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  • The Chemistry Maths Book

    Second Edition

    Erich SteinerUniversity of Exeter

    without mathematics the sciences cannot be understood, normade clear, nor taught, nor learned.

    (Roger Bacon, 12141292)

    1

  • 3Great Clarendon Street, Oxford OX2 6DP

    Oxford University Press is a department of the University of Oxford.It furthers the Universitys objective of excellence in research, scholarship,and education by publishing worldwide in

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    Oxford is a registered trade mark of Oxford University Pressin the UK and in certain other countries

    Published in the United Statesby Oxford University Press Inc., New York

    E. Steiner 2008

    The moral rights of the authors have been assertedDatabase right Oxford University Press (maker)

    First published 1996 Second edition published 2008

    All rights reserved. No part of this publication may be reproduced,stored in a retrieval system, or transmitted, in any form or by any means,without the prior permission in writing of Oxford University Press,or as expressly permitted by law, or under terms agreed with the appropriatereprographics rights organization. Enquiries concerning reproductionoutside the scope of the above should be sent to the Rights Department,Oxford University Press, at the address above

    You must not circulate this book in any other binding or coverand you must impose the same condition on any acquirer

    British Library Cataloguing in Publication Data

    Data available

    Library of Congress Cataloging in Publication Data

    Data available

    Typeset by Graphicraft Limited, Hong KongPrinted in Great Britain on acid-free paper by Ashford Colour Press Ltd, Gosport, Hampshire

    ISBN 9780199205356

    1 3 5 7 9 10 8 6 4 2

  • Preface

    This book describes the mathematics required for the full range of topics that make upa university degree course in chemistry. It has been designed as a textbook for coursesin mathematics for chemists.

    Structure of the book

    The subject is developed in a logical and consistent way with few assumptions made of prior knowledge of mathematics. The material is organized in three largelyindependent parts: Chapters 1 to 15 on algebra, the calculus, differential equations,and expansions in series; Chapters 16 to 19 on vectors, determinants, and matrices;Chapters 20 and 21 are introductions to the big topics of numerical analysis andstatistics.

    A feature of the book is the extensive use of examples to illustrate every importantconcept and method in the text. Some of these examples have also been used todemonstrate applications of the mathematics in chemistry and several basic conceptsin physics. The exercises at the end of each chapter are an essential element of thedevelopment of the subject, and have been designed to give the student a workingunderstanding of the material in the text. The text is accompanied by a footnote history of mathematics.

    Several topics in chemistry are given extended treatments. These include the concept of pressurevolume work in thermodynamics in Chapter 5, periodic systemsin Chapter 8, the differential equations of chemical kinetics in Chapter 11, and severalapplications of the Schrdinger equation in Chapters 12 and 14. In addition, the contents of several chapters are largely dictated by their applications in the physical sciences: Chapter 9, the mathematics of thermodynamics; Chapters 10 and 16, thedescription of systems and processes in three dimensions; Chapter 13 (advanced),some important differential equations and special functions in mathematical chemistryand physics; Chapter 15 (advanced), intermolecular forces, wave analysis, and Fouriertransform spectroscopy; Chapters 18 and 19, molecular symmetry and symmetryoperations, molecular orbital theory, molecular dynamics, and advanced quantummechanics.

    Global changes in this edition

    1. An overall reorganization has been carried out to link the text and examples moreclosely to the exercises at the end of each chapter. The symbol 0 has been placed atappropriate places within the body of the text as a pointer to the relevant exercises.New examples and exercises have been inserted to give a more complete coverageof the development of the mathematics.

    2. In addition to the solutions to the numerical exercises given at the back of thebook, a full set of worked solutions of the end-of-chapter exercises has been placedon the books companion website at www.oxfordtextbooks.co.uk/orc/steiner2e

    3. The opportunity has been taken to consolidate the several major and many minorcorrections and improvements that have been made over the years since publicationof the rst edition in 1996. A small number of new historical footnotes have been

  • vi Preface

    added to accompany new material. The material within some chapters has beenreordered to make the development of the subject more logical.

    Other principal changes

    Chapter 1. A new section, Factorization, factors, and factorials, lls a gap in the coverageof elementary topics. The rules of precedence for arithmetic operations has beenbrought forward from chapter 2 and extended with examples and exercises, providing further revision and practice of the arithmetic that is so important for the understanding of the material in subsequent chapters. The biggest change inthe chapter, reected in the change of title to Numbers, variables, and units, is arewritten and much enlarged section on units to make it a more authoritative anduseful account of this important but often neglected topic. It includes new examplesof the type met in the physical sciences, a brief subsection on dimensional analysis,and a new example and exercise on the structure of atomic units.

    Chapter 2. Parts of the chapter have been rewritten to accommodate more discussionof the factorization and manipulation of algebraic expressions.

    Chapter 7. Numerous small changes have been made, including an introduction tothe multinomial expansion, and revision of the discussion of the Taylor series.

    Chapter 9. Section 9.8 has been rewritten to clarify the relevance of line integrals tochange of state in thermodynamics.

    Chapter 13. The section on the Frobenius method has been revised, with new andmore demanding examples and exercises.

    Chapter 19. Sections 19.2 and 19.3 on eigenvalues and eigenvectors have been rewritten, with new examples and exercises, to improve the ow and clarity of thediscussion.

    Acknowledgements

    I wish to express my gratitude to colleagues and students at Exeter University and otherinstitutions for their often helpful comments on the previous edition of the book, forpointing out errors and obscurities, and for their suggestions for improvements. Iparticularly want to thank Anthony Legon for his valuable comments on the revisedchapters 1 and 9.

    I also wish to thank the reviewers of this book for their generous response to theproposal of a second edition, and the staff of Oxford University Press for theirpatience and help.

    Above all, I want to thank my wife Mary, without whom nothing could have beendone.

    Erich Steiner, Exeter, June 2007

  • Contents

    1 Numbers, variables, and units 11.1 Concepts 1

    1.2 Real numbers 3

    1.3 Factorization, factors, and factorials 7

    1.4 Decimal representation of numbers 9

    1.5 Variables 13

    1.6 The algebra of real numbers 14

    1.7 Complex numbers 19

    1.8 Units 19

    1.9 Exercises 29

    2 Algebraic functions 312.1 Concepts 31

    2.2 Graphical representation of functions 32

    2.3 Factorization and simplication of expressions 34

    2.4 Inverse functions 37

    2.5 Polynomials 40

    2.6 Rational functions 50

    2.7 Partial fractions 52

    2.8 Solution of simultaneous equations 55

    2.9 Exercises 58

    3 Transcendental functions 623.1 Concepts 62

    3.2 Trigonometric functions 63

    3.3 Inverse trigonometric functions 72

    3.4 Trigonometric relations 73

    3.5 Polar coordinates 77

    3.6 The exponential function 80

    3.7 The logarithmic function 83

    3.8 Values of exponential and logarithmic functions 86

    3.9 Hyperbolic functions 87

    3.10 Exercises 89

    4 Differentiation 934.1 Concepts 93

    4.2 The process of differentiation 94

    4.3 Continuity 97

    4.4 Limits 98

    4.5 Differentiation from rst principles 100

    4.6 Differentiation by rule 102

    4.7 Implicit functions 110

  • viii Contents

    4.8 Logarithmic differentiation 111

    4.9 Successive differentiation 113

    4.10 Stationary points 114

    4.11 Linear and angular motion 118

    4.12 The differential 119

    4.13 Exercises 122

    5 Integration 1265.1 Concepts 126

    5.2 The indenite integral 127

    5.3 The denite integral 132

    5.4 The integral calculus 142

    5.5 Uses of the integral calculus 147

    5.6 Static properties of matter 148

    5.7 Dynamics 152

    5.8 Pressurevolume work 157

    5.9 Exercises 160

    6 Methods of integration 1636.1 Concepts 163

    6.2 The use of trigonometric relations 163

    6.3 The method of substitution 165

    6.4 Integration by parts 173

    6.5 Reduction formulas 176

    6.6 Rational integrands. The method of partial fractions 179

    6.7 Parametric differentiation of integrals 184

    6.8 Exercises 187

    7 Sequences and series 1917.1 Concepts 191

    7.2 Sequences 191

    7.3 Finite series 196

    7.4 Innite series 203

    7.5 Tests of convergence 204

    7.6 MacLaurin and Taylor series 208

    7.7 Approximate values and limits 214

    7.8 Operations with power series 219

    7.9 Exercises 221

    8 Complex numbers 2258.1 Concepts 225

    8.2 Algebra of complex numbers 226

    8.3 Graphical representation 228

    8.4 Complex functions 235

    8.5 Eulers formula 236

    8.6 Periodicity 240

  • Contents ix

    8.7 Evaluation of integrals 244

    8.8 Exercises 245

    9 Functions of several variables 2479.1 Concepts 247

    9.2 Graphical representation 248

    9.3 Partial differentiation 249

    9.4 Stationary points 253

    9.5 The total differential 258

    9.6 Some differential properties 262

    9.7 Exact differentials 272

    9.8 Line integrals 275

    9.9 Multiple integrals 281

    9.10 The double integral 283

    9.11 Change of variables 285

    9.12 Exercises 289

    10 Functions in 3 dimensions 29410.1 Concepts 294

    10.2 Spherical polar coordinates 294

    10.3 Functions of position 296

    10.4 Volume integrals 299

    10.5 The Laplacian operator 304

    10.6 Other coordinate systems 307

    10.7 Exercises 312

    11 First-order differential equations 31411.1 Concepts 314

    11.2 Solution of a differential equation 315

    11.3 Separable equations 318

    11.4 Separable equations in chemical kinetics 322

    11.5 First-order linear equations 328

    11.6 An example of linear equations in chemical kinetics 330

    11.7 Electric circuits 332

    11.8 Exercises 334

    12 Second-order differential equations. Constant coefcients 33712.1 Concepts 337

    12.2 Homogeneous linear equations 337

    12.3 The general solution 340

    12.4 Particular solutions 344

    12.5 The harmonic oscillator 348

    12.6 The particle in a one-dimensional box 352

    12.7 The particle in a ring 356

    12.8 Inhomogeneous linear equations 359

    12.9 Forced oscillations 363

    12.10 Exercises 365

  • x Contents

    13 Second-order differential equations. Some special functions 36813.1 Concepts 368

    13.2 The power-series method 369

    13.3 The Frobenius method 371

    13.4 The Legendre equation 375

    13.5 The Hermite equation 381

    13.6 The Laguerre equation 384

    13.7 Bessel functions 385

    13.8 Exercises 389

    14 Partial differential equations 39114.1 Concepts 391

    14.2 General solutions 392

    14.3 Separation of variables 393

    14.4 The particle in a rectangular box 395

    14.5 The particle in a circular box 398

    14.6 The hydrogen atom 401

    14.7 The vibrating string 410

    14.8 Exercises 413

    15 Orthogonal expansions. Fourier analysis 41615.1 Concepts 416

    15.2 Orthogonal expansions 416

    15.3 Two expansions in Legendre polynomials 421

    15.4 Fourier series 425

    15.5 The vibrating string 432

    15.6 Fourier transforms 433

    15.7 Exercises 441

    16 Vectors 44416.1 Concepts 444

    16.2 Vector algebra 445

    16.3 Components of vectors 448

    16.4 Scalar differentiation of a vector 453

    16.5 The scalar (dot) product 456

    16.6 The vector (cross) product 462

    16.7 Scalar and vector elds 466

    16.8 The gradient of a scalar eld 467

    16.9 Divergence and curl of a vector eld 469

    16.10 Vector spaces 471

    16.11 Exercises 471

    17 Determinants 47417.1 Concepts 474

    17.2 Determinants of order 3 476

    17.3 The general case 481

  • Contents xi

    17.4 The solution of linear equations 483

    17.5 Properties of determinants 488

    17.6 Reduction to triangular form 493

    17.7 Alternating functions 494

    17.8 Exercises 496

    18 Matrices and linear transformations 49918.1 Concepts 499

    18.2 Some special matrices 502

    18.3 Matrix algebra 505

    18.4 The inverse matrix 513

    18.5 Linear transformations 516

    18.6 Orthogonal matrices and orthogonal transformations 521

    18.7 Symmetry operations 524

    18.8 Exercises 529

    19 The matrix eigenvalue problem 53219.1 Concepts 532

    19.2 The eigenvalue problem 534

    19.3 Properties of the eigenvectors 537

    19.4 Matrix diagonalization 543

    19.5 Quadratic forms 546

    19.6 Complex matrices 551

    19.7 Exercises 555

    20 Numerical methods 55820.1 Concepts 558

    20.2 Errors 558

    20.3 Solution of ordinary equations 562

    20.4 Interpolation 566

    20.5 Numerical integration 573

    20.6 Methods in linear algebra 581

    20.7 Gauss elimination for the solution of linear equations 581

    20.8 GaussJordan elimination for the inverse of a matrix 584

    20.9 First-order differential equations 585

    20.10 Systems of differential equations 590

    20.11 Exercises 592

    21 Probability and statistics 59521.1 Concepts 595

    21.2 Descriptive statistics 595

    21.3 Frequency and probability 601

    21.4 Combinations of probabilities 603

    21.5 The binomial distribution 604

    21.6 Permutations and combinations 607

    21.7 Continuous distributions 613

    21.8 The Gaussian distribution 615

  • xii Contents

    21.9 More than one variable 618

    21.10 Least squares 619

    21.11 Sample statistics 623

    21.12 Exercises 624

    Appendix. Standard integrals 627

    Solutions to exercises 631

    Index 653

  • 1 Numbers, variables, and units

    1.1 Concepts

    Chemistry, in common with the other physical sciences, comprises

    (i) experiment: the observation of physical phenomena and the measurement ofphysical quantities, and

    (ii) theory: the interpretation of the results of experiment, the correlation of one setof measurements with other sets of measurements, the discovery and applicationof rules to rationalize and interpret these correlations.

    Both experiment and theory involve the manipulation of numbers and of the symbolsthat are used to represent numbers and physical quantities. Equations containingthese symbols provide relations amongst physical quantities. Examples of such equations are

    1. the equation of state of the ideal gas

    pV = nRT (1.1)

    2. Braggs Law in the theory of crystal structure

    n1= 2d1sin1 (1.2)3. the Arrhenius equation for the temperature dependence of rate of reaction

    (1.3)

    4. the Nernst equation for the emf of an electrochemical cell

    (1.4)

    When an equation involves physical quantities, the expressions on the two sides of theequal sign1 must be of the same kind as well as the same magnitude.

    E ERTnF

    Q= o ln

    k AeE RT

    = a /

    1 The sign for equality was introduced by Robert Recorde (c. 15101558) in his The whetstone of witte (London,1557); I will sette as I doe often in woorke use, a paire of paralleles, or Gemowe (twin) lines of one lengthe, thus:, bicause noe.2. thynges can be moare equalle.

  • 2 Chapter 1 Numbers, variables, and units

    EXAMPLE 1.1 The equation of state of the ideal gas, (1.1), can be written as anequation for the volume,

    in which the physical quantities on the right of the equal sign are the pressure p of the gas, the temperature T, the amount of substance n, and the molar gas constantR = 8.31447 J K1 mol1.

    We suppose that we have one tenth of a mole of gas, n1=10.1 mol, at temperature T1=1298 K and pressure p1=1105 Pa. Then

    The quantities on the right side of the equation have been expressed in terms of SIunits (see Section 1.8), and the combination of these units is the SI unit of volume, m3

    (see Example 1.17).

    Example 1.1 demonstrates a number of concepts:

    (i) Function. Given any particular set of values of the pressure p, temperature T,and amount of substance n, equation (1.1) allows us to calculate the corresponding volume V. The value of V is determined by the values of p, T, and n; we say

    V is a function of p, T, and n.

    This statement is usually expressed in mathematics as

    V1=1f ( p, T, n)and means that, for given values of p, T and n, the value of V is given by the value of afunction f ( p, T, n). In the present case, the function is f (p, T, n)1=1nRT2p. A slightlydifferent form, often used in the sciences, is

    V1=1V( p, T, n)which means that V is some function of p, T and n, which may or may not be known.

    Algebraic functions are discussed in Chapter 2. Transcendental functions, includingthe trigonometric, exponential and logarithmic functions in equations (1.2) to (1.4),are discussed in Chapter 3.

    = . 2 478 10 3 3 m

    =

    . .

    0 1 8 31447 298

    105

    1 1mol J K mol KPa

    VnRT

    p= =

    . . 0 1 8 31447 298

    10

    1 1

    5

    mol J K mol K

    Pa

    V

    nRTp

    =

  • 1.2 Real numbers 3

    (ii) Constant and variable. Equation (1.1) contains two types of quantity:

    Constant: a quantity whose value is xed for the present purposes. The quantity R1=18.31447 J K1 mol1 is a constant physical quantity.2 A constant number is anyparticular number; for example, a1=10.1 and 1=13.14159=Variable: a quantity that can have any value of a given set of allowed values. The quantities p, T, and n are the variables of the function f( p, T, n)1=1nRT2p.

    Two types of variable can be distinguished. An independent variable is one whosevalue does not depend on the value of any other variable. When equation (1.1) is written in the form V1=1nRT2p, it is implied that the independent variables are p, T,and n. The quantity V is then the dependent variable because its value depends on thevalues of the independent variables. We could have chosen the dependent variable to be T and the independent variables as p, V, and n; that is, T =1pV2nR. In practice, the choice of independent variables is often one of mathematical convenience, but itmay also be determined by the conditions of an experiment; it is sometimes easier to measure pressure p, temperature T, and amount of substance n, and to calculate Vfrom them.

    Numbers are discussed in Sections 1.2 to 1.4, and variables in Section 1.5. The algebra of numbers (arithmetic) is discussed in Section 1.6.

    (iii) A physical quantity is always the product of two quantities, a number and a unit;for example T1=1298.15 K or R1=18.31447 J K1 mol1. In applications of mathematicsin the sciences, numbers by themselves have no meaning unless the units of thephysical quantities are specied. It is important to know what these units are, but themathematics does not depend on them. Units are discussed in Section 1.8.

    1.2 Real numbers

    The concept of number, and of counting, is learnt very early in life, and nearly everymeasurement in the physical world involves numbers and counting in some way. Thesimplest numbers are the natural numbers, the whole numbers or signless integers1,12,13,1= It is easily veried that the addition or multiplication of two natural numbers always gives a natural number, whereas subtraction and division may not.For example 51131=12, but 5116 is not a natural number. A set of numbers for whichthe operation of subtraction is always valid is the set of integers, consisting of all positive and negative whole numbers, and zero:

    - 3 2 1 0 +1 +2 +3 - The operations of addition and subtraction of both positive and negative integers aremade possible by the rules

    m1+1(n)1=1m11nm11(n)1=1m1+1n (1.5)

    2 The values of the fundamental physical constants are under continual review. For the latest recommendedvalues, see the NIST (National Institute of Standards and Technology) website at www.physics.nist.gov

  • 4 Chapter 1 Numbers, variables, and units

    so that, for example, the subtraction of a negative number is equivalent to the additionof the corresponding positive number. The operation of multiplication is madepossible by the rules

    (m)11(n)1=1+(m11n)(m)11(+n)1=1(m11n) (1.6)

    Similarly for division. Note that m1=1(1)11m.EXAMPLES 1.2 Addition and multiplication of negative numbers

    21+1(3)1=121131=11 211(3)1=121+131=15(2)11(3)1=121131=16 (2)11(3)1=121131=16(6)11(3)1=161131=12 611(3)1=161131=12

    0 Exercises 17In equations (1.5) and (1.6) the letters m and n are symbols used to represent any pair ofintegers; they are integer variables, whose values belong to the (innite) set of integers.

    Division of one integer by another does not always give an integer; for example 61131=12, but 6114 is not an integer. A set of numbers for which the operation of division is always valid is the set of rational numbers, consisting of all the numbersm2n1=1m11n where m and n are integers (m2n, read as m over n, is the more commonly used notation for m divided by n). The denition excludes the case n1=10because division by zero is not dened (see Section 1.6), but integers are includedbecause an integer m can be written as m21. The rules for the combination of rationalnumbers (and of fractions in general) are

    (1.7)

    (1.8)

    (1.9)

    where, for example, mq means m11q.

    EXAMPLES 1.3 Addition of fractions

    (1) Add and .14

    12

    mn

    pq

    mn

    qp

    mqnp

    = =

    mn

    pq

    mpnq

    =

    mn

    pq

    mq npnq

    + =+

  • 1.2 Real numbers 5

    The number one half is equal to two quarters and can be added to one quarter togive three quarters:

    The value of a fraction like 122 is unchanged if the numerator and the denominatorare both multiplied by the same number:

    and the general method of adding fractions is (a) nd a common denominator forthe fractions to be added, (b) express all the fractions in terms of this commondenominator, (c) add.

    (2) Add and .

    A common denominator is 31151=115. Then

    (3) Add and .

    A common denominator is 41161=124, but the lowest (smallest) common denominator is 12:

    0 Exercises 813EXAMPLE 1.4 Multiplication of fractions

    This can be interpreted as taking two thirds of 425 (or four fths of 223).0 Exercises 1417

    23

    45

    2 43 5

    815

    =

    =

    14

    56

    312

    1012

    1312

    + = + =

    56

    14

    23

    45

    2 53 5

    3 43 5

    1015

    1215

    10 1215

    2215

    + =

    +

    = + =

    +=

    45

    23

    12

    1 22 2

    24

    =

    =

    12

    14

    24

    14

    34

    + = + =

  • 6 Chapter 1 Numbers, variables, and units

    EXAMPLE 1.5 Division of fractions

    The number 10212 can be simplied by dividing top and bottom by the commonfactor 2: 102121=1526 (see Section 1.3).0 Exercises 1821

    Every rational number is the solution of a linear equation

    mx1=1n (1.10)where m and n are integers; for example, 3x1=12 has solution x1=1223. Not all numbersare rational however. One solution of the quadratic equation

    x21=12is , the positive square root of 2 (the other solution is ), and this numbercannot be written as a rational number m2n; it is called an irrational number. Other irrational numbers are obtained as solutions of the more general quadraticequation

    ax21+1bx1+1c1=10where a, b, and c are arbitrary integers, and of higher-order algebraic equations; forexample, a solution of the cubic equation

    x31=12is , the cube root of 2. Irrational numbers like and are called surds.

    The rational and irrational numbers obtained as solutions of algebraic equationsof type

    a01+1a1x1+1a2x21+1a3x31+1-1+1anxn1=10 (1.11)where a0, a1, =, an are integers, are called algebraic numbers; these numbers canbe expressed exactly in terms of a nite number of rational numbers and surds. There exist also other numbers that are not algebraic; they are not obtained as solutions of any nite algebraic equation. These numbers are irrational numbers called transcendental numbers; they transcend the power of algebraic methods

    232x = 23

    2x = 2

    23

    45

    23

    54

    1012

    = =

  • 1.3 Factorization, factors, and factorials 7

    (Euler).3 The best known and most important of these are the Euler number e and theArchimedean number .4 These are discussed in Section 1.4.

    The rational and irrational numbers form the continuum of numbers; togetherthey are called the real numbers.

    1.3 Factorization, factors, and factorials

    Factorization is the decomposition of a number (or other quantity) into a product ofother numbers (quantities), or factors; for example

    301=12113115shows the decomposition of the natural number 30 into a product of prime numbers;that is, natural numbers that cannot be factorized further (the number 1 is not countedas a prime number). The fundamental theorem of arithmetic is that every naturalnumber can be factorized as a product of prime numbers in only one way.5

    EXAMPLES 1.6 Prime number factorization

    (1) 41=121121=122(2) 121=121121131=122113(3) 3151=131131151171=132115117(4) 51201=121121121121121121121121121121151=1210115

    0 Exercises 2225

    Factorization and cancellation of common factors can be used for the simplicationof fractions. For example, in

    1242

    6 26 7

    27

    =

    =

    3 Leonhard Euler (17071783). Born in Switzerland, he worked most of his life in St Petersburg and in Berlin. One of the worlds most prolic mathematicians, he wrote voluminous papers and huge textbooks. He contributed to nearly all branches of mathematics and its application to physical problems, including the calculus, differential equations, innite series, complex functions, mechanics, and hydrodynamics, and his nameis associated with many theorems and formulas. One of his important, if unspectacular, contributions was to mathematical notation. He introduced the symbol e, gave the trigonometric functions their modern denition,and by his use of the symbols sin, cos, i, and made them universally accepted.

    4 The symbol was rst used by William Jones (16751749) in a textbook on mathematics, Synopsis palmariorum matheseos (A new introduction to the mathematics) in 1706. Eulers adoption of the symbol ensuredits acceptance.

    5 A version of the fundamental theorem of arithmetic is given by Propositions 31 and 32 in Book VII of EuclidsStoichia (Elements). Euclid was one of the rst teachers at the Museum and Library of Alexandria founded byPtolemy I in about 300 BC after he had gained control of Egypt when Alexanders empire broke up in 323 BC.

  • 8 Chapter 1 Numbers, variables, and units

    cancellation of the common factor 6 is equivalent to dividing both numerator anddenominator by 6, and such an operation does not change the value of the fraction.

    EXAMPLES 1.7 Simplication of fractions

    (1)

    (2)

    (3)

    0 Exercises 2629

    In general, the purpose of factorization is to express a quantity in terms of simplerquantities (see Section 2.3 for factorization of algebraic expressions).

    Factorials

    The factorial of n is the number whose factors are the rst n natural numbers:

    n!1=1111211311-11n(1.12)

    =1n11(n111)11(n112)11-112111(read as n factorial). Consecutive factorials are related by the recurrence relation

    (n1+11)!1=1(n1+11)11n!for example, 3!1=131121111=16 and 4!1=141131121111=14113!1=124. In addition, the factorial of zero is dened as 0!1=11.

    EXAMPLES 1.8 Factorials

    (1) 1!1=11110!1=111111=11(2) 5!1=15114!1=15114113!1=15114113112!1=151141131121=1120(3)

    (4)

    0 Exercises 3036

    73 4

    7 6 5 43 2 4

    7 5 35!

    ! !!

    !=

    = =

    53

    5 4 33

    5 4 20!!

    !!

    =

    = =

    1051470

    3 5 7

    2 3 5 7

    12 7

    1142

    =

    =

    =

    1525

    3 5

    5

    352

    =

    =

    424

    2

    2 3

    2 22 2 2 3

    16

    2

    3=

    =

    =

  • 1.4 Decimal representation of numbers 9

    1.4 Decimal representation of numbers

    These are the nine gures of the Indians

    9 8 7 6 5 4 3 2 1

    With these nine gures, and with this sign 0 which in Arabic iscalled zephirum, any number can be written, as will below bedemonstrated.

    (Fibonacci)6

    In the decimal system of numbers, the ten digit symbols 0 to 9 (Hindu-Arabic numerals)7

    are used for zero and the rst nine positive integers; the tenth positive integer is denotedby 10. A larger integer, such as three hundred and seventy-two is expressed in the form

    3001+1701+121=13111021+1711101+12and is denoted by the symbol 372, in which the value of each digit is dependent on itsposition in the symbol for the number. The decimal system has base 10, and is theonly system in common use.

    Although rational numbers can always be expressed exactly as ratios of integers,this is not so for irrational numbers. For computational purposes, a number that is not an integer is conveniently expressed as a decimal fraction;8 for example,5241=11.25. The general form of the decimal fraction

    (integral part).(fractional part)

    consists of an integer to the left of the decimal point, the integral part of the number,and one or more digits to the right of the decimal point, the decimal or fractional partof the number. The value of each digit is determined by its position; for example

    =12111021+13111011+14111001+15111011+16111021+1711103234 567 200 30 4

    510

    6100

    71000

    . = + + + + +

    6 Leonardo of Pisa, also called Fibonacci (c. 1170after 1240). The outstanding mathematician of the LatinMiddle Ages. In his travels in Egypt, Syria, Greece, and Sicily, Fibonacci studied Greek and Arabic (Muslim) mathematical writings, and became familiar with the Arabic positional number system developed by the Hindumathematicians of the Indus valley of NW India. Fibonaccis rst book, the Liber abaci, or Book of the Abacus,(1202, revised 1228) circulated widely in manuscript, but was published only in 1857 in Scritti di Leonardo Pisano.The rst chapter opens with the quotation given above in the text.

    7 One of the principal sources by which the Hindu-Arabic decimal position system was introduced into (Latin)Europe was Al-Khwarizmis Arithmetic. Muhammad ibn Musa Al-Khwarizmi (Mohammed the son of Mosesfrom Khorezm, modern Khiva in Uzbekistan) was active in the time of the Baghdad Caliph Al-Mamun (813833),and was probably a member of his House of Wisdom (Academy) at a time when Baghdad was the largest city inthe world. Al-Khwarizmis Algebra was widely used in Arabic and in Latin translation as a source on linear andquadratic equations. The word algorithm is derived from his name, and the word algebra comes from the title,Liber algebrae et almucabala, of Robert of Chesters Latin translation (c. 1140) of his work on equations.

    8 The use of decimal fractions was introduced into European mathematics by the Flemish mathematician andengineer Simon Stevin (15481620) in his De Thiende (The art of tenths) in 1585. Although decimal fractions wereused by the Chinese several centuries earlier, and the Persian astronomer Al-Kashi used decimal and sexagesimalfractions in his Key to Arithmetic early in the fteenth century, the common use of decimal fractions in Europeanmathematics can be traced directly to Stevin, especially after John Napier modied the notation into the presentone with the decimal point (or decimal comma as is used in much of continental Europe). It greatly simplied theoperations of multiplication and division.

  • 10 Chapter 1 Numbers, variables, and units

    where 10n1=11210n and 1001=11 (see Section 1.6).0 Exercises 3742

    A number with a nite number of digits after (to the right of ) the decimal point can always be written in the rational form m2n; for example 1.2341=1123421000. Theconverse is not always true however. The number 123 cannot be expressed exactly asa nite decimal fraction:

    the dots indicating that the fraction is to be extended indenitely. If quoted to fourdecimal places, the number has lower and upper bounds 0.3333 and 0.3334:

    where the symbol < means is less than; other symbols of the same kind are for isless than or equal to, > for is greater than, and for is greater than or equal to.Further examples of nonterminating decimal fractions are

    In both cases a nite sequence of digits after the decimal point repeats itselfindenitely, either immediately after the decimal point, as the sequence 142857 in127, or after a nite number of leading digits, as 3 in 1212. This is a characteristicproperty of rational numbers.

    EXAMPLE 1.9 Express 1213 as a decimal fraction. By long division,

    The rational number 12131=10.076923 076923= is therefore a nonterminating decimalfraction with repeating sequence 076923 after the decimal point.

    0 Exercises 4346

    0 0769230713 1 00

    919078120117

    30264039100

    . ...

    .)

    17

    0 142857 1428571

    120 083333 333333= . , = .

    0 3333

    13

    0 3334. < < .

    13

    0 333= .

  • 1.4 Decimal representation of numbers 11

    An irrational number cannot be represented exactly in terms of a nite number ofdigits, and the digits after the decimal point do not show a repeating sequence. Thenumber has approximate value to 16 signicant gures,

    =11.414213 562373 095=and can, in principle, be computed to any desired accuracy by a numerical methodsuch as the NewtonRaphson method discussed in Chapter 20.9

    The Archimedean number

    The number is dened as the ratio of the circumference of a circle to its diameter. It is a transcendental number,10 and has been computed to many signicant gures; it was quoted to 127 decimal places by Euler in 1748. Its value to 16 signicant gures is

    1=13.14159 26535 897931=The value of has been of practical importance for thousands of years. For example,an Egyptian manuscript dated about 1650 BC (the Rhind papyrus in the BritishMuseum) contains a prescription for the calculation of the volume of a cylindricalgranary from which the approximate value 256281113.160 can be deduced. Amethod for generating accurate approximations was rst used by Archimedes11 whodetermined the bounds

    and the upper bound has an error of only 2 parts in a thousand.

    22371

    227

    <

  • 12 Chapter 1 Numbers, variables, and units

    The Euler number e

    The number e is dened by the innite series (see Chapter 7)

    =12.71828 18284 59045=The value of e can be computed from the series to any desired accuracy. The numberwas shown to be a transcendental number by Hermite in 1873.12

    EXAMPLE 1.10 Show that the sum of the rst 10 terms of the series gives anapproximate value of e that is correct to at least 6 signicant gures.

    111+111+10.51+10.1666671+10.0416671+10.0083331+10.0013891+10.000198+10.0000251+10.0000031+10.0000003

    12.71828The value is correct to the 6 gures quoted because every additional term in the seriesis at least ten times smaller than the preceding one.

    Signicant gures and rounding

    In practice, arithmetic involving only integers gives exact answers (unless the numbers are too large to be written). More generally, a number in the decimal system is approximated either with some given number of decimal places or with agiven number of signicant gures, and the result of an arithmetic operation is alsoapproximate. In the xed-point representation, all numbers are given with a xednumber of decimal places; for example,

    3.142, 62.358, 0.013, 1.000

    have 3 decimal places. In the oating-point representation, used more widely in thesciences, the numbers are given with a xed number of signicant gures, with zeroson the left of a number not counted. For example,

    32101=10.321011104, 003.2101=10.321011101, 0.0032101=10.321011102all have 4 signicant gures.

    e = + + + + + + + + +1 1

    12

    16

    124

    1120

    1720

    15040

    140320

    13628880

    13628800

    + +

    e = +

    !+

    !+

    !+

    !+1

    11

    12

    13

    14

    12 Charles Hermite (18221901). French mathematician, professor at the Sorbonne, is known for his work inalgebra and number theory. His work on the algebra of complex numbers (Hermitian forms) became importantin the formulation of quantum theory. The Hermite differential equation and the Hermite polynomials areimportant in the solution of the Schrdinger equation for the harmonic oscillator.

  • 1.5 Variables 13

    A number whose exact (decimal) representation involves more than a given numberof digits is reduced most simply by truncation; that is, by removing or replacing by zeros all superuous digits on the right. For example, to 4 decimal places or 5signicant gures, 3.14159 is truncated to 3.1415. Truncation is not recommendedbecause it can lead to serious computational errors. A more sensible (accurate)approximation of to ve gures is 3.1416, obtained by rounding up. The mostwidely accepted rules for rounding are:

    (i) If the rst digit dropped is greater than or equal to 5, the preceding digit isincreased by 1; the number is rounded up.

    (ii) If the rst digit dropped is less than 5, the preceding digit is left unchanged; thenumber is rounded down. For example, for 4, 3, 2, and 1 decimal places,

    7.36284 is 7.3628, 7.363, 7.36, 7.4

    Errors arising from truncation and rounding are discussed in Section 20.2.

    0 Exercises 47491.5 Variables

    In the foregoing sections, symbols (letters) have been used to represent arbitrarynumbers. A quantity that can take as its value any value chosen from a given setof values is called a variable. If {x1, x2, x3, =, xn} is a set of objects, not necessarily numbers, then a variable x can be dened in terms of this set such that x can have asits value any member of the set; the set forms the domain of the variable. In (real)number theory, the objects of the set are real numbers, and a real variable can have asits domain either the whole continuum of real numbers or a subset thereof. If thedomain of the variable x is an interval a to b,

    a11x11bthen x is a continuous variable in the interval, and can have any value in thecontinuous range of values a to b (including a and b). If the domain consists of a discrete set of values, for example the n numbers x1,1x2,1x3,1=,1xn, then x is called a discrete variable. If the domain consists of integers, x is an integer variable. If the set consists of only one value then the variable is called a constant variable, or simply a constant.

    In the physical sciences, variables are used to represent both numbers and physicalquantities. In the ideal-gas example discussed in Section 1.1, the physical quantitiesp, V, n, and T are continuous variables whose numerical values can in principle be anypositive real numbers. Discrete variables are normally involved whenever objects are counted as opposed to measured. Typically, an integer variable is used for thecounting and the counted objects form a sample of some discrete set. In some caseshowever a physical quantity can have values, some of which belong to a discrete setand others to a continuous set. This is the case for the energy levels and the observedspectral frequencies of an atom or molecule.

  • 14 Chapter 1 Numbers, variables, and units

    EXAMPLE 1.11 The spectrum of the hydrogen atom

    The energy levels of the hydrogen atom are of two types:

    (i) Discrete (quantized) energy levels with (negative) energies given by the formula(in atomic units, see Section 1.8)

    n1=11, 2, 3, =The corresponding states of the atom are the bound states, in which the motion ofthe electron is conned to the vicinity of the nucleus. Transitions between the energylevels give rise to discrete lines in the spectrum of the atom.

    (ii) Continuous energy levels, with all positive energies, E1>10. The correspondingstates of the atom are those of a free (unbound) electron moving in the presence of theelectrostatic eld of the nuclear charge. Transitions between these energy levels andthose of the bound states give rise to continuous ranges of spectral frequencies.

    1.6 The algebra of real numbers

    The importance of the concept of variable is that variables can be used to make statements about the properties of whole sets of numbers (or other objects), and itallows the formulation of a set of rules for the manipulation of numbers. The set ofrules is called the algebra.

    Let a, b, and c be variables whose values can be any real numbers. The basic rules forthe combination of real numbers, the algebra of real numbers or the arithmetic, are

    1. a1+1b1=1b1+1a (commutative law of addition)2. ab1=1ba (commutative law of multiplication)3. a1+1(b1+1c)1=1(a1+1b)1+1c (associative law of addition)4. a(bc)1=1(ab)c (associative law of multiplication)5. a(b1+1c)1=1ab1+1ac (distributive law)

    The operations of addition and multiplication and their inverses, subtraction anddivision, are called arithmetic operations. The symbols +, , and (or 2) are calledarithmetic operators. The result of adding two numbers, a1+1b, is called the sum of aand b; the result of multiplying two numbers, ab1=1a11b1=1a11b, is called the productof a and b.13

    En

    n = ,1

    2 2

    13 In 1698 Leibniz wrote in a letter to Johann Bernoulli: I do not like as a symbol for multiplication, as it easily confounded with x = often I simply relate two quantities by an interposed dot. It is becoming accepted practiceto place the dot in the high position to denote multiplication (2115 = 2 5) and in the low position, on the line,for the decimal point (2.5 = 522). An alternative convention, still widely used, is to place the dot on the line formultiplication (2.5 = 2 5) and high for the decimal point (2115 = 522).

  • 1.6 The algebra of real numbers 15

    EXAMPLES 1.12 Examples of the rules of arithmetic

    rule examples

    1. a1+1b1=1b1+1a 21+131=131+121=152. ab1=1ba 21131=131121=163. a1+1(b1+1c)1=1(a1+1b)1+1c !21+1(31+14)1=121+171=19, and

    @(21+13)1+141=151+141=194. a(bc)1=1(ab)c !211(3114)1=1211121=124, and

    @(2113)1141=161141=1245. a(b1+1c)1=1ab1+1ac !211(31+14)1=121171=114, and

    @211(31+14)1=1(2113)1+1(2114)1=161+181=1142(31+14)1=1(2113)1+1(2114)1=161181=1142(3114)1=1211311211(4)1=161+181=12

    A corollary to rule 5 is(a1+1b)(c1+1d)1=1a(c1+1d)1+1b(c1+1d) (21+13)(41+15)1=12(41+15)1+13(41+15)1=1181+1271=145

    Three rules dene the properties of zero and unity:

    6. a1+101=101+1a1=1a (addition of zero)7. a1101=1011a1=10 (multiplication by zero)8. a1111=1111a1=1a (multiplication by unity)

    We have already seen that subtraction of a number is the same as addition of its negative, and that division by a number is the same as multiplication by its inverse.However, division by zero is not dened; there is no number whose inverse is zero.For example, the number 12a, for positive values of a, becomes arbitrarily large as thevalue of a approaches zero; we say that 12a tends to innity as a tends to zero:

    Although innity is represented by the symbol , it is not a number. If it were a number then, by the laws of algebra, the equations 1201=1 and 2201=1 would imply11=12.

    The modulus of a real number a is dened as the positive square root of a2;

    (read as mod a). It is the magnitude of the number, equal to +a if a ispositive, and equal to a if a is negative:

    (1.13)

    For example, and .| | =3 3| |3 3=

    | |aa a

    a a=

    + >

    10 and to the left if x110 and below if y1

  • 2.3 Factorization and simplication of expressions 35

    The inverse operation of factorization is usually called expansion or multiplyingout.

    EXAMPLE 2.6 Factorize:

    (i) 2xy2114x2y1+16xyThe expression 2xy is a common factor. Therefore

    2xy2114x2y1+16xy1=1(2xy)11(y)11(2xy)11(2x)1+1(2xy)11(3) =12xy(y112x1+13)(ii) x2115x116

    The aim is to express the quadratic function as the product of two linearfunctions; that is, to nd numbers a and b such that

    x2115x1161=1(x1+1a)(x1+1b)Expansion of the product gives

    (x1+1a)(x1+1b)1=1x(x1+1b)1+1a(x1+1b)1=1x21+1bx1+1ax1+1aband, therefore,

    x2115x1161=1x21+1(a1+1b)x1+1abFor this equation to be true for all values of x it is necessary that the coefcient of each power of x be the same on both sides of the equal sign: a1+1b1=15 andab1=16. The two numbers whose sum is 5 and whose product is 6 are a1=16and b1=11. Therefore

    x2115x1161=1(x116)(x1+11)(iii) x2119

    Let x21191=1(x1+1a)(x1+1b)1=1x21+1(a1+1b)x1+1ab. In this case there is no term linearin x: a1+1b1=10, so that b1=1a and ab1=1a21=19. Therefore and thefactorization is

    x21191=1(x1+13)(x113)This is an example of the general form x211a21=1(x1+1a)(x11a).

    (iv) x4115x21+14The quartic in x is a quadratic in disguise. Replacement of x2 by y, followed byfactorization gives

    y2115y1+141=1( y111)( y114)

    a = = 9 3

  • 36 Chapter 2 Algebraic functions

    Therefore

    x4115x21+141=1(x2111)(x2114)Both the quadratic factors have the form x211a21=1(x1+1a)(x11a) discussed incase (iii) above:

    x21111=1(x1+11)(x111) and x21141=1(x1+12)(x112)Therefore,

    x4115x21+141=1(x1+11)(x111)(x1+12)(x112)0 Exercises 916

    The expansion

    (x1+1a)(x1+1b)1=1x21+1(a1+1b)x1+1ab (2.4)used in Examples 2.6, has geometric interpretation as the area of a rectangle of sides(x1+1a) and (x1+1b), as illustrated in Figure 2.3.3

    Other important general forms are

    (a1+1b)21=1a21+12ab1+1b2 square of side (a1+1b)(a11b)21=1a2112ab1+1b2 square of side |a11b | (2.5)(a1+1b)(a11b)1=1a211b2 difference of squares

    The rst two equations of (2.5) can be combined by using the symbol , meaning plusor minus:

    (a11b)21=1a2112ab1+1b2 (2.6)in which either the upper symbol is used on both sides of the equation or the lowersymbol is used on both sides. Sometimes the symbol 3 is used in a similar way; forexample, a131b1=1c represents the pair of equations a11b1=1+c and a1+1b1=1c.

    Factorization can be used to simplify algebraic fractions. For example, in

    xy xx xy

    +

    +

    24 6

    2

    3 Euclid, The Elements, Book II, Propositions 4 and 7 are the geometric equivalents of the rst two equations(2.5) for the squares of (a1+1b) and (a11b).

    ...........................................................................................................................................................................................................................................................................................................................................................................

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    bx ab

    x

    2

    ax

    b

    x

    x a

    Figure 2.3

  • 2.4 Inverse functions 37

    both numerator and denominator have the common factor x, and can be divided bythis factor (when x110) without changing the value of the fraction:

    EXAMPLE 2.7 Simplication of fractions

    (1)

    (2)

    (3)

    0 Exercises 1722

    2.4 Inverse functions

    Given some function f and the equation y1=1f(x), it is usually possible to dene, at leastfor some values of x and y, a function g such that x1=1g(y). This new function is theinverse function of f and is denoted by the symbol f 1 (not to be confused with thereciprocal 12f ):

    if y1=1f(x) then x1=1f 1( y) (2.7)

    EXAMPLE 2.8 If y1=1f(x)1=12x1+13, nd x1=1f 1(y).To nd x in terms of y,

    (i) subtract 3 from both sides of the equation: y1=12x1+1311y1131 =12x(ii) divide both sides by 2:

    Therefore x1=1( y113)221=1f 1( y).In this example, y is a single-valued function of x; that is, for each value of x there

    exists just one value of y. Similarly, x is a single-valued function of y.

    0 Exercises 2325

    EXAMPLE 2.9 If , express x in terms of y. y

    ax bcx d

    =

    +

    +

    =

    yx

    32

    a b

    a ab b

    a b a b

    a b a b

    a ba

    2 2

    2 22

    + +=

    +

    + +=

    ( ) ( )

    ( ) ( )

    ( )( ++ b)

    3 69 18

    3 1 2

    3 1 2

    1 23 1 22

    +

    +=

    +

    +=

    +

    +

    yx

    y

    x

    yx

    ( )

    ( ) ( )

    42

    2 22

    2xy

    xy

    xy

    =

    =

    ( )( )

    xy xx xy

    x y xx y

    y xy

    +

    +=

    +

    +=

    +

    +

    24 6

    22 2 3

    22 2 3

    2 ( )( ) ( )

  • 38 Chapter 2 Algebraic functions

    To solve for x,

    (i) multiply both sides of the equation by (cx1+1d): (cx1+1d)y1=1ax1+1b(ii) expand the l.h.s.: cxy1+1dy1=1ax1+1b

    (iii) subtract (ax1+1b) from both sides: cxy1+1dy11ax11b1=10(iv) collect the terms in x1 and x0: (cy11a)x1+1(dy11b)1=10(v) subtract (dy11b) from both sides: (cy11a)x1=1(dy11b)

    (vi) divide both sides by (cy11a):We note that step (vi) is not valid if (cy11a)1=10 because division by zero has nomeaning. Such complications can normally be ignored.

    This example demonstrates the type of algebraic manipulation routinely used inthe solution of real problems.

    0 Exercises 2629EXAMPLE 2.10 If y1=1f(x)1=1x21+11, express x in terms of y.We have

    y1=1x21+11, x21=1y111,y is a single-valued function of x, but x is a double-valued function of y (except fory1=11); that is, for each real value of y1>11 there exist two real values of x (if y1

  • 2.4 Inverse functions 39

    In physical applications it is usually obvious from the context which value is to bechosen. It is also seen, when x and y are real numbers, that whereas y is dened for allvalues of x, 1

  • 40 Chapter 2 Algebraic functions

    EXAMPLE 2.12 The van der Waals equation

    The equation of state for a slightly imperfect gas is

    (2.8)

    In this case, both T and p are easily expressed as explicit functions of the other variables:

    For V, equation (2.8) can be rearranged into

    which is a cubic equation in V. It is possible to write down explicit solutions of a cubic equation, but these are complicated and seldom used. In this case, it is mostconvenient to regard equation (2.8) as dening V as an implicit function of p, T, andn. For any set of values of the independent variables and of the constants, equation(2.8) can be solved numerically by an iterative method such as the NewtonRaphsonmethod described in Chapter 20.

    0 Exercises 32352.5 Polynomials

    The general polynomial of degree n has the form

    f(x)1=1a01+1a1x1+1a2x21+1-1+1anxn (2.9)where the coefcients a0,1a1,1=,1an are constants, and n is a positive integer. Ifn1=10 the function is the constant a0. The polynomial is often written in short-handnotation as

    (2.10)

    where the symbol represents summation. The notation tells us to add together theterms aix

    i in which the integer variable i takes in turn the values 0, 1, 2,1=1, n:

    = a01+1a1x1+1a2x21+1-1+1anxn(remembering that x01=11 and x11=1x).

    i

    n

    ii

    nna x a x a x a x a x

    =

    = + + + +0

    00

    11

    22( ) ( ) ( ) ( )

    f x a xi

    n

    ii( ) =

    =

    0

    V n b

    RTp

    Vn a

    pV

    n abp

    3 22 3

    0 +

    + =

    TnR

    pn a

    VV nb p

    nRTV nb

    n a

    V= +

    =

    1 2

    2

    2

    2( ),

    pn a

    VV nb nRT+

    =

    2

    20( )

  • Only real coefcients are discussed here; the case of complex coefcients is shownin Section 8.4 to involve no new principles.

    EXAMPLE 2.13 Write out in full:

    (1)

    (2)

    (3)

    0 Exercises 3639Degree n1=11: linear function

    f(x)1=1a01+1a1x (2.11)This is the simplest type of function, and is better known in the form

    y1=1mx1+1c (2.12)The graph of the function is a straight line. It has slope m, and intercepts the verticaly-axis (when x1=10) at the point y1=1c, as shown in Figure 2.6.

    If we take any two points on the line, with coordinates (x1, y1) and (x2, y2), then

    y11=1mx11+1cy21=1mx21+1c

    ( ) ( ) ( ) ( ) = + + = +=

    x x x x x x xii

    2 3 4 2 3 4

    2

    4

    xn

    x x x xx

    x x xn

    n

    2 1 1 1 3 5 3 5

    0

    3

    1 1 2 3 41

    2 3 4

    =+

    = + + + = + + +

    i x x x x x x x xi

    i

    = + + + = + +=

    0 1 2 3 2 30 1 2 3 2 30

    3

    2.5 Polynomials 41

    ........ ........ ........ ........ ........ ........ ....

    ........ ........ ........ ........ ........ ........ ........ ........ ........ ........ ........ ........ ........ ........ ........ ........

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    Figure 2.6

  • 42 Chapter 2 Algebraic functions

    and

    (2.13)

    denes the constant slope. The line crosses the horizontal x-axis at one point:

    y1=10 when (2.14)This value of x is called the root of the linear function. In general, the roots of apolynomial function are those values of the variable for which the value of the functionis zero; that is, the roots are the solutions of the polynomial equation

    f(x)1=10 (2.15)

    EXAMPLE 2.14 Find the equation of the straight line that passes through the points(1, 6) and (3, 2).

    Let the line be y1=1mx1+1c. Then:at point (x1, y1)1=1(1, 6), 61=1m1+1cat point (x2, y2)1=1(3, 2), 21=13m1+1c

    Solution of the pair of simultaneous equations (see Section 2.8) gives m1=12 and c1=14. Therefore

    y1=12x114The graph of the line is shown in Figure 2.7. The line has slope m1=12, which meansthat the value of y increases twice as fast as that of x. The line crosses the y-axis aty1=1c1=14, and crosses the x-axis at x1=12.

    0 Exercises 4043

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    Figure 2.7

  • 2.5 Polynomials 43

    Degree n1=12: quadratic functionf(x)1=1a01+1a1x1+1a2x2 (2.16)

    The quadratic function is usually written as

    y1=1ax21+1bx1+1c (2.17)A typical graph is shown in Figure 2.1 in Section 2.2. The shape of the curve is that ofa parabola. When the constant a is positive, the function has a single minimum value(turning point), and is symmetrical about a vertical line that passes through the pointof minimum value. For the function in Figure 2.1,

    f(x)1=1x2112x113 (2.18)this minimum point has coordinates (x, y)1=1(1, 4). The graph crosses the x-axis,when f(x)1=10, at the two points x1=11 and x1=13. These are the roots of the quadraticfunction, and they are the solutions of the quadratic equation

    x2112x1131=10 (2.19)In this example the roots are easily obtained by factorization:

    x2112x1131=1(x1+11)(x113)and the function is zero when either of the linear factors is zero:

    (the symbol means implies)Whilst it is possible to factorize a variety of quadratic functions by trial and error,

    as in Examples 2.6, the roots can always be found by formula:4

    ax21+1bx1+1c1=10when

    (2.20)xb b ac

    a=

    2 42

    x x

    x x

    x x2 2 3 0

    1 0 1

    3 0 3 =

    + = =

    = =

    when eitheror

    4 A clay tablet (YBC 6967, Yale Babylonian Collection) of the Old Babylonian Period (c. 18001600 BC)has inscribed on it in the Sumerian cuneiform script the following problem (in modern notation): giventhat xy1=160 and x11y1=17, nd x and y. The prescription given for the (positive) solution corresponds to

    and . The method and prescriptive approach is almost identical to that used by Al-Khwarizmi two and a half millennia later. Modern algebra became possible with thedevelopment of a general abstract notation in the 15th to 17th centuries. One important step was taken by FranoisVite (15401603). French lawyer, politician, cryptoanalyst, and amateur mathematician, he made contributionsto trigonometry and algebra. He is best remembered as the man who, in his In artem analyticem isagoge(Introduction to the analytical art) of 1591, introduced the systematic use of symbols (letters) into the theory ofequations, distinguishing between constants and variables.

    y = + ( ) ( )7 2 60 7 22x = + +( ) ( )7 2 60 7 22

  • 44 Chapter 2 Algebraic function