as shown on the balance sheet is used (balance boundary excluding outer dust cycle).- For additional information and explanations see 'Manual Alk/SO3/Cl - Balance"Main Results:HGRS criteria for Preheater / PC kiln :1. "Calculated" Cl in clinker*/**:n/ag/t cli< 200-300 for all kilns2. Actual Sulfur in clinker:n/a%SO3cli< 1.53. Alk/SO3 ratio in clinker:n/a-0.8 - 1.24. "Relevant" Cl input***:n/ag/t cli< 300 (no Cl valve)05. Sulfur Volatility0.00-