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THE RE C STATE O CYCLING EU Chaired by OF THE A G AND TR T UROPEAN y: A.F. CO G. La V RT OF A RANSFOR (CO2 Tuesday N PARLIA ORREIA DE VIA, MEP, PROMIS RMING H 2) INTO F 22 nd Ma AMENT, B E CAMPOS STOA Pan SING TEC HARMFU FUELS arch 2011 BRUSSEL S – MEP, S nel Membe CHNOLOG L CARBO 1 LS, Belgiu STOA Vice er GY AIME ON DIOXI um ePresiden D AT IDE nt

CO2-A Future Chemical Fuel

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Page 1: CO2-A Future Chemical Fuel

 

THE RE

 C

STATE OCYCLING

EU

Chaired by

OF THE AG AND TR

TUROPEAN

y:  A.F. COG. La V

RT OF A RANSFOR

(CO2

Tuesday N PARLIA

ORREIA DEVIA, MEP, 

 

                            

  

PROMISRMING H2) INTO F

 22nd MaAMENT, B

E CAMPOSSTOA Pan

SING TECHARMFUFUELS 

arch 2011BRUSSEL

S – MEP, Snel Membe

CHNOLOGL CARBO

1  LS, Belgiu

STOA Viceer 

GY AIMEON DIOXI

um 

e‐Presiden

D AT IDE 

nt 

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COSTOA

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STOAA Worksh 

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hop - CO22: a Futurre Chemical Fuel

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STO

13.30

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ation and S

me AddressF. Correia dP. M. Siffert

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an ResearcW. Raldow, L. Mennickeutilization asD. Clodic, Eon CO2 captF. Santana, R&D policies

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tor: R. Link

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tions for E

R. Martins: J.R. Morant

remarks: G

STO2: a Fut

de Campa Via, ME

arliamen2nd Marc

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PROGRA

Security Ch

ses de Campost, Secretary

enges and ux, Universi

experienceone, DoE, A

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ch InitiativeEuropean

en, BMBF: s raw materENSMP / CEture and conFTUNL, Po

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cussion wit

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dustry: nella, Deche– Chemical Per, Rhodia Cy: B. Loeffleustry: C. HaSupplier: J

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uropean R

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STOA W

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Chaired pos, MEP

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nt, Rue Wh 2011, 1

oom ASP

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heck

s, MEP, STOy General E

Perspectivity Pierre an

e: Advanced Rese Academ

es in the EnCommissioGermany: R

rial EA: Policy onversion ortugal: Con

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rkshophemicaby P, STOAA Panel M

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STOAA Worksh 

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hop - CO22: a Futurre Chemical Fuel

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LIST JacquAMO

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rue Pierre et Curie PARIS cedexnce

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ny

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h 10 61 08,Ratingen-Germany

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51 92 49 19 45 02 odic@mines

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3 40 48 cenzo@europ

37 60 42 desnost@eu.

Chemica

@gmail.com

ademe.fr

ma.de

on.com

d.de

e.de

enscp.fr

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STOAA Worksh 

6  

Laurent

Robert G

Claude H

Holger H

Zinfer IS

Istvan KA

Shunsuk

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Tatjana

AnathasKONSTALOS

hop - CO2

FORTI

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EMANN

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CO2 HeadResponsibCement&HLiants CTGItalcement Evonik Ind

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EMPA MatScience &TechnoloDept EnvirEnergy&MLaboratoryHydrogen Energy LaboratoireMatériaux,Procédés pCatalyse, UMR/CNRUniversity Strasbourg ProjektträgDeutschenZentrumfürRaumfahrtelt, Kultur, Nachhaltig Head of theand ParticlTechnologUniversity Thessalon

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BP. 311, 92MalmaisonFrance 52 rue La H93306 AubFrance Les Techno01 78931 GueFrance

HandelsstrRue du Co1000 BrussBelgium 18, Pr. SovKEMEROV650099, Ru

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Danie

Giova

Jean

Raffa

Jörg

Rolf L

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Juan MOR

ela KRUSE

anni LA VIA

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ger Str.100, Paderborn, ny rt, Germany

nengasse 12asel, land

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STOAA Worksh 

8  

Pierre O

FrancescPRIOLO

Wiktor R

Thomas

Jose MaROQUE

Martin ROTHAE

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FernandPires SA

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Page 13: CO2-A Future Chemical Fuel

 

HiroaTAKA

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STOAA Worksh 

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hop - CO22: a Futurre Chemical Fuel

Page 15: CO2-A Future Chemical Fuel

 

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as publishede has allowon businessgo into une

Chemica

19 

n mid of uction of d by the wed the s. expected

al Fuel 

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CARA SU

PER

JacqProc(LGP(ENSFran

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IOXIDE: AABLE DEV

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OUROUX, eering and Sle Nationaleersité Pierre

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ch results of

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nits are procome necese steps: coquate locatio

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A NEW M

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Professor aSurface Tree Supérieure et Marie C

SCP/UPMCGeneral of th

f the interna

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g, Russia atory StratPiversity, Japermany, Am

of the conceed the Euro

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ogrammed, ssary for a nllect the COons and pum

ing consistsCHEMICAL EW INDUST

ces are engwho ask for

ty and to home equip

STOA W

MATERIA

ENT ‐ CH

and Directoratment Labre de ChimiCurie (UPMC

C LGPPTS –he Europea

ational team

e PMC Mexicoectrotechnic

Polytechnicapan

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with a unit noticeable rO2 as closemp it in the

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AL FOR EN

HALLENG

r Plasma boratory e de Paris C), Paris,

– EMRS an Material R

ms of

o c and Elect

al University

th Africa

f CO2 in theament and

he ground (0 and 2008-

price of appresult. The

e as possibsoil.

ering CO2 hich can brope.

hat proposamission payinnovative rge Olaf ( N

p - CO2: a

NERGY S

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y of St Pete

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(more detai-01; PE 416

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as a RAWbe used as

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Nobel Price

a Future

STORAGE

Society (EM

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ere, and theean Commiils in many 6.243).

EUR. Later,CS model f

ource, trans

W MATERIAs energy

E. Stieglitzrder to incre

by investin chemist

Chemica

21 

E AND 

RS)

echnical

ssia

e related ission to reports,

, several foresees sfer it by

AL which source,

z (Nobel ease the ment in ry 1994)

al Fuel 

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STOAA Worksh 

22  

who proenergy Taking Steven wind tuenergy the carb In orderesearcBayer, KodackThe goatechnolohouse gcompet

hop - CO2

opose a suand chemic

into accouE. Koonimrbine, geottransportat

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hat we haacademic onmens and coa),Japand understanrder to reduon in agreend create jo

re Chemi

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declarations to storageergy) into cgulation of tthe key of h

ve to devenes as it st10 academ

n (Mitsui chending of ecuce our deement with obs which a

cal Fuel

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n of the see non carbcarbonatedthe electrica

humanity de

elop Europtarts in Ger

mic laboratoemical),Chinconomical aependence

the EEC rre not able

cycle or a c

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regulations to be deloc

carbon diox

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STOA WWorkshopp - CO2: aa Future Chemica

23 

al Fuel 

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STOA W

Workshopp - CO2: aa Future Chemica

25 

al Fuel 

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STOA WWorkshopp - CO2: aa Future Chemica

27 

al Fuel 

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THE CO2ACT EricEner

Eric AgenAgenrewathe ecaptuE EautotAnne Carboxidaoxidiconvbiodifeedsthe Ucomp 

E INTERN

2 : A FUTUTIVITIES IN

c TOONE, rgy US Dep

Toone is ncy – Enerncy, foundeard technoloelectrificatioure, and adlectrofuels trophic appe T. and Ro

bon, in its ration, or buzed carbon

verted to fueiesel, and ostock for thUnited Statpatible liqui

NATIONA

URE CHEMN THE UN

DoE, Advaartment of E

the Deputyrgy (ARPA-ed in 2007 ogy developon of transpdvanced bio

Programmproaches toobert M. Bas

reduced fourning. Th

n – CO2 – inels, either g

other produche productiotes focussed fuels.

AL EXPER

MICAL FUEITED STA

anced ResEnergy. WA

y Director fo-E), a newand funded

pment acrosportation anofuels. Dr. Tme, designeo the produss Professo

rms, serveshroughout hnto reducedgeologicallycts. Viewedon of liquid ed on the c

STOA W

RIENCE: U

EL ATES

search ProjASHINGTO

or Technolow agency od for the fiss the ener

nd the deploToone served to devection of ad

or of Chemis

s as a carhistory, pla forms and

y to oil and d as a carriefuels. This

conversion

Workshop

USA 

jects AgenON, USA

ogy at the of the US rst time in rgy landscaoyment of res as Progelop high dvanced biostry at Duke

rrier for eneants have u

store themgas, or thr

er for energs talk will hof CO2 to

p - CO2: a

ncy

Advanced Departmen2009, supp

ape, includinrenewablesramme Direefficiency

ofuels. Dr. e University

ergy that isused sunlig as sugars.rough fermegy, carbon bighlight somenergy de

a Future

Research t of Energports high ng storage , efficiencyector for thenon-photosToone is

y, in Durham

s released ght to conv. Those sugentation to becomes a vme of the anse, infrast

Chemica

29 

Projects y. The risk/high for both , carbon e ARPA-synthetic also the

m, NC.

through vert fully gars are ethanol, valuable ctivity in tructure-

al Fuel 

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STOA WWorkshopp - CO2: aa Future Chemica

31 

al Fuel 

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THE CO2INDO re XianChem

Prof.Chinfocus110 devehas abun AbstThe matepetromatepetro

E INTERN

2: EMERGDUSTRY esources

nhong WANmistry, Chin

Xianhong ese Acadesing on fixapublication

eloped rare been comm

ndant fuel m

tract of thetalk summa

erial, trying ochemical inerial betweeoleum.

NATIONA

GING FU: China’ss

NG, Professnese Acade

Wang receemy of Scieation of CO2

ns, and maearth terna

mercialized material.

e upcomingarizes the vto elucidat

ndustry, coen plastics

AL EXPER

UEL IN PEs effort i

sor, Changcmy of Scien

eived Ph. Dences (CA

2 into biodegain inventory catalyst fin China,

g talk in STvarious actte that CO2

vering fromand rubbe

STOA W

RIENCE: C

ETROCHEn turnin

chun Institutnces

D. degree oS) in Dec.gradable plar of 4 USfor fixation creating ne

TOA tivities carri2 is an abu

m monomer er), to basic

Workshop

CHINA

EMICAL g CO2 as

te of Applie

of Polymer 1993. Sinastics, he is patents aof CO2 intoew possibil

ed out in Cndant and for plastics

c chemicals

p - CO2: a

s C and

d

r Chemistrynce then hs the main aand 30 Ch biodegradality for CO2

China concecheap raw

s and elastos, as well a

a Future

 

y and Physe worked author of minese Pateable plastic2 to be che

erning CO2

material oomer (an imas fuel add

Chemica

33 

ics from in CAS, ore than

ents. He cs, which eap and

2 as fuel or fuel in mportant ditives in

al Fuel 

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35 

al Fuel 

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EURSUP

AND Wikt

ROPEAN

PPORTED

D NEW F

tor RALDO

 RESEAR

D RESEAR

FUELS 

OW, Europ

RCH INITI

RCH & D

pean Comm

STOA W

ATIVES I

DEMONST

mission, EU

Workshop

IN THE E

TRATION

U R&D pro

p - CO2: a

NERGY S

N ACTIVIT

ogrammes

a Future

SECTOR: TIES IN C

Chemica

37 

EU‐CCS 

al Fuel 

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GERON  LothInter

The of gr(baseappr In or(BMBprogNatioclimaframe“TecCO2”utilizfuelsSixtebeen

RMAN INI

CO2 UTI

har MENNrnational B

German Fereenhouse ge year 199oximately h

rder to achieBF) provideramme "Reonal Sustaiate protectework proghnologies fo”. This fundation of ca

s through eeen large con launched,

ITIATIVE: ILIZATION

ICKEN, PDBureau (IB)

ederal Govegas emissio90 resp. 1

half of prima

eve these ges more thaesearch foinability Strtion, energgramme theor Sustaina

ding activityrbon dioxidenhanced collaborativeseveral mo

RESEARC

N AS RAW

D Dr. Seni) of the BM

ernment haons by 40 %994). By 2

ary energy c

goals, the Gan two billior Sustainarategy and gy and ree BMBF pubability and C (up to 100

de as carbochemical ree R&D projeore are in pr

STOA W

CH FUNDI

W MATERIA

or ScientifMBF at the

s set ambit%, doubling2050, reneconsumptio

German Fedon Euros (2ble Develothe Nation

source effblished a fi

Climate Prot0 million Euon source foeactions anects (industreparation.

Workshop

NG PROG

AL 

ic OfficerDLR, Germ

tious goals of energy

ewable enen.

deral Minist010-2015)

opments" tonal High-Teficiency anve year-restection – Ch

uros) is dedor polymersnd energy try and aca

p - CO2: a

GRAMME 

many

for the yeaand raw ma

ergies are

try of Educafor R&D wi

o consistenech Strategnd sustainasearch fundhemical Proicated to sus, base andefficient ch

ademia toge

a Future

r 2020: a reaterials prointended t

ation and Rithin the frantly implemgy in the aability. Undding activityocesses andupport R&Dd fine chemhemical proether) have

Chemica

39 

eduction oductivity to cover

Research amework ment the areas of der this

y entitled d Use of D for the micals or ocesses.

already

al Fuel 

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POLSAC DenParisCEP

D. C

CO2 procpuritnitropurit Amothat polyparaener(Unirecoare bact

LICY OF TH

CLAY ON C

is CLODICsTech – A

P, France

Clodic, P. M

capture  pcesses.   Thety  (higher ogen.  Aminty and CEP

ong the CO2use  CO2 carbonatesallel  to  CO2rgy  cost, versity  Pagnized  comalso  comperia.  Last, 

HE RESEA

CO2 CAP

C, EmerituRMINES -

Millet, J-M

processes e most adathan  99.5

nes or anti‐P Mines‐Par

2 valorisatieither  as s or for car2  purificatusing  maaris‐Sud  1mpetenciespetent  in  cRhodia Com

ARCH CLU

PTURE AN

s ResearcCentre for

M Agator, E

are  assocpted captu5%)  provi‐sublimatiorisTech wo

on optionsa  raw  m

rbon sourceion,  the  keainly  hydr11,  CEA…)s  on  photocatalysis. mpany is co

STOA W

STER CLAND CONVE

ch Director,r Energy a

ENSMP / C

ciated  in ure processded  the  ron technolorks since m

s, the CLAIRaterial  fore for liquidey  issue  isogen  com)  campus o‐electro‐caCEA  incluompetent b

Workshop

AIRE OF ERSION

, Mines nd Proces

CEA, Sacla

CLAIRE  Ises are thosesidual  0.5ogies are thmore than 1

RE IEED ser  organic  sd fuels suchs  to  generming  from laboratoriatalysis.   Odes  a  laboboth in cata

p - CO2: a

ses –

ay, France

IEED  withse capable 5%  is  maihe most pro10 years on

elects regensynthetic h as ethanorate  hydrogbio‐meth

ies  possesOther  Parisoratory  woalysis and o

a Future

h  CO2  conto reach hinly  compone to matcn those issu

neration strproducts  sol and methgen  at  acchane.  Parisss  internasTech  laboorking  on organic syn

Chemica

41 

nversion high CO2 osed  of ch those ues.   

rategies such  as hanol. In ceptable s‐Saclay ationally ratories Cyano‐

nthesis. 

al Fuel 

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STOA WWorkshopp - CO2: aa Future Chemica

43 

al Fuel 

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RO

Mod

PAN

Techchem AlexProje

The indusinnovStorafrom uncepathsprovivalueObjechem

E

Inre

U

D

P

D Sinceseveand

UND TAB

derator: Ro

NELLISTS:

hnologies mical proc

xis BAZZAect Coordi

motivation stry on mvative efficiage (CCS) a

coal-basedertainties sus for carbonides an attre products.

ectives of thmical produc

Examining a

nvolving preaction par

Using CO2 a

Developing

Photoelectro

Developmen

e the progreral more aacademic p

BLE DISC

olf LINKO

 

 for sustaincesses and 

ANELLA, Dnation Ger

of the progitigation mency technare pursuedd power plauch as safen dioxide mractive cont e funding pcts are:

and develop

revious andrtners for CO

as a compo

alternative

ochemical/p

nt of robust

ramme starare in prepapartners wo

CUSSION 

HR, forme

nability an use of CO2

Dr, DECHErmany

gramme is beasures fo

nologies is d as a transants. Howeety issues amanagement

tribution in

programme

ping possibl

d subsequeO2)

nent for rea

syntheses w

photocatalyt

catalysts us

rt, sixteen caration. Theorking on a

STOA W

WITH M

r MEP

nd climate2 

EMA, e.V,

based on aor climate a major lev

sition technoever, the imand generalt are of highthis contex

in the area

e methods

ent steps (e

active interm

with CO2 as

tic productio

sing impure

collaborativee collaboravariety of t

Workshop

MEPS AN

 protectio

Research

a large natiochange. R

verage. In aology to avomplementatl societal ah importancxt, as it ena

of use of C

for activatin

e.g. intellige

mediate pro

s carbon co

on of hydrog

e CO2

e research tive researctarget prod

p - CO2: a

ND PART

n – 

and

onal consulReducing Caddition, Caoid CO2 emion of CCScceptance. ce. Chemicaables econo

CO2 as a car

ng CO2

ent product

ducts

mponent

gen for con

projects hach projectsucts includ

a Future

TICIPANT

ltation proceCO2 emissarbon Captissions in p

S is hamperHence, alt

al utilizationomic routes

rbon compo

tion of high

nversion with

ave been las comprise ing polyme

Chemica

45 

TS

ess with sions by ture and

particular red from ternative n of CO2 s to high

onent for

h energy

h CO2

aunched, industry rs, base

al Fuel 

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STOAA Worksh 

46  

and fineinclude some oindustryexhaustenergy chemica

hop - CO2

e chemicalsthe investi

of the projey and aim at gases forsuppliers

al industry c

2: a Futur

s. A numbegation of th

ects facilitaat demonstrr the targeseek custocan valorise

re Chemi

r of projectshe CO2 foo

ate collaborration plantseted chemicomers for te CO2 as a

cal Fuel

s in preparaotprint of thrations betws, which inccal processthe CO2 cacheap and

ation expliche developeween energclude the usses. This oaptured froabundantly

citly target fued processegy supplierse of CO2 fropens up vm their po

y available r

uels. All proes. Remarkrs and cherom Power value chainower plantsraw materia

ojects kably, mical plant

ns as s and al.

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CO2  RobDire

The chemenergmainCO2

- -

-

The vusingpeakconv(Win PilotHydr

- - -

And A strCO2

 valorizati

bert GRESctor, Aube

increasing mical and egetic produ

nly for chem valorisation

PolycarboConversio

decarboMicro-alga

seem the

valorisationg the CO2 ak oil). In averting CO2d, Nuclear…

t or semrogenation)

New catalAccess to Technical

finally, deta

rong collabo valorisation

ion: a new

SER, Dr., ervilliers, Fr

pressure tonergy indus

ucts, re-usinmical synthen leading to

onate pilot aon into Metnated Hydroae, converse most econ

n of CO2 is after sequeddition, the

2 into liquid…) vs the co

mi-industrialbut key tecytic system low cost debreakthrou

ailed LCA as

oration betwn and it cou

w opportun

Rhodia, Brrance

o mitigate tstry, create

ng CO2 as aesis or for o industrial d

and pre-induhanol, Dimogen produ

sion of CO2 nomically p

creating a nestration, ane grid equid chemical onsumption

projects chnical hurd

ms to activatecarbonatedugh to improssessments

ween acadeuld be cataly

STOA W

nity for a su

reakthroug

the GHG a an opportua source ofenhanced deployment

ustrial plantsethyl ether

uced with reinto biomasromising te

new industrnd could eveilibrium coufuel using

n.

are devdles remain e CO2 d Hydrogen

ove existings of the “avo

emia and inyzed by Eur

Workshop

ustainable

gh Innovati

nd the neeunity for a nf Carbon. Toil recoveryt within the

s already exfor chemic

enewable enss for chemchnology

ry, which is entually repuld be impH2 produce

veloping (and need R

n processesoided CO2”

ndustry is thropean larg

p - CO2: a

e industry 

ion

ed of non-fonew industroday 150My. The mainext 10 yea

xist cal or energnergies or n

micals and b

complemenplace Petrocproved by ced with the

(PolycarbonR&D and de

(Micro-alga” should be

he key for tge scale pro

a Future

 

ossil carbonry of Chem

MT of CO2 an developm

ars are:

getic produnuclear planbiofuel. Ope

ntary to CCchemistry (acreating ca

e excess of

nate, Micremonstratio

ae) performed

the developogrammes.

Chemica

47 

n for the mical and are used ments of

ucts with nts en ponds

CS by re-after the apacities f energy

ro-algae, on units:

pment of

al Fuel 

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49 

al Fuel 

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50  

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CO2  Clau

Preshas cemetranslimesto theannufrom EngalargeincluemisstocknaturenergtransR&Dbeco

: a future c

ude HAEHN

ent in 22 coa consolidaent processsformation stone in lime consulting

ual world wicement pro

aged in a Se R&D progding biolog

ssions. Arouks like metral photosygy storag

sformations D programmome a scien

 chemical f

NEL, Dr., CO

ountries, Itaated annuas involving cof limesto

me the manug firm “McKde anthropoduction is Sustainablerammes an

gical and cund the wothanol, ure

ynthesis, it ie, especiof CO2 app

mes that Euntific, technic

 fuel 

O2 head se

alcementi gl productioncombustion

one and clufacturing o

Kinsey”, the ogenic CO2equal to 79

e Developmnd collaborachemical traorld, CO2 isea, carboxys today cleally, renepear as prourope shoucal and eco

STOA W

ector, CTG –

roup is the n capacity of fossil fue

lay in cemof cement pworldwide

2 emissions0 kgCO2 / t

ment proactiations in ordansformatios already uylic acids, pear that COwable ene

omising valold greatly s

onomic lead

Workshop

– Italcemen

world’s fifthof approximels to provid

ment and produces alcement ind

s and the gtcement (20ive policy,

der to assesons of the used for thepolycarbona

O2could be ergy. Che

orisation wasupport. W

der within fu

p - CO2: a

nti, France

h largest cemately 70 mde heat powassociated so CO2 em

dustry genelobal avera005). Italcementi

ss best waylatter, in o

e productioates… Duealso studie

emical andays but reque believe tture huge C

a Future

ement produmillion tons.wer required

decarbonamissions. Acrates aroun

age carbon

group mays of CO2 reorder to redn of chemie its majord as a newd electroc

uire today athat EuropeCO2 market

Chemica

51 

ucer and . Due to d for the ation of ccording nd 4% of intensity

nages a ecycling, duce its cal feed r role in w way of chemical mbitious e should ts.

al Fuel 

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CO2  JoséBrus

 emission 

é ROQUE, sels, Belgiu

 abatemen

Petrogal-Pum, Oil and

nt: one oil&

Petróleos deGas Suppl

STOA W

&gas indus

e Portugal ier

Workshop

stry point 

S.A., GAL

p - CO2: a

 of view 

LP Energia,

a Future

Chemica

53 

al Fuel 

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Carb  AthaTechCER

bon neutra

anasios G. hnology Lab

RTH/CPERI,

al solar fue

KONSTANboratory at C, Aristotle U

els 

NDOPOULOCentre of R

University of

STOA W

OS, Head ofResearch & Tf Thessalon

Workshop

f the AerosoTechnologyiki, Greece

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MATERIALS 67037 STR

33 3 88 10 65-mail: emrs@

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