CHM626_L19_defects2

Embed Size (px)

Citation preview

  • 8/18/2019 CHM626_L19_defects2

    1/12

    Graphite Diamond

    Scientific Reports 3, doi:10.1038/srep01331

    Reconstructive

  • 8/18/2019 CHM626_L19_defects2

    2/12

    Graphite Diamond

     Z.Anorg. Allg. Chem. 2014, 681–688

  • 8/18/2019 CHM626_L19_defects2

    3/12

    Graphite Diamond

    SCIENTIFIC REPORTS DOI: 10.1038/srep05930

    AB

    A

    B

    A

    B

    C

    A

  • 8/18/2019 CHM626_L19_defects2

    4/12

    Carbon allotropes

  • 8/18/2019 CHM626_L19_defects2

    5/12

    SiO2: 

    alpha-quartz 

    cristobalite 

    Displacive

  • 8/18/2019 CHM626_L19_defects2

    6/12

    Bi2O3: Displacive

    PHYSICAL REVIEW B 83, 214102 (2011)

  • 8/18/2019 CHM626_L19_defects2

    7/12

    Group-subgroup relations

    P31cTrigonal

    P63mcHexagonal

  • 8/18/2019 CHM626_L19_defects2

    8/12

    Group-subgroup

    relations

  • 8/18/2019 CHM626_L19_defects2

    9/12

  • 8/18/2019 CHM626_L19_defects2

    10/12

    Dialation

    [NaCl] [CsCl]

    T/GPa

  • 8/18/2019 CHM626_L19_defects2

    11/12

    NaCl---> CsCl transformation 

    B1; α=60 B2; α=90

  • 8/18/2019 CHM626_L19_defects2

    12/12

    Order-disorder transition

    The atoms are distributed at random